La. Admin. Code tit. 33 § V-3007

Current through Register Vol. 50, No. 9, September 20, 2024

Section V-3007 - Interim Status Standards for Burners

A. Applicability

1. General

a. The purpose of this Section is to establish minimum interim standards for owners or operators of facilities that burn hazardous waste in "existing" boilers or industrial furnaces. The standards provided in this Section define the acceptable management of hazardous waste during the period of interim status. The standards of this Section apply to owners and operators of facilities that are in operation or under construction on the effective date of this Section until either a permit is issued under LAC 33:V.3009-3015 or until the closure responsibilities identified in this Section are fulfilled.

b. Existing or in existence means a boiler or industrial furnace that, on or before August 21, 1991, is either in operation burning or processing hazardous waste or for which construction (including the ancillary facilities to burn to process the hazardous waste) has commenced. A facility has commenced construction if the owner or operator has obtained the federal, state, and local approvals or permits necessary to begin physical construction; and either:

i. a continuous on-site, physical construction program has begun; or

ii. the owner or operator has entered into contractual obligations, which cannot be canceled or modified without substantial loss, for physical construction of the facility to be completed within a reasonable time.

c. If a boiler or industrial furnace is located at a facility that already has a permit or interim status, then the facility must comply with the applicable regulations dealing with permit modifications in LAC 33:V.4303 or changes in interim status in LAC 33:V.321.C.

2. Exemptions. The requirements of this Section do not apply to hazardous waste exempt under LAC 33:V.3001.B.

3. Prohibition on Burning Dioxin-Containing Wastes. The following hazardous waste listed for dioxin and hazardous waste derived from any of these wastes may not be burned in a boiler or industrial furnace operating under the interim status standards of this Section: EPA Hazardous Waste Numbers F020, F021, F022, F023, F026, and F027.

4. Applicability of LAC 33:V.105.G and Chapter 43. Owners or operators of boilers and industrial furnaces that burn hazardous waste and are operating under interim status are subject to the following provisions of LAC 33:V.Chapter 43, except as provided otherwise by this Section:

a. LAC 33:V.105.G;

b. LAC 33:V.Chapter 43.Subchapter A (General Facility Standards);

c. LAC 33:V.Chapter 43.Subchapter B (Preparedness and Prevention);

d. LAC 33:V.Chapter 43.Subchapter C (Contingency Plan and Emergency Procedures);

e. LAC 33:V.Chapter 43.Subchapter D (Manifest System, Recordkeeping, and Reporting), except that LAC 33:V.4353, 4355 and 4363 do not apply to owners and operators of on-site facilities that do not receive any hazardous waste from off-site sources;

f. LAC 33:V.Chapter 43.Subchapter F (Closure and Post-Closure);

g. LAC 33:V.Chapter 43.Subchapter G (Financial Requirements);

h. LAC 33:V.Chapter 43.Subchapter R (Air Emission Standards for Equipment Leaks).

5. Special Requirements for Furnaces. The following controls apply during interim status to industrial furnaces (e.g., kilns, cupolas) that feed hazardous waste for a purpose other than solely as an ingredient (see LAC 33:V.3007.A.5.b) at any location other than the hot end where products are normally discharged or where fuels are normally fired.

a. Controls

i. The hazardous waste shall be fed at a location where combustion gas temperatures are at least 1800°F;

ii. the owner or operator must determine that adequate oxygen is present in combustion gases to combust organic constituents in the waste and retain documentation of such determination in the facility record;

iii. for cement kiln systems, the hazardous waste shall be fed into the kiln; and

iv. the hydrocarbon controls of LAC 33:V.3007.C.5 or 3009.C apply upon certification of compliance under LAC 33:V.3007.C irrespective of the CO level achieved during the compliance test.

b. Burning Hazardous Waste Solely as an Ingredient. A hazardous waste is burned for a purpose other than solely as an ingredient if it meets either of these criteria:

i. the hazardous waste has a total concentration of nonmetal compounds listed in LAC 33:V.4901.G, Table 6 exceeding 500 ppm by weight, as-fired, and, so, is considered to be burned for destruction. The concentration of nonmetal compounds in a waste as-generated may be reduced to the 500 ppm limit by bona fide treatment that removes or destroys nonmetal constituents. Blending for dilution to meet the 500 ppm limit is prohibited and documentation that the waste has not been impermissibly diluted must be retained in the facility record; or

ii. the hazardous waste has a heating value of 5,000 Btu/lb or more, as-fired, and, so, is considered to be burned as fuel. The heating value of a waste as-generated may be reduced to below the 5,000 Btu/lb limit by bona fide treatment that removes or destroys organic constituents. Blending to augment the heating value to meet the 5,000 Btu/lb limit is prohibited and documentation that the waste has not been impermissibly blended must be retained in the facility record.

6. Restrictions on Burning Hazardous Waste That is Not a Fuel. Prior to certification of compliance under LAC 33:V.3007.C, owners and operators shall not feed hazardous waste that has a heating value less than 5,000 Btu/lb, as-generated, (except that the heating value of a waste as-generated may be increased to above the 5,000 Btu/lb limit by bona fide treatment; however, blending to augment heating value to meet the 5,000 Btu/lb limit is prohibited and records must be kept to document that impermissible blending has not occurred) in a boiler or industrial furnace, except that:

a. hazardous waste may be burned solely as an ingredient; or

b. hazardous waste may be burned for purposes of compliance testing (or testing prior to compliance testing) for a total period of time not to exceed 720 hours; or

c. such waste may be burned if the administrative authority has documentation to show that, prior to August 21, 1991:

i. the boiler or industrial furnace is operating under the interim status standards for incinerators provided by LAC 33:V.Chapter 43.Subchapter N or the interim status standards for thermal treatment units provided by LAC 33:V.Chapter 43.Subchapter O;

ii. the boiler or industrial furnace met the interim status eligibility requirements under LAC 33:V.4301 for LAC 33:V.Chapter 43.Subchapters N or O; and

iii. hazardous waste with a heating value less than 5,000 Btu/lb was burned prior to that date; or

d. such waste may be burned in a halogen acid furnace if the waste is burned as an excluded ingredient under LAC 33:V.109.Solid Waste.5 prior to February 21, 1991, and documentation is kept on file supporting this claim.

