Lead can cause serious health problems. For more information please call or visit [INSERT NAME OF YOUR WATER SYSTEM OR YOUR WEB SITE HERE]. The message or delivery mechanism can be modified in consultation with the Department; specifically, the Department may allow a separate mailing of public education materials to customers if the water system cannot place the information on water bills.
System Size (No. People Served) | Number of sites (Standard Monitoring) | Number of sites (Reduced Monitoring) |
>100,000 | 100 | 50 |
10,001-100,000 | 60 | 30 |
3,301 to 10,000 | 40 | 20 |
501 to 3,300 | 20 | 10 |
101 to 500 | 10 | 5 |
<=100 | 5 | 5 |
System Size (No. People Served) | First Six-month Monitoring Period Begins On |
>50,000 | January 1, 1992 |
3,301 to 50,000 | July 1, 1992 |
<=3,300 | July 1, 1993 |
System Size (No. of People Served) | No. of Sites for Water Quality Parameters |
>100,000 | 25 |
10,001-100,000 | 10 |
3,301 to 10,000 | 3 |
501 to 3,300 | 2 |
101 to 500 | 1 |
<100 | 1 |
System Size (No. of People Served) | Reduced No. of Sites for Water Quality Parameters |
>100,000 | 10 |
10,001 to 100,000 | 7 |
3,301 to 10,000 | 3 |
501 to 3,300 | 2 |
101 to 500 | 1 |
<=100 | 1 |
NOTE: For the purposes of 310 CMR 22.06B(9)(a)1.b., surface water systems include systems with a combination of surface and ground sources.
ANALYTICAL METHODS Reference (Method Number) | |||||||
Contaminant | Methodology9 | EPA1 | ASTM2 | SM3 | SM Online11 | USGS4 | Other |
Lead | Atomic absorption; furnace technique | D3559-96, 03D | 3113B | 3113B-99 | |||
Inductively-coupled | 200.8 | ||||||
plasma; mass spectrometry Atomic absorption; | 200.9 | ||||||
platform furnace technique Differential Pulse Anodic Stripping Voltameter | Method 100110 | ||||||
Copper | Atomic absorption; furnace technique | D1688-95, 02C | 3113B | 3113B-99 | |||
Atomic absorption; direct aspiration | D1688-95, 02A | 3111B | 3113B-99 | ||||
Inductively-coupled plasma | 200.75 | 3120B | 3120B-99 | ||||
Inductively-coupled | 200.86 | ||||||
plasma; mass spectrometry Atomic absorption; | 200.97 | ||||||
platform furnace | |||||||
Magnesium | Atomic absorption; furnace | D 511-93 03B | 3111B | 311B-99 | |||
ICP | 200.7 | 3120B | 3120B-99 | ||||
Complexation Titrimetric | D 511-93, 3A | 3500-Mg E | 3500MB-97 | ||||
Methods | 3500 Mg B | ||||||
Ion Chromatography | D6919-03 | ||||||
pH | Electrometric | 150.1 150.2 | D1293-95, 99 | 4500-H+B | 4500- H +B-00 | ||
Conductivity | Conductance | D1125-95 (Re-approved 1999) | 2510B | 2510B-97 | |||
Calcium | EDTA titrimetric | A D511-9303 A | 3500- Ca-D Ca B | 3500- Ca B-97 | |||
Atomic absorption; direct aspiration | D511-9303 B | 3111B | 3111 B-99 | ||||
Inductively-coupled plasma | 200.7 | 3120B | 3120 B-99 | ||||
Alkalinity | Titrimetric Electrometric titration | D1067-02 B | 922320B | 2320 B-97 | I-1030-85 | ||
Ortho-phosphate, unfiltered, no digestion or hydrolysis | Colorimetric, automated, ascorbic acid | 365.18 | 4500-P-F | ||||
Colorimetric, ascorbic acid, single reagent Colorimetric, | D515-88A | 4500-P-E | |||||
phosphomolybdate; | I-1601-85 | ||||||
automated-segmented flow; automated discrete | I-2601-90 | ||||||
I-2598-85 | |||||||
Ion Chromatography | 300.08 | D4327-97, 03 | 4110B | 4110 B-00 | |||
Capillary Ion Electro- | 300.1 | D6508, | |||||
Phoresis | Rev. 2 -39 | ||||||
Silica | Colorimetric, molybdate blue; | I-1700-85 | |||||
automated-segmented flow | I-2700-85 | ||||||
Colorimetric | D859-9400 | 4500-Si-D (18th,19th) | 4500-SiO2 C-97 | ||||
Molybdosilicate | 4500-SiO2 C (20th ed. | ) | |||||
Heteropoly blue | 4500-Si-E (18th,19th) 4500-SiO2 D (20th ed.) | 4500- SiO2 D-97 | |||||
Automated method for molybdate-reactive silica | 4500-Si- F (18th, 19th) 4500-SiO2 E (20th ed.) | 4500- SiO2 D-97 | |||||
Inductively-coupled plasma | 200.75 | 3120B | 3120 B-99 | ||||
Temperature | Thermometric | 2550 |
