25 Pa. Code § 129.139

Current through Register Vol. 54, No. 45, November 9, 2024

Section 129.139 - Control devices

(a)Applicability. This section applies to the owner or operator of each control device that receives a liquid, gas, vapor or fume from a source subject to § 129.133(b)(1)(iii), § 129.135(b)(1)(ii) or (c)(1), or § 129.136(b)(2) or (c)(2) (relating to storage vessels; natural gas-driven diaphragm pumps; and compressors).

(1) The owner or operator shall perform the following:

(i) Operate each control device whenever a liquid, gas, vapor or fume is routed to the control device.

(ii) Maintain the records under § 129.140(j) (relating to recordkeeping and reporting) and submit the reports under § 129.140(k)(3)(ix).

(2) The owner or operator may route the liquid, gas, vapor or fume from more than one source subject to § 129.133(b)(1)(iii), § 129.135(b)(1)(ii) or (c)(1), or § 129.136(b)(2) or (c)(2) to a control device installed and operated under this section.

(b)General requirements for a control device. The owner or operator of a control device subject to this section shall install and operate one or more control devices listed in subsections (c)-(i). The owner or operator shall meet the following requirements, as applicable:

(1) Operate the control device following the manufacturer's written operating instructions, procedures and maintenance schedule to ensure good air pollution control practices for minimizing VOC emissions.

(2) Ensure that the control device is maintained in a leak-free condition by conducting a physical integrity check according to the manufacturer's instructions, with monthly inspections separated by at least 15 calendar days but not more than 45 calendar days.

(3) Maintain a pilot flame while operating the control device and monitor the pilot flame by installing a heat sensing CPMS as specified under subsection (m)(3). If the heat sensing CPMS indicates the absence of the pilot flame or if the control device is smoking or shows other signs of improper equipment operation, ensure the control device is returned to proper operation by performing the following procedures:

(i) Checking the air vent for obstruction and clearing an observed obstruction.

(ii) Checking for liquid reaching the combustor.

(4) Operate the control device with no visible emissions, except for periods not to exceed a total of 1 minute during a 15-minute period as determined by conducting a visible emissions test according to Section 11 of EPA Method 22.

(i) Each monthly visible emissions test shall be separated by at least 15 calendar days but not more than 45 calendar days.

(ii) The observation period for the test in subparagraph (i) shall be 15 minutes.

(5) Repair the control device if it fails the visible emissions test of paragraph (4) as specified in subparagraph (i) or subparagraph (ii) and return the control device to compliant operation.

(i) The manufacturer's repair instructions, if available.

(ii) The best combustion engineering practice applicable to the control device if the manufacturer's repair instructions are not available.

(6) Ensure the control device passes the EPA Method 22 visual emissions test described in paragraph (4) following return to operation from a maintenance or repair activity.

(7) Record the inspection, repair and maintenance activities for the control device in a maintenance and repair log.

(c)Compliance requirements for a manufacturer-tested combustion device. The owner or operator of a control device subject to this section that installs a control device tested under 40 CFR 60.5413a(d) (relating to what are the performance testing procedures for control devices used to demonstrate compliance at my centrifugal compressor and storage vessel affected facilities?) shall meet subsection (b)(1)- (7) and the following:

(1) Maintain the inlet gas flow rate at less than or equal to the maximum flow rate specified by the manufacturer. This is confirmed by one of the following:

(i) Installing, operating and maintaining a flow CPMS that meets subsection (m)(1) and (2)(i) to measure gas flow rate at the inlet to the control device.

(ii) Conducting a periodic performance test under subsection (k) instead of installing a flow CPMS to demonstrate that the mass content of VOC in the gases vented to the device is reduced by 95.0% by weight or greater.

(2) Submit an electronic copy of the performance test results to the EPA as required by 40 CFR 60.5413a(d) in accordance with 40 CFR 60.5413a(e)(6).

