The Procter & Gamble CompanyDownload PDFPatent Trials and Appeals BoardApr 26, 20212020005041 (P.T.A.B. Apr. 26, 2021) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/271,021 05/06/2014 Jennifer Mary Marsh 12874M 6610 27752 7590 04/26/2021 THE PROCTER & GAMBLE COMPANY GLOBAL IP SERVICES CENTRAL BUILDING, C9 ONE PROCTER AND GAMBLE PLAZA CINCINNATI, OH 45202 EXAMINER RIGGS II, LARRY D ART UNIT PAPER NUMBER 1658 NOTIFICATION DATE DELIVERY MODE 04/26/2021 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): centraldocket.im@pg.com mayer.jk@pg.com pair_pg@firsttofile.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte JENNIFER MARY MARSH, TOSHIYUKI IWATA, and PHAN SHEAN LIM1 ____________ Appeal 2020-005041 Application 14/271,021 Technology Center 1600 ____________ Before FRANCISCO C. PRATS, JOHN G. NEW, and TAWEN CHANG, Administrative Patent Judges. NEW, Administrative Patent Judge. DECISION ON APPEAL 1 We use the word “Appellant” to refer to “applicant” as defined in 37 C.F.R. § 1.42. Appellant identifies The Procter & Gamble Company of Cincinnati, Ohio as the real party-in-interest. App. Br. 1. Appeal 2020-005041 Application 14/271,021 2 SUMMARY Appellant files this appeal under 35 U.S.C. § 134(a) from the Examiner’s Final Rejection of claims 31–34 as unpatentable under 35 U.S.C. § 103 as being obvious over the combination of Ellis et al. (US 2001/0008631 A1, July 19, 2001) (“Ellis”) and Okada et al. (US 2009/0324527 A1, December 31, 2009) (“Okada”), and as evidenced by P. Deschamps et al., The Saga of Copper(II)-L-Histidine, 249 COORDINATION CHEM. REVS. 895–909 (2004) (“Deschamps”) and G. Eby, Stability Constants (logK1) of Various Metal Chelates, in Sequestrants in Foods (Chapter 6), CRC HANDBOOK OF FOOD ADDITIVES, 2d Ed. (T.E. Furia, ed.) (1972) (“Eby”). We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM. NATURE OF THE CLAIMED INVENTION Appellant’s claimed invention is directed to a hair care composition having from about from about 0.025% to about 0.25% by weight of the composition of histidine. Spec. Abstr. REPRESENTATIVE CLAIM Independent claim 31 is representative of the claims on appeal and recites: 31. A stable hair care composition comprising: a. from about 0.025% to about 0.15% by weight of the composition of histidine; and Appeal 2020-005041 Application 14/271,021 3 b. a gel matrix comprising: i. from about 1 % to about 15% by weight of one or more high melting point fatty compounds selected from the group consisting of cetyl alcohol, stearyl alcohol, and mixtures thereof; ii. from about 0.8% to about 10% by weight of a cationic surfactant system comprising cationic surfactant having a single straight alkyl chain with 22 carbon atoms, by weight of said hair care composition; and iii. at least 20% of an aqueous carrier, by weight of said hair care composition; and c. from about 0.2 % to about 5 % by weight a silicone conditioning agent wherein the composition remains stable as measured by no yellowing of the composition. App. Br. 6. ISSUES AND ANALYSIS We agree with, and adopt, the Examiner’s findings, reasoning, and conclusion that the claims are obvious over the combined cited prior art. We address below the arguments raised by Appellant. Issue Appellant argues that the Examiner erred because a person of ordinary skill in the art would not have been motivated to select the elements of claim 31 from the teachings of Ellis. App. Br. 2. Appeal 2020-005041 Application 14/271,021 4 Analysis The Examiner finds that Ellis teaches hair-conditioning compositions comprising 0.005–0.5%, and optimally 0.1–0.3%, basic amino acid by weight, with L-histidine and DL-histidine, and ester derivatives thereof taught as being suitable basic amino acids. Final Act. 3 (citing Ellis ¶¶ 15– 18, 20). The Examiner finds that the compositions taught by Ellis further comprise a fatty alcohol such as cetyl alcohol, stearyl alcohol, and mixtures thereof, in amounts of 0.01–10%, and preferably 0.1–5%, by weight. Id. at 4 (citing Ellis ¶¶ 87–89, Ex. 3). The Examiner also finds that Ellis generally teaches that its compositions comprise approximately 0.1–10 wt% of a cationic surfactant system, and expressly teaches behenyl trimethylammonium chloride, as a suitable species. Final Act. 4 (citing Ellis ¶¶ 78, 80, 86). The Examiner notes that behenyl trimethylammonium chloride is a cationic surfactant having a single straight alkyl chain with 22 carbon atoms, as recited in claim 31). The Examiner finds that Ellis teaches an aqueous solvent as the preferred carrier in its compositions, which comprise more than 20% water. Id. (citing Ellis ¶ 107, Ex. 1–3). Furthermore, the Examiner finds, Ellis teaches silicone conditioning agents as particularly preferred ingredients in its compositions, in amounts of 0.3–5 wt%. Final Act. 4 (citing Ellis ¶¶ 90–106). The Examiner points out that the concentrations for all of constituents taught by Ellis lie within or overlap the claimed