Harmonization With the United Nations Recommendations, International Maritime Dangerous Goods Code, and International Civil Aviation Organization's Technical Instructions

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Federal RegisterDec 20, 2004
69 Fed. Reg. 76043 (Dec. 20, 2004)

AGENCY:

Research and Special Programs Administration (RSPA), DOT.

ACTION:

Final rule.

SUMMARY:

RSPA is amending the Hazardous Materials Regulations (HMR) to maintain alignment with international standards by incorporating various amendments, including changes to proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, air transport quantity limitations and vessel stowage requirements. Because of recent changes to the International Maritime Dangerous Goods Code (IMDG Code), the International Civil Aviation Organization's Technical Instructions for the Safe Transport of Dangerous Goods by Air (ICAO Technical Instructions), and the United Nations Recommendations on the Transport of Dangerous Goods (UN Recommendations), these revisions are necessary to facilitate the transport of hazardous materials in international commerce.

DATES:

The effective date of these amendments is January 1, 2005

Delayed Compliance Date: Unless otherwise specified, compliance with the amendments adopted in this final rule is required beginning January 1, 2006.

Incorporation by Reference Date: The incorporation by reference of the publications adopted in § 171.7 of this final rule have been approved by the Director of the Federal Register as of January 1, 2005.

FOR FURTHER INFORMATION CONTACT:

Charles Betts, Office of Hazardous Materials Standards, telephone (202) 366-8553, or Shane Kelley, International Standards, telephone (202) 366-0656, Research and Special Programs Administration, U.S. Department of Transportation, 400 Seventh Street, SW., Washington, DC 20590-0001.

SUPPLEMENTARY INFORMATION:

Contents

I. Background

II. Overview of Changes in this Final Rule

III. Overview of Amendments Not Being Considered for Adoption in this Final Rule

IV. Section-By-Section Review

V. Regulatory Analyses and Notices

A. Statutory/Legal Authority for this Rulemaking

B. Executive Order 12866 and DOT Regulatory Policies and Procedures

C. Executive Order 13132

D. Executive Order 13175

E. Regulatory Flexibility Act, Executive Order 13272, and DOT Regulatory Policies and Procedures

F. Paperwork Reduction Act

G. Regulatory Identifier Number (RIN)

H. Unfunded Mandates Reform Act

I. Environmental Assessment

J. Privacy Act

I. Background

On December 21, 1990, RSPA (we) published a final rule (Docket HM-181; 55 FR 52402) based on the UN Recommendations, which comprehensively revised the Hazardous Materials Regulations (HMR), 49 CFR Parts 171 to 180, for harmonization with international standards. Since publication of the 1990 final rule we have issued five additional international harmonization final rules (Dockets HM-215A, 59 FR 67390; HM-215B, 62 FR 24690; HM-215C, 64 FR 10742; HM-215D, 66 FR 33316; and HM-215E, 68 FR 44992). The rules provided additional harmonization with international transportation requirements by more fully aligning the HMR with the corresponding biennial updates of the UN Recommendations, the IMDG Code and the ICAO Technical Instructions.

The UN Recommendations are not regulations, but rather are recommendations issued by the UN Committee of Experts on the Transport of Dangerous Goods (TDG) and on the Globally Harmonized System of Classification and Labeling (GHS). These recommendations are amended and updated biennially by the UN Committee of Experts. They serve as the basis for National, regional, and international modal regulations; specifically, the IMDG Code issued by the International Maritime Organization (IMO), and the ICAO Technical Instructions issued by the ICAO. In 49 CFR 171.12, the HMR authorize domestic transportation of hazardous materials shipments prepared in accordance with the IMDG Code if all or part of the transportation is by vessel, subject to certain conditions and limitations. In § 171.11, subject to certain conditions and limitations, the HMR authorize the offering, acceptance and transport of hazardous materials by aircraft, and by motor vehicle either before or after being transported by aircraft, provided the shipment is in accordance with the ICAO Technical Instructions.

The continually increasing amount of hazardous materials transported in international commerce warrants the harmonization of domestic and international requirements to the greatest extent possible. Harmonization serves to facilitate international transportation and at the same time ensures the safety of people, property and the environment. While the intent of the harmonization rulemakings is to align the HMR with international standards, we review and consider each amendment on its own merit. Each amendment is considered on the basis of the overall impact on transportation safety and the economic implications associated with its adoption into the HMR. Our goal is to harmonize without diminishing the level of safety currently provided by the HMR and without imposing undue burdens on the regulated public. In our efforts to continue to align the HMR with international requirements, this final rule incorporates changes into the HMR based on the Thirteenth Revised Edition of the UN Recommendations, Amendment 32 to the IMDG Code, and the 2005-2006 ICAO Technical Instructions, which become effective January 1, 2005. Petitions for rulemaking concerning harmonization with international standards and additional measures concerning facilitation of international transportation are also addressed in this final rule and serve as the basis of certain amendments. Other amendments are based on feedback from the regulated industry, other DOT modal administrations and our initiative. Also included are various editorial clarifications. Unless otherwise stated, the revisions are for harmonization with international standards.

II. Overview of Changes in This Final Rule

Amendments to the HMR in this final rule include, but are not limited to the following:

—Amendments to the Hazardous Materials Table (HMT) which add, revise or remove certain proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, bulk packaging requirements, passenger and cargo aircraft maximum quantity limitations and vessel stowage provisions.

—Amendments to the List of Marine Pollutants.

—Revisions and additions of special provisions.

—Removal of the air eligibility marking requirement.

—Addition of a “KEEP AWAY FROM HEAT” marking requirement for packages offered for transportation by air.

—Amendment to require that aerosols that are carried aboard an aircraft in accordance with § 175.10(a)(4) have their release devices protected by a cap or other suitable means.

—A grandfather provision to allow the shipment of materials classified as corrosive to steel or aluminum under ASTM G 31-72.

— A provision to require that the word “overpack” be marked on overpacks to indicate that inside packages comply with prescribed specifications.

—An amendment to the criteria for classification of materials that are corrosive to metals.

—Revision of the limited quantity provisions for Class 6.1, PG II materials and for materials with a subsidiary hazard of 6.1, PG II.

—Amendments to the packaging requirements for materials classified as Division 6.1, Packing Group I, Hazard Zone A or Hazard Zone B.

—Revision of the organic peroxide packaging requirements in order to have one consolidated packaging section for organic peroxides. The revised section will include three separate tables for organic peroxides authorized for transport in non-bulk packagings, IBCs, and bulk packagings other than IBCs, respectively. Additionally, the packaging tables will be updated through the amendments to the organic peroxide requirements that will add, revise, or delete certain entries in the organic peroxide tables.

III. Overview of Amendments Not Being Considered for Adoption in This Final Rule

This final rule makes changes to the HMR based on amendments to the Thirteenth Revised Edition of the UN Recommendations, Amendment 32 to the IMDG Code, and the 2005-2006 ICAO Technical Instructions, which become effective January 1, 2005. However, we are not adopting all of the amendments to those documents into the HMR. In many cases, amendments to the international regulation have not been adopted because of the framework or structure of the HMR. In several cases, we are handling certain amendments in separate rulemakings. For example, all amendments related to infectious substances are being handled under Docket HM-226A. In some instances, such as the amendment to ICAO Technical Instructions to allow certain oxygen generators aboard passenger carrying aircraft, we do not believe the amendment to be in the interest of public safety.

One of the goals of this rulemaking is to continue to maintain consistency between the HMR and the international requirements. We are not striving to make the HMR identical to the international regulations but rather striving to remove or avoid potential barriers to international transportation.

Below is a listing of those significant amendments to the international regulations that we have not included in this final rule with a brief explanation of why the amendment was not included:

  • Requirements for infectious substances and genetically modified micro-organisms;

[Amendments to the HMR related to infectious substances will be addressed in a future rulemaking under Docket HM-226A. Several other federal agencies regulate genetically modified micro-organisms; thus we do not plan to adopt provisions for their transport in the HMR.]

  • Compressed gas cylinders;

[Amendments to the HMR related to compressed gas cylinders will be addressed in a future rulemaking under Docket HM-220E.]

  • Environmentally hazardous substances;

[Delay in action pending further amendments to the international regulations.]

  • Hazardous materials security;

[Amendments to the HMR related to the UN Model Regulation's hazardous materials security requirements were promulgated in a rulemaking under the HM-232 Docket series.]

  • Requirements for radioactive materials;

[Amendments to the HMR related to Class 7 (radioactive) materials are being addressed in a rulemaking under the HM-230 Docket series.]

  • Non-specification bulk packagings;

[We are not adopting the new requirements in the UN Recommendations for non-specification bulk packagings including the additional inspection, testing and marking requirements. We are unsure about the cost impacts of imposing these additional amendments and, therefore, are not adopting any additional amendments at this time.]

  • The reference to EN 10028-3, Part 3 for defining steel grain size relevant to the definition of fine grain steel;

[We do not believe there is a need to adopt the European standard EN 10028-3, Part 3 because this standard is equivalent to ASTM E 112-96 (IBR, see § 171.7 of this subchapter). In addition, the ASTM standard is currently referenced in the HMR and is more commonly used and recognized in the U.S.]

  • Bulk authorization for UN0331, UN0332 and UN3375;

[For several years, we have authorized, under exemption, the transport of certain blasting agents in bulk packagings. We are currently reviewing those exemptions to determine if they should be included in the HMR. The amendments in the UN Recommendations related to the bulk authorizations for UN0331, UN0332 and UN3375 will be included in that review.]

  • The removal of wooden barrel requirements;

[The removal of the wooden barrel requirements (2C1 and 2C2) may be considered in a future rulemaking.]

  • The 24-hour gasket relaxation requirement;

[A requirement that removable head packagings for liquids not be drop tested until at least 24 hours after filling and closing to allow for any possible gasket relaxation was adopted in the thirteenth revised edition of the UN Model Regulations. We have conducted testing in coordination with drum manufacturers and have determined that this requirement is not substantiated by the results of the tests conducted. Therefore, we are not adopting into the HMR amendments relative to the 24-hour gasket relaxation requirement. We also opposed this requirement when it was considered by the UN TDG Sub-Committee.]

  • Authorization to transport protective breathing equipment (PBE's) with an oxygen generator as cargo onboard a passenger-carrying aircraft.

[We do not believe that oxygen generators should be transported aboard passenger carrying aircraft. Therefore, we are not adopting the ICAO amendment that would allow oxygen generators in protective breathing equipment to be transported in passenger carrying aircraft.]

IV. Section-By-Section Review

Part 171

Section 171.7

Paragraph (a)(3) (incorporation by reference materials) is updated to include the most recent editions of the ICAO Technical Instructions, the IMDG Code and the UN Recommendations. The updated editions of these standards become effective January 1, 2005. Additionally, the International Maritime Organization (IMO) recommends authorizing a one-year transition period, with a delayed compliance date of January 1, 2006, for the use of the updated edition (Amendment 32) of the IMDG Code.

The updated additions are as follows:

—The ICAO Technical Instructions, 2005-2006 Edition.

—The IMDG Code, Amendment 32.

—The UN Recommendations, Thirteenth Edition.

—The UN Manual of Tests and Criteria, 4th Revised Edition.

Paragraph (b) (list of informational materials not requiring incorporation by reference) is revised by adding an additional reference for a new method for determining the size of an emergency-relief device for portable tanks transporting organic peroxides. This revision is based on a petition for rulemaking numbered P-1428. The petition was submitted by the Organic Peroxides Producers Safety Division of the Society of the Plastics Industry, Inc.

One commenter recommended that we revise the “Note to Paragraph (h)(3)(vi)” in § 173.225 to maintain format consistency with the incorporation by reference entry for “Example of a Test Method for Venting Sizing: OPPSD/SPI Methodology” found in § 171.7(a). We disagree. The reference to a second example of a test method for venting sizing is not found in § 171.7(a) as a material incorporated by reference. Rather, it is found in § 171.7(b) as informational material not requiring incorporation by reference. Therefore, for clarification we are revising § 171.7(b) to include the reference to the “American Institute of Chemical Engineers Process Safety Progress Journal.” In addition, we are revising the “Note to Paragraph (h)(3)(vi)” in § 173.225 to include a reference to § 171.7(b), list of informational materials not requiring incorporation by reference.

Section 171.8

The definition for “salvage packaging” is revised to include the term “non-conforming.” The term “non-conforming” was added to the definition by the UN Committee of Experts in December 2000 to accommodate the use of salvage packaging for. Occasionally an undamaged package is found to be tested to a performance level which is less than that required for the specific substance it contains (e.g., a drum tested to PG II standards containing a PG I substance). In other instances, the package is found to be a non-performance tested packaging containing a regulated substance. In these situations, it may not be safe or practical to transfer the material to the correct packaging to continue on to the consignee in order to ensure compliance with the HMR. Therefore, the use of salvage packaging to contain “non-conforming” packages will minimize the risk to those handling the package during its transport back to the shipper or to an appropriate disposal location.

Section 171.11

Paragraph (d)(15) is revised to clarify that the limitations therein also apply to oxygen generators contained in personal breathing equipment. In addition, paragraph (d)(17) is revised to indicate that an organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d).

Section 171.12

In § 171.12, paragraph (b)(20) is revised to indicate that an organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d).

Section 171.12a

Paragraph (a) is revised to clarify the requirements for the return to Canada of bulk packagings that correspond to DOT or UN Specifications. Paragraph (b)(9)(ii) is revised to indicate that the shipping certification must be completed for shipments from Canada that enter the U.S. Paragraph (b)(18) is revised to indicate that an organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.22 must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d).

Section 171.14

Paragraphs (d) and (d)(1) are revised to authorize a delayed implementation date for the amendments in this final rule. The effective date of this final rule is January 1, 2005. We are also, authorizing a delayed compliance date of January 1, 2006, which is comparable to the transitional provisions provided in the final rule published under Docket HM-215E. The delayed mandatory compliance date offers sufficient time to implement the new requirements.

Paragraph (d)(2) is revised to authorize certain intermixing of old and new requirements.

Part 172

Section 172.101

The regulatory text preceding the Hazardous Materials Table is revised as follows:

Paragraph (c)(11) and the corresponding note to paragraph (c)(11) are amended to revise a section reference. The reference to § 173.225(c) in the first sentence is revised to read § 173.225(b) and the reference to § 173.225(c)(2) in the note to paragraph (c)(11) is revised to read § 173.225(b)(2).

Paragraph (d)(4) is revised by adding a statement indicating that when the abbreviation “Comb liq.” is found in the “Hazard class or division” column of the Hazardous Materials Table (column 3), the material falls into the “Combustible liquid” hazard class.

Paragraph (i)(3) of this section is revised to specify that Column 7 of the Hazardous Materials Table contains additional bulk packaging authorizations and limitations for the use of UN portable tanks.

§ 172.101 The Hazardous Materials Table (HMT). In this final rule we made various amendments to the HMT. Readers should review all changes for a complete understanding of the Table amendments. The HMT has been reprinted in its entirety due to the numerous changes. Under this final rule the changes to the HMT for the purpose of harmonizing with international standards, unless otherwise stated, include, but are not limited to the following:

  • We revised several entries by adding the qualifying word “liquid.” This action is consistent with the revisions to proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries are as follows:

UN1392 Alkaline earth metal amalgam

UN1420 Potassium metal alloys

UN1422 Potassium sodium alloys

UN1701 Xylyl bromide

UN1742 Boron trifluoride acetic acid complex

UN1743 Boron trifluoride propionic acid complex

UN2235 Chlorobenzyl chlorides

UN2236 3-Chloro-4-methylphenyl isocyanate

UN2306 Nitrobenzotrifluorides

UN2445 Lithium alkyls

UN2552 Hexafluoroacetone hydrate

UN2937 alpha-Methylbenzyl alcohol

UN3276 Nitriles, toxic, n.o.s.

UN3278 Organophosphorus compound, toxic, n.o.s.

UN3280 Organoarsenic compound, n.o.s.

UN3282 Organometallic compound, toxic, n.o.s.

UN3281 Metal carbonyls, n.o.s.

  • We revised several entries by adding the qualifying word “solid.” This action is consistent with the revisions to proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries are as follows:

UN1445 Barium chlorate

UN1447 Barium perchlorate

UN1459 Chlorate and magnesium chloride mixture

UN1470 Lead perchlorate

UN1578 Chloronitrobenzenes

UN1579 4-Chloro-o-toluidine hydrochloride

UN1650 beta-Naphthylamine

UN1680 Potassium cyanide

UN1689 Sodium cyanide

UN1690 Sodium fluoride

UN1697 Chloroacetophenone

UN1709 2,4-Toluylenediamine

UN1812 Potassium fluoride

UN1843 Ammonium dinitro-o-cresolate

UN2074 Acrylamide

UN2239 Chlorotoluidines

UN2261 Xylenols

UN2446 Nitrocresols

UN2662 Hydroquinone

UN3283 Selenium compound, n.o.s.

  • We revised several entries by removing the qualifying word “solid.” This action provides consistency with the Thirteenth Revised Edition of the UN Recommendations. The affected entries are as follows:

UN1489 Potassium perchlorate, solid

UN1598 Dinitro-o-cresol, solid

UN1638 Mercury iodide, solid

UN1740 Hydrogendifluorides, n.o.s. solid

UN2439 Sodium hydrogendifluoride, solid

  • We deleted several entries. This action removes from the HMR the solution form of entries that are not identified as solutions in the Thirteenth Revised Edition of the UN Recommendations. The deleted entries are as follows:

UN1489 Potassium perchlorate, solution

UN1598 Dinitro-o-cresol, solution

UN1638 Mercury iodide, solution

UN1740 Hydrogendifluorides, n.o.s. solutions

UN2439 Sodium hydrogendifluoride solution

  • We revised the proper shipping name “Butadienes, stabilized,” UN1010 to read “Butadienes, stabilized or Butadienes and hydrocarbon mixture, stabilized, containing more than 40% butadienes.
  • We revised the proper shipping name “Potassium hydrogendifluoride, solid,” UN1811 to read “Potassium hydrogendifluoride, solid.”
  • We revised the proper shipping name “Refrigerating machines, containing non-flammable, non-toxic, liquefied gas or ammonia solution (UN2672),” UN2857 to read “Refrigerating machines containing non-flammable, non-toxic gases or ammonia solutions (UN2672).
  • We removed four references to IB52 and four references to T23 from column 7 of the HMT. This change is necessary because IB52 and T23 have been relocated to § 173.225. The affected entries are:

UN3109 Organic peroxide type F, liquid

UN3110 Organic peroxide type F, solid

UN3119 Organic peroxide type F, liquid, temperature controlled

UN3120 Organic peroxide type F, solid, temperature controlled

  • IP5 is removed from column 7 of the HMT for the following UN entries:

UN1791 Hypochlorite solution

UN2014 Hydrogen peroxide, aqueous solution with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary).

UN3149 Hydrogen peroxide and peroxyacetic acid mixture with acid(s), water and not more than 5% peroxyacetic acid.

  • We deleted several entries. This action is consistent with the deletion of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations that we are proposing to adopt into the HMR. The entries affected are:

UN2003 Metal alkyls, water-reactive, n.o.s. or Metal aryls, water-reactive, n.o.s.

UN3049 Metal alkyl halides, water-reactive, n.o.s. or Metal aryl halides, water-reactive, n.o.s.

UN3050 Metal alkyl hydrides, water-reactive, n.o.s. or Metal aryl hydrides, water-reactive, n.o.s.

UN3207 Organometallic compound or Compound solution or Compound dispersion, water-reactive, flammable, n.o.s.

UN3203 Pyrophoric organometallic compound, water-reactive, n.o.s., liquid Pyrophoric organometallic compound, water-reactive, n.o.s., solid

UN3372 Organometallic compound, solid, water-reactive, flammable, n.o.s.

  • We added the following new entries. Many of these entries are the liquid or solid form of entries that are already listed in the HMT. This action is consistent with the addition of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. The new entries are as follows:

UN3377 Sodium perborate monohydrate

UN3378 Sodium carbonate peroxyhydrate

UN3379 Desensitized explosives, liquid, n.o.s.

UN3380 Desensitized explosives, solid, n.o.s.

UN3401 Alkali metal amalgam, solid

UN3402 Alkaline earth metal amalgam, solid

UN3403 Potassium metal alloys, solid

UN3404 Potassium sodium alloys, solid

UN3405 Barium chlorate solution

UN3406 Barium perchlorate solution

UN3407 Chlorate and magnesium chloride mixture solution

UN3408 Lead perchlorate solution

UN3409 Chloronitrobenzenes, liquid

UN3410 4-Chloro-o-toluidine hydrochloride solution

UN3411 beta-Naphthylamine solution

UN3413 Potassium cyanide solution

UN3414 Sodium cyanide solution

UN3415 Sodium fluoride solution

UN3416 Chloroacetophenone, liquid

UN3417 Xylyl bromide, solid

UN3418 2,4-Toluylenediamine solution

UN3419 Boron trifluoride acetic acid complex, solid

UN3420 Boron trifluoride propionic, acid complex, solid

UN3421 Potassium hydrogendifluoride solution

UN3422 Potassium fluoride solution

UN3423 Tetramethylammonium hydroxide, solid

UN3424 Ammonium dinitro-o-cresolate solution

UN3425 Bromoacetic acid, solid

UN3426 Acrylamide solution

UN3427 Chlorobenzyl chlorides, solid

UN3428 3-Chloro-4-Methylphenyl isocyanate, solid

UN3429 Chloro-toluidines, liquid

UN3430 Xylenols, liquids

UN3431 Nitrobenzotrifluorides, solid

UN3432 Polychlorinated biphenyls, solid

UN3433 Lithium alkyls, solid

UN3434 Nitrocresols, liquid

UN3435 Hydroquinone solution

UN3436 Hexafluoroacetone hydrate, solid

UN3437 Chlorocresols, solid

UN3438 alpha-Methylbenzyl alcohol, solid

UN3439 Nitriles, toxic, solid, n.o.s.

UN3440 Selenium compound, liquid, n.o.s.

UN3441 Chlorodinitrobenzenes, solid

UN3442 Dichloroanilines, solid

UN3443 Dinitrobenzenes, solid

UN3444 Nicotine hydrochloride, solid

UN3445 Nicotine sulphate, solid

UN3446 Nitrotoluenes, solid

UN3447 Nitroxylenes, solid

UN3448 Tear gas substance, solid, n.o.s.

UN3449 Bromobenzyl cyanides, solid

UN3450 Diphenylchloroarsine, solid

UN3451 Toluidines, solid

UN3452 Xylidines, solid

UN3453 Phosphoric acid, solid

UN3454 Dinitrotoluenes, solid

UN3455 Cresols, solid

UN3456 Nitrosyl-sulphuric acid, solid

UN3457 Chloronitrotoluenes, solid

UN3458 Nitroanisoles, solid

UN3459 Nitrobromobenzenes, solid

UN3460 N-Ethylbenzyltoluidines, solid

UN3461 Aluminium alkyl halides, solid

UN3462 Toxins, extracted from living sources, solid, n.o.s.

UN3464 Organophosphorus compound, toxic, solid, n.o.s.

UN3465 Organoarsenic compound, solid, n.o.s.

UN3466 Metal carbonyls, solid, n.o.s.

UN3467 Organometallic compound, toxic, solid, n.o.s.

UN3468 Hydrogen in a metal hydride storage system

A commenter stated that by adding the shipping names for desensitized explosives under identification numbers UN3379 and UN3380, approvals should be modified to authorize the use of classifications for the applicable hazardous materials. The commenter also noted that due to these additions, the definitions for flammable solids and flammable liquids require revision to account for the new shipping names. We do not anticipate a significant number of explosives being assigned to these shipping names. Therefore, we disagree with the commenter's contention that each holder of an EX number request an updated shipping classification. In addition, we do not agree with the commenter's request to revise the definitions of flammable solid and flammable liquid to include the additional proper shipping names. The definitions of flammable solid and flammable liquid adequately describe materials assigned to those shipping names. Additionally, shipping names are not found under hazard class definitions, but rather, in the HMT.

  • We added the following new generic entries for materials that are toxic by inhalation. These new names will replace the existing generic entries in the HMT. This action is consistent with the addition of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries are as follows:

UN3381 Toxic by inhalation liquid, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.

UN3382 Toxic by inhalation liquid, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.

UN3383 Toxic by inhalation liquid, flammable, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.

UN3384 Toxic by inhalation liquid, flammable, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.

UN3385 Toxic by inhalation liquid, water-reactive, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.

UN3386 Toxic by inhalation liquid, water-reactive, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.

UN3387 Toxic by inhalation liquid, oxidizing, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.

UN3388 Toxic by inhalation liquid, oxidizing, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.

UN3389 Toxic by inhalation liquid, corrosive, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.

UN3390 Toxic by inhalation liquid, corrosive, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.

  • We added the following new generic entries for organometallic substances. This action is consistent with the addition of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. The new entries are as follows:

UN3391 Organometallic substance, solid, pyrophoric

UN3392 Organometallic substance, liquid, pyrophoric

UN3393 Organometallic substance, solid, pyrophoric, water-reactive

UN3394 Organometallic substance, liquid, pyrophoric, water-reactive

UN3395 Organometallic substance, solid, water-reactive

UN3396 Organometallic substance, solid, water-reactive, flammable

UN3397 Organometallic substance, solid, water-reactive, self-heating

UN3398 Organometallic substance, liquid, water-reactive

UN3399 Organometallic substance, liquid, water-reactive, flammable

UN3400 Organometallic substance, solid, self-heating

In addition, we are continuing to allow the use of the following specific Organometallic entries: UN1366, UN1370, UN2005, UN2445, UN3051, UN3052, UN3053, and UN3076. However, we anticipate removing these entries from the HMT by January 1, 2007.

  • The U.N. Recommendations have adopted a rationalized approach for the assignment of UN portable tank instructions for solid materials. Based on that rationalized approach, we made several changes to UN portable tank authorizations in the HMR. These changes are summarized as follows. For a more specific identification of the affected shipping descriptions, refer to the UN report located in the public Docket.

For Division 4.1, Packing Group I materials, the use of UN portable tanks is not authorized.

For Division 4.3 materials with a subsidiary class of 6.1, in Packing Group I, the use of portable tanks is not authorized.

For materials of Divisions 4.1, 4.2, 4.3, 5.1, 6.1, and Classes 8 and 9, in Packing Group II, Special Provisions T3 is specified.

For Division 4.2, Packing Group I materials, T21 and TP7 is specified.

For Division 4.3, Packing Group I materials, T9 and TP7 is specified.

For Division 5.1, Packing Group I materials, the use of UN portable tanks is not authorized.

For Division 6.1 and Class 8, Packing Group I materials, T6 is specified.

For materials of Divisions 4.1, 4.2, 4.3, 5.1, 6.1, and Classes 8 and 9, in Packing Group III, Special Provisions T1 is specified.

  • Several entries in the HMT have been revised by amending column 9B to read “forbidden” so that the materials are no longer authorized for transport aboard cargo aircraft. The entries have been revised because they meet the criteria of either Zone C or Zone D inhalation toxicity. All other Zone C and Zone D toxic by inhalation materials listed in the HMR are currently already forbidden from transport aboard passenger and cargo aircraft (these materials are already forbidden from transport aboard passenger aircraft). The entries to be revised include:

Zone C

UN2204 Carbonyl sulfide

UN1023 Coal gas, compressed

UN1064 Methyl mercaptan

UN1048 Hydrogen bromide, anhydrous

UN1079 Sulfur dioxide

Zone D

UN1005 Ammonia, anhydrous

UN3318 Ammonia solution, relative density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia

UN1040 Ethylene oxide or Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 degrees C

UN1040 Ethylene oxide or Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 degrees C

UN2191 Sulfuryl fluoride

Also, see § 172.102 for additional HMT amendments.

Appendix B to § 172.101

In Appendix B to § 172.101, List of Marine Pollutants, we removed the entries “Diphenyl oxide and biphenyl phenyl ether mixtures,” “Isoamyl mercaptan,” “Pentanethiols,” and “Tetrachlorophenol.” We revised the entry “2, 6-Di-tert-Butylphenol” and we added the entry “Chloropicrin.”

Section 172.102

We amended § 172.102, Special Provisions, as follows:

  • Several entries in the HMT are revised by adding special provisions A3, A6, A7, A9, A10, N3, and N36 to align this section with the equivalent special provisions in the ICAO Technical Instructions (13, 2, 5, 4, 7, 21, and 3 respectively). We removed the “A” special provisions for several entries because we have determined that the materials to which the provisions apply are currently not authorized for transportation on either passenger or cargo aircraft.

The following entries are revised by adding special provision A3:

UN1154 Diethylamine

UN1788 Hydrobromic acid, not more than 49% strength

UN1789 Hydrochloric acid

UN2031 Nitric acid, other than red fuming, with more than 70% nitric acid

UN2604 Boron trifluoride diethyl etherate

  • The following entries are revised by adding A6:

UN1111 Amyl mercaptan

UN1228 Mercaptans, liquid, flammable, toxic, n.o.s.

UN1760 Corrosive liquid, n.o.s.

UN1903 Disinfectants, liquid, corrosive, n.o.s.

UN2031 Nitric acid, other than red fuming, with not more than 70% nitric acid

UN2054 Morpholine

UN2347 Butyl mercaptan

UN2363 Ethyl mercaptan

UN2402 Propanethiols

UN2801 Dye, liquid, corrosive, n.o.s.

UN2920 Corrosive liquid, flammable, n.o.s.

UN2922 Corrosive liquid, toxic, n.o.s.

UN3071 Mercaptans, liquid, toxic, flammable, n.o.s.

UN3093 Corrosive liquid, oxidizing, n.o.s.

UN3093 Corrosive liquid, oxidizing, n.o.s.

UN3094 Corrosive liquid, water-reactive, n.o.s.

UN3094 Corrosive liquid, water-reactive, n.o.s.

UN3098 Oxidizing liquid, corrosive, n.o.s.

UN3099 Oxidizing liquid, toxic, n.o.s.

UN3139 Oxidizing liquid, n.o.s.

UN3145 Alkylphenols, liquid, n.o.s. (including C2-C12 homologues)

UN3264 Corrosive liquid, acidic, inorganic, n.o.s.

UN3265 Corrosive liquid, acidic, organic, n.o.s.

UN3266 Corrosive liquid, basic, inorganic, n.o.s.

UN3267 Corrosive liquid, basic, organic, n.o.s.

UN3301 Corrosive liquid, self-heating, n.o.s.

  • The following entries are revised by adding special provision A7:

UN1167 Divinyl ether, stabilized

UN1277 Propylamine

UN1389 Alkali metal amalgam, liquid

UN1389 Alkali metal amalgam, solid

UN1391 Alkali metal dispersion or Alkaline earth metal dispersion

UN1407 Cesium or Caesium

UN1420 Potassium metal alloys

UN1421 Alkali metal alloy, liquid, n.o.s.

UN1422 Potassium sodium alloys

UN1431 Sodium methylate

UN1796 Nitrating acid mixture with not more than 50% nitric acid

UN1796 Nitrating acid mixture with more than 50% nitric acid

UN1826 Nitrating acid mixture, spent with not more than 50% nitric acid

UN1826 Nitrating acid mixture, spent with more than 50% nitric acid

UN1828 Sulphur chlorides

UN1938 Bromoacetic acid

UN2257 Potassium

UN2749 Tetramethylsilane

UN3093 Corrosive liquid, oxidizing, n.o.s.

UN3093 Corrosive liquid, oxidizing, n.o.s.

UN3094 Corrosive liquid, water-reactive, n.o.s.

UN3094 Corrosive liquid, water-reactive, n.o.s.

UN3205 Alkaline earth metal alcoholates, n.o.s.

UN3205 Alkaline earth metal alcoholates, n.o.s.

UN3206 Alkali metal alcoholates, self-heating, corrosive, n.o.s.

UN3206 Alkali metal alcoholates, self-heating, corrosive, n.o.s.

UN3208 Metallic substance, water-reactive, n.o.s.

UN3208 Metallic substance, water-reactive, n.o.s.

UN3208 Metallic substance, water-reactive, n.o.s.

UN3209 Metallic substance, water-reactive, self-heating, n.o.s.

UN3209 Metallic substance, water-reactive, self-heating, n.o.s.

UN3209 Metallic substance, water-reactive, self-heating, n.o.s.

  • The following entries are revised by adding special provision A9:

UN1449 Barium peroxide

UN1452 Calcium chlorate

UN3212 Hypochlorites, inorganic, n.o.s.

  • The following entries are revised by adding special provision A10:

UN1828 Sulphur chlorides

UN2401 Piperidine

  • The following entry is revised by adding special provision N3:

UN2817 Ammonium hydrogendifluoride solution

  • The following entries are revised by adding special provision N36:

UN1184 Ethylene dichloride

UN1732 Antimony pentafluoride

UN1777 Fluorosulphonic acid

UN2699 Trifluoroacetic acid

  • The following entries are revised by removing certain “A” special provisions since the materials themselves are forbidden for transportation aboard passenger and cargo aircraft:

UN1541 Acetone cyanohydrin, stabilized (remove A3)

UN1722 Allyl chloroformate (remove A3)

UN2692 Boron tribromide (remove A3, A7)

UN1744 Bromine or Bromine solutions (remove A3, A6)

UN2484 tert-Butyl isocyanate (remove A7)

UN2485 n-Butyl isocyanate (remove A7)

UN1752 Chloroacetyl chloride (remove A3, A6, A7)

UN1754 Chlorosulfonic acid (with or without sulfur trioxide) (remove A3, A6, A10)

UN2382 Dimethylhydrazine, symmetrical (remove A7)

UN1182 Ethyl chloroformate (remove A3, A6, A7)

UN2481 Ethyl isocyanate (remove A7)

UN2014 Hydrogen peroxide, aqueous solutions with more than 40 percent but not more than 60 percent hydrogen peroxide (stabilized as necessary) (remove A3, A6)

UN2015 Hydrogen peroxide, stabilized or Hydrogen peroxide aqueous solutions, stabilized with more than 60 percent hydrogen peroxide (remove A3, A6)

NA9206 Methyl phosphonic dichloride (remove A3)

UN2534 Methylchlorosilane (remove A2, A3, A7)

UN2304 Naphthalene, molten (remove A1)

UN1670 Perchloromethyl mercaptan (remove A3, A7)

UN1810 Phosphorus oxychloride (remove A7)

UN2740 n-Propyl chloroformate (remove A3, A6, A7)

UN1829 Sulfur trioxide, stabilized (remove A7)

UN1831 Sulfuric acid, fuming with 30 percent or more free sulfur trioxide (remove A3, A6, A7)

UN1834 Sulfuryl chloride (remove A3)

UN1836 Thionyl chloride (remove A7)

UN2474 Thiophosgene (remove A7)

UN1838 Titanium tetrachloride (remove A3, A6)

UN2441 Titanium trichloride, pyrophoric or Titanium trichloride mixtures, pyrophoric (remove A7, A8, A19, A20)

UN2442 Trichloroacetyl chloride (remove A3, A7)

UN1295 Trichlorosilane (remove A7)

UN2438 Trimethylacetyl chloride (remove A3, A6, A7)

  • Paragraph (b)(3) of this section is amended to specify that a “B” code refers to a special provision that applies only to certain bulk packaging requirements and that, unless otherwise stated, does not apply to UN, IM Specification portable tanks or IBCs.
  • Paragraph (b)(4) of this section is amended to specify that a code containing the letters “IB” or “IP” refers to a special provision that applies only to transportation in IBCs.
  • Paragraph (b)(7) of this section is amended to specify that a code containing the letter “T” refers to a special provision which applies only to transportation in UN or IM Specification portable tanks.
  • Paragraph (b)(8) is redesignated (b)(9) and a new paragraph (b)(8) is added to specify that a code containing the letters “TP” refers to a special provision that is in addition to those provided by the portable tank instructions or the requirements in part 178.
  • Special Provision 47 is revised to include an additional exception currently in the UN Model Regulations specifying that a leakproofness test is not required when the liquids are fully absorbed in solid material contained in sealed bags.
  • Special Provision 135 is revised to expand the applicability of the proper shipping names “Vehicle, flammable liquid powered” and “Vehicle, flammable gas powered” to include hybrid electric vehicles.
  • Special Provision 137 is revised to expand the exception for “Cotton, dry”.
  • Special Provision 143 is removed and relocated to § 173.219 so that the limitations on the types of hazardous materials authorized apply to both self-inflating and non-self-inflating life-saving appliances.
  • Special Provision 153 is relocated to new paragraph (k) in § 173.115 and revised to include amended classification criteria for aerosols containing flammable constituents consistent with criteria in the UN Model Regulations. The revised criteria include methods for the classification of aerosols based on the percentage of flammable components. One commenter agreed with the removal of Special Provision 153 and the relocation of classification criteria for aerosols to § 173.115(k).
  • New Special Provision 163 is added to specify that Ammonium Nitrate Emulsions are required to satisfactorily pass Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18.
  • New Special Provision 164 is added to specify that an approval is required for “Desensitized explosives, liquid, n.o.s.” and “Desensitized explosives, solid, n.o.s.”
  • New Special Provision 165 is added to the calcium hypochlorite PG II and the PG III entries for UN1748 and UN2880 to specify the danger of exothermic decomposition and require shading from direct sunlight and sources of heat during transportation. One commenter agreed with our efforts to harmonize the HMR with UN Recommendations, but was concerned with the intent of Special Provision 165. This commenter agreed that calcium hypochlorite should be shaded from direct sunlight but questioned the ambient heat and ventilation provisions. The commenter stated that calcium hypochlorite is currently transported in closed cargo transport units, thus, satisfying the requirement to protect this hazardous material from direct sunlight. However, since the cargo transport units are not ventilated by fan or induced ventilation, and the cargo transport units would be subjected to ambient heat, a violation of Special Provision 165 appears imminent. We disagree. We feel Special Provision 165 provides latitude for compliance with the ventilation and ambient heat requirements. Proper ventilation and protection from ambient heat can be achieved during the loading process of the cargo transport units and throughout the transportation cycle by allowing adequate space for air movement around the calcium hypochlorite packages. We do agree; however, that cargo transport units themselves should not be required to be shaded from direct sunlight. Therefore, we have revised the regulatory text accordingly.
  • New Special Provision 166 is added to the PG II entry for calcium hypochlorite, UN2880 and UN1748 to indicate that calcium hypochlorite in the non-friable tablet form may be transported as a PG III material.
  • New Special Provision 167 is added to the new entry for “Hydrogen in a metal hydride storage system” to specify that such storage systems shall always be considered as containing hydrogen.
  • New Special Provision 170 is added to Organometallic substances entries (UN3391, UN3392, UN3393, and UN3394). The special provision requires air to be eliminated from the vapor space by nitrogen or other means.
  • New Special Provision 171 is added to the UN2880 PG III entry. Since UN2880 also covers mixtures of hydrated calcium hypochlorite in any concentration, some formulations in other than tablet form (e.g., in granular form) may meet the criteria for classification in Division 5.1, Packing Group III when subjected to the relevant test in the UN Manual of Tests and Criteria. The PG III entry for calcium hypochlorite is only authorized when the material is offered in the non-friable tablet form or for granular or powdered mixtures. This entry is not authorized for the pure form of “Calcium hypochlorite, hydrated”. We also recognize that some formulations, when tested, do not meet the criteria for classification in Division 5.1. In light of this, we added a new Special Provision 171 to the UN2880, PG III entry in the HMT to allow for the possibility to classify powdered or granular mixtures of hydrated calcium hypochlorite in Packing Group III when data indicate that the mixture meets the criteria for assignment to PG III. One commenter supports the revisions that align calcium hypochlorite entries in the HMT with UN Recommendations. However, this commenter requested the addition of Special Provision 171 to the entry, “Calcium hypochlorite, dry or Calcium hypochlorite mixtures dry, (UN1748)” for consistent alignment with the UN Recommendations. We agree. After further review of the UN Recommendations, we have determined that the UN Special Provision 316 is equivalent to the proposed Special Provision 171 in Docket HM-215G, and is applicable to both the “dry” and “hydrated” calcium hypochlorite entries. Therefore, we are assigning Special Provision 171 to the “Calcium hypochlorite, dry or Calcium hypochlorite mixtures dry, (UN1748)” entry.
  • Special Provision A11 is currently assigned to UN 2983, Ethylene oxide and Propylene oxide mixtures and UN 1411, Lithium aluminum hydride, ethereal. In the ICAO Technical Instructions these substances are only authorized for transport in metal cylinders. A11 states “For combination packagings, when metal inner packagings are permitted, only specification cylinders constructed of metals which are compatible with the hazardous material may be used. In the NPRM, we proposed to harmonize with the applicable ICAO Technical Instruction particular packing requirement (PPR 8), however discussions with the ICAO Dangerous Goods Panel and further analysis of ICAO PPR 8 has revealed that the requirement may need to be amended. Our analysis showed that other packagings, including glass inner packagings, are authorized, and as such restricting packagings to only specification cylinders appears unnecessarily restrictive. As such we are not proposing to amend Special Provision A11 in this final rule.
  • Consistent with ICAO, we are adding a proper shipping name to the HMT for “Receptacles, small containing gas, 2.2 with a subsidiary of 5.1.” A new “A” code (A14) is added to prohibit this material from being transported as a limited quantity or consumer commodity in accordance with § 173.306 aboard an aircraft. This new “A” code has also been added to the following additional shipping names: “Oxygen, compressed,” Carbon dioxide and oxygen mixtures,” “Nitrous oxide”, “Compressed gas oxidizing,” and “Liquefied gas, oxidizing.”
  • For consistency, the authorization in Special Provision B69 to allow dry sodium or potassium cyanide in siftproof, water-resistant fiberboard IBCs is relocated to new Special Provision IP20.
  • Paragraph (c)(4) of this section is amended by relocating “Table 2.—Organic Peroxide IBC Code (IB52)” to paragraph (e) of § 173.225 and renaming it the “Organic Peroxide IBC Table.” Table 3.—IP Codes is redesignated Table 2.—IP Codes. The wording of paragraph (c)(4) is revised to indicate that Table 3.—IP Codes had been redesignated Table 2.—IP Codes. All references to IB52 in the HMR are removed and replaced with “Organic Peroxide IBC Table” or “§ 173.225(e),” as applicable.
  • Paragraph (c)(7) is amended by relocating the Portable Tank Code T50 Table to § 173.313 and renaming it “UN Portable Tank Table for Liquefied Compressed Gases.” The T50 Table and its description is removed from paragraph (c)(7)(iv) and replaced with a statement indicating that the new “UN Portable Tank Table for Liquefied Compressed Gases” is found in § 173.313. All references to T50 in the HMR are removed and replaced with “UN Portable Tank Table for Liquefied Compressed Gases in § 173.313.” In addition, paragraph (c)(7) is amended by relocating Portable Tank Code T23 to paragraph (g) of § 173.225 and renaming it the “Organic Peroxide Portable Tank Table.” Portable Tank Code T23 and its description found in paragraph (c)(7)(iii) are removed and paragraphs (c)(7)(iv)-(c)(7)(vii) are redesignated (c)(7)(iii)-(c)(7)(vi), respectively. All references to T23 in the HMR are removed and replaced with “Organic Peroxide Portable Tank Table” or “§ 173.225(g),” as applicable.
  • New paragraph (c)(8) is added to provide an introduction to the “TP” codes (i.e., portable tank special provisions). The existing paragraph (c)(8) is redesignated paragraph (c)(9).
  • New Special IBC Packing Provision IP13 is added to specify that transportation by vessel in IBCs is prohibited.
  • New Special IBC Packing Provision IP14 is added to specify that air must be eliminated from the vapor space by nitrogen purging or other means.
  • New Special IBC Packing Provision IP20 is added to specify that dry sodium cyanide and potassium cyanide are also permitted in siftproof, water-resistant, fiberboard IBCs when transported in closed freight containers or transport vehicles.
  • Portable tank Special Provision TP3 is revised to include the maximum degree of filling (in %) for solids transported above their melting points.
  • Special Provision TP6 is revised by removing the word “event” and replacing it with the word “incident.”
  • Portable tank Special Provision TP9 is removed from column (7) of the HMT for all materials that reference a T code special provision. Special provision TP9 states that a material with TP9 in Column (7) may only be transported in a portable tank if approved by the Associate Administrator. A material that has been given a T code does not require approval and is not subject to Special Provision TP9.
  • In the NPRM we proposed adoption of a new portable tank special provision, TP33, by adding the new provision to certain entries in the HMT. However, we neglected to include the text of the provision itself. We are correcting this omission in this final rule.

Section 172.202

We are editorially revising paragraph (a)(2)(iii) by removing the examples that illustrate the optional provision to enter primary and subsidiary hazard class or division names on shipping papers for domestic shipments. In the HM-215E response to appeals final rule (69 FR 34604) that was published on June 22, 2004, we reinstated the provision which was removed in a previous rulemaking (68 FR 44992). During the process of correcting a printing error in one of the examples, we determined that the regulatory text is complete and sufficient without the use of examples.

In the NPRM [69 FR 34741] we proposed to amend paragraph (a)(5)(i) to require the quantity shown on a shipping paper for an explosive article, such as Cartridges, small arms, to be the net mass of the entire article rather than the net mass of the explosive contained in the article. Commenters generally support the proposal, suggesting that it will provide for consistency across modes of transportation and for more accurate calculations. However, several of these commenters note that, for certain explosive articles that contain very small amounts of an explosive, showing the net mass of the article rather than of the explosive contained in the article could misrepresent the transportation risk associated with the article. Two commenters state that, because shippers have historically calculated the net mass based on the actual explosive material contained in the article rather than the entire article, the clarification proposed in the NPRM could cause increased confusion for shippers.

Internationally, as well, there is some concern that, at least for large explosive articles, the quantity indicated on the shipping paper should be the net mass of the explosive substances contained in the article rather than the net mass of the article itself. As suggested by some commenters to the NPRM, a number of the members of UN Transport of Dangerous Goods Sub-Committee agree using the net mass of the entire article rather than the net mass of the explosive material contained in the article may not appropriately communicate the explosive hazard to emergency responders. Until this issue is resolved through a change to the UN Model Recommendations, we are, in this final rule, amending paragraph (a)(5)(i) to clarify that for explosive articles the quantity shown on a shipping paper may be expressed in terms of the net mass of the article or the net mass of the explosive substances contained in the article. It should be noted, however, that for purposes of determining the per-package quantity limitations shown in Column 9 of the HMT, § 172.101(j)(3) specifies that when articles or devices are specifically listed by name, the net quantity limitation applies to the entire article or device rather than to its hazardous components. This would include explosive articles listed by name in the HMT. For example, in the case of a listed explosive article weighing 15 kg and containing 500 grams of explosive substance, the weight shown on the shipping paper may be 500 grams or 15 kg, but the weight used for purposes of compliance with Column (9) of the HMT must be 15 kg as required by § 172.101(j)(3).

Particularly for large articles, the quantity indicated on the shipping paper should be the net mass of the explosive substances contained in the article. For small explosive articles, such as Cartridges, small arms, we believe that the net mass of the article can be used to satisfy the total quantity requirement in § 172.202(a)(5)(i). As a practical matter, it is easier, and in certain instances necessary, for an offeror to provide the net mass of the article and the net explosive mass. For example, as previously stated, the net mass of an article must be used to ensure compliance with the per package quantity limitations set forth in Column 9 of the § 172.101 Hazardous Materials Table for transport aboard aircraft or passenger rail (see § 172.101(j)(3)). However, for operational purposes, such as for stowage and segregation of large quantities of explosives or determining the quantity of explosives that can be transported on a vessel [see § 176.142(b)], the net explosive mass of the explosive substances contained in articles is needed.

Section 172.203

Paragraph (f) is revised by including the passenger and cargo aircraft limitation certification statement that is found in § 172.204. This aligns the HMR with the ICAO TI (see 4.1.5.8.1(b) of the ICAO TI). A new paragraph (i)(3) is added to specify additional shipping paper description requirements for a hazardous material consigned under an “n.o.s.” entry when offered for transportation by vessel. In addition, paragraph (m)(2) is revised to specify that the phrase “Poison Inhalation Hazard” or “Toxic Inhalation Hazard” is not required to be repeated if it otherwise appears in the shipping description. Finally, in paragraph (o)(3), the reference to § 173.225(c)(2) is amended to read § 173.225(b)(2).

One commenter felt the requirement to add a segregation code on the shipping paper for “n.o.s.” entries is unnecessary and unduly burdensome. In addition, the commenter is concerned that there may not be sufficient space on the shipping paper to indicate this notation. If, however, this requirement is adopted, the commenter requested an example of the required entry on shipping papers. We disagree. We do not feel this additional requirement is unnecessary or overly burdensome. The additional shipping paper description requirements apply only to hazardous material consigned under an “n.o.s.” entry when offered for transportation by vessel. We believe that consignors should be familiar with the hazards and segregation risks of their shipments, specifically “n.o.s.” materials that are not assigned segregation groups. By indicating the need to segregate such materials on the shipping paper, the consignor increases the likelihood that appropriate stowage procedures are followed, ensuring the safety of the vessel and its cargo. We also do not agree that there is inadequate space available on shipping papers to include the segregation group. However, we do agree that an example of the required entry should be presented for clarity and uniformity. Therefore, as recommended by the commenter, we are adding the example “IMDG Code segregation group—1 Acids” to § 172.203.

Section 172.204 and Section 172.321—Air Eligibility Marking

Under HM-215E (68 FR 44992), the air eligibility marking was adopted into the HMR as new § 172.321. Since publication of that final rule, the ICAO's Dangerous Goods Panel removed the air eligibility marking requirement from the ICAO Technical Instructions. In lieu of this marking, ICAO adopted a requirement that the shipping paper certification statement include the statement “I declare that all of the applicable air transport requirements have been met” when a hazardous material is offered for air transportation. Additionally, the revised section provided examples of the applicable air transport requirements that must be met. Based on this action, we revised the air eligibility marking requirement by making it optional rather than mandatory and adding the additional shipping paper certification statement for shipments going by aircraft. Therefore, we revised § 172.204(c)(3) by requiring that the statement “I declare that all of the applicable air transport requirements have been met” be included on the shipping paper in addition to the current certification statement when a hazardous material is offered for air transportation. Additionally, the revised section provides examples of the applicable air transport requirements that must be met and various section references. In order to allow shippers to expend stocks of preprinted shipping papers containing the previous certification statement, we are providing an additional ten month transitional provision for the new certification statement. Two commenters support RSPA's decision requiring shippers to sign the certification declaring compliance with requirements for air transportation. Additionally, several commenters agree with the revision to make the air eligibility marking optional. However, some commenters suggest making the marking “permissible” instead of “optional” to avoid potential confusion. We disagree. We are removing the requirement for shippers to mark packages acceptable for air transport with the air eligibility marking. This revision does not prohibit the use of the marking.

Section 172.315

Section 172.315 is amended to ensure that packages containing limited quantities which are transported by air are marked with the proper shipping name. Although the amendment was not proposed in this rulemaking, it was previously proposed and adopted under HM-215E (68 FR 45000) but was omitted due to an editorial error during publication. The amendment provides harmonization with the ICAO Technical Instructions, which do not allow the UN number within a square-on-point border as a substitute for the proper shipping name. Note that this amendment does not preclude the ID number/square-on-point border from appearing on a package transported by air, it simply ensures that the proper shipping name is also required.

Section 172.317

A new § 172.317 is added to require a “KEEP AWAY FROM HEAT” handling mark on packages containing self-reactive substances of Division 4.1 or organic peroxides of Division 5.2 when such packages are transported by air.

Part 173

Section 173.3

The NPRM proposed to revise the requirements for use of salvage drums to include packages of hazardous materials that are found not to conform with the requirements of the HMR. In addition, the NPRM proposed to clarify that salvage drums may only be used for damaged, defective, non-conforming, or leaking packages identified as such after the packages have been placed in transportation. One commenter suggests that the phrase “after having been placed in transportation” as used in the NPRM is confusing and requests that we clarify the phrase using the terms “pre-transportation functions” and “transportation functions” as defined in a final rule published under Docket HM-223 October 30, 2003 (68 FR 61905). In response to this comment, in this final rule, we modified § 173.3(c) to clarify that salvage drums are to be used for damaged, defective, non-conforming, or leaking packages identified during transportation as “transportation” is defined in § 5102(12) of Federal hazardous materials transportation law—that is, the movement of property and loading, unloading, or storage incidental to the movement. When the HM-223 final rule becomes effective, the statutory definition for “transportation” will be added to § 171.8 of the HMR, as will definitions for “movement,” “loading incidental to movement,” “unloading incidental to movement,” and “storage incidental to movement.” Note that a package found to be leaking prior to its being placed in transportation may not be packaged in a salvage drum. Instead, it must be repackaged into an authorized packaging in accordance with applicable HMR requirements.

Section 173.24

For consistency with the UN Recommendations, paragraphs (g)(4) and (g)(5) are revised to clarify the following:

(A) That IBCs (subject to the requirements in § 173.24(g)) are permitted to be vented to reduce internal pressure; and

(B) That venting of IBCs is not conditional upon whether a bulk special provision is indicated for a particular hazardous material in the § 172.101 hazardous materials table.

In addition, paragraph (i) is revised to clarify that other general requirements specific to air transportation apply and are found in § 173.27.

Section 173.25

Paragraph (a)(2) is revised by removing the requirement to mark an overpack with the air eligibility marking. In addition, in paragraph (a)(4), we are amending the HMR to require overpacks to be marked with the word “OVERPACK” or, alternatively, until October 1, 2007, with a statement indicating that inside packages comply with prescribed specifications. This is in response to adoption by the United Nations of the “OVERPACK” marking to indicate that packages within an overpack comply with prescribed specifications when specification markings on inside packagings within the overpack are not visible.

Section 173.27

Paragraph (i) is revised to indicate that the air eligibility mark has been removed. This section references a new requirement for shippers to place the following statement at the end of the certification statement when a hazardous material is authorized for air transportation: “I declare that all applicable air transport requirements have been met.”

Section 173.28

In paragraph (c)(2), we deleted the words “or a UN 1H1 plastic drum” in order to harmonize the HMR with the UN Model Regulations and remove a source of confusion within the regulated community regarding the reconditioning of a non-bulk packaging.

Section 173.115

In § 173.115, a new paragraph (k) is added (see discussion under § 172.102, Special Provision 153). One commenter noted that the proposed new § 173.115(k) would not allow aerosols to contain corrosive substances of Packing Group II. The commenter further noted that UN Special Provision 63 allows aerosols to contain corrosive substances of Packing Group II and requested we harmonize with the UN Special Provision 63 in this regard. We agree with the commenter and further note that currently, the HMR authorizes a proper shipping name of “Aerosols, corrosive Packing Group II or III, each not exceeding 1 L capacity”. We are amending § 173.115(k) accordingly to clarify that aerosols may contain corrosive substances of Packing Group II.

Section 173.120 and Appendix H to Part 173

A commenter noted that under section § 173.120(a)(3), the reference to Appendix H for sustained combustibility tests directs the reader to Figures 5.1 and 5.2 found in the UN Recommendations. These figures are no longer in the UN Recommendations, but, rather, are located in section 32.5.2 of the Fourth Revised Edition of the UN Manual of Tests and Criteria. We agree with the commenter. Therefore, we are amending Appendix H to Part 173 to reference the UN Manual of Tests and Criteria.

Section 173.128

In paragraph (d)(1)(i), the section reference is revised to read § 173.225(c). In addition, in paragraphs (d)(1)(ii) and (d)(1)(iii), the section reference is revised to read § 173.225(b).

Section 173.132

In paragraph (b)(1), we revised the definition of LD50 for acute oral toxicity to indicate that adult albino rats may be tested without regard to gender. The current definition for LD50 for acute oral toxicity in § 173.132(b)(1) is based on the Organization for Economic Co-Operation and Development (OECD) Test Guideline (TG) 401. The OECD has agreed to three test methods that will replace the current TG 401. The United Kingdom, Germany and the United States of America took the lead in the development of the three alternative tests that OECD has now adopted and published in the OECD Guidelines for the Testing of Chemicals. In a continuing attempt to improve the estimate of acute oral toxicity while reducing the number of animals used per test, three alternative TGs have been developed and implemented to replace TG 401. The three TGs are the Fixed Dose Procedure (FDP, TG 420), the Acute Toxic Class Method (ATCM, TG 423), and the Up-and-Down Procedure (UDP, TG 425). The text is consistent with the text in the 13th revised edition of the UN Model Regulations.

Section 173.136

We added a new paragraph (d) to provide a grandfather clause that will allow for the continued shipment of materials classified as corrosive to steel or aluminum under ASTM G 31-72 without retesting.

Section 173.137

In paragraph (c)(2), we propose to eliminate the references to ASTM G 31-72 as an acceptable test description and add a statement indicating an acceptable test is prescribed in the Manual of Tests and Criteria, Part III, Section 37.

Sections 173.150, 173.151, 173.152, 173.153 and 173.154

We are allowing most Division 6.1, Packing Group II materials to be transported under the limited quantity provisions when the packagings contain not more than 100 mL (3.38 ounces) each for liquids or 0.5 kg (1.1 pounds) each for solids. However, consistent with the limited quantity authorization for Division 6.1, Packing Group III, we are not providing a labeling exception for these materials. We are also not allowing these materials to be shipped as consumer commodities. In addition, we revised the limited quantity sections for the other hazard classes of materials to take into account materials with a subsidiary hazard of 6.1 Packing Group II. One commenter agreed with the amendment allowing numerous Class 3, PG II materials with Class 8 and other subsidiary hazards to be transported as limited quantities.

Section 173.185

In § 173.185, we amended paragraphs (c)(3) and (e)(6), to require those lithium cell and battery design types that are required to be subjected to the UN performance tests to be of a type that is proven to meet the requirements of the performance tests specified in the UN Manual of Tests and Criteria, Fourth Revised Edition. These cells and batteries are currently required to be of a type that is proven to meet the tests in the third revised edition. We also proposed a grandfather provision that would authorize a lithium cell or battery that was transported prior to the effective date of this rule that is of a type proven to meet the UN performance tests in the third revised edition to not be required to be retested in accordance with the tests in the fourth revised edition. One commenter supported this approach and stated that it is both necessary and appropriate to allow continued transport of cells and batteries tested and qualified under the UN lithium battery design qualification tests in accordance with the UN Manual of Tests and Criteria, Third Revised Edition. The commenter further stated that providing a grandfather provision for previously tested cells and batteries would avoid the need and expense of requalifying these cells and batteries in accordance with the new tests prescribed in the Fourth Revised Edition of the UN Manual of Tests and Criteria. After further consideration, we believe that authorizing an indefinite period for the transport of batteries that were tested in accordance with the UN Manual of Tests and Criteria, Third Revised Edition, 1999 may not be in the best interest of safety. The tests in the UN Manual of Tests and Criteria, Fourth Revised Edition provide a slightly higher level of safety and we believe that further consideration needs to be taken in considering whether at some point in time all applicable lithium batteries and cell design types should be proven to meet the requirements of the UN Manual of Tests and Criteria, Fourth Revised Edition. As a result, we will issue a proposal shortly specifically to address the full unrestricted adoption of the Fourth Revised Edition of the UN Manual of Tests and Criteria.

Section 173.186

In § 173.186, in paragraph (e), we amended the gross weight for UN 4G outer packages authorized for the transportation of strike-anywhere matches, to be consistent with the UN Model Regulations by increasing the weight from 27 kg (60 pounds) to 30 kg (66 pounds).

Section 173.187

We revised § 173.187 to authorize certain solid hazardous materials to be transported in DOT specification cylinders other than Specification 8 and 3HT cylinders. This change eliminates the need for DOT Exemption “DOT-E 11548.”

Sections 173.211, 173.212, and 173.213

We revised these sections to authorize certain solid hazardous materials to be transported in DOT specification cylinders other than Specification 8 and 3HT cylinders. This change removed the need for DOT Exemption “DOT-E 11548.”

Section 173.219

We revised § 173.219 for consistency with the UN Model Regulations and the ICAO Technical Instructions. Included in the revision is an allowance for self-inflating life-saving appliances to contain cartridges, power devices of Division 1.4S, for purposes of the self-inflating mechanism. In addition, we provided an exception from regulation for life-saving appliances containing only carbon dioxide cylinders not exceeding 100 cm3 capacity, provided they are overpacked in rigid outer packagings with a maximum gross mass of 40 kg. Finally, the limitations currently found in Special Provision 143 are relocated to § 173.219 (see preamble discussion under Special Provision 143).

Section 173.220

Paragraph (b)(2) is amended to harmonize the requirements for transporting flammable gas powered vehicles by air with the requirements of Packing Instruction 900 of the ICAO Technical Instructions.

Section 173.224

Paragraph (b)(4) of this section is amended to include the new references for § 173.225. The section reference to § 173.225(e) for the authorization of bulk packagings is replaced with § 173.225(f) for IBCs and § 173.225(h) for other bulk packagings.

Section 173.225

This section is amended to update the Organic Peroxide Table and eliminate special provisions IB52 and T23 from § 172.102(c). The purpose of the change is to consolidate the packaging requirements for organic peroxides into one section and to have separate tables for organic peroxides authorized for transport in non-bulk packagings, IBCs, and bulk packagings other than IBCs. The changes are as follows:

Paragraph (a) is revised by adding paragraphs (b) and (b)(6), which state that bulk packagings may require a lower control temperature than those specified for non-bulk packagings and that an organic peroxide not identified in either the Organic Peroxide Table, Organic Peroxide IBC Table, or Organic Peroxide Portable Tank Table must be approved under § 173.128(c).

Paragraph (b) is revised to eliminate all IBC and other bulk packaging authorizations from column 6 of the Organic Peroxide Table. Various obsolete entries were also removed. The current paragraph (b), “Organic Peroxide Table,” is moved to paragraph (c) and the current paragraph (c), “New organic peroxides, formulations and samples,” is moved to paragraph (b).

The notes following the Organic Peroxide Table are changed as follows:

  • Revise note 22 to indicate that ethylbenzene with greater than or equal to 25% of dilutant type A is acceptable.
  • Revise note 23 to indicate that methyl isobutyl keytone with greater than or equal to 19% of dilutant type A is acceptable.
  • Add a new note 29 to identify materials which are not included in the UN Model Regulations and note that a Competent Authority approval is required for international transportation.
  • Remove Notes 9, 11, and 14 following the Organic Peroxide Table.

In addition, The Packing Method Table found in paragraph (d), is revised by replacing the 200 kg maximum quantity for solids and combination packagings listed in OP8 with a 400 kg maximum quantity. Note 2, following the table, is revised to allow 200 kg of solid material per box and up to 400 kg of material per authorized combination packaging. The note also indicates that the outer packaging must be a box (4C1, 4C2, 4D, 4F, 4G, 4H1, and 4H2) and each inner packaging must be of plastics or fiber with a maximum net mass of 25 kg. Paragraph (d)(3) is clarified by revising the text to state that the maximum content acceptable for glass receptacles used as inner packagings of a combination packaging is 0.5 kg for solids or 0.5 L for liquids.

A new paragraph (e) is added to include the new “Organic Peroxide IBC Table” that replaces the current “Table 2.—Organic Peroxide IBC Code (IB52)” in § 172.102(c)(4). The new table is revised to add an organic peroxide, “Dicyclohexylperoxydicarbonate, not more than 42% as a stable dispersion, in water.” In addition, the new Organic Peroxide IBC Table identifies, by technical name, those organic peroxides authorized for transportation in the IBCs that are specifically listed in the table.

A new paragraph (f) is added to include the current IBC requirements contained in paragraph (e)(5) of this section. Paragraph (f) also includes requirements that are specific to organic peroxides packaged in IBCs.

A new paragraph (g) is added to include the new “Organic Peroxide Portable Tank Table,” that replaces the current “Portable Tank Code T23” found in § 172.102(c)(7)(iii). The new table is identical to the current table except that for UN 3109, in the entry for Pinanyl hydroperoxyde, 50% is replaced by 56% and all references to self-reactive materials are removed. In addition, the Organic Peroxide Portable Tank Table provides certain portable tank requirements and identifies, by technical name, those organic peroxides authorized for transportation in the bulk packagings listed in the new paragraph (h).

The current paragraph (e) is redesignated as paragraph (h). Paragraph (h) establishes requirements that are specific to organic peroxides packaged in certain bulk packagings. Additionally, the new “Note to Paragraph (h)(3)(vi)” is revised to include changes brought forth by petition for rulemaking P-1428. The petition proposed to amend the current paragraph (e)(3)(vi) and allow for a second but equally acceptable example of an emergency-relief device sizing method to be added to the HMR. We agreed with the petitioner and added a statement to the new paragraph (h)(3)(vi) indicating that an additional example of an emergency-relief device sizing method can be found in the “American Institute of Chemical Engineers Process Safety Progress Journal, June 2002 issue (Vol. 21, No. 2)” as referenced in § 171.7(b).

The changes to this section altered the order of the paragraphs within this section; therefore, various citations were changed. Also, paragraphs referencing IB52 or TP23 are revised to indicate that those provisions no longer exist and the updated requirements are found in paragraph (e) and (g), respectively. A commenter requested that § 173.225 be revised to allow for increased industry flexibility, regulatory uniformity, and to better align with the UN Recommendations. We agree and have made the following revisions:

  • Added wording to 173.225(a) to show that organic peroxides that are not identified in the organic peroxide table, but are in paragraph (b)(3) are not subject to the requirements of § 173.128.
  • Removed Note 1 from both entries of tert-Butyl cumyl peroxide and Note 11 from Dicumyl peroxide.
  • Removed the sentence “The additional requirements in paragraph (h)(5)(i) and (h)(5)(ii) of this section also apply” from § 173.225(f) and renumbered (f)(i) and (f)(ii) as (f)(1) and (f)(2), respectively.
  • Revised the introductory text to Paragraph (h) to indicate that the bulk packagings that follow are for materials authorized for transport in a bulk packaging by Paragraph (h) and organic peroxides listed in the Organic Peroxide Portable Tank Table.
  • Removed two occurrences of the term “Type F” from Paragraph (h)(3) to broaden the applicability of the provisions.
  • Removed statement from § 173.225(h)(3)(xii) indicating that DOT Specification 57 portable tanks are not subject to the requirements of paragraphs (h)(3)(ii) and (h)(3)(iv) of this section.

Sections 173.226 and 173.227

We revised the packaging requirements of §§ 173.226 and 173.227 for materials poisonous by inhalation, Division 6.1, Packing Group I, Hazardous Zone A and Hazard Zone B. These amendments have: Reduced the hydrostatic test pressure of the inner drum in a drum-within-a-drum configuration authorized in § 173.226(b); standardized the minimum thickness requirements of the inner drums in the drum-within-a-drum configuration authorized in §§ 173.226(b) and 173.227(b); clarified the test requirements for inner packaging systems in § 173.226(b)(2)(iv); and in § 173.226(d) added a provision to authorize transportation of PIH materials in single packages when subjected to additional operational controls and approved by the Associate Administrator. Section 173.226(c)(2) is reformatted for ease of understanding. We removed an expired transitional date from paragraph (a) that allows the transport of welded cylinders filled before October 1, 2003 for the purpose of reprocessing or disposal of cylinders's content until December 31, 2003. One commenter recommended that we include a provision in § 173.227(b) to allow for the testing of the outer drum of a drum-in-drum package as either as a package intended to contain inner packagings (combination package) or as a single packaging intended to contain solids or liquids. We agree and have revised § 173.227(b) accordingly. Another commenter suggested that we increase the minimum thickness of a UN 1A1 drum in PIH service from .69 mm to 1.0 mm. Increasing the minimum thickness of a UN 1A1 drum in PIH service was not proposed in this rulemaking and inclusion of such a requirement is beyond the scope of this rulemaking. However, we are reviewing this request for consideration in a future rulemaking.

Section 173.249

Paragraph (c) is revised to be consistent with the current “Bromine” entry in the § 172.101 “Hazardous Material Table” that authorizes the use of a UN portable tank conforming to tank code T22. A commenter suggested that we include a provision authorizing the returning of a tank containing bromine residue. We agree that such a provision is necessary and have amended § 173.249 accordingly.

Sections 173.306 and 173.307

To add clarity to the HMR, the text currently found in § 173.306(i) is removed and replaced with the text currently found in § 173.307(a)(5). Since § 173.306 is devoted exclusively to limited quantities of compressed gases, relocating § 173.307(a)(5) to § 173.306 makes the exception easier to find.

Section 173.313

A new § 173.313 is added to serve as the new location for the Portable Tank Code T50 Table. The table is renamed “UN Portable Tank Table for Liquefied Compressed Gases.” The table provides the maximum allowable working pressures, bottom opening requirements, pressure relief requirements and degree of filling requirements for liquefied compressed gases permitted for transport in portable tanks. The change relocates these packaging requirements to Part 173, which is a more appropriate location, and makes the special provisions less cumbersome. In addition, the new UN Portable Tank Table for Liquefied Compressed Gases is amended by revising the Column 3 heading to read “Minimum design pressure (bar) * * *” The values in column 3 are actually minimum values, however the title of the column is misleading because it uses the term “Maximum allowable working pressure (bar) * * *”

Section 173.315

In paragraph (a), the reference to “portable tank provision T50 in § 172.102” is revised to read “the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313.”

Section 173.323

After further considering the proposed changes to the packaging authorizations for ethylene oxide in § 173.323, we noted that the total quantity per package of ethylene oxide authorized for transport when glass inner receptacles are used was proposed to be increased from 100 grams to 2.5 kg. Due to the extremely flammable and explosive properties of ethylene oxide and the fragile properties of glass, after further consideration we have chosen not to adopt the 2.5 kg outer package limit found in the UN Recommendations and to retain our current outer package limit of 100 grams. The total quantity per package when metal inner receptacles are used will remain unchanged from the proposed 2.5 kg. In this rule, paragraphs (b)(1)-(b)(3) are revised and consolidated for consistency with current international requirements for the transportation of ethylene oxide in combination packagings. Paragraphs (b)(1)-(b)(3) provide the current authorizations for glass, aluminum, and metal receptacles respectively. Amendments to this section include (1) removing the HMR limitation of 12 inner receptacles per outer package currently applied to aluminum and other metal receptacles, (2) removing the overpack restriction in (b)(2) which specifies a maximum of 10 boxes per overpack, (3) requiring a hot water bath test for all inner receptacles, (4) removing the pressure relief device and burst pressure requirements currently applied to metal receptacles, (5) applying the same outer package authorizations consistently to all inner packaging types and allowing any outer package authorized in § 172.201(b), and (6) requiring all inner packagings to be suitably cushioned (the top and bottom pad and perimeter liner requirement currently only applied to outer packages containing aluminum inner packagings is removed). Though we are eliminating the option to utilize certain packaging authorizations for glass and aluminum inner packagings, we believe that this change will have little or no economic impact on the ethylene oxide industry because of the amount of materials that are transported in international commerce. 3M Package Engineering requested that we reduce the maximum quantity of ethylene oxide permitted in any metal inner packaging from 340 g (12 ounces) to 200 g (7 ounces). They stated that such a change would more adequately align the HMR with international standards. We agree that such a change would align the HMR with international requirements. However, allowing a metal inner packaging to contain a maximum quantity of 340 g (12 ounces) does not limit compliance with international requirements. In addition, we cannot adopt the 200 g (7 ounces) limitation in this rulemaking because such a change would be more restrictive then the requirements we proposed. We may consider adopting the 200 g (7 ounces) limitation in a future rulemaking.

Part 175

Section 175.10

Consistent with an amendment to the ICAO TI, we are requiring that aerosol cans that are carried aboard an aircraft in accordance with § 175.10(a)(4) have their release devices protected by a cap or other suitable means. In addition, the ICAO Dangerous Goods Panel will convene a series of working groups to develop recommendations for consideration during the 20th session of the Dangerous Goods Panel to further review this issue. These recommendations may lead to additional amendments to the ICAO TI. Finally, we note that non-flammable gases (e.g., nitrogen) other than carbon dioxide are used for the operation of mechanical limbs. Consistent with an amendment to the ICAO TI, we are proposing to provide an exception from the HMR for mechanical limbs that are powered by any Division 2.2 gas. One commenter recommended that the release device requirements added to § 175.10 also be incorporated into Part 173. Specifically, they requested that aerosol cans that are transported in commerce be protected by a cap or other suitable means to prevent inadvertent release. They indicated that this change should be coordinated with the Federal Aviation Administration (FAA). We disagree. Section 173.24(b)(1) states that each package used for the shipment of hazardous materials must be constructed, maintained, filled, its contents so limited, and closed, so that under conditions normally incident to transportation there will be no identifiable release of hazardous materials to the environment. We feel this section adequately addresses the commenter's concerns, and allows shippers the flexibility to properly protect aerosol cans.

Section 175.85

In § 175.85, a new paragraph (j) is added to specify the cargo location of a package bearing the “KEEP AWAY FROM HEAT” handling marking.

Part 176

Section 176.2

Certain definitions are revised. The definitions for “Explosive article” and “Explosive substance” are revised to remove an incorrect reference. The definition for “Magazine” is revised to include a compartment in the vessel. The definition for “Magazine” is also revised to specify vessel storage location and accessibility. The term “Transport unit” is revised to read “Cargo transport unit” to be consistent with Amendment 32 of the IMDG Code. In addition, in the definition “In containers or the like” the term “transport unit” is removed and the term “cargo transport unit” is added in its place.

Section 176.27

In this section, the words “transport unit” are replaced with the words “transport vehicle” in each place they appear to be consistent with the removal of the term “transport unit” from the definitions in § 176.2.

