Lawrence Livermore National Security, LLCDownload PDFPatent Trials and Appeals BoardMar 12, 20212020002195 (P.T.A.B. Mar. 12, 2021) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 15/441,146 02/23/2017 Anna Hiszpanski LLNLP165/IL-13111 1079 78980 7590 03/12/2021 LLNL/Zilka-Kotab Lawrence Livermore National Laboratory L-703, P.O. Box 808 Livermore, CA 94551 EXAMINER MATZEK, MATTHEW D ART UNIT PAPER NUMBER 1786 NOTIFICATION DATE DELIVERY MODE 03/12/2021 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): llnl-docket@llnl.gov zk-uspto@zilkakotab.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte ANNA HISZPANSKI, THOMAS YONG-JIN HAN, CARLA LIM WATSON, and TIMOTHY DEXTER YEE Appeal 2020-002195 Application 15/441,146 Technology Center 1700 ____________ Before LINDA M. GAUDETTE, MICHAEL P. COLAIANNI, and JANE E. INGLESE, Administrative Patent Judges. COLAIANNI, Administrative Patent Judge. DECISION ON APPEAL Pursuant to 35 U.S.C. § 134(a), Appellant1 appeals from the Examiner’s decision to reject claims 17–20 and 27–36. We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM IN PART. 1 We use the word “Appellant” to refer to “applicant” as defined in 37 C.F.R. § 1.42. Appellant identifies the real party in interest as Lawrence Livermore National Security, LLC. Appeal Br. 2. Appeal 2020-002195 Application 15/441,146 2 Appellant’s invention is directed to metal nanowire meshes (Claim 17). The nanowire meshes may be used in transparent conductive coatings (Spec. ¶ 2). Claim 17 is representative of the subject matter on appeal: 17. A metal nanowire mesh, comprising: first metal wires oriented in approximately straight lines; and second metal wires on the first metal wires, the second metal wires being oriented in approximately straight lines oriented at an angle from greater than 0 degrees to 90 degrees from a mean direction of the lines of the first metal wires, wherein an average diameter of at least one of the first and second metal wires is in a range of about 8 to about 50 nanometers. Appellant appeals the following rejections: 1. Claims 17–19 and 27–36 are rejected under 35 U.S.C. § 103 as unpatentable over Dai et al. (US 2009/0052029 A1; Feb. 26, 2009) (hereinafter “Dai”) in view of Jiao et al. (US 2009/0142558 A1; June 4, 2009) (hereinafter “Jiao”). 2. Claim 20 is rejected under 35 U.S.C. § 103 as unpatentable over Dai in view of Jiao and Hu (Metal nanogrids, nanowires, and nanofibers for transparent electrodes, 36 MRS Bulletin 760–765 (2011)) (hereinafter “Hu”). 3. Claim 36 is rejected under 35 U.S.C. § 112(a) as failing to comply with the written description requirement. Appellant argues the following nine groups of claims with regard to the §103 rejections: (1) Claim 17; (2) Claim 18; (3) Claim 19; (4) Claims 28 and 29; (5) Claim 30; (6) Claim 31; (7) Claim 35; (8) Claims 27, 32, 33, 34, and 36; and (9) Claim 20 (Appeal Br. 5–25). Because there is overlap in the argument between the claim groupings, we will address the following claims Appeal 2020-002195 Application 15/441,146 3 as a group: (A) claims 17, 18, 28, 29, 27, 32, 33, 34, and 36; (B) claims 19 and 31; (C) claim 30; and (D) claims 20 and 35. We separately address claim 36 in the context of the § 112(a) rejection. FINDINGS OF FACT & ANALYSIS (A) Claims 17, 18, 28, 29, 27, 32, 33, 34, and 36 The Examiner’s findings and conclusions regarding the rejection of claims 17, 18, 28, 29, 27, 32, 33, 34, and 36 over Dai and Jiao are located on pages 3–4 of the Final Action and pages 4–6 of the Answer. The Examiner finds that Dai teaches the subject matter of independent claim 17, except for the average diameter of the metal nanowires is between about 8 to about 50 nanometers (Final Act. 3–4). The Examiner finds that Dai teaches that nanowires within the context of the publication include wires with diameters of less than 50 nm (Ans. 4; Dai ¶ 36). The Examiner finds Jiao teaches a nanowire network composed of nanowires having an average diameter from 30–50 nm (Final Act. 4). The Examiner concludes that it would have