Aquatic Life Value Classes I, IA, II, III | Human Health Value | ||||
CAS No. | Pollutant (Compounds) | Acute | Chronic | Classes I, IA, II2 | Class III3 |
71-55-6 | 1,1,1-Trichloroethane | 10,0007 | 200,000 | ||
79-00-5 | 1,1,2-Trichloroethane4 | 0.55 | 8.9 | ||
79-34-5 | 1,1,2,2-Tetrachloroethane4 | 0.2 | 3 | ||
75-35-4 | 1,1-Dichloroethylene4 | 300 | 20,000 | ||
156-60-5 | 1,2-trans-Dichloroethylene7 | 100 | 4,000 | ||
120-82-1 | 1,2,4-Trichlorobenzene | 0.071 | 0.076 | ||
95-50-1 | 1,2-Dichlorobenzene7 | 1,000 | 3,000 | ||
541-73-1 | 1,3-Dichlorobenzene | 7 | 10 | ||
106-46-7 | 1,4-Dichlorobenzene7 | 300 | 900 | ||
107-06-2 | 1,2-Dichloroethane4 | 9.9 | 650 | ||
78-87-5 | 1,2-Dichloropropane | 0.90 | 31 | ||
542-75-6 | 1,3-Dichloropropylene (1,3-Dichloropropene) (cis and trans isomers) | 0.27 | 12 | ||
122-66-7 | 1,2-Diphenylhydrazine4 | 0.03 | 0.20 | ||
121-14-2 | 2,4-Dinitrotoluene4 | 0.049 | 1.7 | ||
95-57-8 | 2-Chlorophenol | 30 | 800 | ||
120-83-2 | 2,4-Dichlorophenol | 10 | 60 | ||
88-06-2 | 2,4,6-Trichlorophenol4 | 1.5 | 2.8 | ||
91-58-7 | 2-Chloronaphthalene | 800 | 1,000 | ||
91-94-1 | 3,3'-Dichlorobenzidine4 | 0.049 | 0.15 | ||
105-67-9 | 2,4-Dimethylphenol | 100 | 3,000 | ||
51-28-5 | 2,4-Dinitrophenol | 10 | 300 | ||
94-75-7 | 2,4-D | 1,300 | 12,000 | ||
72-54-8 | 4,4'-DDD4 | 0.00012 | 0.00012 | ||
75-55-9 | 4,4'-DDE4 | 0.000018 | 0.000018 | ||
50-29-3 | 4,4'-DDT4 | 0.5512 | 0.00112 | 0.000030 | 0.000030 |
534-52-1 | 2-Methyl-4,6-Dinitrophenol | 2 | 30 | ||
59-50-7 | 3-Methyl-4-Chlorophenol | 500 | 2,000 | ||
83-32-9 | Acenaphthene | 70 | 90 | ||
107-02-8 | Acrolein | 3 | 3 | 3 | 400 |
107-13-1 | Acrylonitrile4 | 0.061 | 7.0 | ||
15972-60-8 | Alachlor | 27 | |||
309-00-2 | Aldrin4 | 1.5 | 7.7E-07 | 7.7E-07 | |
319-84-6 | alpha-BHC4 (Hexachlorocyclohexane-alpha) | 0.00036 | 0.00039 | ||
319-85-7 | beta-BHC4 (Hexachlorocyclohexane-beta) | 0.008 | 0.014 | ||
58-89-9 | gamma-BHC (Lindane)4 (Hexachlorocyclohexane-gamma) | 0.95 | 4.27 | 4.4 | |
959-98-8 | alpha-Endosulfan | 0.1111 | 0.05611 | 20 | 30 |
33213-65-9 | beta-Endosulfan | 0.1111 | 0.05611 | 20 | 40 |
120-12-7 | Anthracene (PAH)5 | 300 | 400 | ||
1332-21-4 | Asbestos4,7 | 7,000,000 f/l | 7,000,000 f/l | ||
1912-24-9 | Atrazine | 37 | |||
71-43-2 | Benzene4 | 2.1 | 58 | ||
92-87-5 | Benzidine4 | 0.00014 | 0.011 | ||
56-55-3 | Benzo(a)anthracene (PAH)4 (1,2-Benzanthracene) | 0.0012 | 0.0013 | ||
50-32-8 | Benzo(a)pyrene (PAH)4 (3,4-Benzopyrene) | 0.00012 | 0.00013 | ||
205-99-2 | Benzo(b)fluoranthene (PAH)4 (3,4-Benzofluoranthene) | 0.0012 | 0.0013 | ||
207-08-9 | Benzo(k)fluoranthene (PAH)4 (11,12-Benzofluoranthene) | 0.012 | 0.013 | ||
