Tenn. Comp. R. & Regs. 0400-12-01-.05
Current through October 22, 2024
(Note: Chapter 0400-12-01 became effective as rulemaking hearing rules on March 2, 1981.)
(Comment: The owner or operator of a facility under subparts (ix) and (x) of this part is subject to the requirements of Rule 0400-12-01-.06 to the extent those requirements are included in a permit-by-rule granted to such a person under Rule 0400-12-01-.07(1)(c).)
The regulations in this subpart apply to owners and operators of all hazardous waste facilities, except as subparagraph (1)(b) of this rule provides otherwise.
Every facility owner or operator must apply to the Department for an Installation Identification Number in accordance with the permit application procedures of Rule 0400-12-01-.07(2).
(Comment: For example, the facility's records of analyses performed on the waste before the effective date of these regulations, or studies conducted on hazardous waste generated from processes similar to that which generated the waste to be managed at the facility, may be included in the data base required to comply with subpart (i) of this part. The owner or operator of an off-site facility may arrange for the generator of the hazardous waste to supply part of the information required by subpart (i) of this part, except as otherwise specified in Rule 0400-12-01-.10(1)(g) 2 and 3. If the generator does not supply the information, and the owner or operator chooses to accept a hazardous waste, the owner or operator is responsible for obtaining the information required to comply with this subparagraph.)
(Comment: See Rule 0400-12-01-.01(3)(b) for related discussion.)
(Comment: The requirements of this part are satisfied if the facility or plant within which the active portion is located itself has a surveillance system, or a barrier and a means to control entry, which complies with the requirements of subparts (i) and (ii) of this part.)
(Comment: See part (7)(h)2 of this rule for discussion of security requirements at disposal facilities during the post-closure care period.)
The placement of any hazardous waste in a salt dome, salt bed formation, underground mine or cave is prohibited.
Before construction begins on a unit subject to the CQA program under part 1 of this subparagraph, the owner or operator must develop a written CQA plan. The plan must identify steps that will be used to monitor and document the quality of materials and the condition and manner of their installation. The CQA plan must include:
The owner or operator of units subject to this subparagraph must submit to the Commissioner by certified mail or hand delivery, at least 30 days prior to receiving waste, a certification signed by the CQA officer that the CQA plan has been successfully carried out and that the unit meets the requirements of part (11)(b)1, subparagraph (12)(e), or part (14)(b)1 of this rule. The owner or operator may receive waste in the unit after 30 days from the Commissioner's receipt of the CQA certification unless the Commissioner determines in writing that the construction is not acceptable, or extends the review period for a maximum of 30 more days, or seeks additional information from the owner or operator during this period. Documentation supporting the CQA officer's certification must be furnished to the Commissioner upon request.
The owner or operator may not treat, store, or dispose of other wastes or other materials along with hazardous wastes in hazardous waste management units subject to the requirements of this rule unless:
The regulations in this subpart apply to owners and operators of all hazardous waste facilities, except as subparagraph (1)(b) of this rule provides otherwise.
Facilities must be maintained and operated to minimize the possibility of a fire, explosion, or any unplanned sudden or non-sudden release of hazardous waste or hazardous waste constituents to air, soil, or surface water which could threaten human health or the environment.
All facilities must be equipped with the following, unless none of the hazards posed by waste handled at the facility could require a particular kind of equipment specified below:
All facility communications or alarm systems, fire protection equipment, spill control equipment, and decontamination equipment, where required, must be tested and maintained as necessary to assure its proper operation in time of emergency.
The owner or operator must maintain aisle space to allow the unobstructed movement of personnel, fire protection equipment, spill control equipment, and decontamination equipment to any area of facility operation in an emergency, unless aisle space is not needed for any of these purposes.
The regulations in this subpart apply to owners and operators of all hazardous waste facilities, except as subparagraph (1)(b) of this rule provides otherwise.
A copy of the contingency plan and all revisions to the plan must be:
The contingency plan must be reviewed, and immediately amended, if necessary, whenever:
At all times, there must be at least one employee either on the facility premises or on call (i.e., available to respond to an emergency by reaching the facility within a short period of time) with the responsibility for coordinating all emergency response measures. This emergency coordinator must be thoroughly familiar with all aspects of the facility's contingency plan, all operations and activities at the facility, the location and characteristics of waste handled, the location of all records within the facility, and the facility layout. In addition, this person must have the authority to commit the resources needed to carry out the contingency plan.
(Comment: The emergency coordinator's responsibilities are more fully spelled out in subparagraph (g) of this paragraph. Applicable responsibilities for the emergency coordinator vary, depending on factors such as type and variety of waste(s) handled by the facility, and type and complexity of the facility.)
(Comment: Unless the owner or operator can demonstrate, in accordance with Rule 0400-12-01-.02(1)(c) 3 or 4, that the recovered material is not a hazardous waste, the owner or operator becomes a generator of hazardous waste and must manage it in accordance with all applicable requirements of Rule 0400-12-01-.03, .04, and this rule.)
(Comment: The Department does not intend that the owner or operator of a facility whose procedures under part (2)(d)3 of this rule include waste analysis must perform that analysis before signing the shipping paper and giving it to the transporter. Part (c)2 of this paragraph, however, requires reporting an unreconciled discrepancy discovered during later analysis.)
Electronic manifests that are obtained, completed, and transmitted in accordance with subpart (3)(a)1(iii) of Rule 0400-12-01-.03, and used in accordance with this part in lieu of the paper manifest form are the legal equivalent of paper manifest forms bearing handwritten signatures, and satisfy for all purposes any requirement in these regulations to obtain, complete, sign, provide, use, or retain a manifest.
If a facility receives hazardous waste that is accompanied by a paper replacement manifest for a manifest that was originated electronically, the following procedures apply to the delivery of the hazardous waste by the final transporter:
If an owner or operator using an electronic manifest signs this manifest electronically using an electronic signature method which is undergoing pilot or demonstration tests aimed at demonstrating the practicality or legal dependability of the signature method, then the owner or operator shall also sign with an ink signature the facility's certification of receipt or discrepancies on the printed copy of the manifest provided by the transporter. Upon executing its ink signature on this printed copy, the owner or operator shall retain this original copy among its records for at least 3 years from the date of delivery of the waste.
(Comment: See subparagraphs (7)(j), (13)(j), and (14)(j) of this rule for related requirements.)
(Comment: As required by subparagraph (6)(e) of this rule, monitoring data at disposal facilities must be kept throughout the post-closure period.)
(Note: The authority for implementing 40 CFR 268.5 Procedures for Case-by-Case Extensions to an Effective Date and the authority for implementing 40 CFR 268.6 Petitions to Allow Land Disposal of a Prohibited Waste remains with the U.S. Environmental Protection Agency.)
In addition to submitting the annual report and unmanifested waste reports described in subparagraph (f) and (g) of this paragraph, the owner or operator must also report to the Commissioner:
(Comment: See "Procedures Manual For Ground-water Monitoring At Solid Waste Disposal Facilities," EPA-530/SW-611, August 1977 and "Methods for Chemical Analysis of Water and Wastes," EPA-600/4-79-020, March 1979 for discussions of sampling and analysis procedures.)
Except as paragraph (1) of this rule provides otherwise:
The owner or operator must close the facility in a manner that:
By May 19, 1981, or by six months after the effective date of the rule that first subjects a facility to provisions of this paragraph, the owner or operator of a hazardous waste management facility must have a written closure plan. Until final closure is completed and certified in accordance with subparagraph (f) of this paragraph, a copy of the most current plan must be furnished to the Commissioner upon request, including request by mail. In addition, for facilities without approved plans, it must also be provided during site inspections, on the day of inspection, to any officer, employee, or representative of the Department who is duly designated by the Commissioner.
The plan must identify steps necessary to perform partial and/or final closure of the facility at any point during its active life. The closure plan must include, at least:
The owner or operator may amend the closure plan at any time prior to the notification of partial or final closure of the facility. An owner or operator with an approved closure plan must submit a written request to the Commissioner to authorize a change to the approved closure plan. The written request must include four (4) copies of the amended closure plan for approval by the Commissioner.
Nothing in this subparagraph shall preclude the owner or operator from removing hazardous wastes and decontaminating or dismantling equipment in accordance with the approved partial or final closure plan at any time before or after notification of partial or final closure.
During the partial and final closure periods, all contaminated equipment, structures and soil must be properly disposed of, or decontaminated unless specified otherwise in subparagraphs (10)(h), (11)(i), (12)(i), (13)(k), or (14)(k) of this rule. By removing all hazardous wastes or hazardous constituents during partial and final closure, the owner or operator may become a generator of hazardous waste and must handle that hazardous waste in accordance with all applicable requirements of Rule 0400-12-01-.03.
Within 60 days of completion of closure of each hazardous waste surface impoundment, waste pile, land treatment, and landfill unit, and within 60 days of completion of final closure, the owner or operator must submit to the Commissioner, by registered mail, a certification that the hazardous waste management unit or facility, as applicable, has been closed in accordance with the specifications in the approved closure plan. The certification must be signed by the owner or operator and by a qualified Professional Engineer. Documentation supporting the qualified Professional Engineer's certification must be furnished to the Commissioner upon request until he releases the owner or operator from the financial assurance requirements for closure under part (8)(d)8 of this rule.
As used in this subparagraph, the phrase "hazardous waste surface impoundment, waste pile, land treatment, and landfill unit" shall mean "hazardous waste management unit" as defined in Rule 0400-12-01-.01(2)(a).
No later than the submission of the certification of closure of each hazardous waste disposal unit, an owner or operator must submit to the local zoning authority, or the authority with jurisdiction over local land use, and to the Commissioner, a survey plat (at least four (4) copies) indicating the location and dimensions of landfill cells or other hazardous waste disposal units with respect to permanently surveyed benchmarks. This plat must be prepared and certified by a professional land surveyor. The plat filed with the local zoning authority, or the authority with jurisdiction over local land use must contain a note, prominently displayed, which states the owner's or operator's obligation to restrict disturbance of the hazardous waste disposal unit in accordance with the applicable regulations of this paragraph.
By May 19, 1981, the owner or operator of a hazardous waste disposal unit must have a written post-closure plan. An owner or operator of a surface impoundment or waste pile that intends to remove all hazardous wastes at closure must prepare a post-closure plan and submit it to the Commissioner within 90 days of the date that the owner or operator or Commissioner determines that the hazardous waste management unit or facility must be closed as a landfill, subject to the requirements of subparagraphs (h) through (k) of this paragraph.
