Section 327 IAC 8-2-5.1 - Collection of samples for organic chemical testing other than volatile organic compounds and total trihalomethanesAuthority: IC 13-13-5; IC 13-14-8-7; IC 13-14-9; IC 13-18-3; IC 13-18-16
Affected: IC 13-18
Sec. 5.1.
To determine compliance with section 5(a) of this rule, collection of samples for organic chemical testing, other than volatile organic compounds and TTHMs, shall be made as follows:
(1) Ground water systems shall take a minimum of one (1) sample at every entry point to the distribution system that is representative of each well after treatment (hereafter called a sampling point). Each sample must be taken at the same sampling point unless conditions make another sampling point more representative of each source or treatment plant.(2) Surface water systems, including those systems with a combination of surface and ground sources, shall take a minimum of one (1) sample at points in the distribution system that are representative of each source or at each entry point to the distribution system after treatment (hereafter called a sampling point). Each sample must be taken at the same sampling point unless conditions make another sampling point more representative of each source or treatment plant.(3) If the system draws water from more than one (1) source and the sources are combined before distribution, the system must sample at an entry point to the distribution system during periods of normal operating conditions, such as when water representative of all sources is being used.(4) The monitoring frequency is as follows:(A) Each CWS and NTNCWS shall take four (4) consecutive quarterly samples for each contaminant listed in section 5(a) of this rule during each compliance period beginning with the initial compliance period.(B) Systems serving more than three thousand three hundred (3,300) persons that do not detect a contaminant in the initial compliance period may reduce the sampling frequency to a minimum of two (2) quarterly samples in one (1) year during each repeat compliance period.(C) Systems serving less than or equal to three thousand three hundred (3,300) persons that do not detect a contaminant in the initial compliance period may reduce the sampling frequency to a minimum of one (1) sample during each repeat compliance period.(5) Each CWS and NTNCWS may apply to the commissioner for a waiver from the requirement of subdivision (4). A system must reapply for a waiver for each compliance period.(6) The commissioner may grant a waiver after evaluating the knowledge of previous use, including transport, storage, or disposal of the contaminant within the watershed or zone of influence of the system. If a determination by the commissioner reveals no previous use of the contaminant within the watershed or zone of influence, a waiver may be granted. If previous use of the contaminant is unknown or it has been used previously, then the following factors shall be used to determine whether a waiver is granted:(A) Previous analytical results.(B) The proximity of the system to a potential point or nonpoint source of contamination. (Point sources include spills and leaks of chemicals at or near a water treatment facility or at manufacturing, distribution, or storage facilities, or from hazardous and municipal waste landfills and other waste handling or treatment facilities. Nonpoint sources include the use of pesticides to control insect and weed pests on agricultural areas, forest lands, home and gardens, and other land application uses).(C) The environmental persistence and transport of the pesticide or polychlorinated biphenyls (PCBs).(D) How well the water source is protected against contamination due to such factors as: (ii) the type of soil; and(iii) the integrity of the well casing.(E) Elevated nitrate levels at the water supply source.(F) Use of PCBs in equipment used in the production, storage, or distribution of water, including, but not limited to, PCBs used in pumps or transformers.(7) If an organic contaminant listed in section 5(a) of this rule is detected as defined by subdivision (16), in any sample, then the monitoring requirements are as follows: (A) Each system must monitor quarterly at each sampling point that resulted in a detection.(B) The commissioner may decrease the quarterly monitoring requirement specified in clause (A) provided it has determined that the system is reliably and consistently below the MCL. In no case shall the commissioner make this determination unless a ground water system takes a minimum of two (2) quarterly samples and a surface water system takes a minimum of four (4) quarterly samples.(C) After the commissioner determines the system is reliably and consistently below the MCL, the commissioner may allow the system to monitor annually. Systems that monitor annually must monitor during the quarter that previously yielded the highest analytical result.(D) Systems that have three (3) consecutive annual samples with no detection of contaminant may apply to the commissioner for a waiver as specified in subdivision (6).(E) If monitoring results in detection of one (1) or more of certain related contaminants: (v) heptachlor epoxide; then subsequent monitoring shall include analyses for all related contaminants.