Section 176.63

Paragraph (e) is revised to align the definition of “Closed cargo transport unit” to be consistent with the definition in Amendment 32 of the IMDG Code.

Section 176.76

Paragraph (i) is revised to clarify that for container ships, a distance equivalent to one container space athwartships (i.e., in the direction of the breadth of the vessel) away from possible sources of ignition applied in any direction satisfies the requirement that a cargo transport unit packed or loaded with flammable gas or flammable liquid having a flashpoint below +23 °C transported on deck be stowed “away from” possible ignition sources. This is consistent with Amendment 32 of the IMDG Code. In addition, in paragraphs (h) and (i), the words “transport unit” are removed and replaced with the words “cargo transport unit” in each place they appear to be consistent with Amendment 32 of the IMDG.

Section 176.83

Paragraph (l) is revised to correct an error pertaining to the Segregation Table that sets forth the general requirements for segregation of containers on board hatchless container vessels. In addition, throughout the section the words “transport units” are removed and replaced with the words “cargo transport units” in each place they appear to be consistent with Amendment 32 of the IMDG. A new paragraph (m) is added to specify the provisions for segregation groups.

Section 176.84

Paragraph (a) is revised to specify the various chemical groups listed in the segregation table. In the paragraph (b) Table of Provisions, we added eleven new provisions (codes) for certain stowage and segregation requirements for hazardous materials that are transported by vessel. In addition, in paragraph (c)(2) Provisions for the stowage of Class 1 (explosive) materials, we revised three notes. The terms “separated from” and “away from” in the codes are defined in § 176.83 of the HMR.

Code 133 is added to the entries “Barium chlorate solution,” UN3405; “Barium perchlorate solution,” UN3406; and “Chlorate and magnesium chloride mixture solution,” UN3407, that requires the material to be stowed “separated from” sulfur.

Code 134 is added to the entry “Aluminum alkyl halides, solid,” UN3461, that requires the material to be stowed “separated from” UN2716.

Code 135 is added to the entries “Methylamine, aqueous solution,” UN1235 and “Trimethylamine, aqueous solutions,” UN1297, that requires the material to be stowed “separated from” mercury and mercury compounds.

Code 136 is added to the entry “Tributylphosphane,” UN3254, that requires the material to be stowed “separated from” carbon tetrachloride.

Code 137 is added to the entries “Arsenic compounds, liquid, n.o.s.,” UN1556 and “Arsenic compounds, solid, n.o.s.,” UN1557, that requires arsenic sulphides to be stowed “separated from” acids.

Code 138 is added to the entries for UN1448; UN1456; UN1479; UN1482; UN1490; UN1503; UN1515; UN3085; UN3087; UN3098; UN3099; UN3139; and UN3214, that requires the material to be stowed “separated from” peroxides.

Code 139 is added to the entry “1, 4-Butynediol,” UN2716, that requires the material to be stowed “separated from” mercury salts.

Code 140 is added to the entry “1, 4-Butynediol,” UN2716, that requires the material to be stowed “separated from” UN3052 and UN3461.

Code 141 is added to the entries for UN1732; UN1755; UN1806; UN1908; UN2433; UN2859; and UN2861, that requires the material to be stowed “away from” radioactive materials.

Code 142 is added to the entries for UN1748; UN2208; and UN2880, that requires packages in cargo transport units to be stowed so as to allow for adequate air circulation throughout the cargo.

Code 143 is added to the entry for Organometallic Substance, Liquid, Pyrophoric, UN3392, prohibiting transportation on any vessel carrying explosives (except explosives in Division 1.4, compatibility group S.

Note 19E is revised to specify that materials under entries NA0331; UN0004; UN0222; UN0241; and UN0402 must be stowed “away from” explosives containing chlorates or perchlorates.

Note 22E is revised to specify that materials under the entry “Explosive, blasting, type C,” must be stowed “away from” ammonium compounds and explosives containing ammonium compounds or salts.

Note 23E is revised to specify that materials under entries UN0247; UN0395; UN0396; UN0397; UN0398; UN0399; UN0400; UN0449; and UN0450 must be “separated from” Division 1.4 and “separated longitudinally by an intervening complete compartment or hold from” Division 1.1, 1.2, 1.3, 1.5, and 1.6 except from explosives of compatibility group J.

A commenter questioned how adequate air circulation was achieved in a cargo transport unit. In addition, the commenter stated that it fails to understand why air circulation is necessary in a closed cargo transport unit, as indicated by Stowage Provision 142. Stowage Provision 142 indicates that packages in cargo transport units must be stowed so as to allow for adequate air circulation throughout the cargo. We feel cargo transport units that are properly loaded will allow for the adequate circulation of air by natural means so as to safeguard against excessive heat buildup within the cargo.

Section 176.116

In paragraph (c), the words “transport units” are revised to read “cargo transport units.” In addition, a new paragraph (f) is added to specify the under deck stowage requirements of Class 1 (explosive) materials allocated stowage categories 09 and 10.

Sections 176.122 and 176.124

Sections 176.122 and 176.124 are removed and reserved.

Section 176.128

In § 176.128, the section heading and section are revised.

Section 176.132

Section 176.132 is removed and reserved.

Section 176.133

Section 176.133 is revised to clarify the construction and stowage location requirements for magazine stowage type C.

Section 176.136

Section 176.136 is revised to clarify the special stowage requirements of Class 1 (explosive) materials. In addition, minor editorial revisions are made.

Section 176.138

Paragraph (a) is removed and reserved to be consistent with Amendment 32 of the IMDG Code. This paragraph currently requires Class 1 (explosive) material that is stowed on deck to be carried as close to the vessel's centerline as practicable.(See also change to § 176.170.)

Section 176.142

Paragraph (a) is revised to remove “Pyrophoric organometallic compound, water-reactive, n.o.s.” from the list of liquid hazardous materials of extreme flammability that may not be transported in a vessel carrying Class 1 (explosive) materials. Additionally, we added to the above list the following new liquid entries:

  • “Organometallic substance, liquid, pyrophoric, UN3392”
  • “Organometallic substance, liquid, pyrophoric, water-reactive, UN3394”

These changes are consistent with Amendment 32 of the IMDG Code.

Section 176.144

In this section, the words “transport unit” are replaced with the words “cargo transport unit” in each place they appear to be consistent with the definition in Amendment 32 of the IMDG Code. Additional notes are added to Table 176.144(a)—“Authorized Mixed Stowage For Explosives” to address additional exceptions for mixed stowage of Class 1 materials.

Section 176.146

In § 176.146, in paragraph (d)(1), the wording “transport units” is revised to read “cargo transport units.”

Section 176.168

In § 176.168, in the title before the section heading, the wording “TRANSPORT UNITS AND SHIPBORNE BARGES” are revised to read “CARGO TRANSPORT UNITS AND SHIPBORNE BARGES.”

Section 176.170

A new paragraph (b) is added to prohibit freight containers loaded with Class 1 (explosive) materials, except for explosives in Division 1.4, from being stowed in the outermost row of containers. This change is consistent with Amendment 32 of the IMDG Code.

Section 176.174

Paragraphs (a) and (b) are revised to remove the references to portable magazines. This change is consistent with Amendment 32 of the IMDG Code.

Section 176.600

In § 176.600, in paragraph (a), the wording “closed transport units” is revised to read “closed cargo transport units.”

Part 178

Section 178.274

Paragraph (f)(v) is revised to more clearly specify the rated flow capacity marking required to be placed on every UN portable tank's pressure relief device.

Section 178.275

Paragraph (i)(2) is revised to more clearly specify the combined delivery capacity of UN portable tank's pressure relief systems.

Section 178.276

In paragraph (a)(4)(ii)(A), the reference to “portable tank special provision T50” is revised to read “the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313.” In addition, paragraph (d), the reference to “portable tank special provision T50 in § 172.102(c)(7)” is revised to read “UN Portable Tank Table for Liquefied Compressed Gases in § 173.313.” Finally, in paragraph (e)(3), the reference to “portable tank special provision T50 in § 172.102” is revised to read “the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313.”

Section 178.602

Paragraph (b) is revised to clarify the requirements applicable to filling packaging other than bags in preparation for testing.

Section 178.603

Paragraph (c) is revised to add a definition indicating that a minimum specific gravity for solutions of water and anti-freeze is 0.95 for testing at 18 °C (0 °F) or lower. Additionally, in paragraph (e), we specify the drop test height for liquids in single packagings and for inner packagings of combination packagings, when the test is performed in water.

Section 178.810

Paragraph (b)(3) is revised to specify that water/anti-freeze solutions with a minimum specific gravity of 0.95 for testing at −18 °C (0 °F) or lower are acceptable test liquids for use when conducting IBC drop tests. This is consistent with our amendment to § 178.603(c)(1) regarding the testing of non-bulk packages. In addition, we added a sentence to clarify that when conditioning is required by § 178.810(b), the conditioning specified in § 178.802 (which requires a higher temperature) does not apply.We received a comment from the Reusable Industrial Packaging Association (RIPA) concerning this revision. RIPA believes that RSPA intended to clarify that water/antifreeze solutions with a minimum specific gravity of 0.95 are equivalent for testing purposes to IBCs containing only water, thereby eliminating the need to adjust the drop height of test units. RIPA stated that § 178.810(b)(3) should be revised to indicate that this solution may be considered equivalent to water for testing purposes. We agree and have revised the section accordingly.

Part 180

Section 180.350

Paragraph (c) is revised to expand the definition of routine maintenance of IBCs to include flexible, plastic and textile IBCs.

Section 180.352

Paragraph (d)(1)(iv) is revised to require persons other than the owner of metal, rigid plastics, and composite IBCs to mark the IBC indicating routine maintenance has been performed when such maintenance is performed. A new paragraph (d)(1)(v) is added to this section. This paragraph states that retests and inspections performed under paragraphs (d)(1)(i) and (ii) of this section may be used to satisfy the tests and inspections required by paragraph (b) of this section. This addition incorporates changes made to the 12th revised edition of the Transport of Dangerous Goods Model Regulations into the HMR. Three commenters requested that we revise § 180.352 to distinguish requirements applicable to repair and routine maintenance of IBCs. We agree and have revised § 180.352 creating a new paragraph entitled, “Requirements applicable to routine maintenance of IBCs.”

V. Regulatory Analyses and Notices

A. Statutory/Legal Authority for This Rulemaking

This final rule is published under the following statutory authorities:

1. 49 U.S.C. 5103(b) authorizes the Secretary of Transportation to prescribe regulations for the safe transportation, including security, of hazardous material in intrastate, interstate, and foreign commerce. This final rule amends regulations to maintain alignment with international standards by incorporating various amendments, including changes to proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, air transport quantity limitations and vessel stowage requirements. To this end, as discussed in detail earlier in this preamble, the final rule amends the HMR to more fully align it with the biennial updates of the UN Recommendations, the IMDG Code and the ICAO Technical Instructions to facilitate the transport of hazardous materials in international commerce.

2. 49 U.S.C. 5120(b) authorizes the Secretary of Transportation to ensure that, to the extent practicable, regulations governing the transportation of hazardous materials in commerce are consistent with standards adopted by international authorities. This final rule amends the HMR to maintain alignment with international standards by incorporating various amendments to facilitate the transport of hazardous material in international commerce. To this end, as discussed in detail earlier in this preamble, the final rule incorporates changes into the HMR based on the Thirteenth Revised Edition of the UN Recommendation, Amendment 32 to the IMDG Code, and the 2005-2006 ICAO Technical Instructions, which become effective January 1, 2005. The continually increasing amount of hazardous materials transported in international commerce warrants the harmonization of domestic and international requirements to the greatest extent possible. Harmonization serves to facilitate international transportation; at the same time, harmonization ensures the safety of people, property, and the environment by reducing the potential for confusion and misunderstanding that could result if shippers and transporters were required to comply with two or more conflicting sets of regulatory requirements. While the intent of this rulemaking is to align the HMR with international standards, we review and consider each amendment on its own merit based on its overall impact on transportation safety and the economic implications associated with its adoption into the HMR. Our goal is to harmonize without sacrificing the current HMR level of safety and without imposing undue burdens on the regulated public. Thus, as discussed in detail earlier in this preamble, there are several instances where we elected not to adopt a specific provision of the UN Recommendations, the IMDG Code or the ICAO Technical Instructions; further, we are maintaining a number of current exceptions for domestic transportation that should minimize the compliance burden on the regulated community.

B. Executive Order 12866 and DOT Regulatory Policies and Procedures

This final rule is not considered a significant regulatory action under section 3(f) of Executive Order 12866 and, therefore, was not reviewed by the Office of Management and Budget. This final rule is not considered a significant rule under the Regulatory Policies and Procedures of the Department of Transportation [44 FR 11034]. Benefits resulting from the adoption of the amendments in this final rule include enhanced transportation safety resulting from the consistency of domestic and international hazard communications and continued access to foreign markets by domestic shippers of hazardous materials. This final rule applies to offerors and carriers of hazardous materials, such as chemical manufacturers, chemical users and suppliers, packaging manufacturers, distributors, battery manufacturers, radiopharmaceutical companies, and training companies.

The majority of amendments in this final rule should result in cost savings and ease the regulatory compliance burden for shippers engaged in domestic and international commerce, including trans-border shipments within North America. For example, cost savings will be realized by shippers and carriers as a result of the following:

—Eliminating the air eligibility marking requirement.

—Amendments allowing numerous Class 3, PG II materials with a Class 8 sub-risk and others to be transported as a limited quantity.

—Allowing cylinders to be used for many more substances than currently authorized.

—Allowing salvage packagings to be used for non-conforming packages; and generally minimizing differences between U.S. and international hazardous materials transportation regulations.

We are authorizing a delayed effective date and a one-year transition period to allow for training of employees and to ease any burden on entities affected by the amendments. The total net increase in costs to businesses in implementing this rulemaking is considered to be minimal and a regulatory evaluation is available for review in the Docket.

C. Executive Order 13132

This final rule has been analyzed in accordance with the principles and criteria contained in Executive Order 13132 (“Federalism”). This final rule preempts State, local and Indian tribe requirements but does not propose any regulation that has substantial direct effects on the States, the relationship between the national government and the States, or the distribution of power and responsibilities among the various levels of government. Therefore, the consultation and funding requirements of Executive Order 13132 do not apply.

The Federal hazardous material transportation law, 49 U.S.C. 5101-5127, contains an express preemption provision (49 U.S.C. 5125(b)) that preempts State, local, and Indian tribe requirements on certain covered subjects. Covered subjects are:

(1) The designation, description, and classification of hazardous materials;

(2) The packing, repacking, handling, labeling, marking, and placarding of hazardous materials;

(3) The preparation, execution, and use of shipping documents related to hazardous materials and requirements related to the number, contents, and placement of those documents;

(4) The written notification, recording, and reporting of the unintentional release in transportation of hazardous; and

(5) The design, manufacture, fabrication, marking, maintenance, recondition, repair, or testing of a packaging or container represented, marked, certified, or sold as qualified for use in transporting hazardous material.

This final rule addresses covered subject items (1), (2), (3), and (5) above and preempts State, local, and Indian tribe requirements not meeting the “substantively the same” standard. This final rule is necessary to incorporate changes adopted in international standards, effective January 1, 2005. If the changes in this final rule are not adopted in the HMR, U.S. companies, including numerous small entities competing in foreign markets, are at an economic disadvantage. These companies are forced to comply with a dual system of regulations. The changes in this rulemaking are intended to avoid this result. Federal hazardous materials transportation law provides at section 5125(b)(2) that, if DOT issues a regulation concerning any of the covered subjects, DOT must determine and publish in the Federal Register the effective date of Federal preemption. The effective date may not be earlier than the 90th day following the date of issuance of the final rule and not later than two years after the date of issuance. The effective date of Federal preemption is March 21, 2005.

D. Executive Order 13175

This final rule was analyzed in accordance with the principles and criteria contained in Executive Order 13175 (“Consultation and Coordination with Indian Tribal Governments”). Because this final rule does not have tribal implications, does not impose substantial direct compliance costs, and is required by statute, the funding and consultation requirements of Executive Order 13175 do not apply.

E. Regulatory Flexibility Act, Executive Order 13272, and DOT Procedures and Policies

The Regulatory Flexibility Act (5 U.S.C. 601 et seq.) requires an agency to review regulations to assess their impact on small entities, unless the agency determines that a rule is not expected to have a significant impact on a substantial number of small entities. This final rule facilitates the transportation of hazardous materials in international commerce by providing consistency with international standards. This final rule applies to offerors and carriers of hazardous materials, some of whom are small entities, such as chemical users and suppliers, packaging manufacturers, distributors, battery manufacturers, and training companies. As discussed above, under Executive Order 12866, the majority of amendments in this final rule should result in cost savings and ease the regulatory compliance burden for shippers engaged in domestic and international commerce, including trans-border shipments within North America.

Many companies will realize economic benefits as a result of these amendments. Additionally, the changes brought forth by this final rule will relive U.S. companies, including small entities competing in foreign markets, from the burden of complying with a dual system of regulations. Therefore, I certify that these amendments will not, if promulgated, have a significant economic impact on a substantial number of small entities.

This final rule has been developed in accordance with Executive Order 13272 (“Proper Consideration of Small Entities in Agency Rulemaking”) and DOT's procedures and policies to promote compliance with the Regulatory Flexibility Act to ensure that potential impacts of draft rules on small entities are properly considered.

F. Paperwork Reduction Act

Under the Paperwork Reduction Act of 1995, no person is required to respond to a collection of information unless it displays a valid Office of Management and Budget (OMB) control number. Section 1320.8(d), Title 5, Code of Federal Regulations requires that RSPA provide interested members of the public and affected agencies an opportunity to comment on information collection and recordkeeping requests. RSPA currently has two approved information collections affecting this final rule: OMB Control Number 2137-0557, “Approvals for Hazardous Materials” with 25,605 burden hours and $562,837.40 burden costs; and OMB Control Number 2137-0613, “Subsidiary Hazard Class & Number/Type of Packagings” with 63,309 burden hours and $216,705 burden costs.

There are minor editorial changes under this rule. However, there is no net increase in burden for OMB Control Number 2137-0557 or OMB Control Number 2137-0613. We estimate that the total information collection and recordkeeping burden as follows:

“Approvals for Hazardous Materials”

OMB Number 2137-0557:

Total Annual Number of Respondents: 3,523.

Total Annual Responses: 3,874.8.

Total Annual Burden Hours: 25,605.

Total Annual Burden Cost: $562,837.40.

“Subsidiary Hazard Class & Number/Type of Packagings”

OMB Number 2137-0613:

Total Annual Number of Respondents: 250,000.

Total Annual Responses: 6,337,500.

Total Annual Burden Hours: 17,604.

Total Annual Burden Cost: $216,705.

Total First Year Burden Hours: 45,705.

Total First Year Burden Cost: $1,115,992.

Requests for a copy of this information collection should be directed to Deborah Boothe or T. Glenn Foster, Office of Hazardous Materials Standards (DHM-10), Research and Special Programs Administration, Room 8422, 400 Seventh Street, SW., Washington, DC 20590-0001, telephone (202) 366-8553.

G. Regulatory Identifier Number (RIN)

A regulation identifier number (RIN) is assigned to each regulatory action listed in the Unified Agenda of Federal Regulations. The Regulatory Information Service Center publishes the Unified Agenda in April and October of each year. The RIN contained in the heading of this document can be used to cross-reference this action with the Unified Agenda.

H. Unfunded Mandates Reform Act

This final rule does not impose unfunded mandates under the Unfunded Mandates Reform Act of 1995. It does not result in costs of $120.7 million or more to either State, local or tribal governments, in the aggregate, or to the private sector, and is the least burdensome alternative that achieves the objective of the rule.

I. Environmental Assessment

The National Environmental Policy Act of 1969 (NEPA) requires Federal agencies to consider the consequences of major Federal actions and prepare a detailed statement on actions significantly affecting the quality of the human environment. We developed an assessment to determine the effects of these revisions on the environment and whether a more comprehensive environmental impact statement may be required. Our findings conclude that there are no significant environmental impacts associated with this final rule. Consistency in the regulations for the transportation of hazardous materials aids in the shipper's understanding of what is required and permits shippers to more easily comply with safety regulations and avoid the potential for environmental damage or contamination. For interested parties, an environmental assessment is available in the public docket.

J. Privacy Act

Anyone is able to search the electronic form of any written communications and comments received into any of our dockets by the name of the individual submitting the document (or signing the document, if submitted on behalf of an association, business, labor union, etc.). You may review DOT's complete Privacy Act Statement in the Federal Register published on April 11, 2000 (Volume 65, Number 70; Pages 19477-78) or you may visit http://dms.dot.gov.

List of Subjects

49 CFR Part 171

  • Exports
  • Hazardous materials transportation
  • Hazardous waste
  • Imports
  • Incorporation by reference
  • Reporting and recordkeeping requirements

49 CFR Part 172

  • Education
  • Hazardous materials transportation
  • Hazardous waste
  • Incorporation by reference
  • Labeling
  • Markings
  • Packaging and containers
  • Reporting and recordkeeping requirements

49 CFR Part 173

  • Hazardous materials transportation
  • Incorporation by reference
  • Packaging and containers
  • Radioactive materials
  • Reporting and recordkeeping requirements
  • Uranium

49 CFR Part 175

  • Air carriers
  • Hazardous materials transportation
  • Incorporation by reference
  • Radioactive materials
  • Reporting and recordkeeping requirements

49 CFR Part 176

  • Hazardous materials transportation
  • Incorporation by reference
  • Maritime carriers
  • Radioactive materials
  • Reporting and recordkeeping requirements

49 CFR Part 178

  • Hazardous materials transportation
  • Incorporation by reference
  • Motor vehicle safety
  • Packaging and containers
  • Reporting and recordkeeping requirements

49 CFR Part 180

  • Hazardous materials transportation
  • Motor carriers
  • Motor vehicle safety
  • Packaging and containers
  • Railroad safety
  • Reporting and recordkeeping requirements

In consideration of the foregoing, 49 CFR Chapter I is amended as follows:

PART 171—GENERAL INFORMATION, REGULATIONS, AND DEFINITIONS

1. The authority citation for part 171 continues to read as follows:

Authority:49 U.S.C. 5101-5127, 44701; 49 CFR 1.45 and 1.53; Pub. L. 101-410 section 4 (28 U.S.C. 2461 note); Pub. L. 104-134 section 31001.

2. In § 171.7, in the paragraph (a)(3) table, the following changes are made:

a. Under the entry “International Civil Aviation Organization (ICAO),” the existing entry is revised;

b. Under the entry “International Maritime Organization (IMO),” the entry “International Maritime Dangerous Goods (IMDG) Code, 2002 Consolidated Edition, as amended by Amendment 31 (English edition)” is removed and one entry is added in its place;

c. Under the entry “United Nations,” the entry “UN Recommendations on the Transport of Dangerous Goods, Twelfth Revised Edition (2001)” is revised;

d. Under the entry “United Nations,” the entry “UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Third Revised Edition (1999)” is revised; and

e. In paragraph (b), a new entry “American Institute of Chemical Engineers (AIChE),” 3 Park Avenue New York, NY 10016-5991, Process Safety Progress Journal, Vol. 21, No. 2, “Example of a Test Method for Venting Sizing: OPPSD/SPI Methodology” is added in alphabetical order.

The revisions and additions read as follows:

§ 171.7
Reference material.

(a) * * *

(3) Table of material incorporated by reference. * * *

Source and name of material49 CFR reference
*         *         *         *         *         *         *
International Civil Aviation Organization (ICAO),
*         *         *         *         *         *         *
Technical Instructions for the Safe Transport of Dangerous Goods by Air (ICAO Technical Instructions), 2005-2006 Edition171.8; 171.11; 172.202; 172.401; 172.512; 172.602; 173.320; 175.33; 178.3.
International Maritime Organization (IMO),
*         *         *         *         *         *         *
International Maritime Dangerous Goods Code (IMDG Code), 2004 Edition, Incorporating Amendment 32-04 (English Edition), Volumes 1 and 2171.12; 172.202; 172.401; 172.502; 172.602; 173.21; 176.2; 176.5; 176.11; 176.27; 176.30; 178.3.
*         *         *         *         *         *         *
United Nations,
*         *         *         *         *         *         *
UN Recommendations on the Transport of Dangerous Goods, Thirteenth Revised Edition (2003), Volumes I and II171.12; 172.202; 172.401; 172.502; 173.22; 173.24; 173.24b; 173.197; Part 173, appendix H; 178.274; 178.801.
UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Fourth Revised Edition, (2003)172.102; 173.21; 173.56; 173.57; 173.58; 173.115; 173.124; 173.125; 173.127; 173.128; 173.185.
*         *         *         *         *         *         *

(b) List of informational materials not requiring incorporation by reference. * * *

Source and name of material49 CFR reference
*         *         *         *         *         *         *
American Institute of Chemical Engineers (AIChE),
3 Park Avenue New York, NY 10016-5991
Process Safety Progress Journal, Vol. 21, No. 2
Example of a Test Method for Venting Sizing: OPPSD/SPI MethodologyNote to § 173. 225(h)(3)(vi).
*         *         *         *         *         *         *

3. In § 171.8, the definition for “Salvage packaging” is revised to read as follows:

§ 171.8
Definitions and abbreviations.

Salvage packaging means a special packaging conforming to § 173.3 of this subchapter into which damaged, defective, leaking, or non-conforming hazardous materials packages, or hazardous materials that have spilled or leaked, are placed for purposes of transport for recovery or disposal.

4. In § 171.11, paragraphs (d)(15) and (d)(17) are revised to read as follows:

§ 171.11
Use of ICAO Technical Instructions.

(d) * * *

(15) A chemical oxygen generator, including when fitted in protective breathing equipment or other apparatus, is forbidden for transportation aboard a passenger-carrying aircraft and must be approved, classed, described and packaged in accordance with the requirements of this subchapter for transportation on cargo-only aircraft. A chemical oxygen generator that has been used or spent is also forbidden for transportation on a passenger aircraft and cargo aircraft only.

(17) A self-reactive substance that is not identified by technical name in the Self-reactive Materials Table in § 173.224(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.124(a)(2)(iii) of this subchapter. An organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.

5. In § 171.12, paragraph (b)(20) is revised to read as follows:

§ 171.12
Import and export shipments.

(b) * * *

(20) A self-reactive substance that is not identified by technical name in the Self-Reactive Materials Table in § 173.224(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.124(a)(2)(iii) of this subchapter. An organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.

6. In § 171.12a, paragraphs (a), (b)(9), and (b)(18) are revised to read as follows:

§ 171.12a
Canadian shipments and packagings.

(a) Scope and applicability. This section sets forth provisions for the transportation by rail or highway of shipments of hazardous materials which conform to the regulations of the Government of Canada but which may differ from the requirements of this subchapter with regard to hazard communication, classification or packaging. Except as provided in paragraph (b)(5)(iv) of this section, the provisions apply only to shipments which originate in Canada and either terminate in the U.S. or transit the U.S. to a Canadian or foreign destination, and to the return to Canada of bulk packagings that meet the requirements of a DOT or UN Specification and other bulk packagings containing only residues of hazardous materials that were originally imported into the U.S. Reciprocal provisions, applicable to exports from the U.S., appear in the regulations of the Government of Canada.

(b) * * *

(9) For hazardous waste as defined in this subchapter—

(i) The word “Waste” must precede the proper shipping name on shipping papers and packages; and

(ii) The requirements of § 172.204 of this subchapter with respect to the shipper's certification and § 172.205 of this subchapter with respect to hazardous waste manifests are applicable;

(18) A self-reactive substance that is not identified by technical name in the Self-reactive Materials Table in § 173.224(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.124(a)(2)(iii) of this subchapter. An organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.

7. In § 171.14, paragraphs (d) introductory text, (d)(1), and (d)(2) are revised to read as follows:

§ 171.14
Transitional provisions for implementing certain requirements.

(d) A final rule published in the Federal Register on December 20, 2004, effective January 1, 2005, resulted in revisions to this subchapter. During the transition period, until January 1, 2006, as provided in paragraph (d)(1) of this section, a person may elect to comply with either the applicable requirements of this subchapter in effect on December 31, 2004, or the requirements published in the December 20, 2004, final rule.

(1) Transition dates. The effective date of the final rule published on December 20, 2004, is January 1, 2005. A delayed compliance date of January 1, 2006 is authorized. On and after January 1, 2006, all applicable regulatory requirements adopted in the final rule in effect on January 1, 2005 must be met.

(2) Intermixing old and new requirements. Marking, labeling, placarding, and shipping paper descriptions must conform to either the old requirements of this subchapter in effect on December 31, 2004, or the new requirements of this subchapter in the final rule without intermixing communication elements, except that intermixing is permitted, during the applicable transition period, for packaging, hazard communication, and handling provisions, as follows:

PART 172—HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION, AND TRAINING REQUIREMENTS

8. The authority citation for part 172 continues to read as follows:

Authority:49 U.S.C. 5101-5127; 49 CFR 1.53.

9. In § 172.101, the following amendments are made:

a. Paragraph (c)(11) is revised;

b. Paragraph (d)(4) is revised;

c. Paragraph (i)(3) is revised;

d. Hazardous Materials Table is revised as set forth below:

§ 172.101
Purpose and use of hazardous materials table.

(c) * * *

(11) Except for a material subject to or prohibited by § 173.21, 173.54, 173.56(d), 173.56(e), 173.224(c) or 173.225(b) of this subchapter, a material that is considered to be a hazardous waste or a sample of a material for which the hazard class is uncertain and must be determined by testing may be assigned a tentative proper shipping name, hazard class, identification number and packing group, if applicable, based on the shipper's tentative determination according to:

(i) Defining criteria in this subchapter;

(ii) The hazard precedence prescribed in § 173.2a of this subchapter;

(iii) The shipper's knowledge of the material;

(iv) In addition to paragraphs (c)(11)(i) through (iii) of this section, for a sample of a material other than a waste, the following must be met:

(A) Except when the word “Sample” already appears in the proper shipping name, the word “Sample” must appear as part of the proper shipping name or in association with the basic description on the shipping paper.

(B) When the proper shipping description for a sample is assigned a “G” in Column (1) of the § 172.101 Table, and the primary constituent(s) for which the tentative classification is based are not known, the provisions requiring a technical name for the constituent(s) do not apply; and

(C) A sample must be transported in a combination packaging that conforms to the requirements of this subchapter that are applicable to the tentative packing group assigned, and may not exceed a net mass of 2.5 kg (5.5 pounds) per package.

Note to Paragraph (c)(11): For the transportation of self-reactive, organic peroxide and explosive samples, see §§ 173.224(c)(3), 173.225(b)(2) and 173.56(d) of this subchapter, respectively.

(d) * * *

(4) When an entry in this column reads “Comb liq”, the material is assigned to the hazard class “Combustible liquid.” Additionally, each reference to a Class 3 material is modified to read “Combustible liquid” when that material is reclassified in accordance with § 173.150 (e) or (f) of this subchapter or has a flash point above 60.5 °C (141 °F) but below 93 °C (200 °F).

(i) * * *

(3) Bulk packaging. Column 8C specifies the section in part 173 of this subchapter that prescribes packaging requirements for bulk packagings, subject to the limitations, requirements and additional authorizations of Column 7. A “None” in this column means bulk packagings are not authorized, except as may be provided by special provisions in Column 7. Additional authorizations and limitations for use of UN portable tanks are set forth in Column 7. For each reference in this column to a material that is a hazardous waste or a hazardous substance, and whose proper shipping name is preceded in Column 1 of the Table by the letter “A” or “W” and that is offered for transportation or transported by a mode in which its transportation is not otherwise subject to the requirements of this subchapter:

