The Boeing CompanyDownload PDFPatent Trials and Appeals BoardDec 17, 20212021000838 (P.T.A.B. Dec. 17, 2021) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/058,804 10/21/2013 William Alan Thompson 038190/433063 1015 67141 7590 12/17/2021 Boeing and Alston & Bird, LLP ONE SOUTH AT THE PLAZA 101 SOUTH TRYON STREET, SUITE 4000 CHARLOTTE, NC 28280-4000 EXAMINER BAREFORD, KATHERINE A ART UNIT PAPER NUMBER 1718 NOTIFICATION DATE DELIVERY MODE 12/17/2021 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): patentadmin@boeing.com usptomail@alston.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte WILLIAM ALAN THOMPSON, MICHAEL H. WARE, NEHA BORKAR, and MARC J. FRONING Appeal 2021-000838 Application 14/058,804 Technology Center 1700 Before TERRY J. OWENS, GEORGE C. BEST, and DONNA M. PRAISS, Administrative Patent Judges. OWENS, Administrative Patent Judge. DECISION ON APPEAL STATEMENT OF THE CASE Pursuant to 35 U.S.C. § 134(a), the Appellant1 appeals from the Examiner’s decision to reject claims 1–3, 5–8, 11–14, 22, 23, and 25–32. We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM. 1 “Appellant” refers to “applicant” as defined in 37 C.F.R. § 1.42. The Appellant identifies the real party in interest as The Boeing Company. (Appeal Br. 2). Appeal 2021-000838 Application 14/058,804 2 CLAIMED SUBJECT MATTER The claims are directed to a method for coating a composite material. Claim 1, reproduced below, illustrates the claimed subject matter: 1. A method of coating a composite material, the method comprising: applying an adhesion promotion layer to the composite material, wherein the composite material comprises a plurality of layers stacked one upon another so as to include a major surface formed by an outermost layer and an edge portion at which edges of the plurality of layers are exposed, wherein applying an adhesion promotion layer comprises applying the adhesion promotion layer to at least the edges of the plurality of layers of the composite material that are exposed at the edge portion, wherein the adhesion promotion layer comprises a binder paint and a plurality of metal particles within the binder paint, wherein the binder paint comprises a hardener and a base component that is free of pigments, wherein the binder paint and the plurality of metal particles have a mix ratio in which there is more by volume of the base component than the metal particles and in which there is more by volume of the metal particles than the hardener, and wherein the binder paint comprises a service temperature range from about -65 degrees Fahrenheit to about 350 degrees Fahrenheit; roughening a surface of the adhesion promotion layer by grit blasting the surface at a pressure of between 20 psi and 40 psi and at an angle of between 30 degrees and 60 degrees; applying a twin wire arc bond coating to the adhesion promotion layer after the roughening of the surface of the adhesion promotion layer, wherein the twin wire arc bond coating comprises a thickness of about 50 µm to about 150 µm; and applying a thermal spray coating comprising a high velocity oxygen fuel spray coating including metal particles to the twin wire arc bond coating, wherein applying the thermal spray coating comprises applying the thermal spray coating to the twin wire arc bond coating on at least the edges of the plurality of layers of the composite material, wherein the high Appeal 2021-000838 Application 14/058,804 3 velocity oxygen fuel spray coating comprises a thickness of about 150 µm to about 400 µm. REFERENCES The Examiner relies upon the following prior art: Name Reference Date Ayers US 3,814,558 June 4, 1974 Herman US 4,391,928 July 5, 1983 Goel US 4,698,408 Oct. 6, 1987 Imao US 4,704,328 Nov. 3, 1987 Fisher US 5,230,946 July 27, 1993 Wick US 5,261,191 Nov. 16, 1993 Sangeeta US 6,294,261 B1 Sept. 25, 2001 Mor US 6,428,630 B1 Aug. 6, 2002 Dietz US 6,475,616 B1 Nov. 5, 2002 Lin US 2003/0026917 A1 Feb. 6, 2003 Saylor US 2003/0134956 A1 July 17, 2003 Darolia US 6,607,611 B1 Aug. 19, 2003 Chapman US 2003/0173460 A1 Sept. 18, 2003 Passman US 2007/0042126 A1 Feb. 22, 2007 Fernihough US 2008/0085395 A1 Apr. 10, 2008 Nazmy US 2008/0241560 A1 Oct. 2, 2008 Helmick US 2010/0247927 A1 Sept. 30, 2010 Knepper US 2011/0091709 A1 Apr. 21, 2011 Raybould US 2012/0219808 A1 Aug. 30, 2012 Smith Proceed. 