. Greater than 0 but less than 290 - once per year
. Equal to or greater than 290 but less than 1,500 - once per quarter (four times a year)
. Equal to or greater than 1,500 but less than 15,000 - once per 60 days (six times per year)
. Equal to or greater than 15,000 - once per month (12 times per year)
Table 72.1-1. Estimated Percentages and Amounts of Organic N Mineralized After Sludge of Various Types are Applied to Soils
TimeAftersludgeApplic.(years) | Unstabilized Primaryand Waste Activated | Aerobically Digested | Anaerobically Digested | Composted | ||||
F% No* | Km kg/mt/%No | F % No | Km kg/mt/%No | F % No | Km kg/mt/%No | F % No | Km kg/mt/%No | |
0-11-22-33-44-55-66-77-88-99-1010-yrsteadystate | 402010533333393 | 4.00 1.20 0.48 0.22 0.12 0.12 0.12 0.11 0.11 0.11 | 30 15 8 4 3 3 3 3 3 3 75 | 3.00 1.05 0.45 0.21 0.16 0.15 0.15 0.15 0.15 0.15 | 20 10 5 3 3 3 3 3 3 3 56 | 2.00 0.80 0.36 0.21 0.20 0.19 0.19 0.18 0.18 0.17 | 10 5 3 3 3 3 3 3 3 3 39 | 1.00 0.45 0.25 0.25 0.24 0.23 0.23 0.22 0.21 0.21 |
*Percentage of organic N (No) present mineralized during time interval shown.
kg N released per metric ton of sludge applied per % organic N in the sludge. For example, application of an anaerobically digested sludge containing 3% organic N at 10 mt/ha would result in the following amounts of N mineralization: year 0, 3% No x 10 mt/ha x 2.0 = 60 kg N/ha; year 1 3% No x 10 mt/ha x 0.80 = 24 kg N/ha; year 2, 3% No x 10 mt/ha x 0.36 = 10.8 kg N/ha.
Multiply kg/mt by 2 to obtain lbs./ton.
N
0.0026
Where:
AAR = Annual application rate in gallons per acre per 365 day period.
N = Amount of nitrogen in pounds per acre per 365 day period needed by the crop or vegetation grown on the land.
Equation (1): Np = S [No3-) + Kv (NH4+) + F (No)](10)
Where:
Np = Plant available N from the current year's sludge application only.
S = Sludge application rate (dry mt tons/ha).
No3- = Percent nitrate-N in sludge (as percent, e.g. 1% = 1.0).
Kv = Volatilization factor = 0.5 for surface applied liquid sludge, or 1.0 for incorporated liquid sludge and dewatered sludge applied in any manner.
NH4+ = Percent ammonia-N in the sludge, as percent (e.g. 3% = 3.0).
F = Organic Nitrogen mineralization factor (year 0-1) from Table 702.1 (percentage expressed as a fraction e.g. 20% = .20).
No = Percent organic nitrogen in the sludge (as percent e.g. 3% = 3.0).
Equation (2): Nm = (Km)(No)(s)
Where:
Nm = The quantity of N mineralized in the year under consideration, in kg/ha.
Km = Mineralization factor for the year under consideration from Table 702.1 (in kg/mt/%No).
No = Percent organic N originally present in the sludge (as percent e.g. 3% = 3.0).
S = Sludge Application rate (mt/ha) in the year under consideration.
Surface Subsurface
Application Injection
Occupied off-site dwelling 200 feet 100 feet
Occupied on-site dwelling 100 feet 50 feet
Potable wells 100 feet 100 feet
Non-potable wells 25 feet 25 feet
Public roads 25 feet 15 feet
Property lines 50 feet 25 feet
Bedrock outcrops 50 feet 25 feet
Streams, tidal waters, or 50 feet 25 feet
other water bodies
Drainage ditches 25 feet 25 feet
Sludge Type Percent Solids
Liquid Less than 15
Cake 15 - 35
Dried Greater than 35
An applicant for a Permit to transport sludge or septage in the State shall submit copies of the following information along with the initial application forms supplied by the Department:
The Department recognizes that sludge analysis is difficult due to the inherent complexity of sludge matrices. Sludge is rich in organic matter and highly variable in physical and chemical properties. However, sampling accuracy can be greatly enhanced if the correct protocol is established for the collection, storage, transportation, and analysis of the sludge sample. The Department may reject the method of analysis if it determines that the method of analysis is inaccurate, or for any other good cause.