§ 172.101 Hazardous Materials Table

SymbolsHazardous materials descriptions and proper shipping namesHazard class or DivisionIdentification NumbersPGLabel CodesSpecial provisions (§172.102)(8) Packaging (§173.***)(9) Quantity limitations(10) Vessel stowage
ExceptionsNon-bulkBulkPassenger aircraft/railCargo air- craft onlyLocationOther
(1)(2)(3)(4)(5)(6)(7)(8A)(8B)(8C)(9A)(9B)(10A)(10B)
Accellerene, see p-Nitrosodimethylaniline
Accumulators, electric, see Batteries, wet etc
Accumulators, pressurized, pneumatic or hydraulic (containing non-flamable gas), see Articles pressurized, pneumatic or hydraulic (containing non-flamable gas)
Acetal3UN1088II3IB2, T4, TP11502022425 L60 LE
Acetaldehyde3UN1089I3A3, B16, T11, TP2, TP7None201243Forbidden30 LE
AAcetaldehyde ammonia9UN1841III9IB8, IP3, IP7, T1, TP33155204240200 kg200 kgA34
Acetaldehyde oxime3UN2332III3B1, IB3, T4, TP115020324260 L220 LA
Acetic acid, glacial or Acetic acid solution, with more than 80 percent acid, by mass8UN2789II8, 3A3, A6, A7, A10, B2, IB2, T7, TP21542022431 L30 LA
Acetic acid solution, not less than 50 percent but not more than 80 percent acid, by mass8UN2790II8A3, A6, A7, A10, B2, IB2, T7, TP21542022421 L30 LA
Acetic acid solution, with more than 10 percent and less than 50 percent acid, by mass8UN2790III8IB3, T4, TP11542032425 L60 LA
Acetic anhydride8UN1715II8, 3A3, A6, A7, A10, B2, IB2, T7, TP21542022431 L30 LA40
Acetone3UN1090II3IB2, T4, TP11502022425 L60 LB
Acetone cyanohydrin, stabilized6.1UN1541I6.12, B9, B14, B32, B76, B77, N34, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD25, 40, 52, 53
Acetone oils3UN1091II3IB2, T4, TP1, TP81502022425 L60 LB
Acetonitrile3UN1648II3IB2, T7, TP21502022425 L60 LB40
Acetyl acetone peroxide with more than 9 percent by mass active oxygenForbidden
Acetyl benzoyl peroxide, solid, or with more than 40 percent in solutionForbidden
Acetyl bromide8UN1716II8B2, IB2, T8, TP2, TP121542022421 L30 LC40
Acetyl chloride3UN1717II3, 8A3, A6, A7, IB1, N34, T8, TP2, TP121502022431 L5 LB40
Acetyl cyclohexanesulfonyl peroxide, with more than 82 percent wetted with less than 12 percent waterForbidden
Acetyl iodide8UN1898II8B2, IB2, T7, TP2, TP131542022421 L30 LC40
Acetyl methyl carbinol3UN2621III3B1, IB3, T2, TP115020324260 L220 LA
Acetyl peroxide, solid, or with more than 25 percent in solutionForbidden
Acetylene, dissolved2.1UN10012.1None303NoneForbidden15 kgD25, 40, 57
Acetylene (liquefied)Forbidden
Acetylene silver nitrateForbidden
Acetylene tetrabromide, see Tetrabromoethane
Acid butyl phosphate, see Butyl acid phosphate
Acid, sludge, see Sludge acid
Acridine6.1UN2713III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Acrolein dimer, stabilized3UN2607III3B1, IB3, T2, TP115020324260 L220 LA40
Acrolein, stabilized6.1UN1092I6.1, 31, B9, B14, B30, B42, B72, B77, T22, TP2, TP7, TP13, TP38, TP44None226244ForbiddenForbiddenD40
Acrylamide, solid6.1UN2074III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA12
Acrylamide solution6.1UN3426III6.1IB3, T4, TP115320324160 L220 LA12
Acrylic acid, stabilized8UN2218II8, 3B2, IB2, T7, TP21542022431 L30 LC25, 40
Acrylonitrile, stabilized3UN1093I3, 6.1B9, T14, TP2, TP13None201243Forbidden30 LE40
Actuating cartridge, explosive, see Cartridges, power device
Adhesives, containing a flammable liquid3UN1133I3B42, T11, TP1, TP8, TP271502011431 L30 LB
II3149, B52, IB2, T4, TP1, TP81501732425 L60 LB
III3B1, B52, IB3, T2, TP115017324260 L220 LA
Adiponitrile6.1UN2205III6.1IB3, T3, TP115320324160 L220 LA
Aerosols, corrosive, Packing Group II or III, (each not exceeding 1 L capacity)2.2UN19502.2, 8153, A34306NoneNone75 kg150 kgA48, 87, 126
Aerosols, flammable, (each not exceeding 1 L capacity)2.1UN19502.1153, N82306NoneNone75 kg150 kgA48, 87, 126
Aerosols, flammable, n.o.s. (engine starting fluid) (each not exceeding 1 L capacity)2.1UN19502.1153, N82306304NoneForbidden150 kgA48, 87, 126
Aerosols, non-flammable, (each not exceeding 1 L capacity)2.2UN19502.2153306NoneNone75 kg150 kgA48, 87, 126
Aerosols, poison, each not exceeding 1 L capacity2.2UN19502.2, 6.1153306NoneNoneForbiddenForbiddenA48, 87, 126
IAir bag inflators, or Air bag modules, or Seat-belt pretensioners.1.4GUN0503II1.4G161None62NoneForbidden75 kg02
Air bag inflators, or Air bag modules, or Seat-belt pretensioners.9UN3268III916016616616625 kg100 kgA
Air, compressed2.2UN10022.27830630230275 kg150 kgA
Air, refrigerated liquid, (cryogenic liquid)2.2UN10032.2, 5.1T75, TP5, TP22320316318, 319Forbidden150 kgD51
Air, refrigerated liquid, (cryogenic liquid) non-pressurized2.2UN10032.2, 5.1T75, TP5, TP22320316318, 319ForbiddenForbiddenD51
Aircraft engines (including turbines), see Engines, internal combustion
Aircraft evacuation slides, see Life saving appliances etc
Aircraft hydraulic power unit fuel tank (containing a mixture of anhydrous hydrazine and monomethyl hydrazine) (M86 fuel)3UN3165I3, 6.1, 8None172NoneForbidden42 LE
Aircraft survival kits, see Life saving appliances etc
GAlcoholates solution, n.o.s., in alcohol3UN3274II3, 8IB21502022431 L5 LB
Alcoholic beverages3UN3065II324, 149, B1, IB2, T4, TP11502022425 L60 LA
III324, B1, IB3, N11, T2, TP115020324260 L220 LA
Alcohols, n.o.s.3UN1987I3T11, TP1, TP8, TP27None2012431 L30 LE
II3IB2, T7, TP1, TP8, TP281502022425 L60 LB
III3B1, IB3, T4, TP1, TP2915020324260 L220 LA
GAlcohols, flammable, toxic, n.o.s.3UN1986I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LE40
II3, 6.1IB2, T11, TP2, TP271502022431 L60 LB40
III3, 6.1B1, IB3, T7, TP1, TP28None20324260 L220 LA
Aldehydes, n.o.s.3UN1989I3T11, TP1, TP27None2012431 L30 LE
II3IB2, T7, TP1, TP8, TP281502022425 L60 LB
III3B1, IB3, T4, TP1, TP2915020324260 L220 LA
GAldehydes, flammable, toxic, n.o.s.3UN1988I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LE40
II3, 6.1IB2, T11, TP2, TP271502022431 L60 LB40
III3, 6.1B1, IB3, T7, TP1, TP2815020324260 L220 LA
Aldol6.1UN2839II6.1IB2, T7, TP21532022435 L60 LA12
GAlkali metal alcoholates, self-heating, corrosive, n.o.s.4.2UN3206II4.2, 864, A7, IB5, IP2, T3, TP33None21224215 kg50 kgB
III4.2, 864, A7, IB8, IP3, T1, TP33None21324225 kg100 kgB
Alkali metal alloys, liquid, n.o.s.4.3UN1421I4.3A2, A3, A7, B48, N34None201244Forbidden1 LD52
Alkali metal amalgam, liquid4.3UN1389I4.3A2, A3, A7, N34None201244Forbidden1 LD40, 52
Alkali metal amalgam, solid4.3UN3401I4.3IB4, IP1, N40, T9, TP7, TP33None211242Forbidden15 kgD52
Alkali metal amides4.3UN1390II4.3A6, A7, A8, A19, A20, IB7, IP2, T3, TP3315121224115 kg50 kgE40, 52
Alkali metal dispersions, or Alkaline earth metal dispersions4.3UN1391I4.3A2, A3, A7None201244Forbidden1 LD52
Alkaline corrosive liquids, n.o.s., see Caustic alkali liquids, n.o.s.
GAlkaline earth metal alcoholates, n.o.s.4.2UN3205II4.265, A7, IB6, IP2, T3, TP33None21224115 kg50 kgB
III4.265, A7, IB8, IP3, T1, TP33None21324125 kg100 kgB
Alkaline earth metal alloys, n.o.s.4.3UN1393II4.3A19, IB7, IP2, T3, TP3315121224115 kg50 kgE52
Alkaline earth metal amalgams, liquid4.3UN1392I4.3A19, N34, N40None201244Forbidden1 LE40, 52
Alkaline earth metal amalgams, solid4.3UN3402I4.3A19, N34, N40, T9, TP7, TP33None211242Forbidden15 kgD52
GAlkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s.6.1UN3140I6.1A4, T14, TP2, TP27None2012431 L30 LA
II6.1IB2, T11, TP2, TP271532022435 L60 LA
III6.1IB3, T7, TP1, TP2815320324160 L220 LA
GAlkaloids, solid, n.o.s. [or] Alkaloid salts, solid, n.o.s. [poisonous]6.1UN1544I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with more than 5 percent free sulfuric acid8UN2584II8B2, IB2, T8, TP2, TP12, TP131542022421 L30 LB
Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with not more than 5 percent free sulfuric acid8UN2586III8IB3, T4, TP11542032415 L60 LB
Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid, with more than 5 percent free sulfuric acid8UN2583II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA
Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid with not more than 5 percent free sulfuric acid8UN2585III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Alkylphenols, liquid, n.o.s. (including C2-C12 homologues)8UN3145I8A6, T14, TP2None2012430.5 L2.5 LB
II8IB2, T11, TP2, TP271542022421 L30 LB
III8IB3, T7, TP1, TP281542032415 L60 LA
Alkylphenols, solid, n.o.s. (including C2-C12 homologues)8UN2430I8IB7, IP1, T6, TP33None2112421 kg25 kgB
II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgB
III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Alkylsulfuric acids8UN2571II8B2, IB2, T8, TP2, TP12, TP13, TP281542022421 L30 LC14
Allethrin, see Pesticides, liquid, toxic, n.o.s.
Allyl acetate3UN2333II3, 6.1IB2, T7, TP1, TP131502022431 L60 LE40
Allyl alcohol6.1UN1098I6.1, 32, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Allyl bromide3UN1099I3, 6.1T14, TP2, TP13None201243Forbidden30 LB40
Allyl chloride3UN1100I3, 6.1T14, TP2, TP13None201243Forbidden30 LE40
Allyl chlorocarbonate, see Allyl chloroformate
Allyl chloroformate6.1UN1722I6.1, 3, 82, B9, B14, B32, B74, N41, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Allyl ethyl ether3UN2335II3, 6.1IB2, T7, TP1, TP131502022431 L60 LE40
Allyl formate3UN2336I3, 6.1T14, TP2, TP13None201243Forbidden30 LE40
Allyl glycidyl ether3UN2219III3B1, IB3, T2, TP115020324260 L220 LA
Allyl iodide3UN1723II3, 8A3, A6, IB1, N34, T7, TP2, TP131502022431 L5 LB40
Allyl isothiocyanate, stabilized6.1UN1545II6.1, 3A3, A7, IB2, T7, TP2None202243Forbidden60 LD40
Allylamine6.1UN2334I6.1, 32, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Allyltrichlorosilane, stabilized8UN1724II8, 3A7, B2, B6, IB2, N34, T7, TP2, TP13None202243Forbidden30 LC40
Aluminum alkyl halides, liquid4.2UN3052I4.2, 4.3B9, B11, T21, TP2, TP7None181244ForbiddenForbiddenD134
Aluminium alkyl halides, solid4.2UN3461I4.2, 4.3T21, TP7, TP33None181244ForbiddenForbiddenD134
Aluminum alkyl hydrides4.2UN3076I4.2, 4.3B9, B11, T21, TP2, TP7None181244ForbiddenForbiddenD
Aluminum alkyls4.2UN3051I4.2, 4.3B9, B11, T21, TP2, TP7None181244ForbiddenForbiddenD
Aluminum borohydride or Aluminum borohydride in devices4.2UN2870I4.2, 4.3B11, T21, TP7, TP33None181244ForbiddenForbiddenD
Aluminum bromide, anhydrous8UN1725II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA40
Aluminum bromide, solution8UN2580III8IB3, T4, TP11542032415 L60 LA
Aluminum carbide4.3UN1394II4.3A20, IB7, IP2, N41, T3, TP3315121224215 kg50 kgA52
Aluminum chloride, anhydrous8UN1726II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA40
Aluminum chloride, solution8UN2581III8IB3, T4, TP11542032415 L60 LA
Aluminum dross, wet or hotForbidden
Aluminum ferrosilicon powder4.3UN1395II4.3, 6.1A19, IB5, IP2, T3, TP3315121224215 kg50 kgA39, 40, 52, 53, 85, 103
III4.3, 6.1A19, A20, IB415121324125 kg100 kgA39, 40, 52, 53, 85, 103
Aluminum hydride4.3UN2463I4.3A19, N40None211242Forbidden15 kgE
DAluminum, molten9NA9260III9IB3, T1, TP3NoneNone247ForbiddenForbiddenD
Aluminum nitrate5.1UN1438III5.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA
Aluminum phosphate solution, see Corrosive liquids, etc
Aluminum phosphide4.3UN1397I4.3, 6.1A8, A19, N40None211242Forbidden15 kgE40, 52, 85
Aluminum phosphide pesticides6.1UN3048I6.1A8, IB7, IP1, T6, TP33None211242Forbidden15 kgE40, 85
Aluminum powder, coated4.1UN1309II4.1IB8, IP2, IP4, T3, TP3315121224015 kg50 kgA13, 39, 52, 53, 74, 101
III4.1IB8, IP3, T1, TP3315121324025 kg100 kgA13, 39, 52, 53, 74, 101
Aluminum powder, uncoated4.3UN1396II4.3A19, A20, IB7, IP2, T3, TP3315121224215 kg50 kgA39, 52, 53
III4.3A19, A20, IB8, IP4, T1, TP3315121324125 kg100 kgA39, 52, 53
Aluminum resinate4.1UN2715III4.1IB6, T1, TP3315121324025 kg100 kgA
Aluminum silicon powder, uncoated4.3UN1398III4.3A1, A19, IB8, IP4, T1, TP3315121324125 kg100 kgA39, 40, 52, 53, 85, 103
Aluminum smelting by-products or Aluminum remelting by-products4.3UN3170II4.3128, B115, IB7, IP2, T3, TP33None21224215 kg50 kgB85, 103
III4.3128, B115, IB8, IP4, T1, TP33None21324125 kg100 kgB85, 103
Amatols, see Explosives, blasting, type B
GAmines, flammable, corrosive, n.o.s. or Polyamines, flammable, corrosive, n.o.s.3UN2733I3, 8T14, TP1, TP27None2012430.5 L2.5 LD40
II3, 8IB2, T11, TP1, TP271502022431 L5 LB40
III3, 8B1, IB3, T7, TP1, TP281502032425 L60 LA40
GAmines, liquid, corrosive, flammable, n.o.s. or Polyamines, liquid, corrosive, flammable, n.o.s.8UN2734I8, 3A3, A6, N34, T14, TP2, TP27None2012430.5 L2.5 LA52
II8, 3IB2, T11, TP2, TP27None2022431 L30 LA52
GAmines, liquid, corrosive, n.o.s., or Polyamines, liquid, corrosive, n.o.s.8UN2735I8A3, A6, B10, N34, T14, TP2, TP27None2012430.5 L2.5 LA52
II8B2, IB2, T11, TP1, TP271542022421 L30 LA52
III8IB3, T7, TP1, TP281542032415 L60 LA52
GAmines, solid, corrosive, n.o.s., or Polyamines, solid, corrosive n.o.s.8UN3259I8IB7, IP1, T6, TP33None2112421 kg25 kgA52
II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA52
III8IB8, IP3, T1, TP3315421324025 kg100 kgA52
2-Amino-4-chlorophenol6.1UN2673II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
2-Amino-5-diethylaminopentane6.1UN2946III6.1IB3, T4, TP115320324160 L220 LA
2-Amino-4,6-Dinitrophenol, wetted with not less than 20 percent water by mass4.1UN3317I4.123, A8, A19, A20, N41None211None1 kg15 kgE28, 36
2-(2-Aminoethoxy) ethanol8UN3055III8IB3, T4, TP11542032415 L60 LA
N-Aminoethylpiperazine8UN2815III8IB3, T4, TP11542032415 L60 LA12
+Aminophenols (o-; m-; p-)6.1UN2512III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Aminopropyldiethanolamine, see Amines, etc
n-Aminopropylmorpholine, see Amines, etc
Aminopyridines (o-; m-; p-)6.1UN2671II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB12, 40
IAmmonia, anhydrous2.3UN10052.3, 84, T50None304314, 315ForbiddenForbiddenD40, 57
DAmmonia, anhydrous2.2UN10052.213, T50None304314, 315ForbiddenForbiddenD40, 57
DAmmonia solution, relative density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia2.2UN33182.213, T50None304314, 315ForbiddenForbiddenD40, 57
IAmmonia solution, relative density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia2.3UN33182.3, 84, T50None304314, 315ForbiddenForbiddenD40, 57
Ammonia solutions, relative density between 0.880 and 0.957 at 15 degrees C in water, with more than 10 percent but not more than 35 percent ammonia8UN2672III8IB3, IP8, T7, TP11542032415 L60 LA40, 85
Ammonia solutions, relative density less than 0.880 at 15 degrees C in water, with more than 35 percent but not more than 50 percent ammonia2.2UN20732.2306304314, 315Forbidden150 kgE40, 57
Ammonium arsenate6.1UN1546II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA53
Ammonium azideForbidden
Ammonium bifluoride, solid, see Ammonium hydrogen difluoride, solid
Ammonium bifluoride solution, see Ammonium hydrogen difluoride, solution
Ammonium bromateForbidden
Ammonium chlorateForbidden
Ammonium dichromate5.1UN1439II5.1IB8, IP2, IP4, T3, TP331522122425 kg25 kgA52
Ammonium dinitro-o-cresolate, solid6.1UN1843II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB36, 65, 66, 77
Ammonium dinitro-o-cresolate solution6.1UN3424II6.1IB2, T7, TP21532022435 L60 LB36, 66, 78, 91
III6.1IB2, T7, TP215320324160 L220 LA36, 66, 78, 91
Ammonium fluoride6.1UN2505III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA52
Ammonium fluorosilicate6.1UN2854III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA52
Ammonium fulminateForbidden
Ammonium hydrogen sulfate8UN2506II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA40
Ammonium hydrogendifluoride, solid8UN1727II8IB8, IP2, IP4, N34, T3, TP3315421224015 kg50 kgA25, 40, 52
Ammonium hydrogendifluoride, solution8UN2817II8, 6.1IB2, N34, T8, TP2, TP12, TP131542022431 L30 LB40
III8, 6.1IB3, N3, T4, TP1, TP12, TP131542032415 L60 LB40, 95
Ammonium hydrosulfide, solution, see Ammonium sulfide solution
DAmmonium hydroxide, see Ammonia solutions, etc
Ammonium metavanadate6.1UN2859II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA44, 89, 100, 141
Ammonium nitrate based fertilizer5.1UN2067III5.152, 150, IB8, IP3, T1, TP3315221324025 kg100 kgB48, 59, 60, 66, 117
A WAmmonium nitrate based fertilizer9UN2071III9132, IB8, IP3155213240200 kg200 kgA
Ammonium nitrate emulsion or Ammonium nitrate suspension or Ammonium nitrate gel, intermediate for blasting explosives5.1UN3375II147, 163None214214ForbiddenForbiddenD48, 59, 60, 66, 124
DAmmonium nitrate-fuel oil mixture containing only prilled ammonium nitrate and fuel oil1.5DNA0331II1.5DNone62NoneForbiddenForbidden1019E
Ammonium nitrate, liquid (hot concentrated solution)5.1UN24265.1B5, T7NoneNone243ForbiddenForbiddenD59, 60
Ammonium nitrate, with more than 0.2 percent combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance1.1DUN0222II1.1DNone62NoneForbiddenForbidden1019E
Ammonium nitrate, with not more than 0.2% total combustible material, including any organic substance, calculated as carbon to the exclusion of any other added substance5.1UN1942III5.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA48, 59, 60, 116
Ammonium nitriteForbidden
Ammonium perchlorate1.1DUN0402II1.1D107None62NoneForbiddenForbidden1019E
Ammonium perchlorate5.1UN1442II5.1107, A9, IB6, IP2, T3, TP331522122425 kg25 kgE58, 69
Ammonium permanganateForbidden
Ammonium persulfate5.1UN1444III5.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA
Ammonium picrate, dry or wetted with less than 10 percent water, by mass1.1DUN0004II1.1DNone62NoneForbiddenForbidden105E, 19E
Ammonium picrate, wetted with not less than 10 percent water, by mass4.1UN1310I4.123, A2, N41None211None0.5 kg0.5 kgD28, 36
Ammonium polysulfide, solution8UN2818II8, 6.1IB2, T7, TP2, TP131542022431 L30 LB12, 40, 52
III8, 6.1IB3, T4, TP1, TP131542032415 L60 LB12, 40, 52
Ammonium polyvanadate6.1UN2861II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA44, 89, 100, 141
Ammonium silicofluoride, see Ammonium fluorosilicate
Ammonium sulfide solution8UN2683II8, 6.1, 3IB1, T7, TP2, TP131542022431 L30 LB12, 22, 52, 100
Ammunition, blank, see Cartridges for weapons, blank
Ammunition, illuminating with or without burster, expelling charge or propelling charge1.2GUN0171II1.2G62NoneForbiddenForbidden03
Ammunition, illuminating with or without burster, expelling charge or propelling charge1.3GUN0254II1.3G62NoneForbiddenForbidden03
Ammunition, illuminating with or without burster, expelling charge or propelling charge1.4GUN0297II1.4G62NoneForbidden75 kg02
Ammunition, incendiary liquid or gel, with burster, expelling charge or propelling charge1.3JUN0247II1.3J62NoneForbiddenForbidden0423E
Ammunition, incendiary (water-activated contrivances) with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc.
Ammunition, incendiary, white phosphorus, with burster, expelling charge or propelling charge1.2HUN0243II1.2H62NoneForbiddenForbidden088E, 14E, 15E, 17E
Ammunition, incendiary, white phosphorus, with burster, expelling charge or propelling charge1.3HUN0244II1.3H62NoneForbiddenForbidden088E, 14E, 15E, 17E
Ammunition, incendiary with or without burster, expelling charge, or propelling charge1.2GUN0009II1.2G62NoneForbiddenForbidden03
Ammunition, incendiary with or without burster, expelling charge, or propelling charge1.3GUN0010II1.3G62NoneForbiddenForbidden03
Ammunition, incendiary with or without burster, expelling charge or propelling charge1.4GUN0300II1.4G62NoneForbidden75 kg02
Ammunition, practice1.4GUN0362II1.4G62NoneForbidden75 kg02
Ammunition, practice1.3GUN0488II1.3G62NoneForbiddenForbidden03
Ammunition, proof1.4GUN0363II1.4G62NoneForbidden75 kg02
Ammunition, rocket, see Warheads, rocket etc
Ammunition, SA (small arms), see Cartridges for weapons, etc
Ammunition, smoke (water-activated contrivances), white phosphorus, with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc. (UN 0248)
Ammunition, smoke (water-activated contrivances), without white phosphorus or phosphides, with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc. (UN 0249)
Ammunition smoke, white phosphorus with burster,expelling charge, or propelling charge1.2HUN0245II1.2H62NoneForbiddenForbidden088E, 14E, 15E, 17E
Ammunition, smoke, white phosphorus with burster, expelling charge, or propelling charge1.3HUN0246II1.3H62NoneForbiddenForbidden088E, 14E, 15E, 17E
Ammunition, smoke with or without burster, expelling charge or propelling charge1.2GUN0015II1.2G62NoneForbiddenForbidden8E, 17E, 20E
Ammunition, smoke with or without burster, expelling charge or propelling charge1.3GUN0016II1.3G62NoneForbiddenForbidden8E, 17E, 20E
Ammunition, smoke with or without burster, expelling charge or propelling charge1.4GUN0303II1.4G62NoneForbidden75 kg7E, 8E, 14E, 15E, 17E
Ammunition, sporting, see Cartridges for weapons, etc. (UN 0012; UN 0328; UN 0339)
Ammunition, tear-producing, non-explosive, without burster or expelling charge, non-fuzed6.1UN2017II6.1, 8None212NoneForbidden50 kgE13, 40
Ammunition, tear-producing with burster, expelling charge or propelling charge1.2GUN0018II1.2G, 8, 6.162NoneForbiddenForbidden8E, 17E, 20E
Ammunition, tear-producing with burster, expelling charge or propelling charge1.3GUN0019II1.3G, 8, 6.162NoneForbiddenForbidden8E, 17E, 20E
Ammunition, tear-producing with burster, expelling charge or propelling charge1.4GUN0301II1.4G, 8, 6.162NoneForbidden75 kg7E, 8E, 14E, 15E, 17E
Ammunition, toxic, non-explosive, without burster or expelling charge, non-fuzed6.1UN2016II6.1None212NoneForbidden100 kgE13, 40
Ammunition, toxic (water-activated contrivances), with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc
GAmmunition, toxic with burster, expelling charge, or propelling charge1.2KUN0020II1.2K, 6.162NoneForbiddenForbidden088E, 14E, 15E, 17E
GAmmunition, toxic with burster, expelling charge, or propelling charge1.3KUN0021II1.3K, 6.162NoneForbiddenForbidden088E, 14E, 15E, 17E
Amyl acetates3UN1104III3B1, IB3, T2, TP115020324260 L220 LA
Amyl acid phosphate8UN2819III8IB3, T4, TP11542032415 L60 LA
Amyl butyrates3UN2620III3B1, IB3, T2, TP115020324260 L220 LA
Amyl chlorides3UN1107II3IB2, T4, TP11502022425 L60 LB
Amyl formates3UN1109III3B1, IB3, T2, TP115020324260 L220 LA
Amyl mercaptans3UN1111II3A3, A6, IB2, T4, TP1None2022425 L60 LB95, 102
n-Amyl methyl ketone3UN1110III3B1, IB3, T2, TP115020324260 L220 LA
Amyl nitrate3UN1112III3B1, IB3, T2, TP115020324260 L220 LA40
Amyl nitrites3UN1113II3IB2, T4, TP11502022425 L60 LE40
Amylamines3UN1106II3, 8IB2, T7, TP11502022431 L5 LB
III3, 8B1, IB3, T4, TP11502032425 L60 LA
Amyltrichlorosilane8UN1728II8A7, B2, B6, IB2, N34, T7, TP2, TP13None202242Forbidden30 LC40
Anhydrous ammonia, see Ammonia, anhydrous
Anhydrous hydrofluoric acid, see Hydrogen fluoride, anhydrous
+Aniline6.1UN1547II6.1IB2, T7, TP21532022435 L60 LA40, 52
Aniline hydrochloride6.1UN1548III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Aniline oil, see Aniline
Anisidines6.1UN2431III6.1IB3, T4, TP115320324160 L220 LA
Anisole3UN2222III3B1, IB3, T2, TP115020324260 L220 LA
Anisoyl chloride8UN1729II8B2, B4, IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA
Anti-freeze, liquid, see Flammable liquids, n.o.s.
Antimonous chloride, see Antimony trichloride
Antimony compounds, inorganic, liquid, n.o.s.6.1UN3141III6.135, IB3, T7, TP1, TP2815320324160 L220 LA
Antimony compounds, inorganic, solid, n.o.s.6.1UN1549III6.135, IB8, IP3, T1, TP33153213240100 kg200 kgA
Antimony lactate6.1UN1550III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Antimony pentachloride, liquid8UN1730II8B2, IB2, T7, TP2None2022421 L30 LC40
Antimony pentachloride, solutions8UN1731II8B2, IB2, T7, TP21542022421 L30 LC40
III8IB3, T4, TP11542032415 L60 LC40
Antimony pentafluoride8UN1732II8, 6.1A3, A6, A7, A10, IB2, N3, N36, T7, TP2None202243Forbidden30 LD44, 89, 100, 141
Antimony potassium tartrate6.1UN1551III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Antimony powder6.1UN2871III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Antimony sulfide and a chlorate, mixtures ofForbidden
Antimony sulfide, solid, see Antimony compounds, inorganic, n.o.s.
Antimony trichloride, liquid8UN1733II8B2, IB21542022421 L30 LC40
Antimony trichloride, solid8UN1733II8IB8, IP2, IP415421224015 kg50 kgA40
Aqua ammonia, see Ammonia solution, etc
Argon, compressed2.2UN10062.2306302314, 31575 kg150 kgA
Argon, refrigerated liquid (cryogenic liquid)2.2UN19512.2T75, TP532031631850 kg500 kgB
Arsenic6.1UN1558II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Arsenic acid, liquid6.1UN1553I6.1T20, TP2, TP7, TP13None2012431 L30 LB46
Arsenic acid, solid6.1UN1554II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Arsenic bromide6.1UN1555II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA12, 40
Arsenic chloride, see Arsenic trichloride
Arsenic compounds, liquid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s.6.1UN1556I6.1T14, TP2, TP13, TP27None2012431 L30 LB40, 137
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LB40, 137
III6.1IB3, T7, TP2, TP2815320324160 L220 LB40, 137
Arsenic compounds, solid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s.6.1UN1557I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA137
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA137
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA137
Arsenic pentoxide6.1UN1559II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Arsenic sulfide and a chlorate, mixtures ofForbidden
Arsenic trichloride6.1UN1560I6.12, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenB40
Arsenic trioxide6.1UN1561II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Arsenic, white, solid, see Arsenic trioxide
Arsenical dust6.1UN1562II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Arsenical pesticides, liquid, flammable, toxic, flash point less than 23 degrees C3UN2760I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LB40
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40
Arsenical pesticides, liquid, toxic6.1UN2994I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1IB3, T7, TP2, TP2815320324160 L220 LA40
Arsenical pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN2993I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3B1, IB3, T7, TP2, TP2815320324260 L220 LA40
Arsenical pesticides, solid, toxic6.1UN2759I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Arsenious acid, solid, see Arsenic trioxide
Arsenious and mercuric iodide solution, see Arsenic compounds, liquid, n.o.s.
Arsine2.3UN21882.3, 2.11None192245ForbiddenForbiddenD40
Articles, explosive, extremely insensitive or Articles, EEI1.6NUN0486II1.6N101None62NoneForbiddenForbidden07
GArticles, explosive, n.o.s.1.4SUN0349II1.4S101None62None25 kg100 kg05
GArticles, explosive, n.o.s.1.4BUN0350II1.4B101None62NoneForbiddenForbidden06
GArticles, explosive, n.o.s.1.4CUN0351II1.4C101None62NoneForbidden75 kg06
GArticles, explosive, n.o.s.1.4DUN0352II1.4D101None62NoneForbidden75 kg06
GArticles, explosive, n.o.s.1.4GUN0353II1.4G101None62NoneForbidden75 kg06
GArticles, explosive, n.o.s.1.1LUN0354II1.1L101None62NoneForbiddenForbidden088E, 14E, 15E, 17E
GArticles, explosive, n.o.s.1.2LUN0355II1.2L101None62NoneForbiddenForbidden088E, 14E, 15E, 17E
GArticles, explosive, n.o.s.1.3LUN0356II1.3L101None62NoneForbiddenForbidden088E, 14E, 15E, 17E
GArticles, explosive, n.o.s.1.1CUN0462II1.1C101None62NoneForbiddenForbidden07
GArticles, explosive, n.o.s.1.1DUN0463II1.1D101None62NoneForbiddenForbidden07
GArticles, explosive, n.o.s.1.1EUN0464II1.1E101None62NoneForbiddenForbidden07
GArticles, explosive, n.o.s.1.1FUN0465II1.1F101None62NoneForbiddenForbidden08
GArticles, explosive, n.o.s.1.2CUN0466II1.2C101None62NoneForbiddenForbidden07
GArticles, explosive, n.o.s.1.2DUN0467II1.2D101None62NoneForbiddenForbidden07
GArticles, explosive, n.o.s.1.2EUN0468II1.2E101None62NoneForbiddenForbidden07
GArticles, explosive, n.o.s.1.2FUN0469II1.2F101None62NoneForbiddenForbidden08
GArticles, explosive, n.o.s.1.3CUN0470II1.3C101None62NoneForbiddenForbidden07
GArticles, explosive, n.o.s.1.4EUN0471II1.4E101None62NoneForbidden75 kg06
GArticles, explosive, n.o.s.1.4FUN0472II1.4F101None62NoneForbiddenForbidden08
Articles, pressurized pneumatic or hydraulic containing non-flammable gas2.2UN31642.2306302, 304NoneNo limitNo limitA
Articles, pyrophoric1.2LUN0380II1.2LNone62NoneForbiddenForbidden088E, 14E, 15E, 17E
Articles, pyrotechnic for technical purposes1.1GUN0428II1.1GNone62NoneForbiddenForbidden07
Articles, pyrotechnic for technical purposes1.2GUN0429II1.2GNone62NoneForbiddenForbidden07
Articles, pyrotechnic for technical purposes1.3GUN0430II1.3GNone62NoneForbiddenForbidden07
Articles, pyrotechnic for technical purposes1.4GUN0431II1.4GNone62NoneForbidden75 kg06
Articles, pyrotechnic for technical purposes1.4SUN0432II1.4SNone62None25 kg100 kg05
DAsbestos9NA2212III9156, IB8, IP2, IP4155216240200 kg200 kgA34, 40
Ascaridole (organic peroxide)Forbidden
DAsphalt, at or above its flash point3NA1999III3IB3, T1, TP3150203247ForbiddenForbiddenD
DAsphalt, cut back, see Tars, liquid, etc
Automobile, motorcycle, tractor, other self-propelled vehicle, engine, or other mechanical apparatus, see Vehicles or Battery etc
A GAviation regulated liquid, n.o.s.9UN33349A35155204No limitNo limitA
A GAviation regulated solid, n.o.s.9UN33359A35155204No limitNo limitA
Azaurolic acid (salt of) (dry)Forbidden
Azido guanidine picrate (dry)Forbidden
5-Azido-1-hydroxy tetrazoleForbidden
Azido hydroxy tetrazole (mercury and silver salts)Forbidden
3-Azido-1,2-Propylene glycol dinitrateForbidden
Azidodithiocarbonic acidForbidden
Azidoethyl nitrateForbidden
1-Aziridinylphosphine oxide-(tris), see Tris-(1-aziridinyl) phosphine oxide, solution
Azodicarbonamide4.1UN3242II4.138, IB8, T3, TP33151212240ForbiddenForbiddenD12, 52, 53, 74
Azotetrazole (dry)Forbidden
Barium4.3UN1400II4.3A19, IB7, IP2, T3, TP3315121224115 kg50 kgE52
Barium alloys, pyrophoric4.2UN1854I4.2T21, TP7, TP33None181NoneForbiddenForbiddenD
Barium azide, dry or wetted with less than 50 percent water, by mass1.1AUN0224II1.1A, 6.1111, 117None62NoneForbiddenForbidden12
Barium azide, wetted with not less than 50 percent water, by mass4.1UN1571I4.1, 6.1162, A2None182NoneForbidden0.5 kgD28
Barium bromate5.1UN2719II5.1, 6.1IB8, IP2, IP4, T3, TP331522122425 kg25 kgA56, 58
Barium chlorate, solid5.1UN1445II5.1, 6.1A9, IB6, IP2, N34, T3, TP331522122425 kg25 kgA56, 58
Barium chlorate, solution5.1UN3405II5.1, 6.1A9, IB2, N34, T4, TP11522022431 L5 LA56, 58, 133
III5.1, 6.1A9, IB2, N34, T4, TP11522032422.5 L30 LA56, 58, 133
Barium compounds, n.o.s.6.1UN1564II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Barium cyanide6.1UN1565I6.1IB7, IP1, N74, N75, T6, TP33None2112425 kg50 kgA40, 52
Barium hypochlorite with more than 22 percent available chlorine5.1UN2741II5.1, 6.1A7, A9, IB8, IP2, IP4, N34, T3, TP33152212None5 kg25 kgB4, 52, 56, 58, 106
Barium nitrate5.1UN1446II5.1, 6.1IB8, IP2, IP4, T3, TP331522122425 kg25 kgA
Barium oxide6.1UN1884III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Barium perchlorate, solid5.1UN1447II5.1, 6.1IB6, IP2, T3, TP331522122425 kg25 kgA56, 58
Barium perchlorate, solution5.1UN3406II5.1, 6.1IB2, T4, TP11522022431 L5 LA56, 58, 133
III5.1, 6.1IB2, T4, TP11522032422.5 L30 LA56, 58, 133
Barium permanganate5.1UN1448II5.1, 6.1IB6, IP2, T3, TP331522122425 kg25 kgD56, 58, 138
Barium peroxide5.1UN1449II5.1, 6.1A9, IB6, IP2, T3, TP331522122425 kg25 kgA13, 52, 56, 75
Barium selenate, see Selenates or Selenites
Barium selenite, see Selenates or Selenites
Batteries, containing sodium4.3UN3292II4.3189189189ForbiddenNo limitA
Batteries, dry, containing potassium hydroxide solid, electric, storage8UN3028III8None213None25 kg gross230 kg grossA
Batteries, wet, filled with acid, electric storage8UN2794III815915915930 kg grossNo limitA
Batteries, wet, filled with alkali, electric storage8UN2795III815915915930 kg grossNo limitA
Batteries, wet, non-spillable, electric storage8UN2800III8159159159No LimitNo LimitA
Batteries, dry, not subject to the requirements of this subchapter130
Battery fluid, acid8UN2796II8A3, A7, B2, B15, IB2, N6, N34, T8, TP2, TP121542022421 L30 LB
Battery fluid, alkali8UN2797II8B2, IB2, N6, T7, TP2, TP281542022421 L30 LA29
Battery lithium type, see Lithium batteries etc
Battery-powered vehicle or Battery-powered equipment9UN31719134220220NoneNo limitNo limit
Battery, wet, filled with acid or alkali with vehicle or mechanical equipment containing an internal combustion engine, see Vehicle, etc. or Engines, internal combustion, etc
+Benzaldehyde9UN1990III9IB3, T2, TP1155203241100 L220 LA
Benzene3UN1114II3IB2, T4, TP11502022425 L60 LB40
Benzene diazonium chloride (dry)Forbidden
Benzene diazonium nitrate (dry)Forbidden
Benzene phosphorus dichloride, see Phenyl phosphorus dichloride
Benzene phosphorus thiodichloride, see Phenyl phosphorus thiodichloride
Benzene sulfonyl chloride8UN2225III8IB3, T4, TP11542032415 L60 LA40
Benzene triozonideForbidden
Benzenethiol, see Phenyl mercaptan
Benzidine6.1UN1885II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Benzol, see Benzene
Benzonitrile6.1UN2224II6.1IB2, T7, TP21532022435 L60 LA40, 52
Benzoquinone6.1UN2587II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Benzotrichloride8UN2226II8B2, IB2, T7, TP21542022421 L30 LA40
Benzotrifluoride3UN2338II3IB2, T4, TP11502022425 L60 LB40
Benzoxidiazoles (dry)Forbidden
Benzoyl azideForbidden
Benzoyl chloride8UN1736II8B2, IB2, T8, TP2, TP12, TP131542022421 L30 LC40
Benzyl bromide6.1UN1737II6.1, 8A3, A7, IB2, N33, N34, T8, TP2, TP12, TP131532022431 L30 LD13, 40
Benzyl chloride6.1UN1738II6.1, 8A3, A7, B70, IB2, N33, N42, T8, TP2, TP12, TP131532022431 L30 LD13, 40
Benzyl chloride unstabilized6.1UN1738II6.1, 8A3, A7, B8, B11, IB2, N33, N34, N43, T8, TP2, TP12, TP131532022431 L30 LD13, 40
Benzyl chloroformate8UN1739I8A3, A6, B4, N41, T10, TP2, TP12, TP13None201243Forbidden2.5 LD40
Benzyl iodide6.1UN2653II6.1IB2, T7, TP21532022435 L60 LB12, 40
Benzyldimethylamine8UN2619II8, 3B2, IB2, T7, TP21542022431 L30 LA40, 48
Benzylidene chloride6.1UN1886II6.1IB2, T7, TP21532022435 L60 LD40
Beryllium compounds, n.o.s.6.1UN1566II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Beryllium nitrate5.1UN2464II5.1, 6.1IB8, IP2, IP4, T3, TP331522122425 kg25 kgA
Beryllium, powder6.1UN1567II6.1, 4.1IB8, IP2, IP4, T3, TP3315321224215 kg50 kgA
Bicyclo [2,2,1] hepta-2,5-diene, stabilized or 2,5-Norbornadiene, stabilized3UN2251II3IB2, T7, TP21502022425 L60 LD
Biphenyl triozonideForbidden
Bipyridilium pesticides, liquid, flammable, toxic, flash point less than 23 degrees C3UN2782I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LE
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40
Bipyridilium pesticides, liquid, toxic6.1UN3016I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1IB3, T7, TP2, TP2815320324160 L220 LA40
Bipyridilium pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN3015I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB21, 40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB21, 40
III6.1, 3B1, IB3, T7, TP2, TP2815320324260 L220 LA21, 40
Bipyridilium pesticides, solid, toxic6.1UN2781I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Bis (Aminopropyl) piperazine, see Corrosive liquid, n.o.s.
Bisulfate, aqueous solution8UN2837II8A7, B2, IB2, N34, T7, TP21542022421 L30 LA
III8A7, IB3, N34, T4, TP11542032415 L60 LA
Bisulfites, aqueous solutions, n.o.s.8UN2693III8IB3, T7, TP1, TP281542032415 L60 LA40, 52
Black powder, compressed or Gunpowder, compressed or Black powder, in pellets or Gunpowder, in pellets1.1DUN0028II1.1DNone62NoneForbiddenForbidden10
Black powder or Gunpowder, granular or as a meal1.1DUN0027II1.1DNone62NoneForbiddenForbidden10
DBlack powder for small arms4.1NA0027I4.170None170NoneForbiddenForbiddenE
Blasting agent, n.o.s., see Explosives, blasting etc
Blasting cap assemblies, see Detonator assemblies, non-electric, for blasting
Blasting caps, electric, see Detonators, electric for blasting
Blasting caps, non-electric, see Detonators, non-electric, for blasting
Bleaching powder, see Calcium hypochlorite mixtures, etc
IBlue asbestos (Crocidolite)or Brown asbestos (amosite, mysorite)9UN2212II9156, IB8, IP2, IP4, T3, TP33155216240ForbiddenForbiddenA34, 40
Bombs, photo-flash1.1FUN0037II1.1F62NoneForbiddenForbidden08
Bombs, photo-flash1.1DUN0038II1.1D62NoneForbiddenForbidden03
Bombs, photo-flash1.2GUN0039II1.2G62NoneForbiddenForbidden03
Bombs, photo-flash1.3GUN0299II1.3G62NoneForbiddenForbidden03
Bombs, smoke, non-explosive, with corrosive liquid, without initiating device8UN2028II8None160NoneForbidden50 kgE40
Bombs, with bursting charge1.1FUN0033II1.1F62NoneForbiddenForbidden08
Bombs, with bursting charge1.1DUN0034II1.1D62NoneForbiddenForbidden03
Bombs, with bursting charge1.2DUN0035II1.2D62NoneForbiddenForbidden03
Bombs, with bursting charge1.2FUN0291II1.2F62NoneForbiddenForbidden08
Bombs with flammable liquid, with bursting charge1.1JUN0399II1.1J62NoneForbiddenForbidden0423E
Bombs with flammable liquid, with bursting charge1.2JUN0400II1.2J62NoneForbiddenForbidden0423E
Boosters with detonator1.1BUN0225II1.1BNone62NoneForbiddenForbidden11
Boosters with detonator1.2BUN0268II1.2BNone62NoneForbiddenForbidden07
Boosters, without detonator1.1DUN0042II1.1DNone62NoneForbiddenForbidden07
Boosters, without detonator1.2DUN0283II1.2DNone62NoneForbiddenForbidden07
Borate and chlorate mixtures, see Chlorate and borate mixtures
Borneol4.1UN1312III4.1A1, IB8, IP3, T1, TP33None21324025 kg100 kgA
+Boron tribromide8UN2692I8, 6.12, B9, B14, B32, B74, N34, T20, TP2, TP12, TP13, TP38, TP45None227244ForbiddenForbiddenC12
Boron trichloride2.3UN17412.3, 83, B9, B14None304314ForbiddenForbiddenD25, 40
Boron trifluoride2.3UN10082.32, B9, B14None302314, 315ForbiddenForbiddenD40
Boron trifluoride acetic acid complex, liquid8UN1742II8B2, B6, IB2, T8, TP2, TP121542022421 L30 LA
Boron trifluoride acetic acid complex, solid8UN3419II8B2, B6, IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA
Boron trifluoride diethyl etherate8UN2604I8, 3A3, A19, T10, TP2None2012430.5 L2.5 LD40
Boron trifluoride dihydrate8UN2851II8IB2, T7, TP215421224015 kg50 kgB12, 40,
Boron trifluoride dimethyl etherate4.3UN2965I4.3, 8, 3A19, T10, TP2, TP7None201243Forbidden1 LD21, 28, 40, 49, 100
Boron trifluoride propionic acid complex, liquid8UN1743II8B2, IB2, T8, TP2, TP121542022421 L30 LA
Boron trifluoride propionic acid complex, solid8UN3420II8B2, IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA
Box toe gum, see Nitrocellulose etc
Bromates, inorganic, aqueous solution, n.o.s.5.1UN3213II5.1IB2, T4, TP11522022421 L5 LB56, 58, 133
III5.1IB2, T4, TP11522032412.5 L30 LB56, 58, 133
Bromates, inorganic, n.o.s.5.1UN1450II5.1IB8, IP2, IP4, T3, TP331522122425 kg25 kgA56, 58
Bromine azideForbidden
+Bromine or Bromine solutions8UN1744I8, 6.11, B9, B64, B85, N34, N43, T22, TP2, TP10, TP12, TP13None226249ForbiddenForbidden12, 40, 66, 74, 89, 90
Bromine chloride2.3UN29012.3, 8, 5.12, B9, B14None304314, 315ForbiddenForbiddenD40, 89, 90
+Bromine pentafluoride5.1UN1745I5.1, 6.1, 81, B9, B14, B30, B72, T22, TP2, TP12, TP13, TP38, TP44None228244ForbiddenForbiddenD25, 40, 66, 90
+Bromine trifluoride5.1UN1746I5.1, 6.1, 82, B9, B14, B32, B74, T22, TP2, TP12, TP13, TP38, TP45None228244ForbiddenForbiddenD25, 40, 66, 90
4-Bromo-1,2-dinitrobenzeneForbidden
4-Bromo-1,2-dinitrobenzene (unstable at 59 degrees C)Forbidden
1-Bromo-3-chloropropane6.1UN2688III6.1IB3, T4, TP115320324160 L220 LA
1-Bromo-3-methylbutane3UN2341III3B1, IB3, T2, TP115020324260 L220 LA
1-Bromo-3-nitrobenzene (unstable at 56 degrees C)Forbidden
2-Bromo-2-nitropropane-1,3-diol4.1UN3241III4.146, IB8, IP3151213None25 kg50 kgC12, 25, 40
Bromoacetic acid, solid8UN3425II8A7, IB8, IP2, IP4, N34, T3, TP3315421224015 kg50 kgA
Bromoacetic acid solution8UN1938II8A7, B2, IB2, T7, TP21542022421 L30 LA40
III8B2, IB3, T7, TP21542032415 L60 LA40
+Bromoacetone6.1UN1569II6.1, 32, T20, TP2, TP13None193245ForbiddenForbiddenD40
Bromoacetyl bromide8UN2513II8B2, IB2, T8, TP2, TP121542022421 L30 LC40, 53
Bromobenzene3UN2514III3B1, IB3, T2, TP115020324260 L220 LA
Bromobenzyl cyanides, liquid6.1UN1694I6.1T14, TP2, TP13None201243Forbidden30 LD12, 40, 52
Bromobenzyl cyanides, solid6.1UN3449I6.1T6, TP33None2112425 kg50 kgD12, 40, 52
1-Bromobutane3UN1126II3IB2, T4, TP11502022425 L60 LB40
2-Bromobutane3UN2339II3B1, IB2, T4, TP11502022425 L60 LB40
Bromochloromethane6.1UN1887III6.1IB3, T4, TP115320324160 L220 LA
2-Bromoethyl ethyl ether3UN2340II3IB2, T4, TP11502022425 L60 LB40
Bromoform6.1UN2515III6.1IB3, T4, TP115320324160 L220 LA12, 40
Bromomethylpropanes3UN2342II3IB2, T4, TP11502022425 L60 LB
2-Bromopentane3UN2343II3IB2, T4, TP11502022425 L60 LB
Bromopropanes3UN2344II3IB2, T4, TP11502022425 L60 LB40
III3IB3, T2, TP115020324260 L220 LA
3-Bromopropyne3UN2345II3IB2, T4, TP11502022425 L60 LD40
BromosilaneForbidden
Bromotoluene-alpha, see Benzyl bromide
Bromotrifluoroethylene2.1UN24192.1None304314, 315Forbidden150 kgB40
Bromotrifluoromethane or Refrigerant gas, R 13B1.2.2UN10092.2T50306304314, 31575 kg150 kgA
Brucine6.1UN1570I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA
Bursters, explosive1.1DUN0043II1.1DNone62NoneForbiddenForbidden07
Butadienes, stabilized or Butadienes and Hydrocarbon mixture, stabilized containing more than 40% butadienes2.1UN10102.1T50306304314, 315Forbidden150 kgB40
Butane see also Petroleum gases, liquefied2.1UN10112.119, T50306304314, 315Forbidden150 kgE40
Butane, butane mixtures and mixtures having similar properties in cartridges each not exceeding 500 grams, see Receptacles, etc
Butanedione3UN2346II3IB2, T4, TP11502022425 L60 LB
1,2,4-Butanetriol trinitrateForbidden
Butanols3UN1120II3IB2, T4, TP1, TP291502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
tert-Butoxycarbonyl azideForbidden
Butyl acetates3UN1123II3IB2, T4, TP11502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Butyl acid phosphate8UN1718III8IB3, T4, TP11542032415 L60 LA
Butyl acrylates, stabilized3UN2348III3B1, IB3, T2, TP115020324260 L220 LA
Butyl alcohols, see Butanols
Butyl benzenes3UN2709III3B1, IB3, T2, TP115020324260 L220 LA
n-Butyl bromide, see 1-Bromobutane
n-Butyl chloride, see Chlorobutanes
Dsec-Butyl chloroformate6.1NA2742I6.1, 3, 82, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45None2272441 L30 LA12, 13, 22, 25, 40, 48, 100
n-Butyl chloroformate6.1UN2743I6.1, 8, 32, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenA12, 13, 21, 25, 40, 100
Butyl ethers, see Dibutyl ethers
Butyl ethyl ether, see Ethyl butyl ether
n-Butyl formate3UN1128II3IB2, T4, TP11502022425 L60 LB
tert-Butyl hydroperoxide, with more than 90 percent with waterForbidden
tert-Butyl hypochlorite4.2UN3255I4.2, 8None211243ForbiddenForbiddenD
N-n-Butyl imidazole6.1UN2690II6.1IB2, T7, TP21532022435 L60 LA
tert-Butyl isocyanate6.1UN2484I6.1, 31, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44None226244ForbiddenForbiddenD40
n-Butyl isocyanate6.1UN2485I6.1, 32, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Butyl mercaptans3UN2347II3A3, A6, IB2, T4, TP11502022425 L60 LD52, 95
n-Butyl methacrylate, stabilized3UN2227III3B1, IB3, T2, TP115020324260 L220 LA
Butyl methyl ether3UN2350II3IB2, T4, TP11502022425 L60 LB
Butyl nitrites3UN2351I3T11, TP1, TP8, TP271502012431 L30 LE40
II3IB2, T4, TP11502022425 L60 LB40
III3B1, IB3, T2, TP115020324260 L220 LA40
tert-Butyl peroxyacetate, with more than 76 percent in solutionForbidden
n-Butyl peroxydicarbonate, with more than 52 percent in solutionForbidden
tert-Butyl peroxyisobutyrate, with more than 77 percent in solutionForbidden
Butyl phosphoric acid, see Butyl acid phosphate
Butyl propionates3UN1914III3B1, IB3, T2, TP115020324260 L220 LA
5-tert-Butyl-2,4,6-trinitro-m-xylene or Musk xylene4.1UN2956III4.1159None223NoneForbiddenForbiddenDD12, 25, 48, 127
Butyl vinyl ether, stabilized3UN2352II3IB2, T4, TP11502022425 L60 LB40
n-Butylamine3UN1125II3, 8IB2, T7, TP11502022421 L5 LB40
N-Butylaniline6.1UN2738II6.1IB2, T7, TP21532022435 L60 LA74
tert-Butylcyclohexylchloroformate6.1UN2747III6.1IB3, T4, TP115320324160 L220 LA12, 13, 25
Butylene see also Petroleum gases, liquefied2.1UN10122.119, T50306304314, 315Forbidden150 kgE40
1,2-Butylene oxide, stabilized3UN3022II3IB2, T4, TP11502022425 L60 LB27, 49
Butyltoluenes6.1UN2667III6.1IB3, T4, TP115320324160 L220 LA
Butyltrichlorosilane8UN1747II8, 3A7, B2, B6, IB2, N34, T7, TP2, TP13None202243Forbidden30 LC40
1,4-Butynediol6.1UN2716III6.1A1, IB8, IP3, T1, TP33None213240100 kg200 kgA52, 53, 70, 139, 140
Butyraldehyde3UN1129II3IB2, T4, TP11502022425 L60 LB
Butyraldoxime3UN2840III3B1, IB3, T2, TP115020324260 L220 LA
Butyric acid8UN2820III8IB3, T4, TP11542032415 L60 LA12
Butyric anhydride8UN2739III8IB3, T4, TP11542032415 L60 LA
Butyronitrile3UN2411II3, 6.1IB2, T7, TP1, TP131502022431 L60 LE40
Butyryl chloride3UN2353II3, 8IB2, T8, TP2, TP12, TP131502022431 L5 LC40
Cacodylic acid6.1UN1572II6.1IB8, IP2, IP4,T3, TP3315321224225 kg100 kgE52
Cadmium compounds6.1UN2570I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Caesium hydroxide8UN2682II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA29
Caesium hydroxide solution8UN2681II8B2, IB2, T7, TP21542022421 L30 LA29
III8IB3, T4, TP11542032415 L60 LA29
Calcium4.3UN1401II4.3IB7, IP2, T3, TP3315121224115 kg50 kgE52
Calcium arsenate6.1UN1573II6.1IB8, IP2, IP4, T3, TP3315221224225 kg100 kgA
Calcium arsenate and calcium arsenite, mixtures, solid6.1UN1574II6.1IB8, IP2, IP4, T3, TP3315221224225 kg100 kgA
Calcium bisulfite solution, see Bisulfites, aqueous solutions, n.o.s.
Calcium carbide4.3UN1402I4.3A1, A8, B55, B59, IB4, IP1, N34, T9, TP7, TP33None211242Forbidden15 kgB52
II4.3A1, A8, B55, B59, IB7, IP2, N34, T3, TP3315121224115 kg50 kgB52
Calcium chlorate5.1UN1452II5.1A9, IB8, IP2, IP4, N34, T3, TP331522122425 kg25 kgA56, 58
Calcium chlorate aqueous solution5.1UN2429II5.1A2, IB2, N41, T4, TP11522022421 L5 LB56, 58, 133
III5.1A2, IB2, N41, T4, TP11522032412.5 L30 LB56, 68, 133
Calcium chlorite5.1UN1453II5.1A9, IB8, IP2, IP4, N34, T3, TP331522122425 kg25 kgA56, 58
Calcium cyanamide with more than 0.1 percent of calcium carbide4.3UN1403III4.3A1, A19, IB8, IP4, T1, TP3315121324125 kg100 kgA52
Calcium cyanide6.1UN1575I6.1IB7, IP1, N79, N80, T6, TP33None2112425 kg50 kgA40, 52
Calcium dithionite or Calcium hydrosulfite4.2UN1923II4.2A19, A20, IB6, IP2, T3, TP33None21224115 kg50 kgE13
Calcium hydride4.3UN1404I4.3A19, N40None211242Forbidden15 kgE52
Calcium hydrosulfite, see Calcium dithionite
Calcium hypochlorite, dry or Calcium hypochlorite mixtures dry with more than 39 percent available chlorine (8.8 percent available oxygen)5.1UN1748II5.1165, 166, A7, A9, IB8, IP2, IP4, IP13, N34, W9152212None5 kg25 kgD4, 25, 48, 52, 56, 58, 69, 142
III5.1165, 171, A7, A9, IB8, IP4, IP13, N34, W915221324025 kg100 kgD4, 25, 48, 52, 56, 58, 69, 142
Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixtures, with not less than 5.5 percent but not more than 16 percent water5.1UN2880II5.1165, 166, IB8, IP2, IP4, IP13, W91522122405 kg25 kgD4, 25, 48, 52, 56, 58, 69, 142
III5.1165, 171, IB8, IP4, IP13, W915221324025 kg100 kgD4, 25, 48, 52, 56, 58, 69, 142
Calcium hypochlorite mixtures, dry, with more than 10 percent but not more than 39 percent available chlorine5.1UN2208III5.1165, A1, A29, IB8, IP3, IP13, N34, W915221324025 kg100 kgD4, 25, 48, 52, 56, 58, 69, 142
Calcium manganese silicon4.3UN2844III4.3A1, A19, IB8, IP2, IP4, T1, TP3315121324125 kg100 kgA52, 85, 103
Calcium nitrate5.1UN1454III5.134, IB8, IP3, T1, TP3315221324025 kg100 kgA
ACalcium oxide8UN1910III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Calcium perchlorate5.1UN1455II5.1IB6, IP2, T3, TP331522122425 kg25 kgA56, 58
Calcium permanganate5.1UN1456II5.1IB6, IP2, T3, TP331522122425 kg25 kgD56, 58, 138
Calcium peroxide5.1UN1457II5.1IB6, IP2, T3, TP331522122425 kg25 kgA13, 52, 56, 75
Calcium phosphide4.3UN1360I4.3, 6.1A8, A19, N40None211242Forbidden15 kgE40, 52, 85
Calcium, pyrophoric or Calcium alloys, pyrophoric4.2UN1855I4.2None187NoneForbiddenForbiddenD
Calcium resinate4.1UN1313III4.1A1, A19, IB6, T1, TP33None21324025 kg100 kgA
Calcium resinate, fused4.1UN1314III4.1A1, A19, IB4, T1, TP33None21324025 kg100 kgA
Calcium selenate, see Selenates or Selenites
Calcium silicide4.3UN1405II4.3A19, IB7, IP2, T3, TP3315121224115 kg50 kgB52, 85, 103
III4.3A1, A19, IB8, IP4, T1, TP3315121324125 kg100 kgB52, 85, 103
Camphor oil3UN1130III3B1, IB3, T2, TP115020324260 L220 LA
Camphor, synthetic4.1UN2717III4.1A1, IB8, IP3, T1, TP33None21324025 kg100 kgA
Cannon primers, see Primers, tubular
Caproic acid8UN2829III8IB3, T4, TP11542032415 L60 LA
Caps, blasting, see Detonators, etc
Carbamate pesticides, liquid, flammable, toxic, flash point less than 23 degrees C3UN2758I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LB40
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40
Carbamate pesticides, liquid, toxic6.1UN2992I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1IB3, T7, TP2, TP2815320324160 L220 LA40
Carbamate pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN2991I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3B1, IB3, T7, TP2, TP2815320324260 L220 LA40
Carbamate pesticides, solid, toxic6.1UN2757I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Carbolic acid, see Phenol, solid or Phenol, molten
Carbolic acid solutions, see Phenol solutions
ICarbon, activated4.2UN1362III4.2IB8, IP3, T1, TP33None2132410.5 kg0.5 kgA12
ICarbon, animal or vegetable origin4.2UN1361II4.2IB6, T3, TP33None212242ForbiddenForbiddenA12
III4.2IB8, IP3, T1, TP33None213241ForbiddenForbiddenA12
Carbon bisulfide, see Carbon disulfide
Carbon dioxide2.2UN10132.2306302, 304302, 314, 31575 kg150 kgA
Carbon dioxide and nitrous oxide mixtures2.2UN10152.2306None314, 31575 kg150 kgA
Carbon dioxide and oxygen mixtures, compressed2.2UN10142.2, 5.177, A14306304314, 31575 kg150 kgA
Carbon dioxide, refrigerated liquid2.2UN21872.2T75, TP5306304314, 31550 kg500 kgB
A WCarbon dioxide, solid or Dry ice9UN1845IIINone217217240200 kg200 kgC40
Carbon disulfide3UN1131I3, 6.1B16, T14, TP2, TP7, TP13None201243ForbiddenForbiddenD18, 40, 115
Carbon monoxide, compressed2.3UN10162.3, 2.14None302314, 315Forbidden25 kgD40
Carbon monoxide and hydrogen mixture, compressed2.3UN26002.3, 2.16None302302ForbiddenForbiddenD40, 57
DCarbon monoxide, refrigerated liquid (cryogenic liquid)2.3NA92022.3, 2.14, T75, TP5None316318ForbiddenForbiddenD
Carbon tetrabromide6.1UN2516III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA25
Carbon tetrachloride6.1UN1846II6.1IB2, N36, T7, TP21532022435 L60 LA40
Carbonyl chloride, see Phosgene
Carbonyl fluoride2.3UN24172.3, 82None302NoneForbiddenForbiddenD40
Carbonyl sulfide2.3UN22042.3, 2.13, B14None304314, 315ForbiddenForbiddenD40
Cartridge cases, empty primed, see Cases, cartridge, empty, with primer
Cartridges, actuating, for aircraft ejector seat catapult, fire extinguisher, canopy removal or apparatus, see Cartridges, power device
Cartridges, explosive, see Charges, demolition
Cartridges, flash1.1GUN0049II1.1GNone62NoneForbiddenForbidden07
Cartridges, flash1.3GUN0050II1.3GNone62NoneForbidden75 kg07
Cartridges for weapons, blank1.1CUN0326II1.1CNone62NoneForbiddenForbidden07
Cartridges for weapons, blank1.2CUN0413II1.2CNone62NoneForbiddenForbidden07
Cartridges for weapons, blank or Cartridges, small arms, blank1.4SUN0014IINone6362None25 kg100 kg05
Cartridges for weapons, blank or Cartridges, small arms, blank1.3CUN0327II1.3CNone62NoneForbiddenForbidden07
Cartridges for weapons, blank or Cartridges, small arms, blank1.4CUN0338II1.4CNone62NoneForbidden75 kg06
Cartridges for weapons, inert projectile1.2CUN0328II1.2CNone62NoneForbiddenForbidden03
Cartridges for weapons, inert projectile or Cartridges, small arms1.4SUN0012IINone6362None25 kg100 kg05
Cartridges for weapons, inert projectile or Cartridges, small arms1.4CUN0339II1.4CNone62NoneForbidden75 kg06
Cartridges for weapons, inert projectile or Cartridges, small arms1.3CUN0417II1.3CNone62NoneForbiddenForbidden06
Cartridges for weapons, with bursting charge1.1FUN0005II1.1FNone62NoneForbiddenForbidden08
Cartridges for weapons, with bursting charge1.1EUN0006II1.1ENone62NoneForbiddenForbidden03
Cartridges for weapons, with bursting charge1.2FUN0007II1.2FNone62NoneForbiddenForbidden08
Cartridges for weapons, with bursting charge1.2EUN0321II1.2ENone62NoneForbiddenForbidden03
Cartridges for weapons, with bursting charge1.4FUN0348II1.4FNone62NoneForbiddenForbidden08
Cartridges for weapons, with bursting charge1.4EUN0412II1.4ENone62NoneForbidden75 kg02
Cartridges, oil well1.3CUN0277II1.3CNone62NoneForbiddenForbidden07
Cartridges, oil well1.4CUN0278II1.4CNone62NoneForbidden75 kg06
Cartridges, power device1.3CUN0275II1.3CNone62NoneForbidden75 kg07
Cartridges, power device1.4CUN0276II1.4C110None62NoneForbidden75 kg06
Cartridges, power device1.4SUN0323II1.4S1106362None25 kg100 kg05
Cartridges, power device1.2CUN0381II1.2CNone62NoneForbiddenForbidden07
Cartridges, safety, blank, see Cartridges for weapons, blank (UN 0014)
Cartridges, safety, see Cartridges for weapons, other than blank or Cartridges, power device (UN 0323)
Cartridges, signal1.3GUN0054II1.3GNone62NoneForbidden75 kg07
Cartridges, signal1.4GUN0312II1.4GNone62NoneForbidden75 kg06
Cartridges, signal1.4SUN0405II1.4SNone62None25 kg100 kg05
DCartridges, small armsORM-DNone63NoneNone30 kg gross30 kg grossA
DCartridges power device (used to project fastening devices)ORM-DNone63NoneNone30 kg gross30 kg grossA
Cartridges, sporting, see Cartridges for weapons, other than blank
Cartridges, starter, jet engine, see Cartridges, power device
Cases, cartridge, empty with primer1.4SUN0055II1.4S50None62None25 kg100 kg05
Cases, cartridges, empty with primer1.4CUN0379II1.4C50None62NoneForbidden75 kg06
Cases, combustible, empty, without primer1.4CUN0446II1.4CNone62NoneForbidden75 kg06
Cases, combustible, empty, without primer1.3CUN0447II1.3CNone62NoneForbiddenForbidden07
Casinghead gasoline see Gasoline
A WCastor beans or Castor meal or Castor pomace or Castor flake9UN2969IINoneIB8, IP2, IP4, T3, TP33155204240No limitNo limitE34, 40
GCaustic alkali liquids, n.o.s.8UN1719II8B2, IB2, T11, TP2, TP271542022421 L30 LA29
III8IB3, T7, TP1, TP281542032415 L60 LA29
Caustic potash, see Potassium hydroxide etc
Caustic soda, (etc.) see Sodium hydroxide etc
Cells, containing sodium4.3UN3292II4.318918918925 kg grossNo limitA
Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap4.1UN2000III4.1None21324025 kg100 kgA
Celluloid, scrap4.2UN2002III4.2IB8, IP3None213241ForbiddenForbiddenD
Cement, see Adhesives containing flammable liquid
Cerium, slabs, ingots, or rods4.1UN1333II4.1IB8, IP2, IP4, N34None21224015 kg50 kgA74, 91
Cerium, turnings or gritty powder4.3UN3078II4.3A1, IB7, IP2, T3, TP3315121224215 kg50 kgE52
Cesium or Caesium4.3UN1407I4.3A7, A19, IB4, IP1, N34, N40None211242Forbidden15 kgD52
Cesium nitrate or Caesium nitrate5.1UN1451III5.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA
DCharcoal briquettes, shell, screenings, wood, etc.4.2NA1361III4.2IB8, T1, TP3315121324025 kg100 kgA12
Charges, bursting, plastics bonded1.1DUN0457II1.1DNone62NoneForbiddenForbidden07
Charges, bursting, plastics bonded1.2DUN0458II1.2DNone62NoneForbiddenForbidden07
Charges, bursting, plastics bonded1.4DUN0459II1.4DNone62NoneForbidden75 kg06
Charges, bursting, plastics bonded1.4SUN0460II1.4SNone62None25 kg100 kg05
Charges, demolition1.1DUN0048II1.1DNone62NoneForbiddenForbidden03
Charges, depth1.1DUN0056II1.1DNone62NoneForbiddenForbidden03
Charges, expelling, explosive, for fire extinguishers, see Cartridges, power device
Charges, explosive, commercial without detonator1.1DUN0442II1.1DNone62NoneForbiddenForbidden07
Charges, explosive, commercial without detonator1.2DUN0443II1.2DNone62NoneForbiddenForbidden07
Charges, explosive, commercial without detonator1.4DUN0444II1.4DNone62NoneForbidden75 kg06
Charges, explosive, commercial without detonator1.4SUN0445II1.4SNone62None25 kg100 kg05
Charges, propelling1.1CUN0271II1.1CNone62NoneForbiddenForbidden07
Charges, propelling1.3CUN0272II1.3CNone62NoneForbiddenForbidden07
Charges, propelling1.2CUN0415II1.2CNone62NoneForbiddenForbidden07
Charges, propelling1.4CUN0491II1.4CNone62NoneForbidden75 kg06
Charges, propelling, for cannon1.3CUN0242II1.3CNone62NoneForbiddenForbidden10
Charges, propelling, for cannon1.1CUN0279II1.1CNone62NoneForbiddenForbidden10
Charges, propelling, for cannon1.2CUN0414II1.2CNone62NoneForbiddenForbidden10
Charges, shaped, flexible, linear1.4DUN0237II1.4DNone62NoneForbidden75 kg06
Charges, shaped, flexible, linear1.1DUN0288II1.1D101None62NoneForbiddenForbidden07
Charges, shaped, without detonator1.1DUN0059II1.1DNone62NoneForbiddenForbidden07
Charges, shaped, without detonator1.2DUN0439II1.2DNone62NoneForbiddenForbidden07
Charges, shaped, without detonator1.4DUN0440II1.4DNone62NoneForbidden75 kg06
Charges, shaped, without detonator1.4SUN0441II1.4SNone62None25 kg100 kg05
Charges, supplementary explosive1.1DUN0060II1.1DNone62NoneForbiddenForbidden10
DChemical kit8NA1760II8154161None1 L30 LB40
Chemical kits9UN3316915161161None10 kg10 kgA
Chloral, anhydrous, stabilized6.1UN2075II6.1IB2, T7, TP21532022435 L60 LD40
Chlorate and borate mixtures5.1UN1458II5.1A9, IB8, IP2, IP4, N34, T3, TP331522122405 kg25 kgA56, 58
III5.1A9, IB8, IP3, N34, T1, TP3315221324025 kg100 kgA56, 58
Chlorate and magnesium chloride mixture, solid5.1UN1459II5.1A9, IB8, IP2, IP4, N34, T3, TP331522122405 kg25 kgA56, 58
Chlorate and magnesium chloride mixture solution5.1UN3407II5.1A9, IB2, N34, T4, TP11522022421 L5 LA56, 58, 133
III5.1A9, IB2, N34, T4, TP11522032412.5 L30 LA56, 58, 133
Chlorate and magnesium chloride mixture, solid5.1UN1459III5.1A9, IB8, IP3, N34, T1, TP3315221324025 kg100 kgA56, 58
Chlorate of potash, see Potassium chlorate
Chlorate of soda, see Sodium chlorate
Chlorates, inorganic, aqueous solution, n.o.s.5.1UN3210II5.1IB2, T4, TP11522022421 L5 LB56, 58, 133
III5.1IB2, T4, TP11522032412.5 L30 LB56, 58, 133
Chlorates, inorganic, n.o.s.5.1UN1461II5.1A9, IB6, IP2, N34, T3, TP331522122425 kg25 kgA56, 58
Chloric acid aqueous solution, with not more than 10 percent chloric acid5.1UN2626II5.1IB2, T4, TP1None229NoneForbiddenForbiddenD56, 58
Chloride of phosphorus, see Phosphorus trichloride
Chloride of sulfur, see Sulfur chloride
Chlorinated lime, see Calcium hypochlorite mixtures, etc
Chlorine2.3UN10172.3, 82, B9, B14, T50, TP19None304314, 315ForbiddenForbiddenD40, 51, 55, 62, 68, 89, 90
Chlorine azideForbidden
DChlorine dioxide, hydrate, frozen5.1NA9191II5.1, 6.1None229NoneForbiddenForbiddenE
Chlorine dioxide (not hydrate)Forbidden
Chlorine pentafluoride2.3UN25482.3, 5.1, 81, B7, B9, B14None304314ForbiddenForbiddenD40, 89, 90
Chlorine trifluoride2.3UN17492.3, 5.1, 82, B7, B9, B14None304314ForbiddenForbiddenD40, 89, 90
Chlorite solution8UN1908II8A3, A6, A7, B2, IB2, N34, T7, TP2, TP241542022421 L30 LB26, 44, 89, 100, 141
III8A3, A6, A7, B2, IB3, N34, T4, TP2, TP241542032415 L60 LB26, 44, 89, 100, 141
Chlorites, inorganic, n.o.s.5.1UN1462II5.1A7, IB6, IP2, N34, T3, TP331522122425 kg25 kgA56, 58
1-Chloro-1,1-difluoroethane or Refrigerant gas R 142b2.1UN25172.1T50306304314, 315Forbidden150 kgB40
3-Chloro-4-methylphenyl isocyanate, liquid6.1UN2236II6.1IB21532022435 L60 LB40
3-Chloro-4-methylphenyl isocyanate, solid6.1UN3428II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB40
1-Chloro-1,2,2,2-tetrafluoroethane or Refrigerant gas R 1242.2UN10212.2T50306304314, 31575 kg150 kgA
4-Chloro-o-toluidine hydrochloride, solid6.1UN1579III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
4-Chloro-o-toluidine hydrochloride, solution6.1UN3410III6.1IB3, T4, TP115320324160 L220 LA
1-Chloro-2,2,2-trifluoroethane or Refrigerant gas R 133a2.2UN19832.2T50306304314, 31575 kg150 kgA
Chloroacetic acid, molten6.1UN3250II6.1, 8IB1, T7, TP3, TP28None202243ForbiddenForbiddenC40
Chloroacetic acid, solid6.1UN1751II6.1, 8A3, A7, IB8, IP4, N34, T3, TP3315321224215 kg50 kgA40
Chloroacetic acid, solution6.1UN1750II6.1, 8A7, IB2, N34, T7, TP21532022431 L30 LC40
Chloroacetone, stabilized6.1UN1695I6.1, 3, 82, B9, B14, B32, B74, N12, N32, N34, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD21, 40, 100
Chloroacetone (unstabilized)Forbidden
+Chloroacetonitrile6.1UN2668II6.1, 32, B9, B14, B32, B74, IB99, T20, TP2, TP38, TP45None227244ForbiddenForbiddenA12, 40, 52
Chloroacetophenone, liquid CN6.1UN3416II6.1A3, IB2, N12, N32, N33, T7, TP2, TP13None202243Forbidden60 LD12, 40
Chloroacetophenone, solid (CN)6.1UN1697II6.1A3, IB8, IP2, IP4, N12, N32, N33, N34, T3, TP33 TP2, TP13None212NoneForbidden100 kgD12, 40
Chloroacetyl chloride6.1UN1752I6.1, 82, B3, B8, B9, B14, B32, B74, B77, N34, N43, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Chloroanilines, liquid6.1UN2019II6.1IB2, T7, TP21532022435 L60 LA52
Chloroanilines, solid6.1UN2018II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Chloroanisidines6.1UN2233III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Chlorobenzene3UN1134III3B1, IB3, T2, TP115020324260 L220 LA
Chlorobenzol, see Chlorobenzene
Chlorobenzotrifluorides3UN2234III3B1, IB3, T2, TP115020324260 L220 LA40
Chlorobenzyl chlorides, liquid6.1UN2235III6.1IB3, T4, TP115320324160 L220 LA
Chlorobenzyl chlorides, solid6.1UN3427III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Chlorobutanes3UN1127II3IB2, T4, TP11502022425 L60 LB
Chlorocresols solution6.1UN2669II6.1IB2, T7, TP21532022435 L60 LA12
III6.1IB3, T7, TP215320324160 L220 LA12
Chlorocresols, solid6.1UN3437II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA12
Chlorodifluorobromomethane or Refrigerant gas R 12B12.2UN19742.2T50306304314, 31575 kg150 kgA
Chlorodifluoromethane and chloropentafluoroethane mixture or Refrigerant gas R 502 with fixed boiling point, with approximately 49 percent chlorodifluoromethane2.2UN19732.2T50306304314, 31575 kg150 kgA
Chlorodifluoromethane or Refrigerant gas R 222.2UN10182.2T50306304314, 31575 kg150 kgA
+Chlorodinitrobenzenes, liquid.6.1UN1577II6.1IB2, T7, TP21532022435 L60 LB91
Chlorodinitro-benzenes, solid6.1UN3441II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA91
2-Chloroethanal6.1UN2232I6.12, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Chloroform6.1UN1888III6.1IB3, N36, T7, TP215320324160 L220 LA40
GChloroformates, toxic, corrosive, flammable, n.o.s.6.1UN2742II6.1, 8, 35, IB1, T7, TP21532022431 L30 LA12, 13, 21, 25, 40, 100
GChloroformates, toxic, corrosive, n.o.s.6.1UN3277II6.1, 8IB2, T8, TP2, TP13, TP281532022431 L30 LA12, 13, 25, 40
Chloromethyl chloroformate6.1UN2745II6.1, 8IB2, T7, TP2, TP131532022431 L30 LA12, 13, 21, 25, 40, 100
Chloromethyl ethyl ether3UN2354II3, 6.1IB2, T7, TP1, TP131502022431 L60 LE40
Chloronitroanilines6.1UN2237III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
+Chloronitrobenzene, liquid ortho6.1UN3409II6.1IB2, T7, TP21532022435 L60 LA
+Chloronitrobenzenes, solid meta or para6.1UN1578II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Chloronitrotoluenes, liquid6.1UN2433III6.1IB3, T4, TP115320324160 L220 LA44, 89, 100, 141
Chloronitrotoluenes, solid6.1UN3457III6.1IB8, IP3,T1, TP3315321324025 kg200 kgA
Chloropentafluoroethane or Refrigerant gas R 1152.2UN10202.2T50306304314, 31575 kg150 kgA
Chlorophenolates, liquid or Phenolates, liquid8UN2904III8IB31542032415 L60 LA
Chlorophenolates, solid or Phenolates, solid8UN2905III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Chlorophenols, liquid6.1UN2021III6.1IB3, T4, TP115320324160 L220 LA
Chlorophenols, solid6.1UN2020III6.1IB8, IP3, T1, TP1, TP33153213240100 kg200 kgA
Chlorophenyltrichlorosilane8UN1753II8A7, B2, B6, IB2, N34, T7, TP2None202242Forbidden30 LC40
+Chloropicrin6.1UN1580I6.12, B7, B9, B14, B32, B46, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Chloropicrin and methyl bromide mixtures2.3UN15812.32, B9, B14, T50None193314, 315ForbiddenForbiddenD25, 40
Chloropicrin and methyl chloride mixtures2.3UN15822.32, T50None193245ForbiddenForbiddenD25, 40
Chloropicrin mixture, flammable (pressure not exceeding 14.7 psia at 115 degrees F flash point below 100 degrees F) see Toxic liquids, flammable, etc
Chloropicrin mixtures, n.o.s.6.1UN1583I6.15None201243ForbiddenForbiddenC40
II6.1IB2153202243ForbiddenForbiddenC40
III6.1IB3153203241ForbiddenForbiddenC40
DChloropivaloyl chloride6.1NA9263I6.1, 82, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45None227244ForbiddenForbiddenB40
Chloroplatinic acid, solid8UN2507III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Chloroprene, stabilized3UN1991I3, 6.1B57, T14, TP2, TP13None201243Forbidden30 LD40
Chloroprene, uninhibitedForbidden
1-Chloropropane3UN1278II3IB2, IP8, N34, T7, TP2None202242Forbidden60 LE
2-Chloropropane3UN2356I3N36, T11, TP2, TP131502012431 L30 LE
3-Chloropropanol-16.1UN2849III6.1IB3, T4, TP115320324160 L220 LA
2-Chloropropene3UN2456I3A3, N36, T11, TP21502012431 L30 LE
2-Chloropropionic acid8UN2511III8IB3, T4, TP21542032415 L60 LA8
2-Chloropyridine6.1UN2822II6.1IB2, T7, TP21532022435 L60 LA40
Chlorosilanes, corrosive, flammable, n.o.s.8UN2986II8, 3IB2, T11, TP2, TP27None2022431 L30 LC40
Chlorosilanes, corrosive, n.o.s.8UN2987II8B2, IB2, T14, TP2, TP271542022421 L30 LC40
Chlorosilanes, flammable, corrosive, n.o.s.3UN2985II3, 8IB1, T11, TP2, TP13, TP271502012431 L5 LB40
Chlorosilanes, toxic, corrosive, n.o.s.6.1UN3361II6.1, 8IB1, T11, TP2, TP131532022431 L30 LC40
Chlorosilanes, toxic, corrosive, flammable, n.o.s.6.1UN3362II6.1, 3, 8IB1, T11, TP2, TP131532022431 L30 LC40, 125
Chlorosilanes, water-reactive, flammable, corrosive, n.o.s.4.3UN2988I4.3, 3, 8A2, T10, TP2, TP7, TP13None201244Forbidden1 LD21, 28, 40, 49, 100
+Chlorosulfonic acid (with or without sulfur trioxide)8UN1754I8, 6.12, B9, B10, B14, B32, B74, T20, TP2, TP12, TP38, TP45None227244ForbiddenForbiddenC40
Chlorotoluenes3UN2238III3B1, IB3, T2, TP115020324260 L220 LA
Chlorotoluidines, liquid6.1UN3429III6.1IB3, T4, TP115320324160 L220 LA
Chlorotoluidines, solid6.1UN2239III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Chlorotrifluoromethane and trifluoromethane azeotropic mixture or Refrigerant gas R 503 with approximately 60 percent chlorotrifluoromethane2.2UN25992.2306304314, 31575 kg150 kgA
Chlorotrifluoromethane or Refrigerant gas R 132.2UN10222.2306304314, 31575 kg150 kgA
Chromic acid solution8UN1755II8B2, IB2, T8, TP2, TP121542022421 L30 LC40, 44, 89, 100, 141
III8IB3, T4, TP1, TP121542032415 L60 LC40, 44, 89, 100, 141
Chromic anhydride, see Chromium trioxide, anhydrous
Chromic fluoride, solid8UN1756II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA52
Chromic fluoride, solution8UN1757II8B2, IB2, T7, TP21542022421 L30 LA
III8IB3, T4, TP11542032415 L60 LA
Chromium nitrate5.1UN2720III5.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA
Chromium oxychloride8UN1758I8A3, A6, A7, B10, N34, T10, TP2, TP12None2012430.5 L2.5 LC40, 66, 74, 89, 90
Chromium trioxide, anhydrous5.1UN1463II5.1, 8IB8, IP4, T3, TP33None2122425 kg25 kgA
Chromosulfuric acid8UN2240I8A3, A6, A7, B4, B6, N34, T10, TP2, TP12, TP13None2012430.5 L2.5 LB40, 66, 74, 89, 90
Chromyl chloride, see Chromium oxychloride
Cigar and cigarette lighters, charged with fuel, see Lighters or Lighter refills containing flammable gas.
Coal briquettes, hotForbidden
Coal gas, compressed2.3UN10232.3, 2.13None302314, 315ForbiddenForbiddenD40
Coal tar distillates, flammable3UN1136II3IB2, T4, TP11502022425 L60 LB
III3B1, IB3, T4, TP1, TP2915020324260 L220 LA
Coal tar dye, corrosive, liquid, n.o.s, see Dyes, liquid or solid, n.o.s. or Dye intermediates, liquid or solid, corrosive, n.o.s.
Coating solution (includes surface treatments or coatings used for industrial or other purposes such as vehicle undercoating, drum or barrel lining)3UN1139I3T11, TP1, TP8, TP271502012431 L30 LE
II3149, IB2, T4, TP1, TP81502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Cobalt naphthenates, powder4.1UN2001III4.1A19, IB8, IP3, T1, TP3315121324025 kg100 kgA
Cobalt resinate, precipitated4.1UN1318III4.1A1, A19, IB6, T1, TP3315121324025 kg100 kgA
Coke, hotForbidden
Collodion, see Nitrocellulose etc
D GCombustible liquid, n.o.s.Comb liqNA1993IIINoneIB3, T1, T4, TP115020324160 L220 LA
GComponents, explosive train, n.o.s.1.2BUN0382II1.2B101None62NoneForbiddenForbidden11
GComponents, explosive train, n.o.s.1.4BUN0383II1.4B101None62NoneForbidden75 kg06
GComponents, explosive train, n.o.s.1.4SUN0384II1.4S101None62None25 kg100 kg05
GComponents, explosive train, n.o.s.1.1BUN0461II1.1B101None62NoneForbiddenForbidden11
Composition B, see Hexolite, etc
D GCompounds, cleaning liquid8NA1760I8A7, B10, T14, TP2, TP27None2012430.5 L2.5 LB40
II8B2, IB2, N37, T11, TP2, TP271542022421 L30 LB40
III8IB3, N37, T7, TP1, TP281542032415 L60 LA40
D GCompounds, cleaning liquid3NA1993I3T11, TP11502012431 L30 LE
II3IB2, T7, TP1, TP8, TP281502022425 L60 LB
III3B1, B52, IB3, T4, TP1, TP2915020324260 L220 LA
D GCompounds, tree killing, liquid or Compounds, weed killing, liquid8NA1760I8A7, B10, T14, TP2, TP27None2012430.5 L2.5 LB40
II8B2, IB2, N37, T11, TP2, TP271542022421 L30 LB40
III8IB3, N37, T7, TP1, TP281542032415 L60 LA40
D GCompounds, tree killing, liquid or Compounds, weed killing, liquid3NA1993I3T11, TP11502012431 L30 LE
II3IB2, T7, TP1, TP8, TP281502022425 L60 LB