(8) Systems that violate section 5(a) of this rule as determined by subdivision (11) must monitor quarterly. After a minimum of four (4) quarterly samples shows the system is in compliance and the commissioner determines the system is reliably and consistently below the MCL, as specified in subdivision (11), the system shall monitor at the frequency specified in subdivision (7)(C).(9) The commissioner may require a confirmation sample for positive or negative results. If a confirmation sample is required by the commissioner, the result must be averaged with the first sampling result and the average used for the compliance determination as specified in subdivision (11). The commissioner has the discretion to delete results of obvious sampling errors from this calculation.(10) The commissioner may reduce the total number of samples a system must analyze by allowing the use of compositing. Composite samples from a maximum of five (5) sampling points are allowed, provided that the detection limit of the method used for analysis is less than one-fifth (1/5) of the MCL. Compositing of samples must be done in the laboratory and analyzed within fourteen (14) days of sample collection in accordance with the following: (A) When a composite sample is analyzed, if the concentration in the composite sample detects one (1) or more contaminants listed in section 5(a) of this rule, then a follow-up sample must be analyzed within fourteen (14) days from each sampling point included in the composite and analyzed for that contaminant.(B) If duplicates of the original sample taken from each sampling point used in the composite samples are available, the system may use these instead of resampling. The duplicates must be analyzed and the results reported to the commissioner within fourteen (14) days after completion of the composite analysis or before the holding time for the initial sample is exceeded, whichever is sooner.(C) If the population served by the system is greater than three thousand three hundred (3,300) persons, then compositing may only be permitted by the commissioner at sampling points within a single system. In systems serving less than or equal to three thousand three hundred (3,300) persons, the commissioner may permit compositing among different systems provided the five (5) sample limit is maintained.(11) Compliance with section 5(a) of this rule shall be determined such that, if one (1) sampling point is in violation of an MCL, the system is in violation of the MCL and based on the analytical results obtained at each sampling point in the following manner: (A) For systems that are conducting monitoring at a frequency greater than annual, compliance is determined by a running annual average of all samples taken at each sampling point.(B) Systems monitoring annually, or less frequently, whose sample results exceed the regulatory detection level as specified in subdivision (16) must begin quarterly sampling. The system will not be considered in violation of the MCL until it has completed one (1) year of quarterly sampling.(C) If any sample result will cause the running annual average to exceed the MCL at any sampling point, the system is out of compliance with the MCL immediately.(D) If a system fails to collect the required number of samples, compliance will be based on the total number of samples collected.(E) If a sample result is less than the detection limit, zero (0) will be used to calculate the annual average.(12) If monitoring data collected after January 1, 1990, are generally consistent with this section and section 5.2 of this rule, then the commissioner may allow systems to use that data to satisfy the monitoring requirement for the initial compliance period.(13) The commissioner may increase the required monitoring frequency, where necessary, to detect variations within the system such as fluctuations in concentration due to seasonal use and changes in water source.(14) The commissioner has the authority to determine compliance or initiate enforcement action based upon analytical results and other information compiled by the commissioner's sanctioned representatives or agencies, or both.(15) Each public water system shall monitor at the time designated by the commissioner within each compliance period.(16) Method detection levels for contaminants listed in section 5(a) of this rule are as follows: | Contaminant | Detection Limit (mg/l) |
| Alachlor | 0.0002 |
| Atrazine | 0.0001 |
| Benzo[a]pyrene | 0.00002 |
| Carbofuran | 0.0009 |
| Chlordane | 0.0002 |
| Dalapon | 0.001 |
| 1,2-dibromo-3-chloropropane (DBCP) | 0.00002 |
| Di(2-ethylhexyl)adipate | 0.0006 |
| Di(2-ethylhexyl)phthalate | 0.0006 |
| Dinoseb | 0.0002 |
| Diquat | 0.0004 |
| 2,4-D | 0.0001 |
| Endothall | 0.009 |
| Endrin | 0.00001 |
| Ethylene dibromide (EDB) | 0.00001 |
| Glyphosate | 0.006 |
| Heptachlor | 0.00004 |
| Heptachlor epoxide | 0.00002 |
| Hexachlorobenzene | 0.0001 |
| Hexachlorocyclopentadiene | 0.0001 |
| Lindane | 0.00002 |
| Methoxychlor | 0.0001 |
| Oxamyl | 0.002 |
| Picloram | 0.0001 |
| Polychlorinated biphenyls (PCBs) (as decachlorobiphenyl) | 0.0001 |
| Pentachlorophenol | 0.00004 |
| Simazine | 0.00007 |
| Toxaphene | 0.001 |
| 2,3,7,8-TCDD (dioxin) | 0.000000005 |
| 2,4,5-TP (silvex) | 0.0002 |
(17) All new systems or systems that use a new source of water that begin operation after January 1, 2004, must demonstrate compliance with the MCL within a period of time specified by the commissioner. The system must also comply with the initial sampling frequencies specified by the commissioner to ensure a system can demonstrate compliance with the MCL. Routine and increased monitoring frequencies shall be conducted in accordance with the requirements in this section.Water Pollution Control Board; 327 IAC 8-2-5.1; filed Dec 28, 1990, 5:10 p.m.: 14 IR 1010; filed Aug 24, 1994, 8:15 a.m.: 18 IR 33; errata filed Oct 11, 1994, 2:45 p.m.: 18 IR 531; filed Aug 25, 1997, 8:00 a.m.: 21 IR 44; filed Apr 21, 1999, 3:22 p.m.: 22 IR 2862; errata filed Apr 28, 1999, 6:36 p.m.: 22 IR 2883; filed Jul 23, 2001, 1:02 p.m.: 24 IR 3953; filed Nov 20, 2001, 10:20 a.m.: 25 IR 1084; filed Jun 13, 2005, 2:30 p.m.: 28 IR 3198