No later than 60 days after the completion of the established post-closure care period for each hazardous waste disposal unit, the owner or operator must submit to the Commissioner, by registered mail, a certification that the post-closure care period for the hazardous waste disposal unit was performed in accordance with the specifications in the approved post-closure plan. The certification must be signed by the owner or operator and a qualified Professional Engineer. Documentation supporting the qualified Professional Engineer's certification must be furnished to the Commissioner upon request until he releases the owner or operator from the financial assurance requirements for post-closure care under part (8)(f)3 of this rule.
"Assets" means all existing and all probable future economic benefits obtained or controlled by a particular entity.
"Current assets" means cash or other assets or resources commonly identified as those which are reasonably expected to be realized in cash or sold or consumed during the normal operating cycle of the business.
"Current liabilities" means obligations whose liquidation is reasonably expected to require the use of existing resources properly classifiable as current assets or the creation of other current liabilities.
"Current plugging and abandonment cost estimate" means the most recent of the estimates prepared in accordance with Tennessee Rule 0400-45-06-.09(10) or 40 CFR 144.62(a), (b), and (c) (as this federal regulation exists on the effective date of this rulemaking), whichever is greater.
"Independently audited" refers to an audit performed by an independent certified public accountant in accordance with generally accepted auditing standards.
"Liabilities" means probable future sacrifices of economic benefits arising from present obligations to transfer assets or provide services to other entities in the future as a result of past transactions or events.
"Net working capital" means current assets minus current liabilities.
"Net worth" means total assets minus total liabilities and is equivalent to owner's equity.
"Tangible net worth" means the tangible assets that remain after deducting liabilities; such assets would not include intangibles such as goodwill and rights to patents or royalties.
"Accidental occurrence" means an accident, including continuous or repeated exposure to conditions, which results in bodily injury or property damage neither expected nor intended from the standpoint of the insured.
"Legal defense costs" means any expenses that an insurer incurs in defending against claims of third parties brought under the terms and conditions of an insurance policy.
"Nonsudden accidental occurrence" means an occurrence which takes place over time and involves continuous or repeated exposure.
"Sudden accidental occurrence" means an occurrence which is not continuous or repeated in nature.
By 90 days after the effective date of these regulations, an owner or operator of each facility must file and maintain with the Division Director financial assurance for closure of the facility in accordance with the requirements of this subparagraph.
(Note: See also subparagraphs (h), (i), (j) and (k) of this paragraph.)
Within 60 days after receiving certifications from the owner or operator and a qualified Professional Engineer that final closure has been completed in accordance with the approved closure plan, the Division Director will notify the owner or operator in writing that he is no longer required by this subparagraph to maintain financial assurance for final closure of the facility, unless the Commissioner or Board has reason to believe that final closure has not been in accordance with the approved closure plan. The Division Director shall provide the owner or operator a detailed written statement of any such reason to believe that closure has not been in accordance with the approved closure plan.
(Note: The original effective date of these regulations was October 31, 1980).
By 90 days after the effective date of these regulations, an owner or operator of a facility with a hazardous waste disposal unit must file and maintain with the Division Director financial assurance for post-closure care of the disposal unit(s) in accordance with the requirements of this subparagraph.
(Note: See also subparagraphs (h), (i), (j) and (k) of this paragraph.)
Within 60 days after receiving certifications from the owner or operator and a qualified Professional Engineer that the post-closure care period has been completed for a hazardous waste disposal unit in accordance with the approved post-closure plan, the Division Director will notify the owner or operator in writing that he is no longer required to maintain financial assurance for post-closure care of that unit, unless the Commissioner or Board has reason to believe that post-closure care has not been in accordance with the approved post-closure plan. The Division Director shall provide the owner or operator a detailed written statement of any such reason to believe that post-closure care has not been in accordance with the approved post-closure plan.
(Note: The original effective date of these regulations was October 31, 1980.)
By the effective date of these regulations, an owner or operator of each facility must establish and maintain with the Division Director financial assurance for closure of the facility. He must choose from the options as specified in parts 1 through 5 of this subparagraph.
An owner or operator may satisfy the requirements of subparagraphs (d) and/or (f) of this paragraph by establishing and maintaining a closure trust fund which conforms to the requirements of this part and submitting an originally signed duplicate of the trust agreement to the Division Director.
where CE is the current closure and/or post-closure care cost estimate, CV is the current value of the trust fund, and Y is the number of years remaining in the pay-in period.
An owner or operator may satisfy the requirements of subparagraphs (d) and/or (f) of this paragraph by obtaining a surety bond which conforms to the requirements of this part and submitting the bond to the Division Director.
An owner or operator may satisfy the requirements of subparagraph (d) and/or (f) of this paragraph by obtaining an irrevocable standby letter of credit which conforms to the requirements of this part and submitting the letter to the Division Director.
An owner or operator may satisfy the requirements of subparagraphs (d) and/or (f) of this paragraph by obtaining closure and/or post-closure care insurance which conforms to the requirements of this part and submitting a certificate of such insurance to the Division Director. By the effective date of these regulations the owner or operator must submit to the Division Director a letter from an insurer stating that the insurer is considering issuance of closure and/or post-closure care insurance conforming to the requirements of this part to the owner or operator. Within 90 days after the effective date of these regulations, the owner or operator must submit the certificate of insurance to the Division Director or establish other financial assurance as specified in this paragraph.
Within 60 days after receiving bills for closure and/or post-closure care activities, the Division Director will instruct the insurer to make reimbursements in such amounts as the Division Director specifies in writing if the Division Director determines that the partial or final closure and/or post-closure care expenditures are in accordance with the approved closure plan or otherwise justified. If the Division Director has reason to believe that the maximum cost of closure and/or post-closure care over the remaining life of the facility will be significantly greater than the face amount of the policy, he may withhold reimbursement of such amounts as he deems prudent until the owner or operator is released from the financial assurance requirement as provided in part (d)3 and/or (f)3 of this paragraph. If the Division Director does not instruct the insurer to make such reimbursements, he will provide to the owner or operator a detailed written statement of reasons.
An owner or operator may satisfy the requirements of subparagraph (d) and/or (f) of this paragraph by filing his personal performance guarantee accompanied by collateral in the form of securities. He must guarantee to perform final closure in accordance with the closure plan and other requirements of interim status whenever required to do so, and/or guarantee to perform post-closure care in accordance with the post-closure plan and other requirements of interim status. The wording of the personal bond supported by securities must be identical to the wording specified in Rule 0400-12-01-.06(8)(p) 15. The securities supporting this guarantee must be fully registered as to principal and interest in such manner as to identify the State and the Department as holder of such collateral and to also identify that person filing such collateral. These securities must have a current market value at least adequate to provide the necessary financial assurance, and must be included among the following types:
An owner or operator may satisfy the requirements of subparagraph (d) and/or (f) of this paragraph by filing his personal performance guarantee accompanied by cash in an amount at least adequate to provide the necessary financial assurance. He must guarantee to perform final closure in accordance with the closure plan and other requirements of interim status whenever required to do so and/or guarantee to perform post-closure care in accordance with the post-closure plan and other requirements of interim status.
An owner or operator may satisfy the requirements of subparagraphs (d) and/or (f) of this paragraph by establishing more than one financial mechanism per facility. These mechanisms are limited to trust funds, surety bonds, letters of credit, insurance, and personal bonds supported by securities or cash. The mechanisms must be as specified in subparagraph (g) of this paragraph, except that it is the combination of mechanisms, rather than the single mechanism, which must provide financial assurance for an amount at least equal to the current closure cost and/or post-closure care estimate. If an owner or operator uses a trust fund in combination with a surety bond or a letter of credit, he may use the trust fund as the standby trust fund for the other mechanisms. A single standby trust fund may be established for two or more mechanisms. The Commissioner may use any or all of the mechanisms to provide for closure and/or post-closure care of the facility.
An owner or operator may use a financial assurance mechanism specified in subparagraph (g) of this paragraph to meet the requirements of subparagraph (d) and/or (f) of this paragraph for more than one facility. Evidence of financial assurance submitted to the Division Director must include a list showing, for each facility, the Installation Identification Number, name, address, and the amount of funds for closure assured by the mechanism. The amount of funds available through the mechanism must be no less than the sum of funds that would be available if a separate mechanism had been established and maintained for each facility. In a financial assurance forfeiture action taken under parts (d)4 and/or (f)4 of this paragraph for closure and/ or post-closure care of any of the facilities covered by the mechanism, the Commissioner may order forfeiture of only the amount of funds designated for that facility, unless the owner or operator agrees to the use of additional funds available under the mechanism.
An owner or operator may satisfy the requirements for financial assurance for both closure and post-closure care for one or more facilities by using a mechanism from subparagraph (g) of this paragraph which meets the requirements of both subparagraphs (d) and (f) of this paragraph. The amount of funds available through the mechanism must be no less than the sum of funds that would be available if a separate mechanism had been established and maintained for financial assurance for closure and for post-closure care.
In meeting the requirements of subparagraphs (d) or (f) of this paragraph, an owner or operator may substitute alternate financial assurance meeting the requirements of this paragraph for the financial assurance already filed with the Division Director for the facility. However, the existing financial assurance shall not be released by the Division Director until the substitute financial assurance has been received and approved by him or her.
The Division Director shall obtain possession of, and deposit with the Treasurer of the State of Tennessee, all collateral filed under this paragraph, in accordance with Tennessee Code Annotated Section 8-5-110. At the owner or operator's request, the State Treasurer shall release to the operator any interest income from deposited securities as the same becomes due and payable.