(d)Compliance requirements for an enclosed combustion device. The owner or operator of a control device subject to this section that installs an enclosed combustion device, such as a thermal vapor incinerator, catalytic vapor incinerator, boiler or process heater, shall meet subsection (b)(1)- (7) and the following:

(1) Ensure the enclosed combustion control device is designed and operated to meet one of the following performance requirements:

(i) To reduce the mass content of VOC in the gases vented to the device by 95.0% by weight or greater, as determined under subsection (k).

(ii) To reduce the concentration of TOC in the exhaust gases at the outlet to the device to a level less than or equal to 275 ppmvd as propane corrected to 3% oxygen as determined under subsection (l).

(iii) To operate at a minimum temperature of 760 °Celsius (1,400 °Fahrenheit), if it is demonstrated during the performance test conducted under subsection (k) that combustion zone temperature is an indicator of destruction efficiency.

(iv) To introduce the vent stream into the flame zone of the boiler or process heater if a boiler or process heater is used as the control device.

(2) Install, calibrate, operate and maintain a CPMS according to the manufacturer's specifications and subsection (m) to measure the values of the operating parameters appropriate to the control device as follows:

(i) For a thermal vapor incinerator that demonstrates under subsection (m)(6)(i) that combustion zone temperature is an accurate indicator of performance, a temperature CPMS that meets subsection (m)(1) and (4) with the temperature sensor installed at a location representative of the combustion zone temperature.

(ii) For a catalytic vapor incinerator, a temperature CPMS capable of monitoring temperature at two locations and that meets subsection (m)(1) and (4) with one temperature sensor installed in the vent stream at the nearest feasible point to the catalyst bed inlet and a second temperature sensor installed in the vent stream at the nearest feasible point to the catalyst bed outlet.

(iii) For a boiler or process heater that demonstrates under subsection (m)(6)(i) that combustion zone temperature is an accurate indicator of performance, a temperature CPMS that meets subsection (m)(1) and (4) with the temperature sensor installed at a location representative of the combustion zone temperature. The monitoring requirements do not apply if the boiler or process heater meets either of the following:

(A) Has a design heat input capacity of 44 megawatts (150 MMBtu per hour) or greater.

(B) Introduces the vent stream with the primary fuel or uses the vent stream as the primary fuel.

(iv) For a control device complying with paragraph (1)(ii), an organic concentration CPMS that meets subsection (m)(1) and (5) that measures the concentration level of organic compounds in the exhaust vent stream from the control device.

(3) Operate the control device in compliance with the operating parameter value established under subsection (m)(6).

(4) Calculate the daily average of the monitored operating parameter for each operating day, using the valid data recorded by the monitoring system under subsection (m)(7).

(5) Ensure that the daily average of the monitoring parameter value calculated under paragraph (4) complies with the parameter value established under paragraph (3) as specified in subsection (m)(9).

(6) Operate the CPMS installed under paragraph (2) whenever the source is operating, except during the times specified in subsection (m)(8)(iii).

(e)Compliance requirements for a flare. The owner or operator of a control device subject to this section that installs a flare designed and operated in accordance with 40 CFR 60.18(b) (relating to general control device and work practice requirements) shall meet subsection (b)(3)- (7).

(f)Compliance requirements for a carbon adsorption system. The owner or operator of a control device subject to this section that installs a carbon adsorption system shall meet subsection (b)(1) and (2) and the following:

(1) Design and operate the carbon adsorption system to reduce the mass content of VOC in the gases vented to the device as demonstrated by one of the following:

(i) Determining the VOC emission reduction is 95.0% by weight or greater as specified in subsection (k).

(ii) Reducing the concentration of TOC in the exhaust gases at the outlet to the device to a level less than or equal to 275 ppmvd as propane corrected to 3% oxygen as determined under subsection (l).

(iii) Conducting a design analysis in accordance with subsection (g)(6) or subsection (h)(2) as applicable.

(2) Include a carbon replacement schedule in the design of the carbon adsorption system.