12587-47-2 | Beta/photon emitters | 4 mrem/yr7 | |||
111-44-4 | Bis(2-chloroethyl) ether4 | 0.030 | 2.2 | ||
108-60-1 | Bis(2-chloro-1-Methylethyl) ether | 200 | 4,000 | ||
117-81-7 | Bis(2-ethylhexyl) phthalate4 | 0.32 | 0.37 | ||
15541-45-4 | Bromate | 107 | |||
75-25-2 | Bromoform (HM)5 (Tribromomethane) | 7.0 | 120 | ||
85-68-7 | Butyl benzyl phthalate | 0.10 | 0.10 | ||
63-25-2 | Carbaryl (1-naphthyl-N-methycarbamate) | 2.1 | 2.1 | ||
1563-66-2 | Carbofuran | 407 | |||
56-23-5 | Carbon tetrachloride4 (Tetrachloromethane) | 0.40 | 5 | ||
57-74-9 | Chlordane4 | 1.2 | 0.0043 | 0.00031 | 0.00032 |
14998-27-7 | Chlorite | 1,0007 | |||
108-90-7 | Chlorobenzene (Monochlorobenzene) | 1007 | 800 | ||
124-48-1 | Chlorodibromomethane (HM)5 | 0.80 | 21 | ||
67-66-3 | Chloroform (HM)4 (Trichloromethane) | 60 | 2,000 | ||
2921-88-2 | Chlorpyrifos | 0.083 | 0.041 | ||
218-01-9 | Chrysene (PAH)4 | 0.12 | 0.13 | ||
57-12-5 | Cyanide (total) | 22 | 5.2 | 4 | 400 |
75-99-0 | Dalapon | 2007 | |||
103-23-1 | Di(2-ethylhexyl)adipate | 4007 | |||
333-41-5 | Diazinon | 0.17 | 0.17 | ||
53-70-3 | Dibenzo(a,h)anthracene (PAH)4 (1,2,5,6-Dibenzanthracene) | 0.00012 | 0.00013 | ||
67708-83-2 | Dibromochloropropane | 0.27 | |||
75-27-4 | Dichlorobromomethane (HM)5 | 0.95 | 27 | ||
156-59-2 | Dichloroethylene (cis-1,2-) | 707 | |||
60-57-1 | Dieldrin4 | 0.24 | 0.056 | 1.2E-06 | 1.2E-06 |
84-66-2 | Diethyl phthalate | 600 | 600 | ||
131-11-3 | Dimethyl phthalate | 2,000 | 2,000 | ||
84-74-2 | Di-n-butyl phthalate | 20 | 30 | ||
88-85-7 | Dinoseb | 77 | |||
1746-01-6 | Dioxin (2,3,7,8-TCDD)4 | 5.00E-09 | 5.10E-09 | ||
85-00-7 | Diquat | 207 | |||
1031-07-8 | Endosulfan sulfate | 20 | 40 | ||
145-73-3 | Endothall | 1007 | |||
72-20-8 | Endrin | 0.086 | 0.036 | 0.03 | 0.03 |
7421-93-4 | Endrin aldehyde | 1 | 1 | ||
100-41-4 | Ethylbenzene7 | 68 | 130 | ||
106-93-4 | Ethylene dibromide (EDB) | 0.057 | |||
206-44-0 | Fluoranthene | 20 | 20 | ||
86-73-7 | Fluorene (PAH)5 | 50 | 70 | ||
1071-83-6 | Glyphosate | 7007 | |||
Halocetic acids14 | 607 | ||||
1024-57-3 | Heptachlor epoxide4 | 0.26 | 0.0038 | 0.000032 | 0.000032 |
76-44-8 | Heptachlor4 | 0.26 | 0.0038 | 0.0000059 | 0.0000059 |
118-74-1 | Hexachlorobenzene4 | 0.000079 | 0.000079 | ||
87-68-3 | Hexachlorobutadiene4 | 0.01 | 0.01 | ||
77-47-4 | Hexachlorocyclopentadiene | 4 | 4 | ||
67-72-1 | Hexachloroethane4 | 0.10 | 0.10 | ||
193-39-5 | Indeno(1,2,3-cd) pyrene (PAH)4 | 0.0012 | 0.0013 | ||
78-59-1 | Isophorone4 | 34 | 1,800 | ||
72-43-5 | Methoxychlor | 0.02 | 0.02 | ||
74-83-9 | Methyl bromide (HM) (Bromomethane) | 100 | 10,000 | ||
75-09-2 | Methylene chloride (HM)4 (Dichloromethane) | 20 | 1,000 | ||