7. Direct Transfer to the Burner. If hazardous waste is directly transferred from a transport vehicle to a boiler or industrial furnace without the use of a storage unit, the owner and operator must comply with LAC 33:V.3023.

B. Certification of Precompliance

1. General. The owner or operator must provide complete and accurate information specified in LAC 33:V.3007.B.2 to the administrative authority on or before August 21, 1991, and must establish limits for the operating parameters specified in LAC 33:V.3007.B.3. Such information is termed a certification of precompliance and constitutes a certification that the owner or operator has determined that, when the facility is operated within the limits specified in LAC 33:V.3007.B.3, the owner or operator believes that, using best engineering judgment, emissions of particulate matter, metals, and HCl and Cl₂ are not likely to exceed the limits provided by LAC 33:V.3011-3015. The facility may burn hazardous waste only under the operating conditions that the owner or operator establishes under LAC 33:V.3007.B.3 until the owner or operator submits a revised certification of precompliance under LAC 33:V.3007.B.8 or a certification of compliance under LAC 33:V.3007.C, or until a permit is issued.

2. Information Required. The following information must be submitted with the certification of precompliance to support the determination that the limits established for the operating parameters identified in LAC 33:V.3007.B.3 are not likely to result in an exceedance of the allowable emission rates for particulate matter, metals, and HCl and Cl₂:

a. general facility information:

i. EPA facility ID number;

ii. facility name, contact person, telephone number, and address;

iii. description of boilers and industrial furnaces burning hazardous waste, including type and capacity of device;

iv. a scaled plot plan showing the entire facility and location of the boilers and industrial furnaces burning hazardous waste; and

v. a description of the air pollution control system on each device burning hazardous waste, including the temperature of the flue gas at the inlet to the particulate matter control system;

b. except for facilities complying with the Tier I or Adjusted Tier I feed rate screening limits for metals or total chlorine and chloride provided by LAC 33:V.3013.B or E and LAC 33:V.3015.B or E, respectively, the estimated uncontrolled (at the inlet to the air pollution control system) emissions of particulate matter, each metal controlled by LAC 33:V.3013, and hydrogen chloride and chlorine, and the following information to support such determinations:

i. the feed rate (lb/hr) of ash, chlorine, antimony, arsenic, barium, beryllium, cadmium, chromium, lead, mercury, silver, and thallium in each feedstream (hazardous waste, other fuels, industrial furnace feedstocks);

ii. the estimated partitioning factor to the combustion gas for the materials identified in Subparagraph B.2.a of this Section and the basis for the estimate and an estimate of the partitioning to HCl and Cl₂ of total chloride and chlorine in feed materials. To estimate the partitioning factor, the owner or operator must use either best engineering judgment or the procedures specified in 40 CFR 266, Appendix IX, as adopted and amended at LAC 33:V.3099.Appendix I;

iii. for industrial furnaces that recycle collected particulate matter (PM) back into the furnace and that will certify compliance with the metals emissions standards under Clause C.3.b.i of this Section, the estimated enrichment factor for each metal. To estimate the enrichment factor, the owner or operator must use either best engineering judgment or the procedures specified in "Alternative Methodology for Implementing Metals Controls" in 40 CFR 266, Appendix IX, as adopted and amended at LAC 33:V.3099.Appendix I;

iv. if best engineering judgment is used to estimate partitioning factors or enrichment factors under LAC 33:V.3007.B.2.b or c respectively, the basis for the judgment. When best engineering judgment is used to develop or evaluate data or information and make determinations under this Section, the determinations must be made by a qualified, registered professional engineer and a certification of his/her determinations in accordance with LAC 33:V.513 must be provided in the certification of precompliance;

c. for facilities complying with the Tier I or Adjusted Tier I feed rate screening limits for metals or total chlorine and chloride provided by LAC 33:V.3013.B or E and 3015.B.1 or E, the feed rate (lb/hr) of total chloride and chlorine, antimony, arsenic, barium, beryllium, cadmium, chromium, lead, mercury, silver, and thallium in each feed stream (hazardous waste, other fuels, industrial furnace feedstocks);

d. for facilities complying with the Tier II or Tier III emission limits for metals or HCl and Cl₂ (under LAC 33:V.3013.C or D or 3015.B.2 or C, the estimated controlled (outlet of the air pollution control system) emissions rates of particulate matter, each metal controlled by LAC 33:V.3013, and HCl and Cl₂, and the following information to support such determinations:

i. the estimated air pollution control system (APCS) removal efficiency for particulate matter, HCl, Cl₂, antimony, arsenic, barium, beryllium, cadmium, chromium, lead, mercury, silver, and thallium;

ii. to estimate APCS removal efficiency, the owner or operator must use either best engineering judgment or the procedures prescribed in 40 CFR 266, Appendix IX, as adopted and amended at LAC 33:V.3099.Appendix I;

iii. if best engineering judgment is used to estimate APCS removal efficiency, the basis for the judgment is required. Use of best engineering judgment must be in conformance with provisions of LAC 33:V.3007.B.2.b.iv;

e. determination of allowable emissions rates for HCl, Cl₂, antimony, arsenic, barium, beryllium, cadmium, chromium, lead, mercury, silver, and thallium, and the following information to support such determinations:

i. for all facilities:

(a). physical stack height;

(b). good engineering practice stack height as defined by 40 CFR 51.100(ii);

(c). maximum flue gas flow rate;

(d). maximum flue gas temperature;

(e). attach a US Geological Service topographic map (or equivalent) showing the facility location and surrounding land within five kilometers of the facility;

(f). identify terrain type (complex or noncomplex); and

(g). identify land use (urban or rural);

ii. for owners and operators using Tier III site specific dispersion modeling to determine allowable levels under LAC 33:V.3013.D or 3015.C, or adjusted Tier I feed rate screening limits under LAC 33:V.3013.E or 3015.E:

(a). dispersion model and version used;

(b). source of meteorological data;

(c). the dilution factor in micrograms per cubic meter per gram per second of emissions for the maximum annual average off-site (unless on-site is required) ground level concentration (MEI location); and

(d). indicate the MEI location on the map required under LAC 33:V.3007.B.2.e.i.(e);

f. for facilities complying with the Tier II or III emissions rate controls for metals or HCl and Cl₂, a comparison of the estimated controlled emissions rates determined under LAC 33:V.3017.B.2.d with the allowable emission rates determined under LAC 33:V.3017.B.2.e;

g. for facilities complying with the Tier I (or adjusted Tier I) feed rate screening limits for metals or total chloride and chlorine, a comparison of actual feed rates of each metal and total chlorine and chloride determined under LAC 33:V.3007.B.2.c to the Tier I allowable feed rates; and

h. for industrial furnaces that feed hazardous waste for any purpose other than solely as an ingredient (as defined by LAC 33:V.3007.A.5.b) at any location other than the product discharge end of the device, documentation of compliance with the requirements of LAC 33:V.3007.A.5.a.i-iii;

i. for industrial furnaces that recycle collected particulate matter (PM) back into the furnace and that will certify compliance with the metals emissions standards under LAC 33:V.3007.C.3.b.i:

i. the applicable particulate matter standard in lb/hr; and

ii. the precompliance limit on the concentration of each metal in collected PM.

3. Limits on Operating Conditions. The owner and operator shall establish limits on the following parameters consistent with the determinations made under LAC 33:V.3007.B.2 and certify (under provisions of LAC 33:V.3007.B.9) to the administrative authority that the facility will operate within the limits during interim status when there is hazardous waste in the unit until revised certification of precompliance under LAC 33:V.3007.B.8 or certification of compliance under LAC 33:V.3007.C:

a. feed rate of total hazardous waste and (unless complying with the Tier I or adjusted Tier I metals feed rate screening limits under LAC 33:V.3013.B or E) pumpable hazardous waste;

b. feed rate of each metal in the following feedstreams:

i. total feedstreams, except that industrial furnaces that comply with the alternative metals implementation approach under LAC 33:V.3007.B.4 must specify limits on the concentration of each metal in collected particulate matter in lieu of feed rate limits for total feedstreams;

ii. total hazardous waste feed unless complying with the Tier I or Adjusted Tier I metals feed rate screening limits under LAC 33:V.3013.B or E; and

iii. total pumpable hazardous waste feed, unless complying with the Tier I or adjusted Tier I metals feed rate screening limits under LAC 33:V.3013.B or E;

c. total feed rate of chlorine and chloride in total feedstreams;

d. total feed rate of ash in total feedstreams, except that the ash feed rate for cement kilns and light-weight aggregate kilns is not limited; and

e. maximum production rate of the device in appropriate units when producing normal product, unless complying with the Tier I or Adjusted Tier I feed rate screening limits for chlorine under LAC 33:V.3015.B.1 or E and for all metals under LAC 33:V.3013.B or E and the uncontrolled emissions do not exceed the standard under LAC 33:V.3011.

4. Operating Requirements for Furnaces That Recycle PM. Owners and operators of furnaces that recycle collected particulate matter (PM) back into the furnace and that will certify compliance with the metals emissions controls under Clause C.3.b.i of this Section must comply with the special operating requirements provided in "Alternative Methodology for Implementing Metals Controls" in 40 CFR 266, Appendix IX, as adopted and amended at LAC 33:V.3099.Appendix I.

5. Measurement of Feed Rates and Production Rate

a. General Requirements. Limits on each of the parameters specified in LAC 33:V.3007.B.3 (except for limits on metals concentrations in collected particulate matter (PM) for industrial furnaces that recycle collected PM) shall be established and continuously monitored under either of the following methods.

i. Instantaneous Limits. A limit for a parameter may be established and continuously monitored and recorded on an instantaneous basis (i.e., the value that occurs at any time) not to be exceeded at any time; or

ii. Hourly Rolling Average Limits. A limit for a parameter may be established and continuously monitored on an hourly rolling average basis defined as follows:

(a). a continuous monitor is one which continuously samples the regulated parameter without interruption, and evaluates the detector response at least once each 15 seconds, and computes and records the average value at least every 60 seconds;

(b). an hourly rolling average is the arithmetic mean of the 60 most recent one-minute average values recorded by the continuous monitoring system.

b. Rolling Average Limits for Carcinogenic Metals and Lead. Feed rate limits for the carcinogenic metals (arsenic, beryllium, cadmium, and chromium) and lead may be established either on an hourly rolling average basis as prescribed by LAC 33:V.3007.B.5.a.ii or on (up to) a 24-hour rolling average basis. If the owner or operator elects to use an averaging period from 2 to 24 hours.

i. The feed rate of each metal shall be limited at any time to 10 times the feed rate that would be allowed on an hourly rolling average basis.

ii. The continuous monitor shall meet the following specifications:

(b). the rolling average for the selected averaging period is defined as the arithmetic mean of one-hour block averages for the averaging period. A one-hour block average is the arithmetic mean of the one-minute averages recorded during the 60-minute period beginning at one minute after the beginning of preceding clock hour.

c. Feed Rate Limits for Metals, Total Chloride and Chlorine, and Ash. Feed rate limits for metals, total chlorine and chloride, and ash are established and monitored by knowing the concentration of the substance (i.e., metals, chloride/chlorine, and ash) in each feedstream and the flow rate of the feedstream. To monitor the feed rate of these substances, the flow rate of each feedstream must be monitored under the continuous monitoring requirements of LAC 33:V.3007.B.5.a and b.