(3) Replace the carbon in the control device with fresh carbon on a regular schedule that is no longer than the carbon service life established according to the design analysis in subsection (g)(6) or subsection (h)(2) or according to the replacement schedule in paragraph (2).

(4) Manage the spent carbon removed from the carbon adsorption system in paragraph (3) by one of the following:

(i) Regenerating or reactivating the spent carbon in one of the following:

(A) A thermal treatment unit for which the owner or operator has been issued a permit under 40 CFR Part 270 (relating to EPA administered permit programs: the hazardous waste permit program) that implements the requirements of 40 CFR Part 264, Subpart X (relating to miscellaneous units).

(B) A unit equipped with operating organic air emission controls in accordance with an emissions standard for VOC under a subpart in 40 CFR Part 60 (relating to standards of performance for new stationary sources) or 40 CFR Part 63 (relating to National emission standards for hazardous air pollutants for source categories).

(ii) Burning the spent carbon in one of the following:

(A) A hazardous waste incinerator, boiler or industrial furnace for which the owner or operator complies with the requirements of 40 CFR Part 63, Subpart EEE (relating to National emission standards for hazardous air pollutants from hazardous waste combustors) and has submitted a Notification of Compliance under 40 CFR 63.1207(j) (relating to what are the performance testing requirements?).

(B) An industrial furnace for which the owner or operator has been issued a permit under 40 CFR Part 270 that implements the requirements of 40 CFR Part 266 , Subpart H (relating to hazardous waste burned in boilers and industrial furnaces).

(C) An industrial furnace designed and operated in accordance with the interim status requirements of 40 CFR Part 266, Subpart H.

(g)Additional compliance requirements for a regenerative carbon adsorption system. The owner or operator of a control device subject to this section that installs a regenerative carbon adsorption system shall meet subsection (f) and the following:

(1) Install, calibrate, operate and maintain a CPMS according to the manufacturer's specifications and the applicable requirements of subsection (m) to measure the values of the operating parameters appropriate to the control device as follows:

(i) For a source complying with subsection (f)(1)(i), a flow CPMS system that meets the requirements of subsection (m)(1) and (2)(ii) to measure and record the average total regeneration steam mass flow or volumetric flow during each carbon bed regeneration cycle. The owner or operator shall inspect the following:

(A) The mechanical connections for leakage with monthly inspections separated by at least 15 calendar days but not more than 45 calendar days.

(B) The components of the flow CPMS for physical and operational integrity if the flow CPMS is not equipped with a redundant flow sensor with quarterly inspections separated by at least 60 calendar days but not more than 120 calendar days.

(C) The electrical connections of the flow CPMS for oxidation and galvanic corrosion if the flow CPMS is not equipped with a redundant flow sensor with quarterly inspections separated by at least 60 calendar days but not more than 120 calendar days.

(ii) For a source complying with subsection (f)(1)(i), a temperature CPMS that meets the requirements of subsection (m)(1) and (4) to measure and record the average carbon bed temperature for the duration of the carbon bed steaming cycle and measure the actual carbon bed temperature after regeneration and within 15 minutes of completing the cooling cycle.

(iii) For a source complying with subsection (f)(1)(ii), an organic concentration CPMS that meets subsection (m)(1) and (5) that measures the concentration level of organic compounds in the exhaust vent stream from the control device.

(2) Operate the control device in compliance with the operating parameter value established under subsection (m)(6).

(3) Calculate the daily average of the applicable monitored operating parameter for each operating day, using the valid data recorded by the CPMS as specified in subsection (m)(7).

(4) Ensure that the daily average of the monitoring parameter value calculated under paragraph (3) complies with the parameter value established under paragraph (2) as specified in subsection (m)(9).

(5) Operate the CPMS installed in paragraph (1) whenever the source is operating, except during the times specified in subsection (m)(8)(iii).

(6) Ensure that the design analysis to meet subsection (f)(1)(iii) and (2) for the regenerable carbon adsorption system meets the following:

(i) Includes an analysis of the vent stream, including the following information:

(A) Composition.

(B) Constituent concentrations.

