N.H. Admin. Code § Env-Wq 809.06

Current through Register No. 44, October 31, 2024

Section Env-Wq 809.06 - Testing: Constituents Required For All QC Sludge

(a) Subject to (b), below, sludge samples collected pursuant to Env-Wq 809.05 or Env-Wq 809.07 shall be analyzed for the constituents listed in Table 809-2, below, in accordance with the methods specified.

(b) Testing for enteric viruses as specified in Table 809-2, section G shall be required only for generators of class B biosolids requesting certification of the biosolids for reclamation uses.

(c) The constituents required to be analyzed shall be as follows:

Table 809-2: Compounds, Chemical Abstract Service Registration Number (CAS), Analytical Methods, and Detection Limits

#	Compound		CAS	Analytical Method	Detection Limit (mg/kg)
Section A. Volatile Organic Compounds
1	Dichlorodifluoromethane		75-71-8	SW846 - 8000 series	2.0
2	Chloromethane		74-87-3	SW846 - 8000 series	2.0
3	Vinyl chloride		75-01-4	SW846 - 8000 series	2.0
4	Bromomethane		74-83-9	SW846 - 8000 series	2.0
5	Chloroethane		75-00-3	SW846 - 8000 series	2.0
6	Trichlorofluoromethane		75-69-4	SW846 - 8000 series	2.0
7	Diethyl ether		60-29-7	SW846 - 8000 series	2.0
8	Acetone		67-64-1	SW846 - 8000 series	10.0
9	1,1-Dichloroethene		75-35-4	SW846 - 8000 series	2.0
10	Methylene chloride		75-09-2	SW846 - 8000 series	2.0
11	Carbon disulfide		75-15-0	SW846 - 8000 series	2.0
12	Methyl-tert-butylether (MTBE)		1634-04-4	SW846 - 8000 series	2.0
13	trans-1,2-Dichloroethene		156-60-5	SW846 - 8000 series	2.0
14	1,1-Dichloroethane		75-34-3	SW846 - 8000 series	2.0
15	2-Butanone (MEK)		78-93-3	SW846 - 8000 series	10.0
16	2,2-Dichloropropane		590-20-7	SW846 - 8000 series	2.0
17	cis-1,2-Dichloroethene		156-59-2	SW846 - 8000 series	2.0
18	Chloroform		67-66-3	SW846 - 8000 series	2.0
19	Bromochloromethane		74-97-5	SW846 - 8000 series	2.0
20	Tetrahydrofuran (THF)		109-99-9	SW846 - 8000 series	10.0
21	1,1,1-Trichloroethane		71-55-6	SW846 - 8000 series	2.0
22	1,1-Dichloropropene		563-58-6	SW846 - 8000 series	2.0
23	Carbon tetrachloride		56-23-5	SW846 - 8000 series	2.0
24	1,2-Dichloroethane		107-06-2	SW846 - 8000 series	2.0
25	Benzene		71-43-2	SW846 - 8000 series	2.0
26	Trichloroethene		79-01-6	SW846 - 8000 series	2.0
27	1,2 Dichloropropane		78-87-5	SW846 - 8000 series	2.0
28	Dichlorobromomethane		75-27-4	SW846 - 8000 series	2.0
29	Dibromomethane		74-95-3	SW846 - 8000 series	2.0
30	4-Methyl-2-pentanone (MIBK)		108-10-1	SW846 - 8000 series	10.0
31	Cis-1,3-Dichloropropene		10061-01-5	SW846 - 8000 series	2.0
32	Toluene		108-88-3	SW846 - 8000 series	2.0
33	trans-1,3-Dichloropropene		10061-02-6	SW846 - 8000 series	2.0
34	1,1,2-Trichloroethane		79-00-5	SW846 - 8000 series	2.0
35	2-Hexanone		591-78-6	SW846 - 8000 series	10.0
36	1,3-Dichloropropane		142-28-9	SW846 - 8000 series	2.0
37	Tetrachloroethene		127-18-4	SW846 - 8000 series	2.0
38	Dibromochloromethane		128-48-1	SW846 - 8000 series	2.0
39	1,2-Dibromoethane		106-93-4	SW846 - 8000 series	2.0
40	Chlorobenzene		108-90-7	SW846 - 8000 series	2.0
41	1,1,1,2-Tetrachloroethane		630-20-6	SW846 - 8000 series	2.0
42	Ethylbenzene		100-41-4	SW846 - 8000 series	2.0
43	m&p-Xylene		108-38-3 106-42-3	SW846 - 8000 series	2.0
44	o-Xylene		95-47-6	SW846 - 8000 series	2.0
45	Styrene		100-42-5	SW846 - 8000 series	2.0
46	Bromoform		75-25-2	SW846 - 8000 series	2.0
47	Isopropylbenzene		98-82-8	SW846 - 8000 series	2.0
48	1,1,2,2-Tetrachloroethane		79-34-5	SW846 - 8000 series	2.0
49	1,2,3-Trichloropropane		96-18-4	SW846 - 8000 series	2.0