An owner or operator of a hazardous waste treatment, storage, or disposal facility, or a group of such facilities, must demonstrate financial responsibility for bodily injury and property damage to third parties caused by sudden accidental occurrences arising from operations of the facility or group of facilities. The owner or operator must have and maintain liability coverage for sudden accidental occurrences in the amount of at least $1 million per occurrence with an annual aggregate of at least $2 million, exclusive of legal defense costs. This liability coverage may be demonstrated as specified in subpart (i), (ii), (iii), (iv), (v), or (vi) of this part:
An owner or operator of a surface impoundment, landfill, or land treatment facility which is used to manage hazardous waste, or a group of such facilities, must demonstrate financial responsibility for bodily injury and property damage to third parties caused by nonsudden accidental occurrences arising from operations of the facility or group of facilities. The owner or operator must have and maintain liability coverage for nonsudden accidental occurrences in the amount of at least $3 million per occurrence with an annual aggregate of at least $6 million, exclusive of legal defense costs. An owner or operator who must meet the requirements of this subparagraph may combine the required per-occurrence coverage levels for sudden and nonsudden accidental occurrences into a single per-occurrence level, and combine the required annual aggregate coverage levels for sudden and nonsudden accidental occurrences into a single annual aggregate level. Owners or operators who combine coverage levels for sudden and nonsudden accidental occurrences must maintain liability coverage in the amount of at least $4 million per occurrence and $8 million annual aggregate. This liability coverage may be demonstrated as specified in subpart (i), (ii), (iii), (iv), (v), or (vi) of this part:
If an owner or operator can demonstrate to the satisfaction of the Commissioner that the levels of financial responsibility required by part 1 or 2 of this subparagraph are not consistent with the degree and duration of risk associated with treatment, storage, or disposal at the facility or group of facilities, the owner or operator may obtain a variance from the Commissioner. The request for a variance must be submitted in writing to the Commissioner. If granted, the variance will take the form of an adjusted level of required liability coverage, such level to be based on the Commissioner's assessment of the degree and duration of risk associated with the ownership or operation of the facility or group of facilities. The Commissioner may require an owner or operator who requests a variance to provide such technical and engineering information as is deemed necessary by the Commissioner to determine a level of financial responsibility other than that required by part 1 or 2 of this subparagraph. The Commissioner will process a variance request as if it were a permit modification request under Rule 0400-12-01-.07(9)(c) 3(xiii) and subject to the procedures of Rule 0400-12-01-.07(9)(c) 2. Notwithstanding any other provision, the Commissioner may hold a public hearing at his discretion or whenever he finds, on the basis of requests for a public hearing, a significant degree of pubic interest in a tentative decision to grant a variance.
If the Commissioner determines that the levels of financial responsibility required by part 1 or 2 of this subparagraph are not consistent with the degree and duration of risk associated with treatment, storage, or disposal at the facility or group of facilities, the Commissioner may adjust the level of financial responsibility required under part 1 or 2 of this subparagraph as may be necessary to protect human health and the environment. This adjusted level will be based on the Commissioner's assessment of the degree and duration of risk associated with the ownership or operation of the facility or group of facilities. In addition, if the Commissioner determines that there is a significant risk to human health and the environment from nonsudden accidental occurrences resulting from the operations of a facility that is not a surface impoundment, landfill, or land treatment facility, he may require that an owner or operator of the facility comply with part 2 of this subparagraph. An owner or operator must furnish to the Division Director, within a reasonable time, any information which the Commissioner requests to determine whether cause exists for such adjustments of level or type of coverage. The Commissioner will process an adjustment of the level of required coverage as if it were a permit modification under Rule 0400-12-01-.07(9)(c) 3(xiii) and subject to the procedures of Rule 0400-12-01-.07(9)(c) 2. Notwithstanding any other provision, the Commissioner may hold a public hearing at his discretion or whenever he finds, on the basis of requests for a public hearing, a significant degree of public interest in a tentative decision to adjust the level or type of required coverage.
Within 60 days after receiving certifications from the owner or operator and a qualified Professional Engineer that final closure has been completed in accordance with the approved closure plan, the Division Director will notify the owner or operator in writing that he is no longer required by this subparagraph to maintain liability coverage for that facility, unless the Commissioner or Board has reason to believe that closure has not been in accordance with the approved closure plan. The Division Director shall provide the owner or operator a detailed written statement of any such reason to believe that closure has not been in accordance with the approved closure plan.
The regulations in this paragraph apply to owners and operators of all hazardous waste facilities that store containers of hazardous waste, except as paragraph (1) of this rule provides otherwise.
If a container holding hazardous waste is not in good condition, or if it begins to leak, the owner or operator must transfer the hazardous waste from this container to a container that is in good condition, or manage the waste in some other way that complies with the requirements of this rule.
The owner or operator must use a container made of or lined with materials which will not react with, and are otherwise compatible with, the hazardous waste to be stored, so that the ability of the container to contain the waste is not impaired.
(Comment: Re-use of containers in transportation is governed by U.S. Department of Transportation regulations, including those set forth in 49 CFR 173.28.)
At least weekly, the owner or operator must inspect areas where containers are stored. The owner or operator must look for leaking containers and for deterioration of containers caused by corrosion or other factors. See subparagraph (b) of this paragraph for remedial action required if deterioration or leaks are detected.
Containers holding ignitable or reactive waste must be located at least 15 meters (50 feet) from the facility's property line.
(Comment: See part (2)(h)1 of this rule for additional requirements.)
(Comment: The purpose of this is to prevent fires, explosions, gaseous emissions, leaching, or other discharge of hazardous waste or hazardous waste constituents which could result from the mixing of incompatible wastes or materials if containers break or leak.)
The owner or operator shall manage all hazardous waste placed in a container in accordance with the applicable requirements of paragraphs (27), (28), and (29) of this rule.
The requirements of this paragraph apply to owners and operators of facilities that use tank systems for storing or treating hazardous waste except as otherwise provided in parts 1, 2, and 3 of this subparagraph or in paragraph (1) of this rule.
(Note: The practices described in the American Petroleum Institute (API) Publication, Guide for Inspection of Refinery Equipment, Chapter XIII, "Atmospheric and Low-Pressure Storage Tanks," 4th edition, 1981, may be used, where applicable, as guidelines in conducting the integrity examination of an other than non-enterable underground tank system.)
(Note: The practices described in the National Association of Corrosion Engineers (NACE) standard, "Recommended Practice (RP-02-85) --Control of External Corrosion on Metallic Buried, Partially Buried, or Submerged Liquid Storage Systems," and the American Petroleum Institute (API) Publication 1632, "Cathodic Protection of Underground Petroleum Storage Tanks and Piping Systems," may be used, where applicable, as guidelines in providing corrosion protection for tank systems.)
All discrepancies must be remedied before the tank system is covered, enclosed, or placed in use.
(Note: The piping system installation procedures described in American Petroleum Institute (API) Publication 1615 (November 1979), "Installation of Underground Petroleum Storage Systems," or ANSI Standard B31.3, "Petroleum Refinery System," may be used, where applicable, as guidelines for proper installation of piping systems.)
(Note: If the collected material is a hazardous waste under Rule 0400-12-01-.02, it is subject to management as a hazardous waste in accordance with all applicable requirements of Rule 0400-12-01-.03 through .06. If the collected material is discharged through a point source to waters of the United States, it is subject to the requirements of sections 301, 304, and 402 of the Clean Water Act, as amended. If discharged to Publicly Owned Treatment Works (POTWs), it is subject to the requirements of T.C.A. Section 69-3-101 et seq. and/or section 307 of the Clean Water Act, as amended. If the collected material is released to the environment, it may be subject to the reporting requirements of 40 CFR part 302 .)
(Note: The provisions outlined in the Steel Tank Institute's (STI) "Standard for Dual Wall Underground Steel Storage Tank" may be used as guidelines for aspects of the design of underground steel double-walled tanks.)
(Note: The practices described in the American Petroleum Institute (API) Publication Guide for Inspection of Refining Equipment, Chapter XIII, "Atmospheric and Low Pressure Storage Tanks," 4th edition, 1981, may be used, when applicable, as guidelines for assessing the overall condition of the tank system.)
(Note: Part (2)(f)3 of this rule requires the owner or operator to remedy any deterioration or malfunction he finds. Subparagraph (g) of this paragraph requires the owner or operator to notify the Commissioner within 24 hours of confirming a release. Also, 40 CFR part 302 may require the owner or operator to notify the National Response Center of a release and Section 304 of Title III of the Superfund Amendments and Reauthorization Act of 1986 may require notification of the Tennessee Emergency Management Agency.)
(Note: The practices described in the National Association of Corrosion Engineers (NACE) standard, "Recommended Practice (RP-02-85) -- Control of External Corrosion on Metallic Buried, Partially Buried, or Submerged Liquid Storage Systems," and the American Petroleum Institute (API) Publication 1632, "Cathodic Protection of Underground Petroleum Storage Tanks and Piping Systems," may be used, where applicable, as guidelines in maintaining and inspecting cathodic protection systems.)
A tank system or secondary containment system from which there has been a leak or spill, or which is unfit for use, must be removed from service immediately, and the owner or operator must satisfy the following requirements:
The owner or operator must immediately stop the flow of hazardous waste into the tank system or secondary containment system and inspect the system to determine the cause of the release.
The owner or operator must immediately conduct a visual inspection of the release and, based upon that inspection:
If the owner or operator has repaired a tank system in accordance with part 5 of this subparagraph, and the repair has been extensive (e.g., installation of an internal liner; repair of a ruptured primary containment or secondary containment vessel), the tank system must not be returned to service unless the owner/operator has obtained a certification by a qualified Professional Engineer in accordance with Rule 0400-12-01-.07(2)(a) 10 that the repaired system is capable of handling hazardous wastes without release for the intended life of the system. This certification is to be placed in the operating record and maintained until closure of the facility.
(Note: The Commissioner may, on the basis of any information received that there is or has been a release of hazardous waste or hazardous constituents into the environment, issue an order under T.C.A. § 68-212-111 requiring corrective action or such other response as deemed necessary to protect human health or the environment.)
(Note: See part (2) (f)3 of this rule for the requirements necessary to remedy a failure. Also, 40 CFR part 302 requires the owner or operator to notify the National Response Center of a release of any "reportable quantity" and Section 304 of Title III of the Superfund Amendment and Reauthorization Act of 1986 may require notification of the Tennessee Emergency Management Agency.)
In addition to performing the waste analysis required by subparagraph (2)(d) of this rule, the owner or operator must, whenever a tank system is to be used to treat chemically or to store a hazardous waste that is substantially different from waste previously treated or stored in that tank system; or treat chemically a hazardous waste with a substantially different process than any previously used in that tank system:
(Note: Subparagraph (2)(d) of this rule requires the waste analysis plan to include analyses needed to comply with subparagraphs (i) and (j) of this paragraph. Subparagraph (5)(d) of this rule requires the owner or operator to place the results from each waste analysis and trial test, or the documented information, in the operating record of the facility.)
The owner or operator shall manage all hazardous waste placed in a tank in accordance with the applicable requirements of paragraphs (27), (28), and (29) of this rule.
The regulations in this paragraph apply to owners and operators of facilities that use surface impoundments to treat, store, or dispose of hazardous waste, except as subparagraph (1)(b) of this rule provides otherwise.
All earthen dikes must have a protective cover, such as grass, shale, or rock, to minimize wind and water erosion and to preserve their structural integrity.