98-95-3 | Nitrobenzene | 10 | 600 | ||
62-75-9 | N-Nitrosodimethylamine4 | 0.00069 | 3 | ||
621-64-7 | N-Nitrosodi-n-propylamine4 | 0.005 | 0.51 | ||
86-30-6 | N-Nitrosodiphenylamine4 | 3.3 | 6 | ||
84852-15-3 | Nonylphenol (Isomer mixture)13 | 28 | 6.6 | ||
23135-22-0 | Oxamyl (Vydate) | 2007 | |||
56-38-2 | Parathion | 0.065 | 0.013 | ||
53469-21-9 | PCB-1242 (Arochlor 1242)4 | 0.01410 | 0.00006410 | 0.00006410 | |
126764-11-2 | PCB-1016 (Arochlor 1016)4 | 0.01410 | 0.00006410 | 0.00006410 | |
11104-28-2 | PCB-1221 (Arochlor 1221)4 | 0.01410 | 0.00006410 | 0.00006410 | |
11141-16-5 | PCB-1232 (Arochlor 1232)4 | 0.01410 | 0.00006410 | 0.00006410 | |
12672-29-6 | PCB-1248 (Arochlor 1248)4 | 0.01410 | 0.00006410 | 0.00006410 | |
11097-69-1 | PCB-1254 (Arochlor 1254)4 | 0.01410 | 0.00006410 | 0.00006410 | |
11096-82-5 | PCB-1260 (Arochlor 1260)4 | 0.01410 | 0.00006410 | 0.00006410 | |
87-86-5 | Pentachlorophenol | 198 | 158 | 0.03 | 0.04 |
108-95-2 | Phenol | 4,000 | 300,000 | ||
1918-02-1 | Picloram | 5007 | |||
129-00-0 | Pyrene (PAH)5 | 20 | 30 | ||
122-34-9 | Simazine | 47 | |||
100-42-5 | Styrene | 1007 | |||
127-18-4 | Tetrachloroethylene4 | 10 | 29 | ||
108-88-3 | Toluene | 57 | 520 | ||
8001-35-2 | Toxaphene4 | 0.73 | 0.0002 | 0.0007 | 0.00071 |
688-73-3 | Tributyltin | 0.46 | 0.072 | ||
79-01-6 | Trichloroethylene4 | 0.60 | 7 | ||
75-01-4 | Vinyl chloride4 (Cloroethylene) | 0.022 | 1.6 | ||
1330-20-7 | Xylenes | 10,0007 | |||
Aquatic Life Value Classes I, IA, II, III | Human Health Value | ||||
CAS No. | Pollutant (Elements) | Acute | Chronic | Classes I, IA, II2 | Class III3 |
7440-36-0 | Antimony | 5.6 | 640 | ||
7440-38-2 | Arsenic7 | 3409 | 1509 | 107 | |
7440-41-7 | Beryllium4 | 47 | |||
7440-43-9 | Cadmium | 7.386,15 | 2.396,15 | 57 | |
16065-83-1 | Chromium (III) | 5,611.706,15 | 268.226,15 | 100(total)7 | |
18540-29-9 | Chromium (VI) | 16 | 11 | 100(total)7 | |
7440-50-8 | Copper | 51.686,15,16 | 30.506,15,16 | 1000 | |
7782-41-4 | Fluoride | 4,0007 | |||
7439-92-1 | Lead | 476.826 | 18.586 | 157 | |
7439-97-6 | Mercury | 1.7 | 0.012 | 0.050 | 0.051 |
7440-02-0 | Nickel | 1,516.926,15 | 168.546,15 | 1007 | 4,200 |
7782-49-2 | Selenium | 20 | 5 | 507 | |
7440-22-4 | Silver | 41.076,15 | |||
7440-28-0 | Thallium | 0.24 | 0.47 | ||
7440-61-1 | Uranium | 307 | |||
7440-66-6 | Zinc | 387.836,15 | 387.826,15 | 7,400 | 26,000 |
1 Except for the aquatic life values for metals, the values given in this appendix refer to the total (dissolved plus suspended) amount of each substance unless otherwise noted. For the aquatic life values for metals, the values refer to the total recoverable method for ambient metals analyses.
