A chemical recovery unit is not an incinerator, a waste-burning kiln, an energy recovery unit or a small, remote incinerator under this rule. The following seven types of units are considered chemical recovery units:
Where:
X1 = the PM CPMS data points for the three runs constituting the performance test;
Y1 = the PM concentration value for the three runs constituting the performance test; and
n = the number of data points.
Where:
R = the relative mg/dscm per milliamp, or the digital equivalent, for the PM CPMS;
Y 1= the three run average mg/dscm PM concentration;
X1 = the three run average milliamp output, or the digital 1equivalent, from the PM CPMS; and
z = the milliamp or digital signal equivalent of the instrument zero determined from subparagraph (b)9.(ii)(I) of this paragraph.
Where:
O1 = the operating limit for the PM CPMS on a 30-1 day rolling average, in milliamps;
L = the source emission limit expressed in mg/dscm;
z = the instrument zero in milliamps or digital equivalent, determined from subparagraph (b)9. (ii)(I) of this paragraph; and
R = the relative mg/dscm per milliamp, or per digital signal output equivalent, for the PM CPMS, from Equation 2 of this rule..
Where:
X1 = the PM CPMS data points for all runs i;
n = the number of data points; and
Oh = the site specific operating limit, in milliamps or digital signal equivalent.
Where:
Cadj = pollutant concentration adjusted to 7 percent oxygen;
Cmeas = pollutant concentration measured on a dry basis; (20.9 -7) = 20.9 percent oxygen - 7 percent oxygen (defined oxygen correction basis);
20.9 = oxygen concentration in air, percent; and
%O2 = oxygen concentration measured on a dry basis, percent.
Where:
Cks = Kiln stack concentration (ppmvd, mg/dscm, ng/dscm, depending on pollutant. Each corrected to 7% O2.)
Qab = Alkali bypass flow rate (volume/hr)
Cab = Alkali bypass concentration (ppmvd, mg/dscm, ng/dscm, depending on pollutant. Each corrected to 7% O2.)
Qcm = In-line coal mill flow rate (volume/hr)
Ccm = In-line coal mill concentration (ppmvd, mg/dscm, ng/dscm, depending on pollutant. Each corrected to 7% O2.)
Qks = Kiln stack flow rate (volume/hr)
TABLE 1. EMISSION LIMITS FOR INCINERATORS THAT COMMENCED CONSTRUCTION ON OR BEFORE NOVEMBER 30,1999, AND WERE NOT MODIFIED OR RECONSTRUCTED AFTER JUNE 1, 2001
Pollutant | Units (7 percent oxygen, dry basis, except opacity) | Averaging Time | Compliance Method 40 CFR 60 Appendix A |
Cadmium | 0.004 Milligrams per dry standard cubic meter | 3-run average (1 hour minimum sample time per run) | Method 29 |
Carbon Monoxide | 157 Parts per million by dry volume | 3-run average (1 hour minimum sample time per run) | Methods 10, 10A, or 10B |
Dioxins/furans (toxic equivalency basis) | 0.41 Nanograms per dry standard cubic meter | 3-run average (1 hour minimum sample time per run) | Method 23 |
Hydrogen Chloride | 62 Parts per million by dry volume | 3-run average (For Method 26, collect a minimum volume of 120 liters per run. For Method 26A, collect a minimum volume of 1 dry standard cubic meter per run) | Method 26 or 26A |
Lead | 0.04 Milligrams per dry standard cubic meter | 3-run average (1 hour minimum sample time per run) | Method 29 |
Mercury | 0.47 Milligrams per dry standard cubic meter | 3-run average (1 hour minimum sample time per run) | Method 29 or 30B or ASTM D6784-02 (Reapproved 2008) |
Nitrogen Oxides | 388 Parts per million by dry volume | 3-run average (1 hour minimum sample time per run) | Methods 7 or 7E |
Particulate Matter | 70 Milligrams per dry standard cubic meter | 3-run average (1 hour minimum sample time per run) | Method 5 or 29 |
Sulfur Dioxide | 20 Parts per million by dry volume | 3-run average (1 hour minimum sample time per run) | Method 6 or 6c |
Opacity | 10 Percent | Three 1-hour blocks consisting of ten 6-minute average opacity values | Method 9 |
