Ill. Admin. Code tit. 35, pt. 742, subpt. L, app C, tbl. D

Current through Register Vol. 48, No. 44, November 1, 2024
Table D - RBCA Parameters

Symbol

Parameter

Units

Source

Parameter Value(s)

ATc

Averaging Time for Carcinogens

yr

RBCA

70

ATn

Averaging Time for Noncarcinogens

yr

RBCA

Residential = 30

Industrial/Commercial = 25

Construction Worker = 0.115

BW

Adult Body Weight

kg

RBCA

70

Csource

The greatest potential concentration of the contaminant of concern in the groundwater at the source of the contamination, based on the concentrations of contaminants in groundwater due to the release and the projected concentration of the contaminant migrating from the soil to the groundwater.

mg/L

Field Measurement

Site-Specific

C(x)

Concentration of Contaminant in Groundwater at Distance X form the source

mg/L

Equation R26 in Appendix C, Table C

Calculated Value

C(x)/Csource

Steady-State Attenuation Along the Centerline of a Dissolved Plume

unitless

Equation R15 in Appendix C, Table C

Calculated Value

d

Lower Depth of Surficial Soil Zone

cm

Field Measurement

100 or Site-Specific (not to exceed 100)

Dair

Diffusion Coefficient in Air

cm2/s

Appendix C, Table E

Chemical-Specific

Dwater

Diffusion Coefficient in Water

cm2/s

Appendix C, Table E

Chemical-Specific

Symbol

Parameter

Units

Source

Parameter Value(s)

Dseff

Effective Diffusion Coefficient in Soil Based on Vapor-Phase Concentration

cm2/s

Equation R6 in Appendix C, Table C

Calculated Value

ED

Exposure Duration

yr

RBCA

Residential = 30

Industrial/Commercial = 25

Construction Worker = 1

EF

Exposure Frequency

d/yr

RBCA

Residential = 350

Industrial/Commercial = 250

Construction Worker = 30

erf

Error Function

unitless

Appendix C, Table G

Mathematical Function

foc

Organic Carbon Content of Soil

g/g

RBCA or Field Measurement (See Appendix C, Table F)

Surface Soil = 0.006

Subsurface Soil = 0.002 or

Site-Specific

GWcomp

Groundwater Objective at the Compliance Point

mg/L

Appendix B, Table E, 35 IAC 620.Subpart F, or Equation R25 in Appendix C, Table C

Site-Specific

GWsource

Groundwater Concentration at the Source

mg/L

Equation R13 in Appendix C, Table C

Calculated Value

H'

Henry's Law Constant

cm3water/cm3air

Appendix C, Table E

Chemical-Specific

i

Hydraulic Gradient

cm/cm (unitless)

Field Measurement (See Appendix C, Table F)

Site-Specific

I

Infiltration Rate

cm/yr

RBCA

30

IRair

Daily Outdoor Inhalation Rate

m3/d

RBCA

20

IRsoil

Soil Ingestion Rate

mg/d

RBCA

Residential = 100

Industrial/Commercial = 50

Construction Worker = 480

IRw

Daily Water Ingestion Rate

L/d

RBCA

Residential = 2

Industrial/Commercial = 1

K

Aquifer Hydraulic Conductivity

cm/d for Equations R15, R19 and R26 cm/yr for Equation R24

Field Measurement (See Appendix C, Table F)

Site-Specific

Koc

Organic Carbon Partition Coefficient

cm3/g or L/kg

Appendix C, Table E or Appendix C, Table I

Chemical-Specific

Symbol

Parameter

Units

Source

Parameter Value(s)

ks (non-ionizing organics)

Soil Water Sorption Coefficient

cm3water/gsoil

Equation R20 in Appendix C, Table C

Calculated Value

ks (ionizing organics)

Soil Water Sorption Coefficient

cm3water/gsoil

Equation R20 in Appendix C, Table C

Chemical and pH-Specific (See Appendix C, Table I)

ks (inorganics)

Soil Water Sorption Coefficient

cm3water/gsoil

Appendix C, Table J

Chemical and pH-Specific

Ls

Depth to Subsurface Soil Sources

cm

RBCA

100

LFsw

Leaching Factor

(mg/Lwater)/ (mg/kgsoil)

Equation R14 in Appendix C, Table C

Calculated Value

M

Soil to Skin Adherence Factor

mg/cm2

RBCA

0.5

Pe

Particulate Emission Rate

g/cm2-s

RBCA

6.9 * 10-14

RAFd

Dermal Relative Absorption Factor

unitless

RBCA

0.5

RAFd (PNAs)

Dermal Relative Absorption Factor

unitless

RBCA

0.05

RAFd (inorganics)

Dermal Relative Absorption Factor

unitless

RBCA

0

RAFo

Oral Relative Absorption Factor

unitless

RBCA

1.0

RBSLair

Carcinogenic Risk-Based Screening Level for Air

µg/m3

Equation R9 in Appendix C, Table C

Chemical-, Media-, and Exposure Route-Specific

RBSLair

Noncarcinogenic Risk-Based Screening Level for Air

µg/m3

Equations R10 in Appendix C, Table C

Chemical-, Media-, and Exposure Route-Specific

RfDi

Inhalation Reference Dose

mg/kg-d

IEPA (IRIS/HEASTa)