(C) Flowrate.

(D) Relative humidity.

(E) Temperature.

(ii) Establishes the following parameters for the regenerable carbon adsorption system:

(A) Design exhaust vent stream organic compound concentration level.

(B) Adsorption cycle time.

(C) Number and capacity of carbon beds.

(D) Type and working capacity of activated carbon used for the carbon beds.

(E) Design total regeneration stream flow over the period of each complete carbon bed regeneration cycle.

(F) Design carbon bed temperature after regeneration.

(G) Design carbon bed regeneration time.

(H) Design service life of the carbon.

(h)Additional compliance requirements for a non-regenerative carbon adsorption system. The owner or operator of a control device subject to this section that installs a non-regenerative carbon adsorption system shall meet subsection (f) and the following:

(1) Monitor the design carbon replacement interval established in subsection (f)(2) or paragraph (2). The design carbon replacement interval must be based on the total carbon working capacity of the control device and the source operating schedule.

(2) Ensure that the design analysis to meet subsection (f)(1)(iii) and (2) for a non-regenerable carbon adsorption system, such as a carbon canister, meets the following:

(i) Includes an analysis of the vent stream including the following information:

(A) Composition.

(B) Constituent concentrations.

(C) Flowrate.

(D) Relative humidity.

(E) Temperature.

(ii) Establishes the following parameters for the non-regenerable carbon adsorption system:

(A) Design exhaust vent stream organic compound concentration level.

(B) Capacity of the carbon bed.

(C) Type and working capacity of activated carbon used for the carbon bed.

(D) Design carbon replacement interval based on the total carbon working capacity of the control device and the source operating schedule.

(iii) Incorporates dual carbon canisters in case of emission breakthrough occurring in one canister.

(i)Compliance requirements for a condenser or nondestructive control device. The owner or operator of a control device subject to this section that installs a condenser or other non-destructive control device shall meet subsection (b)(1) and (2) and the following:

(1) Design and operate the condenser or other nondestructive control device to reduce the mass content of VOC in the gases vented to the device as demonstrated by one of the following:

(i) Determining the VOC emissions reduction is 95.0% by weight or greater under subsection (k).

(iii) Conducting a design analysis in accordance with paragraph (7).

(2) Prepare a site-specific monitoring plan that addresses the following CPMS design, data collection, and quality assurance and quality control elements:

(i) The performance criteria and design specifications for the CPMS equipment, including the following:

(A) The location of the sampling interface that allows the CPMS to provide representative measurements. For a temperature CPMS that meets the requirements of subsection (m)(1) and (4) the sensor must be installed in the exhaust vent stream as detailed in the procedures of the site-specific monitoring plan.

(B) Equipment performance checks, system accuracy audits or other audit procedures.

(I) Performance evaluations of each CPMS shall be conducted in accordance with the site-specific monitoring plan.

(II) CPMS performance checks, system accuracy audits or other audit procedures specified in the site-specific monitoring plan shall be conducted at least once every 12 months.

(ii) Ongoing operation and maintenance procedures in accordance with 40 CFR 60.13(b) (relating to monitoring requirements).

(iii) Ongoing reporting and recordkeeping procedures in accordance with 40 CFR 60.7(c), (d) and (f) (relating to notification and record keeping).

(3) Install, calibrate, operate and maintain a CPMS according to the site-specific monitoring plan described in paragraph (2) and the applicable requirements of subsection (m) to measure the values of the operating parameters appropriate to the control device as follows:

(i) For a source complying with paragraph (1)(i), a temperature CPMS that meets subsection (m)(1) and (4) to measure and record the average condenser outlet temperature.

(ii) For a source complying with paragraph (1)(ii), an organic concentration CPMS that meets subsection (m)(1) and (5) that measures the concentration level of organic compounds in the exhaust vent stream from the control device.

(4) Operate the control device in compliance with the operating parameter value established under subsection (m)(6).

