08/11/2021
Solvent cleaning machines using the following hazardous air pollutants (HAPs) [methylene chloride (CAS No. 75-09-2); perchloroethylene (CAS No. 127-18-4); 1,1,1-trichloroethane (CAS No. 71-55-6)], are not covered by Section 33.0 but may be covered by the requirements found at 7 DE Admin. Code 1138, Section 8.0"Emission Standards for Halogenated HAP Solvent Cleaning".
"Airless cleaning system" means a solvent cleaning machine that is automatically operated and seals at a differential pressure of 0.50 pounds per square inch gauge (psig) or less, prior to the introduction of solvent or solvent vapor into the cleaning chamber and maintains differential pressure under vacuum during all cleaning and drying cycles.
"Airtight cleaning system" means a solvent cleaning machine that is automatically operated and seals at a differential pressure of 0.50 pounds per square inch gauge (psig) or less, prior to the introduction of solvent or solvent vapor into the cleaning chamber and during all cleaning and drying cycles.
"Automated parts handling system" means a mechanical device that carries all parts and parts baskets at a controlled speed from the initial loading of soiled or wet parts through the removal of the cleaned or dried parts. Automated parts handling systems include, but are not limited to, hoists and conveyors.
"Batch cold cleaning machine" means a batch operated cleaning machine that is designed to contain a liquid solvent or cleaning solution, has a solvent/air interface, and is always operated at a temperature below the boiling point of the cleaning solution. Batch cold cleaning machine includes batch-loaded and immersion cold cleaning machines, remote reservoir cold cleaning machines (also known as sink-on-a-drum) and various types of spray booths, flush booths or wash stations.
"Batch vapor cleaning machine" means a vapor solvent cleaning machine in which individual parts or a set of parts move through the entire cleaning or drying cycle before new parts are introduced into the cleaning machine. The term does not include machines that do not have a solvent/air interface, such as airless cleaning systems and airtight cleaning systems.
"Carbon adsorber" means a bed of activated carbon into which an air/solvent gas-vapor stream is routed and which adsorbs the solvent on the carbon.
"Cold cleaning machine" means a solvent cleaning machine that contains or uses a non-boiling liquid solvent into which parts are placed to remove soils from the surfaces of the parts or to dry the parts. The term does not include machines that do not have a solvent/air interface, such as airless cleaning systems and airtight cleaning systems.
"Downtime mode" means the time period when a solvent cleaning machine is not cleaning or drying parts and the sump heating coils, if present, are turned off.
"Dwell" means the technique of holding parts within the freeboard area but above the vapor zone of a solvent cleaning machine. Dwell occurs after cleaning or drying to allow solvent to drain from the parts or parts baskets back into the solvent cleaning machine.
"Dwell time" means the period of time between when parts or a parts basket is placed in the vapor zone of a batch vapor or in-line vapor cleaning machine and when solvent dripping ceases.
"Freeboard height" means, for a batch cold cleaning machine, the distance from the liquid solvent level to the lip of the solvent cleaning machine. For a batch vapor cleaning machine, it is the distance from the solvent/air interface to the lip of the solvent cleaning machine, as measured during idling mode. For an in-line cleaning machine, it is the distance from the solvent/air interface to the bottom of the entrance or exit opening, whichever is lower, as measured during idling mode.
"Freeboard ratio" means the ratio of the solvent cleaning machine freeboard height to the smaller interior dimension (length, width, or diameter) of the solvent cleaning machine.
"Freeboard refrigeration device" means a set of secondary coils mounted in the freeboard area of a solvent cleaning machine that carries a refrigerant or other chilled substance to provide a chilled air blanket above the solvent vapor. A primary condenser which is capable of maintaining a temperature in the center of the chilled air blanket at not more than 30 percent of the solvent boiling point is both a primary condenser and a freeboard refrigeration device.
"Idling mode" means the time period when a solvent cleaning machine is turned on but is not actively processing parts.
"In-line cold cleaning machine" means a cold cleaning machine that uses an automated parts handling system, typically a conveyor, to automatically provide a continuous supply of parts to be cleaned or dried. These units are fully enclosed except for the conveyor inlet and exit portals.
"In-line vapor cleaning machine" means a vapor solvent cleaning machine that uses an automated parts handling system, typically a conveyor, to automatically provide a continuous supply of parts to be cleaned or dried. These units are fully enclosed except for the conveyor inlet and exit portals.
"Lip exhaust" means a system which collects solvent vapors escaping from the top of a solvent cleaning machine and directs them away from operating personnel.
"Primary condenser" means a series of circumferential cooling coils on a vapor cleaning machine through which a chilled substance is circulated or recirculated to provide continuous condensation of rising solvent vapors and, thereby, creating a concentrated solvent vapor zone.
"Reduced room draft" means decreasing the flow or movement of air across the top of the freeboard area of a solvent cleaning machine to less than 15.2 meters per minute (50 feet per minute) by methods including, but not limited to, redirecting fans or air vents to not blow across the cleaning machine, moving the cleaning machine to a corner where there is less room draft, and constructing a partial or complete enclosure around the cleaning machine.