The applicant must receive Department approval prior to execution of this program.
The Department may establish a schedule of annual and/or one-time fees with respect to sludge treatment, storage, transportation, land application/treatment, and distribution. This fee schedule may be revised from time-to-time after notice and opportunity for hearing.
Fee Payment.
One time fees shall be submitted to the Department at the time of application. Fees shall be submitted to the Department upon receipt of notice from the Department, or in accordance with the following fee payment schedule:
Fee Amount Payment Schedule
Less than $1,000 Upon receipt of notice from the Department
Between $1,000 and $10,000 Quarterly payments
Over $10,000 Monthly payments
The Department shall impose late charges at the rate of 1 percent per month, compounded, for any fee not received within 30 days of the due date.
Failure to pay fees shall constitute grounds for denial of subsequent applications for Permits, and revocation of previously issued permits involving sludge from the applicant.
Part V
LAND TREATMENT OF WASTE PRODUCTS
This document provides regulations for all people engaged in the handling, marketing or agricultural utilization of non-hazardous waste products generated by industrial or commercial activities which will be utilized in agricultural or horticultural setting as a fertilizer or soil amendment agent. Materials subject to regulations under RCRA, TOSCA or other federal or state regulatory programs governing hazardous wastes are not included in the scope of these regulations. Nor do manures, waste vegetables or other materials produced under agricultural settings, or products of materials currently regulated or managed by the Delaware Department of Agriculture for use by farmers in agricultural activities.
The Delaware Department of Natural Resources and Environmental Control encourages the reuse of utilization of waste products as a viable alternative to disposal or incineration where appropriate. The regulations outlined herein apply to waste products that, because of their physical, chemical or biological characterization, may be used as soil conditioners or as substitutes to commercial fertilizers in agricultural settings.
"Agricultural land" means land cultivated for the production of crops or used for raising livestock.
"Agricultural utilization" means the application rate of wastes products which shall not exceed nutrient needs of the crop grown on the particular soil plus the other assimilative pathways in soils (e.g. immobilization with organic material, volatilization, and leachate in compliance with drinking water standards). The department may require a lower application rate if the design criteria for pathogens, metals or organics contained in these Regulations plus generally accepted technical standards for land treatment technology (e.g. U.S. EPA Process Design Manuals or Overcash, M.R. and P. Pal. 1979 Design of Land Treatment Systems for Industrial Wastes - Theory and Practice) cannot be achieved at the above application rate. This term may be used interchangeably with "agronomic rate".
"Agricultural wastes" means wastes normally associated with the production and processing of food and fiber on farms, feedlots, ranches, ranges and forests which may include animal manure, crop residues and dead animals; also agricultural chemicals, fertilizers and pesticides which may find their way into surface and subsurface and subsurface water.
"Collection" means any action involved in the gathering or subsequent placement of waste products into a vehicle, container or any other vessel for transportation to some other location.
"Crops for direct human consumption" means crops that are consumed by humans without processing to minimize pathogens before distribution to the consumer.
"Department" means the Department of Natural Resources and Environmental Control.
"Disposal" means the discharge, deposit, injection, dumping, spilling, leaking or placing of waste products on or in the land, the air or any waters, including ground water and includes any method of waste products utilization that involves reuse of nutrients in the waste product at greater than agronomic rates.
"Distribute" means to barter, sell, offer for sale, consign, furnish, provide or otherwise supply a material as part of a commercial enterprise or a giveaway program.
"Food chain crops" means tobacco, crops grown for human consumption and crops grown to feed animals whose products are consumed by humans.
"Handling" means any way in which waste products are dealt with, other than collection, burning, storage, treatment, land application, disposal or transportation. It includes distribution of waste products.
"Household waste" means waste derived from households (including single and multiple residences, hotels and motels, bunkhouses, ranger stations, crew quarters, campgrounds and day-use recreation areas) which is not sewage or septage.