(5) Calculate the daily average of the applicable monitored operating parameter for each operating day, using the valid data recorded by the CPMS as follows:

(i) For a source complying with paragraph (1)(i), use the calculated daily average condenser outlet temperature as specified in subsection (m)(7) and the condenser performance curve established under subsection (m)(6)(iii) to determine the condenser efficiency for the current operating day. Calculate the 365-day rolling average TOC emission reduction, as appropriate, from the condenser efficiencies as follows:

(A) If there is less than 120 days of data for determining average TOC emission reduction, calculate the average TOC emission reduction for the first 120 days of operation. Compliance is demonstrated with paragraph (1)(i) if the 120-day average TOC emission reduction is equal to or greater than 95.0% by weight.

(B) After 120 days and no more than 364 days of operation, calculate the average TOC emission reduction as the TOC emission reduction averaged over the number of days of operation for which there is data. Compliance is demonstrated with paragraph (1)(i) if the average TOC emission reduction is equal to or greater than 95.0% by weight.

(C) If there is data for 365 days or more of operation, compliance is demonstrated with the TOC emission reduction if the rolling 365-day average TOC emission reduction calculated in subparagraph (i) is equal to or greater than 95.0% by weight.

(ii) For a source complying with paragraph (1)(ii), calculate the daily average concentration for each operating day, using the data recorded by the CPMS as specified in subsection (m)(7). Compliance is demonstrated with paragraph (1)(ii) if the daily average concentration is less than the operating parameter under paragraph (4) as specified in subsection (m)(9).

(6) Operate the CPMS installed in accordance with paragraph (3) whenever the source is operating, except during the times specified in subsection (m)(8)(iii).

(7) Ensure that the design analysis to meet paragraph (1)(iii) for a condenser or other non-destructive control device meets the following:

(i) Includes an analysis of the vent stream including the following information:

(A) Composition.

(B) Constituent concentrations.

(C) Flowrate.

(D) Relative humidity.

(E) Temperature.

(ii) Establishes the following parameters for the condenser or other non-destructive control device:

(A) Design outlet organic compound concentration level.

(B) Design average temperature of the condenser exhaust vent stream.

(C) Design average temperatures of the coolant fluid at the condenser inlet and outlet.

(j)General performance test requirements. The owner or operator shall meet the following performance test requirements:

(1) The owner or operator shall do the following, as applicable:

(i) Except as specified in subparagraph (iii), conduct an initial performance test within 180 days after installation of a control device.

(ii) Except as specified in subparagraph (iii), conduct a performance test of an existing control device on or before July 30, 2023, unless the owner or operator of the control device is complying with an established performance test interval, in which case the current schedule should be maintained.

(iii) The performance test in subparagraph (i) or subparagraph (ii) is not required if the owner or operator meets one or more of the following:

(A) Installs a manufacturer-tested combustion device that meets the requirements of subsection (c).

(B) Installs a flare that meets the requirements of subsection (e).

(C) Installs a boiler or process heater with a design heat input capacity of 44 megawatts (150 MMBtu per hour) or greater.

(D) Installs a boiler or process heater which introduces the vent stream with the primary fuel or uses the vent stream as the primary fuel.

(E) Installs a boiler or process heater which burns hazardous waste that meets one or more of the following:

(I) For which an operating permit was issued under 40 CFR Part 270 (relating to EPA administered permit programs: the hazardous waste permit program) and complies with the requirements of 40 CFR Part 266 , Subpart H.

(II) For which compliance with the interim status requirements of 40 CFR Part 266 , Subpart H has been certified.

(III) Which complies with 40 CFR Part 63 , Subpart EEE and for which a Notification of Compliance under 40 CFR 63.1207(j) was submitted to the Department.

(IV) Which complies with 40 CFR Part 63 , Subpart EEE and for which a Notification of Compliance under 40 CFR 63.1207(j) will be submitted to the Department within 90 days of the completion of the initial performance test report unless a written request for an extension is submitted to the Department.

(F) Installs a hazardous waste incinerator which meets the requirements of 40 CFR Part 63 , Subpart EEE and for which the Notification of Compliance under 40 CFR 63.1207(j):

(I) Was submitted to the Department.