2 Based on two routes of exposure - ingestion of contaminated aquatic organisms and drinking water.
3 Based on one route of exposure - ingestion of contaminated aquatic organisms only.
4 Substance classified as a carcinogen, with the value based on an incremental risk of one additional instance of cancer in one million persons.
5 Chemicals which are not individually classified as carcinogens but which are contained within a class of chemicals, with carcinogenicity as the basis for the criteria derivation for that class of chemicals; an individual carcinogenicity assessment for these chemicals is pending.
6 Hardness dependent criteria. Value given is an example based on a CaCO3 hardness of 400 mg/l. Criteria for each case must be calculated using the following formula:
For the Criterion Maximum Concentration (CMC):
Cadmium | CMC = e0.9789[ln (hardness)]-3.866 |
Chromium (III) | CMC = e0.8190[ln (hardness)] + 3.7256 |
Copper | CMC = e0.9422[ln (hardness)] - 1.7000 |
Lead | CMC = e1.2730[ln (hardness)] - 1.4600 |
Nickel | CMC = e0.8460[ln (hardness)] + 2.2550 |
Silver | CMC = e1.7200[ln (hardness)] - 6.5900 |
Zinc | CMC = e0.8473[ln (hardness)] + 0.8840 |
CMC = Criterion Maximum Concentration (acute exposure value)
The threshold value at or below which there should be no unacceptable effects to freshwater aquatic organisms and their uses if the one-hour concentration does not exceed that CMC value more than once every three years on the average.
For the Criterion Continuous Concentration (CCC):
Cadmium | CCC = e0.7977[ln (hardness)]-3.909 |
Chromium (III) | CCC = e0.8190[ln (hardness)] + 0.6848 |
Copper | CCC = e0.8545[ln (hardness)] - 1.7020 |
Lead | CCC = e1.2730[ln (hardness)] - 4.7050 |
Nickel | CCC = e0.8460[ln (hardness)] + 0.0584 |
Silver | No CCC criterion for silver |
Zinc | CCC = e0.8473[ln (hardness)] + 0.8840 |
CCC = Criterion Continuous Concentration (chronic exposure value)
The threshold value at or below which there should be no unacceptable effects to freshwater aquatic organisms and their uses if the four-day concentration does not exceed that CCC value more than once every three years on the average.
7 Safe Drinking Water Act (MCL).
8 Freshwater aquatic life criteria for pentachlorophenol are expressed as a function of pH. Values displayed in the table correspond to a pH of 7.8 and are calculated as follows:
CMC =exp [1.005 (pH) - 4.869] | CCC = exp [1.005 (pH) - 5.134] |
9 This criterion applies to total arsenic.
10 This criterion applies to total PCBs (i.e., the sum of all congener or all isomer or homolog or Arochlor analyses).
11 This criterion applies to the sum of alpha-endosulfan and beta-endosulfan.
12 This criterion applies to DDT and its metabolites (i.e., the total concentration of DDT and its metabolites should not exceed this value).
13 The nonylphenol criteria address CAS numbers 84852-15-3 and 25154-52-3.
14 The criterion is for a total measurement of 5 haloacetic acids, dichloroacetic acid, trichloroacetic acid, monochloroacetic acid, bromoacetic acid, and dibromoacetic acid.
15 Hardness values shall be no greater than 400 mg/l. For waters with hardness concentrations greater than 400 mg/l, the actual ambient hardness may be used where a site-specific water effect ratio has been determined consistent with the environmental protection agency's water effect ratio procedure.
16 The department will recognize the biotic ligand model as an appropriate tool for developing site-specific limits for copper as well as the water-effects ratio (WER) method.
N.D. Admin Code tit. 33.1, art. 33.1-16, ch. 33.1-16-02.1, tbl. 2