Lam Research CorporationDownload PDFPatent Trials and Appeals BoardMar 26, 20212020002898 (P.T.A.B. Mar. 26, 2021) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/576,978 12/19/2014 Tom A. Kamp LAM1P492/3541-1US 5865 105653 7590 03/26/2021 Beyer Law Group LLP/Lam P. O. Box 51887 Palo Alto, CA 94303-1887 EXAMINER PHAM, THOMAS T ART UNIT PAPER NUMBER 1713 NOTIFICATION DATE DELIVERY MODE 03/26/2021 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): USPTOmail@beyerlaw.com eofficeaction@appcoll.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte TOM A. KAMP, ALEXANDER M. PATERSON, and NEEMA RASTGAR Appeal 2020-002898 Application 14/576,978 Technology Center 1700 Before JEFFREY T. SMITH, MICHAEL P. COLAIANNI, and SHELDON M. MCGEE, Administrative Patent Judges. MCGEE, Administrative Patent Judge. DECISION ON APPEAL Pursuant to 35 U.S.C. § 134(a), Appellant1 appeals from the Examiner’s decision to reject claims 1–17. We have jurisdiction. 35 U.S.C. § 6(b). We affirm. 1 We use the word “Appellant” to refer to “applicant” as defined in 37 C.F.R. § 1.42. Appellant identifies the real party in interest as Lam Research Corporation. Appeal Br. 3. Appeal 2020-002898 Application 14/576,978 2 CLAIMED SUBJECT MATTER The claims are directed to in-situ methods of etching and cleaning silicon-containing layers within the same plasma processing chamber. In the claimed methods, the etch gas and dry clean gas are converted into etch plasma and dry clean gas plasma, respectively, in the plasma processing chamber where the silicon-containing layer is housed. According to Appellant, such methods are known in the art as a “direct plasma process,” as opposed to a “remote plasma process.” Appeal Br. 5. Claim 1, reproduced below, is illustrative of the claimed subject matter: 1. An in-situ method for etching features into and cleaning a silicon containing etch layer in a plasma processing chamber having an external TCP coil and a wafer support, comprising placing the silicon containing etch layer into the plasma processing chamber; flowing an etch gas into the plasma processing chamber; providing TCP power from the TCP coil to the plasma processing chamber to form the etch gas into an etch plasma in the plasma processing chamber, the etch plasma located between the external TCP coil and the wafer support, wherein the silicon containing etch layer is exposed to the etch plasma, and wherein the etch plasma etches features into the silicon containing etch layer leaving silicon containing residue; stopping the flow of etch gas into the plasma processing chamber; flowing a dry clean gas into the plasma processing chamber, wherein the dry clean gas comprises NH3 and NF3; providing TCP power from the TCP coil to the plasma processing chamber to form the dry clean gas into a dry clean gas plasma in the plasma processing chamber between the external TCP coil and the wafer support, wherein the silicon containing residue is exposed to the dry clean gas plasma, and wherein the dry clean gas plasma converts at least some of the silicon containing residue into ammonium containing compounds; Appeal 2020-002898 Application 14/576,978 3 stopping the flow of the dry clean gas; and removing the silicon containing etch layer from the plasma processing chamber. REJECTIONS The Examiner rejects the following claims under 35 U.S.C. § 103: I. Claims 1–12 and 14–17 over Nemani,2 Kamp,3 and Sato4 as evidenced by Tang5; II. Claim 13 over Nemani, Kamp, Sato, and Chen6 as evidenced by Tang; and III. Claims 1–17 over Chang,7 Woo,8 and Sato as evidenced by Tang. OPINION We review the appealed rejection for reversible error based on the arguments and evidence presented by Appellant. 37 C.F.R. § 41.37(c)(1)(iv); Ex parte Frye, 94 USPQ2d 1072, 1075 (BPAI 2010) (precedential) cited with approval in In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011) (explaining that even if the Examiner had failed to make a prima facie case, “it has long been the Board’s practice to require an applicant to identify the alleged error in the examiner’s rejections”). Having reviewed 2 US 2014/0120726 A1, published May 1, 2014. 3 US 2004/0084406 A1, published May 6, 2004. 4 US 8,633,119 B2, issued Jan. 21, 2014. 5 US 2011/0151674 A1, issued June 23, 2011. 6 US 7,816,227 B2, issued Oct. 19, 2010. 7 US 9,023,723 B2, issued May 5, 2015. 