TABLE 2. OPERATING LIMITS FOR WET SCRUBBERS
For these operating parameters | Establish these operating limits | Data Measurement | Data Recording | Averaging Time (Calculated each hour as the average of the previous 3 operating hours) |
Charge rate. | Maximum charge rate | Continuous | Every hour | Daily (batch units). 3-hour rolling (continuous and intermittent units). |
Pressure drop across the wet scrubber or amperage to wet scrubber. | Minimum pressure drop or amperage. | Continuous | Every 15 minutes | 3-hour rolling. |
Scrubber liquor flow rate. | Minimum flow rate. | Continuous | Every 15 minutes | 3-hour rolling. |
Scrubber liquor pH | Minimum pH | Continuous | Every 15 minutes | 3-hour rolling. |
TABLE 3. TOXIC EQUIVALENCY FACTORS
Dioxin/Furan Isomer | Toxic Equivalency Factor |
2,3,7,8-tetrachlorinated dibenzo-p-dioxin | 1 |
1,2,3,7,8- pentachlorinated dibenzo-p-dioxin | 0.5 |
1,2,3,4,7,8-hexachlorinated dibenzo-p-dioxin | 0.1 |
1,2,3,7,8,9-hexachlorinated dibenzo-p-dioxin | 0.1 |
1,2,3,6,7,8-hexachlorinated dibenzo-p-dioxin | 0.1 |
1,2,3,4,6,7,8-heptachlorinated dibenzo-p-dioxin | 0.01 |
octachlorinated dibenzo-p-dioxin | 0.001 |
2,3,7,8-tetrachlorinated dibenzofuran | 0.1 |
2,3,4,7,8-pentachlorinated dibenzofuran | 0.5 |
1,2,3,7,8-pentachlorinated dibenzofuran | 0.05 |
1,2,3,4,7,8-hexachlorinated dibenzofuran | 0.1 |
1,2,3,6,7,8-hexachlorinated dibenzofuran | 0.1 |
1,2,3,7,8,9-hexachlorinated dibenzofuran | 0.1 |
2,3,4,6,7,8-hexachlorinated dibenzofuran | 0.1 |
1,2,3,4,6,7,8-heptachlorinated dibenzofuran | 0.01 |
1,2,3,4,7,8,9-heptachlorinated dibenzofuran | 0.01 |
octachlorinated dibenzofuran | 0.001 |
TABLE 4. REPORTING REQUIREMENTS
Report | Due Date | Contents | Reference 335-3-.05 |
Waste Management Plan | No later than the date specified for submittal of the final control plan. | * Waste Management Plan | (11)(z) |
Initial Test Report | No later than 60 days following the initial performance test. | *Complete test report for the initial performance test. *The values for the site-specific operating limits. *Installation of bag leak detection systems for fabric filters. | (11)(aa) |
Annual Report | No later than 12 months following the submission of the initial test report. Subsequent reports are to be submitted no more than 12 months following the previous report | * Name and address................... * Statement and signature by responsible official. * Date of report. * Values for the operating limits. * Highest recorded 3hour average and the lowest recorded 3-hour average, as applicable, (or 30-day average, if applicable) for each operating parameter recorded for the calendar year being reported. * If a performance test was conducted during the reporting period, the results of the test. * If a performance test was not conducted during the reporting period, a statement that the requirements of (9)(e) were met. * Documentation of periods when all qualified CISWI operators were unavailable for more than 8 hours but less than 2 weeks. * If performance tests are being conducted once every 3 years consistent with (9)(aa), the date of the last 2 performance tests, a comparison of the emission level achieved in the last 2 performance tests to the 75 percent emission limit threshold required in (9)(aa) and a statement as to whether there have been any operational changes since the last performance test that could increase emissions | (11)(bb) & (cc) |
Emission Limitation or Operating Limit Deviation Report | By August 1 of that year for data collected during the first half of the calendar year. By February 1 of the following year for data collected during the second half of the calendar year. | * Dates and times of deviations * Averaged and recorded data for these dates. "Duration and causes for each deviation and the corrective actions taken. * Copy of operating limit monitoring data and any test reports. "Dates, times, and causes for monitor downtime incidents. | (11)(t)1. - 3. |