ranges, which supports a prima facie case of obviousness. Id. (citing In re Wertheim, 541 F.2d 257, 271 (C.C.P.A. 1976)). Appeal 2020-005041 Application 14/271,021 5 The Examiner acknowledges that Ellis does not teach that the composition yellows. Final Act. 4. However, the Examiner finds that Ellis teaches that the pH of the composition is adjusted to 6–7 by adding acid, such as citric acid. Id. (citing Ellis ¶¶ 35, 37, 84–85, 115, Ex. 1). The Examiner points out that Appellant’s Specification discloses that yellowing is minimized by reducing the pH to about 4.7–7.3, by the addition, e.g., of citric acid. Id. (citing Spec. ¶ 126). The Examiner therefore reasons that the compositions of Ellis can be considered to inherently meet the limitation of claim 31 regarding no yellowing of the composition, absent any evidence to the contrary. The Examiner further finds that, with respect to claims 32–33, Ellis teaches that its compositions may also comprise chelating agents (e.g., EDTA), vitamin E derivatives, fragrances, antimicrobials, and coloring agents. Final Act. 4 (citing Ellis ¶ 108). The Examiner reasons that Ellis inherently teaches a gel matrix, as recited in the claims, by teaching shampoo/conditioning compositions, which are typically “gels” within the meaning of the claims on appeal. Final Act. 5. However, the Examiner also relies upon Okada as expressly teaching a similar composition constituting “gel matrix” within the meaning of the instant claims. Id. The Examiner concludes that it would have been obvious to a person of ordinary skill in the art to compose the compositions of Ellis by (1) combining the behenyl trimethylammonium cationic surfactant with the high melting point fatty compounds (e.g., cetyl alcohol and/or stearyl alcohol) and the aqueous carrier and (2) forming a gel matrix, to provide improved stability and conditioning benefits, such as slippery feel during the Appeal 2020-005041 Application 14/271,021 6 application to wet hair and softness and moisturized feel on dry hair, product appearance, and rheology, as taught by Okada. Final Act. 6 (citing Okada ¶¶ 17–18, 47, 55, 113). The Examiner reasons that a skilled artisan would have been motivated to combine the elements of Ellis in the form of a gel matrix, yielding a product with a richer, thicker, and/or more concentrated product appearance, as taught by Okada. Id. (citing Okada ¶ 7) Appellant argues that a person of ordinary skill in the art would not have been motivated to select the constituents comprising histidine and a cationic surfactant comprising a C22 alkyl moiety, because, Appellant asserts, Ellis does not suggest these elements. App. Br. 2–3. Appellant also argues that the Examiner has failed to demonstrate that a skilled artisan would have been motivated to: (1) modify the teachings of the Ellis and Okada, neither of which are technically similar to the crux of Appellant’s invention (viz., selective metal chelation without impacting hair care composition integrity); 2) consider and combine the teachings of Ellis and Okada, from among all the prior art concerning hair care compositions; 3) modify Ellis based on only certain teachings of a reference with much different disclosure and that is directed to a different problem and solution, and 4) without any motivation to do so–other than the fact that the individual elements of the claims are found in multiple references discussing hair care compositions–combine the specific teachings from Ellis and Okada to arrive at a composition of Appellants' claims. Id. Appellant alleges that the Examiner has impermissibly relied upon hindsight analysis in constructing a prima facie case of obviousness. Id. Alternatively, Appellant argues, even if the Examiner has established a prima facie case of obviousness, any such case is overcome by the Appeal 2020-005041 Application 14/271,021 7 showing of unexpected results in Appellant’s Specification. App. Br. 3 (citing Spec. 2–3, 31–32). Appellant points to the Specification’s disclosure that: It has been found that a chelant having a high Stability Constant for Copper (KCuL) in combination with a low Stability Constant for Calcium (KCaL) will demonstrate a sufficient level of selective affinity for these redox metals and thus inhibit the deposition of the minerals onto hair. Chelants having this selective affinity may also reduce the quantities of redox metals already deposited. Suitable chelants for high affinity for transition metals such as copper and iron generally have at least one negative charge such as amino carboxylates or amino phosphonates. However, chelants with a negative charge, for example EDDS, can interfere with the stability of the product and specifically form a precipitate with the cationic surfactants which ultimately can lead to a difficulties maintaining the desired viscosity of the conditioner, making it runny and not acceptable for use. In addition the higher charged anionic