(Comment: As required by subparagraph (2)(d) of this rule, the waste analysis plan must include analyses needed to comply with subparagraphs (k) and (l) of this paragraph. As required by subparagraph (5)(d) of this rule, the owner or operator must place the results from each waste analysis and trial test, or the documented information, in the operating record of the facility.)
(Comment: As required by part (2)(f)3 of this rule, the owner or operator must remedy any deterioration or malfunction he finds.)
Ignitable or reactive waste must not be placed in a surface impoundment, unless the waste and impoundment satisfy all applicable requirements of Rule 0400-12-01-.10, and:
Incompatible wastes, or incompatible wastes and materials, (see paragraph (53) Appendix V of this rule for examples) must not be placed in the same surface impoundment, unless part (2)(h)2 of this rule is complied with.
The owner or operator shall manage all hazardous waste placed in a surface impoundment in accordance with the applicable requirements of paragraphs (28) and (29) of this rule.
The regulations in this paragraph apply to owners and operators of facilities that treat or store hazardous waste in piles, except as paragraph (1) of this rule provides otherwise. Alternatively, a pile of hazardous waste may be managed as a landfill under paragraph (14) of this rule.
The owner or operator of a pile containing hazardous waste which could be subject to dispersal by wind must cover or otherwise manage the pile so that wind dispersal is controlled.
In addition to the waste analyses required by subparagraph (2)(d) of this rule, the owner or operator must analyze a representative sample of waste from each incoming movement before adding the waste to any existing pile, unless
(Comment: As required by subparagraph (2)(d) of this rule, the waste analysis plan must include analyses needed to comply with subparagraphs (g) and (h) of this paragraph. As required by subparagraph (5)(d) of this rule, the owner or operator must place the results of this analysis in the operating record of the facility.)
If leachate or run-off from a pile is a hazardous waste, then either:
(Comment: If collected leachate or run-off is discharged through a point source to waters of the United States, it is subject to the requirements of T.C.A. Section 69-3-101 et seq. and/or section 402 of the Clean Water Act, as amended.)
The owner or operator of each new waste pile on which construction commences after January 29, 1992, each lateral expansion of a waste pile unit on which construction commences after July 29, 1992, and each such replacement of an existing waste pile unit that is to commence reuse after July 29, 1992 must install two or more liners and a leachate collection and removal system above and between such liners, and operate the leachate collection and removal systems, in accordance with Rule 0400-12-01-.06(12)(b) 3, unless exempted under Rule 0400-12-01-.06(12)(b) 4, 5, or 6; and must comply with the procedures of part (11)(b)2 of this rule. "Construction commences" is as defined in Rule 0400-12-01-.01(2)(a) under "existing facility".
(Comment: The purpose of this is to prevent fires, explosions, gaseous emissions, leaching, or other discharge of hazardous waste or hazardous waste constituents which could result from the contact or mixing of incompatible wastes or materials.)
An owner or operator required to have a leak detection system under subparagraph (e) of this paragraph must record the amount of liquids removed from each leak detection system sump at least once each week during the active life and closure period.
The regulations in this subpart apply to owners and operators of hazardous waste land treatment facilities, except as subparagraph (1) of this rule provides otherwise.
In addition to the waste analyses required by subparagraph (2)(d) of this rule, before placing a hazardous waste in or on a land treatment facility, the owner or operator must:
(Comment: Rule 0400-12-01-.02 specifies the substances for which a waste is listed as a hazardous waste. As required by subparagraph (2)(d) of this rule, the waste analysis plan must include analyses needed to comply with subparagraphs (l) and (m) of this paragraph. As required by subparagraph (5)(d) of this rule, the owner or operator must place the results from each waste analysis, or the documented information, in the operating record of the facility.)
(Comment: The growth of food chain crops at a facility which has never before been used for this purpose is a significant change in process under Rule 0400-12-01-.07(3)(c) 3. Owners or operators of such land treatment facilities who propose to grow food chain crops after the effective date of this rule must comply with Rule 0400-12-01-.07(3)(c) 3.)
Time Period | Annual Cd Application Rate (kg/ha) |
Present to June 30, 1984 | 2.0 |
July 1, 1984 to December 31, 1986 | 1.25 |
Beginning January 1, 1987 | 0.5 |
Maximum Cumulative Application (kg/ha) | ||
Soil Caption Exchange Capacity (meq/100g) | Background Soil pH Less than 6.5 | Background Soil pH Greater than 6.5 |
Less than 5 | 5 | 5 |
5 to 15 | 5 | 10 |
Greater than 15 | 5 | 20 |
Soil Caption Exchange Capacity (meq/100g) | Maximum Cumulative Application (kg/ha) |
Less than 5 | 5 |
5 to 15 | 10 |
Greater than 15 | 20 |
(Comment: As required by subparagraph (5)(d) of this rule, if an owner or operator grows food chain crops on his land treatment facility, he must place the information developed in this subparagraph in the operating record of the facility.)
(Comment: As required by subparagraph (5)(d) of this rule, all data and information developed by the owner or operator under this subparagraph must be placed in the operating record of the facility.)
The owner or operator must include hazardous waste application dates and rates in the operating record required under subparagraph (5)(d) of this rule.
The owner or operator must not apply ignitable or reactive waste to the treatment zone unless the waste and treatment zone meet all applicable requirements of Rule 0400-12-01-.10, and:
Incompatible wastes, or incompatible wastes and materials (see paragraph (53), Appendix V of this rule for examples), must not be placed in the same land treatment area, unless part (2)(h)2 of this rule is complied with.
The regulations in this subpart apply to owners and operators of facilities that dispose of hazardous waste in landfills, except as subparagraph (1) of this rule provides otherwise. A waste pile used as a disposal facility is a landfill and is governed by this paragraph.
(Comment: As required by subparagraph (2)(d) of this rule, the waste analysis plan must include analyses needed to comply with subparagraphs (m), (n), and (o) of this paragraph. As required by subparagraph (5)(d) of this rule, the owner or operator must place the results of these analyses in the operating record of the facility.)
The owner or operator of a landfill must maintain the following items in the operating record required in subparagraph (5)(d) of this rule:
Incompatible wastes, or incompatible wastes and materials, (see paragraph (53) Appendix V of this rule for examples) must not be placed in the same landfill cell, unless part (2)(h)2 of this rule is complied with.
(Note: Implementation of this provision remains with EPA.)
(Note: Implementations of this provision between May 8, 1985 and February 2, 1986 remains with EPA.)
Unless they are very small, such as an ampule, containers must be either:
Small containers of hazardous waste in overpacked drums (lab packs) may be placed in a landfill if the following requirements are met:
In addition to the waste analyses required by subparagraph (2)(d) of this rule, the owner or operator must sufficiently analyze any waste which he has not previously burned in his incinerator to enable him to establish steady state (normal) operating conditions (including waste and auxiliary fuel feed and air flow) and to determine the type of pollutants which might be emitted. At a minimum, the analysis must determine:
(Comment: As required by subparagraph (5)(d) of this rule, the owner or operator must place the results from each waste analysis, or the documented information, in the operating record of the facility.)
During start-up and shut-down of an incinerator, the owner or operator must not feed hazardous waste unless the incinerator is at steady state (normal) conditions of operation, including steady state operating temperature and air flow.
The owner or operator must conduct, as a minimum, the following monitoring and inspections when incinerating hazardous waste:
At closure, the owner or operator must remove all hazardous waste and hazardous waste residues (including but not limited to ash, scrubber waters, and scrubber sludges) from the incinerator.
(Comment: At closure, as throughout the operating period, unless the owner or operator can demonstrate, in accordance with Rule 0400-12-01-.02(1)(c) 4, that the residue removed from his incinerator is not a hazardous waste, the owner or operator becomes a generator of hazardous waste and must manage it in accordance with all applicable requirements of Rule 0400-12-01-.03 through .07 and .09.)
(Note: Implementation of this provision remains with EPA.)
The regulations in this subpart apply to owners or operators of facilities that thermally treat hazardous waste in devices other than enclosed devices using controlled flame combustion, except as paragraph (1) of this rule provides otherwise. Thermal treatment in enclosed devices using controlled flame combustion is subject to the requirements of paragraph (15) of this rule if the unit is an incinerator, and Rule 0400-12-01-.09(8), if the unit is a boiler or an industrial furnace as defined in Rule 0400-12-01-.01(2)(a).
Before adding hazardous waste, the owner or operator must bring his thermal treatment process to steady state (normal) conditions of operation -- including steady state operating temperature -- using auxiliary fuel or other means, unless the process is a non-continuous (batch) thermal treatment process which requires a complete thermal cycle to treat a discrete quantity of hazardous waste.
In addition to the waste analyses required by subparagraph (2)(d) of this rule, the owner or operator must sufficiently analyze any waste which he has not previously treated in his thermal process to enable him to establish steady state (normal) or other appropriate (for a non-continuous process) operating conditions (including waste and auxiliary fuel feed) and to determine the type of pollutants which might be emitted. At a minimum, the analysis must determine:
(Comment: As required by subparagraph (5)(d) of this rule, the owner or operator must place the results from each waste analysis, or the documented information, in the operating record of the facility.)
At closure, the owner or operator must remove all hazardous waste and hazardous waste residues (including, but not limited to, ash) from the thermal treatment process or equipment.
(Comment: At closure, as throughout the operating period, unless the owner or operator can demonstrate, in accordance with Rule 0400-12-01-.02(1)(c) 3 or 4, that any solid waste removed from his thermal treatment process or equipment is not a hazardous waste, the owner or operator becomes a generator of hazardous waste and must manage it in accordance with all applicable requirements of this rule and Rules 0400-12-01-.03 and .04.)
Open burning of hazardous waste is prohibited except for the open burning and detonation of waste explosives. Waste explosives include waste which has the potential to detonate and bulk military propellants which cannot safely be disposed of through other modes of treatment. Detonation is an explosion in which chemical transformation passes through the material faster than the speed of sound (0.33 kilometers/second at sea level). Owners or operators choosing to open burn or detonate waste explosives must do so in accordance with the following table and in a manner that does not threaten human health or the environment.
Pounds of waste explosives or propellants | Minimum distance from open burning or detonation to the property of others |
0 to 100 | 204 meters (670 feet). |
101 to 1,000 | 380 meters (1,250 feet). |
1,001 to 10,000 | 530 meters (1,730 feet). |
10,001 to 30,000 | 690 meters (2,260 feet). |
(Note: Implementation of this provision remains with EPA.)
