Mo. Code Regs. tit. 10 § 10-6.040
Current through Register Vol. 49, No. 24, December 16, 2024
Section 10 CSR 10-6.040 - Reference MethodsPURPOSE: This rule provides reference methods for determining ambient air/atmosphere data and information necessary for the enforcement of air pollution control regulations throughout Missouri.
PUBLISHER'S NOTE: The secretary of state has determined that the publication of the entire text of the material which is incorporated by reference as a portion of this rule would be unduly cumbersome or expensive. This material as incorporated by reference in this rule shall be maintained by the agency at its headquarters and shall be made available to the public for inspection and copying at no more than the actual cost of reproduction. This note applies only to the reference material. The entire text of the rule is printed here.
(1) The percent sulfur in solid fuels shall be determined as specified by American Society of Testing and Materials (ASTM) D4239 - 17 Standard Test Method for Sulfur in the Analysis Sample of Coal and Coke Using High-Temperature Tube Furnace Combustion, as approved and published in 2017, as specified in section (36) of this rule.(2) The heat content or higher heating value (HHV) of solid fuels shall be determined by use of the Adiabatic Bomb Calorimeter as specified by ASTM D5865 - 13 Standard Test Method for Gross Calorific Value of Coal and Coke, as approved and published in 2013, as specified in section (36) of this rule.(3) The heat content or HHV of liquid hydrocarbons shall be determined as specified by ASTM D240 - 17 Standard Test Method for Heat of Combustion of Liquid Hydrocarbon Fuels by Bomb Calorimeter, as approved and published in 2017, as specified in section (36) of this rule.(4) The methods for determining the concentrations of the following air contaminants shall be as specified in 40 CFR 50, Appendices A- R or equivalent methods as specified in 40 CFR 53 . The provisions of 40 CFR 50, Appendices A-R, and 40 CFR 53, both promulgated as of July 1, 2018, apply and are hereby incorporated by reference in this rule, as published by the Office of the Federal Register. Copies can be obtained from the U.S. Publishing Office Bookstore, 710 N. Capitol Street N W, Washington DC 20401. This rule does not incorporate any subsequent amendments or additions.
(A) The concentration of sulfur dioxide shall be determined as specified in 40 CFR 50, Appendix A-Reference Method for the Determination of Sulfur Dioxide in the Atmosphere (Pararosaniline Method) or an equivalent method as approved by 40 CFR 53, as incorporated by reference in section (4) of this rule.(B) The concentration of total suspended particulate shall be determined as specified in 40 CFR 50, Appendix B-Reference Method for the Determination of Suspended Particulate Matter in the Atmosphere (High-Volume Method), as incorporated by reference in section (4) of this rule.(C) The concentration of carbon monoxide shall be determined as specified in 40 CFR 50, Appendix C-Measurement Principle and Calibration Procedure for the Measurement of Carbon Monoxide in the Atmosphere (Non-Dispersive Infrared Photometry) or equivalent methods as approved by 40 CFR 53, as incorporated by reference in section (4) of this rule.(D) The concentration of ozone shall be determined as specified in 40 CFR 50, Appendix D-Measurement Principle and Calibration Procedure for the Measurement of Ozone in the Atmosphere or equivalent methods as approved by 40 CFR 53, as incorporated by reference in section (4) of this rule.(F) The concentration of nitrogen dioxide shall be determined as specified in 40 CFR 50, Appendix F-Measurement Principle and Calibration Procedure for the Measurement of Nitrogen Dioxide in the Atmosphere (Gas Phase Chemiluminescence) or equivalent methods as approved by 40 CFR 53, as incorporated by reference in section (4) of this rule.(G) The concentration of lead shall be determined as specified in 40 CFR 50, Appendix G-Reference Method for the Determination of Lead in Suspended Particulate Matter Collected From Ambient Air or in 40 CFR 50, Appendix Q-Reference Method for the Determination of Lead in Particulate Matter as PM10 Collected From Ambient Air or equivalent methods as approved by 40 CFR 53, as incorporated by reference in section (4) of this rule.