III3B1, B52, IB3, T4, TP1, TP2915020324260 L220 LA
D GCompounds, tree killing, liquid or Compounds, weed killing, liquid6.1NA2810I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP271532022435 L60 LB40
III6.1IB3, T7, TP1, TP2815320324160 L220 LA40
GCompressed gas, flammable, n.o.s.2.1UN19542.1306302, 305314, 315Forbidden150 kgD40
GCompressed gas, n.o.s.2.2UN19562.2306, 307302, 305314, 31575 kg150 kgA
GCompressed gas, oxidizing, n.o.s.2.2UN31562.2, 5.1A14306302314, 31575 kg150 kgD
G ICompressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone A2.3UN33042.3, 81None192245ForbiddenForbiddenD40
G ICompressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone B2.3UN33042.3, 82, B9, B14None302, 305314, 315ForbiddenForbiddenD40
G ICompressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone C2.3UN33042.3, 83, B14None302, 305314, 315ForbiddenForbiddenD40
G ICompressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone D2.3UN33042.3, 84None302, 305314, 315ForbiddenForbiddenD40
G ICompressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone A2.3UN33052.3, 2.1, 81None192245ForbiddenForbiddenD17, 40
G ICompressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone B2.3UN33052.3, 2.1, 82, B9, B14None302, 305314, 315ForbiddenForbiddenD17, 40
G ICompressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone C2.3UN33052.3, 2.1, 83, B14None302, 305314, 315ForbiddenForbiddenD17, 40
G ICompressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone D2.3UN33052.3, 2.1, 84None302, 305314, 315ForbiddenForbiddenD17, 40
GCompressed gas, toxic, flammable, n.o.s. Inhalation hazard Zone A2.3UN19532.3, 2.11None192245ForbiddenForbiddenD40
GCompressed gas, toxic, flammable, n.o.s. Inhalation hazard Zone B2.3UN19532.3, 2.12, B9, B14None302, 305314, 315ForbiddenForbiddenD40
GCompressed gas, toxic, flammable, n.o.s. Inhalation Hazard Zone C2.3UN19532.3, 2.13, B14None302, 305314, 315ForbiddenForbiddenD40
GCompressed gas, toxic, flammable, n.o.s. Inhalation Hazard Zone D2.3UN19532.3, 2.14None302, 305314, 315ForbiddenForbiddenD40
GCompressed gas, toxic, n.o.s. Inhalation Hazard Zone A2.3UN19552.31None192245ForbiddenForbiddenD40
GCompressed gas, toxic, n.o.s. Inhalation Hazard Zone B2.3UN19552.32, B9, B14None302, 305314, 315ForbiddenForbiddenD40
GCompressed gas, toxic, n.o.s. Inhalation Hazard Zone C2.3UN19552.33, B14None302, 305314, 315ForbiddenForbiddenD40
GCompressed gas, toxic, n.o.s. Inhalation Hazard Zone D2.3UN19552.34None302, 305314, 315ForbiddenForbiddenD40
G ICompressed gas, toxic, oxdizing, corrosive, n.o.s. Inhalation Hazard Zone A2.3UN33062.3, 5.1, 81None192244ForbiddenForbiddenD40, 89, 90
G ICompressed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone B2.3UN33062.3, 5.1, 82, B9, B14None302, 305314, 315ForbiddenForbiddenD40, 89, 90
G ICompressed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone C2.3UN33062.3, 5.1, 83, B14None302, 305314, 315ForbiddenForbiddenD40, 89, 90
G ICompressed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone D2.3UN33062.3, 5.1, 84None302, 305314, 315ForbiddenForbiddenD40, 89, 90
GCompressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone A2.3UN33032.3, 5.11None192245ForbiddenForbiddenD40
GCompressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone B2.3UN33032.3, 5.12, B9, B14None302, 305314, 315ForbiddenForbiddenD40
GCompressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone C2.3UN33032.3, 5.13, B14None302, 305314, 315ForbiddenForbiddenD40
GCompressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone D2.3UN33032.3, 5.14None302, 305314, 315ForbiddenForbiddenD40
DConsumer commodityORM-DNone156, 306156, 306None30 kg gross30 kg grossA
Contrivances, water-activated, with burster, expelling charge or propelling charge1.2LUN0248II1.2L101None62NoneForbiddenForbidden088E, 14E, 15E, 17E
Contrivances, water-activated, with burster, expelling charge or propelling charge1.3LUN0249II1.3L101None62NoneForbiddenForbidden088E, 14E, 15E, 17E
Copper acetoarsenite6.1UN1585II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Copper acetylideForbidden
Copper amine azideForbidden
Copper arsenite6.1UN1586II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Copper based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C3UN2776I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LB40
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40
Copper based pesticides, liquid, toxic6.1UN3010I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1IB3, T7, TP2, TP2815320324160 L220 LA40
Copper based pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN3009I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3B1, IB3, T7, TP2, TP2815320324260 L220 LA40
Copper based pesticides, solid, toxic6.1UN2775I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Copper chlorate5.1UN2721II5.1A1, IB8, IP2, IP4, T3, TP331522122425 kg25 kgA56, 58
Copper chloride8UN2802III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Copper cyanide6.1UN1587II6.1IB8, IP2, IP4, T3, TP3315320424225 kg100 kgA52
Copper selenate, see Selenates or Selenites
Copper selenite, see Selenates or Selenites
Copper tetramine nitrateForbidden
A WCopra4.2UN1363III4.2IB8, IP3, IP7None213241ForbiddenForbiddenA13, 19, 48, 119
Cord, detonating, flexible1.1DUN0065II1.1D10263(a)62NoneForbiddenForbidden07
Cord, detonating, flexible1.4DUN0289II1.4DNone62NoneForbidden75 kg06
Cord detonating or Fuse detonating metal clad1.2DUN0102II1.2DNone62NoneForbiddenForbidden07
Cord, detonating or Fuse, detonating metal clad1.1DUN0290II1.1DNone62NoneForbiddenForbidden07
Cord, detonating, mild effect or Fuse, detonating, mild effect metal clad1.4DUN0104II1.4DNone62NoneForbidden75 kg06
Cord, igniter1.4GUN0066II1.4GNone62NoneForbidden75 kg06
Cordeau detonant fuse, see Cord, detonating, etc; Cord, detonating, flexible
Cordite, see Powder, smokeless
GCorrosive liquid, acidic, inorganic, n.o.s.8UN3264I8A6, B10, T14, TP2, TP27None2012430.5 L2.5 LB40
II8A6, B2, IB2, T11, TP2, TP271542022421 L30 LB40
III8IB3, T7, TP1, TP281542032415 L60 LA40
GCorrosive liquid, acidic, organic, n.o.s.8UN3265I8A6, B10, T14, TP2, TP27None2012430.5 L2.5 LB40
II8B2, IB2, T11, TP2, TP271542022421 L30 LB40
III8IB3, T7, TP1, TP281542032415 L60 LA40
GCorrosive liquid, basic, inorganic, n.o.s.8UN3266I8A6, T14, TP2, TP27None2012430.5 L2.5 LB40, 52
II8B2, IB2, T11, TP2, TP271542022421 L30 LB40, 52
III8IB3, T7, TP1, TP281542032415 L60 LA40, 52
GCorrosive liquid, basic, organic, n.o.s.8UN3267I8A6, B10, T14, TP2, TP27None2012430.5 L2.5 LB40, 52
II8B2, IB2, T11, TP2, TP271542022421 L30 LB40, 52
III8IB3, T7, TP1, TP281542032415 L60 LA40, 52
GCorrosive liquid, self-heating, n.o.s.8UN3301I8, 4.2A6, B10None2012430.5 L2.5 LD
II8, 4.2B2, IB11542022421 L30 LD
GCorrosive liquids, flammable, n.o.s.8UN2920I8, 3A6, B10, T14, TP2, TP27None2012430.5 L2.5 LC25, 40
II8, 3B2, IB2, T11, TP2, TP27None2022431 L30 LC25, 40
GCorrosive liquids, n.o.s.8UN1760I8A6, A7, B10, T14, TP2, TP27None2012430.5 L2.5 LB40
II8B2, IB2, T11, TP2, TP271542022421 L30 LB40
III8IB3, T7, TP1, TP281542032415 L60 LA40
GCorrosive liquids, oxidizing, n.o.s.8UN3093I8, 5.1A6, A7None201243Forbidden2.5 LC89
II8, 5.1A6, A7, IB2None2022431 L30 LC89
GCorrosive liquids, toxic, n.o.s.8UN2922I8, 6.1A7, A6, B10, T14, TP2, TP13, TP27None2012430.5 L2.5 LB40
II8, 6.1B3, IB2, T7, TP21542022431 L30 LB40
III8, 6.1IB3, T7, TP1, TP281542032415 L60 LB40
GCorrosive liquids, water-reactive, n.o.s.8UN3094I8, 4.3A6, A7None201243Forbidden1 LE
II8, 4.3A6, A7None2022431 L5 LE
GCorrosive solid, acidic, inorganic, n.o.s.8UN3260I8IB7, IP1, T6, TP33None2112421 kg25 kgB
II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgB
III8IB8, IP3, T1, TP3315421324025 kg100 kgA
GCorrosive solid, acidic, organic, n.o.s.8UN3261I8IB7, IP1, T6, TP33None2112421 kg25 kgB
II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgB
III8IB8, IP3, T1, TP3315421324025 kg100 kgA
GCorrosive solid, basic, inorganic, n.o.s.8UN3262I8IB7, IP1, T6, TP33None2112421 kg25 kgB52
II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgB52
III8IB8, IP3, T1, TP3315421324025 kg100 kgA52
GCorrosive solid, basic, organic, n.o.s.8UN3263I8IB7, IP1, T6, TP33None2112421 kg25 kgB52
II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgB52
III8IB8, IP3, T1, TP3315421324025 kg100 kgA52
GCorrosive solids, flammable, n.o.s.8UN2921I8, 4.1IB6, T6, TP33None2112421 kg25 kgB12, 25
II8, 4.1IB8, IP2, IP4, T3, TP33None21224215 kg50 kgB12, 25
GCorrosive solids, n.o.s.8UN1759I8IB7, IP1, T6, TP33None2112421 kg25 kgB
II8128, IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA
III8128, IB8, IP3, T1, TP3315421324025 kg100 kgA
GCorrosive solids, oxidizing, n.o.s.8UN3084I8, 5.1T6, TP33None2112421 kg25 kgC
II8, 5.1IB6, IP2, T3, TP33None21224215 kg50 kgC
GCorrosive solids, self-heating, n.o.s.8UN3095I8, 4.2T6, TP33None2112431 kg25 kgC
II8, 4.2IB6, IP2, T3, TP33None21224215 kg50 kgC
GCorrosive solids, toxic, n.o.s.8UN2923I8, 6.1IB7, T6, TP33None2112421 kg25 kgB40
II8, 6.1IB8, IP2, IP4, T3, TP3315421224015 kg50 kgB40
III8, 6.1IB8, IP3, T1, TP3315421324025 kg100 kgB40, 95
GCorrosive solids, water-reactive, n.o.s.8UN3096I8, 4.3IB4, IP1, T6, TP33None2112431 kg25 kgD
II8, 4.3IB6, IP2, T3, TP33None21224215 kg50 kgD
D WCotton9NA13659137, IB8, IP2, IP4, W41NoneNoneNoneNo limitNo limitA
A WCotton waste, oily4.2UN1364III4.2IB8, IP3, IP7None213NoneForbiddenForbiddenA54
A I WCotton, wet4.2UN1365III4.2IB8, IP3, IP7None204241ForbiddenForbiddenA
Coumarin derivative pesticides, liquid, flammable, toxic, flash point less than 23 degrees C3UN3024I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LB40
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40
Coumarin derivative pesticides, liquid, toxic6.1UN3026I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP271532022435 L60 LB40
III6.1IB3, T7, TP1, TP2815320324160 L220 LA40
Coumarin derivative pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN3025I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3B1, IB3, T7, TP1, TP2815320324260 L220 LA40
Coumarin derivative pesticides, solid, toxic6.1UN3027I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Cresols, liquid6.1UN2076II6.1, 8IB2, IP2, IP4, T7, TP21532022431 L30 LB
Cresols, solid6.1UN3455II6.1, 8IB8, IP2, IP4, T3, TP3315321224215 kg50 kgB
Cresylic acid6.1UN2022II6.1, 8IB2, T7, TP2, TP131532022431 L30 LB
Crotonaldehyde, stabilized6.1UN1143I6.1, 32, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenB40
Crotonic acid liquid8UN2823III8IB8, T11542032415 L60 LA12
Crotonic acid, solid8UN2823III8IB8, IP3, T1, TP3315421324025 kg100 kgA12
Crotonylene3UN1144I3T11, TP21502012431 L30 LE
Cupriethylenediamine solution8UN1761II8, 6.1IB2, T7, TP21542022431 L30 LA
III8, 6.1IB3, T7, TP1, TP281542032425 L60 LA95
Cutters, cable, explosive1.4SUN0070II1.4SNone62None25 kg100 kg05
Cyanide or cyanide mixtures, dry, see Cyanides, inorganic, solid, n.o.s.
Cyanide solutions, n.o.s.6.1UN1935I6.1B37, T14, TP2, TP13, TP27None2012431 L30 LB40, 52
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LA40, 52
III6.1IB3, T7, TP2, TP13, TP2815320324160 L220 LA40, 52
Cyanides, inorganic, solid, n.o.s.6.1UN1588I6.1IB7, IP1, N74, N75, T6, TP33None2112425 kg50 kgA52
II6.1IB8, IP2, IP4, N74, N75, T3, TP3315321224225 kg100 kgA52
III6.1IB8, IP3, N74, N75, T1, TP33153213240100 kg200 kgA52
Cyanogen2.3UN10262.3, 2.12None304245ForbiddenForbiddenD40
Cyanogen bromide6.1UN1889I6.1, 8A6, A8, T6, TP33None2112421 kg15 kgD40
Cyanogen chloride, stabilized2.3UN15892.3, 81None192245ForbiddenForbiddenD40
Cyanuric chloride8UN2670II8IB8, IP2, IP4, T3, TP33None21224015 kg50 kgA12, 40
Cyanuric triazideForbidden
Cyclobutane2.1UN26012.1306304314, 315Forbidden150 kgB40
Cyclobutyl chloroformate6.1UN2744II6.1, 8, 3IB1, T7, TP2, TP131532022431 L30 LA12, 13, 21, 25, 40, 100
1,5,9-Cyclododecatriene6.1UN2518III6.1IB3, T4, TP115320324160 L220 LA40
Cycloheptane3UN2241II3IB2, T4, TP11502022425 L60 LB40
Cycloheptatriene3UN2603II3, 6.1IB2, T7, TP1, TP131502022431 L60 LE40
Cycloheptene3UN2242II3B1, IB2, T4, TP11502022425 L60 LB
Cyclohexane3UN1145II3IB2, T4, TP11502022425 L60 LE
Cyclohexanone3UN1915III3B1, IB3, T2, TP115020324260 L220 LA
Cyclohexene3UN2256II3IB2, T4, TP11502022425 L60 LE
Cyclohexenyltrichlorosilane8UN1762II8A7, B2, IB2, N34, T7, TP2, TP13None202242Forbidden30 LC40
Cyclohexyl acetate3UN2243III3B1, IB3, T2, TP115020324260 L220 LA
Cyclohexyl isocyanate6.1UN2488I6.1, 32, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Cyclohexyl mercaptan3UN3054III3B1, IB3, T2, TP115020324260 L220 LA40, 95
Cyclohexylamine8UN2357II8, 3IB2, T7, TP2None2022431 L30 LA40
Cyclohexyltrichlorosilane8UN1763II8A7, B2, IB2, N34, T7, TP2, TP13None202242Forbidden30 LC40
Cyclonite and cyclotetramethylenetetranitramine mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc
Cyclonite and HMX mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc
Cyclonite and octogen mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc
Cyclonite, see Cyclotrimethylenetrinitramine, etc
Cyclooctadiene phosphines, see 9-Phosphabicyclononanes
Cyclooctadienes3UN2520III3B1, IB3, T2, TP115020324260 L220 LA
Cyclooctatetraene3UN2358II3IB2, T4, TP11502022425 L60 LB
Cyclopentane3UN1146II3IB2, T7, TP11502022425 L60 LE
Cyclopentane, methyl, see Methylcyclopentane
Cyclopentanol3UN2244III3B1, IB3, T2, TP115020324260 L220 LA
Cyclopentanone3UN2245III3B1, IB3, T2, TP115020324260 L220 LA
Cyclopentene3UN2246II3IB2, IP8, T7, TP21502022425 L60 LE
Cyclopropane2.1UN10272.1T50306304314, 315Forbidden150 kgE40
Cyclotetramethylene tetranitramine (dry or unphlegmatized) (HMX)Forbidden
Cyclotetramethylenetetranitramine, desensitized or Octogen, desensitized or HMX, desensitized1.1DUN0484II1.1DNone62NoneForbiddenForbidden10
Cyclotetramethylenetetranitramine, wetted or HMX, wetted or Octogen, wetted with not less than 15 percent water, by mass1.1DUN0226II1.1DNone62NoneForbiddenForbidden10
Cyclotrimethylenetrinitramine and cyclotetramethylenetetranitramine mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc
Cyclotrimethylenenitramine and octogen, mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc
Cyclotrimethylenetrinitramine and HMX mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc
Cyclotrimethylenetrinitramine, desensitized or Cyclonite, desensitized or Hexogen, desensitized or RDX, desensitized1.1DUN0483II1.1DNone62NoneForbiddenForbidden10
Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted or Hexogen, wetted or RDX, wetted with not less than 15 percent water by mass1.1DUN0072II1.1DNone62NoneForbiddenForbidden10
Cymenes3UN2046III3B1, IB3, T2, TP115020324260 L220 LA
Dangerous Goods in Machinery or Dangerous Goods in Apparatus9UN3363136None222NoneNo limitNo limitA
Decaborane4.1UN1868II4.1, 6.1A19, A20, IB6, IP2, T3, TP33None212NoneForbidden50 kgA74
Decahydronaphthalene3UN1147III3B1, IB3, T2, TP115020324260 L220 LA
n-Decane3UN2247III3B1, IB3, T2, TP115020324260 L220 LA
Deflagrating metal salts of aromatic nitroderivatives, n.o.s.1.3CUN0132II1.3CNone62NoneForbiddenForbidden105E
Delay electric igniter, see Igniters
Depth charges, see Charges, depth
GDesensitized explosive, liquid, n.o.s.3UN3379I3164None201NoneForbiddenForbiddenD36
GDesensitized explosive, solid, n.o.s.4.1UN3380I4.1164None211NoneForbiddenForbiddenD28, 36
Detonating relays, see Detonators, etc
Detonator assemblies, non-electric for blasting1.1BUN0360II1.1BNone62NoneForbiddenForbidden11
Detonator assemblies, non-electric, for blasting1.4BUN0361II1.4B10363(f), 63(g)62NoneForbidden75 kg06
Detonator, assemblies, non-electric for blasting1.4SUN0500II1.4S63(f), 63(g)62None25 kg100 kg05
Detonators, electric, for blasting1.1BUN0030II1.1B63(f), 63(g)62NoneForbiddenForbidden11
Detonators, electric, for blasting1.4BUN0255II1.4B10363(f), 63(g)62NoneForbidden75 kg06
Detonators, electric for blasting1.4SUN0456II1.4S63(f), 63(g)62None25 kg100 kg05
Detonators for ammunition1.1BUN0073II1.1BNone62NoneForbiddenForbidden11
Detonators for ammunition1.2BUN0364II1.2BNone62NoneForbiddenForbidden11
Detonators for ammunition1.4BUN0365II1.4B103None62NoneForbidden75 kg06
Detonators for ammunition1.4SUN0366II1.4SNone62None25 kg100 kg05
Detonators, non-electric, for blasting1.1BUN0029II1.1BNone62NoneForbiddenForbidden11
Detonators, non-electric, for blasting1.4BUN0267II1.4B10363(f), 63(g)62NoneForbidden75 kg06
Detonators, non-electric, for blasting1.4SUN0455II1.4S63(f), 63(g)62None25 kg100 kg5
Deuterium, compressed2.1UN19572.1306302NoneForbidden150 kgE40
Devices, small, hydrocarbon gas powered or Hydrocarbon gas refills for small devices with release device2.1UN31502.1306304None1 kg15 kgB40
Di-n-amylamine3UN2841III3, 6.1B1, IB3, T4, TP115020324260 L220 LA
Di-n-butyl peroxydicarbonate, with more than 52 percent in solutionForbidden
Di-n-butylamine8UN2248II8, 3IB2, T7, TP2None2022431 L30 LA
2,2-Di-(tert-butylperoxy) butane, with more than 55 percent in solutionForbidden
Di-(tert-butylperoxy) phthalate, with more than 55 percent in solutionForbidden
2,2-Di-(4,4-di-tert-butylperoxycyclohexyl) propane, with more than 42 percent with inert solidForbidden
Di-2,4-dichlorobenzoyl peroxide, with more than 75 percent with waterForbidden
1,2-Di-(dimethylamino)ethane3UN2372II3IB2, T4, TP11502022425 L60 LB
Di-2-ethylhexyl phosphoric acid, see Diisooctyl acid phosphate
Di-(1-hydroxytetrazole) (dry)Forbidden
Di-(1-naphthoyl) peroxideForbidden
a,a'-Di-(nitroxy) methyletherForbidden
Di-(beta-nitroxyethyl) ammonium nitrateForbidden
Diacetone alcohol3UN1148II3IB2, T4, TP11502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Diacetone alcohol peroxides, with more than 57 percent in solution with more than 9 percent hydrogen peroxide, less than 26 percent diacetone alcohol and less than 9 percent water; total active oxygen content more than 9 percent by massForbidden
Diacetyl, see Butanedione
Diacetyl peroxide, solid, or with more than 25 percent in solutionForbidden
Diagnostic specimen6.2A82134199None4 L or 4 kg4 L or 4 kgA40
Diallylamine3UN2359II3, 6.1, 8IB2, T7, TP11502022431 L5 LB21, 40, 100
Diallylether3UN2360II3, 6.1IB2, N12, T7, TP1, TP131502022431 L60 LE40
4,4'-Diaminodiphenyl methane6.1UN2651III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
p-DiazidobenzeneForbidden
1,2-DiazidoethaneForbidden
1,1'-DiazoaminonaphthaleneForbidden
Diazoaminotetrazole (dry)Forbidden
Diazodinitrophenol (dry)Forbidden
Diazodinitrophenol, wetted with not less than 40 percent water or mixture of alcohol and water, by mass1.1AUN0074II1.1A111, 117None62NoneForbiddenForbidden12
DiazodiphenylmethaneForbidden
Diazonium nitrates (dry)Forbidden
Diazonium perchlorates (dry)Forbidden
1,3-DiazopropaneForbidden
Dibenzyl peroxydicarbonate, with more than 87 percent with waterForbidden
Dibenzyldichlorosilane8UN2434II8B2, IB2, T7, TP2, TP131542022421 L30 LC40
Diborane2.3UN19112.3, 2.11None302NoneForbiddenForbiddenD40, 57
DDiborane mixtures2.1NA19112.15None302245ForbiddenForbiddenD40, 57
DibromoacetyleneForbidden
1,2-Dibromobutan-3-one6.1UN2648II6.1IB21532022435 L60 LB40
Dibromochloropropane6.1UN2872II6.1IB2, T7, TP21532022435 L60 LA
III6.1IB3, T4, TP115320324160 L220 LA
ADibromodifluoromethane , R12B29UN1941IIINoneT11, TP2155203241100 L220 LA25
1,2-Dibromoethane, see Ethylene dibromide
Dibromomethane6.1UN2664III6.1IB3, T4, TP115320324160 L220 LA
Dibutyl ethers3UN1149III3B1, IB3, T2, TP115020324260 L220 LA
Dibutylaminoethanol6.1UN2873III6.1IB3, T4, TP115320324160 L220 LA
N,N'-Dichlorazodicarbonamidine (salts of) (dry)Forbidden
1,1-Dichloro-1-nitroethane6.1UN2650II6.1IB2, T7, TP21532022435 L60 LA12, 40, 74
D3,5-Dichloro-2,4,6-trifluoropyridine6.1NA9264I6.12, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45None227244ForbiddenForbiddenA40
Dichloroacetic acid8UN1764II8A3, A6, A7, B2, IB2, N34, T8, TP2, TP121542022421 L30 LA
1,3-Dichloroacetone6.1UN2649II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB12, 40
Dichloroacetyl chloride8UN1765II8A3, A6, A7, B2, B6, IB2, N34, T7, TP21542022421 L30 LD40
DichloroacetyleneForbidden
+Dichloroanilines, liquid6.1UN1590II6.1IB2, T7, TP21532022435 L60 LA40
Dichloroanilines, solid6.1UN3442II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
+o-Dichlorobenzene6.1UN1591III6.1IB3, T4, TP115320324160 L220 LA
2,2'-Dichlorodiethyl ether6.1UN1916II6.1, 3IB2, N33, N34, T7, TP21532022435 L60 LA
Dichlorodifluoromethane and difluoroethane azeotropic mixture or Refrigerant gas R 500 with approximately 74 percent dichlorodifluoromethane2.2UN26022.2T50306304314, 31575 kg150 kgA
Dichlorodifluoromethane or Refrigerant gas R 122.2UN10282.2T50306304314, 31575 kg150 kgA
Dichlorodimethyl ether, symmetrical6.1UN2249I6.1, 3None201243ForbiddenForbidden40
1,1-Dichloroethane3UN2362II3IB2, T4, TP11502022425 L60 LB40
1,2-Dichloroethane, see Ethylene dichloride
Dichloroethyl sulfideForbidden
1,2-Dichloroethylene3UN1150II3IB2, T7, TP21502022425 L60 LB
Dichlorofluoromethane or Refrigerant gas R212.2UN10292.2T50306304314, 31575 kg150 kgA
Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts5.1UN2465II5.128, IB8, IP4, T3, TP331522122405 kg25 kgA13
Dichloroisopropyl ether6.1UN2490II6.1IB2, T7, TP21532022435 L60 LB
Dichloromethane6.1UN1593III6.1IB3, IP8, N36, T7, TP215320324160 L220 LA
Dichloropentanes3UN1152III3B1, IB3, T2, TP115020324260 L220 LA
Dichlorophenyl isocyanates6.1UN2250II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB25, 40, 48
Dichlorophenyltrichlorosilane8UN1766II8A7, B2, B6, IB2, N34, T7, TP2, TP13None202242Forbidden30 LC40
1,2-Dichloropropane3UN1279II3IB2, N36, T4, TP11502022425 L60 LB
1,3-Dichloropropanol-26.1UN2750II6.1IB2, T7, TP21532022435 L60 LA12, 40
Dichloropropene and propylene dichloride mixture, see 1,2- Dichloropropane
Dichloropropenes3UN2047II3IB2, T4, TP11502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Dichlorosilane2.3UN21892.3, 2.1, 82, B9, B14None304314, 315ForbiddenForbiddenD17, 40
1,2-Dichloro-1,1,2,2- tetrafluoroethane or Refrigerant gas R 1142.2UN19582.2T50306304314, 31575 kg150 kgA
DichlorovinylchloroarsineForbidden
Dicycloheptadiene, see Bicyclo [2,2,1] hepta-2,5-diene, stabilized
Dicyclohexylamine8UN2565III8IB3, T4, TP11542032415 L60 LA
Dicyclohexylammonium nitrite4.1UN2687III4.1IB8, IP3, T1, TP3315121324025 kg100 kgA48
Dicyclopentadiene3UN2048III3B1, IB3, T2, TP115020324260 L220 LA
Didymium nitrate5.1UN1465III5.1A1, IB8, IP3, T1, TP3315221324025 kg100 kgA
DDiesel fuel3NA1993IIINone144, B1, IB3, T4, TP1, TP2915020324260 L220 LA
IDiesel fuel3UN1202III3144, B1, IB3, T2, TP115020324260 L220 LA
Diethanol nitrosamine dinitrate (dry)Forbidden
Diethoxymethane3UN2373II3IB2, T4, TP11502022425 L60 LE
3,3-Diethoxypropene3UN2374II3IB2, T4, TP11502022425 L60 LB
Diethyl carbonate3UN2366III3B1, IB3, T2, TP115020324260 L220 LA
Diethyl cellosolve, see Ethylene glycol diethyl ether
Diethyl ether or Ethyl ether3UN1155I3T11, TP21502012431 L30 LE40
Diethyl ketone3UN1156II3IB2, T4, TP11502022425 L60 LB
Diethyl peroxydicarbonate, with more than 27 percent in solutionForbidden
Diethyl sulfate6.1UN1594II6.1IB2, T7, TP21532022435 L60 LC
Diethyl sulfide3UN2375II3IB2, T7, TP1, TP13None2022435 L60 LE
Diethylamine3UN1154II3, 8A3, IB2, N34, T7, TP11502022431 L5 LE40
2-Diethylaminoethanol8UN2686II8, 3B2, IB2, T7, TP2None2022431 L30 LA
3-Diethyamino-propylamine.3UN2684III3, 8B1, IB3, T4, TP11502032425 L60 LA
+N, N-Diethylaniline6.1UN2432III6.1IB3, T4, TP115320324160 L220 LA
Diethylbenzene3UN2049III3B1, IB3, T2, TP115020324260 L220 LA
Diethyldichlorosilane8UN1767II8, 3A7, B6, IB2, N34, T7, TP2, TP13None202243Forbidden30 LC40
Diethylene glycol dinitrateForbidden
Diethyleneglycol dinitrate, desensitized with not less than 25 percent non-volatile water-insoluble phlegmatizer, by mass1.1DUN0075II1.1DNone62NoneForbiddenForbidden1321E
Diethylenetriamine8UN2079II8B2, IB2, T7, TP21542022421 L30 LA40, 52
N,N-Diethylethylenediamine8UN2685II8, 3IB2, T7, TP2None2022431 L30 LA
Diethylgold bromideForbidden
Diethylthiophosphoryl chloride8UN2751II8B2, IB2, T7, TP2None21224015 kg50 kgD12, 40
Diethylzinc4.2UN1366I4.2, 4.3B11, T21, TP2, TP7None181244ForbiddenForbiddenD18
Difluorochloroethanes, see 1-Chloro-1,1-difluoroethanes
1,1-Difluoroethane or Refrigerant gas R 152a2.1UN10302.1T50306304314, 315Forbidden150 kgB40
1,1-Difluoroethylene or Refrigerant gas R 1132a2.1UN19592.1306304NoneForbidden150 kgE40
Difluoromethane or Refrigerant gas R 322.1UN32522.1T50306302314, 315Forbidden150 kgD40
Difluorophosphoric acid, anhydrous8UN1768II8A6, A7, B2, IB2, N5, N34, T8, TP2, TP12None2022421 L30 LA40
2,3-Dihydropyran3UN2376II3IB2, T4, TP11502022425 L60 LB
1,8-Dihydroxy-2,4,5,7-tetranitroanthraquinone (chrysamminic acid)Forbidden
DiiodoacetyleneForbidden
Diisobutyl ketone3UN1157III3B1, IB3, T2, TP115020324260 L220 LA
Diisobutylamine3UN2361III3, 8B1, IB3, T4, TP11502032425 L60 LA
Diisobutylene, isomeric compounds3UN2050II3IB2, T4, TP11502022425 L60 LB
Diisooctyl acid phosphate8UN1902III8IB3, T4, TP11542032415 L60 LA
Diisopropyl ether3UN1159II3IB2, T4, TP11502022425 L60 LE40
Diisopropylamine3UN1158II3, 8IB2, T7, TP11502022431 L5 LB
Diisopropylbenzene hydroperoxide, with more than 72 percent in solutionForbidden
Diketene, stabilized6.1UN2521I6.1, 32, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD26, 27, 40
1,2-Dimethoxyethane3UN2252II3IB2, T4, TP11502022425 L60 LB
1,1-Dimethoxyethane3UN2377II3IB2, T7, TP11502022425 L60 LB
Dimethyl carbonate3UN1161II3IB2, T4, TP11502022425 L60 LB
Dimethyl chlorothiophosphate, see Dimethyl thiophosphoryl chloride
2,5-Dimethyl-2,5-dihydroperoxy hexane, with more than 82 percent with waterForbidden
Dimethyl disulfide3UN2381II3IB2, T4, TP11502022425 L60 LB40
Dimethyl ether2.1UN10332.1T50306304314, 315Forbidden150 kgB40
Dimethyl-N-propylamine3UN2266II3, 8IB2, T7, TP2, TP131502022431 L5 LB40
Dimethyl sulfate6.1UN1595I6.1, 82, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Dimethyl sulfide3UN1164II3IB2, IP8, T7, TP21502022425 L60 LE40
Dimethyl thiophosphoryl chloride6.1UN2267II6.1, 8IB2, T7, TP21532022431 L30 LB25
Dimethylamine, anhydrous2.1UN10322.1T50None304314, 315Forbidden150 kgD40
Dimethylamine solution3UN1160II3, 8IB2, T7, TP11502022431 L5 LB
2-Dimethylaminoacetonitrile3UN2378II3, 6.1IB2, T7, TP11502022431 L60 LA52, 40
2-Dimethylaminoethanol8UN2051II8, 3B2, IB2, T7, TP21542022431 L30 LA
2-Dimethylaminoethyl acrylate6.1UN3302II6.1IB2, T7, TP21532022435 L60 LD25
2-Dimethylaminoethyl methacrylate6.1UN2522II6.1IB2, T7, TP21532022435 L60 LB40
N,N-Dimethylaniline6.1UN2253II6.1IB1, T7, TP21532022435 L60 LA
2,3-Dimethylbutane3UN2457II3IB2, T7, TP11502022425 L60 LE
1,3-Dimethylbutylamine3UN2379II3, 8IB2, T7, TP11502022431 L5 LB
Dimethylcarbamoyl chloride8UN2262II8B2, IB2, T7, TP21542022421 L30 LA40
Dimethylcyclohexanes3UN2263II3IB2, T4, TP11502022425 L60 LB
N,N-Dimethylcyclohexylamine8UN2264II8, 3B2, IB2, T7, TP21542022431 L30 LA40
Dimethyldichlorosilane3UN1162II3, 8B77, IB2, T7, TP2, TP13None202243ForbiddenForbiddenB40
Dimethyldiethoxysilane3UN2380II3IB2, T4, TP11502022425 L60 LB
Dimethyldioxanes3UN2707II3IB2, T4, TP11502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
N,N-Dimethylformamide3UN2265III3B1, IB3, T2, TP215020324260 L220 LA
Dimethylhexane dihydroperoxide (dry)Forbidden
Dimethylhydrazine, symmetrical6.1UN2382I6.1, 32, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40, 74
Dimethylhydrazine, unsymmetrical6.1UN1163I6.1, 3, 82, B7, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD21, 38, 40, 100
2,2-Dimethylpropane2.1UN20442.1306304314, 315Forbidden150 kgE40
Dimethylzinc4.2UN1370I4.2, 4.3B11, B16, T21, TP2, TP7None181244ForbiddenForbiddenD18
Dinitro-o-cresol6.1UN1598II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
1,3-Dinitro-5,5-dimethyl hydantoinForbidden
Dinitro-7,8-dimethylglycoluril (dry)Forbidden
1,3-Dinitro-4,5-dinitrosobenzeneForbidden
1,4-Dinitro-1,1,4,4-tetramethylolbutanetetranitrate (dry)Forbidden
2,4-Dinitro-1,3,5-trimethylbenzeneForbidden
Dinitroanilines6.1UN1596II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA91
Dinitrobenzenes, liquid6.1UN1597II6.111, IB2, T7, TP21532022435 L60 LA91
III6.111, IB3, T7, TP215320324160 L220 LA91
Dinitrobenzenes, solid6.1UN3443II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA91
Dinitrochlorobenzene, see Chlorodinitrobenzene
1,2-DinitroethaneForbidden
1,1-Dinitroethane (dry)Forbidden
Dinitrogen tetroxide2.3UN10672.3, 5.1, 81, B7, B14, B45, B46, B61, B66, B67, B77, T50, TP21None336314ForbiddenForbiddenD40, 89, 90
Dinitroglycoluril or Dingu1.1DUN0489II1.1DNone62NoneForbiddenForbidden10
DinitromethaneForbidden
Dinitrophenol, dry or wetted with less than 15 percent water, by mass1.1DUN0076II1.1D, 6.1None62NoneForbiddenForbidden105E
Dinitrophenol solutions6.1UN1599II6.1IB2, T7, TP21532022435 L60 LA36
III6.1IB3, T4, TP115320324160 L220 LA36
Dinitrophenol, wetted with not less than 15 percent water, by mass4.1UN1320I4.1, 6.123, A8, A19, A20, N41None211None1 kg15 kgE28, 36
Dinitrophenolates alkali metals, dry or wetted with less than 15 percent water, by mass1.3CUN0077II1.3C, 6.1None62NoneForbiddenForbidden105E
Dinitrophenolates, wetted with not less than 15 percent water, by mass4.1UN1321I4.1, 6.123, A8, A19, A20, N41None211None1 kg15 kgE28, 36
Dinitropropylene glycolForbidden
Dinitroresorcinol, dry or wetted with less than 15 percent water, by mass1.1DUN0078II1.1DNone62NoneForbiddenForbidden105E
2,4-Dinitroresorcinol (heavy metal salts of) (dry)Forbidden
4,6-Dinitroresorcinol (heavy metal salts of) (dry)Forbidden
Dinitroresorcinol, wetted with not less than 15 percent water, by mass4.1UN1322I4.123, A8, A19, A20, N41None211None1 kg15 kgE28, 36
3,5-Dinitrosalicylic acid (lead salt) (dry)Forbidden
Dinitrosobenzene1.3CUN0406II1.3CNone62NoneForbiddenForbidden10
Dinitrosobenzylamidine and salts of (dry)Forbidden
2,2-DinitrostilbeneForbidden
Dinitrotoluenes, liquid6.1UN2038II6.1IB2, T7, TP21532022435 L60 LA
Dinitrotoluenes, solid6.1UN3454II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Dinitrotoluenes, molten6.1UN1600II6.1T7, TP3None202243ForbiddenForbiddenC
1,9-Dinitroxy pentamethylene-2,4, 6,8-tetramine (dry)Forbidden
Dioxane3UN1165II3IB2, T4, TP11502022425 L60 LB
Dioxolane3UN1166II3IB2, T4, TP11502022425 L60 LB40
Dipentene3UN2052III3B1, IB3, T2, TP115020324260 L220 LA
Diphenylamine chloroarsine6.1UN1698I6.1T6, TP33None201NoneForbiddenForbiddenD40
Diphenylchloroarsine, liquid6.1UN1699I6.1A8, B14, B32, N33, N34, T14, TP2, TP13, TP27None201243Forbidden30 LD40
Diphenyl-chloroarsine, solid6.1UN3450I6.1IB7, IP1, T6, TP33None2112425 kg50 kgD40
Diphenyldichlorosilane8UN1769II8A7, B2, IB2, N34, T7, TP2, TP13None202242Forbidden30 LC40
Diphenylmethyl bromide8UN1770II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgD40
Dipicryl sulfide, dry or wetted with less than 10 percent water, by mass1.1DUN0401II1.1DNone62NoneForbiddenForbidden10
Dipicryl sulfide, wetted with not less than 10 percent water, by mass4.1UN2852I4.1162, A2, N41, N84None211NoneForbidden0.5 kgD28
Dipicrylamine, see Hexanitrodiphenylamine
Dipropionyl peroxide, with more than 28 percent in solutionForbidden
Di-n-propyl ether3UN2384II3IB2, T4, TP11502022425 L60 LB
Dipropyl ketone3UN2710III3B1, IB3, T2, TP115020324260 L220 LA
Dipropylamine3UN2383II3, 8IB2, T7, TP11502022431 L5 LB
GDisinfectant, liquid, corrosive, n.o.s.8UN1903I8A6, A7, B10, T14, TP2, TP27None2012430.5 L2.5 LB
GDisinfectants, liquid, corrosive n.o.s.8UN1903II8B2, IB2, T7, TP21542022421 L30 LB
III8IB3, T4, TP11542032415 L60 LA
GDisinfectants, liquid, toxic, n.o.s.6.1UN3142I6.1A4, T14, TP2, TP27None2012431 L30 LA40
II6.1IB2, T11, TP2, TP271532022435 L60 LA40
III6.1IB3, T7, TP1, TP2815320324160 L220 LA40
GDisinfectants, solid, toxic, n.o.s.6.1UN1601I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Disodium trioxosilicate8UN3253III8IB8, IP3, T1, TP3315421324025 kg100 kgA
GDispersant gases, n.o.s. see Refrigerant gases, n.o.s.
Divinyl ether, stabilized3UN1167I3A7, T11, TP2None2012431 L30 LE40
Dodecyltrichlorosilane8UN1771II8A7, B2, B6, IB2, N34, T7, TP2, TP13None202242Forbidden30 LC40
Dry ice, see Carbon dioxide, solid
GDyes, liquid, corrosive, n.o.s. or Dye intermediates, liquid, corrosive, n.o.s.8UN2801I811, A6, B10, T14, TP2, TP27None2012430.5 L2.5 LA
II811, B2, IB2, T11, TP2, TP271542022421 L30 LA
III811, IB3, T7, TP1, TP281542032415 L60 LA
GDyes, liquid, toxic, n.o.s. or Dye intermediates, liquid, toxic, n.o.s.6.1UN1602I6.1None2012431 L30 LA
II6.1IB21532022435 L60 LA
III6.1IB315320324160 L220 LA
GDyes, solid, corrosive, n.o.s. or Dye intermediates, solid, corrosive, n.o.s.8UN3147I8IB7, IP1, T6, TP33None2112421 kg25 kgA
II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA
III8IB8, IP3, T1, TP3315421324025 kg100 kgA
GDyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s.6.1UN3143I6.1A5, IB7, IP1, T6, TP33None2112425 kg50 kgA
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Dynamite, see Explosive, blasting, type A
Electrolyte (acid or alkali) for batteries, see Battery fluid, acid or Battery fluid, alkali
Elevated temperature liquid, flammable, n.o.s., with flash point above 37.8 C, at or above its flash point3UN3256III3IB1, T3, TP3, TP29NoneNone247ForbiddenForbiddenA
Elevated temperature liquid, n.o.s., at or above 100 C and below its flash point (including molten metals, molten salts, etc.)9UN3257III9IB1, T3, TP3, TP29NoneNone247ForbiddenForbiddenA85
Elevated temperature solid, n.o.s., at or above 240 C, see § 173.247(h)(4)9UN3258III9247(h) (4)None247ForbiddenForbiddenA85
Engines, internal combustion, flammable gas powered9UN31669135220220220ForbiddenNo limitA
Engines, internal combustion, flammable liquid powered9UN31669135220220220No limitNo limitA
GEnvironmentally hazardous substances, liquid, n.o.s.9UN3082III98, 146, IB3, T4, TP1, TP29155203241No limitNo limitA
GEnvironmentally hazardous substances, solid, n.o.s.9UN3077III98, 146, B54, IB8, IP3, N20, T1, TP33155213240No limitNo limitA
Epibromohydrin6.1UN2558I6.1, 3T14, TP2, TP13None201243ForbiddenForbiddenD40
+Epichlorohydrin6.1UN2023II6.1, 3IB2, T7, TP2, TP131532022435 L60 LA40
1,2-Epoxy-3-ethoxypropane3UN2752III3B1, IB3, T2, TP115020324260 L220 LA
Esters, n.o.s.3UN3272II3IB2, T7, TP1, TP8, TP281502022425 L60 LB
III3B1, IB3, T4, TP1, TP2915020324260 L220 LA
Etching acid, liquid, n.o.s., see Hydrofluoric acid, solution etc
Ethane2.1UN10352.1306304302Forbidden150 kgE40
DEthane-Propane mixture, refrigerated liquid2.1NA19612.1T75, TP5None316314, 315ForbiddenForbiddenD40
Ethane, refrigerated liquid2.1UN19612.1T75, TP5NoneNone315ForbiddenForbiddenD40
Ethanol amine dinitrateForbidden
Ethanol or Ethyl alcohol or Ethanol solutions or Ethyl alcohol solutions3UN1170II324, IB2, T4, TP11502022425 L60 LA
III324, B1, IB3, T2, TP115020324260 L220 LA
Ethanolamine or Ethanolamine solutions8UN2491III8IB3, T4, TP11542032415 L60 LA
Ether, see Diethyl ether
Ethers, n.o.s.3UN3271II3IB2, T7, TP1, TP8, TP281502022425 L60 LB
III3B1, IB3, T4, TP1, TP2915020324260 L220 LA
Ethyl acetate3UN1173II3IB2, T4, TP11502022425 L60 LB
Ethyl acrylate, stabilized3UN1917II3IB2, T4, TP1, TP131502022425 L60 LB40
Ethyl alcohol, see Ethanol
Ethyl aldehyde, see Acetaldehyde
Ethyl amyl ketone3UN2271III3B1, IB3, T2, TP115020324260 L220 LA
N-Ethylbenzyltoluidines, solid6.1UN3460III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
N-Ethyl-N-benzylaniline6.1UN2274III6.1IB3, T4, TP115320324160 L220 LA
Ethyl borate3UN1176II3IB2, T4, TP11502022425 L60 LB
Ethyl bromide6.1UN1891II6.1IB2, IP8, T7, TP2, TP131532022435 L60 LB40, 85
Ethyl bromoacetate6.1UN1603II6.1, 3IB2, T7, TP2None202243ForbiddenForbiddenD40
Ethyl butyl ether3UN1179II3B1, IB2, T4, TP11502022425 L60 LB
Ethyl butyrate3UN1180III3B1, IB3, T2, TP115020324260 L220 LA
Ethyl chloride2.1UN10372.1B77, T50None322314, 315Forbidden150 kgB40
Ethyl chloroacetate6.1UN1181II6.1, 3IB2, T7, TP21532022435 L60 LA
Ethyl chloroformate6.1UN1182I6.1, 3, 82, B9, B14, B32, B74, N34, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD21, 40, 100
Ethyl 2-chloropropionate3UN2935III3B1, IB3, T2, TP115020324260 L220 LA
+Ethyl chlorothioformate8UN2826II8, 6.1, 32, B9, B14, B32, B74, T20, TP2, TP38, TP45None227244ForbiddenForbiddenA40
Ethyl crotonate3UN1862II3IB2, T4, TP21502022425 L60 LB
Ethyl ether, see Diethyl ether
Ethyl fluoride or Refrigerant gas R1612.1UN24532.1306304314, 315Forbidden150 kgE40
Ethyl formate3UN1190II3IB2, T4, TP11502022425 L60 LE
Ethyl hydroperoxideForbidden
Ethyl isobutyrate3UN2385II3IB2, T4, TP11502022425 L60 LB
+Ethyl isocyanate3UN2481I3, 6.11, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44None226244ForbiddenForbiddenD40, 52
Ethyl lactate3UN1192III3B1, IB3, T2, TP115020324260 L220 LA
Ethyl mercaptan3UN2363I3A6, T11, TP2, TP13None201243Forbidden30 LE95, 102
Ethyl methacrylate, stabilized3UN2277II3IB2, T4, TP11502022425 L60 LB
Ethyl methyl ether2.1UN10392.1None201314, 315Forbidden150 kgB40
Ethyl methyl ketone or Methyl ethyl ketone3UN1193II3IB2, T4, TP11502022425 L60 LB
Ethyl nitrite solutions3UN1194I3, 6.1None201NoneForbiddenForbiddenE40, 105
Ethyl orthoformate3UN2524III3B1, IB3, T2, TP115020324260 L220 LA
Ethyl oxalate6.1UN2525III6.1IB3, T4, TP115320324160 L220 LA
Ethyl perchlorateForbidden
DEthyl phosphonothioic dichloride, anhydrous6.1NA2927I6.1, 82, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45None227244ForbiddenForbiddenD40
DEthyl phosphonous dichloride, anhydrous pyrophoric liquid6.1NA2845I6.1, 4.22, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45None227244ForbiddenForbiddenD18
DEthyl phosphorodichloridate6.1NA2927I6.1, 82, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Ethyl propionate3UN1195II3IB2, T4, TP11502022425 L60 LB
Ethyl propyl ether3UN2615II3IB2, T4, TP11502022425 L60 LE
Ethyl silicate, see Tetraethyl silicate
Ethylacetylene, stabilized2.1UN24522.1None304314, 315Forbidden150 kgB40
Ethylamine2.1UN10362.1B77, T50None321314, 315Forbidden150 kgD40
Ethylamine, aqueous solution with not less than 50 percent but not more than 70 percent ethylamine3UN2270II3, 8IB2, T7, TP11502022431 L5 LB40
N-Ethylaniline6.1UN2272III6.1IB3, T4, TP115320324160 L220 LA52, 74
2-Ethylaniline6.1UN2273III6.1IB3, T4, TP115320324160 L220 LA52, 74
Ethylbenzene3UN1175II3IB2, T4, TP11502022425 L60 LB
N-Ethylbenzyltoluidines liquid6.1UN2753III6.1IB3, T7, TP115320324160 L220 LA
2-Ethylbutanol3UN2275III3B1, IB3, T2, TP115020324260 L220 LA
2-Ethylbutyl acetate3UN1177III3B1, IB3, T2, TP115020324260 L220 LA
2-Ethylbutyraldehyde3UN1178II3B1, IB2, T4, TP11502022425 L60 LB
Ethyldichloroarsine6.1UN1892I6.12, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Ethyldichlorosilane4.3UN1183I4.3, 8, 3A2, A3, A7, N34, T10, TP2, TP7, TP13None201244Forbidden1 LD21, 28, 40, 49, 100
Ethylene, acetylene and propylene in mixture, refrigerated liquid with at least 71.5 percent ethylene with not more than 22.5 percent acetylene and not more than 6 percent propylene2.1UN31382.1T75, TP5None304314, 315ForbiddenForbiddenD40, 57
Ethylene chlorohydrin6.1UN1135I6.1, 32, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Ethylene2.1UN19622.1306304302Forbidden150 kgE40
Ethylene diamine diperchlorateForbidden
Ethylene dibromide6.1UN1605I6.12, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Ethylene dibromide and methyl bromide liquid mixtures, see Methyl bromide and ethylene dibromide, liquid mixtures
Ethylene dichloride3UN1184II3, 6.1IB2, N36, T7, TP11502022431 L60 LB40
Ethylene glycol diethyl ether3UN1153II3IB2, T4, TP11502022425 L60 LA
III3B1, IB3, T2, TP115020324260 L220 LA
Ethylene glycol dinitrateForbidden
Ethylene glycol monoethyl ether3UN1171III3B1, IB3, T2, TP115020324260 L220 LA
Ethylene glycol monoethyl ether acetate3UN1172III3B1, IB3, T2, TP115020324260 L220 LA
Ethylene glycol monomethyl ether3UN1188III3B1, IB3, T2, TP115020324260 L220 LA
Ethylene glycol monomethyl ether acetate3UN1189III3B1, IB3, T2, TP115020324260 L220 LA
Ethylene oxide and carbon dioxide mixture with more than 87 percent ethylene oxide2.3UN33002.3, 2.14None304314, 315ForbiddenForbiddenD40
Ethylene oxide and carbon dioxide mixtures with more than 9 percent but not more than 87 percent ethylene oxide2.1UN10412.1T50306304314, 315Forbidden25 kgB40
Ethylene oxide and carbon dioxide mixtures with not more than 9 percent ethylene oxide2.2UN19522.2306304314, 31575 kg150 kgA
Ethylene oxide and chlorotetrafluoroethane mixture with not more than 8.8 percent ethylene oxide2.2UN32972.2T50306304314, 31575 kg150 kgA
Ethylene oxide and dichlorodifluoromethane mixture, with not more than 12.5 percent ethylene oxide2.2UN30702.2T50306304314, 31575 kg150 kgA
Ethylene oxide and pentafluoroethane mixture with not more than 7.9 percent ethylene oxide2.2UN32982.2T50306304314, 31575 kg150 kgA
Ethylene oxide and propylene oxide mixtures , with not more than 30 percent ethylene oxide3UN2983I3, 6.15, A11, N4, N34, T14, TP2, TP7, TP13None201243Forbidden30 LE40
Ethylene oxide and tetrafluoroethane mixture with not more than 5.6 percent ethylene oxide2.2UN32992.2T50306304314, 31575 kg150 kgA
Ethylene oxide or Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 degrees C2.3UN10402.3, 2.14, T50, TP20None323323ForbiddenForbiddenD40
Ethylene, refrigerated liquid (cryogenic liquid)2.1UN10382.1T75, TP5None316318, 319ForbiddenForbiddenD40
Ethylenediamine8UN1604II8, 3IB2, T7, TP21542022431 L30 LA40
Ethyleneimine, stabilized6.1UN1185I6.1, 31, B9, B14, B30, B72, B77, N25, N32, T22, TP2, TP13, TP38, TP44None226244ForbiddenForbiddenD40
Ethylhexaldehyde, see Octyl aldehydes etc
2-Ethylhexyl chloroformate6.1UN2748II6.1, 8IB2, T7, TP2, TP131532022431 L30 LA12, 13, 21, 25, 40, 100
2-Ethylhexylamine3UN2276III3, 8B1, IB3, T4, TP11502032425 L60 LA40
Ethylphenyldichlorosilane8UN2435II8A7, B2, IB2, N34, T7, TP2, TP13None202242Forbidden30 LC
1-Ethylpiperidine3UN2386II3, 8IB2, T7, TP11502022431 L5 LB
N-Ethyltoluidines6.1UN2754II6.1IB2, T7, TP21532022435 L60 LA
Ethyltrichlorosilane3UN1196II3, 8A7, IB1, N34, T7, TP2, TP131502022431 L5 LB40
Etiologic agent, see Infectious substances, etc
Explosive articles, see Articles, explosive , n.o.s. etc
Explosive, blasting, type A1.1DUN0081II1.1DNone62NoneForbiddenForbidden1021E, 29E
Explosive, blasting, type B1.1DUN0082II1.1DNone62NoneForbiddenForbidden1029E
Explosive, blasting, type B or Agent blasting, Type B1.5DUN0331II1.5D105, 106None62NoneForbiddenForbidden1029E
Explosive, blasting, type C1.1DUN0083II1.1D123None62NoneForbiddenForbidden1022E
Explosive, blasting, type D1.1DUN0084II1.1DNone62NoneForbiddenForbidden10
Explosive, blasting, type E1.1DUN0241II1.1DNone62NoneForbiddenForbidden1019E, 29E
Explosive, blasting, type E or Agent blasting, Type E1.5DUN0332II1.5D105, 106None62NoneForbiddenForbidden1029E
Explosive, forbidden. See § 173.54Forbidden
Explosive substances, see Substances, explosive, n.o.s. etc
Explosives, slurry, see Explosive, blasting, type E
Explosives, water gels, see Explosive, blasting, type E
Extracts, aromatic, liquid3UN1169II3149, IB2, T4, TP1, TP81502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Extracts, flavoring, liquid3UN1197II3149, IB2, T4, TP1, TP81502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Fabric with animal or vegetable oil, see Fibers or fabrics, etc
Ferric arsenate6.1UN1606II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Ferric arsenite6.1UN1607II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Ferric chloride, anhydrous8UN1773III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Ferric chloride, solution8UN2582III8B15, IB3, T4, TP11542032415 L60 LA
Ferric nitrate5.1UN1466III5.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA
Ferrocerium4.1UN1323II4.159, A19, IB8, IP2, IP4, T3, TP3315121224015 kg50 kgA
Ferrosilicon with 30 percent or more but less than 90 percent silicon4.3UN1408III4.3, 6.1A1, A19, B6, IB8, IP4, IP7, T1, TP3315121324025 kg100 kgA13, 40, 52, 53, 85, 103
Ferrous arsenate6.1UN1608II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
DFerrous chloride, solid8NA1759II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA
DFerrous chloride, solution8NA1760II8B3, IB2, T11, TP2, TP271542022421 L30 LB40
Ferrous metal borings or Ferrous metal shavings or Ferrous metal turnings or Ferrous metal cuttings in a form liable to self-heating4.2UN2793III4.2A1, A19, IB8, IP3, IP7None21324125 kg100 kgA
Fertilizer ammoniating solution with free ammonia2.2UN10432.2306304314, 315Forbidden150 kgE40
A I WFibers, animal or Fibers, vegetable burnt, wet or damp.4.2UN1372III151213240ForbiddenForbiddenA
I WFibers, vegetable, dry4.1UN33604.1137151213240No LimitNo LimitA
A WFibers or Fabrics, animal or vegetable or Synthetic, n.o.s. with animal or vegetable oil4.2UN1373III4.2137, IB8, IP3, T1, TP33None213241ForbiddenForbiddenA
Fibers or Fabrics impregnated with weakly nitrated nitrocellulose, n.o.s.4.1UN1353III4.1A1, IB8, IP3None21324025 kg100 kgD
Films, nitrocellulose base, from which gelatine has been removed; film scrap, see Celluloid scrap
Films, nitrocellulose base, gelatine coated (except scrap)4.1UN1324III4.1None183None25 kg100 kgD28
Fire extinguisher charges, corrosive liquid8UN1774II8N41154202None1 L30 LA
Fire extinguisher charges, expelling, explosive, see Cartridges, power device
Fire extinguishers containing compressed or liquefied gas2.2UN10442.218, 110309309None75 kg150 kgA
Firelighters, solid with flammable liquid4.1UN2623III4.1A1, A19None213None25 kg100 kgA52
Fireworks1.1GUN0333II1.1G108None62NoneForbiddenForbidden07
Fireworks1.2GUN0334II1.2G108None62NoneForbiddenForbidden07
Fireworks1.3GUN0335II1.3G108None62NoneForbiddenForbidden07
Fireworks1.4GUN0336II1.4G108None62NoneForbidden75 kg06
Fireworks1.4SUN0337II1.4S108None62None25 kg100 kg05
First aid kits9UN3316915161161None10 kg10 kgA
WFish meal, stabilized or Fish scrap, stabilized9UN2216IIINone155, IB8, IP3, T1, TP33155218218No limitNo limitB88, 122, 128
Fish meal, unstablized or Fish scrap, unstabilized4.2UN1374II4.2155, A1, A19, IB8, IP2, IP4, T3, TP33None21224115 kg50 kgB18, 128
Fissile radioactive materials, see Radioactive material, fissile, n.o.s.
Flammable compressed gas, see Compressed or Liquefied gas, flammable, etc
Flammable compressed gas (small receptacles not fitted with a dispersion device, not refillable), see Receptacles, etc
Flammable gas in lighters, see Lighters or lighter refills, cigarettes, containing flammable gas
GFlammable liquid, toxic, corrosive, n.o.s.3UN3286I3, 6.1, 8T14, TP2, TP13, TP27None201243Forbidden2.5 LE21, 40, 100
II3, 6.1, 8IB2, T11, TP2, TP13, TP271502022431 L5 LB21, 40, 100
GFlammable liquids, corrosive, n.o.s.3UN2924I3, 8T14, TP2None2012430.5 L2.5 LE40
II3, 8IB2, T11, TP2, TP271502022431 L5 LB40
III3, 8B1, IB3, T7, TP1, TP281502032425 L60 LA40
GFlammable liquids, n.o.s.3UN1993I3T11, TP1, TP271502012431 L30 LE
II3IB2, T7, TP1, TP8, TP281502022425 L60 LB
III3B1, B52, IB3, T4, TP1, TP2915020324260 L220 LA
GFlammable liquids, toxic, n.o.s.3UN1992I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LE40
II3, 6.1IB2, T7, TP2, TP131502022431 L60 LB40
III3, 6.1B1, IB3, T7, TP1, TP2815020324260 L220 LA
GFlammable solid, corrosive, inorganic, n.o.s.4.1UN3180II4.1, 8A1, IB6, IP2, T3, TP3315121224215 kg50 kgD40
III4.1, 8A1, IB6, T1, TP3315121324225 kg100 kgD40
GFlammable solid, inorganic, n.o.s.4.1UN3178II4.1A1, IB8, IP2, IP4, T3, TP3315121224015 kg50 kgB
III4.1A1, IB8, IP3, T1, TP3315121324025 kg100 kgB
GFlammable solid, organic, molten, n.o.s.4.1UN3176II4.1IB1, T3, TP3, TP26151212240ForbiddenForbiddenC
III4.1IB1, T1, TP3, TP26151213240ForbiddenForbiddenC
GFlammable solid, oxidizing, n.o.s.4.1UN3097II4.1, 5.1131None214214ForbiddenForbiddenE40
III4.1, 5.1131, T1, TP33None214214ForbiddenForbiddenD40
GFlammable solid, toxic, inorganic, n.o.s.4.1UN3179II4.1, 6.1A1, IB6, IP2, T3, TP3315121224215 kg50 kgB40
III4.1, 6.1A1, IB6, T1, TP3315121324225 kg100 kgB40
GFlammable solids, corrosive, organic, n.o.s.4.1UN2925II4.1, 8A1, IB6, IP2, T3, TP33None21224215 kg50 kgD40
III4.1, 8A1, IB6, T1, TP3315121324225 kg100 kgD40
GFlammable solids, organic, n.o.s.4.1UN1325II4.1A1, IB8, IP2, IP4, T3, TP3315121224015 kg50 kgB
III4.1A1, IB8, IP3, T1, TP3315121324025 kg100 kgB
GFlammable solids, toxic, organic, n.o.s.4.1UN2926II4.1, 6.1A1, IB6, IP2, T3, TP3315121224215 kg50 kgB40
III4.1, 6.1A1, IB6, T1, TP3315121324225 kg100 kgB40
Flares, aerial1.3GUN0093II1.3GNone62NoneForbidden75 kg07
Flares, aerial1.4GUN0403II1.4GNone62NoneForbidden75 kg06
Flares, aerial1.4SUN0404II1.4SNone62None25 kg100 kg05
Flares, aerial1.1GUN0420II1.1GNone62NoneForbiddenForbidden07
Flares, aerial1.2GUN0421II1.2GNone62NoneForbiddenForbidden07
Flares, airplane, see Flares, aerial
Flares, signal, see Cartridges, signal
Flares, surface1.3GUN0092II1.3GNone62NoneForbidden75 kg07
Flares, surface1.1GUN0418II1.1GNone62NoneForbiddenForbidden07
Flares, surface1.2GUN0419II1.2GNone62NoneForbiddenForbidden07
Flares, water-activated, see Contrivances, water-activated, etc
Flash powder1.1GUN0094II1.1GNone62NoneForbiddenForbidden15
Flash powder1.3GUN0305II1.3GNone62NoneForbiddenForbidden15
Flue dusts, poisonous, see Arsenical dust
Fluoric acid, see Hydrofluoric acid, etc
Fluorine, compressed2.3UN10452.3, 5.1, 81None302NoneForbiddenForbiddenD40, 89, 90
Fluoroacetic acid6.1UN2642I6.1IB7, IP1, T6, TP33None2112421 kg15 kgE
Fluoroanilines6.1UN2941III6.1IB3, T4, TP115320324160 L220 LA
Fluorobenzene3UN2387II3IB2, T4, TP11502022425 L60 LB
Fluoroboric acid8UN1775II8A6, A7, B2, B15, IB2, N3, N34, T7, TP21542022421 L30 LA
Fluorophosphoric acid anhydrous8UN1776II8A6, A7, B2, IB2, N3, N34, T8, TP2, TP12None2022421 L30 LA
Fluorosilicates, n.o.s.6.1UN2856III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA52
Fluorosilicic acid8UN1778II8A6, A7, B2, B15, IB2, N3, N34, T8, TP2, TP12None2022421 L30 LA
Fluorosulfonic acid8UN1777I8A3, A6, A7, A10, B6, B10, N3, N36, T10, TP2, TP12None2012430.5 L2.5 LD40
Fluorotoluenes3UN2388II3IB2, T4, TP11502022425 L60 LB40
Forbidden materials. See § 173.21Forbidden
Formaldehyde, solutions, flammable3UN1198III3, 8B1, IB3, T4, TP11502032425 L60 LA40
Formaldehyde, solutions, with not less than 25 percent formaldehyde8UN2209III8IB3, T4, TP11542032415 L60 LA
Formalin, see Formaldehyde, solutions
Formic acid8UN1779II8B2, B28, IB2, T7, TP21542022421 L30 LA40
Fracturing devices, explosive, without detonators for oil wells1.1DUN0099II1.1DNone62NoneForbiddenForbidden07
Fuel, aviation, turbine engine3UN1863I3144, T11, TP1, TP8, TP281502012431 L30 LE
II3144, IB2, T4, TP1, TP81502022425 L60 LB
III3144, B1, IB3, T2, TP115020324260 L220 LA
DFuel oil (No. 1, 2, 4, 5, or 6)3NA1993III3144, B1, IB3, T4, TP1, TP2915020324260 L220 LA
Fuel system components (including fuel control units (FCU), carburetors, fuel lines, fuel pumps) see Dangerous Goods in Apparatus or Dangerous Goods in Machinery
Fulminate of mercury (dry)Forbidden
Fulminate of mercury, wet, see Mercury fulminate, etc
Fulminating goldForbidden
Fulminating mercuryForbidden
Fulminating platinumForbidden
Fulminating silverForbidden
Fulminic acidForbidden
Fumaryl chloride8UN1780II8B2, IB2, T7, TP21542022421 L30 LC8, 40
Fumigated lading, see §§ 172.302(g), 173.9 and 176.76(h)
Fumigated transport vehicle or freight container see 173.9
Furaldehydes6.1UN1199II6.1, 3IB2, T7, TP21532022435 L60 LA
Furan3UN2389I3T12, TP2, TP13None2012431 L30 LE40
Furfuryl alcohol6.1UN2874III6.1IB3, T4, TP115320324160 L220 LA52, 74
Furfurylamine3UN2526III3, 8B1, IB3, T4, TP11502032425 L60 LA40
Fuse, detonating, metal clad, see Cord, detonating, metal clad
Fuse, detonating, mild effect, metal clad, see Cord, detonating, mild effect, metal clad
Fuse, igniter tubular metal clad1.4GUN0103II1.4GNone62NoneForbidden75 kg06
Fuse, non-detonating instantaneous or quickmatch1.3GUN0101II1.3GNone62NoneForbiddenForbidden07
Fuse, safety1.4SUN0105II1.4SNone62None25 kg100 kg05
DFusee (railway or highway)4.1NA1325II4.1None184None15 kg50 kgB
Fusel oil3UN1201II3IB2, T4, TP11502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Fuses, tracer, see Tracers for ammunition
Fuzes, combination, percussion and time, see Fuzes, detonating (UN0257, UN0367); Fuzes, igniting (UN0317, UN0368)
Fuzes, detonating1.1BUN0106II1.1BNone62NoneForbiddenForbidden11
Fuzes, detonating1.2BUN0107II1.2BNone62NoneForbiddenForbidden11
Fuzes, detonating1.4BUN0257II1.4B116None62NoneForbidden75 kg06
Fuzes, detonating1.4SUN0367II1.4S116None62None25 kg100 kg05
Fuzes, detonating, with protective features1.1DUN0408II1.1DNone62NoneForbiddenForbidden07
Fuzes, detonating, with protective features1.2DUN0409II1.2DNone62NoneForbiddenForbidden07
Fuzes, detonating, with protective features1.4DUN0410II1.4D116None62NoneForbidden75 kg06
Fuzes, igniting1.3GUN0316II1.3GNone62NoneForbiddenForbidden07
Fuzes, igniting1.4GUN0317II1.4GNone62NoneForbidden75 kg06
Fuzes, igniting1.4SUN0368II1.4SNone62None25 kg100 kg05
Galactsan trinitrateForbidden
Gallium8UN2803III8T1, TP33None16224020 kg20 kgB48
Gas cartridges, (flammable) without a release device, non-refillable2.1UN20372.1306304None1 kg15 kgB40
Gas generator assemblies (aircraft), containing a non-flammable non-toxic gas and a propellant cartridge2.22.2None335None75 kg150 kgA
DGas identification set2.3NA90352.36None194NoneForbiddenForbiddenD
Gas oil3UN1202III3144, B1, IB3, T2, TP115020324260 L220 LA
GGas, refrigerated liquid, flammable, n.o.s. (cryogenic liquid)2.1UN33122.1T75, TP5None316318ForbiddenForbiddenD40
GGas, refrigerated liquid, n.o.s. (cryogenic liquid)2.2UN31582.2T75, TP532031631850 kg500 kgD
GGas, refrigerated liquid, oxidizing, n.o.s. (cryogenic liquid)2.2UN33112.2, 5.1T75, TP5, TP22320316318ForbiddenForbiddenD
Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid2.1UN31672.1306302, 304None1 L5 LD
Gas sample, non-pressurized, toxic, flammable, n.o.s., not refrigerated liquid2.3UN31682.3, 2.16306302NoneForbidden1 LD
Gas sample, non-pressurized, toxic, n.o.s., not refrigerated liquid2.3UN31692.36306302, 304NoneForbidden1 LD
DGasohol gasoline mixed with ethyl alcohol, with not more than 20 percent alcohol3NA1203II31441502022425 L60 LE
Gasoline3UN1203II3139, B33, B101, T81502022425 L60 LE
Gasoline, casinghead, see Gasoline
Gelatine, blasting, see Explosive, blasting, type A
Gelatine dynamites, see Explosive, blasting, type A
Germane2.3UN21922.3, 2.12None302245ForbiddenForbiddenD40
Glycerol-1,3-dinitrateForbidden
Glycerol gluconate trinitrateForbidden
Glycerol lactate trinitrateForbidden
Glycerol alpha-monochlorohydrin6.1UN2689III6.1IB3, T4, TP115320324160 L220 LA
Glyceryl trinitrate, see Nitroglycerin, etc
Glycidaldehyde3UN2622II3, 6.1IB2, IP8, T7, TP11502022431 L60 LA40
Grenades, hand or rifle, with bursting charge1.1DUN0284II1.1D62NoneForbiddenForbidden07
Grenades, hand or rifle, with bursting charge1.2DUN0285II1.2D62NoneForbiddenForbidden07
Grenades, hand or rifle, with bursting charge1.1FUN0292II1.1F62NoneForbiddenForbidden08
Grenades, hand or rifle, with bursting charge1.2FUN0293II1.2F62NoneForbiddenForbidden08
Grenades, illuminating, see Ammunition, illuminating, etc
Grenades, practice, hand or rifle1.4SUN0110II1.4S62None25 kg100 kg05
Grenades, practice, hand or rifle1.3GUN0318II1.3G62NoneForbiddenForbidden07
Grenades, practice, hand or rifle1.2GUN0372II1.2G62NoneForbiddenForbidden07
Grenades practice Hand or rifle1.4GUN0452II1.4G62NoneForbidden75 kg06
Grenades, smoke, see Ammunition, smoke, etc
Guanidine nitrate5.1UN1467III5.1A1, IB8, IP3, T1, TP3315221324025 kg100 kgA73
Guanyl nitrosaminoguanylidene hydrazine (dry)Forbidden
Guanyl nitrosaminoguanylidene hydrazine, wetted with not less than 30 percent water, by mass1.1AUN0113II1.1A111, 117None62NoneForbiddenForbidden12
Guanyl nitrosaminoguanyltetrazene (dry)Forbidden
Guanyl nitrosaminoguanyltetrazene, wetted or Tetrazene, wetted with not less than 30 percent water or mixture of alcohol and water, by mass1.1AUN0114II1.1A111, 117None62NoneForbiddenForbidden12
Gunpowder, compressed or Gunpowder in pellets, see Black powder (UN 0028)
Gunpowder, granular or as a meal, see Black powder (UN 0027)
Hafnium powder, dry4.2UN2545I4.2None211242ForbiddenForbiddenD
II4.2A19, A20, IB6, IP2, N34, T3, TP33None21224115 kg50 kgD
III4.2IB8, IP3, T1, TP33None21324125 kg100 kgD
Hafnium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns4.1UN1326II4.1A6, A19, A20, IB6, IP2, N34, T3, TP33None21224115 kg50 kgE74
Hand signal device, see Signal devices, hand
Hazardous substances, liquid or solid, n.o.s., see Environmentally hazardous substances, etc
D GHazardous waste, liquid, n.o.s.9NA3082III9IB3, T2, TP1155203241No limitNo limitA
D GHazardous waste, solid, n.o.s.9NA3077III9B54, IB8, IP2, T1, TP33155213240No limitNo limitA
Heating oil, light3UN1202III3B1, IB3, T2, TP115020324260 L220 LA
Helium, compressed2.2UN10462.2306302302, 31475 kg150 kgA85
Helium-oxygen mixture, see Rare gases and oxygen mixtures
Helium, refrigerated liquid (cryogenic liquid)2.2UN19632.2T75, TP532031631850 kg500 kgB
Heptafluoropropane or Refrigerant gas R 2272.2UN32962.2T50306304314, 31575 kg150 kgA
n-Heptaldehyde3UN3056III3B1, IB3, T2, TP115020324260 L220 LA
Heptanes3UN1206II3IB2, T4, TP11502022425 L60 LB
n-Heptene3UN2278II3IB2, T4, TP11502022425 L60 LB
Hexachloroacetone6.1UN2661III6.1IB3, T4, TP115320324160 L220 LB12, 40
Hexachlorobenzene6.1UN2729III6.1B3, IB8, IP3, T1, TP3315320324160 L220 LA
Hexachlorobutadiene6.1UN2279III6.1IB3, T4, TP115320324160 L220 LA
Hexachlorocyclopentadiene6.1UN2646I6.12, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Hexachlorophene6.1UN2875III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Hexadecyltrichlorosilane8UN1781II8A7, B2, B6, IB2, N34, T7, TP2None202242Forbidden30 LC40
Hexadienes3UN2458II3IB2, T4, TP1None2022425 L60 LB
Hexaethyl tetraphosphate and compressed gas mixtures2.3UN16122.33None334NoneForbiddenForbiddenD40
Hexaethyl tetraphosphate, liquid6.1UN1611II6.1IB2, N76, T7, TP21532022435 L60 LE40
Hexaethyl tetraphosphate, solid6.1UN1611II6.1IB8, IP2, IP4, N7615321224225 kg100 kgE40
Hexafluoroacetone2.3UN24202.3, 82, B9, B14None304314, 315ForbiddenForbiddenD40
Hexafluoroacetone hydrate, liquid6.1UN2552II6.1IB2, T7, TP21532022435 L60 LB40
Hexafluoroacetone hydrate, solid6.1UN3436II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB40
Hexafluoroethane, or Refrigerant gas R 1162.2UN21932.2306304314, 31575 kg150 kgA
Hexafluorophosphoric acid8UN1782II8A6, A7, B2, IB2, N3, N34, T8, TP2, TP12None2022421 L30 LA
Hexafluoropropylene compressed or Refrigerant gas R 12162.2UN18582.2T50306304314, 31575 kg150 kgA
Hexaldehyde3UN1207III3B1, IB3, T2, TP115020324260 L220 LA
Hexamethylene diisocyanate6.1UN2281II6.1IB2, T7, TP2, TP131532022435 L60 LC13, 40
Hexamethylene triperoxide diamine (dry)Forbidden
Hexamethylenediamine, solid8UN2280III8IB8, IP3, T1, TP3315421324025 kg100 kgA12
Hexamethylenediamine solution8UN1783II8IB2, T7, TP2None2022421 L30 LA
III8IB3, T4, TP11542032415 L60 LA
Hexamethyleneimine3UN2493II3, 8IB2, T7, TP11502022431 L5 LB40
Hexamethylenetetramine4.1UN1328III4.1A1, IB8, IP3, T1, TP3315121324025 kg100 kgA
Hexamethylol benzene hexanitrateForbidden
Hexanes3UN1208II3IB2, T4, TP11502022425 L60 LE
2,2',4,4',6,6'- Hexanitro-3,3'-dihydroxyazobenzene (dry)Forbidden
Hexanitroazoxy benzeneForbidden
N,N'-(hexanitrodiphenyl) ethylene dinitramine (dry)Forbidden
Hexanitrodiphenyl ureaForbidden
2,2',3',4,4',6-HexanitrodiphenylamineForbidden
Hexanitrodiphenylamine or Dipicrylamine or Hexyl1.1DUN0079II1.1DNone62NoneForbiddenForbidden10
2,3',4,4',6,6'-HexanitrodiphenyletherForbidden
HexanitroethaneForbidden
HexanitrooxanilideForbidden
Hexanitrostilbene1.1DUN0392II1.1DNone62NoneForbiddenForbidden10
Hexanoic acid, see Corrosive liquids, n.o.s.
Hexanols3UN2282III3B1, IB3, T2, TP115020324260 L220 LA74
1-Hexene3UN2370II3IB2, T4, TP11502022425 L60 LE
Hexogen and cyclotetramethylenetetranitramine mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc
Hexogen and HMX mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc
Hexogen and octogen mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc
Hexogen, see Cyclotrimethylenetrinitramine, etc
Hexolite, or Hexotol dry or wetted with less than 15 percent water, by mass1.1DUN0118II1.1DNone62NoneForbiddenForbidden10
Hexotonal1.1DUN0393II1.1DNone62NoneForbiddenForbidden10
Hexyl, see Hexanitrodiphenylamine
Hexyltrichlorosilane8UN1784II8A7, B2, B6, IB2, N34, T7, TP2, TP13None202242Forbidden30 LC40
High explosives, see individual explosives' entries
HMX, see Cyclotetramethylenete tranitramine, etc
Hydrazine, anhydrous8UN2029I8, 3, 6.1A3, A6, A7, A10, B7, B16, B53None201243Forbidden2.5 LD40, 125
Hydrazine, aqueous solution with not more than 37 percent hydrazine, by mass6.1UN3293III6.1IB3, T4, TP115320324160 L220 LA
Hydrazine azideForbidden
Hydrazine chlorateForbidden
Hydrazine dicarbonic acid diazideForbidden
Hydrazine aqueous solution, with more than 37% hydrazine, by mass8UN2030I8, 6.1151, B16, B53, T10, TP2, TP13None201243Forbidden2.5 LD40
II8, 6.1B16, B53, IB2, T7, TP2, TP13None202243Forbidden30 LD40
III8, 6.1B16, B53, IB3, T4, TP11542032415 L60 LD40
Hydrazine perchlorateForbidden
Hydrazine selenateForbidden
Hydriodic acid, anhydrous, see Hydrogen iodide, anhydrous
Hydriodic acid8UN1787II8A3, A6, B2, IB2, N41, T7, TP21542022421 L30 LC
III8IB3, T4, TP11542032415 L60 LC8
Hydrobromic acid, anhydrous, see Hydrogen bromide, anhydrous
Hydrobromic acid, with more than 49 percent hydrobromic acid8UN1788II8B2, B15, IB2, N41, T7, TP2154202242ForbiddenForbiddenC
III8IB3, T4, TP1154203241ForbiddenForbiddenC8
Hydrobromic acid, with not more than 49 percent hydrobromic acid8UN1788II8A3, A6, B2, B15, IB2, N41, T7, TP21542022421 L30 LC
III8A3, IB3, T4, TP11542032415 L60 LC8
Hydrocarbon gas mixture, compressed, n.o.s.2.1UN19642.1306302314, 315Forbidden150 kgE40
Hydrocarbon gas mixture, liquefied, n.o.s.2.1UN19652.1T50306304314, 315Forbidden150 kgE40
Hydrocarbons, liquid, n.o.s.3UN3295I3144, T11, TP1, TP8, TP281502012431 L30 LE
II3144, IB2, T7, TP1, TP8, TP281502022425 L60 LB
III3144, B1, IB3, T4, TP1, TP2915020324260 L220 LA
Hydrochloric acid, anhydrous, see Hydrogen chloride, anhydrous
Hydrochloric acid8UN1789II8A3, A6, B3, B15, IB2, N41, T8, TP2, TP121542022421 L30 LC
III8A3, IB3, T4, TP1, TP121542032415 L60 LC8
Hydrocyanic acid, anhydrous, see Hydrogen cyanide etc
Hydrocyanic acid, aqueous solutions or Hydrogen cyanide, aqueous solutions with not more than 20 percent hydrogen cyanide6.1UN1613I6.12, B61, B65, B77, B82, T20, TP2, TP13None195244ForbiddenForbiddenD40
DHydrocyanic acid, aqueous solutions with less than 5 percent hydrogen cyanide6.1NA1613II6.1IB1, T14, TP2, TP13, TP27None195243Forbidden5 LD40
Hydrocyanic acid, liquefied, see Hydrogen cyanide, etc
Hydrocyanic acid (prussic), unstabilizedForbidden
Hydrofluoric acid and Sulfuric acid mixtures8UN1786I8, 6.1A6, A7, B15, B23, N5, N34, T10, TP2, TP12, TP13None201243Forbidden2.5 LD40
Hydrofluoric acid, anhydrous, see Hydrogen fluoride, anhydrous
Hydrofluoric acid, with more than 60 percent strength8UN1790I8, 6.1A6, A7, B4, B15, B23, N5, N34, T10, TP2, TP12, TP13None2012430.5 L2.5 LD12, 40
Hydrofluoric acid, with not more than 60 percent strength8UN1790II8, 6.1A6, A7, B15, IB2, N5, N34, T8, TP2, TP121542022431 L30 LD12, 40
Hydrofluoroboric acid, see Fluoroboric acid
Hydrofluorosilicic acid, see Fluorosilicic acid
Hydrogen and Methane mixtures, compressed2.1UN20342.1306302302, 314, 315Forbidden150 kgE40, 57
Hydrogen bromide, anhydrous2.3UN10482.3, 83, B14None304314, 315ForbiddenForbiddenD40
Hydrogen chloride, anhydrous2.3UN10502.3, 83None304NoneForbiddenForbiddenD40
Hydrogen chloride, refrigerated liquid2.3UN21862.3, 83, B6NoneNone314, 315ForbiddenForbiddenB40
Hydrogen, compressed2.1UN10492.1306302302, 314Forbidden150 kgE40, 57
Hydrogen cyanide, solution in alcohol with not more than 45 percent hydrogen cyanide6.1UN3294I6.1, 32, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Hydrogen cyanide, stabilized with less than 3 percent water6.1UN1051I6.1, 31, B35, B61, B65, B77, B82None195244ForbiddenForbiddenD40
Hydrogen cyanide, stabilized, with less than 3 percent water and absorbed in a porous inert material6.1UN1614I6.15None195NoneForbiddenForbiddenD25, 40
Hydrogen fluoride, anhydrous8UN1052I8, 6.13, B7, B46, B71, B77, T10, TP2None163243ForbiddenForbiddenD40
Hydrogen in a metal hydride storage system2.1UN34682.1167None214NoneForbiddenForbiddenD
Hydrogen iodide, anhydrous2.3UN21972.33, B14None304314, 315ForbiddenForbiddenD40
Hydrogen iodide solution, see Hydriodic acid, solution
Hydrogen peroxide and peroxyacetic acid mixtures, stabilized with acids, water and not more than 5 percent peroxyacetic acid5.1UN3149II5.1, 8145, A2, A3, A6, B53, IB2, IP5, T7, TP2, TP6, TP24None2022431 L5 LD25, 66, 75
Hydrogen peroxide, aqueous solutions with more than 40 percent but not more than 60 percent hydrogen peroxide (stabilized as necessary)5.1UN2014II5.1, 812, B53, B80, B81, B85, IB2, T7, TP2, TP6, TP24, TP37None202243ForbiddenForbiddenD25, 66, 75
Hydrogen peroxide, aqueous solutions with not less than 20 percent but not more than 40 percent hydrogen peroxide (stabilized as necessary)5.1UN2014II5.1, 8A2, A3, A6, B53, IB2, IP5, T7, TP2, TP6, TP24, TP37None2022431 L5 LD25, 66, 75
Hydrogen peroxide, aqueous solutions with not less than 8 percent but less than 20 percent hydrogen peroxide (stabilized as necessary)5.1UN2984III5.1A1, IB2, IP5, T4, TP1, TP6, TP24, TP371522032412.5 L30 LB25, 66, 75
Hydrogen peroxide, stabilized or Hydrogen peroxide aqueous solutions, stabilized with more than 60 percent hydrogen peroxide5.1UN2015I5.1, 812, B53, B80, B81, B85, T10, TP2, TP6, TP24, TP37None201243ForbiddenForbiddenD25, 66, 75
Hydrogen, refrigerated liquid (cryogenic liquid)2.1UN19662.1T75, TP5None316318, 319ForbiddenForbiddenD40
Hydrogen selenide, anhydrous2.3UN22022.3, 2.11None192245ForbiddenForbiddenD40
Hydrogen sulfate, see Sulfuric acid
Hydrogen sulfide2.3UN10532.3, 2.12, B9, B14None304314, 315ForbiddenForbiddenD40
Hydrogendifluorides, n.o.s.8UN1740II8IB8, IP2, IP4, N3, N34, T3, TP33None21224015 kg50 kgA25, 40, 52
III8IB8, IP3, N3, N34, T1, TP3315421324025 kg100 kgA25, 40, 52
Hydroquinone, solid6.1UN2662III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Hydroquinone solution6.1UN3435III6.1IB3, T4, TP115320324160 L220 LA
Hydrosilicofluoric acid, see Fluorosilicic acid
Hydroxyl amine iodideForbidden
Hydroxylamine sulfate8UN2865III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Hypochlorite solutions8UN1791II8A7, B2, B15, IB2, IP5, N34, T7, TP2, TP241542022421 L30 LB26
III8IB3, N34, T4, TP2, TP241542032415 L60 LB26
Hypochlorites, inorganic, n.o.s.5.1UN3212II5.1A9, IB8, IP2, IP4, T3, TP331522122405 kg25 kgD4, 48, 52, 56, 58, 69, 106, 116 118
Hyponitrous acidForbidden
Igniter fuse, metal clad, see Fuse, igniter, tubular, metal clad
Igniters1.1GUN0121II1.1GNone62NoneForbiddenForbidden07
Igniters1.2GUN0314II1.2GNone62NoneForbiddenForbidden07
Igniters1.3GUN0315II1.3GNone62NoneForbiddenForbidden07
Igniters1.4GUN0325II1.4GNone62NoneForbidden75 kg06
Igniters1.4SUN0454II1.4SNone62None25 kg100 kg05
3,3'-Iminodipropylamine8UN2269III8IB3, T4, TP21542032415 L60 LA
GInfectious substances, affecting animals only6.2UN29006.2A81, A82134196None50 mL or 50 g4 L or 4 kgB40
GInfectious substances, affecting humans6.2UN28146.2A81, A82134196None50 mL or 50 g4 L or 4 kgB40
Inflammable, see Flammable
Initiating explosives (dry)Forbidden
Inositol hexanitrate (dry)Forbidden
GInsecticide gases, n.o.s.2.2UN19682.2306304314, 31575 kg150 kgA
GInsecticide gases, flammable, n.o.s.2.1UN33542.1T50306304314, 315Forbidden150 kgD40
GInsecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone A2.3UN33552.3, 2.11None192245ForbiddenForbiddenD40
GInsecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone B2.3UN33552.3, 2.12, B9, B14None302, 305314, 315ForbiddenForbiddenD40
GInsecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone C2.3UN33552.3, 2.13, B14None302, 305314, 315ForbiddenForbiddenD
GInsecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone D2.3UN33552.3, 2.14None302, 305314, 315ForbiddenForbiddenD
GInsecticide gases, toxic, n.o.s.2.3UN19672.33None193, 334245ForbiddenForbiddenD40
Inulin trinitrate (dry)Forbidden
Iodine azide (dry)Forbidden
Iodine monochloride8UN1792II8B6, IB8, IP2, IP4, N41, T7, TP2None212240Forbidden50 kgD40, 66, 74, 89, 90
Iodine pentafluoride5.1UN2495I5.1, 6.1, 8None205243ForbiddenForbiddenD25, 40, 52, 66, 90
2-Iodobutane3UN2390II3IB2, T4, TP11502022425 L60 LB
Iodomethylpropanes3UN2391II3IB2, T4, TP11502022425 L60 LB
Iodopropanes3UN2392III3B1, IB3, T2, TP115020324260 L220 LA
Iodoxy compounds (dry)Forbidden
Iridium nitratopentamine iridium nitrateForbidden
Iron chloride, see Ferric chloride
Iron oxide, spent, or Iron sponge, spent obtained from coal gas purification4.2UN1376III4.2B18, IB8, IP3, T1, TP33None213240ForbiddenForbiddenE
Iron pentacarbonyl6.1UN1994I6.1, 31, B9, B14, B30, B72, B77, T22, TP2, TP13, TP38, TP44None226244ForbiddenForbiddenD40
Iron sesquichloride, see Ferric chloride
Irritating material, see Tear gas substances, etc
Isobutane see also Petroleum gases, liquefied2.1UN19692.119, T50306304314, 315Forbidden150 kgE40