been obvious to use nanowires with an average diameter of 30–50 nm in Dai’s nanowire mesh in order to provide uniform diameter nanowires of a size less than 50 nm as taught by Dai (Final Act. 4). Appellant argues Dai teaches a nanowire diameter range from 100 to 150 nm, which is outside the range recited in the claim (Appeal Br. 7). Appellant contends that using Jiao’s smaller nanowire diameters of 30 to 50 nm in Dai’s nanowire mesh polarizer would not permit the polarizer to function as intended (Appeal Br. 5–6). Appellant contends that because the modification of Dai by Jiao would frustrate Dai’s purpose as a polarizer, there is no reason to combine the teachings of the references (Appeal Br. 7– 8). Appellant contends that Dai discloses 100 to 150 nm as the range for the Appeal 2020-002195 Application 15/441,146 4 nanowire diameters because that is the only range that works (Appeal Br. 7). Appellant argues that there is no reasonable expectation of success in combining Jiao’s average nanowire diameters with Dai’s nanowire mesh (Appeal Br. 8). Appellant argues there is no reasonable expectation of success in using Jiao’s smaller diameter nanowires for Dai’s nanowires having a diameter from 100 to 150 nm (Appeal Br. 9). Appellant argues Jiao’s process of growing the nanowire network is not compatible with Dai’s process that uses a nanowire suspension (Appeal Br. 9). Appellant contends that subjecting Jiao’s nanowire network to Dai’s shear force orientation process would likely distort the network and increase the density of nanowires in Dai (Appeal Br. 9). Appellant’s arguments are undermined by Dai’s teaching that nanowires in the context of Dai’s disclosure include diameters of less than 50 nm (Dai ¶ 36). Appellant incorrectly argues that Dai’s disclosure is limited solely to nanowire diameters from 100 to 150 nm because that is the only nanowire diameter range that will work (Appeal Br. 7). To the contrary, Dai exemplifies using a silver nanowire with a width (diameter) from 70 to 80 nm (Dai ¶ 127). Dai further discloses that “[t]ypically, better optical properties (higher transmission and lower haze) can be achieved with higher aspect ratio wires (i.e., longer lengths and thinner widths)” (¶ 127). Dai discloses that thinner nanowires (i.e., smaller diameters) provide better optical properties. Id. Dai is not limited solely to 100 to 150 nm nanowires as argued by Appellant. With this understanding in mind, Appellant’s arguments about lack of reasonable expectation of success, no reason to combine, and frustration of Dai’s purpose are not persuasive. Regarding claim 18, Appellant relies on similar unpersuasive arguments made regarding claim 17 (Appeal Br. 10). Appellant additionally Appeal 2020-002195 Application 15/441,146 5 argues the Examiner fails to provide an explicit analysis of the claim 18 subject matter that explains why a skilled artisan would have modified Dai to use 30 to 100 nanometer spacing between the nanowires (Appeal Br. 11). Appellant argues that Dai teaches a fill factor (FF) relationship (FF=d/d1) that is based on the spacing between nanowires (d) and the nanowire diameter (d1) (Appeal Br. 11). Appellant contends that if the fill factor is defined as being less than 1.0 (i.e., 0.1 to 0.6 as in Dai), then d will always be less than d1 (Appeal Br. 11). Contrary to Appellant’s arguments, the Examiner finds that the combined teachings of Jiao and Dai would have resulted in a fill factor of 0.6 (Ans. 5). Specifically, the Examiner finds that when the 50 nm wire diameter is substituted into the equation for a form factor of 0.6, the resulting nanowire spacing is 30 nm (Ans. 5). As we noted above, the Examiner correctly finds that Dai teaches the nanowires include diameters of less than 50 nm. Appellant does not dispute the Examiner’s calculation (Reply Br. 9). Rather, Appellant responds with the same unpersuasive arguments made in the Appeal Brief (Reply Br. 9). Regarding claims 28 and 29, Appellant relies on similar unpersuasive arguments made regarding claim 17 (Appeal Br. 13–16). Claim 28 depends from claim 17 and recites that the average diameter is in the range of about 8 to about 43 nm. Claim 29 depends from claim 17 and recites that the average nanowire diameter in the range of about 8 to about 40 nm. Appellant argues Dai’s polarizer would not function by using Jiao’s smaller diameter nanowires (Appeal Br. 13). Appellant’s argument is premised on Dai’s nanowire diameter being limited to 100 and 150 nm (Appeal Br. 14). This argument is not persuasive for the reasons given above in our discussion of claim 17. As noted above with our discussion of claim 17, Appeal 2020-002195 Application 15/441,146 6 Jiao describes average diameter ranges that overlap with ranges recited in claims 28 and 29. Moreover, Dai teaches that nanowire diameters may be less than 50 nm (Dai ¶ 36). The Examiner finds that the nanowire diameters would have been optimized based on the teachings of Dai and Jiao to diameters within the range of 30 to 40 nm (Ans. 6). Appellant does not respond specifically to this the determination by the Examiner (Reply Br. 10). We find Appellant’s arguments do not show reversible error in the Examiner’s rejection of claims 28 and 29. Regarding claims 27, 32, 33, 34, and 36, Appellant relies on arguments made regarding claim 17 (Appeal Br. 21). We find those arguments unpersuasive as discussed above with respect to claim 17. We affirm the Examiner’s § 103 rejection of claims 17, 18, 28, 29, 27, 32, 33, 34, and 36 over Dai and Jiao. Claim 30 Claim 30 depends from claim 17 and recites that “the metal nanowire mesh is a mask for making a pattern on a substrate.” The Examiner finds that Dai’s nanowire mesh as modified by Jiao would have been capable of use as a mask for making a pattern on a substrate (Final Act. 4). The Examiner explains that Dai forms a network mesh of fibers that cover an underlying substrate in the same way a pattern masks an underlying substrate (Final Act. 4). Appellant argues Dai and Jiao do not teach using the nanowire mesh as a mask (Appeal Br. 15). Appellant argues that Dai teaches forming a conductive network on an optically clear substrate, so the modification proposed by the Examiner would involve removing the nanowire mesh from the substrate (Appeal Br. 18). Appellant contends the removal of the mesh Appeal 2020-002195 Application 15/441,146 7 from the substrate would frustrate Dai’s purpose (Appeal Br. 18). Appellant argues a person skilled in the art would not modify Dai’s wire-grid to be used as a mask, since without the nanowires, the film does not have any polarizing ability (Appeal Br. 18). Appellant has not shown any structural difference between the claimed nanowire mesh and the nanowire mesh of Dai as modified by Jiao. Even adhering the nanowire mesh to a substrate in Dai would not prevent the nanowire mesh from being used as a mask. Dai’s Figure 2 shows light 60 propagating through the substrate 44, where a portion of the light is blocked by the polarizer (Dai ¶¶ 44, 45). In other words, we find the Examiner is correct that Dai’s nanowire mesh as modified by Jiao would have been capable of use as a mask. See, In re Schreiber, 128 F.3d 1473, 1477 (Fed. Cir. 1997) (anticipation rejection affirmed based on the Board’s factual finding that the reference dispenser (a spout disclosed as useful for purposes such as dispensing oil from an oil can) would be capable of dispensing popcorn in the manner set forth in appellant’s claim 1 (a dispensing top for dispensing popcorn in a specified manner)). We affirm the § 103 rejection of claim 30 over Dai and Jiao. Claims 20 and 35 Claim 20 is rejected under § 103 over Dai, Jiao, and Hu. Claim 20 depends from claim 17 and recites “wherein the first metal wires have at least one difference from the second metal wires, the difference being selected from a group consisting of: composition, average diameter, and average spacing between adjacent wires.” The Examiner finds that Hu teaches silver and copper nanowire grids having a different distance between vertical and