(H) Compliance with the one (1) hour ozone standard shall be determined as specified in 40 CFR 50, Appendix H-Interpretation of the 1-Hour Primary and Secondary National Ambient Air Quality Standards for Ozone, as incorporated by reference in section (4) of this rule.(I) Compliance with the eight (8) hour ozone standards shall be determined as specified in 40 CFR 50, Appendix I-Interpretation of the 8-Hour Primary and Secondary National Ambient Air Quality Standards for Ozone, as incorporated by reference in section (4) of this rule.(J) The concentration of particulate matter 10 micron (PM10) shall be determined as specified in 40 CFR 50, Appendix J-Reference Method for the Determination of Particulate Matter as PM10 in the Atmosphere, or an equivalent method as approved in 40 CFR 53, as incorporated by reference in section (4) of this rule.(K) Compliance with particulate matter 10 PM10 standards shall be determined as specified in 40 CFR 50, Appendix K- Interpretation of the National Ambient Air Quality Standards for Particulate Matter, as incorporated by reference in section (4) of this rule.(L) The concentration of particulate matter 2.5 micron (PM2.5) shall be determined as specified in 40 CFR 50, Appendix L- Reference Method for the Determination of Fine Particulate Matter as PM2.5 in the Atmosphere, or an equivalent method as approved in 40 CFR 53, as incorporated by reference in section (4) of this rule.(M) Compliance with particulate matter 2.5 (PM2.5) standards shall be determined as specified in 40 CFR 50, Appendix N- Interpretation of the National Ambient Air Quality Standards for PM2.5, as incorporated by reference in section (4) of this rule.(N) Compliance with the eight (8)-hour ozone standards shall be determined as specified in 40 CFR 50, Appendix P-Interpretation of the Primary and Secondary National Ambient Air Quality Standards for Ozone, as incorporated by reference in section (4) of this rule.(O) Compliance with the lead standards shall be determined as specified in 40 CFR 50, Appendix R-Interpretation of the National Ambient Air Quality Standards for Lead, as incorporated by reference in section (4) of this rule.(5) The concentration of hydrogen sulfide (H2S) shall be determined by scrubbing all sulfur dioxide (SO2) present in the sample and then converting each molecule of H2S to SO2 with a thermal converter so that the resulting SO2 is detected by an analyzer as specified in 40 CFR 50, Appendix A-Reference Method for the Determination of Sulfur Dioxide in the Atmosphere (Pararosaniline Method) or an equivalent method approved by 40 CFR 53, as incorporated by reference in section (4) of this rule, in which case the calibration gas used must be National Institute of Standards and Technology traceable H2S gas.(6) The concentration of sulfuric acid mist shall be determined as specified in the Compendium Method IO-4.2, Determination of Reactive Acidic and Basic Gases and Strong Acidity of Atmospheric Fine-Particles (<2.5 µm), EPA/625/R-96/010a, as published by E PA June 1999 and hereby incorporated by reference in this rule. Copies can be obtained from the National Technical Information Service (NTIS), 5285 Port Royal Road, Springfield VA 22161. This rule does not incorporate any subsequent amendments or additions.(7) The percent sulfur in liquid hydrocarbons shall be determined as specified by ASTM D2622 - 16 Standard Test Method for Sulfur in Petroleum Products by Wavelength Dispersive X-ray Fluorescence Spectrometry, as approved and published in 2016, as specified in section (36) of this rule.(8) The amount of solvent present in earth filters and distillation wastes shall be determined as specified by ASTM D322 - 97(2016) Standard Test Method for Gasoline Diluent in Used Gasoline Engine Oils by Distillation, as approved and published in 2016, as specified in section (36) of this rule.(9) The atmospheric distillation of petroleum products and liquid fuels shall be determined as specified by ASTM D86-17 Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure, as approved and published in 2017, as specified in section (36) of this rule.(10) The pour point of petroleum specimens shall be determined as specified by ASTM D97-17a Standard Test Method for Pour Point of Petroleum Products, as approved and published in 2017, as specified in section (36) of this rule.