(II) Will be submitted to the Department within 90 days of the completion of the initial performance test report unless a written request for an extension is submitted to the Department.

(G) Requests the performance test be waived under 40 CFR 60.8(b) (relating to performance tests).

(2) Conduct a periodic performance test no more than 60 months after the most recent performance test unless the owner or operator:

(i) Monitors the inlet gas flow for a manufacturer-tested combustion device under subsection (c)(1)(i).

(ii) Installs a control device exempt from testing requirements under paragraph (1)(iii)(A)- (G).

(iii) Establishes a correlation between firebox or combustion chamber temperature and the VOC performance level for an enclosed combustion device under subsection (d)(2)(iii).

(3) Conduct a performance test when establishing a new operating limit.

(k)Performance test method for demonstrating compliance with a control device weight-percent VOC emission reduction requirement. Demonstrate compliance with the control device weight-percent VOC emission reduction requirements of subsections (c)(1)(ii), (d)(1)(i), (f)(1)(i) and (i)(1)(i) by meeting subsection (j) and the following:

(1) Conducting a minimum of three test runs of at least 1-hour duration.

(2) Using EPA Method 1 or EPA Method 1A, as appropriate, to select the sampling sites which must be located at the inlet of the first control device and at the outlet of the final control device. References to particulate mentioned in EPA Method 1 or EPA Method 1A do not apply to this paragraph.

(3) Using EPA Method 2, EPA Method 2A, EPA Method 2C or EPA Method 2D, as appropriate, to determine the gas volumetric flowrate.

(4) Using EPA Method 25A to determine compliance with the control device percent VOC emission reduction performance requirement using the following procedure:

(i) Convert the EPA Method 25A results to a dry basis, using EPA Method 4.

(ii) Compute the mass rate of TOC using the following equations:

Click to view image

Where:

E_i = Mass rate of TOC at the inlet of the control device on a dry basis, in kilograms per hour (pounds per hour).

E_o = Mass rate of TOC at the outlet of the control device on a dry basis, in kilograms per hour (pounds per hour).

K₂ = Constant, 2.494 * 10^-6 (ppm) (mole per standard cubic meter) (kilogram per gram) (minute per hour) where standard temperature (mole per standard cubic meter) is 20 °Celsius

K₂ = Constant, 1.554 * 10^-7 (ppm) (lb-mole per standard cubic feet) (minute per hour), where standard temperature (lb-mole per standard cubic feet) is 68 °Fahrenheit.

C_i = Concentration of TOC, as propane, of the gas stream as measured by EPA Method 25A at the inlet of the control device, ppmvd.

C_o = Concentration of TOC, as propane, of the gas stream as measured by EPA Method 25A at the outlet of the control device, ppmvd.

M_p = Molecular weight of propane, 44.1 gram per mole (pounds per lb-mole).

Q_i = Flowrate of gas stream at the inlet of the control device in dry standard cubic meter per minute (dry standard cubic feet per minute).

Q_o = Flowrate of gas stream at the outlet of the control device in dry standard cubic meter per minute (dry standard cubic feet per minute).

(iii) Calculate the percent reduction in TOC as follows:

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Where:

R_cd = Control efficiency of control device, percent.

E_i = Mass rate of TOC at the inlet to the control device as calculated in subparagraph (ii), kilograms per hour (pounds per hour).

E_o = Mass rate of TOC at the outlet of the control device as calculated in subparagraph (ii), kilograms per hour (pounds per hour).

(iv) If the vent stream entering a boiler or process heater with a performance testing requirement is introduced with the combustion air or as a secondary fuel, the owner or operator shall:

(A) Calculate E_i in subparagraph (ii) by using the TOC concentration in all combusted vent streams, primary fuels and secondary fuels as C_i.

(B) Calculate E_o in subparagraph (ii) by using the TOC concentration exiting the device as C_o.