"Impermeable" means having a hydraulic conductivity equal to or less than 1 x 10-7 cm/sec as determined by field and laboratory permeability tests made according to standard test methods which may be correlated with soil densification as determined by compaction tests.
"Label" means the display of all written, printed or graphic material on the immediate container or information accompanying the material.
"Land application" means the placement of waste products within 2 feet below the surface of land used to support vegetative growth.
"Land reclamation" means the application of waste products at a rate mot greater than necessary to support and maintain immediate revegetation. Application may be in multiple cycles prior to establishment of vegetation, but must be accomplished within a single short-term operational period.
"Land treatment" means a technology for t the intimate mixing or dispersion of wastes into the upper zone of the plant-soil system with the objective of microbial stabilization, immobilization, selective dispersion, or crop recovery loading to an environmentally acceptable assimilation of the waste.
" Liquid waste" means any waste which is not a solid waste as defined for the purposes of these regulations.
"Person" means an individual, trust, firm, joint stock company, federal agency, corporation (including a government corporation), partnership, association, state, municipality, commission, political subdivision of a state, or any interstate body.
"Solid waste" means any garbage, refuse, rubbish and other discarded materials resulting from industrial, commercial, mining, agricultural operations and from community activities which does a not contain free liquids. Containers holding free liquids shall be considered solid waste when the container is designed to hold free liquids for use other than storage (e.g. radiators, batteries, transformers) or the waste is household waste.
"Usable waste product" means an industrial waste that the Department has approved as a product or feedstock for a specified use.
Any person seeking authorization to utilize a by-product under this part shall be required to characterize the source and constituent make-up of the waste product.
The applicant shall describe fully the process or systems that generate the waste product. At a minimum, the following information shall be submitted in characterizing the source of the waste product:
A process flow chart which identifies and explains each phase of the waste product generation process;
A description of all major equipment and components used in the process that generates the waste product;
A description of any stabilization or treatment process the waste product will undergo prior to final utilization, including (where applicable):
A description of all major equipment used in the stabilization or treatment process;
Location and type of all monitoring worksheets used in monitoring the stabilization or treatment process;
Contingency or emergency operating plans; and
Other relevant information requested by the Department.
The applicant shall l provide an estimate of the quantity of the waste product that is currently being produced and the anticipated quantity to be generated annually for utilization.
Waste products containing pathogenic agents shall be stabilized in accordance with a process cited in Part III, B, Section 600 of these regulations.
Waste products to be utilized in land application projects may range from relatively clean by-products such as those from certain food processing industries to those which are potentially toxic above certain threshold limits and would require special considerations. As such it is important that the composition of the waste product be determined.
The degree of analysis required is dependent on the ability of the applicant to identify the composition of the waste product. By-products whose composition can be clearly determined through source identification may only need to be analyzed for nutrient status, providing it can be shown that the constituents identified in part III, B, Subsection 402(2) of these regulations are either absent or at low enough concentrations that they pose no significant environmental or public health risks. However, waste products whose composition is difficult to consistently ascertain will be required to be analyzed for the constituents cited in Part III, B, Subsection 402(2) of these regulations.
The waste product generator shall submit to the Department a chemical analysis of the waste product in accordance with Part III, B, Subsection 402(2) of these regulations every three months following permit issuance for 402 (2) (b) unless the Department approves a different schedule in the permit. The parameters for analysis will be developed based upon the critical or controlling constituents determined through the characterization of the by-product.
In no case shall the cumulative metals loadings exceed the levels set forth in Part III, A, Table 2 of these regulations. The applicant shall utilize table 2 in conjunction with Section 500 to calculate the potential site life for the constitute metals.
The waste product generator shall perform and submit to the Department and landowner additional analyses if there has been a significant change (greater than 25%) in the quality of the waste product from the original characterization.
An application for a permit to utilize a waste product for agricultural purposes or in a distribution and marketing program shall include a Waste Management Plan for Department review and approval. The Waste Management Plan shall, at a minimun, provide:
An explanation of how the waste product will be utilized; i.e. whether the proposed operation is for agricultural utilization, distribution and marketing, research, or land reclamation.