Toxicological-Specific

RfDo

Oral Reference Dose

mg/(kg-d)

IEPA (IRIS/HEASTa)

Toxicological-Specific (Note: for Construction Worker use subchronic reference doses)

SA

Skin Surface Area

cm2/d

RBCA

3,160

Symbol

Parameter

Units

Source

Parameter Value(s)

Sd

Source Width Perpendicular to Groundwater Flow Direction in Vertical Plane

cm

Field Measurement

For Migration to Groundwater Route: Use 200 or Site-Specific

For Groundwater remediation objective: Use Site-Specific

Sw

Source Width Perpendicular to Groundwater Flow Direction in Horizontal Plane

cm

Field Measurement

Site-Specific

SFi

Inhalation Cancer Slope Factor

(mg/kg-d)-1

IEPA (IRIS/HEASTa)

Toxicological-Specific

SFo

Oral Slope Factor

(mg/kg-d)-1

IEPA (IRIS/HEASTa)

Toxicological-Specific

THQ

Target Hazard Quotient

unitless

RBCA

1

TR

Target Cancer Risk

unitless

RBCA

Residential = 10-6 at the point of human exposure

Industrial/Commercial = 10-6 at the point of human exposure

Construction Worker = 10-6 at the point of human exposure

U

Specific Discharge

cm/d

Equation R19 in Appendix C, Table C

Calculated Value

Uair

Average Wind Speed Above Ground Surface in Ambient Mixing zone

cm/s

RBCA

225

[MU]gw

Groundwater Darcy Velocity

cm/yr

Equation R24 in Appendix C, Table C

Calculated Value

VFp

Volatilization Factor for Surficial Soils Regarding Particulates

kg/m3

Equation R5 in Appendix C, Table C

Calculated Value

VFsamb

Volatilization Factor (Subsurface Soils to Ambient Air)

(mg/m3air)/(mg/kgsoil) or kg/m3

Equation R11 in Appendix C, Table C

Calculated Value

Symbol

Parameter

Units

Source

Parameter Value(s)

VFss

Volatilization Factor for Surficial Soils

kg/m3

Use Equations R3 and R4 in Appendix C, Table C

Calculated Value from Equation R3 or R4 (whichever is less)

W

Width of Source Area Parallel to Direction to Wind or Groundwater Movement

cm

Field Measurement

Site-Specific

w

Average Soil Moisture Content

gwater/gsoil

RBCA or Field Measurement (See Appendix C, Table F)

0.1, or

Surface Soil (top 1 meter) = 0.1

Subsurface Soil (below 1 meter) = 0.2, or

Site-Specific

X

Distance along the Centerline of the Groundwater Plume Emanating from a Source. The x direction is the direction of groundwater flow

cm

Field Measurement

Site-Specific

[ALPHA]x

Longitudinal Dispersivity

cm

Equation R16 in Appendix C, Table C

Calculated Value

[ALPHA]y

Transverse Dispersivity

cm

Equation R17 in Appendix C, Table C

Calculated Value

[ALPHA]z

Vertical Dispersivity

cm

Equation R18 in Appendix C, Table C

Calculated Value

[DELTA]air

Ambient Air Mixing Zone Heights

cm

RBCA

200

[DELTA]gw

Groundwater Mixing Zone Thickness

cm

RBCA

200

[THETA]as

Volumetric Air Content in Vadose Zone Soils

cm3air/cm3soil

RBCA or Equation R21 in Appendix C, Table C

Surface Soil (top 1 meter) = 0.28

Subsurface Soil (below 1 meter) = 0.13, o r

Gravel = 0.05

Sand = 0.14

Silt = 0.16

Clay = 0.17, or

Calculate Value

Symbol

Parameter

Units

Source

Parameter Value(s)

[THETA]ws

Volumetric Water Content in Vadose Zone Soils

cm3water/cm3soil

RBCA or Equation R22 in Appendix C, Table C

Surface Soil (top 1 meter) = 0.15

Subsurface Soil (below 1 meter) = 0.30, or

Gravel = 0.20

Sand = 0.18

Silt = 0.16

Clay = 0.17, or

Calculated Value

[THETA]T

Total Soil Porosity

cm3/cm3soil

RBCA or Equation R23 in Appendix C, Table C

0.43, or

Gravel = 0.25

Sand = 0.32

Silt = 0.40

Clay = 0.36, or

Calculated Value

[LAMBDA]

First Order Degradation Constant

d-1

Appendix C, Table E

Chemical-Specific

[PI]

pi

3.1416

[RHO]s

Soil Bulk Density

g/cm3

RBCA or Field Measurement (See Appendix C, Table F)

1.5, or

Gravel = 2.0

Sand = 1.8

Silt = 1.6

Clay = 1.7, or

Site-Specific

[RHO]w

Water Density

g/cm3

RBCA

1

[TAU]

Averaging Time for Vapor Flux

s

RBCA

9.46 * 108

Ill. Admin. Code tit. 35, pt. 742, subpt. L, app C, tbl. D

Amended at 31 Ill. Reg. 4063, effective February 23, 2007