Isobutanol or Isobutyl alcohol3UN1212III3B1, IB3, T2, TP115020324260 L220 LA
Isobutyl acetate3UN1213II3IB2, T4, TP11502022425 L60 LB
Isobutyl acrylate, stabilized3UN2527III3B1, IB3, T2, TP115020324260 L220 LA
Isobutyl alcohol, see Isobutanol
Isobutyl aldehyde, see Isobutyraldehyde
DIsobutyl chloroformate6.1NA2742I6.1, 3, 82, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45None2272441 L30 LA12, 13, 22, 25, 40, 48, 100
Isobutyl formate3UN2393II3IB2, T4, TP11502022425 L60 LB
Isobutyl isobutyrate3UN2528III3B1, IB3, T2, TP115020324260 L220 LA
+Isobutyl isocyanate3UN2486I3, 6.11, B9, B14, B30, B72, T22, TP2, TP13, TP27None226244ForbiddenForbiddenD40
Isobutyl methacrylate, stabilized3UN2283III3B1, IB3, T2, TP115020324260 L220 LA
Isobutyl propionate3UN2394III3B1, IB3, T2, TP115020324260 L220 LB
Isobutylamine3UN1214II3, 8IB2, T7, TP11502022431 L5 LB40
Isobutylene see also Petroleum gases, liquefied2.1UN10552.119, T50306304314, 315Forbidden150 kgE40
Isobutyraldehyde or Isobutyl aldehyde3UN2045II3IB2, T4, TP11502022425 L60 LE40
Isobutyric acid3UN2529III3, 8B1, IB3, T4, TP11502032425 L60 LA
Isobutyronitrile3UN2284II3, 6.1IB2, T7, TP2, TP131502022431 L60 LE40
Isobutyryl chloride3UN2395II3, 8IB1, T7, TP21502022431 L5 LC40
GIsocyanates, flammable, toxic, n.o.s. or Isocyanate solutions, flammable, toxic, n.o.s. flash point less than 23 degrees C3UN2478II3, 6.15, A3, A7, IB2, T11, TP2, TP13, TP271502022431 L60 LD40
III3, 6.15, A3, A7, IB3, T7, TP1, TP13, TP2815020324260 L220 LA
GIsocyanates, toxic, flammable, n.o.s. or Isocyanate solutions, toxic, flammable, n.o.s., flash point not less than 23 degrees C but not more than 61 degrees C and boiling point less than 300 degrees C6.1UN3080II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB25, 40, 48
GIsocyanates, toxic, n.o.s. or Isocyanate solutions, toxic, n.o.s., flash point more than 61 degrees C and boiling point less than 300 degrees C6.1UN2206II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LE25, 40, 48
III6.1IB3, T7, TP1, TP13, TP2815320324160 L220 LE25, 40, 48
Isocyanatobenzotrifluorides6.1UN2285II6.1, 35, IB2, T7, TP21532022435 L60 LD25, 40, 48
Isoheptenes3UN2287II3IB2, T4, TP11502022425 L60 LB
Isohexenes3UN2288II3IB2, IP8, T11, TP11502022425 L60 LE
Isooctane, see Octanes
Isooctenes3UN1216II3IB2, T4, TP11502022425 L60 LB
Isopentane, see Pentane
Isopentanoic acid, see Corrosive liquids, n.o.s.
Isopentenes3UN2371I3T11, TP21502012431 L30 LE
Isophorone diisocyanate6.1UN2290III6.1IB3, T4, TP215320324160 L220 LB40
Isophoronediamine8UN2289III8IB3, T4, TP11542032415 L60 LA
Isoprene, stabilized3UN1218I3T11, TP21502012431 L30 LE
Isopropanol or Isopropyl alcohol3UN1219II3IB2, T4, TP11502022425 L60 LB
Isopropenyl acetate3UN2403II3IB2, T4, TP11502022425 L60 LB
Isopropenylbenzene3UN2303III3B1, IB3, T2, TP115020324260 L220 LA
Isopropyl acetate3UN1220II3IB2, T4, TP11502022425 L60 LB
Isopropyl acid phosphate8UN1793III8IB2, T4, TP115421324025 kg100 kgA
Isopropyl alcohol, see Isopropanol
Isopropyl butyrate3UN2405III3B1, IB3, T2, TP115020324260 L220 LA
Isopropyl chloroacetate3UN2947III3B1, IB3, T2, TP115020324260 L220 LA
Isopropyl chloroformate6.1UN2407I6.1, 3, 82, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP44None227244ForbiddenForbiddenB40
Isopropyl 2-chloropropionate3UN2934III3B1, IB3, T2, TP115020324260 L220 LA
Isopropyl isobutyrate3UN2406II3IB2, T4, TP11502022425 L60 LB
+Isopropyl isocyanate3UN2483I3, 6.11, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44None226244ForbiddenForbiddenD40
Isopropyl mercaptan, see Propanethiols
Isopropyl nitrate3UN1222II3IB99150202None5 L60 LD
Isopropyl phosphoric acid, see Isopropyl acid phosphate
Isopropyl propionate3UN2409II3IB2, T4, TP11502022425 L60 LB
Isopropylamine3UN1221I3, 8T11, TP2None2012430.5 L2.5 LE
Isopropylbenzene3UN1918III3B1, IB3, T2, TP115020324260 L220 LA
Isopropylcumyl hydroperoxide, with more than 72 percent in solutionForbidden
Isosorbide dinitrate mixture with not less than 60 percent lactose, mannose, starch or calcium hydrogen phosphate4.1UN2907II4.1IB6, IP2, N85None212None15 kg50 kgE28, 36
Isosorbide-5-mononitrate4.1UN3251III4.166, IB8151213240ForbiddenForbiddenD12
Isothiocyanic acidForbidden
Jet fuel, see Fuel aviation, turbine engine
DJet perforating guns, charged oil well, with detonator1.1DNA0124II1.1D55, 56None62NoneForbiddenForbidden07
DJet perforating guns, charged oil well, with detonator1.4DNA0494II1.4D55, 56None62NoneForbiddenForbidden06
Jet perforating guns, charged oil well, without detonator1.1DUN0124II1.1D55None62NoneForbiddenForbidden07
Jet perforating guns, charged, oil well, without detonator1.4DUN0494II1.4D55, 114None62NoneForbidden300 kg06
Jet perforators, see Charges, shaped, etc
Jet tappers, without detonator, see Charges, shaped, etc
Jet thrust igniters, for rocket motors or Jato, see Igniters
Jet thrust unit (Jato), see Rocket motors
Kerosene3UN1223III3144, B1, IB3, T2, TP215020324260 L220 LA
GKetones, liquid, n.o.s.3UN1224I3T11, TP1, TP8, TP27None2012431 L30 LE
II3IB2, T7, TP1, TP8, TP281502022425 L60 LB
III3B1, IB3, T4, TP1, TP2915020324260 L220 LA
Krypton, compressed2.2UN10562.2306302None75 kg150 kgA
Krypton, refrigerated liquid (cryogenic liquid)2.2UN19702.2T75, TP5320NoneNone50 kg500 kgB
Lacquer base or lacquer chips, nitrocellulose, dry, see Nitrocellulose, etc. (UN 2557)
Lacquer base or lacquer chips, plastic, wet with alcohol or solvent, see Nitrocellulose (UN2059, UN2555, UN2556, UN2557) or Paint etc.(UN1263)
Lead acetate6.1UN1616III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Lead arsenates6.1UN1617II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Lead arsenites6.1UN1618II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Lead azide (dry)Forbidden
Lead azide, wetted with not less than 20 percent water or mixture of alcohol and water, by mass1.1AUN0129II1.1A111, 117None62NoneForbiddenForbidden12
Lead compounds, soluble, n.o.s.6.1UN2291III6.1138, IB8, IP3, T1, TP33153213240100 kg200 kgA
Lead cyanide6.1UN1620II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA52
Lead dioxide5.1UN1872III5.1A1, IB8, IP3, T1, TP3315221324025 kg100 kgA
Lead dross, see Lead sulfate, with more than 3 percent free acid
Lead nitrate5.1UN1469II5.1, 6.1IB8, IP2, IP4, T3, TP331522122425 kg25 kgA
Lead nitroresorcinate (dry)Forbidden
Lead perchlorate, solid5.1UN1470II5.1, 6.1IB6, IP2, T3, TP331522122425 kg25 kgA56, 58
Lead perchlorate, solution5.1UN3408III5.1, 6.1IB2, T4, TP11522032422.5 L30 LA56, 58
II5.1, 6.1IB2, T4, TP11522022431 L5 LA56, 58
Lead peroxide, see Lead dioxide
Lead phosphite, dibasic4.1UN2989II4.1IB8, IP2, IP4, T3, TP33None2122405 kg25 kgB34
III4.1IB8, IP3, T1, TP3315121324015 kg50 kgB34
Lead picrate (dry)Forbidden
Lead styphnate (dry)Forbidden
Lead styphnate, wetted or Lead trinitroresorcinate, wetted with not less than 20 percent water or mixture of alcohol and water, by mass1.1AUN0130II1.1A111, 117None62NoneForbiddenForbidden12
Lead sulfate with more than 3 percent free acid8UN1794II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA
Lead trinitroresorcinate, see Lead styphnate, etc
Life-saving appliances, not self inflating containing dangerous goods as equipment9UN3072NoneNone219NoneNo limitNo limitA
Life-saving appliances, self inflating9UN2990NoneNone219NoneNo limitNo limitA
Lighter replacement cartridges containing liquefied petroleum gases (and similar devices, each not exceeding 65 grams), see Lighters or lighter refills etc. containing flammable gas
Lighters, fuse1.4SUN0131II1.4SNone62None25 kg100 kg05
Lighters or Lighter refills containing flammable gas2.1UN10572.1N10None21, 308None1 kg15 kgB40
Lime, unslaked, see Calcium oxide
GLiquefied gas, flammable, n.o.s.2.1UN31612.1T50306304314, 315Forbidden150 kgD40
GLiquefied gas, n.o.s.2.2UN31632.2T50306304314, 31575 kg150 kgA
GLiquefied gas, oxidizing, n.o.s.2.2UN31572.2, 5.1A14306304314, 31575 kg150 kgD
G ILiquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone A2.3UN33082.3, 81None192245ForbiddenForbiddenD40
G ILiquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone B2.3UN33082.3, 82, B9, B14None304314, 315ForbiddenForbiddenD40
G ILiquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone C2.3UN33082.3, 83, B14None304314, 315ForbiddenForbiddenD40
G ILiquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone D2.3UN33082.3, 84None304314, 315ForbiddenForbiddenD40
G ILiquefied gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone A2.3UN33092.3, 2.1, 81None192245ForbiddenForbiddenD17, 40
G ILiquefied gas toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone B2.3UN33092.3, 2.1, 82, B9, B14None304314, 315ForbiddenForbiddenD17, 40
G ILiquefied gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone C2.3UN33092.3, 2.1, 83, B14None304314, 315ForbiddenForbiddenD17, 40
G ILiquefied gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone D2.3UN33092.3, 2.1, 84None304314, 315ForbiddenForbiddenD17, 40
GLiquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone A2.3UN31602.3, 2.11None192245ForbiddenForbiddenD40
GLiquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone B2.3UN31602.3, 2.12, B9, B14None304314, 315ForbiddenForbiddenD40
GLiquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone C2.3UN31602.3, 2.13, B14None304314, 315ForbiddenForbiddenD40
GLiquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone D2.3UN31602.3, 2.14None304314, 315ForbiddenForbiddenD40
GLiquefied gas, toxic, n.o.s. Inhalation Hazard Zone A2.3UN31622.31None192245ForbiddenForbiddenD40
GLiquefied gas, toxic, n.o.s. Inhalation Hazard Zone B2.3UN31622.32, B9, B14None304314, 315ForbiddenForbiddenD40
GLiquefied gas, toxic, n.o.s. Inhalation Hazard Zone C2.3UN31622.33, B14None304314, 315ForbiddenForbiddenD40
GLiquefied gas, toxic, n.o.s. Inhalation Hazard Zone D2.3UN31622.34None304314, 315ForbiddenForbiddenD40
G ILiquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone A2.3UN33102.3, 5.1, 81None192245ForbiddenForbiddenD40, 89, 90
G ILiquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone B2.3UN33102.3, 5.1, 82, B9, B14None304314, 315ForbiddenForbiddenD40, 89, 90
G ILiquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone C2.3UN33102.3, 5.1, 83, B14None304314, 315ForbiddenForbiddenD40, 89, 90
G ILiquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone D2.3UN33102.3, 5.1, 84None304314, 315ForbiddenForbiddenD40, 89, 90
GLiquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone A2.3UN33072.3, 5.11None192245ForbiddenForbiddenD40
GLiquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone B2.3UN33072.3, 5.12, B9, B14None304314, 315ForbiddenForbiddenD40
GLiquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone C2.3UN33072.3, 5.13, B14None304314, 315ForbiddenForbiddenD40
GLiquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone D2.3UN33072.3, 5.14None304314, 315ForbiddenForbiddenD40
Liquefied gases, non-flammable charged with nitrogen, carbon dioxide or air2.2UN10582.2306304None75 kg150 kgA
Liquefied hydrocarbon gas, see Hydrocarbon gas mixture, liquefied, n.o.s.
Liquefied natural gas, see Methane, etc. (UN 1972)
Liquefied petroleum gas see Petroleum gases, liquefied
Lithium4.3UN1415I4.3A7, A19, IB4, IP1, N45None211244Forbidden15 kgE52
Lithium acetylide ethylenediamine complex, see Water reactive solid etc
Lithium alkyls, liquid4.2UN2445I4.2, 4.3B11, T21, TP2, TP7None181244ForbiddenForbiddenD
Lithium alkyls, solid4.2UN3433I4.2, 4.3B11, T21, TP7, TP33None181244ForbiddenForbiddenD
Lithium aluminum hydride4.3UN1410I4.3A19None211242Forbidden15 kgE52
Lithium aluminum hydride, ethereal4.3UN1411I4.3, 3A2, A3, A11, N34None201244Forbidden1 LD40
Lithium batteries, contained in equipment9UN3091II929, A54, A55, A102, A104185185None5 kg5 kgA
Lithium batteries packed with equipment9UN3091II929, A54, A55, A101, A103185185None5 kg gross35 kg grossA
Lithium battery9UN3090II929, A54, A55, A100185185None5 kg gross35 kg grossA
Lithium borohydride4.3UN1413I4.3A19, N40None211242Forbidden15 kgE52
Lithium ferrosilicon4.3UN2830II4.3A19, IB7, IP2, T3, TP3315121224115 kg50 kgE40, 85, 103
Lithium hydride4.3UN1414I4.3A19, N40None211242Forbidden15 kgE52
Lithium hydride, fused solid4.3UN2805II4.3A8, A19, A20, IB4, T3, TP3315121224115 kg50 kgE52
Lithium hydroxide8UN2680II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA
Lithium hydroxide, solution8UN2679II8B2, IB2, T7, TP21542022421 L30 LA29
III8IB3, T4, TP21542032415 L60 LA29, 96
Lithium hypochlorite, dry with more than 39% available chlorine (8.8% available oxygen) or Lithium hypochlorite mixtures, dry with more than 39% available chlorine (8.8% available oxygen)5.1UN1471II5.1A9, IB8, IP2, IP4, N341522122405 kg25 kgA4, 48, 52, 56, 58, 69, 106, 116
Lithium in cartridges, see Lithium
Lithium nitrate5.1UN2722III5.1A1, IB8, IP3, T1, TP3315221324025 kg100 kgA
Lithium nitride4.3UN2806I4.3A19, IB4, IP1, N40None211242Forbidden15 kgE
Lithium peroxide5.1UN1472II5.1A9, IB6, IP2, N34, T3, TP33152212None5 kg25 kgA13, 52, 66, 75
Lithium silicon4.3UN1417II4.3A19, A20, IB7, IP2, T3, TP3315121224115 kg50 kgA85, 103
LNG, see Methane etc. (UN 1972)
London purple6.1UN1621II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
LPG, see Petroleum gases, liquefied
Lye, see Sodium hydroxide, solutions
Magnesium alkyls4.2UN3053I4.2, 4.3B11, T21, TP2, TP7None181244ForbiddenForbiddenD18
Magnesium aluminum phosphide4.3UN1419I4.3, 6.1A19, N34, N40None211242Forbidden15 kgE40, 52, 85
+Magnesium arsenate6.1UN1622II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Magnesium bisulfite solution, see Bisulfites, aqueous solutions, n.o.s.
Magnesium bromate5.1UN1473II5.1A1, IB8, IP4, T3, TP331522122425 kg25 kgA56, 58
Magnesium chlorate5.1UN2723II5.1IB8, IP2, IP4, T3, TP331522122425 kg25 kgA56, 58
Magnesium diamide4.2UN2004II4.2A8, A19, A20, IB6, T3, TP33None21224115 kg50 kgC
Magnesium diphenyl4.2UN2005I4.2T21, TP7, TP33None187244ForbiddenForbiddenC
Magnesium dross, wet or hotForbidden
Magnesium fluorosilicate6.1UN2853III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA52
Magnesium granules, coated, particle size not less than 149 microns4.3UN2950III4.3A1, A19, IB8, IP4, T1, TP3315121324025 kg100 kgA52
Magnesium hydride4.3UN2010I4.3A19, N40None211242Forbidden15 kgE52
Magnesium or Magnesium alloys with more than 50 percent magnesium in pellets, turnings or ribbons4.1UN1869III4.1A1, IB8, IP3, T1, TP3315121324025 kg100 kgA39, 52, 53, 74, 101
Magnesium nitrate5.1UN1474III5.1A1, IB8, IP3, T1, TP3315221324025 kg100 kgA
Magnesium perchlorate5.1UN1475II5.1IB6, IP2, T3, TP331522122425 kg25 kgA56, 58
Magnesium peroxide5.1UN1476II5.1IB6, IP2, T3, TP331522122425 kg25 kgA13, 52, 66, 75
Magnesium phosphide4.3UN2011I4.3, 6.1A19, N40None211NoneForbidden15 kgE40, 52, 85
Magnesium, powder or Magnesium alloys, powder4.3UN1418I4.3, 4.2A19, B56None211244Forbidden15 kgA39, 52
II4.3, 4.2A19, B56, IB5, IP2, T3, TP33None21224115 kg50 kgA39, 52
III4.3, 4.2A19, B56, IB8, IP4, T1, TP33None21324125 kg100 kgA39, 52
Magnesium scrap, see Magnesium, etc. (UN 1869)
Magnesium silicide4.3UN2624II4.3A19, A20, IB7, IP2, T3, TP3315121224115 kg50 kgB85, 103
Magnetized material, see § 173.21
Maleic anhydride8UN2215III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Maleic anhydride, molten8UN2215III8T4, TP3None213240ForbiddenForbiddenA
Malononitrile6.1UN2647II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA12
Mancozeb (manganese ethylenebisdithiocarbamate complex with zinc) see Maneb
Maneb or Maneb preparations with not less than 60 percent maneb4.2UN2210III4.2, 4.357, A1, A19, IB6, T1, TP33None21324225 kg100 kgA34
Maneb stabilized or Maneb preparations, stabilized against self-heating4.3UN2968III4.354, A1, A19, IB8, IP4, T1, TP3315121324225 kg100 kgB34, 52
Manganese nitrate5.1UN2724III5.1A1, IB8, IP3, T1, TP3315221324025 kg100 kgA
Manganese resinate4.1UN1330III4.1A1, IB6, T1, TP3315121324025 kg100 kgA
Mannitan tetranitrateForbidden
Mannitol hexanitrate (dry)Forbidden
Mannitol hexanitrate, wetted or Nitromannite, wetted with not less than 40 percent water, or mixture of alcohol and water, by mass1.1DUN0133II1.1D121None62NoneForbiddenForbidden10
Marine pollutants, liquid or solid, n.o.s., see Environmentally hazardous substances, liquid or solid, n.o.s.
Matches, block, see Matches, 'strike anywhere'
Matches, fusee4.1UN2254III4.1186186NoneForbiddenForbiddenA
Matches, safety (book, card or strike on box)4.1UN1944III4.1186186None25 kg100 kgA
Matches, strike anywhere4.1UN1331III4.1186186NoneForbiddenForbiddenB
Matches, wax, Vesta4.1UN1945III4.1186186None25 kg100 kgB
Matting acid, see Sulfuric acid
Medicine, liquid, flammable, toxic, n.o.s.3UN3248II3, 6.136, IB2150202None1 L5 LB40
III3, 6.136, IB3150203None5 L5 LA
Medicine, liquid, toxic, n.o.s.6.1UN1851II6.1361532022435 L5 LC40
III6.1361532032415 L5 LC40
Medicine, solid, toxic, n.o.s.6.1UN3249II6.136, T3, TP33153212None5 kg5 kgC40
III6.136, T1, TP33153213None5 kg5 kgC40
Memtetrahydrophthalic anhydride, see Corrosive liquids, n.o.s.
Mercaptans, liquid, flammable, n.o.s. or Mercaptan mixture, liquid, flammable, n.o.s.3UN3336I3T11, TP21502012431 L30 LE95
II3IB2, T7, TP1, TP8, TP281502022425 L60 LB95
III3B1, B52, IB3, T4, TP1, TP2915020324160 L220 LB95
Mercaptans, liquid, flammable, toxic, n.o.s. or Mercaptan mixtures, liquid, flammable, toxic, n.o.s.3UN1228II3, 6.1IB2, T11, TP2, TP27None202243Forbidden60 LB40, 95
III3, 6.1A6, B1, IB3, T7, TP1, TP281502032425 L220 LA40, 95
Mercaptans, liquid, toxic, flammable, n.o.s. or Mercaptan mixtures, liquid, toxic, flammable, n.o.s. , flash point not less than 23 degrees C6.1UN3071II6.1, 3A6, IB2, T11, TP2, TP13, TP271532022435 L60 LC40, 121
5-Mercaptotetrazol-1-acetic acid1.4CUN0448II1.4CNone62NoneForbidden75 kg09
Mercuric arsenate6.1UN1623II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mercuric chloride6.1UN1624II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mercuric compounds, see Mercury compounds, etc
Mercuric nitrate6.1UN1625II6.1IB8, IP2, IP4, N73, T3, TP3315321224225 kg100 kgA
+Mercuric potassium cyanide6.1UN1626I6.1IB7, IP1, N74, N75, T6, TP33None2112425 kg50 kgA52
Mercuric sulfocyanate, see Mercury thiocyanate
Mercurol, see Mercury nucleate
Mercurous azideForbidden
Mercurous compounds, see Mercury compounds, etc
Mercurous nitrate6.1UN1627II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
A WMercury8UN2809III816416424035 kg35 kgB40, 97
Mercury acetate6.1UN1629II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mercury acetylideForbidden
Mercury ammonium chloride6.1UN1630II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mercury based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C3UN2778I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LB40
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40
Mercury based pesticides, liquid, toxic6.1UN3012I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1IB3, T7, TP2, TP2815320324160 L220 LA40
Mercury based pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN3011I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3IB3, T7, TP2, TP2815320324260 L220 LA40
Mercury based pesticides, solid, toxic6.1UN2777I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Mercury benzoate6.1UN1631II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mercury bromides6.1UN1634II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mercury compounds, liquid, n.o.s.6.1UN2024I6.1None2012431 L30 LB40
II6.1IB21532022435 L60 LB40
III6.1IB315320324160 L220 LB40
Mercury compounds, solid, n.o.s.6.1UN2025I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
AMercury contained in manufactured articles8UN2809III8None164NoneNo limitNo limitB40, 97
Mercury cyanide6.1UN1636II6.1IB8, IP2, IP4, N74, N75, T3, TP3315321224225 kg100 kgA52
Mercury fulminate, wetted with not less than 20 percent water, or mixture of alcohol and water, by mass1.1AUN0135II1.1A111, 117None62NoneForbiddenForbidden12
Mercury gluconate6.1UN1637II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mercury iodide6.1UN1638II6.1IB2, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mercury iodide aquabasic ammonobasic (Iodide of Millon's base)Forbidden
Mercury nitrideForbidden
Mercury nucleate6.1UN1639II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mercury oleate6.1UN1640II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mercury oxide6.1UN1641II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mercury oxycyanideForbidden
Mercury oxycyanide, desensitized6.1UN1642II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA52, 91
Mercury potassium iodide6.1UN1643II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mercury salicylate6.1UN1644II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
+Mercury sulfates6.1UN1645II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mercury thiocyanate6.1UN1646II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Mesityl oxide3UN1229III3B1, IB3, T2, TP115020324260 L220 LA
GMetal carbonyls, liquid, n.o.s.6.1UN3281I6.15, T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP271532022435 L60 LB40
III6.1IB3, T7, TP1, TP2815320324160 L220 LA40
GMetal carbonyls, solid, n.o.s.6.1UN3466I6.1IB7, IP1, T6, TP33None2112425 kg50 kgD40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgB40
Metal catalyst, dry4.2UN2881I4.2N34, T21, TP7, TP33None187NoneForbiddenForbiddenC
II4.2IB6, IP2, N34, T3, TP33None187242Forbidden50 kgC
III4.2IB8, IP3, N34, T1, TP33None18724125 kg100 kgC
Metal catalyst, wetted with a visible excess of liquid4.2UN1378II4.2A2, A8, IB1, N34, T3, TP33None212NoneForbidden50 kgC
Metal hydrides, flammable, n.o.s.4.1UN3182II4.1A1, IB4, T3, TP3315121224015 kg50 kgE
III4.1A1, IB4, T1, TP3315121324025 kg100 kgE
Metal hydrides, water reactive, n.o.s.4.3UN1409I4.3A19, N34, N40None211242Forbidden15 kgD52
II4.3A19, IB4, N34, N40, T3, TP3315121224215 kg50 kgD52
Metal powder, self-heating, n.o.s.4.2UN3189II4.2IB6, IP2, T3, TP33None21224115 kg50 kgC
III4.2IB8, IP3, T1, TP33None21324125 kg100 kgC
Metal powders, flammable, n.o.s.4.1UN3089II4.1IB8, IP2, IP4, T3, TP3315121224015 kg50 kgB
III4.1IB6, T1, TP3315121324025 kg100 kgB
Metal salts of methyl nitramine (dry)Forbidden
GMetal salts of organic compounds, flammable, n.o.s.4.1UN3181II4.1A1, IB8, IP2, IP4, T3, TP3315121224015 kg50 kgB40
III4.1A1, IB8, IP3, T1, TP3315121324025 kg100 kgB40
Metaldehyde4.1UN1332III4.1A1, IB8, IP3, T1, TP3315121324025 kg100 kgA
GMetallic substance, water-reactive, n.o.s.4.3UN3208I4.3A7, IB4None211242Forbidden15 kgE40
II4.3A7, IB7, IP2, T3, TP3315121224215 kg50 kgE40
III4.3A7, IB8, IP4, T1, TP3315121324125 kg100 kgE40
GMetallic substance, water-reactive, self-heating, n.o.s.4.3UN3209I4.3, 4.2A7None211242Forbidden15 kgE40
II4.3, 4.2A7, IB5, IP2, T3, TP33None21224215 kg50 kgE40
III4.3, 4.2A7, IB8, IP4, T1, TP33None21324225 kg100 kgE40
Methacrylaldehyde, stabilized3UN2396II3, 6.145, IB2, T7, TP1, TP131502022431 L60 LE40
Methacrylic acid, stabilized8UN2531II8IB2, T7, TP1, TP18, TP301542022421 L30 LC40
+Methacrylonitrile, stabilized3UN3079I3, 6.12, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD12, 40, 48
Methallyl alcohol3UN2614III3B1, IB3, T2, TP115020324260 L220 LA
Methane and hydrogen, mixtures, see Hydrogen and methane, mixtures, etc
Methane, compressed or Natural gas, compressed (with high methane content)2.1UN19712.1306302302Forbidden150 kgE40
Methane, refrigerated liquid (cryogenic liquid)or Natural gas, refrigerated liquid (cryogenic liquid), with high methane content)2.1UN19722.1T75, TP5NoneNone318ForbiddenForbiddenD40
Methanesulfonyl chloride6.1UN3246I6.1, 82, B9, B14, B32, B74, T20, TP2, TP12, TP13, TP38, TP45None227244ForbiddenForbiddenD40
+ IMethanol3UN1230II3, 6.1IB2, T7, TP21502022421 L60 LB40
DMethanol3UN1230II3IB2, T7, TP21502022421 L60 LB40
Methazoic acidForbidden
4-Methoxy-4-methylpentan-2-one3UN2293III3B1, IB3, T2, TP115020324260 L220 LA
1-Methoxy-2-propanol3UN3092III3B1, IB3, T2, TP115020324260 L220 LA
+Methoxymethyl isocyanate3UN2605I3, 6.11, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44None226244ForbiddenForbiddenD40
Methyl acetate3UN1231II3IB2, T4, TP11502022425 L60 LB
Methyl acetylene and propadiene mixtures, stabilized2.1UN10602.1T50306304314, 315Forbidden150 kgB40
Methyl acrylate, stabilized3UN1919II3IB2, T4, TP1, TP131502022425 L60 LB
Methyl alcohol, see Methanol
Methyl allyl chloride3UN2554II3IB2, T4, TP1, TP131502022425 L60 LE
Methyl amyl ketone, see Amyl methyl ketone
Methyl bromide2.3UN10622.33, B14, T50None193314, 315ForbiddenForbiddenD40
Methyl bromide and chloropicrin mixtures with more than 2 percent chloropicrin, see Chloropicrin and methyl bromide mixtures
Methyl bromide and chloropicrin mixtures with not more than 2 percent chloropicrin, see Methyl bromide
Methyl bromide and ethylene dibromide mixtures, liquid6.1UN1647I6.12, B9, B14, B32, B74, N65, T20, TP2, TP13, TP38, TP44None227244ForbiddenForbiddenC40
Methyl bromoacetate6.1UN2643II6.1IB2, T7, TP21532022435 L60 LD40
2-Methlybutanal3UN3371II3IB2, T4, TP11502022425 L60 LB
2-Methyl-1-butene3UN2459I3T11, TP2None2012431 L30 LE
2-Methyl-2-butene3UN2460II3IB2, IP8, T7, TP1None2022425 L60 LE
3-Methyl-1-butene3UN2561I3T11, TP2None2012431 L30 LE
Methyl tert-butyl ether3UN2398II3IB2, T7, TP11502022425 L60 LE
Methyl butyrate3UN1237II3IB2, T4, TP11502022425 L60 LB
Methyl chloride, or Refrigerant gas R 402.1UN10632.1T50306304314, 3155 kg100 kgD40
Methyl chloride and chloropicrin mixtures, see Chloropicrin and methyl chloride mixtures
Methyl chloride and methylene chloride mixtures2.1UN19122.1T50306304314, 315Forbidden150 kgD40
Methyl chloroacetate6.1UN2295I6.1, 3T14, TP2, TP13None2012431 L30 LD
Methyl chlorocarbonate, see Methyl chloroformate
Methyl chloroform, see 1,1,1-Trichloroethane
Methyl chloroformate6.1UN1238I6.1, 3, 81, B9, B14, B30, B72, N34, T22, TP2, TP13, TP38, TP44None226244ForbiddenForbiddenD21, 40, 100
Methyl chloromethyl ether6.1UN1239I6.1, 31, B9, B14, B30, B72, T22, TP2, TP38, TP44None226244ForbiddenForbiddenD40
Methyl 2-chloropropionate3UN2933III3B1, IB3, T2, TP115020324260 L220 LA
Methyl dichloroacetate6.1UN2299III6.1IB3, T4, TP115320324160 L220 LA
Methyl ethyl ether, see Ethyl methyl ether
Methyl ethyl ketone, see Ethyl methyl ketone
Methyl ethyl ketone peroxide, in solution with more than 9 percent by mass active oxygenForbidden
2-Methyl-5-ethylpyridine6.1UN2300III6.1IB3, T4, TP115320324160 L220 LA
Methyl fluoride, or Refrigerant gas R 412.1UN24542.1306304314, 315Forbidden150 kgE40
Methyl formate3UN1243I3T11, TP21502012431 L30 LE
2-Methyl-2-heptanethiol6.1UN3023I6.1, 32, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40, 102
Methyl iodide6.1UN2644I6.12, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenA12, 40
Methyl isobutyl carbinol3UN2053III3B1, IB3, T2, TP115020324260 L220 LA
Methyl isobutyl ketone3UN1245II3IB2, T4, TP11502022425 L60 LB
Methyl isobutyl ketone peroxide, in solution with more than 9 percent by mass active oxygenForbidden
Methyl isocyanate6.1UN2480I6.1, 31, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44None226244ForbiddenForbiddenD40, 52
Methyl isopropenyl ketone, stabilized3UN1246II3IB2, T4, TP11502022425 L60 LB
Methyl isothiocyanate6.1UN2477I6.1, 32, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenA
Methyl isovalerate3UN2400II3IB2, T4, TP11502022425 L60 LB
Methyl magnesium bromide, in ethyl ether4.3UN1928I4.3, 3None201243Forbidden1 LD
Methyl mercaptan2.3UN10642.3, 2.13, B7, B9, B14, T50None304314, 315ForbiddenForbiddenD40
Methyl mercaptopropionaldehyde, see Thia-4-pentanal
Methyl methacrylate monomer, stabilized3UN1247II3IB2, T4, TP11502022425 L60 LB40
Methyl nitramine (dry)Forbidden
Methyl nitrateForbidden
Methyl nitriteForbidden
Methyl norbornene dicarboxylic anhydride, see Corrosive liquids, n.o.s.
Methyl orthosilicate6.1UN2606I6.1, 32, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenE40
DMethyl phosphonic dichloride6.1NA9206I6.1, 82, B9, B14, B32, B74, N34, N43, T20, TP4, TP12, TP13, TP38, TP45None227244ForbiddenForbiddenC
Methyl phosphonothioic dichloride, anhydrous, see Corrosive liquid, n.o.s.
DMethyl phosphonous dichloride, pyrophoric liquid6.1NA2845I6.1, 4.22, B9, B14, B16, B32, B74, T20, TP4, TP12, TP13, TP38, TP45None227244ForbiddenForbiddenD18
Methyl picric acid (heavy metal salts of)Forbidden
Methyl propionate3UN1248II3IB2, T4, TP11502022425 L60 LB
Methyl propyl ether3UN2612II3IB2, IP8, T7, TP21502022425 L60 LE40
Methyl propyl ketone3UN1249II3IB2, T4, TP11502022425 L60 LB
Methyl sulfate, see Dimethyl sulfate
Methyl sulfide, see Dimethyl sulfide
Methyl trichloroacetate6.1UN2533III6.1IB3, T4, TP115320324160 L220 LA
Methyl trimethylol methane trinitrateForbidden
Methyl vinyl ketone, stabilized6.1UN1251I6.1, 3, 81, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44None226244ForbiddenForbiddenB40
Methylal3UN1234II3IB2, IP8, T7, TP2None2022425 L60 LE
Methylamine, anhydrous2.1UN10612.1T50306304314, 315Forbidden150 kgB40
Methylamine, aqueous solution3UN1235II3, 8B1, IB2, T7, TP11502022431 L5 LE135
Methylamine dinitramine and dry salts thereofForbidden
Methylamine nitroformForbidden
Methylamine perchlorate (dry)Forbidden
Methylamyl acetate3UN1233III3B1, IB3, T2, TP115020324260 L220 LA
N-Methylaniline6.1UN2294III6.1IB3, T4, TP115320324160 L220 LA
alpha-Methylbenzyl alcohol, liquid6.1UN2937III6.1IB3, T4, TP115320324160 L220 LA
alpha-Methylbenzyl alcohol, solid6.1UN3438III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
3-Methylbutan-2-one3UN2397II3IB2, T4, TP11502022425 L60 LB
N-Methylbutylamine3UN2945II3, 8IB2, T7, TP11502022431 L5 LB40
Methylchlorosilane2.3UN25342.3, 2.1, 82, B9, B14, N34None226314, 315ForbiddenForbiddenD17, 40
Methylcyclohexane3UN2296II3B1, IB2, T4, TP11502022425 L60 LB
Methylcyclohexanols, flammable3UN2617III3B1, IB3, T2, TP115020324260 L220 LA
Methylcyclohexanone3UN2297III3B1, IB3, T2, TP115020324260 L220 LA
Methylcyclopentane3UN2298II3IB2, T4, TP11502022425 L60 LB
DMethyldichloroarsine6.1NA1556I6.12, T20, TP4, TP12, TP13, TP38, TP45None192NoneForbiddenForbiddenD40
Methyldichlorosilane4.3UN1242I4.3, 8, 3A2, A3, A7, B6, B77, N34, T10, TP2, TP7, TP13None201243Forbidden1 LD21, 28, 40, 49, 100
Methylene chloride, see Dichloromethane
Methylene glycol dinitrateForbidden
2-Methylfuran3UN2301II3IB2, T4, TP11502022425 L60 LE
a-Methylglucoside tetranitrateForbidden
a-Methylglycerol trinitrateForbidden
5-Methylhexan-2-one3UN2302III3B1, IB3, T2, TP115020324260 L220 LA
Methylhydrazine6.1UN1244I6.1, 3, 81, B7, B9, B14, B30, B72, B77, N34, T22, TP2, TP13, TP38, TP44None226244ForbiddenForbiddenD21, 40, 49, 100
4-Methylmorpholine or n-methylmorpholine3UN2535II3, 8B6, IB2, T7, TP11502022431 L5 LB40
Methylpentadienes3UN2461II3IB2, T4, TP11502022425 L60 LE
2-Methylpentan-2-ol3UN2560III3B1, IB3, T2, TP115020324260 L220 LA
Methylpentanes, see Hexanes
Methylphenyldichlorosilane8UN2437II8IB2, T7, TP2, TP131542022421 L30 LC40
1-Methylpiperidine3UN2399II3, 8IB2, T7, TP11502022431 L5 LB
Methyltetrahydrofuran3UN2536II3IB2, T4, TP11502022425 L60 LB
Methyltrichlorosilane3UN1250I3, 8A7, B6, B77, N34, T11, TP2, TP13None201243Forbidden2.5 LB40
alpha-Methylvaleraldehyde3UN2367II3B1, IB2, T4, TP11502022425 L60 LB
Mine rescue equipment containing carbon dioxide, see Carbon dioxide
Mines with bursting charge1.1FUN0136II1.1F62NoneForbiddenForbidden08
Mines with bursting charge1.1DUN0137II1.1D62NoneForbiddenForbidden03
Mines with bursting charge1.2DUN0138II1.2D62NoneForbiddenForbidden03
Mines with bursting charge1.2FUN0294II1.2F62NoneForbiddenForbidden08
Mixed acid, see Nitrating acid, mixtures etc
Mobility aids, see Battery powered equipment or Battery powered vehicle'
DModel rocket motor1.4CNA0276II1.4C51None62NoneForbidden75 kg06
DModel rocket motor1.4SNA0323II1.4S51None62None25 kg100 kg05
Molybdenum pentachloride8UN2508III8IB8, IP3, T1, TP3315421324025 kg100 kgC40
Monochloroacetone (unstabilized)Forbidden
Monochloroethylene, see Vinyl chloride, stabilized
Monoethanolamine, see Ethanolamine, solutions
Monoethylamine, see Ethylamine
Morpholine8UN2054I8, 3A6, T10, TP2None2012430.5 L2.5 LA
Morpholine, aqueous, mixture, see Corrosive liquids, n.o.s.
Motor fuel anti-knock compounds see Motor fuel anti-knock mixtures
+Motor fuel anti-knock mixtures6.1UN1649I6.1, 314, 151, B9, B90, T14, TP2, TP13None201244Forbidden30 LD25, 40
Motor spirit, see Gasoline
Muriatic acid, see Hydrochloric acid
Musk xylene, see 5-tert-Butyl-2,4,6-trinitro-m-xylene
Naphtha see Petroleum distillates n.o.s.
Naphthalene, crude or Naphthalene, refined4.1UN1334III4.1A1, IB8, IP3, T1, TP3315121324025 kg100 kgA
Naphthalene diozonideForbidden
beta-Naphthylamine6.1UN1650II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
beta-Naphthylamine, solid6.1UN1650II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
beta-Naphthylamine solution6.1UN3411II6.1IB2, T7, TP21532022435 L60 LA
III6.1IB2, T7, TP215320324160 L220 LA
alpha-Naphthylamine6.1UN2077III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Naphthalene, molten4.1UN2304III4.1IB1, T1, TP3151213241ForbiddenForbiddenC
NaphthylamineperchlorateForbidden
Naphthylthiourea6.1UN1651II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Naphthylurea6.1UN1652II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Natural gases (with high methane content), see Methane, etc. (UN 1971, UN 1972)
Neohexane, see Hexanes
Neon, compressed2.2UN10652.230630230275 kg150 kgA
Neon, refrigerated liquid (cryogenic liquid)2.2UN19132.2T75, TP5320316None50 kg500 kgB
New explosive or explosive device, see §§ 173.51 and 173.56
Nickel carbonyl6.1UN1259I6.1, 31None198NoneForbiddenForbiddenD18, 40
Nickel cyanide6.1UN1653II6.1IB8, IP2, IP4, N74, N75, T3, TP3315321224225 kg100 kgA52
Nickel nitrate5.1UN2725III5.1A1, IB8, IP3, T1, TP3315221324025 kg100 kgA
Nickel nitrite5.1UN2726III5.1A1, IB8, IP3, T1, TP3315221324025 kg100 kgA56, 58
Nickel picrateForbidden
Nicotine6.1UN1654II6.1IB21532022435 L60 LA
Nicotine compounds, liquid, n.o.s. or Nicotine preparations, liquid, n.o.s.6.1UN3144I6.1A4None2012431 L30 LB40
II6.1IB2, T11, TP2, TP271532022435 L60 LB40
III6.1IB3, T7, TP1, TP2815320324160 L220 LB40
Nicotine compounds, solid, n.o.s. or Nicotine preparations, solid, n.o.s.6.1UN1655I6.1IB7, IP1, T6, TP33None2112425 kg50 kgB
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Nicotine hydrochloride liquid or solution6.1UN1656II6.1IB21532022435 L60 LA
III6.1IB315320324160 L220 LA
Nicotine hydrochloride, solid6.1UN3444II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Nicotine salicylate6.1UN1657II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Nicotine sulfate solution6.1UN1658II6.1IB2, T7, TP21532022435 L60 LA
III6.1IB3, T7, TP215320324160 L220 LA
Nicotine sulphate, solid6.1UN3445II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Nicotine tartrate6.1UN1659II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Nitrated paper (unstable)Forbidden
Nitrates, inorganic, aqueous solution, n.o.s.5.1UN3218II5.158, IB2, T4, TP11522022421 L5 LB56, 58, 133
III5.158, IB2, T4, TP11522032412.5 L30 LB56, 58, 133
Nitrates, inorganic, n.o.s.5.1UN1477II5.1IB8, IP2, IP4, T3, TP331522122405 kg25 kgA56, 58
III5.1IB8, IP3, T1, TP3315221324025 kg100 kgA56, 58
Nitrates of diazonium compoundsForbidden
Nitrating acid mixtures, spent with more than 50 percent nitric acid8UN1826I8, 5.1A7, T10, TP2, TP12, TP13None158243Forbidden2.5 LD40, 66
Nitrating acid mixtures spent with not more than 50 percent nitric acid8UN1826II8A7, B2, IB2, T8, TP2, TP12None158242Forbidden30 LD40
Nitrating acid mixtures with more than 50 percent nitric acid8UN1796I8, 5.1A7, T10, TP2, TP12, TP13None158243Forbidden2.5 LD40, 66
Nitrating acid mixtures with not more than 50 percent nitric acid8UN1796II8A7, B2, IB2, T8, TP2, TP12, TP13None158242Forbidden30 LD40
Nitric acid other than red fuming, with more than 70 percent nitric acid8UN2031I8, 5.1A3, B47, B53, T10, TP2, TP12, TP13None158243Forbidden2.5 LD44, 66, 89, 90, 110, 111
Nitric acid other than red fuming, with not more than 70 percent nitric acid8UN2031II8A6, B2, B47, B53, IB2, T8, TP2, TP12None158242Forbidden30 LD44, 66, 89, 90, 110, 111
+Nitric acid, red fuming8UN2032I8, 5.1, 6.12, B9, B32, B74, T20, TP2, TP12, TP13, TP38, TP45None227244ForbiddenForbiddenD40, 66, 74, 89, 90
Nitric oxide, compressed2.3UN16602.3, 5.1, 81, B37, B46, B50, B60, B77None337NoneForbiddenForbiddenD40, 89, 90
Nitric oxide and dinitrogen tetroxide mixtures or Nitric oxide and nitrogen dioxide mixtures2.3UN19752.3, 5.1, 81, B7, B9, B14, B45, B46, B61, B66, B67, B77None337NoneForbiddenForbiddenD40, 89, 90
GNitriles, flammable, toxic, n.o.s.3UN3273I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LE40, 52
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40, 52
GNitriles, toxic, flammable, n.o.s.6.1UN3275I6.1, 35, T14, TP2, TP13, TP27None2012431 L30 LB40, 52
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40, 52
GNitriles, toxic, liquid, n.o.s.6.1UN3276I6.15, T14, TP2, TP13, TP27None2012431 L30 LB52
GNitriles, toxic, solid, n.o.s.6.1UN3439I6.1IB7, IP1, T6, TP33None2112425 kg50 kgD52
GNitriles, toxic, liquid, n.o.s.6.1UN3276II6.1IB2, T11, TP2, TP271532022435 L60 LB52
GNitriles, toxic, solid, n.o.s.6.1UN3439II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB52
GNitriles, toxic, liquid, n.o.s.6.1UN3276III6.1IB3, T7, TP1, TP2815320324160 L220 LA52
GNitriles, toxic, solid, n.o.s.6.1UN3439III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA52
Nitrites, inorganic, aqueous solution, n.o.s.5.1UN3219II5.1IB1, T4, TP11522022421 L5 LB46, 56, 58, 133
III5.1IB2, T4, TP11522032412.5 L30 LB46, 56, 58, 133
Nitrites, inorganic, n.o.s.5.1UN2627II5.133, IB8, IP4, T3, TP33152212None5 kg25 kgA46, 56, 58, 133
3-Nitro-4-chlorobenzotrifluoride6.1UN2307II6.1IB2, T7, TP21532022435 L60 LA40
6-Nitro-4-diazotoluene-3-sulfonic acid (dry)Forbidden
Nitro isobutane triol trinitrateForbidden
N-Nitro-N-methylglycolamide nitrateForbidden
2-Nitro-2-methylpropanol nitrateForbidden
Nitro urea1.1DUN0147II1.1DNone62NoneForbiddenForbidden10
N-NitroanilineForbidden
+Nitroanilines (o-; m-; p-;)6.1UN1661II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Nitroanisole, liquid6.1UN2730III6.1IB3, T4, TP115320324160 L220 LA
Nitroanisoles, solid6.1UN3458III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
+Nitrobenzene6.1UN1662II6.1IB2, T7, TP21532022435 L60 LA40
m-Nitrobenzene diazonium perchlorateForbidden
Nitrobenzenesulfonic acid8UN2305II8B2, B4, IB8, IP2, IP4, T3, TP331542022421 L30 LA
Nitrobenzol, see Nitrobenzene
5-Nitrobenzotriazol1.1DUN0385II1.1DNone62NoneForbiddenForbidden10
Nitrobenzotrifluorides, liquid6.1UN2306II6.1IB2, T7, TP21532022435 L60 LA40
Nitrobenzotrifluorides, solid6.1UN3431II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
Nitrobromobenzenes, liquid6.1UN2732III6.1IB3, T4, TP115320324160 L220 LA
Nitrobromobenzenes, solid6.1UN3459III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Nitrocellulose, dry or wetted with less than 25 percent water (or alcohol), by mass1.1DUN0340II1.1DNone62NoneForbiddenForbidden1327E
Nitrocellulose membrane filters, with not more than 12.6% nitrogen, by dry mass4.1UN3270II4.143, A11512122401 kg15 kgD
Nitrocellulose, plasticized with not less than 18 percent plasticizing substance, by mass1.3CUN0343II1.3CNone62NoneForbiddenForbidden10
Nitrocellulose, solution, flammable with not more than 12.6 percent nitrogen, by mass, and not more than 55 percent nitrocellulose3UN2059I3T11, TP1, TP8, TP27None2012431 L30 LE
II3IB2, T4, TP1, TP81502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Nitrocellulose, unmodified or plasticized with less than 18 percent plasticizing substance, by mass1.1DUN0341II1.1DNone62NoneForbiddenForbidden1327E
Nitrocellulose, wetted with not less than 25 percent alcohol, by mass1.3CUN0342II1.3CNone62NoneForbiddenForbidden10
Nitrocellulose with alcohol with not less than 25 percent alcohol by mass, and with not more than 12.6 percent nitrogen, by dry mass4.1UN2556II4.1151212None1 kg15 kgD28
Nitrocellulose, with not more than 12.6 percent nitrogen, by dry mass, or Nitrocellulose mixture with pigment or Nitrocellulose mixture with plasticizer or Nitrocellulose mixture with pigment and plasticizer4.1UN2557II4.144151212None1 kg15 kgD28
Nitrocellulose with water with not less than 25 percent water, by mass4.1UN2555II4.1151212None15 kg50 kgE28
Nitrochlorobenzene, see Chloronitrobenzenes etc
Nitrocresols, solid6.1UN2446III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Nitrocresols, liquid6.1UN3434III6.1IB3, T4, TP115320324160 L220 LA
Nitroethane3UN2842III3B1, IB3, T2, TP115020324260 L220 LA
Nitroethyl nitrateForbidden
Nitroethylene polymerForbidden
Nitrogen, compressed2.2UN10662.2306302314, 31575 kg150 kgA
Nitrogen dioxide, see Dinitrogen tetroxide
Nitrogen fertilizer solution, see Fertilizer ammoniating solution etc
Nitrogen, mixtures with rare gases, see Rare gases and nitrogen mixtures
Nitrogen peroxide, seeDinitrogen tetroxide
Nitrogen, refrigerated liquid cryogenic liquid2.2UN19772.2T75, TP532031631850 kg500 kgD
Nitrogen tetroxide and nitric oxide mixtures, see Nitric oxide and nitrogen tetroxide mixtures
Nitrogen tetroxide, see Dinitrogen tetroxide
Nitrogen trichlorideForbidden
Nitrogen trifluoride2.2UN24512.2, 5.1None302None75 kg150 kgD40
Nitrogen triiodideForbidden
Nitrogen triiodide monoamineForbidden
Nitrogen trioxide2.3UN24212.3, 5.1, 81None336245ForbiddenForbiddenD40, 89, 90
Nitroglycerin, desensitized with not less than 40 percent non-volatile water insoluble phlegmatizer, by mass1.1DUN0143II1.1D, 6.1125None62NoneForbiddenForbidden1321E
Nitroglycerin, liquid, not desensitizedForbidden
Nitroglycerin mixture, desensitized, liquid, flammable, n.o.s. with not more than 30 percent nitroglycerin, by mass3UN33433129None214NoneForbiddenForbiddenD
Nitroglycerin mixture, desensitized, liquid, n.o.s. with not more than 30% nitroglycerin, by mass3UN3357II3142None2022435 L60 LE
Nitroglycerin mixture, desensitized, solid, n.o.s. with more than 2 percent but not more than 10 percent nitroglycerin, by mass4.1UN3319II4.1118NoneNoneNoneForbidden0.5 kgE
Nitroglycerin, solution in alcohol, with more than 1 percent but not more than 5 percent nitroglycerin3UN3064II3N8None202NoneForbidden5 LE
Nitroglycerin, solution in alcohol, with more than 1 percent but not more than 10 percent nitrogylcerin1.1DUN0144II1.1DNone62NoneForbiddenForbidden1021E
Nitroglycerin solution in alcohol with not more than 1 percent nitroglycerin3UN1204II3IB2, N34150202None5 L60 LB
Nitroguanidine nitrateForbidden
Nitroguanidine or Picrite, dry or wetted with less than 20 percent water, by mass1.1DUN0282II1.1DNone62NoneForbiddenForbidden10
Nitroguanidine, wetted or Picrite, wetted with not less than 20 percent water, by mass4.1UN1336I4.123, A8, A19, A20, N41None211None1 kg15 kgE28
1-NitrohydantoinForbidden
Nitrohydrochloric acid8UN1798I8A3, B10, N41, T10, TP2, TP12, TP13None201243Forbidden2.5 LD40, 66, 74, 89, 90
Nitromannite (dry)Forbidden
Nitromannite, wetted, see Mannitol hexanitrate, etc
Nitromethane3UN1261II3150202NoneForbidden60 LA
Nitromuriatic acid, see Nitrohydrochloric acid
Nitronaphthalene4.1UN2538III4.1A1, IB8, IP3, T1, TP3315121324025 kg100 kgA
4-Nitrophenylhydrazine, with not less than 30% water, by mass4.1UN3376I4.1164, A8, A19, A20, N41None211NoneForbidden15 kgE36
+Nitrophenols (o-; m-; p-;)6.1UN1663III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
m-Nitrophenyldinitro methaneForbidden
Nitropropanes3UN2608III3B1, IB3, T2, TP115020324260 L220 LA
p-Nitrosodimethylaniline4.2UN1369II4.2A19, A20, IB6, IP2, N34, T3, TP33None21224115 kg50 kgD34
Nitrostarch, dry or wetted with less than 20 percent water, by mass1.1DUN0146II1.1DNone62NoneForbiddenForbidden10
Nitrostarch, wetted with not less than 20 percent water, by mass4.1UN1337I4.123, A8, A19, A20, N41None211None1 kg15 kgD28
Nitrosugars (dry)Forbidden
Nitrosyl chloride2.3UN10692.3, 83, B14None304314, 315ForbiddenForbiddenD40
Nitrosylsulfuric acid, liquid8UN2308II8A3, A6, A7, B2, IB2, N34, T8, TP2, TP121542022421 L30 LD40, 66, 74, 89, 90
Nitrosylsulphuric acid, solid8UN3456II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgD40, 66, 74, 89, 90
Nitrotoluenes, liquid6.1UN1664II6.1IB2, T7, TP21532022435 L60 LA
Nitrotoluenes, solid6.1UN3446II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Nitrotoluidines (mono)6.1UN2660III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Nitrotriazolone or NTO1.1DUN0490II1.1DNone62NoneForbiddenForbidden10
Nitrous oxide and carbon dioxide mixtures, see Carbon dioxide and nitrous oxide mixtures
Nitrous oxide2.2UN10702.2, 5.1A14306304314, 31575 kg150 kgA40
Nitrous oxide, refrigerated liquid2.2UN22012.2, 5.1B6, T75, TP5, TP22None304314, 315ForbiddenForbiddenB40
Nitroxylenes, liquid6.1UN1665II6.1IB2, T7, TP21532022435 L60 LA
Nitroxylenes, solid6.1UN3447II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Nitroxylol, see Nitroxylenes
Nonanes3UN1920III3B1, IB3, T2, TP115020324260 L220 LA
Non-flammable gas, n.o.s., see Compressed gas, etc. or Liquefied gas, etc
Nonliquefied gases, see Compressed gases, etc
Nonliquefied hydrocarbon gas, see Hydrocarbon gas mixture, compressed, n.o.s.
Nonyltrichlorosilane8UN1799II8A7, B2, B6, IB2, N34, T7, TP2, TP13None202242Forbidden30 LC40
Nordhausen acid, see Sulfuric acid, fuming etc
2,5-Norbornadiene, stabilized, see Bicyclo 2,2,1 hepta-2,5-diene, stabilized
Octadecyltrichlorosilane8UN1800II8A7, B2, B6, IB2, N34, T7, TP2, TP13None202242Forbidden30 LC40
Octadiene3UN2309II3B1, IB2, T4, TP11502022425 L60 LB
1,7-Octadine-3,5-diyne-1,8-dimethoxy-9-octadecynoic acidForbidden
Octafluorobut-2-ene or Refrigerant gas R 13182.2UN24222.2None304314, 31575 kg150 kgA
Octafluorocyclobutane, or Refrigerant gas RC 3182.2UN19762.2T50None304314, 31575 kg150 kgA
Octafluoropropane or Refrigerant gas R 2182.2UN24242.2T50None304314, 31575 kg150 kgA
Octanes3UN1262II3IB2, T4, TP11502022425 L60 LB
Octogen, etc. see Cyclotetramethylene tetranitramine, etc.
Octolite or Octol, dry or wetted with less than 15 percent water, by mass1.1DUN0266II1.1DNone62NoneForbiddenForbidden10
Octonal1.1DUN04961.1DNone62NoneForbiddenForbidden10
Octyl aldehydes3UN1191III3B1, IB3, T2, TP115020324260 L220 LA
Octyltrichlorosilane8UN1801II8A7, B2, B6, IB2, N34, T7, TP2, TP13None202242Forbidden30 LC40
Oil gas, compressed2.3UN10712.3, 2.16None304314, 315Forbidden25 kgD40
Oleum, see Sulfuric acid, fuming
Organic peroxide type A, liquid or solidForbidden
GOrganic peroxide type B, liquid5.2UN3101II5.2, 153152225NoneForbiddenForbiddenD12, 40, 52, 53
GOrganic peroxide type B, liquid, temperature controlled5.2UN3111II5.2, 153None225NoneForbiddenForbiddenD2, 40, 52, 53
GOrganic peroxide type B, solid5.2UN3102II5.2, 153152225NoneForbiddenForbiddenD12, 40, 52, 53
GOrganic peroxide type B, solid, temperature controlled5.2UN3112II5.2, 153None225NoneForbiddenForbiddenD2, 40, 52, 53
GOrganic peroxide type C, liquid5.2UN3103II5.2152225None5 L10 LD12, 40, 52, 53
GOrganic peroxide type C, liquid, temperature controlled5.2UN3113II5.2None225NoneForbiddenForbiddenD2, 40, 52, 53
GOrganic peroxide type C, solid5.2UN3104II5.2152225None5 kg10 kgD12, 40, 52, 53
GOrganic peroxide type C, solid, temperature controlled5.2UN3114II5.2None225NoneForbiddenForbiddenD2, 40, 52, 53
GOrganic peroxide type D, liquid5.2UN3105II5.2152225None5 L10 LD12, 40, 52, 53
GOrganic peroxide type D, liquid, temperature controlled5.2UN3115II5.2None225NoneForbiddenForbiddenD2, 40, 52, 53
GOrganic peroxide type D, solid5.2UN3106II5.2152225None5 kg10 kgD12, 40, 52, 53
GOrganic peroxide type D, solid, temperature controlled5.2UN3116II5.2None225NoneForbiddenForbiddenD2, 40, 52, 53
GOrganic peroxide type E, liquid5.2UN3107II5.2152225None10 L25 LD12, 40, 52, 53
GOrganic peroxide type E, liquid, temperature controlled5.2UN3117II5.2None225NoneForbiddenForbiddenD2, 40, 52, 53
GOrganic peroxide type E, solid5.2UN3108II5.2152225None10 kg25 kgD12, 40, 52, 53
GOrganic peroxide type E, solid, temperature controlled5.2UN3118II5.2None225NoneForbiddenForbiddenD2, 40, 52, 53
GOrganic peroxide type F, liquid5.2UN3109II5.2IP515222522510 L25 LD12, 40, 52, 53
GOrganic peroxide type F, liquid, temperature controlled5.2UN3119II5.2IP5None225225ForbiddenForbiddenD2, 40, 52, 53
GOrganic peroxide type F, solid5.2UN3110II5.2TP3315222522510 kg25 kgD12, 40, 52, 53
GOrganic peroxide type F, solid, temperature controlled5.2UN3120II5.2TP33None225225ForbiddenForbiddenD2, 52, 53
DOrganic phosphate, mixed with compressed gas or Organic phosphate compound, mixed with compressed gas or Organic phosphorus compound, mixed with compressed gas2.3NA19552.33None334NoneForbiddenForbiddenD40
Organic pigments, self-heating4.2UN3313II4.2IB8, IP2, IP4, T3, TP33None21224115 kg50 kgC
III4.2IB8, IP3, T1, TP33None21324125 kg100 kgC
GOrganoarsenic compound, liquid, n.o.s.6.1UN3280I6.15, T14, TP2, TP13, TP27None2112425 kg50 kgB
II6.1IB2, T11, TP2, TP2715321224225 kg100 kgB
III6.1IB3, T7, TP1, TP28153213240100 kg200 kgA
GOrganoarsenic compound, solid, n.o.s.6.1UN3465I6.1IB7, IP1, T6, TP33None2112425 kg50 kgB
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Organochlorine pesticides liquid, flammable, toxic, flash point less than 23 degrees C3UN2762I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LB40
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40
Organochlorine pesticides, liquid, toxic6.1UN2996I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1IB3, T7, TP2, TP2815320324160 L220 LA40
Organochlorine pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN2995I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3B1, IB3, T7, TP2, TP2815320324260 L220 LA40
Organochlorine pesticides, solid, toxic6.1UN2761I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
GOrganometallic compound, toxic, liquid, n.o.s.6.1UN3282I6.1T14, TP2, TP13, TP27None2112425 kg50 kgB
II6.1IB2, T11, TP2, TP2715321224225 kg100 kgB
III6.1IB3, T7, TP1, TP28153213240100 kg200 kgA
GOrganometallic compound, toxic, solid, n.o.s.6.1UN3467I6.1IB7, IP1, T6, TP33None2112425 kg50 kgB
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
GOrganometallic substance, liquid, pyrophoric4.2UN3392I4.2B11, T21, TP2, TP7None181244ForbiddenForbiddenD143
GOrganometallic substance, liquid, pyrophoric, water-reactive4.2UN3394I4.2, 4.3B11, T21, TP2, TP7None181244ForbiddenForbiddenD
GOrganometallic substance, liquid, water-reactive4.3UN3398I4.3T13, TP2, TP7None201244ForbiddenForbiddenE40, 52
II4.3IB1, T7, TP2, TP7None2022431 L5 LE40, 52
III4.3IB2, T7, TP2, TP7None2032425 L60 LE40, 52
GOrganometallic substance, liquid, water-reactive, flammable4.3UN3399I4.3, 3T13, TP2, TP7None201244ForbiddenFobiddenE40, 52
II4.3, 3IB1, T7, TP2, TP7None202243ForbiddenForbiddenE40, 52
III4.3, 3IB2, T7, TP2, TP7None203242ForbiddenForbiddenE40, 52
GOrganometallic substance, solid, pyrophoric4.2UN3391I4.2T21, TP7, TP33None181244ForbiddenForbiddenD
GOrganometallic substance, solid, pyrophoric, water-reactive4.2UN3393I4.2, 4.3B11, T21, TP7, TP33None181244ForbiddenForbiddenD52
GOrganometallic substance, solid, self-heating4.2UN3400II4.2IB6, T3, TP33None21224215 kg50 kgC
III4.2IB8, T1, TP33None20324225 kg100 kgC
GOrganometallic substance, solid, water-reactive4.3UN3395I4.3N40, T9, TP7, TP33None211242ForbiddenForbiddenE40, 52
II4.3IB4, T3, TP3315121224215 kg50 kgE40, 52
III4.3IB6, T1, TP3315121324125 kg100 kgE40, 52
GOrganometallic substance, solid, water-reactive, flammable4.3UN3396I4.3, 4.1N40, T9, TP7, TP33None211242ForbiddenForbiddenE40, 52
II4.3, 4.1IB4, T3, TP3315121224215 kg50 kgE40, 52
III4.3, 4.1IB6, T1, TP3315121324125 kg100 kgE40, 52
GOrganometallic substance, solid, water-reactive, self-heating4.3UN3397I4.3, 4.2N40, T9, TP7, TP33None211242ForbiddenForbiddenE40, 52
II4.3, 4.2IB4, T3, TP33None21224215 kg50 kgE40, 52
III4.3, 4.2IB6, T1, TP33None21324125 kg100 kgE40, 52
Organophosphorus compound, toxic, flammable, n.o.s.6.1UN3279I6.1, 35, T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
GOrganophosphorus compound, toxic, liquid, n.o.s.6.1UN3278I6.15, T14, TP2, TP13, TP27None2012431 L30 LB
II6.1IB2, T11, TP2, TP271532022435 L60 LB
III6.1IB3, T7, TP1, TP2815320324160 L220 LA
GOrganophosphorus compound, toxic, solid, n.o.s.6.1UN3464I6.1IB7, IP1, T6, TP33None2112425 kg50 kgB
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Organophosphorus pesticides, liquid, flammable, toxic, flash point less than 23 degrees C3UN2784I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LB40
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40
Organophosphorus pesticides, liquid, toxic6.1UN3018I6.1N76, T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, N76, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1IB3, N76, T7, TP2, TP2815320324160 L220 LA40
Organophosphorus pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN3017I6.1, 3N76, T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, N76, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3B1, IB3, N76, T7, TP2, TP2815320324260 L220 LA40
Organophosphorus pesticides, solid, toxic6.1UN2783I6.1IB7, IP1, N77, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, N77, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, N77, T1, TP33153213240100 kg200 kgA40
Organotin compounds, liquid, n.o.s.6.1UN2788I6.1A3, N33, N34, T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1A3, IB2, N33, N34, T11, TP2, TP13, TP271532022435 L60 LA40
III6.1IB3, T7, TP2, TP2815320324160 L220 LA40
Organotin compounds, solid, n.o.s.6.1UN3146I6.1A5, IB7, IP1, T6, TP33None2112425 kg50 kgB40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Organotin pesticides, liquid, flammable, toxic, flash point less than 23 degrees C3UN2787I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LB40
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40
Organotin pesticides, liquid, toxic6.1UN3020I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1IB3, T7, TP2, TP2815320324160 L220 LA40
Organotin pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN3019I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3B1, IB3, T7, TP2, TP2815320324260 L220 LA40
Organotin pesticides, solid, toxic6.1UN2786I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Orthonitroaniline, see Nitroanilines etc
Osmium tetroxide6.1UN2471I6.1A8, IB7, IP1, N33, N34, T6, TP33None2112425 kg50 kgB40
D GOther regulated substances, liquid, n.o.s.9NA3082III9IB3, T2, TP1155203241No limitNo limitA
D GOther regulated substances, solid, n.o.s.9NA3077III9B54, IB8, IP2, T1, TP33155213240No limitNo limitA
GOxidizing liquid, corrosive, n.o.s.5.1UN3098I5.1, 8A6None201244Forbidden2.5 LD13, 56, 58, 106, 138
II5.1, 8IB1None2022431 L5 LB34, 56, 58, 106, 138
III5.1, 8IB21522032422.5 L30 LB34, 56, 58, 106, 138
GOxidizing liquid, n.o.s.5.1UN3139I5.1127, A2, A6None201243Forbidden2.5 LD56, 58, 106, 138
II5.1127, A2, IB21522022421 L5 LB56, 58, 106, 138
III5.1127, A2, IB21522032412.5 L30 LB56, 58, 106, 138
GOxidizing liquid, toxic, n.o.s.5.1UN3099I5.1, 6.1A6None201244Forbidden2.5 LD56, 58, 106, 138
II5.1, 6.1IB11522022431 L5 LB56, 58, 95, 106, 138
III5.1, 6.1IB21522032422.5 L30 LB56, 58, 95, 106, 138
GOxidizing solid, corrosive, n.o.s.5.1UN3085I5.1, 8None2112421 kg15 kgD13, 56, 58, 106, 138
II5.1, 8IB6, IP2, T3, TP33None2122425 kg25 kgB13, 34, 56, 58, 106, 138
III5.1, 8IB8, IP3, T1, TP3315221324025 kg100 kgB13, 34, 56, 58, 106, 138
GOxidizing solid, flammable, n.o.s.5.1UN3137I5.1, 4.1None214214ForbiddenForbidden
GOxidizing solid, n.o.s.5.1UN1479I5.1IB5, IP1None2112421 kg15 kgD56, 58, 106, 138
II5.1IB8, IP2, IP4, T3, TP331522122405 kg25 kgB56, 58, 106, 138
III5.1IB8, IP3, T1, TP3315221324025 kg100 kgB56, 58, 106, 138
GOxidizing solid, self-heating, n.o.s.5.1UN3100I5.1, 4.2None214214ForbiddenForbidden
II5.1, 4.2None214214ForbiddenForbidden
GOxidizing solid, toxic, n.o.s.5.1UN3087I5.1, 6.1None2112421 kg15 kgD56, 58, 106, 138
II5.1, 6.1IB6, IP2, T3, TP331522122425 kg25 kgB56, 58, 95, 106, 138
III5.1, 6.1IB8, IP3, T1, TP3315221324025 kg100 kgB56, 58, 95, 106, 138
GOxidizing solid, water-reactive, n.o.s.5.1UN31215.1, 4.3None214214ForbiddenForbidden
Oxygen and carbon dioxide mixtures, see Carbon dioxide and oxygen mixtures
Oxygen, compressed2.2UN10722.2, 5.1A14, A52306302314, 31575 kg150 kgA
Oxygen difluoride, compressed2.3UN21902.3, 5.1, 81None304NoneForbiddenForbiddenD13, 40, 89, 90
Oxygen generator, chemical (including when contained in associated equipment, e.g., passenger service units (PSUs), portable breathing equipment (PBE), etc).5.1UN3356II5.160, A51None212NoneForbidden25 kg grossD56, 58, 69, 106
+Oxygen generator, chemical, spent9NA3356III961None213NoneForbiddenForbiddenA
Oxygen, mixtures with rare gases, see Rare gases and oxygen mixtures
Oxygen, refrigerated liquid (cryogenic liquid)2.2UN10732.2, 5.1T75, TP5, TP22320316318ForbiddenForbiddenD
Paint including paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid filler, and liquid lacquer base3UN1263I3T11, TP1, TP81502012431 L30 LE
II3149, B52, IB2, T4, TP1, TP81501732425 L60 LB
III3B1, B52, IB3, T2, TP115017324260 L220 LA
Paint or Paint related material8UN3066II8B2, IB2, T7, TP21541732421 L30 LA
III8B52, IB3, T4, TP11541732415 L60 LA
Paint related material including paint thinning, drying, removing, or reducing compound3UN1263I3T11, TP1, TP81502012431 L30 LE
II3149, B52, IB2, T4, TP1, TP81501732425 L60 LB
III3B1, B52, IB3, T2, TP115017324260 L220 LA
Paper, unsaturated oil treated incompletely dried (including carbon paper)4.2UN1379III4.2IB8, IP3None213241ForbiddenForbiddenA
Paraformaldehyde4.1UN2213III4.1A1, IB8, IP3, T1, TP3315121324025 kg100 kgA
Paraldehyde3UN1264III3B1, IB3, T2, TP115020324260 L220 LA
Paranitroaniline, solid, see Nitroanilines etc
DParathion and compressed gas mixture2.3NA19672.33None334245ForbiddenForbiddenE40
Paris green, solid, see Copper acetoarsenite
A WPCB, see Polychlorinated biphenyls
+Pentaborane4.2UN1380I4.2, 6.11None205245ForbiddenForbiddenD
Pentachloroethane6.1UN1669II6.1IB2, T7, TP21532022435 L60 LA40
Pentachlorophenol6.1UN3155II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Pentaerythrite tetranitrate (dry)Forbidden
Pentaerythrite tetranitrate mixture, desensitized, solid, n.o.s. with more than 10 percent but not more than 20 percent PETN, by mass4.1UN3344II4.1118, N85None214NoneForbiddenForbiddenE
Pentaerythrite tetranitrate or Pentaerythritol tetranitrate or PETN, with not less than 7 percent wax by mass1.1DUN0411II1.1DNone62NoneForbiddenForbidden10
Pentaerythrite tetranitrate, wetted or Pentaerythritol tetranitrate, wetted, or PETN, wetted with not less than 25 percent water, by mass, or Pentaerythrite tetranitrate, or Pentaerythritol tetranitrate or PETN, desensitized with not less than 15 percent phlegmatizer by mass1.1DUN0150II1.1D121None62NoneForbiddenForbidden10
Pentaerythritol tetranitrate, see Pentaerythrite tetranitrate, etc
Pentafluoroethane or Refrigerant gas R 1252.2UN32202.2T50306304314, 31575 kg150 kgA
Pentamethylheptane3UN2286III3B1, IB3, T2, TP115020324260 L220 LA
Pentane-2,4-dione3UN2310III3, 6.1B1, IB3, T4, TP115020324260 L220 LA
Pentanes3UN1265I3T11, TP21502012431 L30 LE
II3IB2, IP8, T4, TP11502022425 L60 LE
Pentanitroaniline (dry)Forbidden
Pentanols3UN1105II3IB2, T4, TP1, TP291502022425 L60 LB
III3B1, B3, IB3, T2, TP115020324260 L220 LA
1-Pentene (n-amylene)3UN1108I3T11, TP21502012431 L30 LE
1-Pentol8UN2705II8B2, IB2, T7, TP21542022421 L30 LB26, 27
Pentolite, dry or wetted with less than 15 percent water, by mass1.1DUN0151II1.1DNone62NoneForbiddenForbidden10
Pepper spray, see Aerosols, etc. or Self-defense spray, non-pressurized
Perchlorates, inorganic, aqueous solution, n.o.s.5.1UN3211II5.1IB2, T4, TP11522022421 L5 LB56, 58, 133
III5.1IB2, T4, TP11522022412.5 L30 LB56, 58, 69, 133
Perchlorates, inorganic, n.o.s.5.1UN1481II5.1IB6, IP2, T3, TP331522122425 kg25 kgA56, 58
III5.1IB8, IP3, T1, TP3315221324025 kg100 kgA56, 58
Perchloric acid, with more than 72 percent acid by massForbidden
Perchloric acid with more than 50 percent but not more than 72 percent acid, by mass5.1UN1873I5.1, 8A2, A3, N41, T10, TP1, TP12None201243Forbidden2.5 LD66
Perchloric acid with not more than 50 percent acid by mass8UN1802II8, 5.1IB2, N41, T7, TP2None202243Forbidden30 LC66
Perchloroethylene, see Tetrachloroethylene
Perchloromethyl mercaptan6.1UN1670I6.12, B9, B14, B32, B74, N34, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Perchloryl fluoride2.3UN30832.3, 5.12, B9, B14None302314, 315ForbiddenForbiddenD40
Percussion caps, see Primers, cap type
Perfluoro-2-butene, see Octafluorobut-2-ene
Perfluoro(ethyl vinyl ether)2.1UN31542.1306302, 304, 305314, 315Forbidden150 kgE40
Perfluoro(methyl vinyl ether)2.1UN31532.1T50306302, 304, 305314, 315Forbidden150 kgE40
Perfumery products with flammable solvents3UN1266II3149, IB2, T4, TP1, TP815020224215 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Permanganates, inorganic, aqueous solution, n.o.s.5.1UN3214II5.126, IB2, T4, TP11522022421 L5 LD56, 58, 133, 138
Permanganates, inorganic, n.o.s.5.1UN1482II5.126, A30, IB6, IP2, T3, TP331522122425 kg25 kgD56, 58, 138
III5.126, A30, IB8, IP3, T1, TP3315221324025 kg100 kgD56, 58, 138
Peroxides, inorganic, n.o.s.5.1UN1483II5.1A7, A20, IB6, IP2, N34, T3, TP33None2122425 kg25 kgA13, 52, 66, 75
III5.1A7, A20, IB8, IP3, N34, T1, TP3315221324025 kg100 kgA13, 52, 66, 75
Peroxyacetic acid, with more than 43 percent and with more than 6 percent hydrogen peroxideForbidden
Persulfates, inorganic, aqueous solution, n.o.s.5.1UN3216III5.1IB2, T4, TP1, TP291522032412.5 L30 LA56, 133
Persulfates, inorganic, n.o.s.5.1UN3215III5.1IB8, IP3, T1, TP3315221324025 kg100 kgA56, 58
GPesticides, liquid, flammable, toxic, flash point less than 23 degrees C3UN3021I3, 6.1B5, T14, TP2, TP13, TP27None201243Forbidden30 LB
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB
GPesticides, liquid, toxic, flammable, n.o.s. flash point not less than 23 degrees C6.1UN2903I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3B1, IB3, T7, TP215320324260 L220 LA40
GPesticides, liquid, toxic, n.o.s.6.1UN2902I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1IB3, T7, TP2, TP2815320324160 L220 LA40
GPesticides, solid, toxic, n.o.s.6.1UN2588I6.1IB7, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
PETN, see Pentaerythrite tetranitrate
PETN/TNT, see Pentolite, etc
Petrol, see Gasoline
Petroleum crude oil3UN1267I3144, T11, TP1, TP81502012431 L30 LE
II3144, IB2, T4, TP1, TP81502022425 L60 LB
III3144, B1, IB3, T2, TP115020324260 L220 LA
Petroleum distillates, n.o.s. or Petroleum products, n.o.s.3UN1268I3144, T11, TP1, TP81502012431 L30 LE
II3144, IB2, T7, TP1, TP8, TP281502022425 L60 LB
III3144, B1, IB3, T4, TP1, TP2915020324260 L220 LA
Petroleum gases, liquefied or Liquefied petroleum gas2.1UN10752.1T50306304314, 315Forbidden150 kgE40
DPetroleum oil3NA1270I3144, T11, TP1None2012431 L30 LE
II3144, IB2, T7, TP1, TP8, TP281502022425 L60 LB
III3144, B1, IB3, T4, TP1, TP2915020324260 L220 LA
Phenacyl bromide6.1UN2645II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB40
+Phenetidines6.1UN2311III6.1IB3, T4, TP115320324160 L220 LA
Phenol, molten6.1UN2312II6.1B14, T7, TP3None202243ForbiddenForbiddenB40
+Phenol, solid6.1UN1671II6.1IB8, IP2, IP4, N78, T3, TP3315321224225 kg100 kgA
Phenol solutions6.1UN2821II6.1IB2, T7, TP21532022435 L60 LA
III6.1IB3, T4, TP115320324160 L220 LA
Phenolsulfonic acid, liquid8UN1803II8B2, IB2, N41, T7, TP21542022421 L30 LC14
Phenoxyacetic acid derivative pesticide, liquid, flammable, toxic flash point less than 23 degrees C3UN3346I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LB40
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40
Phenoxyacetic acid derivative pesticide, liquid, toxic6.1UN3348I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP271532022435 L60 LB40
III6.1IB3, T7, TP2, TP2815320324160 L220 LA40
Phenoxyacetic acid derivative pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN3347I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3IB3, T7, TP2, TP2815320324160 L220 LA40
Phenoxyacetic acid derivative pesticide, solid, toxic6.1UN3345I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Phenyl chloroformate6.1UN2746II6.1, 8IB2, T7, TP2, TP131532022431 L30 LA12, 13, 21, 25, 40, 100
Phenyl isocyanate6.1UN2487I6.1, 32, B9, B14, B32, B74, B77, N33, N34, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
Phenyl mercaptan6.1UN2337I6.1, 32, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenB40, 52
Phenyl phosphorus dichloride8UN2798II8B2, B15, IB2, T7, TP2154202242Forbidden30 LB40
Phenyl phosphorus thiodichloride8UN2799II8B2, B15, IB2, T7, TP2154202242Forbidden30 LB40
Phenylacetonitrile, liquid6.1UN2470III6.1IB3, T4, TP115320324160 L220 LA52
Phenylacetyl chloride8UN2577II8B2, IB2, T7, TP21542022421 L30 LC40
Phenylcarbylamine chloride6.1UN1672I6.12, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD40
m-Phenylene diaminediperchlorate (dry)Forbidden
+Phenylenediamines (o-; m-; p-;)6.1UN1673III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Phenylhydrazine6.1UN2572II6.1IB2, T7, TP21532022435 L60 LA40
Phenylmercuric acetate6.1UN1674II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Phenylmercuric compounds, n.o.s.6.1UN2026I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Phenylmercuric hydroxide6.1UN1894II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Phenylmercuric nitrate6.1UN1895II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Phenyltrichlorosilane8UN1804II8A7, B6, IB2, N34, T7, TP2None202242Forbidden30 LC40
Phosgene2.3UN10762.3, 81, B7, B46None192314ForbiddenForbiddenD40
9-Phosphabicyclononanes or Cyclooctadiene phosphines4.2UN2940II4.2A19, IB6, IP2, T3, TP33None21224115 kg50 kgA
Phosphine2.3UN21992.3, 2.11None192245ForbiddenForbiddenD40
Phosphoric acid solution8UN1805III8A7, IB3, N34, T4, TP11542032415 L60 LA
Phosphoric acid, solid8UN3453III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Phosphoric acid triethyleneimine, see Tris-(1-aziridiyl)phosphine oxide, solution
Phosphoric anhydride, see Phosphorus pentoxide
Phosphorous acid8UN2834III8IB8, IP3, T1, TP3315421324025 kg100 kgA48
Phosphorus, amorphous4.1UN1338III4.1A1, A19, B1, B9, B26, IB8, IP3, T1, TP33None21324325 kg100 kgA74
Phosphorus bromide, see Phosphorus tribromide
Phosphorus chloride, see Phosphorus trichloride
Phosphorus heptasulfide, free from yellow or white phosphorus4.1UN1339II4.1A20, IB4, N34, T3, TP33None21224015 kg50 kgB74
Phosphorus oxybromide8UN1939II8B8, IB8, IP2, IP4, N41, N43, T3, TP33None212240Forbidden50 kgC12, 40
Phosphorus oxybromide, molten8UN2576II8B2, B8, IB1, N41, N43, T7, TP3, TP13None202242ForbiddenForbiddenC40
+Phosphorus oxychloride8UN1810II8, 6.12, B9, B14, B32, B74, B77, N34, T20, TP2, TP38, TP45None227244ForbiddenForbiddenC40
Phosphorus pentabromide8UN2691II8A7, IB8, IP2, IP4, N34, T3, TP33154212240Forbidden50 kgB12, 40, 53, 55
Phosphorus pentachloride8UN1806II8A7, IB8, IP2, IP4, N34, T3, TP33None212240Forbidden50 kgC40, 44, 89, 100, 141
Phosphorus2.3UN21982.3, 82, B9, B14None302, 304314, 315ForbiddenForbiddenD40
Phosphorus pentasulfide, free from yellow or white phosphorus4.3UN1340II4.3, 4.1A20, B59, IB4, T3, TP3315121224215 kg50 kgB74
Phosphorus pentoxide8UN1807II8A7, IB8, IP2, IP4, N34, T3, TP3315421224015 kg50 kgA
Phosphorus sesquisulfide, free from yellow or white phosphorus4.1UN1341II4.1A20, IB4, N34, T3, TP33None21224015 kg50 kgB74
Phosphorus tribromide8UN1808II8A3, A6, A7, B2, B25, IB2, N34, N43, T7, TP2None202242Forbidden30 LC40
Phosphorus trichloride6.1UN1809I6.1, 82, B9, B14, B15, B32, B74, B77, N34, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenC40
Phosphorus trioxide8UN2578III8IB8, IP3, T1, TP3315421324025 kg100 kgA12
Phosphorus trisulfide, free from yellow or white phosphorus4.1UN1343II4.1A20, IB4, N34, T3, TP33None21224015 kg50 kgB74
Phosphorus, white dry or Phosphorus, white, under water or Phosphorus white, in solution or Phosphorus, yellow dry or Phosphorus, yellow, under water or Phosphorus, yellow, in solution4.2UN1381I4.2, 6.1B9, B26, N34, T9, TP3, TP31None188243ForbiddenForbiddenE
Phosphorus white, molten4.2UN2447I4.2, 6.1B9, B26, N34, T21, TP3, TP7, TP26None188243ForbiddenForbiddenD
Phosphorus (white or red) and a chlorate, mixtures ofForbidden
Phosphoryl chloride, see Phosphorus oxychloride
Phthalic anhydride with more than .05 percent maleic anhydride8UN2214III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Picolines3UN2313III3B1, IB3, T4, TP115020324260 L220 LA40
Picric acid, see Trinitrophenol, etc
Picrite, see Nitroguanidine, etc
Picryl chloride, see Trinitrochlorobenzene
Pine oil3UN1272III3B1, IB3, T2, TP115020324260 L220 LA
alpha-Pinene3UN2368III3B1, IB3, T2, TP115020324260 L220 LA
Piperazine8UN2579III8IB8, IP3, T1, TP3315421324025 kg100 kgA12, 52
Piperidine8UN2401I8, 3A10, T10, TP2None2012430.5 L2.5 LB52
Pivaloyl chloride, see Trimethylacetyl chloride
Plastic molding compound in dough, sheet or extruded rope form evolving flammable vapor9UN3314III932, IB8, IP3, IP7155221221100 kg200 kgA85, 87
Plastic solvent, n.o.s., see Flammable liquids, n.o.s.