The regulations in this paragraph apply to owners and operators of facilities which treat hazardous wastes by chemical, physical, or biological methods in other than tanks, surface impoundments, and land treatment facilities, except as paragraph (1) of this rule provides otherwise. Chemical, physical, and biological treatment of hazardous waste in tanks, surface impoundments, and land treatment facilities must be conducted in accordance with paragraphs (10), (11) and (13) of this rule, respectively.
(Comment: These systems are intended to be used in the event of a malfunction in the treatment process or equipment.)
In addition to the waste analysis required by subparagraph (2)(d) of this rule, whenever a hazardous waste which is substantially different from waste previously treated in a treatment process or equipment at the facility is to be treated in that process or equipment or whenever a substantially different process from any previously used at the facility is to be used chemically to treat hazardous waste, before treating the different waste or using the different process or equipment, the owner or operator must:
(Comment: As required by subparagraph (2)(d) of this rule, the waste analysis plan must include analyses needed to comply with subparagraphs (f) and (g) of this paragraph. As required by subparagraph (5)(d) of this rule, the owner or operator must place the results from each waste analysis and trial test, or the documented information, in the operating record of the facility.)
(Comment: As required by subparagraph (2)(f)3 of this rule, the owner or operator must remedy any deterioration or malfunction he finds.)
At closure, all hazardous waste and hazardous waste residues must be removed from treatment processes or equipment, discharge control equipment, and discharge confinement structures.
(Comment: At closure, as throughout the operating period, unless the owner or operator can demonstrate, in accordance with Rule 0400-12-01-.02(1)(c) 3 or 4, that any solid waste removed from his treatment process or equipment is not a hazardous waste, the owner or operator becomes a generator of hazardous waste and must manage it in accordance with all applicable requirements of this rule and Rules 0400-12-01-.03 and .04.)
Except as subparagraph (1)(b) of this rule provides otherwise:
(Note: Implementation of these provisions between December 6, 1990 and February 14, 1992 remains with EPA.)
Owners and operators of new drip pads must ensure that the pads are designed, installed, and operated in accordance with one of the following:
(Note: The Commissioner will generally consider applicable standards established by professional organizations generally recognized by industry such as the American Concrete Institute (ACI) and the American Society of Testing Materials (ASTM) in judging the structural integrity requirement of this subpart.)
(Note: See part 13 of this subparagraph for remedial action required if deterioration or leakage is detected.)
(Note: See part (d)13 of this paragraph for remedial action required if deterioration or leakage is detected.)
(Note: The requirements of subparagraphs (c) through (f) of this paragraph apply to process vents on hazardous waste recycling units previously exempt under Rule 0400-12-01-.02(1)(f) 3(i). Other exemptions under Rules 0400-12-01-.02(1)(d) and part (1)(b)2 of this rule are not affected by these requirements.)
As used in this paragraph, all terms shall have the meaning given them in Rule 0400-12-01-.06(30)(b), Tennessee Code Annotated §§ 68-212-101 et seq., Rules 0400-12-01-.01 through .06, and Rule 0400-12-01-.09.
where:
Ht = Net heating value of the sample, MJ/scm; where the net enthalpy per mole of offgas is based on combustion at 25 °C and 760 mm Hg, but the standard temperature for determining the volume corresponding to 1 mol is 20 °C;
K = Constant, 1.74 x 10-7 (1/ppm) (g mol/scm) (MJ/kcal) where standard temperature for (g mol/scm) is 20 °C;
Ci = Concentration of sample component i in ppm on a wet basis, as measured for organics by Reference Method 18 in 40 CFR part 60 and measured for hydrogen and carbon monoxide by ASTM D 1946-82 (listed in Rule 0400-12-01-.01(2)(b)); and
Hi = Net heat of combustion of sample component i, kcal/ g mol at 25 °C and 760 mm Hg. The heats of combustion may be determined using ASTM D 2382-83 (listed in Rule 0400-12-01-.01(2)(b)) if published values are not available or cannot be calculated.
Log 10 (Vmax) = (Ht + 28.8) ÷ 31.7 where:
HT= The net heating value as determined in subpart 5(ii) of this subparagraph,
28.8 = Constant,
31.7 = Constant.
Vmax = Vmax = 8.706 + 0.7084 (HT) where:
8.706 = Constant,
0.7084 = Constant,
HT = The net heating value as determined in subpart 5(ii) of this subparagraph.
where:
Eh = Total organic mass flow rate, kg/h;
Q2sd = Volumetric flow rate of gases entering or exiting control device, as determined by Method 2, dscm/h;
n = Number of organic compounds in the vent gas;
Ci = Organic concentration in ppm, dry basis, of compound i in the vent gas, as determined by Method 18;
MWi = Molecular weight of organic compound i in the vent gas, kg/kg-mol;
0.0416 = Conversion factor for molar volume, kg - mol/m 3 (@ 293 K and 760 mm Hg);
10-6 = Conversion from ppm.
Eh = (Q)(C)(MW)(0.0416)(10-6) where:
Eh = Total organic mass flow rate, kg/h;
Q = Volumetric flow rate of gases entering or exiting control device, as determined by Method 2, dscm/h;
C = Organic concentration in ppm, dry basis, as determined by Method 25A;
MW = Molecular weight of propane, 44;
0.0416 = Conversion factor for molar volume, kg - mol/m3 (@ 293 K and 760 mm Hg);
10-6 = Conversion from ppm.
EA = (Eh)(H) where:
EA = Total organic mass emission rate, kg/y;
Eh = Total organic mass flow rate for the process vent, kg/h;
H = Total annual hours of operations for the affected unit, h.
(Note: The requirements of subparagraphs (c) through (o) of this paragraph apply to equipment associated with hazardous waste recycling units previously exempt under subpart (1)(f)3(i) of Rule 0400-12-01-.02. Other exemptions under subparagraph (1)(d) of Rule 0400-12-01-.02 and part (1)(b)2 of this rule are not affected by these requirements.)
As used in this subpart, all terms shall have the meaning given them in Rule 0400-12-01-.06(30)(b), Tennessee Code Annotated §§ 68-212-101 et seq., Rules 0400-12-01-.01 through .06, and Rule 0400-12-01-.09.
As used in this paragraph, all terms not defined herein shall have the meaning given to them in the Act and Rules 0400-12-01-.01 through .06 and .09.
"Average volatile organic concentration" or "average VO concentration" means the mass-weighted average volatile organic concentration of a hazardous waste as determined in accordance with the requirements of subparagraph (e) of this paragraph.
"Closure device" means a cap, hatch, lid, plug, seal, valve, or other type of fitting that blocks an opening in a cover such that when the device is secured in the closed position it prevents or reduces air pollutant emissions to the atmosphere. Closure devices include devices that are detachable from the cover (e.g., a sampling port cap), manually operated (e.g., a hinged access lid or hatch), or automatically operated (e.g., a spring-loaded pressure relief valve).
"Continuous seal" means a seal that forms a continuous closure that completely covers the space between the edge of the floating roof and the wall of a tank. A continuous seal may be a vapor-mounted seal, liquid-mounted seal, or metallic shoe seal. A continuous seal may be constructed of fastened segments so as to form a continuous seal.
"Cover" means a device that provides a continuous barrier over the hazardous waste managed in a unit to prevent or reduce air pollutant emissions to the atmosphere. A cover may have openings (such as access hatches, sampling ports, gauge wells) that are necessary for operation, inspection, maintenance, and repair of the unit on which the cover is used. A cover may be a separate piece of equipment which can be detached and removed from the unit or a cover may be formed by structural features permanently integrated into the design of the unit.
"Enclosure" means a structure that surrounds a tank or container, captures organic vapors emitted from the tank or container, and vents the captured vapors through a closed vent system to a control device.
"External floating roof" means a pontoon-type or double-deck type cover that rests on the surface of the material managed in a tank with no fixed roof.
"Fixed roof" means a cover that is mounted on a unit in a stationary position and does not move with fluctuations in the level of the material managed in the unit.
"Floating membrane cover" means a cover consisting of a synthetic flexible membrane material that rests upon and is supported by the hazardous waste being managed in a surface impoundment.
"Floating roof" means a cover consisting of a double deck, pontoon single deck, or internal floating cover which rests upon and is supported by the material being contained, and is equipped with a continuous seal.
"Hard-piping" means pipe or tubing that is manufactured and properly installed in accordance with relevant standards and good engineering practices.
"In light material service" means the container is used to manage a material for which both of the following conditions apply: The vapor pressure of one or more of the organic constituents in the material is greater than 0.3 kilopascals (kPa) at 20 oC; and the total concentration of the pure organic constituents having a vapor pressure greater than 0.3 kPa at 20 oC is equal to or greater than 20 percent by weight.
"Internal floating roof" means a cover that rests or floats on the material surface (but not necessarily in complete contact with it) inside a tank that has a fixed roof.
"Liquid-mounted seal" means a foam or liquid-filled primary seal mounted in contact with the hazardous waste between the tank wall and the floating roof continuously around the circumference of the tank.
"Malfunction" means any sudden, infrequent, and not reasonably preventable failure of air pollution control equipment, process equipment, or a process to operate in a normal or usual manner. Failures that are caused in part by poor maintenance or careless operation are not malfunctions.
"Maximum organic vapor pressure" means the sum of the individual organic constituent partial pressures exerted by the material contained in a tank, at the maximum vapor pressure-causing conditions (i.e., temperature, agitation, pH effects of combining wastes, etc.) reasonably expected to occur in the tank. For the purpose of this subpart, maximum organic vapor pressure is determined using the procedures specified in part (e)3 of this paragraph.
"Metallic shoe seal" means a continuous seal that is constructed of metal sheets which are held vertically against the wall of the tank by springs, weighted levers, or other mechanisms and is connected to the floating roof by braces or other means. A flexible coated fabric (envelope) spans the annular space between the metal sheet and the floating roof.
"No detectable organic emissions" means no escape of organics to the atmosphere as determined using the procedure specified in part (e)4 of this paragraph.
"Point of waste origination" means as follows:
(Note: In this case, this term is being used in a manner similar to the use of the term "point of generation" in air standards established for waste management operations under authority of the Clean Air Act in 40 CFR Parts 60, 61, and 63.)
"Point of waste treatment" means the point where a hazardous waste to be treated in accordance with subpart (d)3(ii) of this paragraph exits the treatment process. Any waste determination shall be made before the waste is conveyed, handled, or otherwise managed in a manner that allows the waste to volatilize to the atmosphere.