materials increase ionic strength of the system which can lead to phase separation. Specifically, the longer chain cationic surfactants (C22) will form a turbid solution when these anionic chelants are added, even at low levels. (See Fig. 1) These longer chain surfactants (C22) will be more sensitive to the addition of anionic chelants than the shorter chain surfactants (C18) due to their higher molecular weight. In addition, the longer chain C22 cationic surfactants are more hydrophobic than C18 cationic surfactants and have lower water solubility. The C22 cationic surfactants are important to deliver a high level of wet hair feel conditioning performance because the structures formed have a higher percentage of lamella structure which drives deposition of silicone and the surfactant/fatty alcohol gel matrix which ultimately leads to improved wet conditioning performance vs. the C18 cationic surfactants. App. Br. 3–4 (quoting Spec. 2–3). Appellant argues that the claimed conditioner composition thus comprises a “chelant that can inhibit the Appeal 2020-005041 Application 14/271,021 8 deposition of minerals in hair but not interfere with the stability of the conditioner and its wet conditioning performance and deliver superior conditioning performance.” Id. Furthermore, contends Appellant the Specification discloses that: To demonstrate the stability of histidine in a hair conditioning composition, the histidine level in Example 1 was varied from 0% up to 0.25% and the viscosity was measured. The viscosity remains stable with histidine at a level of 0.10% and 0.25%, as demonstrated by the viscosity measurements included in Table 1. App. Br. 4 (quoting Spec. 32–33, Table 1). We are not persuaded by Appellant’s arguments. As an initial matter, and contrary to Appellant’s contention that Ellis does not suggest “compositions comprising histidine and a cationic surfactant comprising a C22 alkyl moiety” (App. Br. 2–3), Ellis expressly teaches: Compositions of the invention contain as a further essential component, a hair benefit agent which is a mixture of a basic amino acid and a fatty acid. … By “basic amino acid” is meant those amino acids having more basic groups than carboxyl groups. Suitable basic amino acids are L-arginine, DL-arginine hydrochloride, L-histidine, DL- histidine, L-lysine, and DL-lysine. L-Arginine is particularly preferred. Ellis ¶¶ 14–15 (emphasis added). Ellis thus expressly teaches “histidine.” Although Ellis teaches that L-arginine is “particularly preferred,” that does not negate Ellis’ express teaching of histidine. In our obviousness analysis “all disclosures of the prior art, including unpreferred embodiments, must be considered.” Merck & Co., Inc. v. Biocraft Labs., Inc., 874 F.2d 804, 807 Appeal 2020-005041 Application 14/271,021 9 (Fed. Cir. 1989) (quoting In re Lamberti, 545 F.2d 747, 750 (C.C.P.A. 1976)). Histidine is one of a very small genus of basic amino acids taught by Ellis as acceptable in its compositions. Ellis also teaches: Such a conditioner will comprise one or more conditioning surfactants which are cosmetically acceptable and suitable for topical application to the hair. Suitable conditioning surfactants are selected from cationic surfactants, used singly or in admixture. Examples of suitable cationic conditioning surfactants include quaternary ammonium cationic surfactants. Suitable quaternary ammonium cationic surfactants for use in hair conditioners of the invention include cetyltrimethylammonium chloride, behenyltrimethylammonium chloride,…. Ellis ¶¶ 77–80 (emphasis added). Behenyl trimethylammonium chloride is a “cationic surfactant having a single straight alkyl chain with 22 carbon atoms,” as recited in claim 1. See, e.g., Chemical Book, Behenyl Trimethyl Ammonium Chloride, available at: https://www.chemicalbook.com/ ChemicalProductProperty_EN_CB31122373.htm (last visited April 16, 2021). Both histidine and behenyl trimethylammonium chloride are taught by Ellis in ranges of concentrations that are within, or substantially overlap those recited in claim 31. See Ellis ¶¶ 20, 86. Ellis thus expressly teaches the constituents disputed by Appellant. Appellant argues that a person of ordinary skill in the art would have had no reason to modify the teachings of Ellis and Okada, neither of which are technically similar to the crux of Appellant’s invention. App. Br. 3. Appeal 2020-005041 Application 14/271,021 10 However, both Ellis and Okada teach hair conditioner compositions (see Ellis Abstr., Okada Abstr.), and Ellis expressly teaches the constituents and concentration ranges recited in the claims, which, with the exception of histidine and behenyl trimethylammonium chloride, Appellant does not dispute. Appellant also argues that the Examiner has failed to demonstrate that a skilled artisan would have been motivated to “consider and combine the teachings of Ellis and Okada, from among all the prior art concerning hair care