7th Natl. Thermal Spray Conf. June 24, 1994 AWS AWS Welding Handbook 9.3, Ch. 11 2007 Desothane® Data Desothane® HS Polyurethane Topcoats/CA 8000 Series Feb. 2010 REJECTIONS The claims stand rejected under 35 U.S.C. § 103 as follows: Appeal 2021-000838 Application 14/058,804 4 1) Claims 1, 2, 6–8, 22, 31, and 32 over Knepper in view of Imao, Goel, Desothane® Data, Fisher, Passman, Dietz, either Saylor or Wick, Smith, AWS, Helmick, and either Nazmy or Raybould; 2) Claim 3 over Knepper in view of Imao, Goel, Desothane® Data, Fisher, Passman, Dietz, either Saylor or Wick, Smith, AWS, Helmick, either Nazmy or Raybould, and Ayers; 3) Claim 5 over Knepper in view of Imao, Goel, Desothane® Data, Fisher, Passman, Dietz, either Saylor or Wick, Smith, AWS, Helmick, and either Nazmy or Raybould, alone or in view of Chapman; 4) Claim 23 over Knepper in view of Imao, Goel, Desothane® Data, Fisher, Passman, Dietz, either Saylor or Wick, Smith, AWS, Helmick, either Nazmy or Raybould, and Mor; 5) Claim 27 over Knepper in view of Imao, Goel, Desothane® Data, Fisher, Passman, Dietz, either Saylor or Wick, Smith, AWS, Helmick, either Nazmy or Raybould, Darolia, and Lin; 6) Claims 11, 13, and 25 over Knepper in view of Imao, Goel, Desothane® Data, Dietz, Smith, AWS, Helmick, Nazmy, Fernihough, Passman, and either Saylor or Wick; 7) Claim 12 over Knepper in view of Imao, Goel, Desothane® Data, Dietz, Smith, AWS, Helmick, Nazmy, Fernihough, Passman, and either Saylor or Wick, and Ayres; 8) Claim 14 over Knepper in view of Imao, Goel, Desothane® Data, Dietz, Smith, AWS, Helmick, Nazmy, Fernihough, Passman, and either Saylor or Wick, and Fisher; Appeal 2021-000838 Application 14/058,804 5 9) Claim 26 over Knepper in view of Imao, Goel, Desothane® Data, Dietz, Smith, AWS, Helmick, Nazmy, Fernihough, Passman, and either Saylor or Wick, and Mor; 10) Claim 28 over Knepper in view of Imao, Goel, Desothane® Data, Dietz, Smith, AWS, Helmick, Nazmy, Fernihough, Passman, and either Saylor or Wick, and either the admitted state of the prior art or Herman; and 11) Claims 29 and 30 over Knepper in view of Imao, Goel, Desothane® Data, Dietz, Smith, AWS, Helmick, Nazmy, Fernihough, Passman, and either Saylor or Wick, and Sangeeta. OPINION The Appellant argues only the independent claims (1 and 11) (Appeal Br. 8–19). We therefore limit our discussion to those claims. The dependent claims stand or fall with the independent claim from which they depend. See 37 C.F.R. § 41.37(c)(1)(iv) (2013). The Appellant argues that “the large number of references cited and combined in an effort to reject the currently pending claims is unreasonable and such a combination would not be apparent to one of ordinary skill in the art” (Appeal Br. 8), and “[t]here is no motivation to combine the fourteen cited references and to select arbitrary features of each reference in an effort to arrive at the claimed features” (Appeal Br. 9). The Appellant sets forth the Examiner’s obviousness conclusion and then asserts that “the asserted combination is merely a statement of possibilities of combining various features extracted from the cited art without any suggestion within the references that it would be desirable to combine the references in any manner, or to solve a problem identified in any of the cited references” (Appeal Br. 10), and: Appeal 2021-000838 Application 14/058,804 6 The motivation quoted above has no relation to any recognized problem, deficiency, or purpose of the cited art. Nothing in either Knepper, Imao, Goel, or Dietz provides a reasonable basis or rationale for why or how one of ordinary skill in the art would modify Knepper, Imao, Goel, or Dietz with the disclosures of one another. There was no known problem that would lead to the result of combining Knepper, Imao, Goel, and Dietz in such a way as to arrive at the claimed features. This alleged motivation amounts merely to a general conclusory statement without a clear articulation of the reasons why the claimed invention would have been obvious. [(Appeal Br. 10–11).] The Appellant’s arguments do not specifically address the Examiner’s reasoning in arriving at the obviousness conclusion. The Appellant’s broad assertions are insufficient to show that the Examiner’s reasoning is incorrect and, consequently, there is reversible