"Safety device" means a closure device such as a pressure relief valve, frangible disc, fusible plug, or any other type of device which functions exclusively to prevent physical damage or permanent deformation to a unit or its air emission control equipment by venting gases or vapors directly to the atmosphere during unsafe conditions resulting from an unplanned, accidental, or emergency event. For the purpose of this subpart, a safety device is not used for routine venting of gases or vapors from the vapor headspace underneath a cover such as during filling of the unit or to adjust the pressure in this vapor headspace in response to normal daily diurnal ambient temperature fluctuations. A safety device is designed to remain in a closed position during normal operations and open only when the internal pressure, or another relevant parameter, exceeds the device threshold setting applicable to the air emission control equipment as determined by the owner or operator based on manufacturer recommendations, applicable regulations, fire protection and prevention codes, standard engineering codes and practices, or other requirements for the safe handling of flammable, ignitable, explosive, reactive, or hazardous materials.
"Single-seal system" means a floating roof having one continuous seal. This seal may be vapor-mounted, liquid-mounted, or a metallic shoe seal.
"Vapor-mounted seal" means a continuous seal that is mounted such that there is a vapor space between the hazardous waste in the unit and the bottom of the seal.
"Volatile organic concentration" or "VO concentration" means the fraction by weight of the volatile organic compounds contained in a hazardous waste expressed in terms of parts per million (ppmw) as determined by direct measurement or by knowledge of the waste in accordance with the requirements of subparagraph (e) of this paragraph. For the purpose of determining the VO concentration of a hazardous waste, organic compounds with a Henry's law constant value of at least 0.1 mole-fraction-in-the-gas-phase/mole-fraction-in-the-liquid-phase (0.1 Y/X) (which can also be expressed as 1.8 x 10-6 atmospheres/ gram-mole/m3) at 25 degrees Celsius must be included. Appendix VI of paragraph (53) of this rule presents a list of compounds known to have a Henry's law constant value less than the cutoff level.
"Waste determination" means performing all applicable procedures in accordance with the requirements of subparagraph (e) of this paragraph to determine whether a hazardous waste meets standards specified in this paragraph. Examples of a waste determination include performing the procedures in accordance with the requirements of subparagraph (e) of this paragraph to determine the average VO concentration of a hazardous waste at the point of waste origination; the average VO concentration of a hazardous waste at the point of waste treatment and comparing the results to the exit concentration limit specified for the process used to treat the hazardous waste; the organic reduction efficiency and the organic biodegradation efficiency for a biological process used to treat a hazardous waste and comparing the results to the applicable standards; or the maximum volatile organic vapor pressure for a hazardous waste in a tank and comparing the results to the applicable standards.
"Waste stabilization process" means any physical or chemical process used to either reduce the mobility of hazardous constituents in a hazardous waste or eliminate free liquids as determined by Test Method 9095B (Paint Filter Liquids Test) in "Test Methods for Evaluating Solid Waste, Physical/Chemical Methods," EPA Publication No. SW-846, (see CFR 260.11; Rule 0400-12-01-.01(2)(b) 1). A waste stabilization process includes mixing the hazardous waste with binders or other materials, and curing the resulting hazardous waste and binder mixture. Other synonymous terms used to refer to this process are "waste fixation" or "waste solidification." This does not include the adding of absorbent materials to the surface of a waste, without mixing, agitation, or subsequent curing, to absorb free liquid.
Where:
[C-BAR] = Average VO concentration of the hazardous waste at the point of waste origination on a mass-weighted basis, ppmw.
i = Individual waste determination "i" of the hazardous waste.
n = Total number of waste determinations of the hazardous waste conducted for the averaging period (not to exceed 1 year).
Qi = Mass quantity of hazardous waste stream represented by Ci, kg/hr.
QT = Total mass quantity of hazardous waste during the averaging period, kg/hr.
Ci = Measured VO concentration of waste determination "i" as determined in accordance with the requirements of item 1(iii)(III) of this subparagraph, (i.e., the average of the four or more samples specified in subitem 1(iii)(II)II of this subparagraph), ppmw.
Where:
[C-BAR] = Average VO concentration of the hazardous waste at the point of waste treatment on a mass-weighted basis, ppmw.
i = Individual waste determination "i" of the hazardous waste.
n = Total number of waste determinations of the hazardous waste conducted for the averaging period (not to exceed 1 year).
Qi = Mass quantity of hazardous waste stream represented by Ci, kg/hr.
QT = Total mass quantity of hazardous waste during the averaging period, kg/hr.
Ci = Measured VO concentration of waste determination "i" as determined in accordance with the requirements of item (III) of this subpart, (i.e. the average of the four or more samples specified in subitem (II)II of this subpart), ppmw.
Where:
Ct = Exit concentration limit for treated hazardous waste, ppmw.
x = Individual hazardous waste stream "x" that has an average VO concentration less than 500 ppmw at the point of waste origination as determined in accordance with the requirements of part (e)1 of this paragraph.
y = Individual hazardous waste stream "y" that has an average VO concentration equal to or greater than 500 ppmw at the point of waste origination as determined in accordance with the requirements of part (e)1 of this paragraph.
m = Total number of "x" hazardous waste streams treated by process.
n = Total number of "y" hazardous waste streams treated by process.
Qx = Annual mass quantity of hazardous waste stream "x," kg/yr.
Qy = Annual mass quantity of hazardous waste stream "y," kg/yr.
[C-BAR] = Average VO concentration of hazardous waste stream "x" at the point of waste origination as determined in accordance with the requirements of part (e)1 of this paragraph, ppmw.
Where:
Ea = Waste volatile organic mass flow exiting process, kg/hr.
Eb = Waste volatile organic mass flow entering process, kg/hr.
m = Total number of runs (at least 3)
j = Individual run "j"
Qb = Mass quantity of hazardous waste entering process during run "j," kg/hr.
Qa = Average mass quantity of hazardous waste exiting process during run "j," kg/hr.
[C-BAR]a = Average VO concentration of hazardous waste exiting process during run "j" as determined in accordance with the requirements of subpart (e)2(iii) of this paragraph, ppmw.
[C-BAR]b = Average VO concentration of hazardous waste entering process during run "j" as determined in accordance with the requirements of subpart (e)1(iii) of this paragraph, ppmw.
Where:
R = Organic reduction efficiency, percent.
Eb = Waste volatile organic mass flow entering process as determined in accordance with the requirements of item (IV) of this subpart, kg/hr.
Ea = Waste volatile organic mass flow exiting process as determined in accordance with the requirements of item (IV) of this subpart, kg/hr.
Rbio = Fbio x 100%
Where:
Rbio = Organic biodegradation efficiency, percent.
Fbio = Fraction of organic biodegraded as determined in accordance with the requirements of item (I) of this subpart.
Where:
RMR = Required organic mass removal rate, kg/hr.
y = Individual hazardous waste stream "y" that has an average VO concentration equal to or greater than 500 ppmw at the point of waste origination as determined in accordance with the requirements of part (e)1 of this paragraph.
n = Total number of "y" hazardous waste streams treated by process.
Vy = Average volumetric flow rate of hazardous waste stream "y" at the point of waste origination, m3/hr.
ky = Density of hazardous waste stream "y," kg/m3
[C-BAR]y = Average VO concentration of hazardous waste stream "y" at the point of waste origination as determined in accordance with the requirements of part (e)1 of this paragraph, ppmw.
MR = Eb - Ea
Where:
MR = Actual organic mass removal rate, kg/hr.
Eb = Waste volatile organic mass flow entering process as determined in accordance with the requirements of item (v)(IV) of this part, kg/hr.
Ea = Waste volatile organic mass flow exiting process as determined in accordance with the requirements of item (v)(IV) of this part, kg/hr.
MRbio = Eb x Fbio
Where:
MRbio = Actual organic mass biodegradation rate, kg/hr.
Eb = Waste organic mass flow entering process as determined in accordance with the requirements of item (v)(IV) of this part, kg/hr.
Fbio = Fraction of organic biodegraded as determined in accordance with the requirements of item (III) of this subpart.
Repair of the defect shall be completed before the process or unit resumes operation.
The requirements of this paragraph apply to owners or operators who store or treat hazardous waste in units designed and operated under subparagraph (b) of this paragraph. The owner or operator is not subject to the definition of land disposal in Rule 0400-12-01-.01(2)(a) provided that the unit:
The requirements of this paragraph apply to owners or operators who store munitions and explosive hazardous wastes, except as subparagraph (1)(b) of this rule provides otherwise.
(NOTE: Depending on explosive hazards, hazardous waste munitions and explosives may also be managed in other types of storage units, including containment buildings (paragraph (30) of this rule), tanks (paragraph (10) of this rule), or containers (paragraph (9) of this rule); see Rule 0400-12-01-.09(13)(f) for storage of waste military munitions.)
Appendix I -- Recordkeeping Instructions [40 CFR 265 Appendix I]
The recordkeeping provisions of subparagraph (5)(d) of this rule specify that an owner or operator must keep a written operating record at his facility. This appendix provides additional instructions for keeping portions of the operating record. See part (5)(d)2 of this rule for additional recordkeeping requirements.
The following information must be recorded, as it becomes available, and maintained in the operating record until closure of the facility in the following manner:
Each hazardous waste listed in Rule 0400-12-01-.02(4), and each hazardous waste characteristic defined in Rule 0400-12-01-.02(3), has a four-digit Hazardous Waste Code assigned to it. This code must be used for recordkeeping and reporting purposes. Where a hazardous waste contains more than one listed hazardous waste, or where more than one hazardous waste characteristic applies to the waste, the waste description must include all applicable Hazardous Waste Codes.
Table 1
Unit of Measure | Code1 |
Gallons | G |
Gallons per Hour | E |
Gallons per Day | U |
Liters | L |
Liters Per Hour | H |
Liters Per Day | V |
Tons | M |
Short tons | T |
Short Tons Per Hour | D |
Metric Tons Per Hour | W |
Short Tons Per Day | N |
Metric Tons Per Day | S |
Pounds | P |
Pounds Per Hour | J |
Kilograms | K |
Kilograms Per Hour | R |
Cubic Yards | Y |
Cubic Meters | C |
Acres | B |
Acre-feet | A |
Hectares | Q |
Hectare-meter | F |
Btu's per Hour | I |
FOOTNOTE: 1Single digit symbols are used here for data processing purposes.
Table 2-Handling Codes for Treatment, Storage and Disposal Methods
Enter the handling code(s) listed below that most closely represents the technique(s) used at the facility to treat, store or dispose of each quantity of hazardous waste received.
S01 Container (barrel, drum, etc.)