1 The procedures 239.2, 220.2, 220.1, 150.1, 150.2, 120.1, 215.2, 310.1, 365.1, 365.3, 365.2, and 370.1 are incorporated by reference and shall be done in accordance with "Methods for Chemical Analysis of Water and Wastes", EPA Environmental Monitoring and Support Laboratory, Cincinnati, OH (EPA-600/4-79-020), Revised March 1983, pp. 239.2-1 through 239.2-2 and metals-1 through metals-19, 220.2-1 through 220.2-2 and metals-1 through metals-19, 220.1-1 through 220.1-2 and metals-1 through metals-19, 150.1-1 through 150.1-3, 150.2-1 through 150.2-3, 120.1-1 through 120.1-3, 215.2-1 through 215.2-3, 215.1-1 through 215.1-2, 310.1-1 through 310.1-3, 365.1-1 through 365.1-9, 365.3-1 through 365.3-4, 365.2-1 through 365.2-6, and 370.1-1 through 370.1-5, respectively. This incorporation by reference was approved by the Director of the Federal Register in accordance with 5 U.S.C. 552(a) and 1 CFR Part 51. Copies may be obtained from ORD Publications, CERI, EPA, Cincinnati, OH 45268. Copies may be inspected at the United Departments Environmental Protection Agency, 401 M Street, SW., Room EB-15, Washington, D.C. 20460 or at the Office of the Federal Register, 1100 L Street, NW., Room 8401, Washington, D.C.
2 The procedures D3559-96D, D1688-95C, D1688-95A, D1293-95B, D1125-82B, D511-88A, D511-88B, D1067-88B, D515-88A, D4327-97, and D859-88 are incorporated by reference and shall be done in accordance with Annual Book of ASTM Standards, 1994, 1996, or 1999, Vols. 11.01 and 11.02, ASTM International; any year containing the cited version of the method may be used. The previous versions of D1688-95A, D1688-95C (copper), D3559-95D (lead), D1293-95 (pH), D1125-91A (conductivity), and D859-94 (silica) are also approved. These previous versions D1688-90A, C; D355990D, D1293-84, D1125-91A and D859-88, respectively are located in the Annual Book of ASTM Standards, 1994, Vol. 11.01. Copies may be obtained from ASTM International, 100 Barr Harbor Drive, West Conshohocken, PA 19428.
3 The procedures 3113, 3111-B, 3120, 4500-H+, 2510, 3500-Ca-D, 3120, 2320, 4500-P-F, 4500-P-E, 4110, 4500-Si-D, 4500-Si-E, 4500-Si-F, and 2550 are incorporated by reference and shall be done in accordance with Standard Methods for the Examination of Water and Wastewater, 18th edition (1992), 19th edition (1995) or 20th edition (1998), American Public Health Association, 1015 Fifteenth Street, NW, Washington, DC 20005. The cited methods published in any of these three editions may be used, except that the versions of 3111B and 3113B in the 20th edition may not be used. This incorporation by reference was approved by the Director of the Federal Register in accordance with 5 U.S.C. 552(a) and 1 CFR Part 51. Copies may be obtained from the American Water Works Association, Customer Services, 6666 West Quincy Avenue, Denver, Co 80235, Phone (303) 794-7711. Copies may be inspected at the United Departments Environmental Protection Agency, 401 M Street, SW., Room EB-15, Washington, D.C. 20460 or at the Office of the Federal Register, 1100 L Street, NW., Room 8401, Washington, D.C.
4 The procedures I-1030-85, I-1601-85, I-2601-85, I-2598-85, I-1700-85, and I-2700-85 are incorporated by reference and shall be done in accordance with "Methods for Determination of Inorganic Substances in Water and Fluvial Sediments", 3rd edition, U.S. Department of Interior , U.S. Geological Survey, 1989, pp. 55-56, 381-382, 383-385, 387-388, 415-416, and 417-419, respectively. This incorporation by reference was approved by the Director of the Federal Register in accordance with 5 U.S.C. 552(a) and 1 CFR Part 51. Copies may be purchased from the Books and Open-file Reports Section, U.S. Geological Survey, Federal Center, Box 25425, Denver, Co 80225. Copies may be inspected at the United Departments Environmental Protection Agency, 401 M Street, SW., Room EB-15, Washington, D.C. 20460 or at the Office of the Federal Register, 1100 L Street, NW., Room 8401, Washington, D.C.
