Kurt E. HeikkilaDownload PDFPatent Trials and Appeals BoardAug 29, 201912278638 - (D) (P.T.A.B. Aug. 29, 2019) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 12/278,638 11/07/2008 Kurt E. Heikkila 0592.000001US20 3432 26813 7590 08/29/2019 MUETING, RAASCH & GEBHARDT, P.A. P.O. BOX 581336 MINNEAPOLIS, MN 55458-1336 EXAMINER NERANGIS, VICKEY M ART UNIT PAPER NUMBER 1768 NOTIFICATION DATE DELIVERY MODE 08/29/2019 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): ptodocketing@mrgs.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________________ Ex parte KURT E. HEIKKILA ____________________ Appeal 2017-009996 Application 12/278,638 Technology Center 1700 ____________________ Before JAMES C. HOUSEL, CHRISTOPHER L. OGDEN, and DEBRA L. DENNETT, Administrative Patent Judges. OGDEN, Administrative Patent Judge. DECISION ON APPEAL1 Appellant2 appeals under 35 U.S.C. § 134(a) from the Examiner’s decision rejecting claims 56, 57, 59, 61, 63–66, 68–73, 78–83, and 88–90 in the above-identified application.3 Counsel for Appellant appeared for a hearing on June 3, 2019.4 We affirm. 1 e appeal record includes the following: Specification, Aug. 7, 2008 (“Spec.”); Non-final Office Action, Nov. 8, 2016 (“Action”); Appeal Brief, Mar. 9, 2017 (“Appeal Br.”); Examiner’s Answer, May 17, 2017 (“Answer”); and Reply Brief, July 17, 2017 (“Reply Br.”). 2 According to the Appeal Brief, the real party in interest is Tundra Composites, LLC. Appeal Br. 3. 3 See Action 1 (omitting claim 59); id. at 2, 5, 9 (listing claim 59 as among the rejected claims). 4 See Hearing Transcript, entered July 10, 2019 (“Tr.”). Appeal 2017-009996 Application 12/278,638 2 BACKGROUND Appellant’s invention relates to “methods of manufacturing a metal polymer composite.” Appeal Br. 3. According to the Specification, this composite material, “through a selection of metal particle size distribution, polymer and processing conditions, attains improved density or other properties through minimization of the polymer filled excluded volume of the composite.” Spec. 3:26–28. Appellant distinguishes the invention from prior art composite materials because the latter “use metal particles that are either uncoated or coated with a reactive coupling agent.” Appeal Br. 4 (citations omitted). According to Appellant, “[w]ithout pre-treatment with interfacial modifier, the metal particles of composites formed by conventional methods lack desirable viscoelastic and thermoplastic properties due to, e.g., detrimental particle to particle friction and/or particle to polymer bonding.” Id. Appellant argues that coating the particles with an interfacial modifier “provides the metal particulate with ‘greater freedom of movement’ within the polymer phase after processing,” and this freedom “results from the interfacial modifier not being reactively bonded to the polymer phase and from the prevention of particle–particle interactions.” Id. at 4–5 Independent claim 68, which we reproduce below, is representative: 68. A method of manufacturing a metal polymer composite, said method comprising: (a) combining a polymer with about 96 to 40 volume % of a pre-treated metal particulate comprising a coating comprising an effective composite forming amount of an interfacial modifier wherein the metal particulate comprises particles having a particle size of at least about 10 microns; wherein the polymer is present in an amount sufficient to Appeal 2017-009996 Application 12/278,638 3 substantially occupy excluded volume of the metal particulate in a metal polymer composite; (b) mixing the pre-treated interfacial modifier coated metal particulate and the polymer to form a mixture; and (c) compounding the mixture to form a metal polymer composite comprising pre-treated metal particulate within a polymer phase; wherein the metal particulate exhibit a circularity greater than 13 and an aspect ratio less than 1:3; and wherein the interfacial modifier coating allows for a greater freedom of movement of the pre-treated metal particulate within the polymer phase of the metal composite after compounding compared to the same composite without the exterior coating on the metal particulate, when measured under the same conditions. Appeal Br. Claims App’x 2–3 (emphases added). Claims 56, 73, and 80 are also independent, and have similar limitations, one difference being that in claim 68, the “greater freedom of movement” property exists “after compounding,” whereas in the other independent claims, this property exists after melt processing (claim 56), “or in a shaped article (independent claim 73) or a composite article (independent claim 80).” Appeal Br. 21. Claims 57, 61, and 63–66 depend directly or indirectly from claim 56; claims 69–72 and 89 depend directly or indirectly from claim 68; claims 78 and 79 depend from claim 73; and claims 81–83, 88, and 90 depend directly or indirectly from claim 80. Appeal Br. Claims App’x 1–5. Appeal 2017-009996 Application 12/278,638 4 e Examiner’s grounds of rejection are as follows: Rejection 1: claims 56, 57, 59, 61, 63–65, 68–73, 78, 80–83, and 88 under 35 U.S.C. § 103(a) as being unpatentable over Ando5 in view of Economy6 and Ohkawa.7 Answer 2–5. Rejection 2: claims 56, 57, 59, 61, 63–65, 68–73, 78, 80–83, and 88 under 35 U.S.C. § 103(a) as being unpatentable over Ando in view of Suezaki,8 Economy, and Ohkawa. Id. at 5–9. Rejection 3: claims 56, 57, 59, 63, 66, 73, 78, and 79 under 35 U.S.C. § 103(a) as being unpatentable over Sakaki9 in view of Economy and Ohkawa. Id. at 9–13. Rejection 4: claims 68–72 and 89 under 35 U.S.C. § 103(a) as being unpatentable over Sakaki in view of Economy, Ohkawa, and Ando. Id. at 13–14. Rejection 5: claims 80–83, 88, and 90 under 35 U.S.C. § 103(a) as being unpatentable over Sakaki in view of Economy, Ohkawa, and Bray.10 Id. at 14–17. 