Qualified Operator Deviation Notification. | Within 10 days of deviation. | * Statement of cause of deviation. "Description of efforts to have an accessible qualified operator. "The date a qualified operator will be accessible | (11)(dd)4.(i) |
Qualified Operator Deviation Status Report. | Every 4 weeks following deviation. | * Description of efforts to have an accessible qualified operator. "The date a qualified operator will be accessible. "Request for approval to continue operation. | (11)(dd)4.(ii) |
Qualified Operator Deviation Notification of Resumed Operation | Prior to resuming operation. | * Notification that operation will resume | (11)(dd)4.(iii) |
TABLE 5. EMISSION LIMITS FOR INCINERATORS THAT COMMENCED CONSTRUCTION AFTER NOVEMBER 30, 1999, BUT NO LATER THAN JUNE 4, 2010, OR COMMENCED MODIFICATION OR RECONSTRUCTION AFTER JUNE 1, 2001 BUT NO LATER THAN AUGUST 7, 2013
Pollutant | Emission Limitation | Averaging Time | Compliance Method 40 CFR 60 Appendix A |
Cadmium | 0.0026 Milligrams per dry standard cubic meter | 3-run average (collect a minimum volume of 2 dry standard cubic meters) | Method 29 Use ICPMS for the analytical finish. |
Carbon Monoxide | 17 Parts per million dry volume | 3-run average (1 hour minimum sample time per run) | Methods 10 |
Dioxins/furans (toxic mass basis) | 4.6 Nanograms per dry standard cubic meter | 3-run average (collect a minimum volume of 2 dry standard cubic meters) | Method 23 |
Dioxins/furans (toxic equivalency basis) | 0.13 Nanograms per dry standard cubic meter | 3-run average (collect a minimum volume of 2 dry standard cubic meters | Method 23 |
Hydrogen Chloride | 29 Parts per million dry volume | 3-run average (For Method 26, collect a minimum volume of 60 liters per run. For Method 26A, collect a minimum volume of 1 dry standard cubic meter per run) | Method 26 or 26A |
Lead | 0.015 Milligrams per dry standard cubic meter | 3-run average (collect a minimum volume of 2 dry standard cubic meters) | Method 29 (Use ICPMS for the analytical finish. |
Mercury | 0.0048 Milligrams per dry standard cubic meter | 3-run average (For Method 29 an ASTM D6784-02 (Reapproved 2008), collect a minimum volume of 2 dry standard cubic meters. For Method 30B, collect a minimum sample as specified in Method 30B) | Method 29 or 30B or ASTM D6784-02 (Reapproved 2008) |
Nitrogen Oxides | 53 Parts per million dry volume | 3-run average (for Method 7E, 1 hour minimum sample time per run) | Methods 7 or 7E |
Particulate Matter | 34 Milligrams per dry standard cubic meter | 3-run average (collect a minimum volume of 1 dry standard cubic meter) | Method 5 or 29 |
Sulfur Dioxide | 11 Parts per million by dry volume | 3-run average (1 hour minimum sample time per run) | Method 6 or 6c |
Fugitive ash | Visible emissions for no more than 5% of the hourly observation period | Three 1-hour observation periods | Method 22 (Visible emission test) |
TABLE 6. EMISSION LIMMITS FOR ENERGY RECOVERY UNITS THAT COMMENCED CONSTRUCTION ON OR BEFORE JUNE 4, 2010, OR THAT COMMENCED RECONSTRUCTION OR MODIFICATION AFTER JUNE 4, 2010 BUT NO LATER THAN AUGUST 7, 2013
Pollutant | Emission Limit (Liquid/Gas) | Emission Limit (Solids) | Averaging Time | Compliance Method 40 CFR 60 Appendix A |
Cadmium | 0.023 Milligrams per dry standard cubic meter | Biomass "0.0014 milligrams per dry standard cubic meter. Coal" 0.0017 milligrams per dry standard cubic meter. | 3-run average (collect a minimum volume of 2 dry standard cubic meters) | Method 29 (Use ICPMS for the analytical finish.) |
Carbon Monoxide | 35 Parts per million dry volume | Biomass "260 parts per million dry volume Coal" 95 parts per million dry volume | 3-run average (1 hour minimum sample time per run) | Methods 10 |