Plastics, nitrocellulose-based, self-heating, n.o.s.4.2UN2006III4.2None213NoneForbiddenForbiddenC
Poisonous gases, n.o.s., see Compressed or liquefied gases, flammable or toxic, n.o.s.
Polyalkylamines, n.o.s., see Amines, etc
Polychlorinated biphenyls, liquid9UN2315II99, 81, 140, IB3, T4, TP1155202241100 L220 LA95
Polychlorinated biphenyls, solid9UN3432II99, 81, 140, IB8, T3, TP33155212240100 kg200 kgA95
Polyester resin kit3UN3269340, 149152225None5 kg5 kgB
Polyhalogenated biphenyls, liquid or Polyhalogenated terphenyls liquid9UN3151II9IB2155204241100 L220 LA95
Polyhalogenated biphenyls, solid or Polyhalogenated terphenyls, solid9UN3152II9IB8, IP2, IP4, T3, TP33155204241100 kg200 kgA95
Polymeric beads, expandable, evolving flammable vapor9UN2211III932, IB8, IP3, IP7, T1, TP33155221221100 kg200 kgA85, 87
Potassium4.3UN2257I4.3A7, A19, A20, B27, IB4, IP1, N6, N34, T9, TP7, TP33None211244Forbidden15 kgD52
Potassium arsenate6.1UN1677II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Potassium arsenite6.1UN1678II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Potassium bisulfite solution, see Bisulfites, aqueous solutions, n.o.s.
Potassium borohydride4.3UN1870I4.3A19, N40None211242Forbidden15 kgE52
Potassium bromate5.1UN1484II5.1IB8, IP4, T3, TP331522122425 kg25 kgA56, 58
Potassium carbonylForbidden
Potassium chlorate5.1UN1485II5.1A9, IB8, IP4, N34, T3, TP331522122425 kg25 kgA56, 58
Potassium chlorate, aqueous solution5.1UN2427II5.1A2, IB2, T4, TP11522022411 L5 LB56, 58, 133
III5.1A2, IB2, T4, TP11522032412.5 L30 LB56, 58, 69, 133
Potassium chlorate mixed with mineral oil, see Explosive, blasting, type C
Potassium cuprocyanide6.1UN1679II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA52
Potassium cyanide, solid6.1UN1680I6.1B69, B77, IB7, IP1, N74, N75, T6, TP33None2112425 kg50 kgB52
Potassium cyanide solution6.1UN3413I6.1B69, B77, N74, N75, T14, TP2, TP13None2012431 L30 LB52
II6.1B69, B77, IB2, N74, N75, T11, TP2, TP13, TP271532022435 L60 LB52
III6.1B69, B77, IB3, N74, N75, T7, TP2, TP13, TP2815320324160 L220 LA52
Potassium dichloro isocyanurate or Potassium dichloro-s-triazinetrione, see Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts etc
Potassium dithionite or Potassium hydrosulfite4.2UN1929II4.2A8, A19, A20, IB6, IP2, T3, TP33None21224115 kg50 kgE13
Potassium fluoride, solid6.1UN1812III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA52
Potassium fluoride solution6.1UN3422III6.1IB3, T4, TP115320324160 L220 LA52
Potassium fluoroacetate6.1UN2628I6.1IB7, IP1, T6, TP33None2112425 kg50 kgE
Potassium fluorosilicate6.1UN2655III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA52
Potassium hydrate, see Potassium hydroxide, solid
Potassium hydrogen fluoride, see Potassium hydrogen difluoride
Potassium hydrogen fluoride solution, see Corrosive liquid, n.o.s.
Potassium hydrogen sulfate8UN2509II8A7, IB8, IP2, IP4, N34, T3, TP3315421224015 kg50 kgA
Potassium hydrogendifluoride solid8UN1811II8, 6.1IB8, IP2, IP4, N3, N34, T3, TP3315421224015 kg50 kgA25, 40, 52
Potassium hydrogendifluoride solution8UN3421II8, 6.1IB2, N3, N34, T7, TP21542022431 L30 LA25, 40, 52
III8, 6.1IB3, N3, N34, T4, TP11542032415 L60 LA40, 52
Potassium hydrosulfite, see Potassium dithionite
Potassium hydroxide, liquid, see Potassium hydroxide solution
Potassium hydroxide, solid8UN1813II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA
Potassium hydroxide, solution8UN1814II8B2, IB2, T7, TP21542022421 L30 LA
III8IB3, T4, TP11542032415 L60 LA
Potassium hypochlorite, solution, see Hypochlorite solutions, etc
Potassium, metal alloys, liquid4.3UN1420I4.3A7, A19, A20, B27None201244Forbidden1 LE40, 52
Potassium, metal alloys, solid4.3UN3403I4.3A19, A20, B27, IB4, IP1, T9, TP7, TP33None211244Forbidden15 kgD
Potassium metal, liquid alloy, see Alkali metal alloys, liquid, n.o.s.
Potassium metavanadate6.1UN2864II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Potassium monoxide8UN2033II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA29
Potassium nitrate5.1UN1486III5.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA
Potassium nitrate and sodium nitrite mixtures5.1UN1487II5.1B78, IB8, IP4, T3, TP331522122405 kg25 kgA56, 58
Potassium nitrite5.1UN1488II5.1IB8, IP4, T3, TP331522122425 kg25 kgA56, 58
Potassium perchlorate5.1UN1489II5.1IB6, IP2, T3, TP331522122425 kg25 kgA56, 58
Potassium permanganate5.1UN1490II5.1IB8, IP4, T3, TP331522122405 kg25 kgD56, 58, 138
Potassium peroxide5.1UN1491I5.1A20, IB6, IP1, N34None211NoneForbidden15 kgB13, 52, 66, 75
Potassium persulfate5.1UN1492III5.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA56, 58
Potassium phosphide4.3UN2012I4.3, 6.1A19, N40None211NoneForbidden15 kgE40, 52, 85
Potassium selenate, see Selenates or Selenites
Potassium selenite, see Selenates or Selenites
Potassium sodium alloys, solid4.3UN3404I4.3A19, B27, N34, N40, T9, TP7, TP33None211244Forbidden15 kgD52
Potassium sodium alloys, liquid4.3UN1422I4.3A7, A19, B27, N34, N40, T9, TP3, TP7, TP31None201244Forbidden1 LE40, 52
Potassium sulfide, anhydrous or Potassium sulfide with less than 30 percent water of crystallization4.2UN1382II4.2A19, A20, B16, IB6, IP2, N34, T3, TP33None21224115 kg50 kgA52
Potassium sulfide, hydrated with not less than 30 percent water of crystallization8UN1847II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA52
Potassium superoxide5.1UN2466I5.1A20, IB6, IP1None211NoneForbidden15 kgB13, 52, 66, 75
Powder cake, wetted or Powder paste, wetted with not less than 17 percent alcohol by mass1.1CUN0433II1.1CNone62NoneForbiddenForbidden10
Powder cake, wetted or Powder paste, wetted with not less than 25 percent water, by mass1.3CUN0159II1.3CNone62NoneForbiddenForbidden10
Powder paste, see Powder cake, etc
Powder, smokeless1.1CUN0160II1.1CNone62NoneForbiddenForbidden26E
Powder, smokeless1.3CUN0161II1.3CNone62NoneForbiddenForbidden26E
Power device, explosive, see Cartridges, power device
Primers, cap type1.4SUN0044IINoneNone62None25 kg100 kg05
Primers, cap type1.1BUN0377II1.1BNone62NoneForbiddenForbidden11
Primers, cap type1.4BUN0378II1.4BNone62NoneForbidden75 kg06
Primers, small arms, see Primers, cap type
Primers, tubular1.3GUN0319II1.3GNone62NoneForbiddenForbidden07
Primers, tubular1.4GUN0320II1.4GNone62NoneForbidden75 kg06
Primers, tubular1.4SUN0376IINoneNone62None25 kg100 kg05
Printing ink, flammable or Printing ink related material (including printing ink thinning or reducing compound), flammable3UN1210I3T11, TP1, TP81501732431 L30 LE
II3149, IB2, T4, TP1, TP81501732425 L60 LB
III3B1, IB3, T2, TP115017324260 L220 LA
Projectiles, illuminating, see Ammunition, illuminating, etc
Projectiles, inert with tracer1.4SUN0345II1.4S62None25 kg100 kg01
Projectiles, inert, with tracer1.3GUN0424II1.3G62NoneForbiddenForbidden03
Projectiles, inert, with tracer1.4GUN0425II1.4G62NoneForbidden75 kg02
Projectiles, with burster or expelling charge1.2DUN0346II1.2D62NoneForbiddenForbidden03
Projectiles, with burster or expelling charge1.4DUN0347II1.4D62NoneForbidden75 kg02
Projectiles, with burster or expelling charge1.2FUN0426II1.2F62NoneForbiddenForbidden08
Projectiles, with burster or expelling charge1.4FUN0427II1.4F62NoneForbiddenForbidden08
Projectiles, with burster or expelling charge1.2GUN0434II1.2G62NoneForbiddenForbidden03
Projectiles, with burster or expelling charge1.4GUN0435II1.4G62NoneForbidden75 kg02
Projectiles, with bursting charge1.1FUN0167II1.1F62NoneForbiddenForbidden08
Projectiles, with bursting charge1.1DUN0168II1.1D62NoneForbiddenForbidden03
Projectiles, with bursting charge1.2DUN0169II1.2D62NoneForbiddenForbidden03
Projectiles, with bursting charge1.2FUN0324II1.2F62NoneForbiddenForbidden08
Projectiles, with bursting charge1.4DUN0344II1.4D62NoneForbidden75 kg02
Propadiene, stabilized2.1UN22002.1None304314, 315Forbidden150 kgB40
Propadiene mixed with methyl acetylene, see Methyl acetylene and propadiene mixtures, stabilized
Propane see also Petroleum gases, liquefied2.1UN19782.119, T50306304314, 315Forbidden150 kgE40
Propanethiols3UN2402II3A6, IB2, T4, TP1, TP131502022425 L60 LE95, 102
n-Propanol or Propyl alcohol, normal3UN1274II3B1, IB2, T4, TP11502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Propellant, liquid1.3CUN0495II1.3C37None62NoneForbiddenForbidden10
Propellant, liquid1.1CUN0497II1.1C37None62NoneForbiddenForbidden10
Propellant, solid1.1CUN0498II1.1CNone62NoneForbiddenForbidden26E
Propellant, solid1.3CUN0499II1.3CNone62NoneForbiddenForbidden26E
Propellant, solid1.4CUN05011.4CNone62NoneForbiddenForbiddenA24E
Propionaldehyde3UN1275II3IB2, T7, TP11502022425 L60 LE
Propionic acid8UN1848III8IB3, T4, TP11542032415 L60 LA
Propionic anhydride8UN2496III8IB3, T4, TP11542032415 L60 LA
Propionitrile3UN2404II3, 6.1IB2, T7, TP1, TP13None202243Forbidden60 LE40
Propionyl chloride3UN1815II3, 8IB1, T7, TP11502022431 L5 LB40
n-Propyl acetate3UN1276II3IB2, T4, TP11502022425 L60 LB
Propyl alcohol, see Propanol
n-Propyl benzene3UN2364III3B1, IB3, T2, TP115020324260 L220 LA
n-Propyl chloroformate6.1UN2740I6.1, 3, 82, B9, B14, B32, B74, B77, N34, T20, TP2, TP13, TP38, TP44None227244ForbiddenForbiddenB21, 40, 100
Propyl chloride see 1-Chloropropane
Propyl formates3UN1281II3IB2, T4, TP11502022425 L60 LB
n-Propyl isocyanate6.1UN2482I6.1, 31, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44None226244ForbiddenForbiddenD40
Propyl mercaptan, see Propanethiols
n-Propyl nitrate3UN1865II3IB99150202None5 L60 LD44, 89, 90, 100
Propylamine3UN1277II3, 8A7, IB2, N34, T7, TP11502022431 L5 LE40
Propylene see also Petroleum gases, liquefied2.1UN10772.119, T50306304314, 315Forbidden150 kgE40
Propylene chlorohydrin6.1UN2611II6.1, 3IB2, T7, TP2, TP131532022435 L60 LA12, 40, 48
Propylene oxide3UN1280I3A3, N34, T11, TP2, TP7None2012431 L30 LE40
Propylene tetramer3UN2850III3B1, IB3, T2, TP115020324260 L220 LA
1,2-Propylenediamine8UN2258II8, 3A3, A6, IB2, N34, T7, TP2None2022431 L30 LA40
Propyleneimine, stabilized3UN1921I3, 6.1A3, N34, T14, TP2, TP13None2012431 L30 LB40
Propyltrichlorosilane8UN1816II8, 3A7, B2, B6, IB2, N34, T7, TP2, TP13None202243Forbidden30 LC40
Prussic acid, see Hydrogen cyanide
Pyrethroid pesticide, liquid, flammable, toxic, flash point less than 23 degrees C3UN3350I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LB40
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40
Pyrethroid pesticide, liquid toxic6.1UN3352I6.1T14, TP2, TP13, TP27None2112421 L30 LA40
II6.1IB2, T11, TP2, TP271532122425 L60 LA40
III6.1IB3, T7, TP2, TP2815321324060 L220 LA40
Pyrethroid pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN3351I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3IB3, T7, TP2, TP2815320324160 L220 LB40
Pyrethroid pesticide, solid, toxic6.1UN3349I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Pyridine3UN1282II3IB2, T4, TP2None2022425 L60 LB21, 100
Pyridine perchlorateForbidden
GPyrophoric liquid, inorganic, n.o.s.4.2UN3194I4.2None181244ForbiddenForbiddenD18
GPyrophoric liquids, organic, n.o.s.4.2UN2845I4.2B11, T22, TP2, TP7None181244ForbiddenForbiddenD18
GPyrophoric metals, n.o.s., or Pyrophoric alloys, n.o.s.4.2UN1383I4.2B11, T21, TP7, TP33None187242ForbiddenForbiddenD
GPyrophoric solid, inorganic, n.o.s.4.2UN3200I4.2T21, TP7, TP33None187242ForbiddenForbiddenD
GPyrophoric solids, organic, n.o.s.4.2UN2846I4.2None187242ForbiddenForbiddenD
Pyrosulfuryl chloride8UN1817II8B2, IB2, T8, TP2, TP121542022421 L30 LC40
Pyroxylin solution or solvent, see Nitrocellulose
Pyrrolidine3UN1922II3, 8IB2, T7, TP11502022431 L5 LB40
Quebrachitol pentanitrateForbidden
Quicklime, see Calcium oxide
Quinoline6.1UN2656III6.1IB3, T4, TP115320324160 L220 LA12
R 12, see Dichlorodifluoromethane
R 12B1, see Chlorodifluorobromomethane
R 13, see Chlorotrifluoromethane
R 13B1, see Bromotrifluoromethane
R 14, see Tetrafluoromethane
R 21, see Dichlorofluoromethane
R 22, see Chlorodifluoromethane
R 114, see Dichlorotetrafluoroethane
R 115, see Chloropentafluoroethane
R 116, see Hexafluoroethane
R 124, see Chlorotetrafluoroethane
R 133a, see Chlorotrifluoroethane
R 152a, see Difluoroethane
R 500, see Dichlorodifluoromethane and difluorethane, etc
R 502, see Chlorodifluoromethane and chloropentafluoroethane mixture, etc
R 503, see Chlorotrifluoromethane and trifluoromethane, etc
Radioactive material, excepted package-articles manufactured from natural uranium or depleted uranium or natural thorium7UN2909None422, 426422, 426422, 426A
Radioactive material, excepted package-empty packaging7UN2908Empty422, 428422, 428422, 428A
Radioactive material, excepted package-instruments or articles7UN2911None422, 424422, 424A
Radioactive material, excepted package-limited quantity of material7UN2910None421, 422421, 422421, 422A
Radioactive material, low specific activity (LSA-I) non fissile or fissile-excepted7UN29127A56, T5, TP4, W7421, 422, 428427427A95, 129
Radioactive material, low specific activity (LSA-II) non fissile or fissile-excepted7UN33217A56, T5, TP4, W7421, 422, 428427427A95, 129
Radioactive material, low specific activity (LSA-III) non fissile or fissile excepted7UN33227A56, T5, TP4, W7421, 422, 428427427A95, 129
Radioactive material, surface contaminated objects (SCO-I or SCO-II) non fissile or fissile-excepted7UN29137A56421, 422, 428427427A95
Radioactive material, transported under special arrangement, non fissile or fissile excepted7UN29197A56, 139A95, 105
Radioactive material, transported under special arrangement, fissile7UN33317A56, 139A95, 105
Radioactive material, Type A package, fissile non-special form7UN33277A56, W7, W8453417417A95, 105, 131
Radioactive material, Type A package non-special form, non fissile or fissile-excepted7UN29157A56, W7, W8415415A95, 130
Radioactive material, Type A package, special form non fissile or fissile-excepted7UN33327A56, W7, W8415, 476415, 476A95
Radioactive material, Type A package, special form, fissile7UN33337A56, W7, W8453417, 476417, 476A95, 105
Radioactive material, Type B(M) package, fissile7UN33297A56453417417A95, 105
Radioactive material, Type B(M) package non fissile or fissile-excepted7UN29177A56416416A95, 105
Radioactive material, Type B(U) package, fissile7UN33287A56453417417A95, 105
Radioactive material, Type B(U) package non fissile or fissile-excepted7UN29167A56416416A95, 105
Radioactive material, uranium hexafluoride non fissile or fissile-excepted7UN29787, 8423420, 427420, 427A95, 132
IRadioactive material, uranium hexafluoride, fissile7UN29777, 8453417, 420417, 420A95, 132
A WRags, oily4.2UN1856III4.2151213240ForbiddenForbiddenA
Railway torpedo, see Signals, railway track, explosive
Rare gases and nitrogen mixtures, compressed2.2UN19812.2306302None75 kg150 kgA
Rare gases and oxygen mixtures, compressed2.2UN19802.279306302None75 kg150 kgA
Rare gases mixtures, compressed2.2UN19792.2306302None75 kg150 kgA
RC 318, see Octafluorocyclobutane
RDX and cyclotetramethylenetetranitramine, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized
RDX and HMX mixtures, wetted with not less than 15 percent water by massor RDX and HMX mixtures, desensitized with not less than 10 percent phlegmatizer by mass1.1DUN0391II1.1DNone62NoneForbiddenForbidden10
RDX and Octogen mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc
RDX, see Cyclotrimethylene trinitramine, etc
Receptacles, small, containing gas (gas cartridges) flammable, without release device, not refillable and not exceeding 1 L capacity2.1UN20372.1306304None1 kg15 kgB40
Receptacles, small, containing gas (gas cartridges) non-flammable, without release device, not refillable and not exceeding 1 L capacity2.2UN20372.2306304None1 kg15 kgB40
2.2, 5.1A14306304None1 kg15 kgB40
Red phosphorus, see Phosphorus, amorphous
Refrigerant gas R 404A2.2UN33372.2T50306304314, 31575 kg150 kgA
Refrigerant gas R 407A2.2UN33382.2T50306304314, 31575 kg150 kgA
Refrigerant gas R 407B2.2UN33392.2T50306304314, 31575 kg150 kgA
Refrigerant gas R 407C2.2UN33402.2T50306304314, 31575 kg150 kgA
GRefrigerant gases, n.o.s.2.2UN10782.2T50306304314, 31575 kg150 kgA
DRefrigerant gases, n.o.s. or Dispersant gases, n.o.s.2.1NA19542.1T50306304314, 315Forbidden150 kgD40
Refrigerating machines, containing flammable, non-toxic, liquefied gas2.1UN33582.1306306306ForbiddenForbiddenC40
Refrigerating machines, containing non-flammable, non-toxic, or ammonia solution (UN2672)2.2UN28572.2A53306, 307306306, 307450 kg450 kgA
Regulated medical waste6.2UN3291II6.2A13134197197No limitNo limitA40
Release devices, explosive1.4SUN0173II1.4SNone62None25 kg100 kg05
Resin solution, flammable3UN1866I3B52, T11, TP1, TP8, TP281502012431 L30 LE
II3149, B52, IB2, T4, TP1, TP81501732425 L60 LB
III3B1, B52, IB3, T2, TP115017324260 L220 LA
Resorcinol6.1UN2876III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Rifle grenade, see Grenades, hand or rifle, etc
Rifle powder, see Powder, smokeless (UN 0160)
Rivets, explosive1.4SUN0174II1.4SNone62None25 kg100 kg05
Road asphalt or tar liquid, see Tars, liquid, etc
Rocket motors1.3CUN0186II1.3C109None62NoneForbidden220 kg03
Rocket motors1.1CUN0280II1.1C109None62NoneForbiddenForbidden03
Rocket motors1.2CUN0281II1.2C109None62NoneForbiddenForbidden03
Rocket motors, liquid fueled1.2JUN0395II1.2J109None62NoneForbiddenForbidden0423E
Rocket motors, liquid fueled1.3JUN0396II1.3J109None62NoneForbiddenForbidden0423E
Rocket motors with hypergolic liquids with or without an expelling charge1.3LUN0250II1.3L109None62NoneForbiddenForbidden088E, 14E, 15E
Rocket motors with hypergolic liquids with or without an expelling charge1.2LUN0322II1.2L109None62NoneForbiddenForbidden088E, 14E, 15E
Rockets, line-throwing1.2GUN0238II1.2GNone62NoneForbiddenForbidden07
Rockets, line-throwing1.3GUN0240II1.3GNone62NoneForbidden75 kg07
Rockets, line-throwing1.4GUN0453II1.4GNone62NoneForbidden75 kg06
Rockets, liquid fueled with bursting charge1.1JUN0397II1.1JNone62NoneForbiddenForbidden0423E
Rockets, liquid fueled with bursting charge1.2JUN0398II1.2JNone62NoneForbiddenForbidden0423E
Rockets, with bursting charge1.1FUN0180II1.1FNone62NoneForbiddenForbidden08
Rockets, with bursting charge1.1EUN0181II1.1ENone62NoneForbiddenForbidden03
Rockets, with bursting charge1.2EUN0182II1.2ENone62NoneForbiddenForbidden03
Rockets, with bursting charge1.2FUN0295II1.2FNone62NoneForbiddenForbidden08
Rockets, with expelling charge1.2CUN0436II1.2CNone62NoneForbiddenForbidden03
Rockets, with expelling charge1.3CUN0437II1.3CNone62NoneForbiddenForbidden03
Rockets, with expelling charge1.4CUN0438II1.4CNone62NoneForbidden75 kg02
Rockets, with inert head1.3CUN0183II1.3CNone62NoneForbiddenForbidden03
Rockets, with inert head1.2CUN05021.2CNone62NoneForbiddenForbiddenB1E, 5E
Rosin oil3UN1286II3IB2, T4, TP11502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Rubber solution3UN1287II3149, IB2, T4, TP1, TP81502022425 L60 LB
Rubber scrap or shoddy, powdered or granulated, not exceeding 840 microns and rubber contend exceeding 45%4.1UN1345II4.1IB8, IP2, IP4, T3, TP3315121224015 kg50 kgA
Rubber solution3UN1287III3B1, IB3, T2, TP115020324260 L220 LA
Rubidium4.3UN1423I4.322, A7, A19, IB4, IP1, N34, N40, N45None211242Forbidden15 kgD52
Rubidium hydroxide8UN2678II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA29
Rubidium hydroxide solution8UN2677II8B2, IB2, T7, TP21542022421 L30 LA29
III8IB3, T4, TP11542032415 L60 LA29
Safety fuse, see Fuse, safety
Sand acid, see Fluorosilicic acid
Seed cake, containing vegetable oil solvent extractions and expelled seeds, with not more than 10 percent of oil and when the amount of moisture is higher than 11 percent, with not more than 20 percent of oil and moisture combined4.2UN1386IIINoneIB8, IP3, IP7, N7None213241ForbiddenForbiddenA13
ISeed cake with more than 1.5 percent oil and not more than 11 percent moisture4.2UN1386IIINoneIB8, IP3, IP7, N7None213241ForbiddenForbiddenE13
ISeed cake with not more than 1.5 percent oil and not more than 11 percent moisture4.2UN2217IIINoneIB8, IP3, IP7, N7None213241ForbiddenForbiddenA13
Selenates or Selenites6.1UN2630I6.1IB7, IP1, T6, TP33None2112425 kg50 kgE
Selenic acid8UN1905I8IB7, IP1, N34, T6, TP33None211242Forbidden25 kgA
Selenium compound, solid, n.o.s.6.1UN3283I6.1IB7, IP1, T6, TP33None2112425 kg50 kgB
Selenium compound, liquid, n.o.s.6.1UN3440I6.1T14, TP2, TP27None2012431 L30 LB
Selenium compound, solid, n.o.s.6.1UN3283II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB
Selenium compound, liquid, n.o.s.6.1UN3440II6.1IB2, T11, TP2, TP271532022435 L60 LB
Selenium compound, solid, n.o.s.6.1UN3283III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Selenium compound, liquid, n.o.s.6.1UN3440III6.1IB3, T7, TP1, TP2815320324160 L220 LA
Selenium disulfide6.1UN2657II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Selenium hexafluoride2.3UN21942.3, 81None302NoneForbiddenForbiddenD40
Selenium nitrideForbidden
Selenium oxychloride8UN2879I8, 6.1A3, A6, A7, N34, T10, TP2, TP12, TP13None2012430.5 L2.5 LE40
Self-defense spray, aerosol, see Aerosols, etc
+ A DSelf-defense spray, non-pressurized9NA3334III9A37155203NoneNo limitNo limitA
GSelf-heating liquid, corrosive, inorganic, n.o.s.4.2UN3188II4.2, 8IB2None2022431 L5 LC
III4.2, 8IB2None2032415 L60 LC
GSelf-heating liquid, corrosive, organic, n.o.s.4.2UN3185II4.2, 8IB2None2022431 L5 LC
III4.2, 8IB2None2032415 L60 LC
GSelf-heating liquid, inorganic, n.o.s.4.2UN3186II4.2IB2None2022421 L5 LC
III4.2IB2None2032415 L60 LC
GSelf-heating liquid, organic, n.o.s.4.2UN3183II4.2IB2None2022421 L5 LC
III4.2IB2None2032415 L60 LC
GSelf-heating liquid, toxic, inorganic, n.o.s.4.2UN3187II4.2, 6.1IB2None2022431 L5 LC
III4.2, 6.1IB2None2032415 L60 LC
GSelf-heating liquid, toxic, organic, n.o.s.4.2UN3184II4.2, 6.1IB2None2022431 L5 LC
III4.2, 6.1IB2None2032415 L60 LC
GSelf-heating solid, corrosive, inorganic, n.o.s.4.2UN3192II4.2, 8IB5, IP2, T3, TP33None21224215 kg50 kgC
III4.2, 8IB8, IP3, T1, TP33None21324225 kg100 kgC
GSelf-heating, solid, corrosive, organic, n.o.s.4.2UN3126II4.2, 8IB5, IP2, T3, TP33None21224215 kg50 kgC
III4.2, 8IB8, IP3, T1, TP33None21324225 kg100 kgC
GSelf-heating solid, inorganic, n.o.s.4.2UN3190II4.2IB6, IP2, T3, TP33None21224115 kg50 kgC
III4.2IB8, IP3, T1, TP33None21324125 kg100 kgC
GSelf-heating, solid, organic, n.o.s.4.2UN3088II4.2IB6, IP2, T3, TP33None21224115 kg50 kgC
III4.2IB8, IP3, T1, TP33None21324125 kg100 kgC
GSelf-heating, solid, oxidizing, n.o.s.4.2UN31274.2, 5.1None214214ForbiddenForbidden
GSelf-heating solid, toxic, inorganic, n.o.s.4.2UN3191II4.2, 6.1IB5, IP2, T3, TP33None21224215 kg50 kgC
III4.2, 6.1IB8, IP3, T1, TP33None21324225 kg100 kgC
GSelf-heating, solid, toxic, organic, n.o.s.4.2UN3128II4.2, 6.1IB5, IP2, T3, TP33None21224215 kg50 kgC
III4.2, 6.1IB8, IP3, T1, TP33None21324225 kg100 kgC
Self-propelled vehicle, see Engines or Batteries etc
GSelf-reactive liquid type B4.1UN3221II4.153None224NoneForbiddenForbiddenD52, 53
GSelf-reactive liquid type B, temperature controlled4.1UN3231II4.153None224NoneForbiddenForbiddenD2, 52, 53
GSelf-reactive liquid type C4.1UN3223II4.1None224None5 L10 LD52, 53
GSelf-reactive liquid type C, temperature controlled4.1UN3233II4.1None224NoneForbiddenForbiddenD2, 52, 53
GSelf-reactive liquid type D4.1UN3225II4.1None224None5 L10 LD52, 53
GSelf-reactive liquid type D, temperature controlled4.1UN3235II4.1None224NoneForbiddenForbiddenD2, 52, 53
GSelf-reactive liquid type E4.1UN3227II4.1None224None10 L25 LD52, 53
GSelf-reactive liquid type E, temperature controlled4.1UN3237II4.1None224NoneForbiddenForbiddenD2, 52, 53
GSelf-reactive liquid type F4.1UN3229II4.1T23None224None10 L25 LD52, 53
GSelf-reactive liquid type F, temperature controlled4.1UN3239II4.1None224NoneForbiddenForbiddenD2, 52, 53
GSelf-reactive solid type B4.1UN3222II4.153None224NoneForbiddenForbiddenD52, 53
GSelf-reactive solid type B, temperature controlled4.1UN3232II4.153None224NoneForbiddenForbiddenD2, 52, 53
GSelf-reactive solid type C4.1UN3224II4.1None224None5 kg10 kgD52, 53
GSelf-reactive solid type C, temperature controlled4.1UN3234II4.1None224NoneForbiddenForbiddenD2, 52, 53
GSelf-reactive solid type D4.1UN3226II4.1None224None5 kg10 kgD52, 53
GSelf-reactive solid type D, temperature controlled4.1UN3236II4.1None224NoneForbiddenForbiddenD2, 52, 53
GSelf-reactive solid type E4.1UN3228II4.1None224None10 kg25 kgD52, 53
GSelf-reactive solid type E, temperature controlled4.1UN3238II4.1None224NoneForbiddenForbiddenD2, 52, 53
GSelf-reactive solid type F4.1UN3230II4.1None224None10 kg25 kgD52, 53
GSelf-reactive solid type F, temperature controlled4.1UN3240II4.1None224NoneForbiddenForbiddenD2, 52, 53
Shale oil3UN1288I3T11, TP1, TP8, TP27None2012431 L30 LB
II3IB2, T4, TP1, TP81502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Shaped charges, see Charges, shaped, etc
Signal devices, hand1.4GUN0191II1.4GNone62NoneForbidden75 kg06
Signal devices, hand1.4SUN0373II1.4SNone62None25 kg100 kg05
Signals, distress, ship1.1GUN0194II1.1GNone62NoneForbiddenForbidden07
Signals, distress, ship1.3GUN0195II1.3GNone62NoneForbidden75 kg07
Signals, highway, see Signal devices, hand
Signals, railway track, explosive1.1GUN0192II1.1GNone62NoneForbiddenForbidden07
Signals, railway track, explosive1.4SUN0193II1.4SNone62None25 kg100 kg05
Signals, railway track, explosive1.3GUN04921.3GNone62NoneForbiddenForbidden07
Signals, railway track, explosive1.4GUN04931.4GNone62NoneForbidden75 kg06
Signals, ship distress, water-activated, see Contrivances, water-activated, etc
Signals, smoke1.1GUN0196II1.1GNone62NoneForbiddenForbidden07
Signals, smoke1.4GUN0197II1.4GNone62NoneForbidden75 kg06
Signals, smoke1.2GUN0313II1.2GNone62NoneForbiddenForbidden07
Signals, smoke1.3GUN0487II1.3GNone62NoneForbiddenForbidden07
Silane2.1UN22032.1None302NoneForbiddenForbiddenE40, 57, 104
Silicofluoric acid, see Fluorosilicic acid
Silicon chloride, see Silicon tetrachloride
Silicon powder, amorphous4.1UN1346III4.1A1, IB8, IP3, T1, TP33None21324025 kg100 kgA74
Silicon tetrachloride8UN1818II8A3, A6, B2, B6, IB2, T7, TP2, TP71542022421 L30 LC40
Silicon tetrafluoride2.3UN18592.3, 82None302NoneForbiddenForbiddenD40
Silver acetylide (dry)Forbidden
Silver arsenite6.1UN1683II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Silver azide (dry)Forbidden
Silver chlorite (dry)Forbidden
Silver cyanide6.1UN1684II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40, 52
Silver fulminate (dry)Forbidden
Silver nitrate5.1UN1493II5.1IB8, IP4, T3, TP331522122425 kg25 kgA
Silver oxalate (dry)Forbidden
Silver picrate (dry)Forbidden
Silver picrate, wetted with not less than 30 percent water, by mass4.1UN1347I4.123None211NoneForbiddenForbiddenD28, 36
Sludge, acid8UN1906II8A3, A7, B2, IB2, N34, T8, TP2, TP12, TP28None202242Forbidden30 LC14
DSmokeless powder for small arms (100 pounds or less)4.1NA3178I4.116None171NoneForbidden7.3 kgA
Soda lime with more than 4 percent sodium hydroxide8UN1907III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Sodium4.3UN1428I4.3A7, A8, A19, A20, B9, B48, B68, IB4, IP1, N34, T9, TP7, TP33, TP46None211244Forbidden15 kgD52
Sodium aluminate, solid8UN2812III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Sodium aluminate, solution8UN1819II8B2, IB2, T7, TP21542022421 L30 LA
III8IB3, T4, TP11542032415 L60 LA
Sodium aluminum hydride4.3UN2835II4.3A8, A19, A20, IB4, T3, TP33151212242Forbidden50 kgE52
Sodium ammonium vanadate6.1UN2863II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Sodium arsanilate6.1UN2473III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Sodium arsenate6.1UN1685II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Sodium arsenite, aqueous solutions6.1UN1686II6.1IB2, T7, TP21532022435 L60 LA
III6.1IB3, T4, TP215320324160 L220 LA
Sodium arsenite, solid6.1UN2027II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Sodium azide6.1UN1687II6.1IB8, IP2, IP415321224225 kg100 kgA36, 52, 91
Sodium bifluoride, see Sodium hydrogendifluoride
Sodium bisulfite, solution, see Bisulfites, aqueous solutions, n.o.s.
Sodium borohydride4.3UN1426I4.3N40None211242Forbidden15 kgE52
Sodium borohydride and sodium hydroxide solution, with not more than 12 percent sodium borohydride and not more than 40 percent sodium hydroxide by mass8UN3320II8B2, IB2, N34, T7, TP21542022421 L30 LA52
III8B2, IB3, N34, T4, TP21542032415 L60 LA52
Sodium bromate5.1UN1494II5.1IB8, IP4, T3, TP331522122425 kg25 kgA56, 58
Sodium cacodylate6.1UN1688II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA52
Sodium carbonate peroxyhydrate5.1UN3378II5.1IB8, IP2, IP4, T3, TP331522122405 kg25 kgA13, 48, 75
III5.1IB8, IP3, T1, TP3315221324025 kg100 kgA13, 48, 75
Sodium chlorate5.1UN1495II5.1A9, IB8, IP4, N34, T3, TP331522122405 kg25 kgA56, 58
Sodium chlorate, aqueous solution5.1UN2428II5.1A2, IB2, T4, TP11522022411 L5 LB56, 58, 133
III5.1A2, IB2, T4, TP11522032412.5 L30 LB56, 58, 69, 133
Sodium chlorate mixed with dinitrotoluene, see Explosive blasting, type C
Sodium chlorite5.1UN1496II5.1A9, IB8, IP2, IP4, N34, T3, TP33None2122425 kg25 kgA56, 58
Sodium chloroacetate6.1UN2659III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Sodium cuprocyanide, solid6.1UN2316I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA52
Sodium cuprocyanide, solution6.1UN2317I6.1T14, TP2, TP13None2012431 L30 LB40, 52
Sodium cyanide, solid6.1UN1689I6.1B69, B77, IB7, N74, N75, T6, TP33None2112425 kg50 kgB52
Sodium cyanide solution6.1UN3414I6.1B69, B77, N74, N75, T14, TP2, TP13None2012431 L30 LB52
II6.1B69, B77, IB2, N74, N75, T11, TP2, TP13, TP271532022435 L60 LB52
III6.1B69, B77, IB3, N74, N75, T7, TP2, TP13, TP2815320324160 L220 LA52
Sodium dichloroisocyanurate or Sodium dichloro-s-triazinetrione, see Dichloroisocyanuric acid etc
Sodium dinitro-o-cresolate, dry or wetted with less than 15 percent water, by mass1.3CUN0234II1.3CNone62NoneForbiddenForbidden105E
Sodium dinitro-o-cresolate, wetted with not less than 10% water, by mass4.1UN3369I4.1162, A8, A19, N41, N84None211None0.5 kg0.5 kgE36
Sodium dinitro-o-cresolate, wetted with not less than 15 percent water, by mass4.1UN1348I4.1, 6.123, A8, A19, A20, N41None211None1 kg15 kgE28, 36
Sodium dithionite or Sodium hydrosulfite4.2UN1384II4.2A19, A20, IB6, IP2, T3, TP33None21224115 kg50 kgE13
Sodium fluoride, solid6.1UN1690III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA52
Sodium fluoride solution6.1UN3415III6.1IB3, T4, TP115320324160 L220 LA52
Sodium fluoroacetate6.1UN2629I6.1IB7, IP1, T6, TP33None2112425 kg50 kgE
Sodium fluorosilicate6.1UN2674III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA52
Sodium hydrate, see Sodium hydroxide, solid
Sodium hydride4.3UN1427I4.3A19, N40None211242Forbidden15 kgE52
Sodium hydrogendifluoride8UN2439II8IB8, IP2, IP4, N3, N34, T3, TP3315421224015 kg50 kgA12, 25, 40, 52
Sodium hydrosulfide, with less than 25 percent water of crystallization4.2UN2318II4.2A7, A19, A20, IB6, IP2, T3, TP33None21224115 kg50 kgA
Sodium hydrosulfide with not less than 25 percent water of crystallization8UN2949II8A7, IB8, IP2, IP4, T7, TP215421224015 kg50 kgA52
Sodium hydrosulfite, see Sodium dithionite
Sodium hydroxide, solid8UN1823II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA
Sodium hydroxide solution8UN1824II8B2, IB2, N34, T7, TP21542022421 L30 LA
III8IB3, N34, T4, TP11542032415 L60 LA
Sodium hypochlorite, solution, see Hypochlorite solutions etc
Sodium metal, liquid alloy, see Alkali metal alloys, liquid, n.o.s.
Sodium methylate4.2UN1431II4.2, 8A7, A19, IB5, IP2, T3, TP33None21224215 kg50 kgB
Sodium methylate solutions in alcohol3UN1289II3, 8IB2, T7, TP1, TP81502022431 L5 LB
III3, 8B1, IB3, T4, TP11502032425 L60 LA
Sodium monoxide8UN1825II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA
Sodium nitrate5.1UN1498III5.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA
Sodium nitrate and potassium nitrate mixtures5.1UN1499III5.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA
Sodium nitrite5.1UN1500III5.1, 6.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA56, 58
Sodium pentachlorophenate6.1UN2567II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Sodium perborate monohydrate5.1UN3377III5.1IB8, IP3, T1, TP3315221324025 kg100 kgA13, 48, 75
Sodium perchlorate5.1UN1502II5.1IB6, IP2, T3, TP331522122425 kg25 kgA56, 58
Sodium permanganate5.1UN1503II5.1IB6, IP2, T3, TP331522122425 kg25 kgD56, 58, 138
Sodium peroxide5.1UN1504I5.1A20, IB5, IP1, N34None211NoneForbidden15 kgB13, 52, 66, 75
Sodium peroxoborate, anhydrous5.1UN3247II5.1IB8, IP4, T3, TP331522122405 kg25 kgA13, 25
Sodium persulfate5.1UN1505III5.1A1, IB8, IP3, T1, TP3315221324025 kg100 kgA56, 58
Sodium phosphide4.3UN1432I4.3, 6.1A19, N40None211NoneForbidden15 kgE40, 52, 85
Sodium picramate, dry or wetted with less than 20 percent water, by mass1.3CUN0235II1.3CNone62NoneForbiddenForbidden105E
Sodium picramate, wetted with not less than 20 percent water, by mass4.1UN1349I4.123, A8, A19, N41None211NoneForbidden15 kgE28, 36
Sodium picryl peroxideForbidden
Sodium potassium alloys, see Potassium sodium alloys
Sodium selenate, see Selenates or Selenites
Sodium sulfide, anhydrous or Sodium sulfide with less than 30 percent water of crystallization4.2UN1385II4.2A19, A20, IB6, IP2, N34, T3, TP33None21224115 kg50 kgA52
Sodium sulfide, hydrated with not less than 30 percent water8UN1849II8IB8, IP2, IP4, T3, TP3315421224015 kg50 kgA26
Sodium superoxide5.1UN2547I5.1A20, IB6, IP1, N34None211NoneForbidden15 kgE13, 52, 66, 75
Sodium tetranitrideForbidden
GSolids containing corrosive liquid, n.o.s.8UN3244II849, IB5, T3, TP3315421224015 kg50 kgB40
GSolids containing flammable liquid, n.o.s.4.1UN3175II4.147, IB6, IP2, T3, TP3315121224015 kg50 kgB
GSolids containing toxic liquid, n.o.s.6.1UN3243II6.148, IB2, T2, TP3315321224025 kg100 kgB40
Sounding devices, explosive1.2FUN0204II1.2FNone62NoneForbiddenForbidden08
Sounding devices, explosive1.1FUN0296II1.1FNone62NoneForbiddenForbidden08
Sounding devices, explosive1.1DUN0374II1.1DNone62NoneForbiddenForbidden07
Sounding devices, explosive1.2DUN0375II1.2DNone62NoneForbiddenForbidden07
Spirits of salt, see Hydrochloric acid
Squibs, see Igniters etc
Stannic chloride, anhydrous8UN1827II8B2, IB2, T7, TP21542022421 L30 LC
Stannic chloride pentahydrate8UN2440III8IB8, IP3, T1, TP3315421324025 kg100 kgA
Stannic phosphide4.3UN1433I4.3, 6.1A19, N40None211242Forbidden15 kgE40, 52, 85
Steel swarf, see Ferrous metal borings, etc
Stibine2.3UN26762.3, 2.11None304NoneForbiddenForbiddenD40
Storage batteries, wet, see Batteries, wet etc
Strontium arsenite6.1UN1691II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Strontium chlorate5.1UN1506II5.1A1, A9, IB8, IP2, IP4, N34, T3, TP331522122425 kg25 kgA56, 58
Strontium nitrate5.1UN1507III5.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA
Strontium perchlorate5.1UN1508II5.1IB6, IP2, T3, TP331522122425 kg25 kgA56, 58
Strontium peroxide5.1UN1509II5.1IB6, IP2, T3, TP331522122425 kg25 kgA13, 52, 66, 75
Strontium phosphide4.3UN2013I4.3, 6.1A19, N40None211NoneForbidden15 kgE40, 52, 85
Strychnine or Strychnine salts6.1UN1692I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
Styphnic acid, see Trinitroresorcinol, etc
Styrene monomer, stabilized3UN2055III3B1, IB3, T2, TP115020324260 L220 LA
GSubstances, explosive, n.o.s.1.1LUN0357II1.1L101None62NoneForbiddenForbidden8E, 14E, 15E, 17E
GSubstances, explosive, n.o.s.1.2LUN0358II1.2L101None62NoneForbiddenForbidden8E, 14E, 15E, 17E
GSubstances, explosive, n.o.s.1.3LUN0359II1.3L101None62NoneForbiddenForbidden8E, 14E, 15E, 17E
GSubstances, explosive, n.o.s.1.1AUN0473II1.1A101, 111None62NoneForbiddenForbidden12
GSubstances, explosive, n.o.s.1.1CUN0474II1.1C101None62NoneForbiddenForbidden10
GSubstances, explosive, n.o.s.1.1DUN0475II1.1D101None62NoneForbiddenForbidden10
GSubstances, explosive, n.o.s.1.1GUN0476II1.1G101None62NoneForbiddenForbidden08
GSubstances, explosive, n.o.s.1.3CUN0477II1.3C101None62NoneForbiddenForbidden10
GSubstances, explosive, n.o.s.1.3GUN0478II1.3G101None62NoneForbiddenForbidden08
GSubstances, explosive, n.o.s.1.4CUN0479II1.4C101None62NoneForbidden75 kg09
GSubstances, explosive, n.o.s.1.4DUN0480II1.4D101None62NoneForbidden75 kg09
GSubstances, explosive, n.o.s.1.4SUN0481II1.4S101None62None25 kg75 kg05
GSubstances, explosive, n.o.s.1.4GUN0485II1.4G101None62NoneForbidden75 kg08
GSubstances, explosive, very insensitive, n.o.s., or Substances, EVI, n.o.s.1.5DUN0482II1.5D101None62NoneForbiddenForbidden10
Substituted nitrophenol pesticides, liquid, flammable, toxic, flash point less than 23 degrees C3UN2780I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LB40
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40
Substituted nitrophenol pesticides, liquid, toxic6.1UN3014I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1IB3, T7, TP2, TP2815320324160 L220 LA40
Substituted nitrophenol pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN3013I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3B1, IB3, T7, TP2, TP2815320324260 L220 LA40
Substituted nitrophenol pesticides, solid, toxic6.1UN2779I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Sucrose octanitrate (dry)Forbidden
Sulfamic acid8UN2967III8IB8, IP3, T1, TP3315421324025 kg100 kgA
DSulfur9NA1350III910, IB8, IP2NoneNone240No limitNo limitA19, 74
ISulfur4.1UN1350III4.130, IB8, IP3, T1, TP33NoneNone240No limitNo limitA19, 74
Sulfur and chlorate, loose mixtures ofForbidden
Sulfur chlorides8UN1828I85, A3, A7, A10, B10, B77, N34, T20, TP2, TP12None201243Forbidden2.5 LC40
Sulfur dichloride, see Sulfur chlorides
Sulfur dioxide2.3UN10792.3, 83, B14, T50, TP19None304314, 315ForbiddenForbiddenD40
Sulfur dioxide solution, see Sulfurous acid
Sulfur hexafluoride2.2UN10802.2306304314, 31575 kg150 kgA
DSulfur, molten9NA2448III930, IB3, T1, TP3None213247ForbiddenForbiddenC61
ISulfur, molten4.1UN2448III4.130, IB1, T1, TP3None213247ForbiddenForbiddenC61
Sulfur tetrafluoride2.3UN24182.3, 81None302245ForbiddenForbiddenD40, 52
+Sulfur trioxide, stabilized8UN1829I8, 6.12, B9, B14, B32, B49, B74, B77, N34, T20, TP4, TP12, TP13, TP25, TP26, TP38, TP45None227244ForbiddenForbiddenA40
Sulfuretted hydrogen, see Hydrogen sulfide
Sulfuric acid, fuming with less than 30 percent free sulfur trioxide8UN1831I8B84, N34, T20, TP2, TP12, TP13None201243Forbidden2.5 LC14, 40
+Sulfuric acid, fuming with 30 percent or more free sulfur trioxide8UN1831I8, 6.12, A3, A6, A7, B9, B14, B32, B74, B77, B84, N34, T20, TP2, TP12, TP13None227244ForbiddenForbiddenC14, 40
Sulfuric acid, spent8UN1832II8A3, A7, B2, B83, B84, IB2, N34, T8, TP2, TP12None202242Forbidden30 LC14
Sulfuric acid with more than 51 percent acid8UN1830II8A3, A7, B3, B83, B84, IB2, N34, T8, TP2, TP121542022421 L30 LC14
Sulfuric acid with not more than 51% acid8UN2796II8A3, A7, B2, B15, IB2, N6, N34, T8, TP2, TP121542022421 L30 LB
Sulfuric and hydrofluoric acid mixtures, see Hydrofluoric and sulfuric acid mixtures
Sulfuric anhydride, see Sulfur trioxide, stabilized
Sulfurous acid8UN1833II8B3, IB2, T7, TP21542022421 L30 LB40
+Sulfuryl chloride8UN1834I8, 6.11, B6, B9, B10, B14, B30, B74, B77, N34, T22, TP2, TP12, TP38, TP44None226244ForbiddenForbiddenC40
Sulfuryl fluoride2.3UN21912.34None304314, 315ForbiddenForbiddenD40
Tars, liquid including road asphalt and oils, bitumen and cut backs3UN1999II3149, B13, IB2, T3, TP3, TP291502022425 L60 LB
III3B1, B13, IB3, T1, TP315020324260 L220 LA
Tear gas candles6.1UN1700II6.1, 4.1None340NoneForbidden50 kgD40
Tear gas cartridges, see Ammunition, tear-producing, etc
DTear gas devices with more than 2 percent tear gas substances, by mass6.1NA1693I6.1None340NoneForbiddenForbiddenD40
II6.1None340NoneForbiddenForbiddenD40
Tear gas devices, with not more than 2 percent tear gas substances, by mass, see Aerosols, etc
Tear gas grenades, see Tear gas candles
GTear gas substances, liquid, n.o.s.6.1UN1693I6.1None201NoneForbiddenForbiddenD40
II6.1IB2None202NoneForbidden5 LD40
GTear gas substance, solid, n.o.s.6.1UN3448I6.1T6, TP33None211242ForbiddenForbiddenD40
II6.1IB8, IP2, IP4, T3, TP33None212242Forbidden25 kgD40
Tellurium compound, n.o.s.6.1UN3284I6.1IB7, IP1, T6, TP33None2112425 kg50 kgB
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Tellurium hexafluoride2.3UN21952.3, 81None302NoneForbiddenForbiddenD40
Terpene hydrocarbons, n.o.s.3UN2319III3B1, IB3, T4, TP1, TP2915020324260 L220 LA
Terpinolene3UN2541III3B1, IB3, T2, TP115020324260 L220 LA
Tetraazido benzene quinoneForbidden
Tetrabromoethane6.1UN2504III6.1IB3, T4, TP115320324160 L220 LA
1,1,2,2-Tetrachloroethane6.1UN1702II6.1IB2, N36, T7, TP21532022435 L60 LA40
Tetrachloroethylene6.1UN1897III6.1IB3, N36, T4, TP115320324160 L220 LA40
Tetraethyl dithiopyrophosphate6.1UN1704II6.1IB2, T7, TP215321224225 kg100 kgD40
Tetraethyl silicate3UN1292III3B1, IB3, T2, TP115020324260 L220 LA
Tetraethylammonium perchlorate (dry)Forbidden
Tetraethylenepentamine8UN2320III8IB3, T4, TP11542032415 L60 LA
1,1,1,2-Tetrafluoroethane or Refrigerant gas R 134a2.2UN31592.2T50306304314, 31575 kg150 kgA
Tetrafluoroethylene, stabilized2.1UN10812.1306304NoneForbidden150 kgE40
Tetrafluoromethane or Refrigerant gas R 142.2UN19822.2None302None75 kg150 kgA
1,2,3,6-Tetrahydrobenzaldehyde3UN2498III3B1, IB3, T2, TP115020324260 L220 LA
Tetrahydrofuran3UN2056II3IB2, T4, TP1None2022425 L60 LB
Tetrahydrofurfurylamine3UN2943III3B1, IB3, T2, TP115020324260 L220 LA
Tetrahydrophthalic anhydrides with more than 0.05 percent of maleic anhydride8UN2698III8IB8, IP3, T1, TP3315421324025 kg100 kgA
1,2,3,6-Tetrahydropyridine3UN2410II3IB2, T4, TP11502022425 L60 LB
Tetrahydrothiophene3UN2412II3IB2, T4, TP11502022425 L60 LB
Tetramethylammonium hydroxide, solid8UN3423II8B2, IB8, IP2, IP4, T3, TP3315421324015 kg50 kgA52
Tetramethylammonium hydroxide solution8UN1835II8B2, IB2, T7, TP21542022421 L30 LA52
III8B2, IB3, T7, TP21542032415 L60 LA52
Tetramethylene diperoxide dicarbamideForbidden
Tetramethylsilane3UN2749I3A7, T14, TP2None201243Forbidden30 LD
Tetranitro diglycerinForbidden
Tetranitroaniline1.1DUN0207II1.1DNone62NoneForbiddenForbidden10
+Tetranitromethane5.1UN1510I5.1, 6.12, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP44None227NoneForbiddenForbiddenD40, 66
2,3,4,6-TetranitrophenolForbidden
2,3,4,6-Tetranitrophenyl methyl nitramineForbidden
2,3,4,6-TetranitrophenylnitramineForbidden
Tetranitroresorcinol (dry)Forbidden
2,3,5,6-Tetranitroso-1,4-dinitrobenzeneForbidden
2,3,5,6-Tetranitroso nitrobenzene (dry)Forbidden
Tetrapropylorthotitanate3UN2413III3B1, IB3, T4, TP115020324260 L220 LA
Tetrazene, see Guanyl nitrosaminoguanyltetrazene
Tetrazine (dry)Forbidden
Tetrazol-1-acetic acid1.4CUN0407II1.4CNone62NoneForbidden75 kg09
1H-Tetrazole1.1DUN05041.1DNone62NoneForbiddenForbiddenB1E, 5E
Tetrazolyl azide (dry)Forbidden
Tetryl, see Trinitrophenylmethylnitramine
A I WTextile waste, wet4.2UN1857III4.2151213240ForbiddenForbiddenA
Thallium chlorate5.1UN2573II5.1, 6.1IB6, IP2, T3, TP331522122425 kg25 kgA56, 58
Thallium compounds, n.o.s.6.1UN1707II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Thallium nitrate6.1UN2727II6.1, 5.1IB6, IP2, T3, TP331532122425 kg25 kgA
4-Thiapentanal6.1UN2785III6.1IB3, T4, TP115320324160 L220 LD25, 49
Thioacetic acid3UN2436II3IB2, T4, TP11502022425 L60 LB
Thiocarbamate pesticide, liquid, flammable, toxic, flash point less than 23 degrees C3UN2772I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LB40
II3, 6.1IB2, T11, TP13, TP271502022431 L60 LB40
Thiocarbamate pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN3005I6.1, 3T14, TP2, TP13None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3IB3, T7, TP2, TP2815320324260 L220 LA40
Thiocarbamate pesticide, liquid, toxic6.1UN3006I6.1T14, TP2, TP13None2012431 L30 LB40
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1IB3, T7, TP2, TP2815320324160 L220 LA40
Thiocarbamate pesticides, solid, toxic6.1UN2771I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Thiocarbonylchloride, see Thiophosgene
Thioglycol6.1UN2966II6.1IB2, T7, TP21532022435 L60 LA
Thioglycolic acid8UN1940II8A7, B2, IB2, N34, T7, TP21542022421 L30 LA
Thiolactic acid6.1UN2936II6.1IB2, T7, TP21532022435 L60 LA
Thionyl chloride8UN1836I8B6, B10, N34, T10, TP2, TP12, TP13None201243ForbiddenForbiddenC40
Thiophene3UN2414II3IB2, T4, TP11502022425 L60 LB40
+Thiophosgene6.1UN2474II6.12, B9, B14, B32, B74, N33, N34, T20, TP2, TP38, TP45None227244ForbiddenForbiddenB40, 52
Thiophosphoryl chloride8UN1837II8A3, A7, B2, B8, B25, IB2, N34, T7, TP2None202242Forbidden30 LC40
Thiourea dioxide4.2UN3341II4.2IB6, IP2, T3, TP33None21224115 kg50 kgD
III4.2IB8, IP3, T1, TP33None21324125 kg100 kgD
Tin chloride, fuming, see Stannic chloride, anhydrous
Tin perchloride or Tin tetrachloride, see Stannic chloride, anhydrous
Tinctures, medicinal3UN1293II3IB2, T4, TP1, TP81502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Tinning flux, see Zinc chloride
Titanium disulphide4.2UN3174III4.2IB8, IP3, T1, TP33None21324125 kg100 kgA
Titanium hydride4.1UN1871II4.1A19, A20, IB4, N34, T3, TP33None21224115 kg50 kgE
Titanium powder, dry4.2UN2546I4.2None211242ForbiddenForbiddenD
II4.2A19, A20, IB6, IP2, N5, N34, T3, TP33None21224115 kg50 kgD
III4.2IB8, IP3, T1, TP33None21324125 kg100 kgD
Titanium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns4.1UN1352II4.1A19, A20, IB6, IP2, N34, T3, TP33None21224015 kg50 kgE74
Titanium sponge granules or Titanium sponge powders4.1UN2878III4.1A1, IB8, IP3, T1, TP33None21324025 kg100 kgD74
+Titanium tetrachloride8UN1838II8, 6.12, B7, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenC40
Titanium trichloride mixtures8UN2869II8A7, IB8, IP2, IP4, N34, T3, TP3315421224015 kg50 kgA40
III8A7, IB8, IP3, N34, T1, TP3315421324025 kg100 kgA40
Titanium trichloride, pyrophoric or Titanium trichloride mixtures, pyrophoric4.2UN2441I4.2, 8N34None181244ForbiddenForbiddenD40
TNT mixed with aluminum, see Tritonal
TNT, see Trinitrotoluene, etc
Toluene3UN1294II3IB2, T4, TP11502022425 L60 LB
+Toluene diisocyanate6.1UN2078II6.1IB2, T7, TP2, TP131532022435 L60 LD25, 40
Toluene sulfonic acid, see Alkyl, or Aryl sulfonic acid etc
+Toluidines, liquid6.1UN1708II6.1IB2, T7, TP21532022435 L60 LA
Toluidines, solid6.1UN3451II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
2,4-Toluylenediamine, solid or 2,4-Toluenediamine, solid6.1UN1709III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
2,4-Toluylenediamine solution or 2,4-Toluenediamine solution6.1UN3418III6.1IB3, T4, TP115320324160 L220 LA
Torpedoes, liquid fueled, with inert head1.3JUN0450II1.3J62NoneForbiddenForbidden0423E
Torpedoes, liquid fueled, with or without bursting charge1.1JUN0449II1.1J62NoneForbiddenForbidden0423E
Torpedoes with bursting charge1.1EUN0329II1.1E62NoneForbiddenForbidden03
Torpedoes with bursting charge1.1FUN0330II1.1F62NoneForbiddenForbidden08
Torpedoes with bursting charge1.1DUN0451II1.1D62NoneForbiddenForbidden03
GToxic by inhalation liquid, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC506.1UN3381I6.11, B9, B14, B30, B72, T22, TP2, TP13, TP27, TP38, TP44None226244ForbiddenForbiddenD40
GToxic by inhalation liquid, n.o.s. with an inhalation toxicity toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC506.1UN3382I6.12, B9, B14, B32, B74, T20, TP2, TP13, TP27, TP38, TP4527, TP38, TP4513None227244ForbiddenForbiddenD40
GToxic by inhalation liquid, flammable, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC506.1UN3383I6.1, 31, B9, B14, B30, B72, T22, TP2, TP13, TP27, TP38, TP44None226244ForbiddenForbiddenD40
GToxic by inhalation liquid, flammable, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC506.1UN3384I6.1, 32, B9, B14, B32, B74, T20, TP2, TP13, TP27, TP38, TP45None227244ForbiddenForbiddenD40
GToxic by inhalation liquid, water-reactive, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC506.1UN3385I6.1, 4.31, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44None226244ForbiddenForbiddenD40
GToxic by inhalation liquid, water-reactive, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC506.1UN3386I6.1, 4.32, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP44None227244ForbiddenForbiddenD40
GToxic by inhalation liquid, oxidizing, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC506.1UN3387I6.1, 5.11, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44None226244ForbiddenForbiddenD40
GToxic by inhalation liquid, oxidizing, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC506.1UN3388I6.1, 5.12, B9, B14, B32, T20, TP2, TP13, TP38, TP44None227244ForbiddenForbiddenD40
GToxic by inhalation liquid, corrosive, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC506.1UN3389I6.1, 81, B9, B14, B30, B72, T22, TP2, TP13, TP27, TP38, TP44None226244ForbiddenForbiddenD40
GToxic by inhalation liquid, corrosive, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC506.1UN3390I6.1, 82, B9, B14, B32, B74, T20, TP2, TP13, TP27, TP38, TP45None227244ForbiddenForbiddenD40
GToxic liquid, corrosive, inorganic, n.o.s.6.1UN3289I6.1, 8T14, TP2, TP13, TP27None2012430.5 L2.5 LA
II6.1, 8IB2, T11, TP2, TP271532022431 L30 LA
GToxic liquid, inorganic, n.o.s.6.1UN3287I6.1T14, TP2, TP13, TP27None2012431 L30 LA
II6.1IB2, T11, TP2, TP271532022435 L60 LA
III6.1IB3, T7, TP1, TP2815320324160 L220 LA
GToxic liquids, corrosive, organic, n.o.s.6.1UN2927I6.1, 8T14, TP2, TP13, TP27None2012430.5 L2.5 LB40
II6.1, 8IB2, T11, TP2, TP271532022431 L30 LB40
GToxic liquids, flammable, organic, n.o.s.6.1UN2929I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
GToxic, liquids, organic, n.o.s.6.1UN2810I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1IB3, T7, TP1, TP2815320324160 L220 LA40
GToxic liquids, oxidizing, n.o.s.6.1UN3122I6.1, 5.1A4None201243Forbidden2.5 LC
II6.1, 5.1IB21532022431 L5 LC
GToxic liquids, water-reactive, n.o.s.6.1UN3123I6.1, 4.3A4None201243Forbidden1 LE40
II6.1, 4.3IB2None2022431 L5 LE40
GToxic solid, corrosive, inorganic, n.o.s.6.1UN3290I6.1, 8IB7, T6, TP33None2112421 kg25 kgA
II6.1, 8IB6, IP2, T3, TP3315321224215 kg50 kgA
GToxic solid, inorganic, n.o.s.6.1UN3288I6.1IB7, T6, TP33None2112425 kg50 kgA
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
GToxic solids, corrosive, organic, n.o.s.6.1UN2928I6.1, 8IB7, T6, TP33None2112421 kg25 kgB40
II6.1, 8IB6, IP2, T3, TP3315321224215 kg50 kgB40
GToxic solids, flammable, organic, n.o.s.6.1UN2930I6.1, 4.1IB6, T6, TP33None2112421 kg15 kgB
II6.1, 4.1IB8, IP2, IP4, T3, TP3315321224215 kg50 kgB
GToxic solids, organic, n.o.s.6.1UN2811I6.1IB7, T6, TP33None2112425 kg50 kgB
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
GToxic solids, oxidizing, n.o.s.6.1UN3086I6.1, 5.1T6, TP33None2112421 kg15 kgC
II6.1, 5.1IB6, IP2, T3, TP3315321224215 kg50 kgC
GToxic solids, self-heating, n.o.s.6.1UN3124I6.1, 4.2A5, T6, TP33None2112425 kg15 kgD40
II6.1, 4.2IB6, IP2, T3, TP33None21224215 kg50 kgD40
GToxic solids, water-reactive, n.o.s.6.1UN3125I6.1, 4.3A5, T6, TP33None2112425 kg15 kgD40
II6.1, 4.3IB6, IP2, T3, TP3315321224215 kg50 kgD40
GToxins, extracted from living sources, liquid, n.o.s.6.1UN3172I6.1141None2012431 L30 LB40
II6.1141, IB2None2022435 L60 LB40
III6.1141, IB315320324160 L220 LB40
Toxins, extracted from living sources, solid, n.o.s.6.1UN3462I6.1141, IB7, IP1, T6, TP33None2112435 kg50 kgB
II6.1141, IB8, IP2, IP4, T3, TP33None21224325 kg100 kgB
III6.1141, IB8, IP3, T1, TP33153213241100 kg200 kgA
DToy Caps1.4SNA0337II1.4SNone62None25 kg100 kg05
Tracers for ammunition1.3GUN0212II1.3GNone62NoneForbiddenForbidden07
Tracers for ammunition1.4GUN0306II1.4GNone62NoneForbidden75 kg06
Tractors, see Vehicle, etc
Tri-(b-nitroxyethyl) ammonium nitrateForbidden
Triallyl borate6.1UN2609III6.1IB315320324160 L220 LA13
Triallylamine3UN2610III3, 8B1, IB3, T4, TP1None2032425 L60 LA40
Triazine pesticides, liquid, flammable, toxic, flash point less than 23 degrees C3UN2764I3, 6.1T14, TP2, TP13, TP27None201243Forbidden30 LB40
II3, 6.1IB2, T11, TP2, TP13, TP271502022431 L60 LB40
Triazine pesticides, liquid, toxic6.1UN2998I6.1T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1IB3, T7, TP2, TP2815320324160 L220 LA40
Triazine pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C6.1UN2997I6.1, 3T14, TP2, TP13, TP27None2012431 L30 LB40
II6.1, 3IB2, T11, TP2, TP13, TP271532022435 L60 LB40
III6.1, 3IB3, T7, TP2, TP2815320324260 L220 LA40
Triazine pesticides, solid, toxic6.1UN2763I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA40
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA40
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Tributylamine6.1UN2542II6.1IB2, T7, TP21532022435 L60 LA
Tributylphosphane4.2UN3254I4.2T21, TP7, TP33None211242ForbiddenForbiddenD136
Trichloro-s-triazinetrione dry, with more than 39 percent available chlorine, see Trichloroisocyanuric acid, dry
Trichloroacetic acid8UN1839II8A7, IB8, IP2, IP4, N34, T3, TP3315421224015 kg50 kgA
Trichloroacetic acid, solution8UN2564II8A3, A6, A7, B2, IB2, N34, T7, TP21542022421 L30 LB
III8A3, A6, A7, IB3, N34, T4, TP11542032415 L60 LB8
+Trichloroacetyl chloride8UN2442II8, 6.12, B9, B14, B32, B74, N34, T20, TP2, TP38, TP45None227244ForbiddenForbiddenD40
Trichlorobenzenes, liquid6.1UN2321III6.1IB3, T4, TP115320324160 L220 LA
Trichlorobutene6.1UN2322II6.1IB2, T7, TP21532022435 L60 LA25, 40
1,1,1-Trichloroethane6.1UN2831III6.1IB3, N36, T4, TP115320324160 L220 LA40
Trichloroethylene6.1UN1710III6.1IB3, N36, T4, TP115320324160 L220 LA40
Trichloroisocyanuric acid, dry5.1UN2468II5.1IB8, IP4, T3, TP331522122405 kg25 kgA13
Trichloromethyl perchlorateForbidden
Trichlorosilane4.3UN1295I4.3, 3, 8N34, T14, TP2, TP7, TP13None201244ForbiddenForbiddenD21, 28, 40, 49, 100
Tricresyl phosphate with more than 3 percent ortho isomer6.1UN2574II6.1A3, IB2, N33, N34, T7, TP21532022435 L60 LA
Triethyl phosphite3UN2323III3B1, IB3, T2, TP115020324260 L220 LA
Triethylamine3UN1296II3, 8IB2, T7, TP11502022431 L5 LB40
Triethylenetetramine8UN2259II8B2, IB2, T7, TP21542022421 L30 LB40, 52
Trifluoroacetic acid8UN2699I8A3, A6, A7, B4, N3, N34, N36, T10, TP2, TP12None2012430.5 L2.5 LB12, 40
Trifluoroacetyl chloride2.3UN30572.3, 82, B7, B9, B14, T50, TP21None304314, 315ForbiddenForbiddenD40
Trifluorochloroethylene, stabilized2.3UN10822.3, 2.13, B14, T50None304314, 315ForbiddenForbiddenD40
Trifluoromethane or Refrigerant gas R 232.2UN19842.2306304314, 31575 kg150 kgA
1,1,1-Trifluoroethane or Refrigerant gas, R 143a2.1UN20352.1T50306304314, 315Forbidden150 kgB40
Trifluoromethane, refrigerated liquid2.2UN31362.2T75, TP5306None314, 31550 kg500 kgD
2-Trifluoromethylaniline6.1UN2942III6.1IB315320324160 L220 LA
3-Trifluoromethylaniline6.1UN2948II6.1IB2, T7, TP21532022435 L60 LA40
Triformoxime trinitrateForbidden
Triisobutylene3UN2324III3B1, IB3, T4, TP115020324260 L220 LA
Triisopropyl borate3UN2616II3IB2, T4, TP11502022425 L60 LA
III3B1, IB3, T2, TP115020324260 L220 LA
DTrimethoxysilane6.1NA9269I6.1, 32, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45None227244ForbiddenForbiddenE40
Trimethyl borate3UN2416II3IB2, T7, TP11502022425 L60 LB
Trimethyl phosphite3UN2329III3B1, IB3, T2, TP115020324260 L220 LA
1,3,5-Trimethyl-2,4,6-trinitrobenzeneForbidden
Trimethylacetyl chloride6.1UN2438I6.1, 8, 32, B3, B9, B14, B32, B74, N34, T20, TP2, TP13, TP38, TP45None227244ForbiddenForbiddenD25, 40
Trimethylamine, anhydrous2.1UN10832.1T50306304314, 315Forbidden150 kgB40
Trimethylamine, aqueous solutions with not more than 50 percent trimethylamine by mass3UN1297I3, 8T11, TP1None2012430.5 L2.5 LD40, 135
II3, 8B1, IB2, T7, TP11502022431 L5 LB40, 41
III3, 8B1, IB3, T7, TP11502032425 L60 LA40, 41
1,3,5-Trimethylbenzene3UN2325III3B1, IB3, T2, TP115020324260 L220 LA
Trimethylchlorosilane3UN1298II3, 8A3, A7, B77, IB2, N34, T7, TP2, TP131502022431 L5 LE40
Trimethylcyclohexylamine8UN2326III8IB3, T4, TP11542032415 L60 LA
Trimethylene glycol diperchlorateForbidden
Trimethylhexamethylene diisocyanate6.1UN2328III6.1IB3, T4, TP2, TP1315320324160 L220 LB
Trimethylhexamethylenediamines8UN2327III8IB3, T4, TP11542032415 L60 LA
Trimethylol nitromethane trinitrateForbidden
Trinitro-meta-cresol1.1DUN0216II1.1DNone62NoneForbiddenForbidden105E
2,4,6-Trinitro-1,3-diazobenzeneForbidden
2,4,6-Trinitro-1,3,5-triazido benzene (dry)Forbidden
Trinitroacetic acidForbidden
TrinitroacetonitrileForbidden
Trinitroamine cobaltForbidden
Trinitroaniline or Picramide1.1DUN0153II1.1DNone62NoneForbiddenForbidden10
Trinitroanisole1.1DUN0213II1.1DNone62NoneForbiddenForbidden10
Trinitrobenzene (picryl chloride), wetted, with not less than 10% water by mass4.1UN3365I4.1162, A8, A19, N41, N84None211None0.5 kg0.5 kgE36
Trinitrobenzene, wetted, with not less than 10% water, by mass4.1UN3367I4.1162, A8, A19, N41, N84None211None0.5 kg0.5 kgE36
Trinitrobenzene, dry or wetted with less than 30 percent water, by mass1.1DUN0214II1.1DNone62NoneForbiddenForbidden10
Trinitrobenzene, wetted with not less than 30 percent water, by mass4.1UN1354I4.123, A2, A8, A19, N41None211None0.5 kg0.5 kgE28
Trinitrobenzenesulfonic acid1.1DUN0386II1.1DNone62NoneForbiddenForbidden105E
Trinitrobenzoic acid, dry or wetted with less than 30 percent water, by mass1.1DUN0215II1.1DNone62NoneForbiddenForbidden10
Trinitrobenzoic acid, wetted with not less than 10% water by mass4.1UN3368I4.1162, A8, A19, N41, N84None211None0.5 kg0.5 kgE36
Trinitrobenzoic acid, wetted with not less than 30 percent water, by mass4.1UN1355I4.123, A2, A8, A19, N41None211None0.5 kg0.5 kgE28
Trinitrochlorobenzene or Picryl chloride1.1DUN0155II1.1DNone62NoneForbiddenForbidden10
TrinitroethanolForbidden
TrinitroethylnitrateForbidden
Trinitrofluorenone1.1DUN0387II1.1DNone62NoneForbiddenForbidden10
TrinitromethaneForbidden
1,3,5-TrinitronaphthaleneForbidden
Trinitronaphthalene1.1DUN0217II1.1DNone62NoneForbiddenForbidden10
Trinitrophenetole1.1DUN0218II1.1DNone62NoneForbiddenForbidden10
Trinitrophenol (picric acid), wetted, with not less than 10 percent water by mass4.1UN3364I4.1162, A8, A19, N41, N84None211None0.5 kg0.5 kgE36
Trinitrophenol or Picric acid, dry or wetted with less than 30 percent water, by mass1.1DUN0154II1.1DNone62NoneForbiddenForbidden105E
Trinitrophenol, wetted with not less than 30 percent water, by mass4.1UN1344I4.123, A8, A19, N41None211None1 kg15 kgE28, 36
2,4,6-Trinitrophenyl guanidine (dry)Forbidden
2,4,6-Trinitrophenyl nitramineForbidden
2,4,6-Trinitrophenyl trimethylol methyl nitramine trinitrate (dry)Forbidden
Trinitrophenylmethylnitramine or Tetryl1.1DUN0208II1.1DNone62NoneForbiddenForbidden10
Trinitroresorcinol or Styphnic acid, dry or wetted with less than 20 percent water, or mixture of alcohol and water, by mass1.1DUN0219II1.1DNone62NoneForbiddenForbidden105E
Trinitroresorcinol, wetted or Styphnic acid, wetted with not less than 20 percent water, or mixture of alcohol and water by mass1.1DUN0394II1.1DNone62NoneForbiddenForbidden105E
2,4,6-Trinitroso-3-methyl nitraminoanisoleForbidden
Trinitrotetramine cobalt nitrateForbidden
Trinitrotoluene and Trinitrobenzene mixtures or TNT and trinitrobenzene mixtures or TNT and hexanitrostilbene mixtures or Trinitrotoluene and hexanitrostilnene mixtures1.1DUN0388II1.1DNone62NoneForbiddenForbidden10
Trinitrotoluene mixtures containing Trinitrobenzene and Hexanitrostilbene or TNT mixtures containing trinitrobenzene and hexanitrostilbene1.1DUN0389II1.1DNone62NoneForbiddenForbidden10
Trinitrotoluene or TNT, dry or wetted with less than 30 percent water, by mass1.1DUN0209II1.1DNone62NoneForbiddenForbidden10
Trinitrotoluene (TNT), wetted, with not less than 10 percent water by mass4.1UN3366I4.1162, A8, A19, N41, N84None211None0.5 kg0.5 kgE36
Trinitrotoluene, wetted with not less than 30 percent water, by mass4.1UN1356I4.123, A2, A8, A19, N41None211None0.5 kg0.5 kgE28
Tripropylamine3UN2260III3, 8B1, IB3, T4, TP11502032425 L60 LA40
Tripropylene3UN2057II3IB2, T4, TP11502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Tris-(1-aziridinyl)phosphine oxide, solution6.1UN2501II6.1IB2, T7, TP21532022435 L60 LA
III6.1IB3, T4, TP115320324160 L220 LA
Tris, bis-bifluoroamino diethoxy propane (TVOPA)Forbidden
Tritonal1.1DUN0390II1.1DNone62NoneForbiddenForbidden10
Tungsten hexafluoride2.3UN21962.3, 82None338NoneForbiddenForbiddenD40
Turpentine3UN1299III3B1, IB3, T2, TP115020324260 L220 LA
Turpentine substitute3UN1300I3T11, TP1, TP8, TP27None2012431 L30 LB
II3IB2, T4, TP11502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Undecane3UN2330III3B1, IB3, T2, TP115020324260 L220 LA
Urea hydrogen peroxide5.1UN1511III5.1, 8A1, A7, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA13
Urea nitrate, dry or wetted with less than 20 percent water, by mass1.1DUN0220II1.1D119None62NoneForbiddenForbidden10
Urea nitrate, wetted, with not less than 10 percent water by mass4.1UN3370I4.1162, A8, A19, N41, N84None211None0.5 kg0.5 kgE36
Urea nitrate, wetted with not less than 20 percent water, by mass4.1UN1357I4.123, 39, A8, A19, N41None211None1 kg15 kgE28, 36
Urea peroxide, see Urea hydrogen peroxide
Valeraldehyde3UN2058II3IB2, T4, TP11502022425 L60 LB
Valeric acid, see Corrosive liquids, n.o.s.
Valeryl chloride8UN2502II8, 3A3, A6, A7, B2, IB2, N34, T7, TP21542022431 L30 LC40
Vanadium compound, n.o.s.6.1UN3285I6.1IB7, IP1, T6, TP33None2112425 kg50 kgB
II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgB
III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA
Vanadium oxytrichloride8UN2443II8A3, A6, A7, B2, B16, IB2, N34, T7, TP2154202242Forbidden30 LC40
Vanadium pentoxide, non-fused form6.1UN2862III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA40
Vanadium tetrachloride8UN2444I8A3, A6, A7, B4, N34, T10, TP2None201243Forbidden2.5 LC40
Vanadium trichloride8UN2475III8IB8, IP3, T1, TP3315421324025 kg100 kgA40
Vanadyl sulfate6.1UN2931II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Vehicle, flammable gas powered9UN31669135, 157220220220ForbiddenNo limitA
Vehicle, flammable liquid powered9UN31669135, 157220220220No limitNo limitA
Very signal cartridge, see Cartridges, signal
Vinyl acetate, stabilized3UN1301II3IB2, T4, TP11502022425 L60 LB
Vinyl bromide, stabilized2.1UN10852.1T50306304314, 315Forbidden150 kgB40
Vinyl butyrate, stabilized3UN2838II3IB2, T4, TP11502022425 L60 LB
Vinyl chloride, stabilized2.1UN10862.121, B44, T50306304314, 315Forbidden150 kgB40
Vinyl chloroacetate6.1UN2589II6.1, 3IB2, T7, TP21532022435 L60 LA
Vinyl ethyl ether, stabilized3UN1302I3A3, T11, TP2None2012431 L30 LD
Vinyl fluoride, stabilized2.1UN18602.1306304314, 315Forbidden150 kgE40
Vinyl isobutyl ether, stabilized3UN1304II3IB2, T4, TP11502022425 L60 LB
Vinyl methyl ether, stabilized2.1UN10872.1B44, T50306304314, 315Forbidden150 kgB40
Vinyl nitrate polymerForbidden
Vinylidene chloride, stabilized3UN1303I3T12, TP2, TP71502012431 L30 LE40
Vinylpyridines, stabilized6.1UN3073II6.1, 3, 8IB1, T7, TP2, TP131532022431 L30 LB40
Vinyltoluenes, stabilized3UN2618III3B1, IB3, T2, TP115020324260 L220 LA
Vinyltrichlorosilane, stabilized3UN1305I3, 8A3, A7, B6, N34, T11, TP2, TP13None201243Forbidden2.5 LB40
Warheads, rocket with burster or expelling charge1.4DUN0370II1.4DNone62NoneForbidden75 kg02
Warheads, rocket with burster or expelling charge1.4FUN0371II1.4FNone62NoneForbiddenForbidden08
Warheads, rocket with bursting charge1.1DUN0286II1.1DNone62NoneForbiddenForbidden03
Warheads, rocket with bursting charge1.2DUN0287II1.2DNone62NoneForbiddenForbidden03
Warheads, rocket with bursting charge1.1FUN0369II1.1FNone62NoneForbiddenForbidden08
Warheads, torpedo with bursting charge1.1DUN0221II1.1DNone62NoneForbiddenForbidden03
GWater-reactive liquid, corrosive, n.o.s.4.3UN3129I4.3, 8None201243Forbidden1 LD
II4.3, 8IB1None2022431 L5 LE85
III4.3, 8IB2None2032425 L60 LE
GWater-reactive liquid, n.o.s.4.3UN3148I4.3None201244Forbidden1 LE40
II4.3IB1None2022431 L5 LE40
III4.3IB2None2032425 L60 LE40
GWater-reactive liquid, toxic, n.o.s.4.3UN3130I4.3, 6.1A4None201243Forbidden1 LD
II4.3, 6.1IB1None2022431 L5 LE85
III4.3, 6.1IB2None2032425 L60 LE85
GWater-reactive solid, corrosive, n.o.s.4.3UN3131I4.3, 8IB4, IP1, N40None211242Forbidden15 kgD
II4.3, 8IB6, IP2, T3, TP3315121224215 kg50 kgE85
III4.3, 8IB8, IP4, T1, TP3315121324125 kg100 kgE85
GWater-reactive solid, flammable, n.o.s.4.3UN3132I4.3, 4.1IB4, N40None211242Forbidden15 kgD
II4.3, 4.1IB4, T3, TP3315121224215 kg50 kgE
III4.3, 4.1IB6, T1, TP3315121324125 kg100 kgE
GWater-reactive solid, n.o.s.4.3UN2813I4.3IB4, N40None211242Forbidden15 kgE40
II4.3IB7, IP2, T3, TP3315121224215 kg50 kgE40
III4.3IB8, IP4, T1, TP3315121324125 kg100 kgE40
GWater-reactive, solid, oxidizing, n.o.s.4.3UN3133II4.3, 5.1None214214ForbiddenForbiddenE40
III4.3, 5.1None214214ForbiddenForbiddenE40
GWater-reactive solid, self-heating, n.o.s.4.3UN3135I4.3, 4.2N40None211242Forbidden15 kgE
II4.3, 4.2IB5, IP2, T3, TP33None21224215 kg50 kgE
III4.3, 4.2IB8, IP4, T1, TP33None21324125 kg100 kgE
GWater-reactive solid, toxic, n.o.s.4.3UN3134I4.3, 6.1A8, IB4, IP1, N40None211242Forbidden15 kgD
II4.3, 6.1IB5, IP2, T3, TP3315121224215 kg50 kgE85
III4.3, 6.1IB8, IP4, T1, TP3315121324125 kg100 kgE85
Wheel chair, electric, see Battery powered vehicle or Battery powered equipment
White acid, see Hydrofluoric acid
IWhite asbestos (chrysotile, actinolite, anthophyllite, tremolite)9UN2590III9156, IB8, IP2, IP3, T1, TP33155216240200 kg200 kgA34, 40
Wood preservatives, liquid3UN1306II3149, IB2, T4, TP1, TP81502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA40
A I WWool waste, wet4.2UN1387III4.2151213240ForbiddenForbiddenA
Xanthates4.2UN3342II4.2IB6, IP2, T3, TP33None21224115 kg50 kgD40
III4.2IB8, IP3, T1, TP33None21324125 kg100 kgD40
Xenon2.2UN20362.2306302None75 kg150 kgA
Xenon, refrigerated liquid (cryogenic liquids)2.2UN25912.2T75, TP5320NoneNone50 kg500 kgB
Xylenes3UN1307II3IB2, T4, TP11502022425 L60 LB
III3B1, IB3, T2, TP115020324260 L220 LA
Xylenols, solid6.1UN2261II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Xylenols, liquid6.1UN3430II6.1IB2, T7, TP21532022435 L60 LA
Xylidines, liquid6.1UN1711II6.1IB2, T7, TP21532022435 L60 LA
Xylidines, solid6.1UN3452II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Xylyl bromide, liquid6.1UN1701II6.1A3, A6, A7, IB2, N33, T7, TP2, TP13None340NoneForbidden60 LD40
Xylyl bromide, solid6.1UN3417II6.1A3, A6, A7, IB8, IP2, IP4, N33, T3, TP33None340None25 kg100 kgB40
p-Xylyl diazideForbidden
Zinc ammonium nitrite5.1UN1512II5.1IB8, IP4, T3, TP33None2122425 kg25 kgE
Zinc arsenate or Zinc arsenite or Zinc arsenate and zinc arsenite mixtures6.1UN1712II6.1IB8, IP2, IP4, T3, TP3315321224225 kg100 kgA
Zinc ashes4.3UN1435III4.3A1, A19, IB8, IP4, T1, TP3315121324125 kg100 kgA
Zinc bisulfite solution, see Bisulfites, aqueous solutions, n.o.s.
Zinc bromate5.1UN2469III5.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA56, 58
Zinc chlorate5.1UN1513II5.1A9, IB8, IP2, IP4, N34, T3, TP331522122425 kg25 kgA56, 58
Zinc chloride, anhydrous8UN2331III8IB8, IP3, T1, TP33None21324025 kg100 kgA
Zinc chloride, solution8UN1840III8IB3, T4, TP11542032415 L60 LA
Zinc cyanide6.1UN1713I6.1IB7, IP1, T6, TP33None2112425 kg50 kgA52
Zinc dithionite or Zinc hydrosulfite9UN1931IIINoneIB8, IP3, T1, TP33155204240100 kg200 kgA49
Zinc ethyl, see Diethylzinc
Zinc fluorosilicate6.1UN2855III6.1IB8, IP3, T1, TP33153213240100 kg200 kgA52
Zinc hydrosulfite, see Zinc dithionite
Zinc muriate solution, see Zinc chloride, solution
Zinc nitrate5.1UN1514II5.1IB8, IP4, T3, TP331522122405 kg25 kgA
Zinc permanganate5.1UN1515II5.1IB6, IP2, T3, TP331522122425 kg25 kgD56, 58, 138
Zinc peroxide5.1UN1516II5.1IB6, IP2, T3, TP331522122425 kg25 kgA13, 52, 66, 75
Zinc phosphide4.3UN1714I4.3, 6.1A19, N40None211NoneForbidden15 kgE40, 52, 85
Zinc powder or Zinc dust4.3UN1436I4.3, 4.2A19, IB4, IP1, N40None211242Forbidden15 kgA52, 53
II4.3, 4.2A19, IB7, IP2, T3, TP33None21224215 kg50 kgA52, 53
III4.3, 4.2IB8, IP4, T1, TP33None21324225 kg100 kgA52, 53
Zinc resinate4.1UN2714III4.1A1, IB6, T1, TP3315121324025 kg100 kgA
Zinc selenate, see Selenates or Selenites
Zinc selenite, see Selenates or Selenites
Zinc silicofluoride, see Zinc fluorosilicate
Zirconium, dry, coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns)4.1UN2858III4.1A115121324025 kg100 kgA
Zirconium, dry, finished sheets, strip or coiled wire4.2UN2009III4.2A1, A19None21324025 kg100 kgD
Zirconium hydride4.1UN1437II4.1A19, A20, IB4, N34, T3, TP33None21224015 kg50 kgE
Zirconium nitrate5.1UN2728III5.1A1, A29, IB8, IP3, T1, TP3315221324025 kg100 kgA
Zirconium picramate, dry or wetted with less than 20 percent water, by mass1.3CUN0236II1.3CNone62NoneForbiddenForbidden105E
Zirconium picramate, wetted with not less than 20 percent water, by mass4.1UN1517I4.123, N41None211None1 kg15 kgD28, 36
Zirconium powder, dry4.2UN2008I4.2T21, TP7, TP33None211242ForbiddenForbiddenD
II4.2A19, A20, IB6, IP2, N5, N34, T3, TP33None21224115 kg50 kgD
III4.2IB8, IP3, T1, TP33None21324125 kg100 kgD
Zirconium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns4.1UN1358II4.1A19, A20, IB6, IP2, N34, T3, TP33None21224115 kg50 kgE74
Zirconium scrap4.2UN1932III4.2IB8, IP3, N34, T1, TP33None213240ForbiddenForbiddenD
Zirconium suspended in a liquid3UN1308I3None201243ForbiddenForbiddenB
II3IB2None2022425 L60 LB
III3B1, IB215020324260 L220 LB
Zirconium tetrachloride8UN2503III8IB8, IP3, T1, TP3315421324025 kg100 kgA