6. Public Notice Requirements at Precompliance. On or before August 21, 1991, the owner or operator must submit a notice with the following information for publication in a major local newspaper of general circulation and send a copy of the notice to the appropriate units of state and local government. The owner or operator must provide to the Office of Environmental Services with the certification of precompliance evidence of submitting the notice for publication. The notice, which shall be entitled "Notice of Certification of Precompliance with Hazardous Waste Burning Requirements of LAC 33:V.3007.B," must include:

a. name and address of the owner or operator of the facility as well as the location of the device burning hazardous waste;

b. date that the certification of precompliance is submitted to the administrative authority;

c. brief description of the regulatory process required to comply with the interim status requirements of this Section including required emissions testing to demonstrate conformance with emissions standards for organic compounds, particulate matter, metals, and HCl and Cl₂;

d. types and quantities of hazardous waste burned including, but not limited to, source, whether solid or liquid, as well as an appropriate description of the waste;

e. type of device(s) in which the hazardous waste is burned including a physical description and maximum production rate of each device;

f. types and quantities of other fuels and industrial furnace feedstocks fed to each unit;

g. brief description of the basis for this certification of precompliance as specified in LAC 33:V.3007.B.2;

h. locations where the record for the facility can be viewed and copied by interested parties. These records and locations shall, at a minimum, include:

i. the administrative record kept by the Louisiana Department of Environmental Quality (LDEQ) where the supporting documentation was submitted or another location designated by the administrative authority; and

ii. the BIF correspondence file kept at the facility site where the device is located. The correspondence must include all correspondence between the facility and the director, administrative authority, including copies of all certifications and notifications, such as the precompliance certification, precompliance public notice, notice of compliance testing, compliance test report, compliance certification, time extension requests and approvals or denials, enforcement notifications of violations, and copies of EPA and state site visit reports submitted to the owner or operator;

i. notification of the establishment of a facility mailing list whereby interested parties shall notify the LDEQ that they wish to be placed on the mailing list to receive future information and notices about this facility; and

j. location (mailing address) of the applicable LDEQ Regional Office, where further information can be obtained on LDEQ regulation of hazardous waste burning.

7. Monitoring Other Operating Parameters. When the monitoring systems for the operating parameters listed in Subparagraphs C.1.e-m of this Section are installed and operating in conformance with vendor specifications or (for CO, HC, and oxygen) specifications provided by 40 CFR 266, Appendix IX, as adopted and amended at LAC 33:V.3099.Appendix I, as appropriate, the parameters shall be continuously monitored and records shall be maintained in the operating record.

8. Revised Certification of Precompliance. The owner or operator may revise at any time the information and operating conditions documented under LAC 33:V.3007.B.2 and 3 in the certification of precompliance by submitting a revised certification of precompliance under procedures provided by those paragraphs.

a. The public notice requirements of LAC 33:V.3007.B.6 do not apply to recertifications.

b. The owner or operator must operate the facility within the limits established for the operating parameters under LAC 33:V.3007.B.3 until a revised certification is submitted under this Paragraph or a certification of compliance is submitted under LAC 33:V.3007.C.

9. Certification of Precompliance Statement. The owner or operator must include the following signed statement with the certification of precompliance submitted to the administrative authority.

"I certify under penalty of law that this information was prepared under my direction or supervision in accordance with a system designed to ensure that qualified personnel properly gathered and evaluated the information and supporting documentation. Copies of all emissions tests, dispersion modeling results and other information used to determine conformance with the requirements of LAC 33:V.3007.B are available at the facility and can be obtained from the facility contact person listed above. Based on my inquiry of the person or persons who manages the facility, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.

"I also acknowledge that the operating limits established in this certification pursuant to LAC 33:V.3007.B.3 and 4 are enforceable limits at which the facility can legally operate during interim status until:

(1) a revised certification of precompliance is submitted,

(2) a certification of compliance is submitted, or

(3) an operating permit is issued."

C. Certification of Compliance. The owner or operator shall conduct emissions testing to document compliance with the emissions standards of Clause A.5.a.iv of this Section and LAC 33:V.3009.B-E, 3011, 3013, and 3015, under the procedures prescribed by this Subsection, except under extensions of time provided by Paragraph C.7 of this Section. Based on the compliance test, the owner or operator shall submit to the administrative authority, on or before August 21, 1992, a complete and accurate "certification of compliance" (under LAC 33:V.3007.C.4) with those emission standards establishing limits on the operating parameters specified in LAC 33:V.3007.C.1.

1. Limits on Operating Conditions. The owner or operator shall establish limits on the following parameters based on operations during the compliance test (under procedures prescribed in LAC 33:V.3007.C.4.d) or as otherwise specified and include these limits with the certification of compliance. The boiler or industrial furnace must be operated in accordance with these operating limits and the applicable emissions standards of LAC 33:V.3009.B-E, 3011, 3013, 3015, and 3007.A.5.a.iv at all times when there is hazardous waste in the unit:

a. feed rate of total hazardous waste and (unless complying with the Tier I or adjusted Tier I metals feed rate screening limits under LAC 33:V.3013.B or E), pumpable hazardous waste;

b. feed rate of each metal in the following feedstreams:

i. total feed streams, except that:

(a). facilities that comply with Tier I or Adjusted Tier I metals feed rate screening limits may set their operating limits at the metal feed rate screening limit determined under LAC 33:V.3013.B or E; and

(b). industrial furnaces that must comply with the alternative metals implementation approach under LAC 33:V.3007.C.3.b.ii must specify limits on the concentration of each metal in the collected particulate matter in lieu of feed rate limits for total feedstreams;

ii. total hazardous waste feed (unless complying with the Tier I or adjusted Tier I metals feed rate screening limits under LAC 33:V.3013.B or E); and

iii. total pumpable hazardous waste feed;

c. total feed rate of chlorine and chloride in total feed streams, except that facilities that comply with Tier I or Adjusted Tier I feed rate screening limits may set their operating limits at the total chlorine and chlorine feed rate screening limits determined under LAC 33:V.3015.B.1 or E;

d. total feed rate of ash in total feedstreams, except that the ash feed rate for cement kilns and light-weighted aggregate kilns is not limited;