5Determination of Metals and Trace Elements in Water and Wastes by Inductively-Coupled Plasma--Atomic Emission Spectrometry, Revision 3.3, April 1991, Methods for the Determination of Metals in Environmental Samples, Office of Research and Development, Washington, DC 20460, EPA/4-91/010, June 1991.
6Determination of Trace Elements in Water and Wastes by Inductively-Coupled Plasma--Mass Spectrometry, Revision 4.4, April 1991, Methods for the Determination of Metals in Environmental Samples, Office of Research and Development, Washington, DC 20460, EPA/600/4-91/010, June, 1991.
7Determination of Trace Elements by Stabilized Temperature Graphite Furnace Atomic Absorption Spectrometry, Revision 1.2, April 1991, Methods for the Determination of Metals in Environmental Samples, Office of Research and Development, Washington, DC 20460, EPA/600/4-91/010, June 1991.
8Determination of Inorganic Ions in Water by Ion Chromatography, Method 300.0, December 1989, U.S. EPA EMSL. This document is available from U.S. EPA, EMSL, Cincinnati, OH 45268.
9 For analyzing lead and copper, the technique applicable to total metals shall be used and samples cannot be filtered. Samples that contain less than one NTU (nephelometric turbidity unit) and are properly preserved (conc HNO3 TO pH <2) may be analyzed directly (without digestion) for total metals: otherwise, digestion is required. Turbidity shall be measured on the preserved samples just prior to when metals analysis is initiated. When digestion is required, the "total recoverable" technique as defined in the method shall be used.
10 The description for Method 1001 for lead is available from Palintest, LTD, 21 Kenton Lands Road, P.O. Box 18395, Erlanger, KY 41018, or from the Hach Company, P.O. Box 389, Loveland, CO 80539.
11 Standard Methods Online are available at http://www.standardmethods.org. The year in which each method was approved by the Standard Methods Committee is designated by the last two digits in the method number. The methods listed are the only online versions that may be used.
Summary of Monitoring Requirements for Water Quality Parameters1
Monitoring Period | Parameters2 | Location | Frequency |
Initial Monitoring. | pH, alkalinity, orthophosphate or silica3, calcium, conductivity, temperature. | Taps and at entry point(s) to distribution system. | Two samples every six months. |
After Installation of Corrosion Control. | pH, alkalinity, orthophosphate or silica3, calcium4. | Taps. | Two samples every six months. |
pH, alkalinity, dosage rate and concentration (if alkalinity adjusted as part of corrosion control), inhibitor dosage rate and inhibitor residual5. | Entry point(s) to distribution system6. | No less frequently than every two weeks. | |
After State Specifies Parameter Values for Optimal Corrosion Control. | pH, alkalinity, orthophosphate or silica3, calcium4. | Taps. | Two Samples every six months. |
pH, alkalinity dosage rate and concentration (if alkalinity adjusted as part of corrosion control), inhibitor dosage rate and inhibitor residual5. | Entry point(s) to distribution system6. | No less frequently than every two weeks. | |
Reduced Monitoring. | pH, alkalinity, orthophosphate or silica3, calcium4. | Taps. | Two samples every six months, annually7 or every three years8; reduced number of sites. |
pH, alkalinity dosage rate and concentration (if alkalinity adjusted as part of corrosion control), inhibitor dosage rate and inhibitor residual5. | Entry point(s) to distribution system6. | No less frequently than every two weeks. |
1 Table is for illustrative purposes; consult the text of 310 CMR 22.06B(12) for precise regulatory requirements.
2 Small and medium-size systems have to monitor for water quality parameters only during monitoring periods in which the system exceeds the lead or copper action level.
3 Orthophosphate shall be measured only when an inhibitor containing a phosphate compound is used. Silica shall be measured only when an inhibitor containing silicate compound is used.
4 Calcium shall be measured only when calcium carbonate stabilization is used as part of corrosion control.
5 Inhibitor dosage rates and inhibitor residual concentrations (orthophosphate or silica) shall be measured only when an inhibitor is used.
6 Ground water systems may limit monitoring to representative locations throughout the system.
7 Water systems may reduce frequency of monitoring for water quality parameters at the tap from every six months to annually if they have maintained the range of values for water quality parameters reflecting optimal corrosion control during three consecutive years of monitoring.
8 Water systems may further reduce the frequency of monitoring for water quality parameters at the tap from annually to once every three years if they have maintained the range of values for water quality parameters reflecting optimal corrosion control during three consecutive years of annual monitoring. Water systems may accelerate to triennial monitoring for water quality parameters at the tap if they have maintained 90th percentile lead levels less than or equal to 0.005 mg/L, 90th percentile copper levels less than or equal to 0.65 mg/L, and the range of water quality parameters designated by the State under 40 CFR 141.82(f) as representing optimal corrosion control during two consecutive six-month monitoring periods.
310 CMR, § 22.06B