error in the Examiner’s conclusion of obviousness. The Appellant sets forth three specific arguments: 1) the prior art fails to suggest the recited service temperature; 2) the prior art’s teaching of high velocity oxygen fuel (HVOF) and arc-wire coatings is only for ceramics; and 3) the prior art fails to suggest the recited relative coating thicknesses (Appeal Br. 11–18). Service Temperature The Appellant’s claims 1 and 11 require an adhesion promoting layer comprising a binder paint having a service temperature of about -65 to about 350 °F. The Appellant’s Specification states (¶ 23): The binder paint of one aspect has a service temperature range with an upper end temperature that is sufficiently high so as to withstand the transient high temperatures to which the binder paint may be subjected during a thermal spray process. In one Appeal 2021-000838 Application 14/058,804 7 aspect, for example, the binder paint service temperature ranges from about -65°F to about +350°F. Knepper, before thermal spraying a functional coating onto an aircraft or spacecraft fiber composite component (1), applies a resin/adhesive primer coating (13) to the fiber composite component (1) (¶¶ 25, 34, 44, 45, 58). Imao discloses an undercoat composition that comprises an inorganic filler and an organic binder that can be a urethane resin, and strongly adheres a flame-sprayed ceramic to a fiber-reinforced resin (col. 1, ll. 7–11; col. 3, ll. 8–17, 43–46, 54–55). Desothane® Data discloses a polyurethane topcoat for conventional and high-solids epoxy primers that is useful for protecting the exterior of aircraft and has a service temperature of -65 to 350 °F (pp. 1–2). Goel discloses a high-heat-resistant, two-component, polyurethane- based adhesive that has excellent adhesion to fiberglass-reinforced plastic and withstands high heat bake cycles of around 400 °F for one hour or more (col. 1, ll. 6–13, 64–66; col. 4, ll. 18–25). Thus, the adhesive can “withstand the transient high temperatures to which the binder paint may be subjected during a thermal spray process” (Spec. ¶ 23) and, therefore, can meet the Appellant’s service temperature range requirement of about -65 °F to about +350 °F. The Appellant argues that Desothane® Data’s topcoat does not correspond to the Appellant’s adhesion promotion layer (Appeal Br. 13), and in reliance upon Goel’s column 1, lines 53–57, argues that Goel’s 400 °F is not a service temperature, but, rather, is a temperature at which adhesion loss is resisted after exposure for 30 minutes or more (Appeal Br. 12). Appeal 2021-000838 Application 14/058,804 8 The cited portion of Goel discloses: “The conventional adhesives based on the above polymerization reactions are known to have poor high heat resistance and usually suffer loss of adhesion after high temperature exposures near 400 degrees F. for 30 minutes or more.” Goal’s adhesive “withstands high heat bake cycles of around 400 degrees F. for a period of one hour or more” (col. 4, ll. 23–25). Imao would have indicated to one of ordinary skill in the art that the disclosed undercoat composition comprising an inorganic filler and an organic binder that can be a urethane resin would strongly adhere Knepper’s thermal sprayed coating to the fiber composite component, thereby functioning as Knepper’s resin/adhesive primer coating. Goel’s disclosure that the high-heat-resistant, two-component, polyurethane- based adhesive has excellent adhesion to fiberglass-reinforced plastic and withstands high heat bake cycles of around 400 °F for one hour or more would have indicated to one of ordinary skill in the art that Goel’s two- component, polyurethane-based adhesive would be suitable as Imao’s urethane resin used as the resin/adhesive primer coating on Knepper’s aircraft component which, as indicated by Desothane® Data, has a service temperature no higher than 350 °F. Thus, the applied references would have led one of ordinary skill in the art, through no more than ordinary creativity, to the Appellant’s adhesion promoting layer comprising a binder paint having a service temperature of about -65 to about 350 °F. See KSR Int’l Co. v. Teleflex Inc., 550 U.S. 398, 421 (2007) (“A person of ordinary skill is also a person of ordinary creativity, not an automaton”). In making an obviousness determination