(C) Determine the weight-percent reduction of TOC across the device in accordance with subparagraph (iii).

(5) The weight-percent reduction of TOC across the control device represents the VOC weight-percent reduction for demonstration of compliance with subsections (c)(1)(ii), (d)(1)(i), (f)(1)(i) and (i)(1)(i).

(l)Performance test method for demonstrating compliance with an outlet concentration requirement. Demonstrate compliance with the TOC concentration requirement of subsections (d)(1)(ii), (f)(1)(ii) and (i)(1)(ii) by meeting subsection (j) and the following:

(1) Conducting a minimum of three test runs of at least 1-hour duration.

(2) Using EPA Method 1 or EPA Method 1A, as appropriate, to select the sampling sites which must be located at the outlet of the control device. References to particulate mentioned in EPA Method 1 or EPA Method 1A do not apply to this paragraph.

(3) Using EPA Method 2, EPA Method 2A, EPA Method 2C, or EPA Method 2D, as appropriate, to determine the gas volumetric flowrate.

(4) Using EPA Method 25A to determine compliance with the TOC concentration requirement using the following procedures:

(i) Measure the TOC concentration, as propane.

(ii) For a control device subject to subsection (f) or subsection (i), the results of EPA Method 25A in subparagraph (i) may be adjusted by subtracting the concentration of methane and ethane measured using EPA Method 18 taking either:

(A) An integrated sample.

(B) A minimum of four grab samples per hour using the following procedures:

(I) Taking the samples at approximately equal intervals in time, such as 15-minute intervals during the run.

(II) Taking the samples during the same time as the EPA Method 25A sample.

(III) Determining the average methane and ethane concentration per run.

(iii) The TOC concentration must be adjusted to a dry basis, using EPA Method 4.

(iv) The TOC concentration must be corrected to 3% oxygen as follows:

(A) The oxygen concentration must be determined using the emission rate correction factor for excess air, integrated sampling and analysis procedures from one of the following methods:

(I) EPA Method 3A.

(II) EPA Method 3B.

(III) ASTM D6522-00.

(IV) ANSI/ASME PTC 19.10-1981, Part 10.

(B) The samples for clause (A) must be taken during the same time that the samples are taken for determining the TOC concentration.

(C) The TOC concentration for percent oxygen must be corrected as follows:

Click to view image

Where:

C_c = TOC concentration, as propane, corrected to 3% oxygen, ppmvd.

C_m = TOC concentration, as propane, ppmvd.

%O_2m = Concentration of oxygen, percent by volume as measured, dry.

(m)Continuous parameter monitoring system requirements. The owner or operator of a source subject to § 129.131(a) (relating to general provisions and applicability) and controlled by a device listed in subsections (c)-(i) that is required to install a CPMS shall:

(1) Ensure the CPMS measures the applicable parameter at least once every hour and continuously records either:

(i) The measured operating parameter value.

(ii) The block average operating parameter value for each 1-hour period calculated using the following procedures:

(A) The block average from all measured data values during each period.

(B) If values are measured more frequently than once per minute, a single value for each minute may be used instead of all measured values.

(2) Ensure the flow CPMS has either:

(i) An accuracy of ±2% or better at the maximum expected flow rate.

(ii) A measurement sensitivity of 5% of the flow rate or 10 standard cubic feet per minute, whichever is greater.

(3) Ensure the heat-sensing CPMS indicates the presence of the pilot flame while emissions are routed to the control device. Heat-sensing CPMS are exempt from the calibration, quality assurance and quality control requirements in this section.

(4) Ensure the temperature CPMS has a minimum accuracy of ±1% of the temperature being monitored in °Celsius (±1.8% in °Fahrenheit) or ±2.5 °Celsius (±4.5 °Fahrenheit), whichever value is greater.

(5) Ensure the organic concentration CPMS meets the requirements of Performance Specification 8 or 9 of 40 CFR Part 60 , Appendix B (relating to performance specifications).