(11) The vapor pressure of petroleum products shall be determined as specified by ASTM D323-15a Standard Test Method for Vapor Pressure of Petroleum Products (Reid Method), as approved and published in 2015, as specified in section (36) of this rule.(12) The specification for fuel oil shall be determined as specified by ASTM D396-17 Standard Specification for Fuel Oils, as approved and published in 2017, as specified in section (36) of this rule.(13) The gloss measurement rating shall be determined as specified by ASTM D523-14 Standard Test Method for Specular Gloss, as approved and published in 2014, as specified in section (36) of this rule.(14) The specification for diesel fuel oils shall be determined as specified by ASTM D975-17 Standard Specification for Diesel Fuel Oils, as approved and published in 2017, as specified in section (36) of this rule.(15) The specification for emulsified asphalt shall be determined as specified by ASTM D977-17 Standard Specification for Emulsified Asphalt, as approved and published in 2017, as specified in section (36) of this rule.(16) The chemical composition reformed and similar gases shall be determined as specified by ASTM D1946-90(2015)e1 Standard Practice for Analysis of Reformed Gas by Gas Chromatography, as approved and published in 2015, as specified in section (36) of this rule.(17) The practice for the reduction and division of gross or divided samples and the preparation of composite samples shall be determined as specified by ASTM D2013/D2013M-12 Standard Practice for Preparing Coal Samples for Analysis, as approved and published in 2012, as specified in section (36) of this rule.(18) The procedure for collection of samples shall be determined as specified by ASTM D2234/D2234M-16 Standard Practice for Collection of a Gross Sample of Coal, as approved and published in 2016, as specified in section (36) of this rule.(19) The specification of grades of cationic emulsified asphalt shall be determined as specified by ASTM D2397/D2397M-17 Standard Specification for Cationic Emulsified Asphalt, as approved and published in 2017, as specified in section (36) of this rule.(20) The properties of fuels shall be determined as specified by ASTM D2880-15 Standard Specification for Gas Turbine Fuel Oils, as approved and published in 2015, as specified in section (36) of this rule.(21) The formulas that allow analytical data to be expressed in various bases shall be determined as specified by ASTM D3180-15 Standard Practice for Calculating Coal and Coke Analyses from As-Determined to Different Bases, as approved and published in 2015, as specified in section (36) of this rule.(22) The procedures and equipment for manually obtaining samples of liquid petroleum and petroleum products shall be determined as specified by ASTM D4057-12 Practice for Manual Sampling of Petroleum and Petroleum Products, as approved and published in 2012, as specified in section (36) of this rule.(23) The determination of H2S in gaseous fuels shall be determined as specified by ASTM D4084-07(2012) Standard Test Method for Analysis of Hydrogen Sulfide in Gaseous Fuels (Lead Acetate Reaction Rate Method), as approved and published in 2012, as specified in section (36) of this rule.(24) The determination of sulfur in samples of coal or coke shall be determined as specified by ASTM D4239-17 Standard Test Method for Sulfur in the Analysis Sample of Coal and Coke Using High-Temperature Tube Furnace Combustion, as approved and published in 2017, as specified in section (36) of this rule.(25) The determination of the heat of combustion of hydrocarbon fuels shall be determined as specified by ASTM D4809-13 Standard Test Method for Heat of Combustion of Liquid Hydrocarbon Fuels by Bomb Calorimeter (Precision Method), as approved and published in 2013, as specified in section (36) of this rule.(26) The determination of gasoline and gasoline-oxygenate blends shall be determined as specified by ASTM D4953-15 Standard Test Method for Vapor Pressure of Gasoline and Gasoline-Oxygenate Blends (Dry Method), as approved and published in 2015, as specified in section (36) of this rule.