one “can take account of the inferences and creative steps that a person of ordinary skill in the art would employ.” KSR 550 U.S. at 418. Appeal 2021-000838 Application 14/058,804 9 High Velocity Oxygen Fuel and Arc-wire Coatings Smith discloses that high interfacial stresses in fiberglass-reinforced polymers (FRPs) many times need to be accommodated by interfacial layers to achieve acceptable bonding of a thermal spray coating (pp. 68–69), and that an wire arc spray interlayer: 1) due to lower droplet impact velocities, lowers the potential for FRP fiber/matrix damage; 2) due to low jet temperature, eliminates polymer matrix degradation; and 3) due to increased thermal conductivity, protects underlying FRPs from thermal degradation from subsequent combustion (HVOF) or plasma spraying (p. 69, col. 2). The exemplified thermal spray coating materials for FRPs include aluminum and copper (p. 69; Table 3). The Appellant argues that Smith’s disclosure that “[i]f ceramic coatings are needed, many times a wire-arc sprayed interlayer is deposited first followed by a plasma sprayed ceramic layer” (p. 69, col. 2) would have indicated to one of ordinary skill in the art that a wire-arc sprayed interlayer is to be deposited onto FRP before a thermal spray coating is applied thereto only when the coating is ceramic (Appeal Br. 14). Smith’s benefits of a wire-arc sprayed interlayer set forth above, i.e., lowering of the potential for FRP fiber/matrix damage, elimination of polymer matrix degradation, and protection of underlying FRPs from thermal degradation from subsequent combustion or plasma spraying, appear to be applicable to combustion and plasma spraying generally. Hence, one of ordinary skill in the art, through no more than ordinary creativity, would have applied a wire-arc sprayed interlayer to FRP before combustion or plasma spraying onto it any of Smith’s disclosed ceramics, metals, or WC/Co (p. 69). See KSR, 550 U.S. at 421. Appeal 2021-000838 Application 14/058,804 10 Relative Coating Thicknesses Helmick discloses “a coating system that provides sulfidation protection at elevated temperatures within a sulfur-containing environment, such as the hostile thermal environment of a gasification system used in gas turbine power generation plants” (¶ 1). The surface region (12) coated can be a nickel-based superalloy (¶ 12). The coating system comprises a thermal barrier coating (TCB 18) adhered to the surface region (12) by a bond coat (16) overlying and directly contacting the surface (12) (¶ 13). The bond coat (16) can be made of niobium or molybdenum blended with a bond coat composition such as CoCrAlY or FeCrAlY (¶ 20). A particularly suitable TBC material is yttria-stabilized zirconia (¶ 13). The bond coat (16) can be formed by cored-wire arc spray and has a particularly suitable thickness range of about 150–400 micrometers (¶¶ 15, 21). The TBC can be formed by HVOF and typically has a thickness of about 75–300 micrometers (¶ 13). The Appellant argues that “neither Smith nor AWS, nor any of the remaining cited references, teach or suggest applying a twin wire arc bond coating having a thickness of about 50 µm to about 150 µm followed by a thermal spray coating including a high velocity oxygen fuel spray coating having a thickness of about 150 µm to about 400 µm” (Appeal Br. 14). The Examiner relies upon Helmick for a disclosure of thickness ranges overlapping the Appellant’s recited ranges (Final 15). Use of amounts within the overlapping ranges would have been prima facie obvious to one of ordinary skill in the art. See In re Geisler, 116 F.3d 1465, 1469-70 (Fed. Cir. 1997); In re Boesch, 617 F.2d 272, 276 (CCPA 1980); In re Malagari, 499 F.2d 1297, 1303 (CCPA 1974). The Appellant does not address Helmick. Appeal 2021-000838 Application 14/058,804 11 The Appellant argues that “the ranges ensure that the twin wire arc bond coating is thinner than the subsequent functional layer,2 but is sufficiently thick so as to withstand the heat incurred during the application of the subsequent functional layer” (Appeal Br. 14–15). That limitation is not in the claims. See In re Self, 671 F.2d 1344, 1348 (CCPA 1982) (“[A]ppellant’s arguments fail from the outset because . . . they are not based on limitations appearing in the claims.”). Regardless, Smith would have suggested, to one of ordinary skill in the art, a wire-arc sprayed interlayer having sufficient thickness to protect underlying FRPs from subsequent combustion or plasma spraying (p. 69, col. 2). CONCLUSION For the above reasons, we are not persuaded of reversible error in the Examiner’s rejections.3 Accordingly, we affirm the rejections. 