10. In Appendix B to § 172.101, the List of Marine Pollutants is amended by removing three entries, revising one entry and adding one entry in appropriate alphabetical order to read as follows:

Appendix B to § 172.101—List of Marine Pollutants.

List of Marine Pollutants

S, M, P (1)Marine Pollutant (2)
[Remove:]Diphenyl oxide and biphenyl phenyl ether mixtures Isoamyl mercaptan Pentanethiols Tetrachlorophenol
[Revise:]
PP2, 6-Di-tert-Butylphenol
[Add:]
*    *    *    *    *
Chloropicrin
*    *    *    *    *

11. In § 172.102:

a. Paragraphs (b)(3), (b)(4), (b)(7) and (b)(8) are revised and a new paragraph (b)(9) is added.

b. In paragraph (c)(1), Special Provisions 47, 135, and 137 are revised; Special Provisions 163, 164, 165, 166, 167, 170 and 171 are added; and Special Provision 143 and 153 are removed.

c. In paragraph (c)(2), a new Special Provision A14 is added.

d. The introductory text of paragraph (c)(3) is revised; in paragraph (c)(3) Special Provision B69 is revised and paragraph (c)(4) is revised.

e. Paragraphs (c)(7)(viii) and (c)(8) are redesignated as paragraphs (c)(8) and (c)(9) respectively, the introductory paragraph of (c)(8) is revised, a new paragraph (c)(8)(ii) is added, Special Provisions TP3 and TP6 are revised and a new Special Provision TP32 and TP33 are added.

f. Paragraph (c)(7) is revised.

The additions and revisions read as follows:

§ 172.102
Special provisions.

(b) * * *

(3) A code containing the letter “B” refers to a special provision that applies only to bulk packaging requirements. Unless otherwise provided in this subchapter, these special provisions do not apply to UN, IM Specification portable tanks or IBCs.

(4) A code containing the letters “IB” or “IP” refers to a special provision that applies only to transportation in IBCs.

(7) A code containing the letter “T” refers to a special provision which applies only to transportation in UN or IM Specification portable tanks.

(8) A code containing the letters “TP” refers to a portable tank special provision for UN or IM Specification portable tanks that is in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter.

(9) A code containing the letter “W” refers to a special provision that applies only to transportation by water.

(c) * * *

(1) * * *

Code/Special Provisions

47 Mixtures of solids that are not subject to this subchapter and flammable liquids may be transported under this entry without first applying the classification criteria of Division 4.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Except when the liquids are fully absorbed in solid material contained in sealed bags, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. Small inner packagings consisting of sealed packets containing less than 10 mL of a Class 3 liquid in Packing Group II or III absorbed into a solid material are not subject to this subchapter provided there is no free liquid in the packet.

135  The entries “Vehicle, flammable gas powered” or “Vehicle, flammable liquid powered,” as appropriate, must be used when internal combustion engines are installed in a vehicle. These entries include hybrid electric vehicles powered by both an internal combustion engine and batteries.

137 Cotton, dry; flax, dry; and sisal, dry are not subject to the requirements of this subchapter when they are baled in accordance with ISO 8115, “Cotton Bales—Dimensions and Density” (IBR, see § 171.7 of this subchapter) to a density of not less than 360 kg/m3 (22.1 lb/ft3) for cotton, 400 kg/m3 (24.97 lb/ft3) for flax and 620 kg/m3 (38.71 lb/ft3) for sisal and transported in a freight container or closed transport vehicle.

163 Substances must satisfactorily pass Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18 (IBR, see § 171.7 of this subchapter).

164 Substances must not be transported under this entry unless approved by the Associate Administrator on the basis of the results of appropriate tests according to Part I of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter). The material must be packaged so that the percentage of diluent does not fall below that stated in the approval at any time during transportation.

165 These substances are susceptible to exothermic decomposition at elevated temperatures. Decomposition can be initiated by heat, moisture or by impurities (e.g., powdered metals (iron, manganese, cobalt, magnesium)). During the course of transportation, these substances must be shaded from direct sunlight and all sources of heat and be placed in adequately ventilated areas.

166 When transported in non-friable tablet form calcium hypochlorite, dry or hydrated, may be transported as a Packing Group III material.

167 These storage systems shall always be considered as containing hydrogen.

170 Air must be eliminated from the vapor space by nitrogen or other means.

171 This entry may only be used when the material is transported in non-friable tablet form or for granular or powered mixtures that have been shown to meet the PG III criteria in § 173.127.

(2) “A” codes. These provisions apply only to transportation by aircraft:

Code/Special Provisions

A14 This material is not authorized to be transported as a limited quantity or consumer commodity in accordance with § 173.306 of this subchapter when transported aboard an aircraft.

(3) “B” codes. These provisions apply only to bulk packagings. Except as otherwise provided in this subchapter, these special provisions do not apply to UN portable tanks or IBCs:

Code/Special Provisions

B69 Dry sodium cyanide or potassium cyanide may be shipped in sift-proof weather-resistant metal covered hopper cars, covered motor vehicles, portable tanks or non-specification bins. Bins must approved by the Associate Administrator.

(4) Table 1 and Table 2—IB Codes and IP Special IBC Packing Provisions. These provisions apply only to transportation in IBCs. When no IBC code is assigned in the § 172.101 Table for a specific proper shipping name, or in § 173.225(e) for Type F organic peroxides, an IBC may not be used unless authorized by the Associate Administrator. The letter “Z” shown in the marking code for composite IBCs must be replaced with a capital code letter designation found in § 178.702(a)(2) of this subchapter to specify the material used for the outer packaging. Tables 1 and 2 follow:

Table 1.—IB Codes (IBC Codes)

IBC CodeAuthorized IBCs
IB1Authorized IBCs: Metal (31A, 31B and 31N).
Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized.
B2Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1).
Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130kPa at 55 °C (1.3 bar at 131 °F) are authorized.
IB3Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2).
Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized, except for UN2672 (also see Special Provision IP8 in Table 3 for UN2672).
IB4Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N).
IB5Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 21HZ1 and 31HZ1).
IB6Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2).
Additional Requirement: Composite IBCs 11HZ2 and 21HZ2 may not be used when the hazardous materials being transported may become liquid during transport.
IB7Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Wooden (11C, 11D and 11F).
Additional Requirement: Liners of wooden IBCs must be sift- proof.
IB8Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2).
IB9IBCs are only authorized if approved by the Associate Administrator.

Table 2.—IP Codes

IBC CodeAuthorized IBCs
IP1IBCs must be packed in closed freight containers or a closed transport vehicle.
IP2When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle.
IP3Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner.
IP4Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner.
IP5IBCs must have a device to allow venting. The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions.
IP6Non-specification bulk bins are authorized.
IP7For UN identification numbers 1327, 1363, 1364, 1365, 1386, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC performance tests specified in part 178, subpart N of this subchapter.
IP8Ammonia solutions may be transported in rigid or composite plastic IBCs (31H1, 31H2 and 31HZ1) that have successfully passed, without leakage or permanent deformation, the hydrostatic test specified in § 178.814 of this subchapter at a test pressure that is not less than 1.5 times the vapor pressure of the contents at 55 °C (131 °F).
IP13Transportation by vessel in IBCs is prohibited.
IP14Air shall be eliminated from the vapor space by nitrogen or other means.
IP20Dry sodium cyanide or potassium cyanide is also permitted in siftproof, water-resistant, fiberboard IBCs when transported in closed freight containers or transport vehicles.

(7) “T” codes. (i) These provisions apply to the transportation of hazardous materials in UN portable tanks. Portable tank instructions specify the requirements applicable to a portable tank when used for the transportation of a specific hazardous material. These requirements must be met in addition to the design and construction specifications in part 178 of this subchapter. Portable tank instructions T1 through T22 specify the applicable minimum test pressure, the minimum shell thickness (in reference steel), bottom opening requirements and pressure relief requirements. Liquefied compressed gases are assigned to portable tank instruction T50. Refrigerated liquefied gases that are authorized to be transported in portable tanks are specified in tank instruction T75.

(ii) The following table specifies the portable tank requirements applicable to “T” Codes T1 through T22. Column 1 specifies the “T” Code. Column 2 specifies the minimum test pressure, in bar (1 bar = 14.5 psig), at which the periodic hydrostatic testing required by § 180.605 of this subchapter must be conducted. Column 3 specifies the section reference for minimum shell thickness or, alternatively, the minimum shell thickness value. Column 4 specifies the applicability of § 178.275(g)(3) of this subchapter for the pressure relief devices. When the word “Normal” is indicated, § 178.275(g)(3) of this subchapter does not apply. Column 5 references the applicable requirements for bottom openings in part 178 of this subchapter or references “Prohibited” which means bottom openings are prohibited. The table follows:

Table of Portable Tank T Codes T1-T22

[Portable tank codes T1-T22 apply to liquid and solid hazardous materials of Classes 3 through 9 which are transported in portable tanks.]

Portable tank instruction (1)Minimum test pressure (bar) (2)Minimum shell thickness (in mm-reference steel) (See § 178.274(d)) (3)Pressure-relief requirements (See § 178.275(g)) (4)Bottom opening requirements (See § 178.275(d)) (5)
T11.5§ 178.274(d)(2)Normal§ 178.275(d)(2)0
T21.5§ 178.274(d)(2)Normal§ 178.275(d)(3)
T32.65§ 178.274(d)(2)Normal§ 178.275(d)(2)
T42.65§ 178.274(d)(2)Normal§ 178.275(d)(3)
T52.65§ 178.274(d)(2)§ 178.275(g)(3)Prohibited
T64§ 178.274(d)(2)Normal§ 178.275(d)(2)
T74§ 178.274(d)(2)Normal§ 178.275(d)(3)
T84§ 178.274(d)(2)NormalProhibited
T946 mmNormalProhibited
T1046 mm§ 178.275(g)(3)Prohibited
T116§ 178.274(d)(2)Normal§ 178.275(d)(3)
T126§ 178.274(d)(2)§ 178.275(g)(3)§ 178.275(d)(3)
T1366 mmNormalProhibited
T1466 mm§ 178.275(g)(3)Prohibited
T1510§ 178.274(d)(2)Normal§ 178.275(d)(3)
T1610§ 178.274(d)(2)§ 178.275(g)(3)§ 178.275(d)(3)
T17106 mmNormal§ 178.275(d)(3)
T18106 mm§ 178.275(g)(3)§ 178.275(d)(3)
T19106 mm§ 178.275(g)(3)Prohibited
T20108 mm§ 178.275(g)(3)Prohibited
T211010 mmNormalProhibited
T221010 mm§ 178.275(g)(3)Prohibited

(iii) T50. When portable tank instruction T50 is referenced in Column (7) of the § 172.101 Table, the applicable liquefied compressed gases are authorized to be transported in portable tanks in accordance with the requirements of § 173.313 of this subchapter.

(iv) T75. When portable tank instruction T75 is referenced in Column (7) of the § 172.101 Table, the applicable refrigerated liquefied gases are authorized to be transported in portable tanks in accordance with the requirements of § 178.277 of this subchapter.

(v) UN and IM portable tank codes/special provisions. When a specific portable tank instruction is specified by a “T” Code in Column (7) of the § 172.101 Table for a specific hazardous material, a specification portable tank conforming to an alternative tank instruction may be used if:

(A) The alternative portable tank has a higher or equivalent test pressure (for example, 4 bar when 2.65 bar is specified);

(B) The alternative portable tank has greater or equivalent wall thickness (for example, 10 mm when 6 mm is specified);

(C) The alternative portable tank has a pressure relief device as specified in the “T” Code. If a frangible disc is required in series with the reclosing pressure relief device for the specified portable tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pressure relief device; and

(D) With regard to bottom openings—

(1) When two effective means are specified, the alternative portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings; or

(2) When three effective means are specified, the portable tank has no bottom openings or three effective means of closure; or

(3) When no bottom openings are authorized, the alternative portable tank must not have bottom openings.

(vi) Except when an organic peroxide is authorized under § 173.225(g), if a hazardous material is not assigned a portable tank “T” Code, the hazardous material may not be transported in a portable tank unless approved by the Associate Administrator.

(8) “TP” codes. (i) These provisions apply to the transportation of hazardous materials in IM and UN Specification portable tanks. Portable tank special provisions are assigned to certain hazardous materials to specify requirements that are in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter. Portable tank special provisions are designated with the abbreviation TP (tank provision) and are assigned to specific hazardous materials in Column (7) of the § 172.101 Table.

(ii) The following is a list of the portable tank special provisions:

Code/Special Provisions

TP3 The maximum degree of filling (in %) for solids transported above their melting points and for elevated temperature liquids shall be determined by the following:

Image Not Available

Where: df and dr are the mean densities of the liquid at the mean temperature of the liquid during filling and the maximum mean bulk temperature during transport respectively.

TP6 The tank must be equipped with a pressure release device which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see § 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous material to be transported.

TP32 Portable tanks may be used subject to the following conditions:

a. Each portable tank constructed of metal must be fitted with a pressure-relief device consisting of a reclosing spring loaded type, a frangible disc or a fusible element. The set to discharge for the spring loaded pressure relief device and the burst pressure for the frangible disc, as applicable, must not be greater than 2.65 bar for portable tanks with minimum test pressures greater than 4 bar;

b. The suitability for transport in tanks must be demonstrated using test 8(d) in Test Series 8 (see UN Manual of Tests and Criteria, Part 1, Sub-section 18.7) (IBR, see § 171.7 of this subchapter) or an alternative means approved by the Associate Administrator.

TP33 The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter.

12. In § 172.202, paragraphs (a)(2)(iii) and (a)(5)(i) are revised to read as follows:

§ 172.202
Description of hazardous material on shipping papers.

(a) * * *

(2) * * *

(iii) For domestic shipments, primary and subsidiary hazard class or division names may be entered following the numerical hazard class or division, or following the basic description.

(5) * * *

(i) For Class I materials, the quantity must be the net explosive mass. For an explosive that is an article, such as Cartridges, small arms, the net explosive mass may be expressed in terms of the net mass of either the article or the explosive materials contained in the article.

13. In § 172.203, paragraphs (f), (m)(2) and (o)(3) are revised and a new paragraph (i)(3) is added to read as follows:

§ 172.203
Additional description requirements.

(f) Transportation by air. A statement indicating that the shipment is within the limitations prescribed for either passenger and cargo aircraft or cargo aircraft only must be entered on the shipping paper.

(i) * * *

(3) For a hazardous material consigned under an “n.o.s.” entry not included in the segregation groups listed in section 3.1.4 of the IMDG Code but belonging, in the opinion of the consignor, to one of these groups, the appropriate segregation group must be shown in association with the basic description (for example, IMDG Code segregation group—1 Acids). When no segregation group is applicable, there is no requirement to indicate that condition.

(m) * * *

(2) For materials that are poisonous by inhalation (see § 171.8 of this subchapter), the words “Poison-Inhalation Hazard” or “Toxic-Inhalation Hazard” and the words “Zone A”, “Zone B”, “Zone C”, or “Zone D”, for gases or “Zone A” or “Zone B” for liquids, as appropriate, must be entered on the shipping description. The word “Poison” or “Toxic” or the phrase “Poison-Inhalation Hazard” or “Toxic Inhalation Hazard” need not be repeated if it otherwise appears in the shipping description.

(o) * * *

(3) The word “SAMPLE” must be included in association with the basic description when a sample of a Division 4.1 (self-reactive) material (see § 173.224(c)(3) of this subchapter) or Division 5.2 (organic peroxide) material (see § 173.225(b)(2) of this subchapter) is offered for transportation.

14. In § 172.204, paragraph (c)(3) is revised to read as follows:

§ 172.204
Shipper's certification.

(c) * * *

(3) Additional certification requirements. Effective October 1, 2006, each person who offers a hazardous material for transportation by air must add to the certification required in this section the following statement:

“I declare that all of the applicable air transport requirements have been met.”

(i) Each person who offers any package or overpack of hazardous materials for transport by air must ensure that:

(A) The articles or substances are not prohibited for transport by air (see the § 172.101 Table);

(B) The articles or substances are properly classed, marked and labeled and otherwise in a condition for transport as required by this subchapter;

(C) The articles or substances are packaged in accordance with all the applicable air transport requirements, including appropriate types of packaging that conform to the packing requirements and the “A” Special Provisions in § 172.102; inner packaging and maximum quantity per package limits; the compatibility requirements (see, for example, § 173.24 of this subchapter); and requirements for closure for both inner and outer packagings, absorbent materials, and pressure differential in § 173.27 of this subchapter. Other requirements may also apply. For example, single packagings may be prohibited, inner packaging may need to be packed in intermediate packagings, and certain materials may be required to be transported in packagings meeting a more stringent performance level.

(ii) [Reserved]

14a. The introductory text of § 172.315 is revised to read as follows:

§ 172.315
Packages containing limited quantities.

Except for transportation by aircraft or as otherwise provided in this subchapter, a package containing a limited quantity of hazardous materials is not required to be marked with the proper shipping name provided it is marked with the identification (ID) number, preceded by the letters “UN” or “NA,” as applicable, for the entry as shown in the § 172.101 Table, and placed within a square-on-point border in accordance with the following:

15. A new § 172.317 is added to read as follows:

§ 172.317
KEEP AWAY FROM HEAT handling mark.

(a) General. For transportation by aircraft, each package containing self-reactive substances of Division 4.1 or organic peroxides of Division 5.2 must be marked with the KEEP AWAY FROM HEAT handling mark specified in this section.

(b) Location and design. The marking must be a rectangle measuring at least 105 mm (4.1 inches) in height by 74 mm (2.9 inches) in width. Markings with not less than half this dimension are permissible where the dimensions of the package can only bear a smaller mark.

(c) KEEP AWAY FROM HEAT handling mark. The KEEP AWAY FROM HEAT handling mark must conform to the following:

(1) Except for size, the KEEP AWAY FROM HEAT handling mark must appear as follows:

Image Not Available

(2) The symbol, letters and border must be black and the background white, except for the starburst which must be red.

(3) The KEEP AWAY FROM HEAT handling marking required by paragraph (a) of this section must be durable, legible and displayed on a background of contrasting color.

§ 172.321
[Removed]

16. Section 172.321 is removed.

PART 173—SHIPPERS—GENERAL REQUIREMENTS FOR SHIPMENTS AND PACKAGINGS

17. The authority citation for part 173 continues to read as follows:

Authority:49 U.S.C. 5101-5127, 44701; 49 CFR 1.45, 1.53.

18. In § 173.3, paragraph (c) introductory text is revised to read as follows:

§ 173.3
Packaging and exceptions.

(c) Salvage drums. During transportation, as defined in 49 U.S.C. 5102(12), damaged or defective hazardous materials packages, hazardous materials packages that are found not to conform with the requirements of this subchapter, leaking hazardous materials packages, or hazardous materials that have spilled or leaked may be placed for repackaging or disposal in a metal or plastic removable head salvage drum that is compatible with the lading under the following conditions:

19. In § 173.24, paragraphs (g) and (i) are revised to read as follows:

§ 173.24
General requirements for packagings and packages.

(g) Venting. Venting of packagings, to reduce internal pressure which may develop by the evolution of gas from the contents, is permitted only when—

(1) Transportation by aircraft is not involved;

(2) Except as otherwise provided in this subchapter, the evolved gases are not poisonous, likely to create a flammable mixture with air or be an asphyxiant under normal conditions of transportation;

(3) The packaging is designed so as to preclude an unintentional release of hazardous materials from the receptacle;

(4) For bulk packagings, other than IBCs, venting is authorized for the specific hazardous material by a special provision in the § 172.101 table or by the applicable bulk packaging specification in part 178 of this subchapter; and

(5) Intermediate bulk packagings (IBCs) may be vented when required to reduce internal pressure that may develop by the evolution of gas subject to the requirements of paragraphs (g)(1) through (g)(3) of this section. The IBC must be of a type that has successfully passed (with the vent in place) the applicable design qualification tests with no release of hazardous material.

(i) Air transportation. Packages offered or intended for transportation by aircraft are subject to requirements additional to those of other modes of transport (e.g., quantity limitations, requirements for absorbent material, pressure differential requirements, appropriate closure procedures, and specific packaging requirements) and must conform to the general requirements for transportation by aircraft in § 173.27.

20. In § 173.25, paragraphs (a)(2) and (a)(4) are revised to read as follows:

§ 173.25
Authorized packagings and overpacks.

(a) * * *

(2) The overpack is marked with the proper shipping name and identification number, when applicable, and is labeled as required by this subchapter for each hazardous material contained therein, unless marking and labels representative of each hazardous material in the overpack are visible.

(4) The overpack is marked with the word “OVERPACK” when specification packagings are required, unless specification markings on the inside packages are visible. Alternatively, until October 1, 2007, the overpack may be marked with a statement indicating that the “inside (inner) packages comply with prescribed specifications.”

21. In § 173.27, paragraph (i) is revised to read as follows:

§ 173.27
General requirements for transportation by aircraft.

(i) Effective October 1, 2006, each person who offers a hazardous material for transportation by aircraft must include the certification statement specified in § 172.204(c)(3).

22. In § 173.28, paragraph (c)(2) introductory text is revised to read as follows:

§ 173.28
Reuse, reconditioning and remanufacture of packagings.

(c) * * *

(2) For the purpose of this subchapter, reconditioning of a non-bulk packaging other than a metal drum includes:

23. In § 173.115, a new paragraph (k) is added to read as follows:

§ 173.115
Class 2, Division 2.1, 2.2 and 2.3—Definitions.

(k) The following applies to aerosols (see § 171.8 of this subchapter):

(1) An aerosol must be assigned to Division 2.1 if the contents include 85% by mass or more flammable components and the chemical heat of combustion is 30 kJ/g or more;

(2) An aerosol must be assigned to Division 2.2 if the contents contain 1% by mass or less flammable components and the heat of combustion is less than 20 kJ/g.

(3) Aerosols not meeting the provisions of paragraphs (a) or (b) of this section must be classed in accordance with the appropriate tests of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter).

(4) Division 2.3 gases may not be transported in an aerosol container.

(5) When the contents are classified as Division 6.1 or Class 8, PG III, the aerosol must be assigned a subsidiary hazard of Division 6.1 or Class 8.

(6) Substances of Division 6.1, PG I or II, and substances of Class 8, PG I are forbidden from transportation in an aerosol container.

(7) Flammable components are Class 3 flammable liquids, Class 4.1 flammable solids, or Division 2.1 flammable gases. The chemical heat of combustion must be determined in accordance with the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter).

24. In § 173.128, paragraph (d)(1) is revised to read as follows:

§ 173.128
Class 5, Division 5.2—Definitions and types.

(d) Approvals. (1) An organic peroxide must be approved, in writing, by the Associate Administrator, before being offered for transportation or transported, including assignment of a generic type and shipping description, except for—

(i) An organic peroxide which is identified by technical name in the Organic Peroxides Table in § 173.225(c);

(ii) A mixture of organic peroxides prepared according to § 173.225(b); or

(iii) An organic peroxide which may be shipped as a sample under the provisions of § 173.225(b).

25. In 173.132, paragraph (b)(1) is revised to read as follows:

§ 173.132
Class 6, Division 6.1—Definitions.

(b) * * *

(1) LD50 (median lethal dose) for acute oral toxicity is the statistically derived single dose of a substance that can be expected to cause death within 14 days in 50% of young adult albino rats when administered by the oral route. The LD50 value is expressed in terms of mass of test substance per mass of test animal (mg/kg).

26. In § 173.136, paragraph (d) is added to read as follows:

§ 173.136
Class 8—Definitions.

(d) Steel or aluminum corrosion test data produced no later than September 30, 2005, using the procedures of § 173.137(c)(2), in effect on September 30, 2004 (see 49 CFR 173.137 revised as of October 1, 2003), for appropriate steel or aluminum types may be used for classification and assignment of packing group for Class 8 materials corrosive to steel or aluminum.

27. In § 173.137, paragraph (c)(2) is revised to read as follows:

§ 173.137
Class 8—Assignment of packing group.

(c) * * *

(2) That do not cause full thickness destruction of intact skin tissue but exhibit a corrosion on steel or aluminum surfaces exceeding 6.25 mm (0.25 inch) a year at a test temperature of 55 °C (130 °F). The corrosion must be determined in accordance with the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter).

28. In § 173.150, paragraph (a), the introductory text of paragraph (b), paragraph (b)(2) and paragraph (c) are revised to read as follows:

§ 173.150
Exceptions for Class 3 (flammable) and combustible liquids.

(a) General. Exceptions for hazardous materials shipments in the following paragraphs are permitted only if this section is referenced for the specific hazardous material in the § 172.101 Table of this subchapter.

(b) Limited quantities. Limited quantities of flammable liquids (Class 3) and combustible liquids are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:

(2) For flammable liquids in Packing Group II, inner packagings not over 1.0 L (0.3 gallons) net capacity each, unless the material has a subsidiary hazard of Division 6.1, Packing Group II, in which case the inner packagings may not exceed 100 mL (3.38 ounces) net capacity each, packed in a strong outer packaging.

(c) Consumer commodities. Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section and is a “consumer commodity” as defined in 171.8 of this subchapter, may be renamed “Consumer commodity” and reclassed as ORM-D material. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or are offered for transportation and transported by aircraft, and are eligible for the exceptions provided in § 173.156.

29. In 173.151, paragraphs (b) and (c), and the introductory text of paragraph (d) are revised to read as follows:

§ 173.151
Exceptions for Class 4.

(b) Limited quantities of Division 4.1. Limited quantities of flammable solids (Division 4.1) in Packing Group II or III are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:

(1) For flammable solids in Packing Group II, inner packagings not over 1.0 kg (2.2 pounds) net capacity each, unless the material has a subsidiary hazard of Division 6.1, Packing Group II, in which case the inner packagings may not exceed 0.5 kg (1.1 pounds) net capacity each, packed in a strong outer packaging.

(2) For flammable solids in Packing Group III, inner packagings not over 5.0 kg (11 pounds) net capacity each, packed in a strong outer packaging.

(c) Consumer commodities. Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section, and charcoal briquettes in packagings not exceeding 30 kg (66 pounds) gross weight, may be renamed “Consumer commodity” and reclassed as ORM-D material if the material is a “consumer commodity” as defined in 171.8 of this subchapter. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or is offered for transportation and transported by aircraft, and are eligible for the exceptions provided in § 173.156.

(d) Limited quantities of Division 4.3. Limited quantities of dangerous when wet (Division 4.3) solids in Packing Group II or III are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:

30. In § 173.152, the introductory text of paragraph (b), paragraph (b)(1), and paragraph (c) are revised to read as follows:

§ 173.152
Exceptions for Division 5.1 (oxidizers) and Division 5.2 (organic peroxides).

(b) Limited quantities. Limited quantities of oxidizers (Division 5.1) in Packing Group II and III and organic peroxides are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:

(1) For oxidizers in Packing Group II, inner packagings not over 1.0 L (0.3 gallon) net capacity each for liquids or not over 1.0 kg (2.2 pounds) net capacity each for solids, unless the material has a subsidiary hazard of Division 6.1, Packing Group II, in which case the inner packagings may not exceed 100 mL (3.38 ounces) for liquids or 0.5 kg (1.1 pounds) for solids, packed in a strong outer packaging.

(c) Consumer commodities. Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section, and is a “consumer commodity” as defined in § 171.8 of this subchapter, may be renamed “Consumer commodity” and reclassed as ORM-D. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or are offered for transportation and transported by aircraft, and are eligible for the exceptions provided in § 173.156.

31. In § 173.153, paragraph (b), and paragraph (c)(1) are revised to read as follows:

§ 173.153
Exceptions for Division 6.1 (poisonous materials).

(b) Limited quantities. The exceptions in this paragraph do not apply to poison-by-inhalation materials. Limited quantities of poisonous materials (Division 6.1) in Packing Group II and III are excepted from the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:

(1) For poisonous materials in Packing Group II, inner packagings not over 100 mL (3.38 ounces) each for liquids or 0.5 kg (1.1 pounds) each for solids, packed in a strong outer packaging.

(2) For poisonous materials in Packing Group III, inner packagings not over 4 L (1.0 gallon) each for liquids or 5.0 kg (11 pounds) each for solids, packed in a strong outer packaging.

(c) * * *

(1) A limited quantity of poisonous material in Packing Group III which conforms to the provisions of paragraph (b) of this section, and is a “consumer commodity” as defined in § 171.8 of this subchapter, may be renamed “Consumer commodity” and reclassed as ORM-D.

32. In § 173.154, the introductory text of paragraph (b), paragraph (b)(1), and paragraph (c) are revised to read as follows:

§ 173.154
Exceptions for Class 8 (corrosive materials).

(b) Limited quantities. Limited quantities of corrosive materials (Class 8) in Packing Group II and III are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:

(1) For corrosive materials in Packing Group II, inner packagings not over 1.0 L (0.3 gallon) net capacity each for liquids or not over 1.0 kg (2.2 pounds) net capacity each for solids, unless the material has a subsidiary hazard of Division 6.1, Packing Group II in which case the inner packagings may not exceed 100 mL (3.38 ounces) for liquids or 0.5 kg (1.1 pounds) for solids, packed in a strong outer packaging.

(c) Consumer commodities. Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section, and is a “consumer commodity” as defined in § 171.8 of this subchapter, may be renamed “Consumer commodity” and reclassed as ORM-D. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or are offered for transportation and transported by aircraft, and are eligible for the exceptions provided in § 173.156.

33. In § 173.185, paragraphs (c)(3) and (e)(6) are revised to read as follows:

§ 173.185
Lithium batteries and cells.

(c) * * *

(3) Each cell or battery is of the type proven to be non-dangerous by testing in accordance with Tests in the UN Manual of Tests and Criteria (IBR; see § 171.7 of this subchapter). Such testing must be carried out on each type of cell or battery prior to the initial transport of that type. A cell or battery and equipment containing a cell or battery which was first transported prior to January 1, 2006 and is of a type proven to meet the criteria of Class 9 by testing in accordance with the tests in the UN Manual of Tests and Criteria, Third Revised Edition, 1999 is not required to be retested;

(e) * * *

(6) Each cell or battery is of the type proven to meet the lithium battery requirements in the UN Manual of Tests and Criteria (IBR; see § 171.7 of this subchapter). A cell or battery and equipment containing a cell or battery which was first transported prior to January 1, 2006 and is of a type proven to meet the criteria of Class 9 by testing in accordance with the tests in the UN Manual of Tests and Criteria, Third Revised Edition, 1999 is not required to be retested.

34. In § 173.186, paragraph (e) is revised to read as follows:

§ 173.186
Matches.

(e) Packagings. Strike-anywhere matches must be tightly packed in securely closed chipboard, fiberboard, wooden, or metal inner packagings to prevent accidental ignition under conditions normally incident to transportation. Each inner packaging may contain no more than 700 strike-anywhere matches and must be packed in outer steel drums (1A2), aluminum drums (1B2), steel jerricans (3A2), wooden (4C1, 4C2), plywood (4D), reconstituted wood (4F) or fiberboard (4G) boxes, plywood (1D) or fiber (1G) drums. Gross weight of fiberboard boxes (4G) must not exceed 30 kg (66 pounds). Gross weight of other outer packagings must not exceed 45 kg (100 pounds).

35. In § 173.187, a new paragraph (f) is added to read as follows:

§ 173.187
Pyrophoric solids, metals or alloys, n.o.s.

(f) In specification cylinders, as prescribed for any compressed gas, except for Specifications 8 and 3HT.

36. In § 173.211, paragraph (c) is revised to read as follows:

§ 173.211
Non-bulk packagings for solid hazardous materials in Packing Group I.

(c) Except for transportation by passenger aircraft, the following single packagings are authorized:

Steel drum: 1A1 or 1A2

Aluminum drum: 1B1 or 1B2

Metal drum other than steel or aluminum: 1N1 or 1N2

Plastic drum: 1H1 or 1H2

Fiber drum: 1G

Steel jerrican: 3A1 or 3A2

Plastic jerrican: 3H1 or 3H2

Aluminum jerrican: 3B1 or 3B2

Steel box with liner: 4A

Aluminum box with liner: 4B

Natural wood box, sift proof: 4C2

Plastic receptacle in steel, aluminum, plywood, fiber or plastic drum: 6HA1, 6HB1, 6HD1, 6HG1 or 6HH1

Glass, porcelain or stoneware in steel, aluminum, plywood or fiber drum: 6PA1, 6PB1, 6PD1 or 6PG1

Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB2, 6PC or 6PG2

Glass, porcelain or stoneware in expanded or solid plastic packaging: 6PH1 or 6PH2

Cylinders, as prescribed for any compressed gas, except for Specification 8 and 3HT

37. In § 173.212, paragraph (c) is revised to read as follows:

§ 173.212
Non-bulk packagings for solid hazardous materials in Packing Group III.

(c) Except for transportation by passenger aircraft, the following single packagings are authorized:

Steel drum: 1A1 or 1A2

Aluminum drum: 1B1 or 1B2

Plywood drum: 1D

Plastic drum: 1H1 or 1H2

Fiber drum: 1G

Metal drum other than steel or aluminum: 1N1 or 1N2

Wooden barrel: 2C1 or 2C2

Steel jerrican: 3A1 or 3A2

Plastic jerrican: 3H1 or 3H2

Aluminum jerrican: 3B1 or 3B2

Steel box: 4A

Steel box with liner: 4A

Aluminum box: 4B

Aluminum box with liner: 4B

Natural wood box: 4C1

Natural wood box, sift proof: 4C2

Plywood box: 4D

Reconstituted wood box: 4F

Fiberboard box: 4G

Expanded plastic box: 4H1

Solid plastic box: 4H2

Bag, woven plastic: 5H1, 5H2 or 5H3

Bag, plastic film: 5H4

Bag, textile: 5L1, 5L2 or 5L3

Bag, paper, multiwall, water resistant: 5M2

Plastic receptacle in steel, aluminum, plywood, fiber or plastic drum: 6HA1, 6HB1, 6HD1, 6HG1 or 6HH1

Plastic receptacle in steel, aluminum, wood, plywood or fiberboard box: 6HA2, 6HB2, 6HC, 6HD2 or 6HG2

Glass, porcelain or stoneware in steel, aluminum, plywood or fiber drum: 6PA1, 6PB1, 6PD1 or 6PG1

Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB1, 6PC or 6PG2

Glass, porcelain or stoneware in expanded or solid plastic packaging: 6PH1 or 6PH2

Cylinders, as prescribed for any compressed gas, except for Specification 8 and 3HT

38. In § 173.213, paragraph (c) is revised to read as follows:

§ 173.213
Non-bulk packagings for solid hazardous materials in Packing Group III.

(c) The following single packagings are authorized:

Steel drum: 1A1 or 1A2

Aluminum drum: 1B1 or 1B2

Plywood drum: 1D

Plastic drum: 1H1 or 1H2

Fiber drum: 1G

Metal drum other than steel or aluminum: 1N1 or 1N2

Wooden barrel: 2C1 or 2C2

Steel jerrican: 3A1 or 3A2

Plastic jerrican: 3H1 or 3H2

Aluminum jerrican: 3B1 or 3B2

Steel box: 4A

Steel box with liner: 4A

Aluminum box: 4B

Aluminum box with liner: 4B

Natural wood box: 4C1

Natural wood box, sift proof: 4C2

Plywood box: 4D

Reconstituted wood box: 4F

Fiberboard box: 4G

Expanded plastic box: 4H1

Solid plastic box: 4H2

Bag, woven plastic: 5H1, 5H2 or 5H3

Bag, plastic film: 5H4

Bag, textile: 5L1, 5L2 or 5L3

Bag, paper, multiwall, water resistant: 5M2

Plastic receptacle in steel, aluminum, plywood, fiber or plastic drum: 6HA1, 6HB1, 6HD1, 6HG1 or 6HH1

Plastic receptacle in steel, aluminum, wood, plywood or fiberboard box: 6HA2, 6HB2, 6HC, 6HD2 or 6HG2

Glass, porcelain or stoneware in steel, aluminum, plywood or fiber drum: 6PA1, 6PB1, 6PD1 or 6PG1

Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB1, 6PC or 6PG2

Glass, porcelain or stoneware in expanded or solid plastic packaging: 6PH1 or 6PH2

Cylinders, as prescribed for any compressed gas, except for Specification 8 and 3HT

39. Section 173.219 is revised to read as follows:

§ 173.219
Life-saving appliances.

(a) A life-saving appliance, self-inflating or non-self-inflating, containing small quantities of hazardous materials that are required as part of the life-saving appliance must conform to the requirements of this section. Packagings must conform to the general packaging requirements of subpart B of this part but need not conform to the requirements of part 178 of this subchapter. The appliances must be packed, so that they cannot be accidentally activated and, except for life vests, the hazardous materials must be in inner packagings packed so as to prevent movement. The hazardous materials must be an integral part of the appliance and in quantities that do not exceed those appropriate for the actual appliance when in use.

(b) Life saving appliances may contain:

(1) Division 2.2 compressed gases, including oxygen. However, oxygen generators are not permitted;

(2) Signal devices (Class 1), which may include smoke and illumination signal flares;

(3) Electric storage batteries and lithium batteries (Life saving appliances containing lithium batteries must be transported in accordance with § 173.185.);

(4) First aid or repair kits conforming to the applicable material and quantity limitations of § 173.161 of this subchapter;

(5) Strike-anywhere matches;

(6) For self-inflating life saving appliances only, cartridges power device of Division 1.4S, for purposes of the self-inflating mechanism provided that the quantity of explosives per appliance does not exceed 3.2 g; or

(7) Limited quantities of other hazardous materials.

(c) Hazardous materials in life saving appliances must be packaged as follows:

(1) Division 2.2 compressed gases must be packaged in cylinders in accordance with the requirements of this subchapter;

(2) Signal devices (Class 1) must be in packagings that prevent them from being inadvertently activated;

(3) Strike-anywhere matches must be cushioned to prevent movement or friction in a metal or composition receptacle with a screw-type closure in a manner that prevents them from being inadvertently activated;

(4) Limited quantities of other hazardous materials must be packaged in accordance with the requirements of this subchapter; and

(5) For other than transportation by aircraft, life saving appliances containing no hazardous materials other than carbon dioxide cylinders with a capacity not exceeding 100 cm3 are not subject to the provisions of this subchapter provided they are overpacked in rigid outer packagings with a maximum gross mass of 40 kg.

40. In § 173.220, paragraph (b)(2) is revised to read as follows:

§ 173.220
Internal combustion engines, self-propelled vehicles, mechanical equipment containing internal combustion engines, and battery powered vehicles or equipment.

(b) * * *

(2) Flammable liquefied or compressed gas fuel. (i) For transportation by motor vehicle, rail car or vessel, fuel tanks and fuel systems containing flammable liquefied or compressed gas fuel must be securely closed. For transportation by vessel, the requirements of §§ 176.78(k) and 176.905 of this subchapter apply.

(ii) For transportation by aircraft:

(A) Flammable gas-powered vehicles, machines, equipment or cylinders containing the flammable gas must be completely emptied of flammable gas. Lines from vessels to gas regulators, and gas regulators themselves, must also be drained of all traces of flammable gas. To ensure that these conditions are met, gas shut-off valves must be left open and connections of lines to gas regulators must be left disconnected upon delivery of the vehicle to the operator. Shut-off valves must be closed and lines reconnected at gas regulators before loading the vehicle aboard the aircraft; or alternatively

(B) Flammable gas powered vehicles, machines or equipment, which have cylinders (fuel tanks) that are equipped with electrically operated valves, may be transported under the following conditions:

(1) The valves must be in the closed position and in the case of electrically operated valves, power to those valves must be disconnected;

(2) After closing the valves, the vehicle, equipment or machinery must be operated until it stops from lack of fuel before being loaded aboard the aircraft;

(3) In no part of the system between the pressure receptacle and the shut off valve shall the pressure exceed more than 5% of the maximum allowable working pressure of the system; and

(4) There must not be any residual liquefied gas in the system, including the fuel tank.

41. In § 173.224, paragraph (b)(4) is revised to read as follows:

§ 173.224
Packaging and control and emergency temperatures for self-reactive materials.

(b) * * *

(4) Packing method. Column 4 specifies the highest packing method which is authorized for the self-reactive material. A packing method corresponding to a smaller package size may be used, but a packing method corresponding to a larger package size may not be used. The Table of Packing Methods in § 173.225(d) defines the packing methods. Bulk packagings for Type F self-reactive substances are authorized by § 173.225(f) for IBCs and § 173.225(h) for bulk packagings other than IBCs. Additional bulk packagings are authorized if approved by the Associate Administrator.

42. Section 173.225 is revised to read as follows:

§ 173.225
Packaging requirements and other provisions for organic peroxides.

(a) General. When the § 172.101 table specifies that an organic peroxide must be packaged under this section, the organic peroxide must be packaged and offered for transportation in accordance with the provisions of this section. Each packaging must conform to the general requirements of subpart B of part 173 and to the applicable requirements of part 178 of this subchapter. Non-bulk packagings must meet Packing Group II performance levels. To avoid unnecessary confinement, metallic non-bulk packagings meeting Packing Group I are not authorized. No used material, other than production residues or regrind from the same production process, may be used in plastic packagings. Organic peroxides that require temperature control are subject to the provisions of § 173.21(f). When an IBC or bulk packaging is authorized and meets the requirements of paragraph (f) or (h) of this section, respectively, lower control temperatures than those specified for non-bulk packaging may be required. An organic peroxide not identified in paragraph (c), (e), or (g) of this section by technical name, or not assigned to a generic type in accordance with the provisions in paragraph (b)(3) of this section, must conform to the provisions of paragraph (c) of § 173.128.

(b) New organic peroxides, formulations and samples. (1) Except as provided for samples in paragraph (b)(2) of this section, no person may offer for transportation an organic peroxide that is not identified by technical name in the Organic Peroxides Table, Organic Peroxide IBC Table, or the Organic Peroxide Portable Tank Table of this section, or a formulation of one or more organic peroxides that are identified by technical name in one of those tables, unless the organic peroxide is assigned a generic type and shipping description and is approved by the Associate Administrator under the provisions of § 173.128(d) of this subchapter.

(2) Samples. Samples of new organic peroxides or new formulations of organic peroxides identified in the Organic Peroxides Table in paragraph (c) of this section, for which complete test data are not available, and that are to be transported for further testing or product evaluation, may be assigned an appropriate shipping description for organic peroxide Type C, packaged and offered for transportation, under the following conditions:

(i) Data available to the person offering the material for transportation must indicate that the sample would pose a level of hazard no greater than that of an organic peroxide Type B and that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation;

(ii) The sample must be packaged in accordance with packing method OP2, for a liquid or solid, respectively;

(iii) Packages of the organic peroxide may be offered for transportation and transported in a quantity not to exceed 10 kg (22 pounds) per transport vehicle; and

(iv) One of the following shipping descriptions must be assigned:

(A) Organic peroxide Type C, liquid, 5.2, UN 3103;

(B) Organic peroxide Type C, solid, 5.2, UN 3104;

(C) Organic peroxide Type C, liquid, temperature controlled, 5.2, UN 3113; or

(D) Organic peroxide Type C, solid, temperature controlled, 5.2, UN 3114.

(3) Mixtures. Mixtures of organic peroxides individually identified in the Organic Peroxides Table in paragraph (c) of this section may be classified as the same type of organic peroxide as that of the most dangerous component and be transported under the conditions for transportation given for this type. If the stable components form a thermally less stable mixture, the SADT of the mixture must be determined and the new control and emergency temperature derived under the provisions of § 173.21(f).

(c) Organic peroxides table. The following Organic Peroxides Table specifies by technical name those organic peroxides that are authorized for transportation and not subject to the approval provisions of § 173.128 of this part. An organic peroxide identified by technical name in the following table is authorized for transportation only if it conforms to all applicable provisions of the table. The column headings of the Organic Peroxides Table are as follows:

(1) Technical name. The first column specifies the technical name.

(2) ID number. The second column specifies the identification (ID) number which is used to identify the proper shipping name in the § 172.101 table. The word “EXEMPT” appearing in the column denotes that the material is not regulated as an organic peroxide.

(3) Concentration of organic peroxide. The third column specifies concentration (mass percent) limitations, if any, in mixtures or solutions for the organic peroxide. Limitations are given as minimums, maximums, or a range, as appropriate. A range includes the lower and upper limits (i.e., “53-100” means from, and including, 53% to, and including 100%). See introductory paragraph of § 172.203(k) of this subchapter for additional description requirements for an organic peroxide that may qualify for more than one generic listing, depending on its concentration.

(4) Concentration of diluents. The fourth column specifies the type and concentration (mass percent) of diluent or inert solid, when required. Other types and concentrations of diluents may be used if approved by the Associate Administrator.

(i) The required mass percent of “Diluent type A” is specified in column 4a. A diluent type A is an organic liquid that does not detrimentally affect the thermal stability or increase the hazard of the organic peroxide and with a boiling point not less than 150 °C at atmospheric pressure. Type A diluents may be used for desensitizing all organic peroxides.

(ii) The required mass percent of “Diluent type B” is specified in column 4b. A diluent type B is an organic liquid which is compatible with the organic peroxide and which has a boiling point, at atmospheric pressure, of less than 150 °C (302 °F) but at least 60 °C (140 °F), and a flash point greater than 5 °C (41 °F). Type B diluents may be used for desensitizing all organic peroxides, when specified in the organic peroxide tables, provided that the boiling point is at least 60 °C (140 °F) above the SADT of the peroxide in a 50 kg (110 lbs) package. A type A diluent may be used to replace a type B diluent in equal concentration.

(iii) The required mass percent of “Inert solid” is specified in column 4c. An inert solid is a solid that does not detrimentally affect the thermal stability or hazard of the organic peroxide.

(5) Concentration of water. Column 5 specifies, in mass percent, the minimum amount of water, if any, which must be in formulation.

(6) Packing method. Column 6 specifies the highest packing method (largest packaging capacity) authorized for the organic peroxide. Lower numbered packing methods (smaller packaging capacities) are also authorized. For example, if OP3 is specified, then OP2 and OP1 are also authorized. The Table of Packing Methods in paragraph (d) of this section defines the non-bulk packing methods.

(7) Temperatures. Column 7a specifies the control temperature. Column 7b specifies the emergency temperature. Temperatures are specified only when temperature controls are required. (See § 173.21(f)).

(8) Notes. Column 8 specifies other applicable provisions, as set forth in notes following the table.

Organic Peroxide Table

Technical nameID numberConcentration (mass %)Diluent (mass %)Water (mass %)Packing methodTemperature (°C)Notes
ABIControlEmergency
(1)(2)(3)(4a)(4b)(4c)(5)(6)(7a)(7b)(8)
Acetyl acetone peroxideUN3105≤42≥48≥8OP72
Acetyl acetone peroxide [as a paste]UN3106≤32OP721
Acetyl cyclohexanesulfonyl peroxideUN3112≤82≥12OP4−100
Acetyl cyclohexanesulfonyl peroxideUN3115≤32≥68OP7−100
tert-Amyl hydroperoxideUN3107≤88≥6≥6OP8
tert-Amyl peroxyacetateUN3105≤62≥38OP7
tert-Amyl peroxybenzoateUN3103≤100OP5
tert-Amyl peroxy-2-ethylhexanoateUN3115≤100OP7+20+25
tert-Amyl peroxy-2-ethylhexyl carbonateUN3105≤100OP7
tert-Amyl peroxy isopropyl carbonateUN3103≤77≥23OP5
tert-Amyl peroxyneodecanoateUN3115≤77≥23OP70+10
tert-Amyl peroxypivalateUN3113≤77≥23OP5+10+15
tert-Amyl peroxy-3,5,5-trimethylhexanoateUN3101≤100OP5
tert-Butyl cumyl peroxideUN3107>42-100OP89
tert-Butyl cumyl peroxideUN3108≤52≥48OP89
n-Butyl-4,4-di-(tert-butylperoxy)valerateUN3103>52-100OP5
n-Butyl-4,4-di-(tert-butylperoxy)valerateUN3108≤52≥48OP8
tert-Butyl hydroperoxideUN3103>79-90≥10OP513
tert-Butyl hydroperoxideUN3105≤80≥20OP74, 13
tert-Butyl hydroperoxideUN3107≤79>14OP813, 16
tert-Butyl hydroperoxideUN3109≤72≥28OP813
tert-Butyl hydroperoxide [and] Di-tert-butylperoxideUN3103<82+>9≥7OP513
tert-Butyl monoperoxymaleateUN3102>52-100OP5
tert-Butyl monoperoxymaleateUN3103≤52≥48OP6
tert-Butyl monoperoxymaleateUN3108≤52≥48OP8
tert-Butyl monoperoxymaleate [as a paste]UN3108≤52OP8
tert-Butyl peroxyacetateUN3101>52-77≥23OP5
tert-Butyl peroxyacetateUN3103>32-52≥48OP6
tert-Butyl peroxyacetateUN3109≤32≥68OP8
tert-Butyl peroxybenzoateUN3103>77-100OP5
tert-Butyl peroxybenzoateUN3105>52-77≥23OP71
tert-Butyl peroxybenzoateUN3106≤52≥48OP7
tert-Butyl peroxybutyl fumarateUN3105≤52≥48OP7
tert-Butyl peroxycrotonateUN3105≤77≥23OP7
tert-Butyl peroxydiethylacetateUN3113≤100OP5+20+25
tert-Butyl peroxy-2-ethylhexanoateUN3113>52-100OP6+20+25
tert-Butyl peroxy-2-ethylhexanoateUN3117>32-52≥48OP8+30+35
tert-Butyl peroxy-2-ethylhexanoateUN3118≤52≥48OP8+20+25
tert-Butyl peroxy-2-ethylhexanoateUN3119≤32≥68OP8+40+45
tert-Butyl peroxy-2-ethylhexanoate [and] 2,2-di-(tert-Butylperoxy)butaneUN3106≤12+≤14≥14≥60OP7
tert-Butyl peroxy-2-ethylhexanoate [and] 2,2-di-(tert-Butylperoxy)butaneUN3115≤31+≤36≥33OP7+35+40
tert-Butyl peroxy-2-ethylhexylcarbonateUN3105≤100OP7
tert-Butyl peroxyisobutyrateUN3111>52-77≥23OP5+15+20
tert-Butyl peroxyisobutyrateUN3115≤52≥48OP7+15+20
tert-Butylperoxy isopropylcarbonateUN3103≤77≥23OP5
1-(2-tert-Butylperoxy isopropyl)-3-isopropenylbenzeneUN3105≤77≥23OP7
1-(2-tert-Butylperoxy isopropyl)-3-isopropenylbenzeneUN3108≤42≥58OP8
tert-Butyl peroxy-2-methylbenzoateUN3103≤100OP5
tert-Butyl peroxyneodecanoateUN3115>77-100OP7−5+5
tert-Butyl peroxyneodecanoateUN3115≤77≥23OP70+10
tert-Butyl peroxyneodecanoate [as a stable dispersion in water]UN3119≤52OP80+10
tert-Butyl peroxyneodecanoate [as a stable dispersion in water (frozen)]UN3118≤42OP80+10
tert-Butyl peroxyneodecanoateUN3119≤32≥68OP80+10
tert-Butyl peroxyneoheptanoateUN3115≤77≥23OP70+10
tert-Butyl peroxyneoheptanoate [as a stable dispersion in water]UN3117≤42OP80+10
tert-Butyl peroxypivalateUN3113>67-77≥23OP50+10
tert-Butyl peroxypivalateUN3115>27-67≥33OP70+10
tert-Butyl peroxypivalateUN3119≤27≥73OP8+30+35
tert-Butylperoxy stearylcarbonateUN3106≤100OP7
tert-Butyl peroxy-3,5,5-trimethylhexanoateUN3105>32-100OP7
tert-Butyl peroxy-3,5,5-trimethylhexanoateUN3109≤32≥68OP8
3-Chloroperoxybenzoic acidUN3102>57-86≥14OP1
3-Chloroperoxybenzoic acidUN3106≤57≥3≥40OP7
3-Chloroperoxybenzoic acidUN3106≤77≥6≥17OP7
Cumyl hydroperoxideUN3107>90-98≤10OP813
Cumyl hydroperoxideUN3109≤90≥10OP813, 15
Cumyl peroxyneodecanoateUN3115≤77≥23OP7−100
Cumyl peroxyneodecanoate [as a stable dispersion in water]UN3119≤52OP8−100
Cumyl peroxyneoheptanoateUN3115≤77≥23OP7−100
Cumyl peroxypivalateUN3115≤77≥23OP7−5+5
Cyclohexanone peroxide(s)UN3104≤91≥9OP613
Cyclohexanone peroxide(s)UN3105≤72≥28OP75
Cyclohexanone peroxide(s) [as a paste]UN3106≤72OP75, 21
Cyclohexanone peroxide(s)Exempt≤32≥68Exempt
Diacetone alcohol peroxidesUN3115≤57≥26≥8OP7+40+455
Diacetyl peroxideUN3115≤27≥73OP7+20+258,13
Di-tert-amyl peroxideUN3107≤100OP8
1,1-Di-(tert-amylperoxy)cyclohexaneUN3103≤82≥18OP6
Dibenzoyl peroxideUN3102>51-100≤48OP23
Dibenzoyl peroxideUN3102>77-94≥6OP43
Dibenzoyl peroxideUN3104≤77≥23OP6
Dibenzoyl peroxideUN3106≤62≥28≥10OP7
Dibenzoyl peroxide [as a paste]UN3106>52-62OP721
Dibenzoyl peroxideUN3106>35-52≥48OP7
Dibenzoyl peroxideUN3107>36-42≥18≤40OP8
Dibenzoyl peroxide [as a paste]UN3108≤56.5≥15OP8
Dibenzoyl peroxide [as a paste]UN3108≤52OP821
Dibenzoyl peroxide [as a stable dispersion in water]UN3109≤42OP8
Dibenzoyl peroxideExempt≤35≥65Exempt
Di-(4-tert-butylcyclohexyl)peroxydicarbonateUN3114≤100OP6+30+35
Di-(4-tert-butylcyclohexyl)peroxydicarbonate [as a stable dispersion in water]UN3119≤42OP8+30+35
Di-tert-butyl peroxideUN3107>52-100OP8
Di-tert-butyl peroxideUN3109≤52≥48OP824
Di-tert-butyl peroxyazelateUN3105≤52≥48OP7
2,2-Di-(tert-butylperoxy)butaneUN3103≤52≥48OP6
1,6-Di-(tert-butylperoxycarbonyloxy)hexaneUN3103≤72≥28OP5
1,1-Di-(tert-butylperoxy)cyclohexaneUN3101>80-100OP5
1,1-Di-(tert-butylperoxy)cyclohexaneUN3103>52-80≥20OP5
1,1-Di-(tert-butylperoxy)cyclohexaneUN3105>42-52≥48OP7
1,1-Di-(tert-butylperoxy)cyclohexaneUN3106≤42≥13≥45OP7
1,1-Di-(tert-butylperoxy)cyclohexaneUN3107≤27≥25OP822
1,1-Di-(tert-butylperoxy)cyclohexaneUN3109≤42≥58OP8
1,1-Di-(tert-butylperoxy)cyclohexaneUN3109≤25≥25≥50OP829
1,1-Di-(tert-butylperoxy)cyclohexaneUN3109≤13≥13≥74OP8
Di-n-butyl peroxydicarbonateUN3115>27-52≥48OP7−15−5
Di-n-butyl peroxydicarbonateUN3117≤27≥73OP8−100
Di-n-butyl peroxydicarbonate [as a stable dispersion in water (frozen)]UN3118≤42OP8−15−5
Di-sec-butyl peroxydicarbonateUN3113>52-100OP4−20−106
Di-sec-butyl peroxydicarbonateUN3115≤52≥48OP7−15−5
Di-(2-tert-butylperoxyisopropyl)benzene(s)UN3106>42-100≤57OP71, 9
Di-(2-tert-butylperoxyisopropyl)benzene(s)Exempt≤42≥58Exempt
Di-(tert-butylperoxy)phthalateUN3105>42-52≥48OP7
Di-(tert-butylperoxy)phthalate [as a paste]UN3106≤52OP721
Di-(tert-butylperoxy)phthalateUN3107≤42≥58OP8
2,2-Di-(tert-butylperoxy)propaneUN3105≤52≥48OP7
2,2-Di-(tert-butylperoxy)propaneUN3106≤42≥13≥45OP7
1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexaneUN3101>90-100OP5
1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexaneUN3103>57-90≥10OP5
1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexaneUN3103≤77≥23OP5
1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexaneUN3110≤57≥43OP8
1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexaneUN3107≤57≥43OP8
1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexaneUN3107≤32≥26≥42OP8
Dicetyl peroxydicarbonateUN3116≤100OP7+30+35
Dicetyl peroxydicarbonate [as a stable dispersion in water]UN3119≤42OP8+30+35
Di-4-chlorobenzoyl peroxideUN3102≤77≥23OP5
Di-4-chlorobenzoyl peroxide [as a paste]UN3106≤52OP721
Di-4-chlorobenzoyl peroxideExempt≤32≥68Exempt
Dicumyl peroxideUN3110>52-100≤48OP8
Dicumyl peroxideExempt≤52≥48Exempt
Dicyclohexyl peroxydicarbonateUN3112>91-100OP3+10+15
Dicyclohexyl peroxydicarbonateUN3114≤91≥9OP5+10+15
Dicyclohexyl peroxydicarbonate [as a stable dispersion in water]UN3119≤42OP8+15+20
Didecanoyl peroxideUN3114≤100OP6+30+35
2,2-Di-(4,4-di(tert-butylperoxy)cyclohexyl)propaneUN3106≤42≥58OP7
2,2-Di-(4,4-di(tert-butylperoxy)cyclohexyl)propaneUN3107≤22≥78OP8
Di-2,4-dichlorobenzoyl peroxideUN3102≤77≥23OP5
Di-2,4-dichlorobenzoyl peroxide [as a paste with silicone oil]UN3106≤52OP7
Di-(2-ethoxyethyl) peroxydicarbonateUN3115≤52≥48OP7−100
Di-(2-ethylhexyl) peroxydicarbonateUN3113>77-100OP5−20−10
Di-(2-ethylhexyl) peroxydicarbonateUN3115≤77≥23OP7−15−5
Di-(2-ethylhexyl) peroxydicarbonate [as a stable dispersion in water]UN3117≤62OP8−15−5
Di-(2-ethylhexyl) peroxydicarbonate [as a stable dispersion in water]UN3119≤52OP8−15−5
Di-(2-ethylhexyl) peroxydicarbonate [as a stable dispersion in water (frozen)]UN3120≤52OP8−15−5
2,2-DihydroperoxypropaneUN3102≤27≥73OP5
Di-(1-hydroxycyclohexyl)peroxideUN3106≤100OP7
Diisobutyryl peroxideUN3111>32-52≥48OP5−20−10
Diisobutyryl peroxideUN3115≤32≥68OP7−20−10
Diisopropylbenzene dihydroperoxideUN3106≤82≥5≥5OP717
Diisopropyl peroxydicarbonateUN3112>52-100OP2−15−5
Diisopropyl peroxydicarbonateUN3115≤52≥48OP7−20−10
Diisopropyl peroxydicarbonateUN3115≤28≥72OP7−15−5
Dilauroyl peroxideUN3106≤100OP7
Dilauroyl peroxide [as a stable dispersion in water]UN3109≤42OP8
Di-(3-methoxybutyl) peroxydicarbonateUN3115≤52≥48OP7−5+5
Di-(2-methylbenzoyl)peroxideUN3112≤87≥13OP5+30+35
Di-(4-methylbenzoyl)peroxide [as a paste with silicone oil]UN3106≤52OP7
Di-(3-methylbenzoyl) peroxide + Benzoyl (3-methylbenzoyl) peroxide + Dibenzoyl peroxideUN3115≤20+≤18+≤4≥58OP7+35+40
2,5-Dimethyl-2,5-di-(benzoylperoxy)hexaneUN3102>82-100OP5
2,5-Dimethyl-2,5-di-(benzoylperoxy)hexaneUN3106≤82≥18OP7
2,5-Dimethyl-2,5-di-(benzoylperoxy)hexaneUN3104≤82≥18OP5
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexaneUN3105>52-100OP7
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexaneUN3108≤77≥23OP8
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexaneUN3109≤52≥48OP8
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane [as a paste]UN3108≤47OP8
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3UN3101>86-100OP5
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3UN3103>52-86≥14OP5
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3UN3106≤52≥48OP7
2,5-Dimethyl-2,5-di-(2-ethylhexanoylperoxy)hexaneUN3113≤100OP5+20+25
2,5-Dimethyl-2,5-dihydroperoxyhexaneUN3104≤82≥18OP6
2,5-Dimethyl-2,5-di-(3,5,5-trimethylhexanoylperoxy)hexaneUN3105≤77≥23OP7
1,1-Dimethyl-3-hydroxybutylperoxyneoheptanoateUN3117≤52≥48OP80+10
Dimyristyl peroxydicarbonateUN3116≤100OP7+20+25
Dimyristyl peroxydicarbonate [as a stable dispersion in water]UN3119≤42OP8+20+25
Di-(2-neodecanoylperoxyisopropyl)benzeneUN3115≤52≥48OP7−100
Di-n-nonanoyl peroxideUN3116≤100OP70+10
Di-n-octanoyl peroxideUN3114≤100OP5+10+15
Di-(2-phenoxyethyl)peroxydicarbonateUN3102>85-100OP5
Di-(2-phenoxyethyl)peroxydicarbonateUN3106≤85≥15OP7
Dipropionyl peroxideUN3117≤27≥73OP8+15+20
Di-n-propyl peroxydicarbonateUN3113≤100OP3−25−15
Di-n-propyl peroxydicarbonateUN3113≤77≥23OP5−20−10
Disuccinic acid peroxideUN3102>72-100OP418
Disuccinic acid peroxideUN3116≤72≥28OP7+10+15
Di-(3,5,5-trimethylhexanoyl)peroxideUN3115>38-82≥18OP70+10
Di-(3,5,5-trimethylhexanoyl)peroxide [as a stable dispersion in water]UN3119≤52OP8+10+15
Di-(3,5,5-trimethylhexanoyl)peroxideUN3119≤38≥62OP8+20+25
Ethyl 3,3-di-(tert-amylperoxy)butyrateUN3105≤67≥33OP7
Ethyl 3,3-di-(tert-butylperoxy)butyrateUN3103>77-100OP5
Ethyl 3,3-di-(tert-butylperoxy)butyrateUN3105≤77≥23OP7
Ethyl 3,3-di-(tert-butylperoxy)butyrateUN3106≤52≥48OP7
1-(2-ethylhexanoylperoxy)-1,3-Dimethylbutyl peroxypivalateUN3115≤52≥45≥10OP7−20−10
tert-Hexyl peroxyneodecanoateUN3115≤71≥29OP70+10
tert-Hexyl peroxypivalateUN3115≤72≥28OP7+10+15
Isopropyl sec-butyl peroxydicarbonat +Di-sec-butyl peroxydicarbonate+Di-isopropyl peroxydicarbonateUN3111≤52+≤28+≤22OP5−20−10
Isopropyl sec-butyl peroxydicarbonate+Di-sec-butyl peroxydicarbonate+Di-isopropyl peroxydicarbonateUN3115≤32+≤15−18+≤12−15≥38OP7−20−10
Isopropylcumyl hydroperoxideUN3109≤72≥28OP813
p-Menthyl hydroperoxideUN3105> 72-100OP713
p-Menthyl hydroperoxideUN3109≤72≥28OP8
Methylcyclohexanone peroxide(s)UN3115≤67≥33OP7+35+40
Methyl ethyl ketone peroxide(s)UN3101≤52≥48OP55, 13, 29
Methyl ethyl ketone peroxide(s)UN3105≤45≥55OP75, 29
Methyl ethyl ketone peroxide(s)UN3107≤40≥60OP87
Methyl isobutyl ketone peroxide(s)UN3105≤62≥19OP75, 23
Organic peroxide, liquid, sampleUN3103OP212
Organic peroxide, liquid, sample, temperature controlledUN3113OP212
Organic peroxide, solid, sampleUN3104OP212
Organic peroxide, solid, sample, temperature controlledUN3114OP212
Peroxyacetic acid, type D, stabilizedUN3105≤43OP713, 20
Peroxyacetic acid, type E, stabilizedUN3107≤43OP813, 20
Peroxyacetic acid, type F, stabilizedUN3109≤43OP813, 20, 28
Peroxyacetic acid or peracetic acid [with not more than 7% hydrogen peroxide]UN3107≤36≥15OP813, 20, 28, 29
Peroxyacetic acid or peracetic acid [with not more than 20% hydrogen peroxide]Exempt≤6≥60Exempt28, 29
Peroxyacetic acid or peracetic acid [with not more than 26% hydrogen peroxide]UN3109≤17OP813, 20, 28, 29
Peroxylauric acidUN3118≤100OP8+35+40
Pinanyl hydroperoxideUN3105>56-100OP713
Pinanyl hydroperoxideUN3109≤56≥44OP8
Polyether poly-tert-butylperoxycarbonateUN3107≤52≥48OP8
Tetrahydronaphthyl hydroperoxideUN3106≤100OP7
1,1,3,3-Tetramethylbutyl hydroperoxideUN3105≤100OP7
1,1,3,3-Tetramethylbutyl peroxy-2-ethylhexanoateUN3115≤100OP7+15+20
1,1,3,3-Tetramethylbutyl peroxyneodecanoateUN3115≤72≥28OP7-5+5
1,1,3,3-Tetramethylbutyl peroxyneodecanoate [as a stable dispersion in water]UN3119≤52OP8−5+5
1,1,3,3-tetramethylbutyl peroxypivalateUN3115≤77≥23OP70+10
3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonaneUN3105≤42≥58OP726

Notes

1. For domestic shipments, OP8 is authorized.

2. Available oxygen must be <4.7%.

3. For concentrations <80% OP5 is allowed. For concentrations of at least 80% but <85%, OP4 is allowed. For concentrations of at least 85%, maximum package size is OP2.