An operation plan to include proposed application rates and identification of land limiting constituents (LLC); the proposed life of the operation; equipment to be used for site preparation, land application and incorporation of the waste (if applicable); storage practices and specifications including storage volume, holding time, runon/runoff control and site access control; and other relevant information requested by the Department.
The applicant shall develop a printed handout for the waste product that provides instructions for the proper use of the waste product. It shall identify the source and make-up of the waste product and provide detailed instructions for its proper use on different plant types, soils, and slopes, maximum loading rates for specified uses, any unacceptable use of the material and shall provide information on essential plant nutrient content. The printed handout shall also provide information on essential plant nutrient content. The printed handout shall also provide information on essential plant nutrient content, address maximum cumulative loading rates (if contaminant concentrations are of concern), provide instructions for proper storage, stockpiling and transportation of the waste product and application methods to be employed. The Department may require that specific restrictions, warnings or a caution statement be included in the hand out.
The applicant shall develop a QA/QC plan for department review and approval to assure that the consistency of the waste product is maintained. If the waste product is to be stabilized or other wise processed, the process shall be routinely monitored and the information recorded on a form approved by the Department. The QA/QC plan shall provide in detail, measures taken to assure product uniformity and consistency. In addition, the QA/QC plan shall include a waste product sampling plan in accordance with Part III, B, Section 1200 of these regulations.
The applicant shall develop a recordkeeping and reporting system for department review and approval which at a minimum, provides for maintaining distribution records, application rates, results of all tests performed as part of the QA/QC plan, procedures for monitoring the stabilization process (if applicable) and procedures for reporting this information to the Department.
Agricultural Utilization. If the applicant proposes to repeatedly (more than two consecutive years) utilize the waste product at a specific agricultural site, the following additional information shall be submitted:
A topographic map or other map on a scale no less than 1" = 400'. The map shall include the following information:
The boundaries of the land where the waste product will be applied, including total acreage available for utilization;
The location of any watercourses, drainage structures or wetlands within 1000' of the proposed site;
Residences and habitable structures within 1000' of the proposed site:
Flood elevations:
A description of the soil characteristics of the site in accordance with Part III, B, Subsection 402(3) (a), (b), (c), of these regulations; and
On-Site storage facility specifications (if applicable).
A Vegetable Management Plan which shall include, at a minimum, the following information:
A projected crop rotation plan which shall specify crops to be grown, anticipated yield, fertilizer requirements, planting and harvesting schedules, timing of application of the waste product, application rate of the waste product and final use of the crop;
The method and frequency for applying the waste product to the site and the method of incorporating the waste product to the site, if applicable;
The total volume of waste product to be applied to the site and the proposed life of the operation;
Methods to manage runoff and control erosion during the life of the project; and
If the waste product is to be applied to land owned by persons other than the generator of the waste product, the name and address of the landowner and evidence that the landowner has reviewed and approved by the project.
Distribution and Marketing. If the applicant proposes to utilize the waste product in a Distribution and Marketing program, the following additional information shall be submitted.
Evidence that pathogenic organisms are absent from the waste product;
Evidence that the waste product is dried of otherwise amended to a minimum of twenty percent (20%) solids prior to distribution and marketing;
Evidence that the waste product contains no Free Liquids;
Evidence that the waste product does not exceed the limitations for heavy metals and other constituents as established in Part III, B, Subsection 1101(1) (b) of these regulations;
Evidence that there is a market for the waste material; and
A description of the distribution and marketing system to include an identification of the end-users and the final use of the waste product.
Land Reclamation. In addition to the requirements cited in this part, each application for a permit to utilize a waste product for land reclamation shall adhere to the requirements of Part III, B, Subsection 702 of these regulations.
Storage facilities shall be designed and constructed in accordance with Part III, B, Section 900 of these regulations unless the applicant can demonstrate that the proposed storage practices for the waste product will not allow contaminants to leach into the groundwater, contribute to surface runoff, attract vectors, or create nuisance conditions and odors.
7 Del. Admin. Code § 7202-7.0