50	n-Propylbenzene		98-06-6	SW846 - 8000 series	2.0
51	Bromobenzene		108-86-1	SW846 - 8000 series	2.0
52	1,3,5-Trimethylbenzene		108-67-8	SW846 - 8000 series	2.0
53	2-Chlorotoluene		95-49-8	SW846 - 8000 series	2.0
54	4-Chlorotoluene		106-43-4	SW846 - 8000 series	2.0
55	tert-Butylbenzene		104-51-8	SW846 - 8000 series	2.0
56	1,2,4-Trimethylbenzene		95-63-6	SW846 - 8000 series	2.0
57	sec-Butylbenzene		135-98-8	SW846 - 8000 series	2.0
58	p-Isopropyltoluene		99-87-6	SW846 - 8000 series	2.0
59	1,3-Dichlorobenzene		541-73-1	SW846 - 8000 series	2.0
60	1,4-Dichlorobenzene		106-46-7	SW846 - 8000 series	2.0
61	n-Butylbenzene		104-51-8	SW846 - 8000 series	2.0
62	1,2-Dichlorobenzene		95-50-1	SW846 - 8000 series	2.0
63	1,2-Dibromo-3-chloropropane		96-12-8	SW846 - 8000 series	2.0
64	1,2,4-Trichlorobenzene		120-82-1	SW846 - 8000 series	2.0
65	Hexachlorobutadiene		87-68-3	SW846 - 8000 series	2.0
66	Naphthalene		91-20-3	SW846 - 8000 series	2.0
67	1,2,3-Trichlorobenzene		87-61-6	SW846 - 8000 series	2.0
Section B. Semi-volatile Compounds
68	1,2-Diphenylhydrazine (as Azobenzene)		122-66-7	SW846 - 8000 series	2.5
69	2,4,5-Trichlorophenol		95-95-4	SW846 - 8000 series	2.5
70	2,4,6-Trichlorophenol		88-06-2	SW846 - 8000 series	2.5
71	2,4-Dichlorophenol		120-83-2	SW846 - 8000 series	2.5
72	2,4-Dimethylphenol		105-67-9	SW846 - 8000 series	2.5
73	2,4-Dinitrophenol		51-28-5	SW846 - 8000 series	25.0
74	2,4-Dinitrotoluene		121-14-2	SW846 - 8000 series	2.5
75	2,6-Dinitrotoluene		606-20-2	SW846 - 8000 series	2.5
76	2-Chloronaphthalene		91-59-7	SW846 - 8000 series	2.5
77	2-Chlorophenol		95-97-8	SW846 - 8000 series	2.5
78	2-Methylnaphthalene		91-57-6	SW846 - 8000 series	2.5
79	2-Methylphenol (o-Cresol)		95-48-7	SW846 - 8000 series	5.0
80	2-Nitroaniline		88-74-4	SW846 - 8000 series	5.0
81	2-Nitrophenol		88-75-5	SW846 - 8000 series	5.0
82	3,3'-Dichlorobenzidine		91-94-1	SW846 - 8000 series	10.0
83	3-Nitroaniline		99-09-2	SW846 - 8000 series	5.0
84	3&4-Methylphenol (m&p-Cresol)		106-44-5	SW846 - 8000 series	5.0
85	4,6-Dinitro-2-methylphenol		534-52-1	SW846 - 8000 series	20.0
86	4-Bromophenyl phenylether		85-68-7	SW846 - 8000 series	10
87	4-Chloro-3-methylphenol		59-50-7	SW846 - 8000 series	10
88	4-Chloroaniline		106-47-8	SW846 - 8000 series	2.5
89	4-Chlorophenyl phenylether		7005-72-3	SW846 - 8000 series	10
90	4-Nitroaniline		100-01-6	SW846 - 8000 series	5.0
91	4-Nitrophenol		100-02-7	SW846 - 8000 series	12
92	Acenaphthene		83-32-9	SW846 - 8000 series	5.0
93	Acenaphthylene		208-96-8	SW846 - 8000 series	5.0
94	Anthracene		120-12-7	SW846 - 8000 series	5.0
95	Benzidine		92-87-5	SW846 - 8000 series	25.0
96	Benzo (a) anthracene		56-55-3	SW846 - 8000 series	2.5
97	Benzo (a) pyrene		50-32-8	SW846 - 8000 series	2.5
98	Benzo (b) fluoranthene		205-99-2	SW846 - 8000 series	2.5
99	Benzo (g,h,i) perylene		191-24-2	SW846 - 8000 series	2.5
100	Benzo (k) fluoranthene		207-08-9	SW846 - 8000 series	2.5
101	Bis (2-chloroethoxy) methane		111-91-1	SW846 - 8000 series	5.0
102	Bis (2-chloroethyl) ether		111-44-4	SW846 - 8000 series	2.5
103	Bis (2-chloroisopropyl) ether		39638-32-9	SW846 - 8000 series	2.0
104	Bis (2-ethylhexyl) phthalate		117-81-7	SW846 - 8000 series	5.0
105	Butyl Benzyl phthalate		85-68-7	SW846 - 8000 series	5.0
106	Carbazole		86-74-8	SW846 - 8000 series	2.5
107	Chrysene		218-01-9	SW846 - 8000 series	2.5
108	Di-n-butyl phthalate		84-74-2	SW846 - 8000 series	5.0
109	Di-n-octyl phthalate		117-84-0	SW846 - 8000 series	5.0
110	Dibenzo (a,h) anthracene		53-70-3	SW846 - 8000 series	2.5