8 US 2015/0000844 A1, issued Jan. 1, 2015. Appeal 2020-002898 Application 14/576,978 4 the appeal record, we affirm the obviousness rejections for the reasons provided by the Examiner and below. Final Act. 4–13; Ans. 8–11. Rejection I The Examiner rejects claims 1–12 and 14–17 over the combined disclosures of Nemani, Kamp, and Sato, as evidenced by Tang. Final Act. 4–8. Specifically, the Examiner finds that Nemani teaches an in-situ method for etching and cleaning a porous silicon dioxide layer by performing two plasma processes. Id. at 5. The Examiner finds that each of these processes may be performed in a plasma etch chamber. Id. The Examiner finds that Nemani is silent, however, regarding the precise method of igniting the plasma. Id. at 6. To address this difference between the prior art and the claims, the Examiner turns to Kamp, which the Examiner finds teaches that the plasma may be ignited by a TCP coil. Id. The Examiner additionally finds that Sato teaches using a combination of ammonia and nitrogen trifluoride plasma and that such “plasma may be formed within the chamber supporting the substrate.” Id. Based on the combined disclosures of Nemani, Kamp, and Sato, the Examiner determines that it would have been obvious to use a TCP coil as the plasma ignition device in Nemani’s method. Id. Appellant addresses the rejected claims as a group. Appeal Br. 10–13. We, therefore, select claim 1 as representative and decide the appeal of this rejection on the basis of claim 1 alone. 37 C.F.R. § 41.37(c)(1)(iv). Appellant argues that “Kamp does not disclose or suggest cleaning the wafer using dry clean plasma” or “etching features into and cleaning a wafer post-etch by applying TCP power.” Appeal Br. 10. We are not persuaded by this argument because it focuses on the disclosure of Kamp alone without Appeal 2020-002898 Application 14/576,978 5 considering the teachings of Nemani. Here, the Examiner relies on Nemani to evince every recited limitation except for the use of TCP power–– including etching and cleaning a wafer post-etch. Final Act. 4–6. Thus, it is insufficient for Appellant to point out that Kamp does not disclose process steps for which it was not relied upon. In re Merck & Co., 800 F.2d 1091, 1097 (Fed. Cir. 1986) (“Non-obviousness cannot be established by attacking references individually where the rejection is based upon the teachings of a combination of references. . . . [The reference] must be read, not in isolation, but for what it fairly teaches in combination with the prior art as a whole.”). Appellant next argues that Nemani discloses two types of plasma processes: a “direct” (e.g., “non-remote”) plasma process that deposits a protective layer, and a “remote” plasma process which cleans the surface by removing the protective layer and modified low-k material. Appeal Br. 11; see also id. at 11–13 (arguing how Nemani’s second process is a “remote” process). Appellant asserts that the skilled artisan would have understood that TCP power is not used in a remote plasma generation process. Id. at 10. Thus, according to Appellant, the skilled artisan would not have been motivated to apply TCP power to Nemani’s process. Id. at 13. We are not persuaded by this argument because it attempts to improperly narrow the breadth of Nemani’s disclosure. First, Appellant acknowledges that Nemani’s two stage process occurs in the same processing chamber. Appeal Br. 11. Such in-situ processing appears to meet Appellant’s description of the claimed “direct” process. See id. at 10 (where Appellant asserts that a direct plasma process is “where etch gas and dry clean gas are both flowed into the plasma processing chamber”). Appeal 2020-002898 Application 14/576,978 6 Appellant also provides a Declaration from inventor Tom A. Kamp9 supporting this description. See Kamp Decl. ¶ 6 (testifying that “[a] direct plasma process is a plasma process in which the interaction between the plasma and the semiconductor substrate takes place where the gas is formed into a plasma” and that “in a direct plasma processing apparatus . . . a gas (e.g., etch gas or dry clean gas) is converted into a plasma in the same space in which the plasma interacts with the semiconductor substrate.” (emphases added)). Furthermore, while Nemani discusses certain embodiments which use remote plasma processing post-etch (see, e.g., Nemani ¶¶ 24, 56, 62), the full scope of Nemani’s disclosure is not limited to those embodiments. For example, Nemani generally discloses flowchart 200 having two plasma operations 204, 206 after mask layer formation. Nemani, Fig. 2, ¶¶ 34, 39. Although Appellant asserts that Nemani’s second stage, i.e., operation 206, is a remote plasma process, Nemani does not describe operation 206 as one that can only be carried out remotely. Id. ¶ 39. In fact, Nemani suggests that operation 206 can be carried out by a “direct” plasma process. See id. ¶ 58 (disclosing an embodiment where “one or more of the above processes is performed in a plasma etch chamber” and where one of those “above processes” is operation 206 depicted in Figure 2 (emphasis added)); see also Final Act. 5 (finding that “all processes” in Nemani, including the removal process, “may be performed in a plasma etch chamber” (citing Nemani ¶ 58)). “It is well settled that a prior art reference is relevant for all that it teaches to those of ordinary skill in the art.” In re Fritch, 972 F.2d 1260, 9 Declaration executed by Tom A. Kamp dated November 17, 2017 (“Kamp Decl.”). Appeal 2020-002898 Application 14/576,978 7 1264 (Fed. Cir. 1992). Therefore, we are not persuaded that the skilled artisan would have viewed Nemani’s disclosure as narrowly as Appellant urges. Rejection I is sustained. Rejection II Claim 13 is similar to claim 1, but is directed to a method of etching and cleaning “a silicon wafer, a source layer, a drain layer, or a polysilicon layer” instead of “a silicon containing etch layer” as recited in in claim 1. Appeal Br. 21 (Claims App.). Given these similarities, the Examiner relies on Nemani, Kamp, and Sato as set forth in Rejection I for most of the limitations recited in claim 13, but turns to Chen to undisputedly evince the claimed details of the silicon substrate, and to determine the claimed method would have been obvious. Final Act. 8–9; Appeal Br. 13–14. Appellant presents arguments about a specific embodiment depicted in Nemani’s Figure 5B––an embodiment not expressly relied upon by the Examiner (Final Act. 4–10). In the context of Nemani’s Figure 5B embodiment, Appellant repeats its deficient arguments regarding a remote plasma process vis-à-vis the claimed direct plasma process. Appeal Br. 13– 14. We are unpersuaded by this line of argument because it does not adequately address the rejection as set forth by the Examiner, and again seeks to narrow the breadth of Nemani’s disclosure as discussed with respect to Rejection I. Appeal Br. 13–14. Rejection II is sustained. Appeal 2020-002898 Application 14/576,978 8 Rejection III The Examiner additionally rejects claims 1–17 using different references than those relied on in Rejections I and II. Final Act. 10–13. Specifically, with respect to claim 1, the Examiner finds that Chang teaches a method of etching and cleaning a silicon oxide layer, but is silent regarding the specific details of the etching and cleaning steps. Id. at 10. The Examiner additionally finds that Woo teaches the use of a TCP plasma generator to carry out plasma etching and plasma cleaning, and that Sato teaches forming a NH3/NF3 plasma in the same chamber as the substrate to clean the layer. Id. at 10–11. Based on these combined teachings, the Examiner determines it would have been obvious to employ a TCP plasma generator in the same plasma apparatus using Chang’s method to simplify manufacturing. Id. Appellant addresses this rejection as a group. Appeal Br. 15–17. We, therefore, select claim 1 as representative and decide the appeal of this rejection on the basis of claim 1 alone. 37 C.F.R. § 41.37(c)(1)(iv). Appellant argues that Woo teaches away from using the same plasma supply apparatus for etching and cleaning. Appeal Br. 15–16. This argument is not persuasive because it mischaracterizes the teachings of Woo. Woo ¶¶ 6, 8. Woo discloses that separating the etching and cleaning processes into different apparatuses suffers from “degraded” efficiency, and “provide[s] a multiple-mode plasma generation apparatus that is capable of supplying plasma in multiple processes to improve processing efficiency.” Id. Thus, Woo teaches the opposite of what Appellant’s argument suggests. Appellant also argues that Tang discloses “remote” plasma processing. Appeal Br. 16. This argument is unpersuasive because it Appeal 2020-002898 Application 14/576,978 9 addresses the disclosure of Tang in a vacuum and does not address the collective teachings of the relied-upon prior art. In re Merck & Co., 800 F.2d at 1097. Appellant also makes several arguments regarding Nemani and Kamp, but we do not consider such arguments because these references were not relied on in this rejection. Rejection III is sustained. CONCLUSION The Examiner’s rejections are affirmed. DECISION SUMMARY Claim(s) Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed 1–12, 14– 17 103 Nemani, Kamp, Sato, Tang 1–12, 14–17 13 103 Nemani, Kamp, Sato, Chen, Tang 13 1–17 103 Chang, Woo, Sato, Tang 1–17 Overall Outcome: 1–17 TIME PERIOD FOR RESPONSE No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). See 37 C.F.R. § 1.136(a)(1)(iv). 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