e. carbon monoxide concentration, and where required, hydrocarbon concentration in stack gas. When complying with the CO controls of LAC 33:V.3009.B, the CO limit is 100 ppmv, and when complying with the HC controls of LAC 33:V.3009.C, the HC limit is 20 ppmv. When complying with the CO controls of LAC 33:V.3009.C, the CO limit is established based on the compliance test;

f. maximum production rate of the device in appropriate units when producing normal product, unless complying with the Tier I or Adjusted Tier I feed rate screening limits for chlorine under LAC 33:V.3015.B.1 or E and for all metals under LAC 33:V.3013.B or E and the uncontrolled particulate emissions do not exceed the standard under LAC 33:V.3011;

g. maximum combustion chamber temperature where the temperature measurement is as close to the combustion zone as possible and is upstream of any quench water injection, (unless complying with the Tier I or adjusted Tier I metals feed rate screening limits under LAC 33:V.3013.B or E);

h. maximum flue gas temperature entering a particulate matter control device (unless complying with Tier I or Adjusted Tier I metals feed rate screening limits under LAC 33:V.3013.B or E and the total chlorine and chloride feed rate screening limits under LAC 33:V.3015.B.1 or E);

i. for systems using wet scrubbers, including wet ionizing scrubbers (unless complying with the Tier I or Adjusted Tier I metals feed rate screening limits under LAC 33:V.3013.B or E and the total chlorine and chloride feed rate screening limits under LAC 33:V.3015.B.1 or E):

i. minimum liquid to flue gas ratio;

ii. minimum scrubber blowdown from the system or maximum suspended solids content of scrubber water; and

iii. minimum pH level of the scrubber water;

j. for systems using venturi scrubbers, the minimum differential gas pressure across the venturi (unless complying with the Tier I or adjusted Tier I metals feed rate screening limits under LAC 33:V.3013.B or E and the total chlorine and chloride feed rate screening limits under LAC 33:V.3015.B.1 or E);

k. for systems using dry scrubbers (unless complying with the Tier I or adjusted Tier I metals feed rate screening limits under LAC 33:V.3015.B.1 or E and the total chlorine and chloride feed rate screening limits under LAC 33:V.3015.B.1 or E):

i. minimum caustic feed rate; and

ii. maximum flue gas flow rate;

l. for systems using wet ionizing scrubbers or electrostatic precipitators (unless complying with the Tier I or adjusted Tier I metals feed rate screening limits under LAC 33:V.3013.B or E and the total chlorine and chloride feed rate screening limits under LAC 33:V.3015.B.1 or E):

i. minimum electrical power in kilovolt amperes (kVA) to the precipitator plates; and

ii. maximum flue gas flow rate;

m. for systems using fabric filters (baghouses), the minimum pressure drop (unless complying with the Tier I or adjusted Tier I metals feed rate screening limits under LAC 33:V.3013.B or E and the total chlorine and chloride feed rate screening limits under LAC 33;V.3015.B.1 or E).

2. Prior Notice of Compliance Testing. At least 30 days prior to the compliance testing required by Paragraph C.3 of this Section, the owner or operator shall notify the Office of Environmental Services and submit the following information:

a. general facility information including:

i. EPA facility ID number;

ii. facility name, contact person, telephone number, and address;

iii. person responsible for conducting compliance testing, including company name, address, and telephone number, and a statement of qualifications;

iv. planned date of the compliance test;

b. specific information on each device to be tested including:

i. description of boiler or industrial furnace;

ii. a scaled plot plan showing the entire facility and location of the boiler or industrial furnace;

iii. a description of the air pollution control system;

iv. identification of the continuous emission monitors that are installed, including:

(a). carbon monoxide monitor;

(b). oxygen monitor;

(c). hydrocarbon monitor, specifying the minimum temperature of the system and, if the temperature is less than 150°C, an explanation of why a heated system is not used (see LAC 33:V.3007.C.5) and a brief description of the sample gas conditioning system;

v. indication of whether the stack is shared with another device that will be in operation during the compliance test;

vi. other information useful to an understanding of the system design or operation;

c. information on the testing planned, including a complete copy of the test protocol and Quality Assurance/Quality Control (QA/QC) plan, and a summary description for each test providing the following information at a minimum:

i. purpose of the test (e.g., demonstrate compliance with emissions of particulate matter); and

ii. planned operating conditions, including levels for each pertinent parameter specified in LAC 33:V.3007.C.1.

3. Compliance Testing

a. General. Compliance testing must be conducted under conditions for which the owner or operator has submitted a certification of precompliance under LAC 33:V.3007.B and under conditions established in the notification of compliance testing required by LAC 33:V.3007.C.2. The owner or operator may seek approval on a case-by-case basis to use compliance test data from one unit in lieu of testing a similar on-site unit. To support the request, the owner or operator must provide a comparison of the hazardous waste burned and other feed streams and the design, operation, and maintenance of both the tested unit and the similar unit. The administrative authority shall provide a written approval to use compliance test data in lieu of testing a similar unit if he finds that the hazardous wastes, the devices, and the operating conditions are sufficiently similar and the data from the other compliance test is adequate to meet the requirements of LAC 33:V.3007.C.

b. Special Requirements for Industrial Furnaces that Recycle Collected PM. Owners and operators of industrial furnaces that recycle back into the furnace particulate matter (PM) from the air pollution control system must comply with one of the following procedures for testing to determine compliance with the metals standards of LAC 33:V.3013.C or D:

i. the special testing requirements prescribed in "Alternative Method for Implementing Metals Controls" in 40 CFR 266, Appendix IX, as adopted and amended at LAC 33:V.3099.Appendix I; or

ii. stack emissions testing for a minimum of six hours each day while hazardous waste is burned during interim status. The testing must be conducted when burning normal hazardous waste for that day at normal feed rates for that day and when the air pollution control system is operated under normal conditions. During interim status, hazardous waste analysis for metals content must be sufficient for the owner or operator to determine if changes in metals content may affect the ability of the facility to meet the metals emissions standards established under LAC 33:V.3013.C or D. Under this option, operating limits (under LAC 33:V.3007.C.1) must be established during compliance testing under LAC 33:V.3007.C.3 only on the following parameters:

(a). feed rate of total hazardous waste;

(b). total feed rate of chlorine and chloride in total feedstreams;

(c). total feed rate of ash in total feedstreams, except that the ash feed rate for cement kilns and light-weight aggregate kilns is not limited;

(d). carbon monoxide concentration and, where required, hydrocarbon concentration in stack gas;

(e). maximum production rate of the device in appropriate units when producing normal product; or

iii. conduct compliance testing to determine compliance with the metals standards to establish limits on the operating parameters of LAC 33:V.3007.C.1 only after the kiln system has been conditioned to enable it to reach equilibrium with respect to metals fed into the system and metals emissions. During conditioning, hazardous waste and raw materials having the same metals content as will be fed during the compliance test must be fed at the feed rates that will be fed during the compliance test.

c. Conduct of Compliance Testing

i. If compliance with all applicable emissions standards of LAC 33:V.3009-3015 is not demonstrated simultaneously during a set of test runs, the operating conditions of additional test runs required to demonstrate compliance with remaining emissions standards must be as close as possible to the original operating conditions.

ii. Prior to obtaining test data for purposes of demonstrating compliance with the applicable emissions standards of LAC 33:V.3009-3015 or establishing limits on operating parameters under this Section, the facility must operate under compliance test conditions for a sufficient period to reach steady-state operations. Industrial furnaces that recycle collected particulate matter back into the furnace and that comply with LAC 33:V.3007.C.3.b.i or ii, however, need not reach steady state conditions with respect to the flow of metals in the system prior to beginning compliance testing for metals.

iii. Compliance test data on the level of an operating parameter for which a limit must be established in the certification of compliance must be obtained during emissions sampling for the pollutant(s) (i.e., metals, PM, HCl/Cl₂, organic compounds) for which the parameter must be established as specified by LAC 33:V.3007.C.1.

4. Certification of Compliance. Within 90 days of completing compliance testing, the owner or operator must certify to the administrative authority compliance with the emissions standards of LAC 33:V.3007.A.5.a.iv, 3009.B, C, and E, 3011, 3013, and 3015. The certification of compliance must include the following information:

a. general facility and testing information including:

i. EPA facility ID number;

ii. facility name, contact person, telephone number, and address;

iii. person responsible for conducting compliance testing, including company name, address, and telephone number, and a statement of qualifications;

iv. date(s) of each compliance test;

v. description of boiler or industrial furnace tested;

vi. person responsible for quality assurance/quality control (QA/QC), title, and telephone number, and statement that procedures prescribed in the QA/QC plan submitted under LAC 33:V.3007.C.2.c have been followed, or a description of any changes and an explanation of why changes were necessary;

vii. description of any changes in the unit configuration prior to or during testing that would alter any of the information submitted in the prior notice of compliance testing under LAC 33:V.3007.C.2, and an explanation of why the changes were necessary;

viii. description of any changes in the planned test conditions prior to or during the testing that alter any of the information submitted in the prior notice of compliance testing under LAC 3007.C.2, and an explanation of why the changes were necessary; and

ix. the complete report on results of emissions testing;

b. specific information on each test including:

i. purpose(s) of test (e.g., demonstrate conformance with the emissions limits for particulate matter, metals, HCl, Cl₂, and CO);

ii. summary of test results for each run and for each test including the following information:

(a). date of run;

(b). duration of run;

(c). time-weighted average and highest hourly rolling average CO level for each run and for the test;

(d). highest hourly rolling average HC level, if HC monitoring is required for each run and for the test;

(e). if dioxin and furan testing is required under LAC 33:V.3009.E, time-weighted average emissions for each run and for the test of chlorinated dioxin and furan emissions, and the predicted maximum annual average ground level concentration of the toxicity equivalency factor;

(f). time-weighted average particulate matter emissions for each run and for the test;

(g). time-weighted average HCl and Cl₂ emissions for each run and for the test;

(h). time-weighted average emissions for the metals subject to regulation under LAC 33:V.3013 for each run and for the test; and

(i). QA/QC results;

c. comparison of the actual emissions during each test with the emissions limits prescribed by LAC 33:V.3009.B, C, and E, 3011, 3013, and 3015 and established for the facility in the certification of precompliance under LAC 33:V.3007.B;

d. determination of operating limits based on all valid runs of the compliance test for each applicable parameter listed in LAC 33:V.3007.C.1 using either of the following procedures:

i. Instantaneous Limits. A parameter may be measured and recorded on an instantaneous basis (i.e., the value that occurs at any time) and the operating limit specified as the time-weighted average during all runs of the compliance test; or

ii. Hourly Rolling Average Basis

(a). The limit for a parameter may be established and continuously monitored on an hourly rolling average basis defined as follows:

(i). a continuous monitor is one which continuously samples the regulated parameter without interruption, and evaluates the detector response at least once each 15 seconds, and computes and records the average value at least every 60 seconds;

(ii). an hourly rolling average is the arithmetic mean of the 60 most recent one-minute average values recorded by the continuous monitoring system;

(b). The operating limit for the parameter shall be established based on compliance test data as the average over all test runs of the highest hourly rolling average value for each run;

iii. Rolling Average Limits for Carcinogenic Metals and Lead. Feed rate limits for the carcinogenic metals (i.e., arsenic, beryllium, cadmium and chromium) and lead may be established either on an hourly rolling average basis as prescribed by LAC 33:V.3007.C.4.d.ii or on (up to) a 24-hour rolling average basis. If the owner or operator elects to use an averaging period from 2 to 24 hours:

(a). the feed rate of each metal shall be limited at any time to 10 times the feed rate that would be allowed on an hourly rolling average basis;

(b). the continuous monitor shall meet the following specifications:

(ii). the rolling average for the selected averaging period is defined as the arithmetic mean of one-hour block averages for the averaging period. A one-hour block average is the arithmetic mean of the one-minute averages recorded during the 60-minute period beginning at one minute after the beginning of preceding clock hour; and

(c). the operating limit for the feed rate of each metal shall be established based on compliance test data as the average over all test runs of the highest hourly rolling average feed rate for each run;

iv. Feed Rate Limits for Metals, Total Chloride and Chlorine, and Ash. Feed rate limits for metals, total chlorine and chloride, and ash are established and monitored by knowing the concentration of the substance (i.e., metals, chloride/chlorine, and ash) in each feedstream and the flow rate of the feedstream. To monitor the feed rate of these substances, the flow rate of each feedstream must be monitored under the continuous monitoring requirements of LAC 33:V.3007.C.4.d.i-iii;

e. Certification of Compliance Statement. The following statement shall accompany the certification of compliance.