horizontal nanowires in the grid as shown in Hu’s Figure 1a Appeal 2020-002195 Application 15/441,146 8 (Final Act. 4–5). The Examiner concludes that it would have been obvious to align the nanowires of Dai so that the distance separating parallel nanowires in one set of nanowires differs for the nanowire spacing in the other set as a matter of design choice as shown in Hu (Final Act. 5). Claim 35 is rejected under § 103 over Dai and Jiao. Claim 35 depends from claim 34 and recites “wherein an average spacing between the first metal wires is different than an average spacing between the second metal wires.” The Examiner finds that Dai teaches in paragraph 51 that uniformity in nanowire spacing is preferred, but not required (Ans. 7). The Examiner finds that Dai teaches that nanowire spacing may vary between first and second sets of nanowires (Ans. 7). Appellant argues that Dai fails to teach a difference in spacing between the first wires and the spacing between the second wires as recited in claim 35 (Appeal Br. 19-20). Contrary to Appellant’s argument, Dai teaches that uniformity in spacing between the nanowires is preferred but it is not necessary to form the structure (¶ 51). Stated differently, Dai teaches a non-preferred embodiment where there are differences in spacing between nanowires. In re Preda, 401 F.2d 825, 826 (CCPA 1968) (explaining that a prior art reference’s disclosure must be considered for all that it teaches, including “the inferences which one skilled in the art would reasonably be expected to draw therefrom”). The Examiner cited Hu in the rejection of claim 20 for Hu’s disclosure in Figure 1a that the spacing between the first and second set of nanowires may be different (Final Act. 4–5). Appellant argues the Examiner improperly relies on design choice as a reason for modifying the spacing between nanowires in Dai’s mesh (Appeal Br. 23). Appellant argues that the Board in Ex parte Gunasekar, Appeal No. 2009-008345, held that to rely on Appeal 2020-002195 Application 15/441,146 9 design choice an Examiner must present a convincing line of reasoning as to why one of ordinary skill in the art would have found the claimed feature obvious (Appeal Br. 23). While we generally agree that a well-reasoned basis for the conclusion that the proposed modification is an obvious design choice is necessary, we note that we are not bound by the holding in the non- precedential Gunsekar decision. Nevertheless, we find that the Examiner has provided a line of reasoning as to why Hu would have suggested modifying Dai’s nanowire mesh to have different spacing between the first and second set of nanowires (Ans. 8). The Examiner finds that Hu teaches two factors that must be considered when making nanowire grids: (1) the diameter or thickness of the nanowire must be a subwavelength to provide sufficient transparency and (2) the period of the mesh (distance between adjacent nanowires) is submicron to ensure uniform current across the active electrode layer (Ans. 8). We understand the Examiner to find that a person of ordinary skill would have considered these parameters in determining the spacing between nanowires in each set. The Examiner further finds that Hu’s Figure 1a shows a different nanowire spacing between the first and second set of fibers (Ans. 8). Appellant does not respond to these findings or this reasoning (Reply Br. 10–11). On this record, we affirm the Examiner’s § 103 rejection of claim 20 over Dai, Jiao, and Hu and the § 103 rejection of claim 35 over Dai and Jiao. Appeal 2020-002195 Application 15/441,146 10 Claims 19 and 31 Claim 19 depends from claim 17 and recites “wherein an average spacing between the first metal wires varies by less than 20% along lengths thereof.” The Examiner finds that Dai teaches that the nanowires are typically straight (preferably deviate less than 5 degrees) and the spacing between adjacent nanowires is preferably uniform (Ans. 5). The Examiner concludes that “it would have been obvious to have the average spacing between a first set