S02 Tank
S03 Waste Pile
S04 Surface Impoundment
S05 Drip Pad
S06 Containment Building (Storage)
S99 Other Storage (specify)
T06 Liquid injection incinerator
T07 Rotary kiln incinerator
T08 Fluidized bed incinerator
T09 Multiple hearth incinerator
T10 Infrared furnace incinerator
T11 Molten salt destructor
T12 Pyrolysis
T13 Wet Air oxidation
T14 Calcination
T15 Microwave discharge
T18 Other (specify)
T19 Absorption mound
T20 Absorption field
T21 Chemical fixation
T22 Chemical oxidation
T23 Chemical precipitation
T24 Chemical reduction
T25 Chlorination
T26 Chlorinolysis
T27 Cyanide destruction
T28 Degradation
T29 Detoxification
T30 Ion exchange
T31 Neutralization
T32 Ozonation
T33 Photolysis
T34 Other (specify)
T35 Centrifugation
T36 Clarification
T37 Coagulation
T38 Decanting
T39 Encapsulation
T40 Filtration
T41 Flocculation
T42 Flotation
T43 Foaming
T44 Sedimentation
T45 Thickening
T46 Ultrafiltration
T47 Other (specify)
T48 Absorption-molecular sieve
T49 Activated carbon
T50 Blending
T51 Catalysis
T52 Crystallization
T53 Dialysis
T54 Distillation
T55 Electrodialysis
T56 Electrolysis
T57 Evaporation
T58 High gradient magnetic separation
T59 Leaching
T60 Liquid ion exchange
T61 Liquid-liquid extraction
T62 Reverse osmosis
T63 Solvent recovery
T64 Stripping
T65 Sand filter
T66 Other (specify)
T67 Activated sludge
T68 Aerobic lagoon
T69 Aerobic tank
T70 Anaerobic tank
T71 Composting
T72 Septic tank
T73 Spray irrigation
T74 Thickening filter
T75 Trickling filter
T76 Waste stabilization pond
T77 Other (specify)
T78 [Reserved]
T79 [Reserved]
T80 Boiler
T81 Cement Kiln
T82 Lime Kiln
T83 Aggregate Kiln
T84 Phosphate Kiln
T85 Coke Oven
T86 Blast Furnace
T87 Smelting, Melting, or Refining Furnace
T88 Titanium Dioxide Chloride Process Oxidation Reactor
T89 Methane Reforming Furnace
T90 Pulping Liquor Recovery Furnace
T91 Combustion Device Used in the Recovery of Sulfur Values from Spent Sulfuric Acid
T92 Halogen Acid Furnaces
T93 Other Industrial Furnaces Listed in 40 CFR 260.10 (specify) (f) Other Treatment
T94 Containment Building (Treatment)
D79 Underground Injection
D80 Landfill
D81 Land Treatment
D82 Ocean Disposal
D83 Surface Impoundment (to be closed as a landfill)
D99 Other Disposal (specify)
X01 Open Burning/Open Detonation
X02 Mechanical Processing
X03 Thermal Unit
X04 Geologic Repository
X99 Other (specify)
Appendix II -- (RESERVED) [40 CFR 265 Appendix II]
Appendix III -- EPA Interim Primary Drinking Water Standards [40 CFR 265 Appendix III]
Parameter | Maximum Level (mg/l) |
Arsenic | 0.05 |
Barium | 1.0 |
Cadmium | 0.01 |
Chromium | 0.05 |
Fluoride | 1.4-2.4 |
Lead | 0.05 |
Mercury | 0.002 |
Nitrate (as N) | 10 |
Selenium | 0.01 |
Silver | 0.05 |
Endrin | 0.0002 |
Lindane | 0.004 |
Methoxychlor | 0.1 |
Toxaphene | 0.005 |
2,4-D | 0.1 |
2,4,5-TP Silver | 0.01 |
Radium | 5 pCi/1 |
Gross Alpha | 15 pCi/1 |
Gross Beta | 4 millirem/yr |
Turbidity | 1/TU |
Coliform Bacteria | 1/100 ml |
Footnote: (Comment: Turbidity is applicable only to surface water supplies.)
Appendix IV-- Tests for Significance [40 CFR 265 Appendix IV]
As required in part (6)(d)2 of this rule the owner or operator must use the Student's t-test to determine statistically significant changes in the concentration or value of an indicator parameter in periodic ground-water samples when compared to the initial background concentration or value of that indicator parameter. The comparison must consider individually each of the wells in the monitoring system. For three of the indicator parameters (specific conductance, total organic carbon, and total organic halogen) a single-tailed Student's t-test must be used to test at the 0.01 level of significance for significant increases over background. The difference test for pH must be a two-tailed Student's t-test at the overall 0.01 level of significance.
The student's t-test involves calculation of the value of a t-statistic for each comparison of the mean (average) concentration or value (based on a minimum of four replicate measurements) of an indicator parameter with its initial background concentration or value. The calculated value of the t-statistic must then be compared to the value of the t-statistic found in a table for t-test of significance at the specified level of significance. A calculated value of t which exceeds the value of t found in the table indicates a statistically significant change in the concentration or value of the indicator parameter.
Formulae for calculation of the t-statistic and tables for t-test of significance can be found in most introductory statistics texts.
Appendix V -- Examples of Potentially Incompatible Waste [40 CFR 265 Appendix V]
Many hazardous wastes, when mixed with other waste or materials at a hazardous waste facility, can produce effects which are harmful to human health and the environment, such as (1) heat or pressure, (2) fire or explosion, (3) violent reaction, (4) toxic dusts, mists, fumes, or gases, or (5) flammable fumes or gases.
Below are examples of potentially incompatible wastes, waste components, and materials, along with the harmful consequences which result from mixing materials in one group with materials in another group. The list is intended as a guide to owners or operators of treatment, storage, and disposal facilities, and to enforcement and permit granting officials, to indicate the need for special precautions when managing these potentially incompatible waste materials or components.
This list is not intended to be exhaustive. An owner or operator must, as the regulations require, adequately analyze his wastes so that he can avoid creating uncontrolled substances or reactions of the type listed below, whether they are listed below or not.
It is possible for potentially incompatible wastes to be mixed in a way that precludes a reaction (e.g., adding acid to water rather than water to acid) or that neutralizes them (e.g., a strong acid mixed with a strong base), or that controls substances produced (e.g., by generating flammable gases in a closed tank equipped so that ignition cannot occur, and burning the gases in an incinerator).
In the lists below, the mixing of a Group A material with a Group B material may have the potential consequence as noted.
Group 1-A
Acetylene sludge
Alkaline caustic liquids
Alkaline cleaner
Alkaline corrosive liquids
Alkaline corrosive battery fluid
Caustic wastewater
Lime sludge and other corrosive alkalies
Lime wastewater
Lime and water
Spent caustic
Group 1-B
Acid sludge
Acid and water
Battery acid
Chemical cleaners
Electrolyte, acid
Etching acid liquid or solvent
Pickling liquor and other corrosive acids
Spent acid
Spent mixed acid
Spent sulfuric acid
Potential consequences: Heat generation; violent reaction.
* * * * * * * * * *
Group 2-A
Aluminum
Beryllium
Calcium
Lithium
Magnesium
Potassium
Sodium
Zinc powder
Other reactive metals and metal hydrides
Group 2-B
Any waste in Group 1-A or 1-B
Potential consequences: Fire or explosion; generation of flammable hydrogen gas.
* * * * * * * * * *
Group 3-A
Alcohols Water
Group 3-B
Any concentrated waste in Groups 1-A or 1-B
Calcium
Lithium
Metal hydrides
Potassium SO2C12, SOC12, PC13, CH3SiC13
Other water-reactive waste
Potential consequences: Fire, explosion, or heat generation; generation of flammable or toxic gases.
* * * * * * * * * *
Group 4-A
Alcohols
Aldehydes
Halogenated hydrocarbons
Nitrated hydrocarbons
Unsaturated hydrocarbons
Other reactive organic compounds and solvents
Group 4-B
Concentrated Group 1-A or 1-B wastes Group 2-A wastes
Potential consequences: Fire, explosion, or violent reaction.
* * * * * * * * * *
Group 5-A
Spent cyanide and sulfide solutions
Group 5-B
Group 1-B wastes
Potential consequences: Generation of toxic hydrogen cyanide or hydrogen sulfide gas.
* * * * * * * * * *
Group 6-A
Chlorates
Chlorine
Chlorites
Chromic acid
Hyphochlorites
Nitrates
Nitric acid, fuming
Perchlorates
Permanganates
Peroxides
Other strong oxidizers
Group 6-B
Acetic acid and other organic acids
Concentrated mineral acids
Group 2-A wastes
Group 4-A wastes
Other flammable and combustible wastes
Potential consequences: Fire, explosion, or violent reaction.