"I certify under penalty of law that this information was prepared under my direction or supervision in accordance with a system designed to ensure that qualified personnel properly gathered and evaluated the information and supporting documentation. Copies of all emissions tests, dispersion modeling results and other information used to determine conformance with the requirements of LAC 33:V.3007.C are available at the facility and can be obtained from the facility contact person listed above. Based on my inquiry of the person or persons who manages the facility, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.

"I also acknowledge that the operating conditions established in this certification pursuant to LAC 33:V.3007.C.4.d are enforceable limits at which the facility can legally operate during interim status until a revised certification of compliance is submitted."

5. Special Requirements for HC Monitoring Systems. When an owner or operator is required to comply with the hydrocarbon (HC) controls provided by Clause A.5.a.iv of this Section or LAC 33:V.3009.C, a conditioned gas monitoring system may be used in conformance with specifications provided in 40 CFR 266, Appendix IX, as adopted and amended at LAC 33:V.3099.Appendix I, provided that the owner or operator submits a certification of compliance without using extensions of time provided by Paragraph C.7 of this Section.

6. Special Operating Requirements for Industrial Furnaces that Recycle Collected PM. Owners and operators of industrial furnaces that recycle back into the furnace particulate matter (PM) from the air pollution control system must:

a. when complying with the requirements of Paragraph C.7 of this Section, comply with the operating requirements prescribed in "Alternative Method to Implement the Metals Controls" in 40 CFR 266, Appendix IX, as adopted and amended at LAC 33:V.3099.Appendix I; and

b. when complying with the requirements of LAC 33:V.3007.C.3.b.ii, comply with the operating requirements prescribed by that paragraph.

7. Extensions of Time

a. If the owner or operator does not submit a complete certification of compliance for all of the applicable emissions standards of LAC 33:V.3009-3015 by August 21, 1992, he/she must either:

i. stop burning hazardous waste and begin closure activities under LAC 33:V.3007 for the hazardous waste portion of the facility; or

ii. limit hazardous waste burning only for purposes of compliance testing (and pretesting to prepare for compliance testing) a total period of 720 hours for the period of time beginning August 21, 1992, submit a notification to the administrative authority by August 21, 1992 stating that the facility is operating under restricted interim status and intends to resume burning hazardous waste, and submit a complete certification of compliance by August 23, 1993; or

iii. obtain a case-by-case extension of time under LAC 33:V.3007.C.7.b.

b. The owner or operator may request a case-by-case extension of time to extend any time limit provided by LAC 33:V.3007.C if compliance with the time limit is not practicable for reasons beyond the control of the owner or operator.

i. In granting an extension, the administrative authority may apply conditions as the facts warrant to ensure timely compliance with the requirements of this Section and that the facility operates in a manner that does not pose a hazard to human health and the environment.

ii. When an owner or operator requests an extension of time to enable the facility to comply with the alternative hydrocarbon provisions of LAC 33:V.3009.F and to obtain a RCRA operating permit because the facility cannot meet the HC limit of LAC 33:V.3009.C, the administrative authority shall, in considering whether to grant the extension:

(a). determine whether the owner or operator has submitted in a timely manner a complete Part B permit application that includes information required under LAC 33:V.535; and

(b). consider whether the owner or operator has made a good faith effort to certify compliance with all other emission controls, including the controls on dioxins and furans of LAC 33:V.3009.E and the controls on PM, metals, and HCl/Cl₂.

iii. If an extension is granted, the administrative authority shall, as a condition of the extension, require the facility to operate under flue gas concentration limits on CO and HC that, based on available information, including information in the Part B permit application, are baseline CO and HC levels as defined by LAC 33:V.3009.F.1.

8. Revised Certification of Compliance. The owner or operator may submit at any time a revised certification of compliance (recertification of compliance) to the Office of Environmental Services under the following procedures:

a. prior to submittal of a revised certification of compliance, hazardous waste may not be burned for more than a total of 720 hours under operating conditions that exceed those established under a current certification of compliance, and such burning may be conducted only for purposes of determining whether the facility can operate under revised conditions and continue to meet the applicable emissions standards of LAC 33:V.3009-3015;

b. at least 30 days prior to first burning hazardous waste under operating conditions that exceed those established under a current certification of compliance, the owner or operator shall notify the Office of Environmental Services and submit the following information:

i. EPA facility ID number, and facility name, contact person, telephone number, and address;

ii. operating conditions that the owner or operator is seeking to revise and description of the changes in facility design or operation that prompted the need to seek to revise the operating conditions;

iii. a determination that when operating under the revised operating conditions, the applicable emissions standards of LAC 33:V.3009-3015 are not likely to be exceeded. To document this determination, the owner or operator shall submit the applicable information required under LAC 33:V.3007.B.2; and

iv. complete emissions testing protocol for any pretesting and for a new compliance test to determine compliance with the applicable emissions standards of LAC 33:V.3009-3015 when operating under revised operating conditions. The protocol shall include a schedule of pre-testing and compliance testing. If the owner and operator revises the scheduled date for the compliance test, he/she shall notify the Office of Environmental Services in writing at least 30 days prior to the revised date of the compliance test;

c. conduct a compliance test under the revised operating conditions and the protocol submitted to the administrative authority to determine compliance with the applicable emissions standards of LAC 33:V.3009-3015; and

d. submit to the Office of Environmental Services a revised certification of compliance under Paragraph C.4 of this Section.