Dioxins/furans (total mass basis) | 2.9 nanograms per dry standard cubic meter | Biomass "0.52 nanograms per dry standard cubic meter. Coal" 5.1 nanograms per dry standard cubic meter. c | 3-run average (collect a minimum volume of 4 dry standard cubic meter) | Method 23 |
Dioxins/furans (toxic equivalency basis) | 0.32 Nanograms per dry standard cubic meter | Biomass "0.12 nanograms per dry standard cubic meter Coal" 0.075 nanograms per dry standard cubic meter. | 3-run average (collect a minimum volume of 4 dry standard cubic meters | Method 23 |
Hydrogen Chloride | 14 Parts per million by dry volume | Biomass "0.20 parts per million dry volume Coal" 58 parts per million dry volume | 3-run average (for Method 26, collect a minimum of 120 liters; for Method 26A, collect a minimum volume of 1 dry standard cubic meter) | Method 26 or 26A |
Lead | 0.096 Milligrams per dry standard cubic meter | Biomass "0.014 milligrams per dry standard cubic meter. Coal" 0.057 milligrams per dry standard cubic meter | 3-run average (collect a minimum volume of 2 dry standard cubic meters) | Method 29 (Use ICPMS for the analytical finish. |
Mercury | 0.0024 Milligrams per dry standard cubic meter | Biomass "0.0022 milligrams per dry standard cubic meter Coal" 0.013 milligrams per dry standard cubic meter | 3-run average (For Method 29 and ASTM D6784-02 (Reapproved 2008) d, collect a minimum volume of 2 dry standard cubic meters per run. For Method 30B, collect a minimum sample as specified in Method 30B. | Method 29 or 30B or ASTM D6784-02 (Reapproved 2008) |
Nitrogen Oxides | 76 Parts per million dry volume | Biomass "290 parts per million dry volume Coal" 460 parts per million dry volume | 3-run average (for Method 7E, 1 hour minimum sample time per run) | Methods 7 or 7E |
Particulate Matter Filterable | 110 milligrams per dry standard cubic meter | Biomass "11 milligrams per dry standard cubic meter Coal" 130 milligrams per dry standard cubic meter | 3-run average (collect a minimum volume of 1 dry standard cubic meter) | Method 5 or 29 if the unit has an annual average heat input rate less than or equal to 250 MMBtu/hr; or PM CPMS (as specified in §60.2710(x)) if the unit has an annual average heat input rate greater than 250 MMBtu/hr. |
Sulfur Dioxide | 720 Parts per million dry volume | Biomass "7.3 parts per million dry volume Coal" 850 parts per million dry volume | 3-run average (1 hour minimum sample time per run) | Method 6 or 6c |
Fugitive ash | Visible emissions for nomore than 5 percent of the hourly observation period | Visible emissions for no more than 5 percent of the hourly observation period | Three 1-hour observation periods | Method 22 (Visible emission test) |
TABLE 7. EMISSION LIMITS FOR WASTE-BURNING KILNS THAT COMMENCED CONSTURCTION ON OR BEFORE JUNE 4, 2010, OR THAT COMMENCED RECONSTRUCTION OR MODIFICATION AFTER JUNE 4, 2010 BUT NO LATER THAN AUGUST 7, 2013
Pollutant | Emission Limitation | Averaging Time | Compliance Method 40 CFR 60 Appendix A |
Cadmium | 0.0014 Milligrams per dry standard cubic meter | 3-run average (collect a minimum volume of 2 dry standard cubic meters) | Method 29 |
Carbon Monoxide | 110 (long kilns)/790 (preheater/precalciner) parts per million dry volume | 3-run average (1 hour minimum sample time per run) | Methods 10 |
Dioxins/furans (total mass basis) | 1.3 Nanograms per dry standard cubic meter. | 3-run average (collect a minimum volume of 4 dry standard cubic meters) | Method 23 |
Dioxins/furans (toxic equivalency basis) | 0.075 Nanograms per dry standard cubic meter | 3-run average (collect a minimum volume of 4 dry standard cubic meters) | Method 23 |