of nanowires vary by less than 20% because Dai teaches a preference in minimizing spacing variation (i.e., run in parallel) through the use of straight nanowires that have a uniform distance between them” (Ans. 6). Appellant argues that neither Dai nor Jiao teaches a variation of less than 20% along lengths thereof (Appeal Br. 12; Reply Br. 6). We agree. The Examiner has not established that Dai or Jiao teaches or would have suggested a less than 20% variation in the spacing between nanowires. The Examiner appears to rely on the parallel arrangement to teach the variation recited in claim 19. However, just because two lines are ideally parallel does not suggest a less than 20% variation along the length of the fiber. The Examiner has not explained how Dai’s teaching to keep the wire spacing below 10 or 5 degrees of deviation equates to a less than 20% variation in the spacing. Claim 31 depends from claim 17 and recites “wherein the first metal wires extend along an entire length of the metal nanowire mesh.” The Examiner finds that because Dai teaches that the mesh is electrically conductive, that means that nanowires must extend along the entire length of the metal nanowire mesh in order to provide electrical conductivity (Ans. 7). Appeal 2020-002195 Application 15/441,146 11 Appellant persuasively argues that interconnected mesh may be electrically conductivity via the joints in the nanofiber mesh (Appeal Br. 19). We agree in that the electrical conductivity alone is an insufficient basis to conclude that each wire in the mesh extends along the entire length metal mesh. Rather, the interconnected mesh may provide the connections required to support electrical conductivity. On this record, we reverse the Examiner’s § 103 of claims 19 and 31 over Dai and Jiao. Claim 36 35 U.S.C. § 112(a), Written Description The Examiner finds that the Specification fails to provide adequate support for coupling of the metal wires at their intersection (Final Act. 3). The Examiner finds the verb “couple” is defined as connecting or joining (Ans. 8). The Examiner finds that first and second metal wires in Appellant’s Figures 4A and 4B show two sets of wires that cross each other, but there is no support for two sets of wires being located in the same plane, which would be required in order to connect the wire sets shown in the Figures (Ans. 8). Appellant argues that Figures 4A and 4B show interconnected first and second sets of wires (Appeal Br. 27). Appellant contends the nanowire mesh in Figures 4A and 4B are formed by sintering the metal nanowires (Reply Br. 4). Appellant argues that sintering is defined as “to cause to become a coherent mass by heating without melting” (Reply Br. 4). Appellant argues that sintering would have resulted in a forming a nanowires coupled together as the intersections (Reply Br. 4–5). To satisfy the written description requirement, an applicant must convey with reasonable clarity to those skilled in the art that, as of the filing Appeal 2020-002195 Application 15/441,146 12 date sought, he or she was in possession of the invention, and that the invention, in that context, is whatever is now claimed. Vas-Cath, Inc. v. Mahurkar, 935 F.2d 1555, 1563-64 (Fed. Cir. 1991). In the present appeal, the Specification describes Figures 4A and 4B as being formed by sintering the metal lines to form the nanowire mesh (Spec. ¶¶ 57, 70). We find that sintering of the formed metal lines would have resulted in the bonding of the two sets of metal lines at their intersection points. Appellant has shown possession of claim 36’s subject matter. We reverse the Examiner’s § 112(a) written description rejection. DECISION SUMMARY In summary: Claim(s) Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed 17–19, 27–36 103 Dai, Jiao 17, 18, 27-30, 32–36 19, 31 20 103 Dai, Jiao, Hu 20 36 112(a) Written Description 36 Overall Outcome 17, 18, 20, 27– 30, 32– 36 19, 31 No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1)(iv). AFFIRMED IN PART Copy with citationCopy as parenthetical citation