111	Dibenzofuran		132-64-9	SW846 - 8000 series	2.5
112	Diethyl phthalate		84-66-2	SW846 - 8000 series	5.0
113	Dimethyl phthalate		131-11-3	SW846 - 8000 series	5.0
114	Fluoranthene		206-44-0	SW846 - 8000 series	2.5
115	Fluorene		86-73-7	SW846 - 8000 series	2.5
116	Hexachlorobenzene		118-74-1	SW846 - 8000 series	2.5
117	Hexachlorocyclopentadiene		77-47-4	SW846 - 8000 series	5.0
118	Hexachloroethane		67-72-1	SW846 - 8000 series	2.5
119	Indeno (1,2,3-cd) pyrene		193-39-5	SW846 - 8000 series	2.5
120	Isophorone		78-59-1	SW846 - 8000 series	2.5
121	N-Nitroso-di-n-propylamine		621-64-7	SW846 - 8000 series	2.5
122	N-Nitrosodimethylamine		62-75-9	SW846 - 8000 series	5.0
123	N-Nitrosodiphenylamine		86-30-6	SW846 - 8000 series	2.5
124	Nitrobenzene		98-95-3	SW846 - 8000 series	2.5
125	Pentachlorophenol		87-86-5	SW846 - 8000 series	5.0
126	Phenanthrene		85-01-8	SW846 - 8000 series	2.5
127	Phenol		108-95-2	SW846 - 8000 series	5.0
128	Pyrene		129-00-0	SW846 - 8000 series	2.5
Section C. Metals
129	Total Arsenic		7440-38-2	SW846 6000/7000 series	10
130	Total Cadmium		7440-43-9	SW846 6000/7000 series	1.0
131	Total Chromium		16065-83-1	SW846 6000/7000 series	10
132	Total Copper		7440-50-8	SW846 6000/7000 series	10
133	Total Lead		7439-92-1	SW846 6000/7000 series	11
134	Total Mercury		7439-97-6	SW846 7000 series	0.05
135	Total Molybdenum		7439-98-7	SW846 6000/7000 series	10
136	Total Nickel		7440-02-0	SW846 6000/7000 series	10
137	Total Selenium		7782-49-2	SW846 6000/7000 series	18
138	Total Zinc		7440-66-6	SW846 6000/7000 series	10
139	Total Antimony		7440-36-0	SW846 6000/7000 series	8.0
140	Total Beryllium		7440-41-7	SW846 6000/7000 series	0.1
141	Total Silver		7440-22-4	SW846 6000/7000 series	4.0
142	Total Thallium		7440-28-0	SW846 6000/7000 series	10
Section D. Polychlorinated Biphenyls
143	PCB-1242		53469-21-9	SW846 - 8000 series	0.7
144	PCB-1254		11097-69-1	SW846 - 8000 series	0.7
145	PCB-1221		11104-28-2	SW846 - 8000 series	0.7
146	PCB-1232		11141-16-5	SW846 - 8000 series	0.7
147	PCB-1248		12672-29-6	SW846 - 8000 series	0.7
148	PCB-1260		11096-82-5	SW846 - 8000 series	0.7
149	PCB-1016		12674-11-2	SW846 - 8000 series	0.7
Section E. Additional Analyses
150	pH		not applicable (na)	SM-4500-H	na
151	Percent solids		na	SM-2540 G	na
152	nitrate-nitrite		14797-55-8 14797-65-0	SM-4500-NO3 SW846 - 9210 EPA 353 -3000 series	30
153	Total Kjeldalh nitrogen		na	SM-4500-Norg EPA-351.3	300
154	ammonia nitrogen		na	SM-4500-NH3 EPA-350	30
155	Total organic nitrogen		na	calculation	na
156	potassium		na	SM-3500-K SW846 6000/7000 series	15
157	phosphorus		na	SM-4500-P EPA-365	15
Section F. Dioxins
158		Total Toxic Equivalent, 2,3,7,8 TCDD	1746-01-6	EPA 1613	5 ppt TEQ
Section G. Enteric Virus
159		Enteric Virus	na	ASTM D4994-89 (2002)	1 PFU/ 4 grams

(d) The following shall apply to Table 809-2:

(1) Subject to (2) and (3), below, the detection limit for all the analyses shall be at or below the detection limits specific in Table 809-2;

(2) If the percent solids in a sludge is below 5%, the results shall be reported in mg/L and the detection limits shall be appropriate to the methodology specified in Table 809-2 for a water matrix; and

(3) If the detection limit specified in Table 809-2 cannot be achieved by the methodology listed, the department shall accept the detection limits that are routinely achievable.

N.H. Admin. Code § Env-Wq 809.06

Adopted by Volume XXXVI Number 01, Filed January 7, 2016, Proposed by #10998, Effective 1/1/2016, Expires 1/1/2026.