4. The diluent may be replaced by di-tert-butyl peroxide.

5. Available oxygen must be ≤9% with or without water.

6. For domestic shipments, OP5 is authorized.

7. Available oxygen must be ≤8.2% with or without water.

8. Only non-metallic packagings are authorized.

9. For domestic shipments this material maybe transported under the provisions of paragraph (h)(3)(xii) of this section.

10. [Reserved]

11. [Reserved]

12. Samples may only be offered for transportation under the provisions of paragraph (c)(2) of this section.

13. “Corrosive” subsidiary risk label is required.

14. [Reserved]

15. No “Corrosive” subsidiary risk label is required for concentrations below 80%.

16. With <6% di-tert-butyl peroxide.

17. With ≥8% 1-isopropylhydroperoxy-4-isopropylhydroxybenzene.

18. Addition of water to this organic peroxide will decrease its thermal stability.

19. [Reserved]

20. Mixtures with hydrogen peroxide, water and acid(s).

21. With diluent type A, with or without water.

22. With ≥36% diluent type A by mass, and in addition ethylbenzene.

23. With ≥19% diluent type A by mass, and in addition methyl isobutyl ketone.

24. Diluent type B with boiling point >100 C.

25. No “Corrosive” subsidiary risk label is required for concentrations below 56%.

26. Available oxygen must be ≤7.6%.

27. Formulations derived from distillation of peroxyacetic acid originating from peroxyacetic acid in a concentration of not more than 41% with water, total active oxygen less than or equal to 9.5% (peroxyacetic acid plus hydrogen peroxide).

28. For the purposes of this section, the names “Peroxyacetic acid” and “Peracetic acid” are synonymous.

29. For international transportation, shipments of this material must be accompanied by a Competent Authority approval from the Associate Administrator.

(d) Packing Method Table. Packagings for organic peroxides and self-reactive substances are listed in the Maximum Quantity per Packing Method Table. The packing methods are designated OP1 to OP8. The quantities specified for each packing method represent the maximum that is authorized.

(1) The following types of packagings are authorized:

(i) Drums: 1A1, 1A2, 1B1, 1B2, 1D, 1G, 1H1, 1H2;

(ii) Jerricans: 3A1, 3A2, 3B1, 3B2, 3H1, 3H2;

(iii) Boxes: 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2, 4A, 4B; or

(iv) Composite packagings with a plastic inner receptacle: 6HA1, 6HA2, 6HB1, 6HB2, 6HC, 6HD1, 6HD2, 6HG1, 6HG2, 6HH1, 6HH2.

(2) Metal packaging (including inner packagings of combination packagings and outer packagings of combination or composite packagings) are used only for packing methods OP7 and OP8.

(3) In combination packagings, glass receptacles are used only as inner packagings with a maximum content of 0.5 kg for solids or 0.5 L for liquids.

(4) The maximum quantity per packaging or package for Packing Methods OP1-OP8 must be as follows:

Maximum Quantity Per Packaging/Package

[For Packing Methods OP1 to OP8]

Maximum quantityPacking Method
OP1OP2OP3OP4 OP5OP6OP7OP8
Solids and combination packagings (liquid and solid) (kg)0.50.5/1055255050 400
Liquids (L)0.55306060 225
If two values are given, the first applies to the maximum net mass per inner packaging and the second to the maximum net mass of the complete package.
60 kg for jerricans/200 kg for boxes and, for solids, 400 kg in combination packagings with outer packagings comprising boxes (4C1, 4C2, 4D, 4F, 4G, 4H1, and 4H2) and with inner packagings of plastics or fiber with a maximum net mass of 25 kg.
60 L for jerricans.

(e) Organic Peroxide IBC Table. The following Organic Peroxide IBC Table specifies, by technical name, those organic peroxides that are authorized for transportation in certain IBCs and not subject to the approval provisions of § 173.128 of this part. Additional requirements for authorized IBCs are found in paragraph (f) of this section.

Organic Peroxide IBC Table

UN No.Organic peroxideType of IBCMaximum quantity (litres)Control temperatureEmergency temperature
3109ORGANIC PEROXIDE, TYPE F, LIQUID
tert-Butyl hydroperoxide, not more than 72% with water31A1250
tert-Butyl peroxyacetate, not more than 32% in diluent type A31A1250
31HA11000
tert-Butyl peroxy-3,5,5-trimethylhexanoate, not more than 32% in diluent type A31A1250
31HA11000
Cumyl hydroperoxide, not more than 90% in diluent type A31HA11250
Dibenzoyl peroxide, not more than 42% as a stable dispersion31H11000
Di-tert-butyl peroxide, not more than 52% in diluent type B31A1250
31HA11000
1,1-Di-(tert-butylperoxy) cyclohexane, not more than 42% in diluent type A31H11000
Dicumyl peroxide, less than or equal to 100%31A1250
31HA11000
Dilauroyl peroxide, not more than 42%, stable dispersion, in water31HA11000
Isopropyl cumyl hydroperoxide, not more than 72% in diluent type A31HA11250
p-Menthyl hydroperoxide, not more than 72% in diluent type A31HA11250
Peroxyacetic acid, stabilized, not more than 17%31H11500
31HA11500
31A1500
Peroxyacetic acid, with not more than 26% hydrogen peroxide31A1500
31HA11500
Peroxyacetic acid, type F, stabilized31A1500
31HA11500
3110ORGANIC PEROXIDE TYPE F, SOLID
Dicumyl peroxide, less than or equal to 100%31A2000
31H1
31HA1
3119ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED
tert-Butyl peroxy-2-ethylhexanoate, not more than 32% in diluent type B31HA11000+30 °C+35 °C
31A1250+30 °C+35 °C
tert-Butyl peroxyneodecanoate, not more than 32% in diluent type A31A12500 °C+10 °C
tert-Butyl peroxyneodecanoate, not more than 42% stable dispersion, in water31A1250−5 °C+5 °C
tert-Butyl peroxypivalate, not more than 27% in diluent type B31HA11000+10 °C+15 °C
31A1250+10 °C+15 °C
Cumyl peroxyneodecanoate, not more than 52%, stable dispersion, in water31A1250−15 °C−5 °C
Dicyclohexylperoxydicarbonate, not more than 42% as a stable dispersion, in water31A1250+10 °C+15 °C
Di-(4-tert-butylcyclohexyl) peroxydicarbonate, not more than 42%, stable dispersion, in water31HA11000+30 °C+35 °C
Dicetyl peroxydicarbonate, not more than 42%, stable dispersion, in water31HA11000+30 °C+35 °C
Di-(2-ethylhexyl) peroxydicarbonate, not more than 52%, stable dispersion, in water31A1250−20 °C−10 °C
Dimyristyl peroxydicarbonate, not more than 42%, stable dispersion, in water31HA11000+15 °C+20 °C
Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 38% in diluent type A31HA11000+10 °C+15 °C
31A1250+10 °C+15 °C
Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 52%, stable dispersion, in water31A1250+10 °C+15 °C
1,1,3,3-Tetramethylbutyl peroxyneodecanoate, not more than 52%, stable dispersion, in water31A1250−5 °C+5 °C

(f) IBCs. IBCs are authorized subject to the conditions and limitations of this section if the IBC type is authorized according to paragraph (e) of this section, as applicable, and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group II performance level. Type F organic peroxides or self-reactive substances are not authorized for transportation in IBCs other than those specified, unless approved by the Associate Administrator.

(1) IBCs shall be provided with a device to allow venting during transportation. The inlet to the pressure relief device shall be sited in the vapor space of the IBC under maximum filling conditions during transportation.

(2) To prevent explosive rupture of metal IBCs or composite IBCs with a complete metal casing, the emergency-relief devices shall be designed to vent all the decomposition products and vapors evolved during self-accelerating decomposition or during a period of not less than one hour of complete fire-engulfment as calculated by the formula in paragraph (h)(3)(v) of this section. The control and emergency temperatures specified in the Organic Peroxide IBC Table are based on a non-insulated IBC.

(g) Organic Peroxide Portable Tank Table. The following Organic Peroxide Portable Tank Table provides certain portable tank requirements and identifies, by technical name, those organic peroxides that are authorized for transportation in the bulk packagings listed in paragraph (h). Organic peroxides listed in this table, provided they meet the specific packaging requirements found in paragraph (h), are not subject to the approval provisions of § 173.128 of this part.

Organic Peroxide Portable Tank Table

UN No.Hazardous materialMinimum test pressure (bar)Minimum shell thickness (mm-reference steel) See. . .Bottom opening requirements See. . .Pressure-relief requirements See. . .Filling limitsControl temperatureEmergency temperature
3109ORGANIC PEROXIDE, TYPE F, LIQUID
tert-Butyl hydroperoxide, not more than 72% with water *Provided that steps have been taken to achieve the safety equivalence of 65% tert-Butyl hydroperoxide and 35% water4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)
Cumyl hydro-peroxide, not more than 90% in diluent type A4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)
Di-tert-butyl peroxide, not more 32% in diluent type A4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)
Dicumyl peroxide, less than or equal to 100% in diluent type B4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)
Isopropyl cumyl hydroperoxide, not more 72% in diluent type A4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)
p-Menthyl hydro-peroxide, not more 72% in diluent type A4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)
Pinanyl hydro-peroxide, not more than 56% in diluent type A4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)
3110ORGANIC PEROXIDE, TYPE F, SOLID
Dicumyl peroxide less than or equal to 100% with inert solids *Maximum quantity per portable tank 2,000 kg4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)
3119ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED
tert-Butyl peroxyacetate, not more than 32% in diluent type B4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)+30 °C+35 °C
tert-Butyl peroxy-2-ethylhexanoate, not more than 32% in diluent B4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)+15 °C+20 °C
tert-Butylperoxypivalate, not more than 27% in diluent type B4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)+5 °C+10 °C
tert-Butyl peroxy-3,5,5-trimethyl-hexanoate, not more than 32% in diluent type B4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)+35 °C+40 °C
Di-(3,5,5-trimethyl-hexanoyl) peroxide, not more than 38% in diluent type A4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)0 °C+5 °C
Peroxyacetic acid, distilled, stabilized, not more than 41%4§ 178.274(d)(2)§ 178.275(d)(3)§ 178.275(g)(1)Not more than 90% at 59 °F (15 °C)+30 °C+35 °C

(h) Bulk packagings other than IBCs. The following bulk packagings are authorized, subject to the conditions and limitations of this section, if the organic peroxide is listed in the Organic Peroxide Portable Tank Table and bulk packagings are authorized, or if the organic peroxide is specifically authorized for transport in a bulk packaging by this paragraph (h), and the bulk packaging conforms to the requirements of this subchapter:

(1) Rail cars. Class DOT 103, 104, 105, 109, 111, 112, 114, 115, or 120 fusion-weld tank car tanks are authorized. DOT 103W, 111A60F1 and 111A60W1 tank car tanks must have bottom outlets effectively sealed from inside. Gauging devices are required on DOT 103W tank car tanks. Riveted tank car tanks are not authorized.

(2) Cargo tanks. Specification MC 307, MC 310, MC 311, MC 312, DOT 407, and DOT 412 cargo tank motor vehicles with a tank design pressure of at least 172 kPa (25 psig) are authorized.

(3) Portable tanks. The following requirements apply to portable tanks intended for the transport of organic peroxides or self-reactive substances. DOT 51, 57, IM 101 portable tanks, and UN portable tanks that conform to the requirements of paragraph (g) of this section, are authorized. Type F organic peroxide or self-reactive substance formulations other than those indicated in the Organic Peroxide Portable Tank Table may be transported in portable tanks if approved by the Associate Administrator. The following conditions also apply:

(i) The portable tank must be designed for a test pressure of at least 0.4 MPa (4 bar).

(ii) The portable tank must be fitted with temperature-sensing devices.

(iii) The portable tank must be fitted with pressure relief devices and emergency-relief devices. Vacuum-relief devices may also be used. Pressure relief devices must operate at pressures determined according to both the properties of the hazardous material and the construction characteristics of the portable tank. Fusible elements are not allowed in the shell.

(iv) The pressure relief devices must consist of reclosing devices fitted to prevent significant build-up within the portable tank of the decomposition products and vapors released at a temperature of 50 °C (122 °F). The capacity and start-to-discharge pressure of the relief devices must be in accordance with the applicable requirements of this subchapter specified for the portable tank. The pressure relief devices must not allow liquid to escape in the event the portable tank is overturned in a loaded condition.

(v)(A) The emergency-relief devices may be of the reclosing or frangible types, or a combination of the two, designed to vent all the decomposition products and vapors evolved during a period of not less than one hour of complete fire engulfment as calculated by the following formula:

Where:

q = heat absorption (W)

A = wetted area (m2)

F = insulation factor (−)

(B) Insulation factor (F) in the formula in paragraph (h)(3)(v)(A) of this section equals 1 for non-insulated vessels and for insulated vessels F is calculated using the following formula:

Where:

U = K/L = heat transfer coefficient of the insulation (W·m−2·K−1); where K = heat conductivity of insulation layer (W·m−1·K−1), and L = thickness of insulation layer (m).

TPO = temperature of material at relieving conditions (K).

(vi) The start-to-discharge pressure of emergency-relief devices must be higher than that specified for the pressure relief devices in paragraph (h)(3)(iv) of this section. The emergency-relief devices must be sized and designed in such a way that the maximum pressure in the shell never exceeds the test pressure of the portable tank.

Note to Paragraph (h)(3)(vi):

An example of a method to determine the size of emergency-relief devices is given in Appendix 5 of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter). A second example of a test method for venting sizing is given in the American Institute of Chemical Engineers Process Safety Progress Journal, June 2002 issue (Vol. 21, No. 2) (Informational materials not requiring incorporation by reference, see § 171.7(b)).

(vii) For insulated portable tanks, the capacity and setting of emergency-relief devices must be determined assuming a loss of insulation from 1% of the surface area.

(viii) Vacuum-relief devices and reclosing devices on portable tanks used for flammable hazardous materials must be provided with flame arresters. Any reduction of the relief capacity caused by the flame arrester must be taken into account and the appropriate relief capacity must be provided.

(ix) Service equipment such as devices and external piping must be designed and constructed so that no hazardous material remains in them after filling the portable tank.

(x) Portable tanks may be either insulated or protected by a sun-shield. If the SADT of the hazardous material in the portable tank is 55 °C (131 °F) or less, the portable tank must be completely insulated. The outer surface must be finished in white or bright metal.

(xi) The degree of filling must not exceed 90% at 15 °C (59 °F).

(xii) DOT 57 metal portable tanks are authorized only for tert-butyl cumyl peroxide, di-(2-tert-butylperoxyisopropyl-benzene(s)), dicumyl peroxide and mixtures of two or more of these peroxides. DOT 57 portable tanks must conform to the venting requirements of paragraph (f) of this section. These portable tanks are not subject to any other requirements of paragraph (h) of this section.

(4) For tertiary butyl hydroperoxide (TBHP), each tank car, cargo tank or portable tank must contain 7.6 cm (3.0 inches) low density polyethylene (PE) saddles having a melt index of at least 0.2 grams per 10 minutes (for example see, ASTM D1238, condition E) as part of the lading, with a ratio of PE to TBHP over a range of 0.008 to 0.012 by mass. Alternatively, plastic or metal containers equipped with fusible plugs having a melting point between 69 °C (156 °F) and 71 °C (160 °F) and filled with a sufficient quantity of water to dilute the TBHP to 65% or less by mass may be used. The PE saddles must be visually inspected after each trip and, at a minimum, once every 12 months, and replaced when discoloration, fracture, severe deformation, or other indication of change is noted.

43. Section 173.226 is revised to read as follows:

§ 173.226
Materials poisonous by inhalation, Division 6.1, Packing Group I, Hazard Zone A.

Division 6.1, Packing Group I, Zone A poisonous by inhalation (see § 173.133) must be packed in non-bulk packagings in accordance with the following paragraphs:

(a) In seamless specification cylinders conforming to the requirements of § 173.40.

(b) In 1A1, 1B1, 1H1, 1N1, or 6HA1 drums further packed in a 1A2 or 1H2 drum. Both inner and outer drums must conform to the performance test requirements of subpart M of part 178 of this subchapter at the Packing Group I performance level. The outer drums may be tested either as a package intended to contain inner packagings (combination package) or as a single packaging intended to contain solids or liquids at a mass corresponding to the mass of the assembled packaging system. All outer drums, even those tested to contain inner packaging or as single packagings for solids, must withstand a hydrostatic test pressure of 100 kPa (15 psig). The outer drum must have a minimum thickness of 1.35 mm (0.053 inch) for a 1A2 outer drum or 6.3 mm (0.248 inch) for a 1H2 outer drum. In addition, the inner drum must—

(1) Be capable of satisfactorily withstanding the hydrostatic pressure test in § 178.605 of this subchapter at a test pressure of 300 kPa (45 psig);

(2) Satisfactorily withstand the leakproofness test in § 178.604 of this subchapter using an internal air pressure of at least twice the vapor pressure at 55 °C (131 °F) of the material to be packaged;

(3) Have screw-type closures that are—

(i) Closed and tightened to a torque prescribed by the closure manufacturer, using a properly calibrated device that is capable of measuring torque;

(ii) Physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation; and

(iii) Provided with a cap seal that is properly applied in accordance with the cap seal manufacturer's recommendations and is capable of withstanding an internal pressure of at least 100 kPa (15 psig).

(4) Have a minimum thickness as follows:

(i) For a 1A1 or 1N1 drum, 1.3 mm (0.051 inch);

(ii) For a 1B1 drum, 3.9 mm (0.154 inch);

(iii) For a 1H1 drum, 3.16 mm (0.124 inch); and

(iv) For a 6HA1 drum, the plastic inner container shall be 1.58 mm (0.0622 inch) and the outer steel drum shall be 0.96 mm (0.0378 inch).

(5) Be isolated from the outer drum by a shock-mitigating, non-reactive material, which completely surrounds the inner packaging on all sides.

(c) In combination packagings, consisting of an inner packaging system and an outer packaging, as follows:

(1) Outer packagings:

Steel drum: 1A2

Aluminum drum: 1B2

Metal drum, other than steel or aluminum: 1N2

Plywood drum: 1D

Fiber drum: 1G

Plastic drum: 1H2

Steel box: 4A

Aluminum box: 4B

Natural wood box: 4C1 or 4C2

Plywood box: 4D

Reconstituted wood box: 4F

Fiberboard box: 4G

Expanded plastic box: 4H2

Solid plastic box: 4H2

(2) Inner packaging system. The inner packaging system consists of two packagings:

(i) an impact-resistant receptacle of glass, earthenware, plastic or metal securely cushioned with a non-reactive, absorbent material, and

(A) Capacity of each inner receptacle may not exceed 4 L (1 gallon).

(B) An inner receptacle that has a closure must have a closure which is physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation.

(ii) Packed within a leak-tight packaging of metal or plastic.

(iii) This combination packaging in turn is packed within the outer packaging.

(A) The total amount of liquid contained in the outer packaging may not exceed 16 L (4 gallons).

(iv) the inner packaging system must conform to the performance test requirements of subpart M of part 178 of this subchapter, at the Packaging Group I performance level when subjected to the following tests:

(A) § 178.603—Drop Test

(B) § 178.604—Leakproofness Test

(C) § 178.605—Hydrostatic Pressure Test

(v) The inner packaging system must meet the above tests without the benefit of the outer packaging.

(vi) The leakproofness and hydrostatic pressure test may be conducted on either the inner receptacle or the outer packaging of the inner packaging system.

(vii) In addition to the requirements in § 173.226(b), the outer package must conform to the performance test requirements of subpart M of part 178 of this subchapter, at the Packaging Group I performance level as applicable for the type of package being used.

(d) If approved by the Associate Administrator, 1A1, 1B1, 1H1, 1N1, 6HA1 or 6HH1 drums described in paragraph (b) of this section may be used without being further packed in a 1A2 or 1H2 drum if the shipper loads the material, palletizes the drums, blocks and braces the drums within the transport vehicle and seals the transport vehicle used. Drums may not be stacked (double decked) within the transport vehicle. Shipments must be from one origin to one destination only without any intermediate pickup or delivery.

(e) Prior to reuse, all authorized inner drums must be leakproofness tested and marked in accordance with § 173.28 using a minimum test pressure as indicated in paragraph (b)(2) of this section.

44. Section 173.227 is revised to read as follows:

§ 173.227
Materials poisonous by inhalation. Division 6.1, Packing Group I, Hazard Zone B.

(a) In packagings as authorized in § 173.226 and seamless and welded specification cylinders conforming to the requirements of § 173.40.

(b) 1A1, 1B1, 1N1 or 1H1 drum or 6HA1 composite further packed in a 1A2 or 1H2 drum. Both the inner and outer drums must conform to the performance test requirements of subpart M of part 178 of this subchapter at the Packing Group I performance level. The outer drums may be tested either as a package intended to contain inner packagings (combination package) or as a single packaging intended to contain solids or liquids at a mass corresponding to the mass of the assembled packaging system. The outer drum must have a minimum thickness of 1.35 mm (0.053 inches) for a 1A2 outer drum or 6.30 mm (0.248 inches) for a 1H2 outer drum. Outer 1A2 and 1H2 drums must withstand a hydrostatic test pressure of 100 kPa (15 psig). Capacity of the inner drum may not exceed 220 liters. In addition, the inner drum must conform to all of the following requirements:

(2) Have screw closures that are—

(i) Closed and tightened to a torque prescribed by the closure manufacturer, using a properly calibrated device that is capable of measuring torque;

(ii) Physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation; and

(iii) Provided with a cap seal that is properly applied in accordance with the cap seal manufacturer's recommendations and is capable of withstanding an internal pressure of at least 100 kPa (15 psig).

(3) Have a minimum thickness as follows:

(i) For a 1A1 drum, 0.69 mm (0.027 inch);

(ii) For a 1B1 drum, 2.79 mm (0.110 inch);

(iii) For a 1H1 drum, 1.14 mm (0.045 inch); or

(iv) For a 6HA1 drum, the plastic inner container shall be 1.58 mm (0.0625 inch), the outer steel drum shall be 0.70 mm (0.027 inch).

(4) Be isolated from the outer drum by a shock-mitigating, non-reactive material which completely surrounds the inner packaging on all sides.

(5) Prior to reuse, all authorized inner drums must be leakproofness tested and marked in accordance with § 173.28 using a minimum test pressure as indicated in paragraph (b)(1) of this section.

(c) 1A1, 1B1, 1H1, 1N1, 6HA1 or 6HH1 drums described in paragraph (b) of this section may be used without being further packed in a 1A2 or 1H2 drum if the shipper loads the material, blocks and braces the drums within the transport vehicle and seals the transport vehicle used. Drums may not be stacked (double decked) within the transport vehicle. Shipments must be from one origin to one destination only without any intermediate pickup or delivery.

45. In § 173.249, paragraph (c) is revised to read as follows:

§ 173.249
Bromine.

(c) UN portable tanks conforming to tank code T22 (see § 172.102 of this subchapter) or specification IM 101 portable tanks conforming with paragraphs (d) through (f) of this section. Except when transported as a residue, the total quantity in one tank may not be less than 88% nor more than 92% of the volume of the tank.

46. In § 173.306, paragraphs (i) and (j) are removed and a new paragraph (i) is added to read as follows:

§ 173.306
Limited quantities of compressed gases.

(i) Aerosols with a capacity of less than 50 ml. Aerosols, as defined in § 171.8 of this subchapter, with a capacity not exceeding 50 ml and with a pressure not exceeding 970 kPa (141 psig) at 55 °C (131 °F), containing no hazardous materials other than a Division 2.2 gas, are not subject to the requirements of this subchapter.

§ 173.307
[Amended]

47. In § 173.307, paragraph (a)(5) is removed.

48. Section 173.313 is added to read as follows:

§ 173.313
UN Portable Tank Table for Liquefied Compressed Gases.

The UN Portable Tank Table for Liquefied Compressed Gases is referenced in § 172.102(c)(7)(iii) of this subchapter for portable tanks that are used to transport liquefied compressed gases. The table applies to each liquefied compressed gas that is identified with Special Provision T50 in Column (7) of the § 172.101 Table. In addition to providing the UN identification number and proper shipping name, the table provides maximum allowable working pressures, bottom opening requirements, pressure relief device requirements, and degree of filling requirements for liquefied compressed gas permitted for transportation in a T50 portable tank. In the minimum test pressure column, “small” means a portable tank with a diameter of 1.5 meters or less when measured at the widest part of the shell, “sunshield” means a portable tank with a shield covering at least the upper third of the shell, “bare” means no sunshield or insulation is provided, and “insulated” means a complete cladding of sufficient thickness of insulating material necessary to provide a minimum conductance of not more than 0.67 w/m2/k. In the pressure relief requirements column, the word “Normal” denotes that a frangible disc as specified in § 178.276(e)(3) of this subchapter is not required.

UN Portable Tank Table for Liquefied Compressed Gases

UN No.Non-refrigerated liquefied compressed gasesMinimum design pressure (bar) small; bare; sunshield; insulatedOpenings below liquid levelPressure relief requirements (See § 178.276(e))Maximum filling density (kg/l)
1005Ammonia, anhydrous29.0Allowed§ 178.276(e)(3)0.53
25.7
22.0
19.7
1009Bromotrifluoromethane or Refrigerant gas R 13B138.0AllowedNormal1.13
34.0
30.0
27.5
1010Butadienes, stabilized7.5AllowedNormal0.55
7.0
7.0
7.0
1011Butane7.0AllowedNormal0.51
7.0
7.0
7.0
1012Butylene8.0AllowedNormal0.53
7.0
7.0
7.0
1017Chlorine19.0Not§ 178.276(e)(3)1.25
17.0Allowed
15.0
13.5
1018Chlorodifluoromethane or Refrigerant gas R 2226.0AllowedNormal1.03
24.0
21.0
19.0
1020Chloropentafluoroethane or Refrigerant gas R 11523.0AllowedNormal1.06
20.0
18.0
16.0
10211-Chloro-1,2,2,2-tetrafluoroethane or Refrigerant gas R 12410.3AllowedNormal1.2
9.8
7.9
7.0
1027Cyclopropane18.0AllowedNormal0.53
16.0
14.5
13.0
1028Dichlorodifluoromethane or Refrigerant gas R 1216.0AllowedNormal1.15
15.0
13.0
11.5
1029Dichlorofluoromethane or Refrigerant gas R 217.0AllowedNormal1.23
7.0
7.0
7.0
10301,1-Difluoroethane or Refrigerant gas R 152a16.0AllowedNormal0.79
14.0
12.4
11.0
1032Dimethylamine, anhydrous7.0AllowedNormal0.59
7.0
7.0
7.0
1033Dimethyl ether15.5AllowedNormal0.58
13.8
12.0
10.6
1036Ethylamine7.0AllowedNormal0.61
7.0
7.0
7.0
1037Ethyl chloride7.0AllowedNormal0.8
7.0
7.0
7.0
1040Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 °COnly authorized in 10 bar insulated portable tanks—Not Allowed§ 178.276(e)(3)0.78
1041Ethylene oxide and carbon dioxide mixture with more than 9% but not more than 87% ethylene oxideSee MAWP definition in § 178.276(a)AllowedNormalSee § 173.32(f)
1055Isobutylene8.1AllowedNormal0.52
7.0
7.0
7.0
1060Methyl acetylene and propadiene mixture, stabilized28.0AllowedNormal0.43
24.5
22.0
20.0
1061Methylamine, anhydrous10.8AllowedNormal0.58
9.6
7.8
7.0
1062Methyl bromide7.0Not Allowed§ 178.276(e)(3)1.51
7.0
7.0
7.0
1063Methyl chloride or Refrigerant gas R 4014.5AllowedNormal0.81
12.7
11.3
10.0
1064Methyl mercaptan7.0Not Allowed§ 178.276(e)(3)0.78
7.0
7.0
7.0
1067Dinitrogen tetroxide7.0Not Allowed§ 178.276(e)(3)1.3
7.0
7.0
7.0
1075Petroleum gas, liquefiedSee MAWP definition in § 178.276(a)AllowedNormalSee § 173.32(f)
1077Propylene28.0AllowedNormal0.43
24.5
22.0
20.0
1078Refrigerant gas, n.o.s.See MAWP definition in § 178.276(a)AllowedNormalSee § 173.32(f)
1079Sulphur dioxide11.6Not Allowed§ 178.276(e)(3)1.23
10.3
8.5
7.6
1082Trifluorochloroethylene, stabilized or Refrigerant gas R 111317.0Not Allowed§ 178.276(e)(3)1.13
15.0
13.1
11.6
1083Trimethylamine, anhydrous7.0AllowedNormal0.56
7.0
7.0
7.0
1085Vinyl bromide, stabilized7.0AllowedNormal1.37
7.0
7.0
7.0
1086Vinyl chloride, stabilized10.6AllowedNormal0.81
9.3
8.0
7.0
1087Vinyl methyl ether, stabilized7.0AllowedNormal0.67
7.0
7.0
7.0
1581Chloropicrin and methyl bromide mixture7.0Not Allowed§ 178.276(e)(3)1.51
7.0
7.0
7.0
1582Chloropicrin and methyl chloride mixture19.2Not Allowed§ 178.276(e)(3)0.81
16.9
15.1
13.1
1858Hexafluoropropylene compressed or Refrigerant gas R 121619.2AllowedNormal1.11
16.9
15.1
13.1
1912Methyl chloride and methylene chloride mixture15.2AllowedNormal0.811954
1954n.o.s.
13.0
11.6
10.1
NAInsecticide gases, flammable,See MAWP definition in § 178.276(a)AllowedNormal§ 173.32(f)
19581,2-Dichloro-1,1,2,2-tetrafluoroethane or Refrigerant gas R 1147.0AllowedNormal1.3
7.0
7.0
7.0
1965Hydrocarbon gas, mixture liquefied, n.o.s.See MAWP definition in 178.276(a)AllowedNormalSee § 173.32(f)
1969Isobutane8.5AllowedNormal0.49
7.5
7.0
7.0
1973Chlorodifluoromethane and chloropentafluoroethane mixture with fixed boiling point, with approximately 49% chlorodifluoromethane or Refrigerant gas R 50228.3AllowedNormal1.05
25.3
22.8
20.3
1974Chlorodifluorobromomethane or Refrigerant gas R 12B17.4AllowedNormal1.61
7.0
7.0
7.0
1976Octafluorocyclobutane or Refrigerant gas RC 3188.8AllowedNormal1.34
7.8
7.0
7.0
1978Propane22.5AllowedNormal0.42
20.4
18.0
16.5
19831-Chloro-2,2,2-trifluoroethane or Refrigerant gas R 133a7.0AllowedNormal1.18
7.0
7.0
7.0
20351,1,1-Trifluoroethane compressed or Refrigerant gas R 143a31.0AllowedNormal0.76
27.5
24.2
21.8
2424Octafluoropropane or Refrigerant gas R 21823.1AllowedNormal1.07
20.8
18.6
16.6
25171-Chloro-1,1-difluoroethane or Refrigerant gas R 142b8.9AllowedNormal0.99
7.8
7.0
7.0
2602Dichlorodifluoromethane and difluoroethane azeotropic mixture with approximately 74% dichlorodifluoromethane or Refrigerant gas R 50020.0AllowedNormal1.01
18.0
16.0
14.5
3057Trifluoroacetyl chloride14.6Not allowed§ 178.276(e)(3)1.17
12.9
11.3
9.9
3070Ethylene oxide and dichlorodifluoromethane mixture with not more than 12.5% ethylene oxide14.0Allowed§ 178.276(e)(3)1.09
12.0
11.0
9.0
3153Perfluoro (methyl vinyl ether)14.3AllowedNormal1.14
13.4
11.2
10.2
31591,1,1,2-Tetrafluoroethane or Refrigerant gas R 134a17.7AllowedNormal1.04
15.7
13.8
12.1
3161Liquefied gas, flammable, n.o.s.See MAWP definition in § 178.276(a)AllowedNormal§ 173.32(f)
3163Liquefied gas, n.o.s.See MAWP definition in § 178.276(a)AllowedNormal§ 173.32(f)
3220Pentafluoroethane or Refrigerant gas R 12534.4AllowedNormal0.95
30.8
27.5
24.5
3252Difluoromethane or Refrigerant gas R 3243.0AllowedNormal0.78
39.0
34.4
30.5
3296Heptafluoropropane or Refrigerant gas R 22716.0AllowedNormal1.2
14.0
12.5
11.0
3297Ethylene oxide and chlorotetrafluoroethane mixture, with not more than 8.8% ethylene oxide8.1AllowedNormal1.16
7.0
7.0
7.0
3298Ethylene oxide and pentafluoroethane mixture, with not more than 7.9% ethylene oxide25.9AllowedNormal1.02
23.4
20.9
18.6
3299Ethylene oxide and tetrafluoroethane mixture, with not more than 5.6% ethylene oxide16.7AllowedNormal1.03
14.7
12.9
11.2
3318Ammonia solution, relative density less than 0.880 at 15 °C in water, with more than 50% ammoniaSee MAWP definition in § 178.276(a)Allowed§ 178.276(e)(3)§ 173.32(f)
3337Refrigerant gas R 404A31.6AllowedNormal0.84
28.3
25.3
22.5
3338Refrigerant gas R 407A31.3AllowedNormal0.95
28.1
25.1
22.4
3339Refrigerant gas R 407B33.0AllowedNormal0.95
29.6
26.5
23.6
3340Refrigerant gas R 407C29.9AllowedNormal0.95
26.8
23.9
21.3

49. In § 173.315, paragraph (a) introductory text is revised to read as follows:

§ 173.315
Compressed gases in cargo tanks and portable tanks.

(a) Liquefied compressed gases that are transported in UN portable tanks must be loaded and offered for transportation in accordance with the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313. A liquefied compressed gas offered for transportation in a cargo tank motor vehicle or a portable tank must be prepared in accordance with this section, §§ 173.32 and 173.33 and subpart E or subpart G of part 180 of this subchapter, as applicable. For cryogenic liquids, see § 173.318. For marking requirements, see §§ 172.326 and 172.328 of this subchapter. Except for UN portable tanks, a liquefied compressed gas must be loaded and offered for transportation in accordance with the following table:

50. In § 173.323, paragraph (b) is revised to read as follows:

§ 173.323
Ethylene oxide.

(b) Ethylene oxide must be packaged in one of the following:

(1) In hermetically sealed glass or metal inner packagings suitably cushioned in an outer package authorized by § 173.201(b). The maximum quantity permitted in any glass inner packaging is 100 g (3.5 ounces), and the maximum quantity permitted in any metal inner packaging is 340 g (12 ounces). After filling, each inner packaging shall be determined to be leak-tight by placing the inner packaging in a hot water bath at a temperature, and for a period of time, sufficient to ensure that an internal pressure equal to the vapor pressure of ethylene oxide at 55 °C is achieved. The total quantity in any outer packaging shall not exceed 100 g (3.5 ounces), and the total quantity in any outer packaging containing only metal inner packagings shall not exceed 2.5 kg (5.5 pounds). Each completed package must be capable of passing all Packing Group I performance tests.

(2) In specification cylinders, as authorized for any compressed gas except acetylene. Pressurizing valves and insulation are required for cylinders over 4 L (1 gallon) capacity. Eductor tubes must be provided for cylinders over 19 L (5 gallons) capacity. Cylinders must be seamless or welded steel (not brazed) with a nominal capacity of no more than 115 L (30 gallons) and may not be liquid full below 82 °C (180 °F). Before each refilling, each cylinder must be tested for leakage at no less than 103.4 kPa (15 psig) pressure. In addition, each cylinder must be equipped with a fusible type relief device with yield temperature of 69 °C to 77 °C (157 °F to 170 °F). The capacity of the relief device and the effectiveness of the insulation must be such that the charged cylinder will not explode when tested by the method described in CGA Pamphlet C-14 or other equivalent method.

(3) In 1A1 steel drums of no more than 231 L (61 gallons) and meeting Packing Group I performance standards. The drum must be lagged of all welded construction with the inner shell having a minimum thickness of 1.7 mm (0.068 inches) and the outer shell having a minimum thickness of 2.4 mm (0.095 inches). Drums must be capable of withstanding a hydrostatic test pressure of 690 kPa (100 psig). Lagging must be of sufficient thickness so that the drum, when filled with ethylene oxide and equipped with the required pressure relief device, will not rupture when exposed to fire. The drum may not be liquid full below 85 °C (185 °F), and must be marked “THIS END UP” on the top head. Before each refilling, each drum must be tested for leakage at no less than 103 kPa (15 psig) pressure. Each drum must be equipped with a fusible type relief device with yield temperature of 69 °C to 77 °C (157 °F to 170 °F), and the capacity of the relief device must be such that the filled drum is capable of passing, without rupture, the test method described in CGA Pamphlet C-14 or other equivalent method.

50a. In Appendix H to Part 173, the fifth sentence of paragraph 3. and paragraph 3.(a) are revised to read as follows:

Appendix H to Part 173—Method of Testing for Sustained Combustibility

3. * * * A suitable apparatus is shown in Figure 32.5.2.1 of the UN Manual of Test and Criteria, and the essential dimensions are given in Figures 32.5.2.1 and 32.5.2.2 of the UN Manual and Tests and Criteria. * * *

(a) Gauge, for checking that the height of the center of the gas jet above the top of the test portion well is 2.2 mm (see Figure 32.5.2.1);

PART 175—CARRIAGE BY AIRCRAFT

51. The authority citation for part 175 continues to read as follows:

Authority:49 U.S.C. 5101-5127; 49 CFR 1.53.

52. In § 175.10, paragraphs (a)(4)(i), (a)(4)(iii), and (a)(18) are revised to read as follows:

§ 175.10
Exceptions.

(a) * * *

(4) * * *

(i) Non-radioactive medicinal and toilet articles (including aerosols) may be carried in checked or carry-on baggage. Release devices on aerosols must be protected by a cap or other suitable means to prevent inadvertent release;

(iii) Other aerosols in Division 2.2 with no subsidiary risk may be carried in checked baggage only. Release devices on aerosols must be protected by a cap or other suitable means to prevent inadvertent release;

(18) Compressed gas cylinders of Division 2.2 worn by passengers for the operation of mechanical limbs and spare cylinders of a similar size for the same purpose in sufficient quantities to ensure an adequate supply for the duration of the journey.

53. Section 175.85 is revised by adding new paragraph (j) to read as follows:

§ 175.85
Cargo location.

(j) A package bearing a KEEP AWAY FROM HEAT handling marking must be protected from direct sunshine and stored in a cool and ventilated place, away from sources of heat.

PART 176—CARRIAGE BY VESSEL

54. The authority citation for part 176 continues to read as follows:

Authority:49 U.S.C. 5101-5127; 49 CFR 1.53.

55. In § 176.2:

a. The definitions for “Explosive article”, “Explosive substance” and “Magazine” are revised.

b. The term “Transport unit” is revised to read “Cargo transport unit”.

c. In the definition “In containers or the like”, the term “transport unit” is removed and the term “cargo transport unit” is added in its place.

The revisions and additions read as follows:

Cargo transport unit means a transport vehicle, a freight container or a portable tank. A closed cargo transport unit means a cargo transport unit in which the contents are totally enclosed by permanent structures. An open cargo transport unit means a cargo transport unit that is not a closed cargo transport unit. Cargo transport units with fabric sides or tops are not closed cargo transport units for the purposes of this part.

Explosive article means an article or device which contains one or more explosive substances. Individual explosive substances are identified in column 17 of the Dangerous Goods List in the IMDG Code.

Explosive substance means a solid or liquid material, or a mixture of materials, which is in itself capable by chemical reaction of producing gas at such a temperature and pressure and at such a speed as to cause damage to its surroundings. Individual explosive substances are identified in column 17 of the Dangerous Goods List in the IMDG Code.

In containers or the like means any clean, substantial, weatherproof box structure which can be secured to the vessel's structure, including a portable magazine or a closed cargo transport unit. Whenever this stowage is specified, stowage in deckhouses, mast lockers and oversized weatherproof packages (overpacks) is also acceptable.

Magazine means an enclosure designed to protect certain goods of Class 1 (explosive) materials from damage by other cargo and adverse weather conditions during loading, unloading, and when in transit; and to prevent unauthorized access. A magazine may be a fixed structure or compartment in the vessel, a closed freight container, a closed transport vehicle, or a portable magazine. Magazines may be positioned in any part of the ship conforming with the relevant provisions for Class 1 (explosive) materials contained in Subpart G of this part provided that magazines which are fixed structures are sited so that their doors, where fitted, are easily accessible.

56. Section 176.27 is revised to read as follows:

§ 176.27
Certificate.

(a) A carrier may not transport a hazardous material by vessel unless a certificate prepared in accordance with § 172.204 of this subchapter has been received.

(b) In the case of an import or export shipment of a hazardous material that will not be transported by rail, highway, or air, the shipper may certify on the bill of lading or other shipping paper that the hazardous material is properly classed, described, marked, packaged, and labeled according to part 172 of this subchapter or in accordance with the requirements of the IMDG Code (IBR, see § 171.7 of this subchapter). See § 171.12 of this subchapter.

(c)(1) A person responsible for packing or loading a freight container or transport vehicle with packages of hazardous materials for transportation by a manned vessel in ocean or coastwise service, must provide the vessel operator, at the time the shipment is offered for transportation by vessel, with a signed container packing certificate stating, at a minimum, that—

(i) The freight container or transport vehicle is serviceable for the materials loaded therein, contains no incompatible goods, and is properly marked, labeled or placarded, as applicable; and

(ii) When the freight container or transport vehicle contains packages, those packages have been inspected prior to loading, are properly marked, labeled or placarded, as applicable; are not damaged; and are properly secured.

(2) The certification may appear on a shipping paper or on a separate document as a statement, such as “It is declared that the packing of the container has been carried out in accordance with the applicable provisions [of 49 CFR], [of the IMDG Code], or [of 49 CFR and the IMDG Code].”

57. In § 176.63, paragraph (e) is revised to read as follows:

§ 176.63
Stowage locations.

(e) Closed cargo transport unit, for the purpose of stowage of Class 1 (explosive) materials on board a vessel, means a unit which fully encloses the contents by permanent structures and can be secured to the ship's structure, and includes a magazine. Cargo transport units with fabric sides or tops are not closed cargo transport units. Where this stowage is specified, stowage in small compartments such as deck-houses and mast lockers are acceptable alternatives. The floor of any closed cargo transport unit or compartment shall either be constructed of wood, close-boarded or so arranged that goods are stowed on sparred gratings, wooden pallets or dunnage. Provided that the necessary additional specifications are met, a closed cargo transport unit may be used for type “A” or “C” class 1 stowage or as a magazine.”

58. In § 176.76, paragraphs (h) and (i) are revised to read as follows:

§ 176.76
Transport vehicles, freight containers, and portable tanks containing hazardous materials.

(h) A fumigated cargo transport unit may only be transported on board a vessel subject to the following conditions and limitations:

(1) The fumigated cargo transport unit may be placed on board a vessel only if at least 24 hours have elapsed since the unit was last fumigated;

(2) The fumigated cargo transport unit is accompanied by a document showing the date of fumigation and the type and amount of fumigant used;

(3) Prior to loading, the master is informed of the intended placement of the fumigated cargo transport unit on board the vessel and the information provided on the accompanying document;

(4) Equipment that is capable of detecting the fumigant and instructions for the equipment's use is provided on the vessel;

(5) The fumigated cargo transport unit must be stowed at least 5 m from any opening to accommodation spaces;

(6) Fumigated cargo transport units may only be transported on deck on vessels carrying more than 25 passengers; and

(7) Fumigants may not be added to cargo transport units while on board a vessel.

(i) A cargo transport unit packed or loaded with flammable gas or flammable liquid having a flashpoint below +23 °C transported on deck must be stowed “away from” possible sources of ignition. In the case of container ships, a distance equivalent to one container space athwartships away from possible sources of ignition applied in any direction will satisfy this requirement.

59. In § 176.83:

a. Paragraphs (a)(5), (d), (e), (f)(1), (f)(3), (g)(1), (g)(2), (g)(3), and (l) are revised;

b. The headings to paragraphs (g) and (f) and the title to Table 176.83(g) are revised; and

c. A new paragraph (m) is added.

The revisions and additions read as follows:

§ 176.83
Segregation.

(a) * * *

(5) Whenever hazardous materials are stowed together, whether or not in a cargo transport unit, the segregation of such hazardous materials from others must always be in accordance with the most restrictive requirements for any of the hazardous materials concerned.

(d) Segregation in cargo transport units: Two hazardous materials for which any segregation is required may not be stowed in the same cargo transport unit.

(e) Segregation of hazardous materials stowed as breakbulk cargo from those packed in cargo transport units: (1) Hazardous materials stowed as breakbulk cargo must be segregated from materials packed in open cargo transport units in accordance with paragraph (c) of this section.

(2) Hazardous materials stowed as breakbulk cargo must be segregated from materials packed in closed cargo transport units in accordance with paragraph (c) of this section, except that:

(i) Where “away from” is required, no segregation between packages and the closed cargo transport units is required; and

(ii) Where “separated from” is required, the segregation between the packages and the closed cargo transport units may be the same as for “away from”.

(f) Segregation of cargo transport units on board container vessels: (1) Except for hatchless container ships, this paragraph applies to segregation of cargo transport units that are carried on board container vessels, or on other types of vessels, provided these cargo spaces are properly fitted for permanent stowage of containers during transport.

(3) Segregation Table. Table § 176.83(f) sets forth the general requirements for segregation between cargo transport units on board container vessels.

(g) Segregation of cargo transport units on board trailerships and trainships: (1) The requirements of this paragraph apply to the segregation of cargo transport units which are carried on board trailerships and trainships or in “roll-on/roll-off” cargo spaces.

(2) For trailerships and trainships which have spaces suitable for breakbulk cargo, containers, or any other method of stowage, the appropriate paragraph of this section applies to the relevant cargo space.

(3) Segregation Table. Table § 176.83(g) sets forth the general requirements for segregation between transport units on board trailerships and trainships.

Table 176.83(g).—Segregation of Cargo Transport Units on Board Trailerships and Trainships

(1) Segregation of containers on board hatchless (open-top) container ships: (1) This paragraph applies to the segregation of cargo transport units that are transported on board hatchless container ships provided that the cargo spaces are properly fitted to give permanent stowage of the cargo transport units during transport.

(2) For container ships that have both hatchless container spaces and other spaces suitable for breakbulk cargo, conventional container stowage, or any other method of stowage, the appropriate requirements of this section apply to the relevant cargo space.

(3) Segregation Table. Table § 176.83(l)(3) sets forth the general requirements for segregation of cargo transport units on board hatchless container ships.

(4) In Table § 176.83(l)(3), a container space means a distance of not less than 6 m (20 feet) fore and aft or not less than 2.5 m (8 feet) athwartship.

TABLE 176.83(l)(3)—Segregation of Cargo Transport Units on Board Hatchless Container Ships

VERTICALHORIZONTAL
Segregation requirementClosed versus closedClosed versus openOpen versus openClosed versus closedClosed versus openOpen versus open
On deckUnder deckOn deckUnder deckOn deckUnder deck
“Away from” 1.One on top of the other permittedOpen on top of closed permittedFore and AFTNo restrictionNo restrictionNo restrictionNo restrictionone container spaceone container space or one bulkhead
Otherwise as for “Open versus open”Athwart-shipsNo restrictionNo restrictionNo restrictionNo restrictionOne container spaceOne container space
“Separated from” 2.Not in the same vertical lineFore and AFTOne container spaceOne container space or one bulkheadOne container spaceone container space or one bulkheadOne container space and not in or above same holdOne bulkhead
Not in the same vertical lineAs for “open versus open”Athwart-shipsOne container spaceOne container spaceTwo container spacesTwo container spacesTwo container spaces and not in or above same holdOne bulkhead
“Separated by a complete compartment or hold from” 3.Fore and AFTOne container space and not in or above same holdOne bulkheadOne container space and not in or above same holdOne bulkheadTwo container spaces and not in or above same holdTwo bulkheads
Athwart-shipsTwo container spaces and not in or above same holdOne bulkheadTwo container spaces and not in or above same holdOne bulkheadTree container spaces and not in or above same holdTwo bulkheads
“Separated longitudinally by an intervening complete compartment or hold from” 4.ProhibitedFore and AFTMinimum horizontal distance of 24 m and not in or above same holdOne bulkhead and minimum horizontal distance of 24 M*Minimum horizontal distance of 24 m and not in or above same holdTwo bulkheadsMinimum horizontal distance of 24 m and not in or above same holdTwo bulkheads
Athwart-shipsProhibitedProhibitedProhibitedProhibitedProhibitedProhibited
*Containers not less than 6 m (20 feet) from intervening bulkhead.
Note: All bulkheads and decks must be resistant to fire and liquid.

(m) Provisions for segregation groups: (1) For the purpose of segregation, materials having certain similar chemical properties have been grouped together in segregation groups. The segregation groups ( such as “acids”, “chlorates”, “permanganates”) and the entries allocated to each of these groups include the substances identified in section 3.1.4 of the IMDG Code. When column (10B) of the § 172.101 Table refers to a numbered stowage provision set forth in § 176.84(b) such as “Stow ‘away from’ acids”, that particular stowage/segregation requirement applies to all the materials allocated to the respective segregation group.

(2) Not all hazardous materials falling within a segregation group are listed by name in the regulations. These materials are shipped under “n.o.s.” entries. Although these “n.o.s.” entries are not listed themselves in the above groups, the shipper must decide whether allocation under a segregation group is appropriate. Mixtures, solutions or preparations containing hazardous materials falling within a segregation group and shipped under an “n.o.s.” entry are also considered to fall within that segregation group.

(3) The segregation groups described above do not address materials which fall outside the classification criteria of the hazardous materials regulations although it is recognized that some non-hazardous materials have certain chemical properties similar to hazardous materials listed in the segregation groups. A shipper or the person responsible for packing the materials into a cargo transport unit who does have knowledge of the chemical properties of such non-hazardous materials may identify a relevant segregation group and apply the segregation requirements for that segregation group.

60. In § 176.84, paragraph (a) is revised, in paragraph (b), Table of provisions, eleven new entries are added in appropriate numerical order and in paragraph (c)(2), three notes in the Provisions for the stowage of Class 1 (explosive) materials table are revised to read as follows: § 176.84 Other requirements for stowage and segregation for cargo vessels and passenger vessels.

(a) General. When Column 10B of the § 172.101 Table refers to a numbered or alpha-numeric stowage provision for water shipments, the meaning and requirements of that provision are set forth in this section. Terms in quotation marks are defined in § 176.83. Other terms used in the table in this section such as “acids”, “chlorates” and “permanganates” indicate different chemical groups referred to here as segregation groups. Materials falling within a segregation group are considered to have certain similar chemical properties and, although not exhaustive in nature, the materials belonging to each group include those substances identified in section 3.1.4 of the IMDG Code as set forth in § 176.83(m).

(b) * * *

CodeProvisions
*  *  *  *  *
133Stow “separated from” sulfur.
134Stow “separated from” UN2716.
135Stow “Separated from” mercury and mercury compounds.
136Stow “Separated from” carbon tetrachloride.
137For arsenic sulphides, Stow “separated from” acids.
138Stow “Separated from” peroxides.
139Stow “Separated from” mercury salts.
140Stow “Separated from” UN3052 and UN3461.
141Stow “away from” radioactive materials.
142Packages in cargo transport units must be stowed so as to allow for adequate air circulation throughout the cargo.
143Prohibited on any vessel carrying explosives (except explosives in Division 1.4, Compatibility group S).
*  *  *  *  *

(c) * * *

(2) * * *

NoteProvision
*  *  *  *  *
19E“Away from” explosives containing chlorates or perchlorates.
*  *  *  *  *
22E“Away from” ammonium compounds and explosives containing ammonium compounds or salts.
23E“Separated from” Division 1.4 and “separated longitudinally by an intervening complete compartment or hold from” Division 1.1, 1.2, 1.3, 1.5, and 1.6 except from explosives of compatibility group J.
*  *  *  *  *

61. In § 176.116, paragraph (c) is revised and a new paragraph (f) is added to read as follows:

§ 176.116
General stowage conditions for Class 1 (explosive) materials.

(c) Security: All compartments, magazines, and cargo transport units containing Class 1 (explosive) materials must be locked or suitably secured in order to prevent unauthorized access.

(f) Under deck stowage of Class 1 (explosive) materials allocated stowage categories 09 and 10:

(1) These Class 1 (explosive) materials must not be stowed in the same compartment or hold with other cargo that is readily combustible (such as items packaged in straw).

(2) The position of stowage of these Class 1 (explosive) materials must be such as to maintain direct access to the hatchway by not overstowing with other cargo except for other Class 1 (explosive) materials.

(3) In all cases, all cargo within the compartment or hold, including Class 1 (explosive) materials stowed in cargo transport units, must be secured so as to eliminate the possibility of significant movement. Where an entire deck is used as a magazine, the stowage must be so arranged that the Class 1 (explosive) materials stowed therein must be removed from the ship before working any cargo in any decks above or below the space in the same hold.

§ 176.122
[Removed and Reserved]

62. Section 176.122 is removed and reserved.

§ 176.124
[Removed and Reserved]

63. Section 176.124 is removed and reserved.

64. Section 176.128 is revised to read as follows:

§ 176.128
Magazine stowage types “A”, “C” and Special Stowage.

(a) The stowage arrangements of Class 1 (explosive) substances and certain articles are subject to varying levels of containment, (except for compatibility group S substances), when stowed below deck. The levels are dependent on the hazard presented and the nature of the particular explosives involved. Columns (10A) and (10B) of the Hazardous Materials Table specify the stowage applicable to each substance or article. The different levels of containment are defined below as “A”, “C” and “Special”.

(b) Magazine stowage type “A”. Magazine stowage type A is required for those substances that must be kept clear of steelwork.

(c) Magazine stowage type “C”. Magazine stowage type C is required for those substances in compatibility group A.

(d) Special Stowage. Special Stowage is required for Explosive substances, n.o.s. in compatibility groups G or L, and for articles in compatibility groups G, H, L and K, which are particularly hazardous.

§ 176.132
[Removed and Reserved]

65. Section 176.132 is removed and reserved.

66. Section 176.133 is revised to read as follows:

§ 176.133
Magazine stowage Type C.

The construction requirements for magazine stowage type C are the same as for a closed cargo transport unit in § 176.63(e). In addition, the magazine must be located as near as practicable to the centerline of the vessel and must not be closer to the vessel's side than a distance equal to one-eighth of the vessel's beam or 2.4 m (8 feet), whichever is less.

67. Section 176.136 is revised to read as follows:

§ 176.136
Special stowage.

(a) Special stowage is required for certain articles presenting both explosive and chemical hazards, such as smoke or lachrymatory (compatibility group G or H), toxic (compatibility group K), or substances and articles which present a special risk (compatibility group L). Except as permitted in paragraph (c) of this section, Class 1 (explosive) materials requiring special stowage must be stowed on deck unless such stowage is impracticable and the COTP authorizes special stowage below deck. Where on deck stowage is recommended and an alternative stowage below deck is permitted by the COTP, the stowage must always be subject to special stowage.

(b) Class 1 (explosive) materials for which special stowage is required must be stowed as far away as practicable from living, accommodation, and working areas, and may not be overstowed. Closed cargo transport units in which such Class 1 (explosive) materials are stowed may not be located closer to the vessel's side than a distance equal to one-eighth of the vessel's beam or 2.4 m (8 feet), whichever is less.

(c) Class 1 (explosive) materials in compatibility groups G and H may be transported in steel magazines or in freight containers. If a freight container is used for this purpose, the floor of the freight container must be leakproof; for example, an all-metal container may be used and a fillet of cement or other material worked across the bottom of the door opening.

(d) Class 1 (explosive) materials stowed in one compartment may not be of more than one compatibility group, except the COTP may allow Class 1 (explosive) materials of compatibility groups G and H in separate steel magazines to be stowed in the same compartment, not less than 3 m (10 feet) apart.

(e) Class 1 (explosive) materials in compatibility groups K and L must be stowed in a steel magazine regardless of the stowage position in the vessel.

68. In § 176.138, paragraph (a) is revised to read as follows:

§ 176.138
Deck stowage.

(a) [Reserved]

69. In § 176.142, paragraph (a) is revised to read as follows:

§ 176.142
Hazardous materials of extreme flammability.

(a) Except as allowed by paragraph (b) of this section, certain hazardous materials of extreme flammability may not be transported in a vessel carrying Class 1 (explosive) materials. This prohibition applies to the following liquid hazardous materials:

Carbon disulfideUN1131Class 3
DiethylzincUN1366Division 4.2
DimethylzincUN1370Division 4.2
Magnesium alkysUN3053Division 4.2
Methyl phosphonous di-chloride, pyrophoric liquid.NA2845Division 6.1
Nickel carbonylUN1259Division 6.1
Pyrophoric liquid, inorganic, n.o.s.UN3194Division 4.2
Pyrophoric liquid, organic, n.o.s.UN2845Division 4.2
Organometallic substance, liquid, pyrophoric.UN3392Division 4.2
Organometallic substance, liquid, pyrophoric, water-reactive.UN3394Division 4.2

70. In § 176.144, paragraphs (a), (b), (c) and (e) are revised to read as follows:

§ 176.144
Segregation of Class 1 (explosive) materials.

(a) Except as provided in § 176.145 of this subchapter, stowage of Class 1 (explosive) materials within the same compartment, magazine, or cargo transport unit is subject to provisions contained in table 176.144(a).

Table 176.144(a)—Authorized Mixed Stowage for Explosives

[An “X” indicates that explosives in the two different compatibility groups reflected by the location of the “X” may not be stowed in the same compartment, magazine, or cargo transport unit]

Compatibility groupsABCDEFGHJKLNS
AXXXXXXXXXXXX
BXXXXXXXXXXX
CXX66X1XXXX4
DXX66X1XXXX4
EXX661XXXX4
FXXXXXXXXXXXX
GXX111XXXXXX
HXXXXXXXXXXX
JXXXXXXXXXXX
KXXXXXXXXXXX
LXXXXXXXXXX2XX
NXX444XXXXXX35
SXX5
Notes: 1. Explosive articles in compatibility group G, other than fireworks and those requiring special stowage, may be stowed with articles of compatibility groups C, D, and E, provided no explosive substances are carried in the same compartment, magazine or cargo transport unit.
2. Explosives in compatibility group L may only be stowed in the same compartment, magazine or cargo transport unit with identical explosives within compatibility group L.
3. Different types of articles of Division 1.6, compatibility group N, may only be transported together when it is proven that there is no additional risk of sympathetic detonation between the articles. Otherwise they must be treated as division 1.1.
4. When articles of compatibility group N are transported with articles or substances of compatibility groups C, D or E, the goods of compatibility group N must be treated as compatibility group D.
5. When articles of compatibility group N are transported together with articles or substances of compatibility group S, the entire load must be treated as compatibility group N.
6. Any combination of articles in compatibility groups C, D and E must be treated as compatibility group E. Any combination of substances in compatibility groups C and D must be treated as the most appropriate compatibility group shown in Table 2 of § 173.52 taking into account the predominant characteristics of the combined load. This overall classification code must be displayed on any label or placard on a unit load or cargo transport unit as prescribed in subpart E (Labeling) and subpart F (Placarding).

(b) Where Class 1 (explosive) materials of different compatibility groups are allowed to be stowed in the same compartment, magazine, or cargo transport unit, the stowage arrangements must conform to the most stringent requirements for the entire load.

(c) Where a mixed load of Class 1 (explosive) materials of different hazard divisions and/or stowage arrangements is carried within a compartment, magazine, or cargo transport unit, the entire load must be treated as belonging to the hazard division having the greatest hazard. (For example, if a load of Division 1.1 (explosive) materials is mixed with Division 1.3 (explosive) materials, the load is treated as a Division 1.1 (explosive) material as defined in § 173.50(b) of this subchapter and the stowage must conform to the most stringent requirements for the entire load).

(e) Segregation on deck: When Class 1 (explosive) materials in different compatibility groups are carried on deck, they must be stored not less than 6 m (20 feet) apart unless they are allowed under Table 176.144(a) to be stowed in the same compartment, magazine, or cargo transport unit.

71. In § 176.146, paragraph (d)(1) is revised to read as follows:

§ 176.146
Segregation from non-hazardous materials.

(d) In order to avoid contamination:

(1) An explosive substance or article which has a secondary POISON hazard label must be stowed “separated from” all foodstuffs, except when such materials are stowed in separate closed cargo transport units, the requirements for “away from” segregation apply.

§ 176.168
[Amended]

72. In § 176.168, the undesignated center heading before § 176.168 is revised to read “CARGO TRANSPORT UNITS AND SHIPBORNE BARGES”.

73. In § 176.170, a new paragraph (b) is added to read as follows:

§ 176.170
Transport of Class 1 (explosive) materials in freight containers.

(b) Freight containers loaded with Class 1 (explosive) materials, except for explosives in Division 1.4, must not be stowed in the outermost row of containers.

74. In § 176.174, paragraphs (a) and (b) are revised to read as follows:

§ 176.174
Transport of Class 1 (explosive) materials in shipborne barges.

(a) Fixed magazines may be built within a shipboard barge. Freight containers may be used as magazines within a barge.

(b) Shipborne barges may be used for the carriage of all types of Class 1 (explosive) materials. When carrying Class 1 (explosive) materials requiring special stowage, the following requirements apply:

(1) Class 1 (explosive) materials in compatibility group G or H must be stowed in freight containers.

(2) Class 1 (explosive) materials in compatibility group K or L must be stowed in steel magazines.

§ 176.600
[Amended]

75. In § 176.600, in paragraph (a), in the last sentence, the wording “closed transport units” is removed and the wording “closed cargo transport units” is added in its place.

PART 178—SPECIFICATIONS FOR PACKAGINGS

76. The authority citation for part 178 continues to read as follows:

Authority:49 U.S.C. 5101-5127; 49 CFR 1.53.

77. In § 178.274, paragraph (f)(l)(v) is revised to read as follows:

§ 178.274
Specifications for UN portable tanks.

(f) * * *

(l) * * *

(v) The rated flow capacity of the spring loaded pressure relief devices, frangible disc or fusible elements in standard cubic meters of air per second (m3/s). For spring loaded pressure relief device the rated flow capacity shall be determined according to ISO 4126-1 (IBR, see § 171.1 of this subchapter); and

78. In § 178.275, paragraph (i)(2) is revised to read as follows:

§ 178.275
Specification for UN Portable Tanks intended for the transportation of liquid and solid hazardous materials.

(i) * * *

(2) The combined delivery capacity of the pressure relief system (taking into account the reduction of the flow when the portable tank is fitted with frangible-discs preceding spring-loaded pressure-relief devices or when the spring-loaded pressure-relief devices are provided with a device to prevent the passage of the flame), in condition of complete fire engulfment of the portable tank must be sufficient to limit the pressure in the shell to 20% above the start to discharge pressure limiting device (pressure relief device). The total required capacity of the relief devices may be determined using the formula in paragraph (i)(2)(i)(A) of this section or the table in paragraph (i)(2)(iii) of this section.

79. In § 178.276, paragraphs (a)(4)(ii)(A), (d), and (e)(3) are revised to read as follows:

§ 178.276
Requirements for the design, construction, inspection and testing of portable tanks intended for the transportation of non-refrigerated liquefied compressed gases.

(a) * * *

(4) * * *

(ii) * * *

(A) Not less than the pressure specified for each liquefied compressed gas listed in the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313; and

(d) Bottom openings. Bottom openings are prohibited on portable tanks when the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313 of this subchapter indicates that bottom openings are not allowed. In this case, there may be no openings located below the liquid level of the shell when it is filled to its maximum permissible filling limit.

(e) * * *

(3) A portable tank intended for the transportation of certain liquefied compressed gases identified in the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313 of this subchapter must have a pressure relief device which conforms to the requirements of this subchapter. Unless a portable tank, in dedicated service, is fitted with a relief device constructed of materials compatible with the hazardous material, the relief device must be comprised of a frangible disc preceded by a reclosing device. The space between the frangible disc and the device must be provided with a pressure gauge or a suitable tell-tale indicator. This arrangement must facilitate the detection of disc rupture, pinholing or leakage which could cause a malfunction of the pressure relief device. The frangible disc must rupture at a nominal pressure 10% above the start-to-discharge pressure of the relief device.

80. In § 178.602, paragraph (b) is revised to read as follows:

§ 178.602
Preparation of packagings and packages for testing.

(b) For the drop and stacking test, inner and single-unit receptacles other than bags must be filled to not less than 95% of maximum capacity (see § 171.8 of this subchapter) in the case of solids and not less than 98% of maximum in the case of liquids. Bags shall be filled to the maximum mass at which they may be used. The material to be transported in the packagings may be replaced by a non-hazardous material, except for chemical compatibility testing or where this would invalidate the results of the tests.

81. In § 178.603, paragraphs (c) and (e)(2) introductory text are revised to read as follows:

§ 178.603
Drop test.

(c) Special preparation of test samples for the drop test.

(1) Testing of plastic drums, plastic jerricans, plastic boxes other than expanded polystyrene boxes, composite packagings (plastic material), and combination packagings with plastic inner packagings other than plastic bags intended to contain solids or articles must be carried out when the temperature of the test sample and its contents has been reduced to −18 °C (0 °F) or lower. Test liquids must be kept in the liquid state, if necessary, by the addition of anti-freeze. Water/anti-freeze solutions with a minimum specific gravity of 0.95 for testing at −18 °C (0 °F) or lower are considered acceptable test liquids. Test samples prepared in this way are not required to be conditioned in accordance with § 178.602(d).

(e) * * *

(2) For liquids in single packagings and for inner packagings of combination packagings, if the test is performed with water:

82. In § 178.810, paragraph (b)(3) is revised to read as follows:

§ 178.810
Drop test.

(b) Special preparation for the drop test.

(3) Rigid plastic IBCs and composite IBCs with plastic inner receptacles must be conditioned for testing by reducing the temperature of the packaging and its contents to −18 °C (0 °F) or lower. Test liquids must be kept in the liquid state, if necessary, by the addition of anti-freeze. Water/anti-freeze solutions with a minimum specific gravity of 0.95 for testing at −18 °C (0 °F) or lower are considered acceptable test liquids, and may be considered equivalent to water for test purposes. IBCs conditioned in this way are not required to be conditioned in accordance with § 178.802.

PART 180—CONTINUING QUALIFICATION AND MAINTENANCE OF PACKAGINGS

83. The authority citation for part 180 continues to read as follows:

Authority:49 U.S.C. 5101-5127; 49 CFR 1.53.

84. In § 180.350, paragraph (c) is revised to read as follows:

§ 180.350
Applicability and definitions.

(c) Routine maintenance of IBCs is the routine performance on:

(1) Metal, rigid plastic or composite IBCs of operations such as:

(i) Cleaning;

(ii) Removal and reinstallation or replacement of body closures (including associated gaskets), or of service equipment conforming to the original manufacturer's specifications provided that the leaktightness of the IBC is verified; or

(iii) Restoration of structural equipment not directly performing a hazardous material containment or discharge pressure retention function so as to conform to the design type (for example, the straightening of legs or lifting attachments), provided the containment function of the IBC is not affected.

(2) Plastics or textile flexible IBCs of operations, such as:

(i) Cleaning; or

(ii) Replacement of non-integral components, such as non-integral liners and closure ties, with components conforming to the original manufacturer's specification; provided that these operations do not adversely affect the containment function of the flexible IBC or alter the design type.

85. In § 180.352, paragraph (d)(1)(iv) is revised and a new paragraph (d)(1)(v) is added to read as follows:

§ 180.352
Requirements for retest and inspection of IBCs.

(d) * * *

(1) * * *

(iv) Retests and inspections performed in accordance with paragraphs (d)(1)(i) and (ii) of this section may be used to satisfy the requirements for the 2.5 and five year periodic tests and inspections required by paragraph (b) of this section, as applicable.

(A) The County in which the routine maintenance was carried out; and

(B) The name or authorized symbol of the party performing the routine maintenance.

(v) Retests and inspections performed in accordance with paragraphs (d)(1)(i) and (ii) of this section may be used to satisfy the requirements for the 2.5 and five year periodic tests and inspections required by paragraph (b) of this section, as applicable.

(e) Requirements applicable to routine maintenance of IBCs. Except for routine maintenance of metal, rigid plastics and composite IBCs performed by the owner of the IBC, whose State and name or authorized symbol is durably marked on the IBC, the party performing the routine maintenance shall durably mark the IBC near the manufacturer's UN design type marking to show the following:

(1) The County in which the routine maintenance was carried out; and

(2) The name or authorized symbol of the party performing the routine maintenance.

(f) Retest date. The date of the most recent periodic retest must be marked as provided in § 178.703(b) of this subchapter.

(g) Record retention. The owner or lessee of the IBC must keep records of periodic retests, initial and periodic inspections, and tests performed on the IBC if it has been repaired. Records must include design types and packaging specifications, test and inspection dates, name and address of test and inspection facilities, names or name of any persons conducting tests or inspections, and test or inspection specifics and results. Records must be kept for each packaging at each location where periodic tests are conducted, until such tests are successfully performed again or for at least 2.5 years from the date of the last test. These records must be made available for inspection by a representative of the Department on request.

Issued in Washington, DC on November 24, 2004, under authority delegated in 49 CFR part 1.

Elaine E. Joost,

Acting Deputy Administrator, Research and Special Programs Administration.

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[FR Doc. 04-27087 Filed 12-17-04; 8:45 am]

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