Ill. Admin. Code tit. 35 § 219.111

Current through Register Vol. 48, No. 49, December 6, 2024

Section 219.111 - Vapor Pressure of Volatile Organic Material

a) If the VOM consists of only a single compound, the vapor pressure shall be determined by ASTM Method D2879-86 (incorporated by reference in Section 219.112 of this Part) or the vapor pressure may be obtained from a publication such as: Boublik, T., B. Fried and E. Hala, "The Vapor Pressure of Pure Substances," Elsevier Scientific Publishing Co., New York (1973); Perry's Chemical Engineer's Handbook, McGraw-Hill Book Company (1984); CRC Handbook of Chemistry and Physics, Chemical Rubber Publishing Company (1986-87); and Lange's Handbook of Chemistry, John A. Dean, editor, McGraw-Hill Book Company (1985).

b) If the VOM is in a mixture made up of both VOM compounds and compounds which are not VOM, the vapor pressure shall be determined by the following equation:

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where:

Pvom	=	Total vapor pressure of the portion of the mixture which is composed of VOM;
n	=	Number of VOM components in the mixture;
i	=	Subscript denoting an individual component;
Pi	=	Vapor pressure of a VOM component determined in accordance with subsection (a) of this Section;
Xi	=	Mole fraction of the VOM component of the total organic mixture.

c) If the VOM is in a mixture made up on only VOM compounds, the vapor pressure shall be determined by ASTM Method D2879-86 (incorporated by reference in Section 219.112 of this Part) or by the above equation.

Ill. Admin. Code tit. 35, § 219.111

Amended at 20 Ill. Reg. 14462, effective October 28, 1996