Wis. Admin. Code NR § 284.22

Current through May 28, 2024
Section NR 284.22 - Discharge standards
(1) PRETREATMENT STANDARDS FOR EXISTING SOURCES (PSES). Except as provided in ss. NR 211.13 and pertaining 211.14 to removal credits and fundamentally different factors, any existing source subject to this section which introduces pollutants into a publicly owned treatment works shall comply with ch. NR 211 and achieve the following pretreatment standards for existing sources by July 1, 1984:
(a) The daily maximum limitations for PCP, TCP and zinc are set forth in Table 6 in both lbs/ton and mg/l.
(b) PCP and TCP limitations are only applicable to facilities where chlorophenolic-containing biocides are used. Permittees not using chlorophenolic-containing biocides shall certify to the control authority that they are not using these biocides.
(c) Zinc limitations are only applicable to groundwood facilities where zinc hydrosulfite is used as a bleaching agent. Groundwood facilities not using zinc hydrosulfite as a bleaching agent shall certify to the control authority that they are not using this bleaching compound.

TABLE 6

PSES Effluent Limitations

PCP1

TCP1

Zinc2

maximum for any one day

maximum for any one day

maximum for any one day

Subcategory

lbs/ton

mg/1

lbs/ton

mg/1

lbs/ton

mg/1

Integrated Facilities

1.

BCT Bleached Kraft

0.0032

(0.011)(35.4)/y

0.024

(0.082)(35.4)/y

2.

Fine Bleached Kraft

0.0028

(0.011)(30.9)/y

0.022

(0.082)(30.9)/y

3.

Groundwood-CMN Papers

0.0022

(0.011)(23.8)/y

0.00198

(0.010)(23.8)/y

0.6

(3.0)(23.8)/y

4.

Groundwood-Chemi-Mechanical

-

-

-

-

-

-

5.

Groundwood-Fine Papers

0.002

(0.011)(21.9)/y

0.00184

(0.010)(21.9)/y

0.54

(3.0)(21.9)/y

6.

Groundwood-Thermo-Mechanical

0.00194

(0.011)(21.1)/y

0.00176

(0.010)(21.1)/y

0.52

(3.0)(21.1)/y

7.

Papergrade Sulfite

0.00116

((0.011)(12.67)

0.0086

((0.082)(12.67)

(Blow Pit Wash)

exp(0.017x;

) exp(0.017x))/y

exp(0.017x

) exp(0.017x))/y

8.

Papergrade Sulfite

0.00116

((0.011)(12.67)

0.0086

((0.082)(12.67)

(Drum Wash)

exp(0.017x;

) exp(0.017x))/y

exp(0.017x

) exp(0.017x))/y

9.

Semi-Chemical

0.0028

(0.032)(10.3)/y

0.00086

(0.010)(10.3)/y

10.

Soda

0.0028

(0.011)(30.9)/y

0.022

(0.082)(30.9)/y

11.

Unbleached Kraft

0.00116

(0.011)(12.6)/y

0.00106

(0.010)(12.6)/y

12.

Unbleached Kraft and Semi-Chemical

0.00128

(0.011)(14.0)/y

0.00118

(0.010)(14.0)/y

13.

Unbleached Kraft-Neutral Sulfite Semi-Chemical (Cross Recovery)

0.00128

(0.011)(14.0)/y

0.00118

(0.010)(14.0)/y

Nonintegrated Facilities

14.

Nonintegrated-Filter and Nonwoven Papers

0.016

(0.032)(59.9)/y

0.005

(0.010)(59.9)/y

15.

Nonintegrated-Fine Papers

(a) Wood fiber furnish subdivision

0.004

(0.032)(15.2)/y

0.00128

(0.010)(15.2)/y

(b) Cotton fiber furnish subdivision

0.0112

(0.032)(42.3)/y

0.0036

(0.010)(42.3)/y

16.

Nonintegrated-Lightweight Papers

0.013

(0.032)(48.7)/y

0.004

(0.010)(48.7)/y

(a) Facilities where electrical grade papers are produced

0.02

(0.032)(76.9)/y

0.0064

(0.010)(76.9)/y

17.

Nonintegrated Paperboard

0.0034

(0.032)(12.9)/y

0.00108

(0.010)(12.9)/y

18.

Nonintegrated-Tissue Papers

0.0062

(0.032)(22.9)/y

0.00192

(0.010)(22.9)/y

From Wastepaper Facilities

19.