compositions.” App. Br. 3. Both Ellis and Okada are analogous art, teaching hair conditioning compositions; Ellis expressly teaches the constituents and concentration ranges recited in the claims, and Okada’s compositions substantially overlap this teaching. Furthermore, a person of ordinary skill is “presumed to be aware of all the pertinent prior art.” Standard Oil Co. v. American Cyanamid Co., 774 F.2d 448, 454 (Fed. Cir. 1985) (emphasis added). Consequently, the Examiner need not provide a further motivation to seek out the cited references. Appellant argues further that the Examiner has failed to demonstrate why a person of ordinary skill in the art would have been motivated to “modify Ellis based on only certain teachings of a reference with much different disclosure and that is directed to a different problem and solution.” App. Br. 3. We are not persuaded. Claim 31 is directed to a “stable hair care composition.” As we have explained, Ellis and Okada are both directed to hair care compositions, and Ellis expressly teaches all of the constituents and concentration ranges recited by the claims on appeal. It is not necessary to “modify” the teachings of Ellis when directly following its express teachings and suggestions. Appeal 2020-005041 Application 14/271,021 11 Appellant’s alleged demonstration of “unexpected results” is no more persuasive. As an initial matter, “when unexpected results are used as evidence of nonobviousness, the results must be shown to be unexpected compared with the closest prior art.” In re Baxter Travenol Labs., 952 F.2d 388, 392 (Fed. Cir. 1991). In this instance, the closest prior art is the Ellis reference, as cited by the Examiner. Appellant makes no showing of record that the compositions of Ellis, which comply with the requirements of the claimed composition, would not also possess the same allegedly unexpected properties. Indeed: Where, as here, the claimed and prior art products are identical or substantially identical, or are produced by identical or substantially identical processes, the PTO can require an applicant to prove that the prior art products do not necessarily or inherently possess the characteristics of his claimed product.… Whether the rejection is based on ‘inherency’ under 35 U.S.C. § 102, on ‘prima facie obviousness’ under 35 U.S.C. § 103, jointly or alternatively, the burden of proof is the same, and its fairness is evidenced by the PTO’s inability to manufacture products or to obtain and compare prior art products. In re Best, 562 F.2d 1252, 1255 (C.C.P.A. 1977). Absent any such comparative showing by Appellant, we are not persuaded that the claimed composition possesses unexpected properties. Furthermore, Appellant argues that its claimed conditioner composition comprises a “chelant that can inhibit the deposition of minerals in hair but not interfere with the stability of the conditioner and its wet conditioning performance and deliver superior conditioning performance.” See App. Br. 4 (citing Spec. 2–3). Appeal 2020-005041 Application 14/271,021 12 As an initial matter, we note that only dependent claim 33 recites a “chelants” as part of a genus of “additional benefit agents,” without further elaboration. Moreover, Ellis teaches: Compositions of this invention may contain any other ingredient normally used in hair treatment formulations. These other ingredients may include viscosity modifiers, preservatives, colouring agents, polyols such as glycerine and polypropylene glycol, chelating agents such as EDTA, antioxidants such as vitamin E acetate, fragrances, antimicrobials and sunscreens. Each of these ingredients will be present in an amount effective to accomplish its purpose. Ellis ¶ 108 (emphasis added). Ellis thus expressly teaches a “chelant” as an additional constituent. As for the properties of such a chelant, as argued by Appellant, viz., that it can “inhibit the deposition of minerals in hair but not interfere with the stability of the conditioner and its wet conditioning performance and deliver superior conditioning performance,” no such functional limitation is recited in the claims on appeal. Consequently, these properties are not limiting upon claim 33. See In re Van Geuns, 988 F.2d 1181, 1184 (Fed. Cir. 1993) (holding that although the claims are interpreted in light of the specification, limitations from the specification may not be read into the claims). Because we are not persuaded by Appellant that the Examiner has either failed to establish a prima facie case, or that Appellant’s unexpected results overcome any prima facie conclusion of obviousness, we affirm the Examiner’s rejection of claims 31–34. Appeal 2020-005041 Application 14/271,021 13 CONCLUSION The rejection of claims 31–34 as unpatentable under 35 U.S.C. § 101 is affirmed. AFFIRMED Claim(s) Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed 31–34 103 Ellis, Okada 31–34 Copy with citationCopy as parenthetical citation