D. Periodic Recertifications. The owner or operator must conduct compliance testing and submit to the Office of Environmental Services a recertification of compliance under provisions of Subsection C of this Section within five years from submitting the previous certification or recertification. If the owner or operator seeks to recertify compliance under new operating conditions, he/she must comply with the requirements of Paragraph C.8 of this Section.

E. Noncompliance with Certification Schedule. If the owner or operator does not comply with the interim status compliance schedule provided by LAC 33:V.3007.B-D, hazardous waste burning must terminate on the date that the deadline is missed, closure activities must begin under LAC 33:V.3007, and hazardous waste burning may not resume except under an operating permit issued under LAC 33:V.537. For purposes of compliance with the closure provisions of LAC 33:V.3007.L, 4381.D.2, and 4383, the boiler or industrial furnace has received "the known final volume of hazardous waste" on the date that the deadline is missed.

F. Start-Up and Shutdown. Hazardous waste (except waste fed solely as an ingredient under the Tier I, or adjusted Tier I, feed rate screening limits for metals and chloride/chlorine) must not be fed into the device during start-up and shutdown of the boiler or industrial furnace, unless the device is operating within the conditions of operation specified in the certification of compliance.

G. Automatic Waste Feed Cutoff. During the compliance test required by LAC 33:V.3007.C.3, and upon certification of compliance under LAC 33:V.3007.C, a boiler or industrial furnace must be operated with a functioning system that automatically cuts off the hazardous waste feed when the applicable operating conditions specified in LAC 33:V.3007.C.1.a and e-m deviate from those established in the certification of compliance. In addition:

1. to minimize emissions of organic compounds, the minimum combustion chamber temperature (or the indicator of combustion chamber temperature) that occurred during the compliance test must be maintained while hazardous waste or hazardous waste residues remain in the combustion chamber, with the minimum temperature during the compliance test defined as either:

a. if compliance with the combustion chamber temperature limit is based on an hourly rolling average, the minimum temperature during the compliance test is considered to be the average over all runs of the lowest hourly rolling average for each run; or

b. if compliance with the combustion chamber temperature limit is based on an instantaneous temperature measurement, the minimum temperature during the compliance test is considered to be the time-weighted average temperature during all runs of the test; and

2. operating parameters limited by the certification of compliance must continue to be monitored during the cutoff, and the hazardous waste feed shall not be restarted until the levels of those parameters comply with the limits established in the certification of compliance.

H. Fugitive Emissions. Fugitive emissions must be controlled by:

1. keeping the combustion zone totally sealed against fugitive emissions; or

2. maintaining the combustion zone pressure lower than atmospheric pressure; or

3. an alternate means of control that the owner or operator can demonstrate provides fugitive emissions control equivalent to maintenance of combustion zone pressure lower than atmospheric pressure. Support for such demonstration shall be included in the operating record.

I. Changes. A boiler or industrial furnace must cease burning hazardous waste when changes in combustion properties, or feed rates of the hazardous waste, other fuels, or industrial furnace feedstocks, or changes in the boiler or industrial furnace design or operating conditions deviate from the limits specified in the certification of compliance.

J. Monitoring and Inspections

1. The owner or operator must monitor and record, at a minimum, the following while burning hazardous waste:

a. feed rates and composition of hazardous waste, other fuels, and industrial furnace feedstocks, and feed rates of ash, metals, and total chloride and chlorine as necessary to ensure conformance with the certification of precompliance or certification of compliance;

b. carbon monoxide (CO), oxygen, and if applicable, hydrocarbons (HC) must be monitored on a continuous basis at a common point in the boiler or industrial furnace downstream of the combustion zone and prior to release of stack gases to the atmosphere in accordance with the operating limits specified in the certification of compliance. CO, HC and oxygen monitors must be installed, operated, and maintained in accordance with methods specified in 40 CFR 266, Appendix IX, as adopted and amended at LAC 33:V.3099.Appendix I;

c. upon the request of the administrative authority, sampling and analysis of the hazardous waste (and other fuels and industrial furnace feedstocks as appropriate) and the stack gas emissions must be conducted to verify that the operating conditions established in the certification of precompliance or certification of compliance achieve the applicable standards of LAC 33:V.3009-3015.

2. The boiler or industrial furnace and associated equipment (pumps, valves, pipes, fuel, storage tanks, etc.) must be subjected to thorough visual inspection at least daily when hazardous waste is burned for leaks, spills, fugitive emissions, and signs of tampering.

3. The automatic hazardous waste feed cutoff system and associated alarms must be tested at least once every seven days when hazardous waste is burned to verify operability, unless the owner or operator has written documentation that weekly inspections will unduly restrict or upset operations and that less frequent inspections will be adequate, and the administrative authority approves less frequent inspections or testing. Support for such demonstration shall be included in the operating record. At a minimum, operational testing must be conducted at least monthly.

4. These monitoring and inspection data must be recorded and the records must be placed in the operating log.

K. Recordkeeping. The owner or operator must keep in the operating record of the facility all information and data required by this Section for five years.

L. Closure. At closure, the owner or operator must remove all hazardous waste and hazardous waste residues (including, but not limited to, ash, scrubber waters, and scrubber sludges) from the boiler or industrial furnace site and must comply with LAC 33:V.3023-3025.

La. Admin. Code tit. 33, § V-3007

Promulgated by the Department of Environmental Quality, Office of Solid and Hazardous Waste, Hazardous Waste Division, LR 18:1375 (December 1992), amended LR 21:266 (March 1995), LR 22:822 (September 1996), amended by the Office of Waste Services, Hazardous Waste Division, LR 24:1740 (September 1998), amended by the Office of Environmental Assessment, Environmental Planning Division, LR 26:2483 (November 2000), amended by the Office of the Secretary, Legal Affairs Division, LR 31:2463 (October 2005), LR 33:2114 (October 2007), LR 34:629 (April 2008), LR 34:999 (June 2008).

AUTHORITY NOTE: Promulgated in accordance with R.S. 30:2180 et seq.