Builders' Paper and Roofing Felt

0.0038

(0.032)(14.4)/y

0.0012

(0.010)(14.4)/y

20.

Deink

(a) Facilities where fine or tissue paper is produced

0.0066

(0.032)(24.4)/y

0.0168

(0.082)(24.4)/y

(b) Facilities where newsprint is produced

0.0066

(0.032)(24.4)/y

0.002

(0.010)(24.4)/y

21.

Paperboard FWP

0.00192

(0.032)(7.2)/y

0.0006

(0.010)(7.2)/y

22.

Tissue FWP

0.0068

(0.032)(25.2)/y

0.00192

(0.010)(25.2)/y

23.

Wastepaper-Molded Products

0.0056

(0.032)(21.1)/y

0.00176

(0.010)(21.1)/y

Pu

lp Facilities

24.

Dissolving Kraft

0.005

(0.011)(55.1)/y

0.038

(0.082)(55.1)/y

25.

Dissolving Sulfite Pulp

(a) Facilities where nitration, viscose or cellophane grade pulps are produced

0.006

(0.011)(66.0)/y

0.046

(0.082)(66.0)/y

(b) Facilities where acetate grade pulp is produced

0.0066

(0.011)(72.7)/y

0.05

(0.082)(72.7)/y

26.

Market Bleached Kraft

0.0038

(0.011)(41.6)/y

0.028

(0.082)(41.6)/y

Mass limitations are in lbs/ton except where otherwise stated. For kg/kkg, divide by 2.

y=wastewater discharged in kgal per ton of product.

x=percent sulfite in final product.

1These limitations apply only to facilities where chlorophenolic - containing biocides are used. Permittees not using chlorophenolic - containing biocides shall certify to the department that they are not using these biocides.

2 These limitations apply only to groundwood facilities using zinc hydrosulfite as a bleaching agent. Groundwood facilities not using zinc hydrosulfite as a bleaching agent shall certify to the department that they are not using this bleaching compound.

1These limitations apply only when the publicly owned treatment works finds it necessary to impose mass effluent limitations.

(2) PRETREATMENT STANDARDS FOR NEW SOURCES (PSNS). Except as provided in s. NR 211.13 pertaining to removal credits, any new source subject to this section which introduces pollutants into a publicly owned treatment works shall comply with ch. NR 211 and achieve the following pretreatment standards for new sources:
(a) The daily maximum limitations for PCP, TCP and zinc are set forth in Table 7 in both lbs/ton and mg/l.
(b) PCP and TCP limitations are only applicable to facilities where chlorophenolic-containing biocides are used. Permittees not using chlorophenolic-containing biocides shall certify to the control authority that they are not using these biocides.
(c) Zinc limitations are only applicable to groundwood facilities where zinc hydrosulfite is used as a bleaching agent. Groundwood facilities not using zinc hydrosulfite as a bleaching agent shall certify to the control authority that they are not using this bleaching compound.

TABLE 7

PSNS Effluent Limitations

PCP1

TCP1

Zinc2

maximum for any one day

maximum for any one day

maximum for any one day

Subcategory

lbs/ton3

mg/l

lbs/ton3

mg/l

lbs/ton3

mg/l

Integrated Facilities

1.

BCT Bleached Kraft

0.0032

(0.012)(31.7)/y

0.024

(0.092)(31.7)/y

2.

Fine Bleached Kraft

0.0028

(0.014)(25.1)/y

0.022

(0.101)(25.1)/y

3.

Groundwood-CMN Papers

0.0022

(0.016)(16.8)/y

0.00198

(0.014)(16.8)/y

0.42

(3.0)(16.8)/y

4.

Groundwood-Chemi-Mechanical

-

-

-

-

-

-

5.

Groundwood-Fine Papers

0.002

(0.016)(15.4)/y

0.00184

(0.014)(15.4)/y

0.38

(3.0)(15.4)/y

6.

Groundwood-Thermo-Mechanical

0.00194

(0.017)(13.8)/y

0.00176

(0.015)(13.8)/y

0.34

(3.0)(13.8)/y

7.

Papergrade Sulfite

0.00116

((0.015)(9.12)

0.0086

((0.114)(9.12)

(Blow Pit Wash)

exp(0.017x)

exp(0.017x))/y

exp(0.017x)

exp(0.017x))/y

8.