2 The twin wire arc bond coating and the subsequent functional layer (thermal spray coating) can have the same thickness (about 150 µm). 3 In the Reply Brief, the Appellant argues: Knepper and Imao do not specifically indicate that the edge portions of the disclosed articles are also coated with the adhesion promotor and thermal spray coating. Fischer is cited to correct this deficiency; however, Fischer does not relate to the use of an adhesion promotor or thermal spray coating. Fischer merely teaches an anti-oxidation coating applied to an edge of a stack of carbon fiber layers such as for coating exposed peripheral drive areas of carbon discs of a multi-disc aircraft disc brake. This coating is desirable as these discs are stacked with exposed edges that benefit from being sealed through the methods described in Fischer. The materials disclosed by Knepper and Imao are neither disclosed nor suitable for use as carbon discs of multi-disc aircraft brakes. Further, Fischer would not benefit from use of the modified Appeal 2021-000838 Application 14/058,804 12 DECISION SUMMARY In summary: Claim(s) Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed 1, 2, 6–8, 22, 31, 32 103 Knepper, Imao, Goel, Desothane® Data, Fisher, Passman, Dietz, either Saylor or Wick, Smith, AWS, Helmick, either Nazmy or Raybould 1, 2, 6–8, 22, 31, 32 3 103 Knepper, Imao, Goel, Desothane® Data, Fisher, Passman, Dietz, either Saylor or Wick, Smith, AWS, Helmick, either Nazmy or Raybould, Ayers 3 5 103 Knepper, Imao, Goel, Desothane® Data, Fisher, Passman, Dietz, 5 adhesion promotor and thermal spray material described in the Final Office Action, such that there is no motivation to combine Fischer with Knepper, Imao, and Goel as alleged in the Final Office Action. [(Reply Br. 3–4)] We do not consider this argument because it is untimely. See 37 C.F.R. § 41.41(b)(2) (2011) (“Any argument raised in the reply brief which was not raised in the appeal brief, or is not responsive to an argument raised in the examiner's answer, including any designated new ground of rejection, will not be considered by the Board for purposes of the present appeal, unless good cause is shown.”). Appeal 2021-000838 Application 14/058,804 13 Claim(s) Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed either Saylor or Wick, Smith, AWS, Helmick, either Nazmy or Raybould, Chapman 23 103 Knepper, Imao, Goel, Desothane® Data, Fisher, Passman, Dietz, either Saylor or Wick, Smith, AWS, Helmick, either Nazmy or Raybould, Mor 23 27 103 Knepper, Imao, Goel, Desothane® Data, Fisher, Passman, Dietz, either Saylor or Wick, Smith, AWS, Helmick, either Nazmy or Raybould, Darolia, Lin 27 11, 13, 25 103 Knepper, Imao, Goel, Desothane® Data, Dietz, Smith, AWS, Helmick, Nazmy, Fernihough, Passman, either Saylor or Wick 11, 13, 25 12 103 Knepper, Imao, Goel, Desothane® Data, Dietz, Smith, 12 Appeal 2021-000838 Application 14/058,804 14 Claim(s) Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed AWS, Helmick, Nazmy, Fernihough, Passman, either Saylor or Wick, Ayers 14 103 Knepper, Imao, Goel, Desothane® Data, Dietz, Smith, AWS, Helmick, Nazmy, Fernihough, Passman, either Saylor or Wick, Fisher 14 26 103 Knepper, Imao, Goel, Desothane® Data, Dietz, Smith, AWS, Helmick, Nazmy, Fernihough, Passman, either Saylor or Wick, Mor 26 28 103 Knepper, Imao, Goel, Desothane® Data, Dietz, Smith, AWS, Helmick, Nazmy, Fernihough, Passman, either Saylor or Wick, either the admitted state of the prior art or Herman 28 Appeal 2021-000838 Application 14/058,804 15 Claim(s) Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed 29, 30 103 Knepper, Imao, Goel, Desothane® Data, Dietz, Smith, AWS, Helmick, Nazmy, Fernihough, Passman, either Saylor or Wick, Sangeeta 29,30 Overall Outcome 1–3, 5–8, 11–14, 22, 23, 25–32 TIME PERIOD FOR RESPONSE No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). See 37 C.F.R. § 1.136(a)(1)(iv). AFFIRMED Copy with citationCopy as parenthetical citation