Hydrogen Chloride | 3.0 Parts per million by dry volume | 3-run average (collect a minimum volume of 1 dry standard cubic meter) or 30-day rolling average if HCl CEMS is being used | If a wet scrubber or dry scrubber is used performance test (Method 321 at 40 CFR part 63, appendix A of this part). If a wet scrubber or dry scrubber is not used, HCl CEMS as specified in (9)(j). |
Lead | 0.014 Milligrams per dry standard cubic meter | 3-run average (collect a minimum volume of 2 dry standard cubic meters) | Method 29 |
Mercury | 0.011 Milligrams per dry standard cubic meter OR *58 Pounds per Million Tons of Clinker | 30-day rolling average | Mercury CEMS or integrated sorbent trap monitoring system (performance specification 12A or 12B, respectively, of appendix B and procedure 5 of appendix F of 40 CFR 60.) |
Nitrogen Oxides | 630 Parts per million by dry volume | 3-run average (for Method 7E, 1 hour minimum sample time per run) | Methods 7 or 7E |
Particulate Matter Filterable | 13.5 Milligrams per dry standard cubic meter | 30-day rolling average | PM CPMS (as specified in 60.2710(x)) |
Sulfur Dioxide | 600 Parts per million by dry volume | 3-run average (for Method 6, collect a minimum of 20 liters; for Method 6C, 1 hour minimum sample time per run) | Method 6 or 6c |
*Equivalent Production-Based Limit " See rules 335-3-3-.05(8)(g), 335-3-3-.05(9)(ee), 335-3-3-.05(10)(v), and 335-3-3-.05(11)(ll) for additional requirements.
TABLE 8. EMISSION LIMITS FOR SMALL, REMOTE INCINERATORS THAT COMMENCED CONSTURCITON ON OR BEFORE JUNE 4, 2010, OR THAT COMMENCED RECONSTRUCTION OR MODIFICATION AFTER JUNE 4, 2010 BUT NO LATER THAN AUGUST 7, 2013
Pollutant | Units (7 percent oxygen, dry basis, except opacity) | Averaging Time | Compliance Method 40 CFR 60 Appendix A |
Cadmium | 0.95 milligrams per dry standard cubic meter | 3-run average (collect a minimum volume of 1 dry standard cubic meters per run) | Method 29 |
Carbon Monoxide | 64 parts per million dry volume | 3-run average (1 hour minimum sample time per run) | Methods 10 |
Dioxins/furans (total mass basis) | 4,400 nanograms per dry standard cubic meter b | 3-run average (collect a minimum volume of 1 dry standard cubic meters per run) | Method 23 |
Dioxins/furans (toxic equivalency basis) | 180 nanograms per dry standard cubic meter b | 3-run average (collect a minimum volume of 1 dry standard cubic meters) | Method 23 |
Hydrogen Chloride | 300 parts per million dry volume | 3-run average (For Method 26, collect a minimum volume of 120 liters per run. For Method 26A, collect a minimum volume of 1 dry standard cubic meter per run) | Method 26 or 26A |
Lead | 2.1 milligrams per dry standard cubic meter | 3-run average (collect a minimum volume of 1 dry standard cubic meters) | Method 29 (Use ICPMS for the analytical finish |
Mercury | 0.0053 milligrams per dry standard cubic meter | 3-run average (For Method 29 and ASTM D6784-02 (Reapproved 2008), collect a minimum volume of 2 dry standard cubic meters per run. For Method 30B, collect a minimum sample as specified in Method 30B at 40 CFR part 60, appendix A) | Method 29 or 30B or ASTM D6784-02 (Reapproved 2008) |
Nitrogen Oxides | 190 parts per million dry volume | 3-run average (for Method 7E, 1 hour minimum sample time per run) | Methods 7 or 7E |
Particulate Matter (Filterable) | 270 milligrams per dry standard cubic meter | 3-run average (collect a minimum volume of 1 dry standard cubic meters) | Method 5 or 29 |
Sulfur Dioxide | 150 parts per million dry volume | 3-run average (for Method 6, collect a minimum of 20 liters per run; for Method 6C, 1 hour minimum sample time per run) | Method 6 or 6c |
Fugitive Ash | Visible emissions for no more than 5 percent of the hourly observation period | Three 1-hour observation periods | Method 22 (Visible emissions test) |
Ala. Admin. Code r. 335-3-3-.05
Author: Ronald W. Gore
Statutory Authority:Code of Ala. 1975, §§ 22-28-14, 22-22A-5, 22-22A-6, 22-22A-8.