Papergrade Sulfite

0.00116

((0.015)(9.12)

0.0086

((0.114)(9.12)

(Drum Wash)

exp(0.017x)

exp(0.017x))/y

exp(0.017x)

exp(0.017x))/y

9.

Semi-Chemical

0.0028

(0.045)(7.3)/y

0.00086

(0.014)(7.3)/y

10.

Soda

0.0028

(0.014)(25.1)/y

0.022

(0.101)(25.1)/y

11.

Unbleached Kraft

(a) Facilities where linerboard is produced

0.00116

(0.015)(9.4)/y

0.00106

(0.013)(9.4)/y

(b) Facilities where bag paper and other mixed products are produced

0.00116

(0.012)(11.4)/y

0.00106

(0.011)(11.4)/y

12.

Unbleached Kraft and Semi-Chemical

0.00128

(0.013)(11.5)/y

0.00118

(0.012)(11.5)/y

13.

Unbleached Kraft-Neutral Sulfite Semi-Chemical (Cross Recovery)

0.00128

(0.013)(11.5)/y

0.00118

(0.012)(11.5)/y

Nonintegrated Facilities

14.

Nonintegrated-Filter and Nonwoven Papers

0.016

(0.040)(47.5)/y

0.005

(0.013)(47.5)/y

15.

Nonintegrated-Fine Papers

(a) Wood fiber furnish subdivision

0.004

(0.052)(9.4)/y

0.00128

(0.016)(9.4)/y

(b) Cotton fiber furnish subdivision

0.0112

(0.044)(31.1)/y

0.0036

(0.014)(31.1)/y

16.

Nonintegrated-Lightweight Papers

0.013

(0.041)(38.2)/y

0.004

(0.013)(38.2)/y

(a) Facilities where electrical grade papers are produced

0.02

(0.037)(66.8)/y

0.0064

(0.012)(66.8)/y

17.

Nonintegrated-Paperboard

0.0034

(0.037)(11.2)/y

0.00108

(0.012)(11.2)/y

18.

Nonintegrated-Tissue Papers

0.0062

(0.038)(19.1)/y

0.00192

(0.012)(19.1)/y

From Wastepaper Facilities

19.

Builders' Paper and Roofing Felt

0.0038

(0.171)(2.7)/y

0.0012

(0.053)(2.7)/y

20.

Deink

(a) Facilities where fine paper is produced

0.0066

(0.049)(15.9)/y

0.0168

(0.126)(15.9)/y

(b) Facilities where tissue paper is produced

0.0066

(0.040)(19.5)/y

0.0168

(0.103)(19.5)/y

(c) Facilities where newsprint is produced

0.0066

(0.048)(16.2)/y

0.002

(0.015)(16.2)/y

21.

Paperboard FWP

0.00192

(0.072)(3.2)/y

0.0006

(0.023)(3.2)/y

22.

Tissue FWP

0.0068

(0.049)(16.3)/y

0.0022

(0.015)(16.3)/y

23.

Wastepaper-Molded Products

0.0056

(0.118)(5.7)/y

0.00176

(0.037)(5.7)/y

Pulp

Facilities

24.

Dissolving Kraft

0.005

(0.012)(50.7)/y

0.038

(0.089)(50.7)/y

25.

Dissolving Sulfite Pulp

(a) Facilities where nitration, viscose or cellophane grade pulps are produced

0.006

(0.012)(59.0)/y

0.046

(0.092)(59.0)/y

(b) Facilities where acetate grade pulp is produced

0.0066

(0.012)(65.7)/y

0.05

(0.091)(65.7)/y

26.

Market Bleached Kraft

0.0038

(0.013)(36.6)/y

0.028

(0.093)(36.6)/y

Mass limitations are in lbs/ton except where otherwise stated. For kg/kkg, divide by 2.

y=wastewater discharged in kgal per ton of product.

x=percent sulfite in final product.

1These limitations apply only to facilities where chlorophenolic - containing biocides are used. Permittees not using chlorophenolic - containing biocides shall certify to the department that they are not using these biocides.

2These limitations apply only to groundwood facilities using zinc hydrosulfite as a bleaching agent. Groundwood facilities not using zinc hydrosulfite as a bleaching agent shall certify to the department that they are not using this bleaching compound.

3These limitations apply only when the publicly owned treatment works find it necessary to impose mass effluent limitations.

Wis. Admin. Code Department of Natural Resources § NR 284.22

Cr. Register, October, 1986, No. 370, eff. 11-1-86.