* * * * * * * * * *
Appendix VI--Compounds With Henry's Law Constant Less Than 0.1 Y/X [40 CFR 265 Appendix VI]
Compound name | CAS No. |
Acetaldol | 107-89-1 |
Acetamide | 60-35-5 |
2-Acetylaminofluorene | 53-96-3 |
3-Acetyl-5-hydroxypiperidine | |
3-Acetylpiperidine | 618-42-8 |
1-Acetyl-2-thiourea | 591-08-2 |
Acrylamide | 79-06-1 |
Acrylic acid | 79-10-7 |
Adenine | 73-24-5 |
Adipic acid | 124-04-9 |
Adiponitrile | 111-69-3 |
Alachlor | 15972-60-8 |
Aldicarb | 116-06-3 |
Ametryn | 834-12-8 |
4-Aminobiphenyl | 92-67-1 |
4-Aminopyridine | 504-24-5 |
Aniline | 62-53-3 |
o-Anisidine | 90-04-0 |
Anthraquinone | 84-65-1 |
Atrazine | 1912-24-9 |
Benzenearsonic acid | 98-05-5 |
Benzenesulfonic acid | 98-11-3 |
Benzidine | 92-87-5 |
Benzo(a)anthracene | 56-55-3 |
Benzo(k)fluoranthene | 207-08-9 |
Benzoic acid | 65-85-0 |
Benzo(g,h,i)perylene | 191-24-2 |
Benzo(a)pyrene | 50-32-8 |
Benzyl alcohol | 100-51-6 |
gamma-BHC | 58-89-9 |
Bis(2-ethylhexyl)phthalate | 117-81-7 |
Bromochloromethyl acetate | |
Bromoxynil | 1689-84-5 |
Butyric acid | 107-92-6 |
Caprolactam (hexahydro-2H-azepin-2-one) | 105-60-2 |
Catechol (o-dihydroxybenzene) | 120-80-9 |
Cellulose | 9004-34-6 |
Cell wall | |
Chlorhydrin (3-Chloro-1,2-propanediol). | 96-24-2 |
Chloroacetic acid | 79-11-8 |
2-Chloroacetophenone | 93-76-5 |
p-Chloroaniline | 106-47-8 |
p-Chlorobenzophenone | 134-85-0 |
Chlorobenzilate | 510-15-6 |
p-Chloro-m-cresol (6-chloro-m-cresol) | 59-50-7 |
3-Chloro-2,5-diketopyrrolidine | |
Chloro-1,2-ethane diol | |
4-Chlorophenol | 106-48-9 |
Chlorophenol polymers (2-chlorophenol & 4-chlorophenol) | 95-57-8 & |
106-48-9 | |
1-(o-Chlorophenyl)thiourea | 5344-82-1 |
Chrysene | 218-01-9 |
Citric acid | 77-92-9 |
Creosote | 8001-58-9 |
m-Cresol | 108-39-4 |
o-Cresol | 95-48-7 |
p-Cresol | 106-44-5 |
Cresol (mixed isomers) | 19-77-3 |
4-Cumylphenol | 27576-86 |
Cyanide | 57-12-5 |
4-Cyanomethyl benzoate | |
Diazinon | 333-41-5 |
Dibenzo(a,h)anthracene | 53-70-3 |
Dibutylphthalate | 84-74-2 |
2,5-Dichloroaniline (N,N'-dichloroaniline) | 95-82-9 |
2,6-Dichlorobenzonitrile11 | 1194-65-6 |
2,6-Dichloro-4-nitroaniline | 99-30-9 |
2,5-Dichlorophenol | 333-41-5 |
3,4-Dichlorotetrahydrofuran | 3511-19 |
Dichlorvos (DDVP) | 62-73-7 |
Diethanolamine | 111-42-2 |
N,N-Diethylaniline | 91-66-7 |
Diethylene glycol | 111-46-6 |
Diethylene glycol dimethyl ether (dimethyl Carbitol) | 111-96-6 |
Diethylene glycol monobutyl ether (butyl Carbitol) | 112-34-5 |
Diethylene glycol monoethyl ether acetate (Carbitol acetate) | 112-15-2 |
Diethylene glycol monoethyl ether (Carbitol Cellosolve) | 111-90-0 |
Diethylene glycol monomethyl ether (methyl Carbitol) | 111-77-3 |
N,N'-Diethylhydrazine | 1615-80-1 |
Diethyl (4-methylumbelliferyl) thionophosphate | 299-45-6 |
Diethyl phosphorothioate | 126-75-0 |
N,N'-Diethylpropionamide | 15299-99-7 |
Dimethoate | 60-51-5 |
2,3-Dimethoxystrychnidin-10-one | 357-57-3 |
4-Dimethylaminoazobenzene | 60-11-7 |
7,12-Dimethylbenz(a)anthracene | 57-97-6 |
3,3-Dimethylbenzidine | 119-93-7 |
Dimethylcarbamoyl chloride | 79-44-7 |
Dimethyldisulfide | 624-92-0 |
Dimethylformamide | 68-12-2 |
1,1-Dimethylhydrazine | 57-14-7 |
Dimethylphthalate | 131-11-3 |
Dimethylsulfone | 67-71-0 |
Dimethylsulfoxide | 67-68-5 |
4,6-Dinitro-o-cresol | 534-52-1 |
1,2-Diphenylhydrazine | 122-66-7 |
Dipropylene glycol (1,1'-oxydi-2-propanol) | 110-98-5 |
Endrin | 72-20-8 |
Epinephrine | 51-43-4 |
mono-Ethanolamine | 141-43-5 |
Ethyl carbamate (urethane) | 5-17-96 |
Ethylene glycol | 107-21-1 |
Ethylene glycol monobutyl ether (butyl Cellosolve) | 111-76-2 |
Ethylene glycol monoethyl ether (Cellosolve) | 110-80-5 |
Ethylene glycol monoethyl ether acetate (Cellosolve acetate) | 111-15-9 |
Ethylene glycol monomethyl ether (methyl Cellosolve) | 109-86-4 |
Ethylene glycol monophenyl ether (phenyl Cellosolve) | 122-99-6 |
Ethylene glycol monopropyl ether (propyl Cellosolve) | 2807-30-9 |
Ethylene thiourea (2-imidazolidinethione) | 96-45-7 |
4-Ethylmorpholine | 100-74-3 |
3-Ethylphenol | 620-17-7 |
Fluoroacetic acid, sodium salt | 62-74-8 |
Formaldehyde | 50-00-0 |
Formamide | 75-12-7 |
Formic acid | 64-18-6 |
Fumaric acid | 110-17-8 |
Glutaric acid | 110-94-1 |
Glycerin (Glycerol) | 56-81-5 |
Glycidol | 556-52-5 |
Glycinamide | 598-41-4 |
Glyphosate | 1071-83-6 |
Guthion | 86-50-0 |
Hexamethylene-1,6-diisocyanate (1,6-diisocyanatohexane) | 822-06-0 |
Hexamethyl phosphoramide | 680-31-9 |
Hexanoic acid | 142-62-1 |
Hydrazine | 302-01-2 |
Hydrocyanic acid | 74-90-8 |
Hydroquinone | 123-31-9 |
Hydroxy-2-propionitrile (hydracrylonitrile) | 109-78-4 |
Indeno (1,2,3-cd) pyrene | 193-39-5 |
Lead acetate | 301-04-2 |
Lead subacetate (lead acetate, monobasic) | 1335-32-6 |
Leucine | 61-90-5 |
Malathion | 121-75-5 |
Maleic acid | 110-16-7 |
Maleic anhydride | 108-31-6 |
Mesityl oxide | 141-79-7 |
Methane sulfonic acid | 75-75-2 |
Methomyl | 16752-77-5 |
p-Methoxyphenol | 150-76-5 |
Methyl acrylate | 96-33-3 |
4,4'-Methylene-bis-(2-chloroaniline) | 101-14-4 |
4,4'-Methylenediphenyl diisocyanate (diphenyl methane | 101-68-8 |
diisocyanate) | |
4,4'-Methylenedianiline | 101-77-9 |
Methylene diphenylamine (MDA) | |
5-Methylfurfural | 620-02-0 |
Methylhydrazine | 60-34-4 |
Methyliminoacetic acid | |
Methyl methane sulfonate | 66-27-3 |
1-Methyl-2-methoxyaziridine | |
Methylparathion | 298-00-0 |
Methyl sulfuric acid (sulfuric acid, dimethyl ester) | 77-78-1 |
4-Methylthiophenol | 106-45-6 |
Monomethylformamide (N-methylformamide) | 123-39-7 |
Nabam | 142-59-6 |
alpha-Naphthol | 90-15-3 |
beta-Naphthol | 135-19-3 |
alpha-Naphthylamine | 134-32-7 |
beta-Naphthylamine | 91-59-8 |
Neopentyl glycol (dimethylpropane) | 126-30-7 |
Niacinamide | 98-92-0 |
o-Nitroaniline | 88-74-4 |
Nitroglycerin | 55-63-0 |
2-Nitrophenol | 88-75-5 |
4-Nitrophenol | 100-02-7 |
N-Nitrosodimethylamine | 62-75-9 |
Nitrosoguanidine | 674-81-7 |
N-Nitroso-n-methylurea | 684-93-5 |
N-Nitrosomorpholine (4-nitrosomorpholine) | 59-89-2 |
Oxalic acid | 144-62-7 |
Parathion | 56-38-2 |
Pentaerythritol | 115-77-5 |
Phenacetin | 62-44-2 |
Phenol | 108-95-2 |
Phenylacetic acid | 103-82-2 |
m-Phenylene diamine | 108-45-2 |
o-Phenylene diamine | 95-54-5 |
p-Phenylene diamine | 106-50-3 |
Phenyl mercuric acetate | 62-38-4 |
Phorate | 298-02-2 |
Phthalic anhydride | 85-44-9 |
alpha-Picoline (2-methyl pyridine) | 109-06-8 |
1,3-Propane sultone | 1120-71-4 |
beta-Propiolactone | 57-57-8 |
Proporur (Baygon) | |
Propylene glycol | 57-55-6 |
Pyrene | 129-00-0 |
Pyridinium bromide | 39416-48-3 |
Quinoline | 91-22-5 |
Quinone (p-benzoquinone) | 106-51-4 |
Resorcinol | 108-46-3 |
Simazine | 122-34-9 |
Sodium acetate | 127-09-3 |
Sodium formate | 141-53-7 |
Strychnine | 57-24-9 |
Succinic acid | 110-15-6 |
Succinimide | 123-56-8 |
Sulfanilic acid | 121-47-1 |
Terephthalic acid | 100-21-0 |
Tetraethyldithiopyrophosphate | 3689-24-5 |
Tetraethylenepentamine | 112-57-2 |
Thiofanox | 39196-18-4 |
Thiosemicarbazide | 79-19-6 |
2,4-Toluenediamine | 95-80-7 |
2,6-Toluenediamine | 823-40-5 |
3,4-Toluenediamine | 496-72-0 |
2,4-Toluene diisocyanate | 584-84-9 |
p-Toluic acid | 99-94-5 |
m-Toluidine | 108-44-1 |
1,1,2-Trichloro-1,2,2-trifluoroethane | 76-13-1 |
Triethanolamine | 102-71-6 |
Triethylene glycol dimethyl ether | |
Tripropylene glycol | 24800-44-0 |
Warfarin | 81-81-2 |
3,4-Xylenol (3,4-dimethylphenol) | 95-65-8 |
NOTE: RELATION BETWEEN HENRY'S LAW CONSTANT AS Y/X (MOLE FRACTION GAS PHASE/MOLE FRACTION AQUEOUS PHASE, UNITLESS) AND HENRY'S LAW CONSTANT AS EQUILIBRIUM CONSTANT (Ka) IN UNITS OF ATMOSPHERES/(MOLE/M3): Y/X= Kax5.2x10-4; THUS, 0.1 Y/X=1.8x10-4 atmospheres/mole/m3, which is the partial pressure of the compound in the gas phase in equilibrium with the compound dissolved in water at a concentration of one mole per cubic meter. (Volume of one cubic meter=1,000 liters=1 kiloliter.)
Tenn. Comp. R. & Regs. 0400-12-01-.05
Authority: T.C.A. §§ 4-5-201, et seq., and 68-212-101, et seq.