(27) The use of automated vapor pressure instruments to determine the total vapor pressure shall be determined as specified by ASTM D5191-15 Standard Test Method for Vapor Pressure of Petroleum Products (Mini Method), as approved and published in 2015, as specified in section (36) of this rule.(28) The determination of speciated volatile sulfur-containing compounds in high methane content gaseous fuels shall be determined as specified by ASTM D5504-12 Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence, as approved and published in 2012, as specified in section (36) of this rule.(29) The determination of the gross calorific value of coal and coke shall be determined as specified by ASTM D5865-13 Standard Test Method for Gross Calorific Value of Coal and Coke, as approved and published in 2013, as specified in section (36) of this rule.(30) The determination of total mercury in natural gas shall be determined as specified by ASTM D5954-98(2014)e1 Standard Test Method for Mercury Sampling and Measurement in Natural Gas by Atomic Absorption Spectroscopy, as approved and published in 2014, as specified in section (36) of this rule.(31) The determination of individual volatile sulfur-containing compounds in gaseous fuels shall be determined as specified by ASTM D6228-10 Standard Practice for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatographs and Flame Photometric Detection, as approved and published in 2010, as specified in section (36) of this rule.(32) This test method shall be used to determine the total mercury concentration of a natural gas stream as specified by ASTM D6350-14 Standard Test Method for Mercury Sampling and Analysis in Natural Gas by Atomic Fluorescence Spectroscopy, as approved and published in 2010, as specified in section (36) of this rule.(33) The use of automated vapor pressure instruments to determine the vapor pressure exerted in vacuum by volatile, liquid petroleum products, hydrocarbons, and hydrocarbon-oxygenate mixtures shall be determined as specified by ASTM D6378-10(2016) Standard Test Method for Determination of Vapor Pressure (VPX) of Petroleum Products, Hydrocarbons, and Hydrocarbon-Oxygenate Mixtures (Triple Expansion Method), as approved and published in 2016, as specified in section (36) of this rule.(34) The determination of elemental, oxidized, particle-bound, and total mercury emissions from coal-fired stationary sources shall be determined as specified by ASTM D6784-16 Standard Test Method for Elemental, Oxidized, Particle-Bound and Total Mercury in Flue Gas Generated from Coal-Fired Stationary Sources (Ontario Hydro Method), as approved and published in 2016, as specified in section (36) of this rule.(35) The determination of the vapor pressure of pure liquids, the vapor pressure exerted by mixtures in a closed vessel at 40 ± 5% ullage, and the initial thermal decomposition temperature of pure and mixed liquids shall be determined as specified by ASTM D2879-10 Standard Test Method for Vapor Pressure-Temperature Relationship and Initial Decomposition Temperature of Liquids by Isoteniscope, as approved and published in 2010, as specified in section (36) of this rule.(36) All of the documents in sections (1) through (3) and (7) through (35) of this rule are published by the American Society for Testing and Materials (ASTM) and incorporated by reference in this rule. Copies can be obtained from ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. This rule does not incorporate any subsequent amendments or additions. AUTHORITY: section 643.050, RSMo Supp. 2012.* Original rule filed Aug. 16, 1977, effective Feb. 11, 1978. Amended: Filed Sept. 14, 1978, effective 4/12/1979. Amended: Filed Dec. 10, 1979, effective April 11, 1980. Amended: Filed March 13, 1980, effective 9/12/1980. Amended: Filed Feb. 14, 1984, effective 7/12/1984. Amended: Filed Jan. 5, 1988, effective 4/28/1988. Amended: Filed Oct. 13, 2000, effective 7/30/2001. Amended: Filed July 6, 2005, effective 2/28/2006. Amended: Filed Sept. 24, 2009, effective 5/30/2010. Amended: Filed March 18, 2013, effective 11/30/2013. Amended by Missouri Register October 1, 2014/Volume 39, Number 19, effective 11/30/2014Amended by Missouri Register December 3, 2018/Volume 43, Number 23, effective 1/29/2019*Original authority: 643.050, RSMo 1965, amended 1972, 1992, 1993, 1995, 2011.