"Remote reservoir cold cleaning machine" means a solvent cleaning machine in which liquid solvent is pumped to a sink-like work area that immediately drains solvent back into an enclosed container while parts are being cleaned or dried, allowing no solvent to pool in the work area. A remote reservoir cold cleaning machine is also termed a sink-on-a-drum. A remote reservoir cold cleaning machine that uses an enclosed container for dipping or soaking parts is considered to be a batch-loaded, or immersion cold cleaning machine.
"Soils" means contaminants that are removed from the parts, products, tools and machinery being cleaned. Soils include, but are not limited to, grease, oils, waxes, metal chips, carbon deposits, fluxes, and tars.
"Solvent" means any liquid containing volatile organic compounds (VOC) which is used to perform solvent cleaning or drying.
"Solvent/air interface" means, for a vapor cleaning machine, the location of contact between the concentrated solvent vapor layer and the air. This location of contact is defined as the mid-line height of the primary condenser coils. For a cold cleaning machine, it is the location of contact between the liquid solvent and the air.
"Solvent cleaning machine" means any device or piece of equipment that uses volatile organic compounds, liquid or vapor, to remove soils from parts or to dry parts. Types of solvent cleaning machines include, but are not limited to, batch vapor, in-line vapor, in-line cold, immersion cold, and remote reservoir cold cleaning machines, as well as, airless cleaning systems and airtight cleaning systems.
"Superheated vapor system" means a system that heats the solvent vapor, either passively or actively, to a temperature 10°F above the solvent's boiling point. Parts are held in the superheated vapor before exiting the machine to evaporate the liquid solvent on the parts. Hot vapor recycle is an example of a superheated vapor system.
"Vapor cleaning machine" means a batch or in-line solvent cleaning machine that heats liquid solvent that is used as part of the cleaning or drying cycle. The heated solvent may or may not be boiling. The term does not include machines that do not have a solvent/air interface, such as airless cleaning systems and airtight cleaning systems.
"Vapor up control switch" means a thermostatically controlled switch that shuts off or prevents solvent from being sprayed when there is no vapor. On in-line vapor cleaning machines the switch also prevents the conveyor from operating when there is no vapor.
"Working mode" means the time period when the solvent cleaning machine is actively cleaning or drying parts.
"Working mode cover" means any cover or solvent cleaning machine design that allows the cover to shield the cleaning machine openings from outside air disturbances while parts are being cleaned or dried in the cleaning machine. A cover that is used during the working mode is opened only during parts entry and removal.
(33-1)
where:
EL = the three-month rolling average monthly emission limit (kilograms/month).
Vol = the cleaning capacity of machine (cubic meters).
(33-2)
where:
E = the total VOC solvent emissions from the solvent cleaning machine during the most recent monthly reporting period (kilograms of solvent per month).
SA = the total amount of VOC liquid solvent added to the solvent cleaning machine during the most recent monthly reporting period (kilograms of solvent per month).
LSR = the total amount of VOC liquid solvent removed from the solvent cleaning machine during the most recent monthly reporting period (kilograms of solvent per month).
SSR = the total amount of VOC solvent removed from the solvent cleaning machine in solid waste during the most recent monthly reporting period (kilograms of solvent per month), as determined from tests conducted using Method 25D in Appendix A of 40 CFR part 60, dated July 1, 2019 and hereby incorporated by reference or by engineering calculations included in the compliance report.
(33-3)
where:
EA = the average VOC solvent emissions over the preceding three monthly reporting periods (kilograms of solvent per month).
E = the total VOC solvent emissions for each month (j) for the most recent three monthly reporting periods (kilograms of solvent per month).
j = 1 = the most recent monthly reporting period.
j = 2 = the monthly reporting period immediately prior to j = 1.
j = 3 = the monthly reporting period immediately prior to j = 2.
Table 33-1 - Emission Limits for Batch Vapor and In-line Cleaning Machines
Solvent cleaning machine | Three-Month rolling average monthly emission limit (kilograms/square meters/month) |
Batch vapor cleaning machines | 150 |
Existing in-line cleaning machines | 153 |
New in-line cleaning machines | 99 |
(33-4)
where:
E = the total VOC solvent emissions from the solvent cleaning machine during the most recent monthly reporting period (kilograms of solvent per square meter of solvent/air interface area per month).
SA = the total amount of VOC liquid solvent added to the solvent cleaning machine during the most recent monthly reporting period (kilograms of solvent per month).
LSR = the total amount of VOC liquid solvent removed from the solvent cleaning machine during the most recent monthly reporting period (kilograms of solvent per month).
SSR = the total amount of VOC solvent removed from the solvent cleaning machine in solid waste during the most recent monthly reporting period (kilograms of solvent per month), as determined from tests conducted using Method 25D in Appendix A of 40 CFR part 60, dated July 1, 2019 and hereby incorporated by reference or by engineering calculations included in the compliance report.
AREA = the solvent/air interface area of the solvent cleaning machine (square meters).
(33-5)
where:
EA = the average VOC solvent emissions over the preceding three monthly reporting periods (kilograms of solvent per square meter of solvent/air interface area per month).
E = the total VOC solvent emissions for each month (j) for the most recent three monthly reporting periods (kilograms of solvent per square meter of solvent/air interface area per month).
j = 1 = the most recent monthly reporting period.
j = 2 = the monthly reporting period immediately prior to j = 1.
j = 3 = the monthly reporting period immediately prior to j = 2.
7 Del. Admin. Code § 1124-33.0
25 DE Reg. 196 (8/1/2021) (final)