(6) Establish the operating parameter value to define the conditions at which the control device must be operated to continuously achieve the applicable performance requirement as follows:

(i) For a parameter value established while conducting a performance test under subsection (k) or subsection (l):

(A) Base each minimum operating parameter value on the value established while conducting the performance test and supplemented, as necessary, by the design analysis of subsection (g)(6), subsection (h)(2) or subsection (i)(7), the manufacturer's recommendations, or both.

(B) Base each maximum operating parameter value on the value established while conducting the performance test and supplemented, as necessary, by the design analysis of subsection (g)(6), subsection (h)(2) or subsection (i)(7), the manufacturer's recommendations, or both.

(ii) Except as specified in clause (C), for a parameter value established using a design analysis in subsection (g)(6), subsection (h)(2) or subsection (i)(7):

(A) Base each minimum operating parameter value on the value established in the design analysis and supplemented, as necessary, by the manufacturer's recommendations.

(B) Base each maximum operating parameter value on the value established in the design analysis and supplemented, as necessary, by the manufacturer's recommendations.

(C) If the owner or operator and the Department do not agree on a demonstration of control device performance using a design analysis as specified in clause (A) or (B), then the owner or operator shall perform a performance test under subsection (k) or subsection (l) to resolve the disagreement. The Department may choose to have an authorized representative observe the performance test.

(iii) For a condenser, establish a condenser performance curve showing the relationship between condenser outlet temperature and condenser control efficiency that demonstrates the condenser complies with the applicable performance requirements in subsection (i)(1) as follows:

(A) Based on the value measured while conducting a performance test under subsection (k) or subsection (l) and supplemented, as necessary, by a condenser design analysis performed under subsection (i)(7), the manufacturer's recommendations, or both.

(B) Based on the value from a condenser design analysis performed under subsection (i)(7) supplemented, as necessary, by the manufacturer's recommendations.

(7) Except for the CPMS in paragraphs (2) and (3), calculate the daily average for each monitored parameter for each operating day using the data recorded by the CPMS. Valid data points must be available for 75% of the operating hours in an operating day to compute the daily average where the operating day is:

(i) A 24-hour period if the control device operation is continuous.

(ii) The total number of hours of control device operation per 24-hour period.

(8) Except as specified in subparagraph (iii), do both of the following:

(i) Ensure the data recorded by the CPMS is used to assess the operation of the control device and associated control system.

(ii) Report the failure to collect the required data in paragraph (1) as a deviation of the monitoring requirements.

(iii) The requirements of subparagraphs (i) and (ii) do not apply during:

(A) A monitoring system malfunction.

(B) A repair associated with a monitoring system malfunction.

(C) A required monitoring system quality assurance or quality control activity.

(9) Determine compliance with the established parameter value by comparing the calculated daily average to the established operating parameter value as follows:

(i) For a minimum operating parameter established in paragraph (6)(i)(A) or paragraph (6)(ii)(A), the control device is in compliance if the calculated value is equal to or greater than the established value.

(ii) For a maximum operating parameter established in paragraph (6)(i)(B) or paragraph (6)(ii)(B), the control device is in compliance if the calculated value is less than or equal to the established value.

25 Pa. Code § 129.139

The provisions of this §129.139 added December 9, 2022, effective 12/2/2022, 52 Pa.B. 7635.

The provisions of this §129.139 added under section 5(a)(1) and (8) of the Air Pollution Act (35 P.S. § 4005(a)(1) and (8)).

This section cited in 25 Pa. Code § 129.131 (relating to general provisions and applicability); 25 Pa. Code § 129.132 (relating to definitions, acronyms and EPA methods); 25 Pa. Code § 129.133 (relating to storage vessels); 25 Pa. Code § 129.135 (relating to natural gas-driven diaphragm pumps); 25 Pa. Code § 129.136 (relating to compressors); 25 Pa. Code § 129.137 (relating to fugitive emissions components); 25 Pa. Code § 129.138 (relating to covers and closed vent systems); and 25 Pa. Code § 129.140 (relating to recordkeeping and reporting).