5 Ando, JP 2001-183099 A (published July 6, 2001) (“Ando”). ere are three translations of record: two provided by Appellant (Appeal Br. Ex. A (“Ando A”) and Ex. B (“Ando B”), and one provided by the Examiner (“Ando C”). See Appeal Br. Evidence App’x; Action 2. 6 Economy et al., US 4,614,629 (issued Sept. 30, 1986) (“Economy”). 7 Ohkawa et al., US 4,891,399 (issued Jan. 2, 1990) (“Ohkawa”). 8 Suezaki et al., US 5,834,549 (issued Nov. 10, 1998) (“Suezaki”). 9 Sakaki et al., US 6,364,422 B1 (issued Apr. 2, 2002) (“Sakaki”). 10 Bray et al., US 6,048,379 (issued Apr. 11, 2000) (“Bray”). Appeal 2017-009996 Application 12/278,638 5 DISCUSSION A. Rejection 1 (Ando, Economy, and Ohkawa) e Examiner finds that Ando discloses mixing and compounding a composite material from the components recited in the independent claims, to form a bullet. Action 2–3. Regarding claim 68, the Examiner finds, “Ando shows that the metal particles have a spherical shape which reads on circularity of greater than 13 and aspect ratio of less than 1:3.” Id. at 5. Regarding claims 56 and 73, which recite specific parameters for melt processing or extruding the composite material (see Appeal Br. Claims App’x 1, 4), the Examiner cites Economy as evidence “that conventional process[ing] techniques such as extrusion” operate at a shear rate within the recited range, and that temperature is a result-effective variable. Action 3 (citing Economy 2:49–63); see also Answer 28–29. Also, according to the Examiner, “Ando fails to disclose . . . that the interfacial modifier allows for [the] claimed greater freedom of movement between particles.” Id. at 3. However, the Examiner finds that Ohkawa teaches a “metallic filler having a surface coated with a water repellent agent (i.e., interfacial modifier) such as silane and titanate coupling agents.” Id. at 4 (citing Ohkawa, Abstract). According to the Examiner, Ohkawa teaches that these coupling agents provide “good moldability, good molded appearance, high mechanical properties, dimensional stability, and resistance against rusting.” Id. (citing Ohkawa 1:40–2:60). Ohkawa teaches that [w]hen the amount of the water repellent agent is too small, no sufficient coupling effect can be exhibited between the surface of the filler and the matrix phase so that the resultant molding composition would be poor in the moldability. When the Appeal 2017-009996 Application 12/278,638 6 amount thereof is too large, on the other hand, a phenomenon of slipping may be caused due to the excessively strong effect of lubrication between the filler surface and the matrix phase leading to disadvantages . . . . Ohkawa 8:10–18. According to the Examiner, this passage “strongly suggests that the water repellent agent is not reacted with [the polymer] matrix because there is lubrication between the filler surface and matrix phase (i.e., not ‘excessive lubrication’) when used in lower amounts like claimed and therefore [the composition] provides the claimed ‘greater freedom of movement.’” Action 4 (citing Ohkawa 8:14–26). us, the Examiner determines that “it would have been obvious to one of ordinary skill in the art to utilize a coupling agent that improved moldability, i.e., improved freedom of movement between particles.” Id. at 5. Appellant argues the following: (1) the Examiner did not articulate a motivation to combine references to achieve the recited “greater freedom of movement,” (2) Ando fails to teach pre-treating the metal particles, (3) Ando fails to teach the recited circularity of claim 68, and (4) Economy is a non- analogous reference.11 Appeal Br. 16–30. Appellant argues the claims as a 11 At the hearing, counsel for Appellant also argued that Ando “fails as a primary reference because it wants a blend of large and small particles.” Tr. 4:20–22 (citing Ando, claim 3, ¶¶ 43, 44, 78). Similarly, counsel argued that Sakaki teaches a broad 2–100 μm particle range and expresses a preference for a “blend of 5 and 27 micron particles.” Id. at 7:1–4 (citing Sakaki 5:25– 30). However, according to Appellant, it is not feasible to form a coating on very small particles. Id. at 7:1–8:13. Because Appellant did not raise these particle-size issues in the briefs, we do not consider them in the present appeal. See 37 C.F.R. § 41.47(e)(1) (“At the oral hearing, appellant may only rely on Evidence that has been previously entered and considered by the primary examiner and present argument that has been relied upon in the brief or reply brief . . . .”). Appeal 2017-009996 Application 12/278,638 7 group, with the additional argument regarding the particle circularity and aspect ratio of independent claim 68. See Appeal Br. 19–30. erefore, under 37 C.F.R. § 41.37(c)(1)(iv), we limit our discussion to claim 68. Claims 56, 57, 59, 61, 63–66, 69–73, 78–83, and 88–90 fall with claim 68. Whether the Examiner articulated a sufficient rationale, based on the references, for a skilled artisan to achieve the recited “greater freedom of movement” Appellant argues that the Examiner failed to articulate why a person of ordinary skill in the art would have combined the recited references to produce a particle coating that allows for “greater freedom of movement” of the particles within the polymer. Appeal Br. 21. For the reasons below, we disagree. First, Appellant argues that Ando’s coupling agents and Ohkawa’s water repellent agents are “reactive coupling agents” that would cause a “coupling effect” between the particle surfaces and the polymer, such that they would not promote freedom of movement of the particles. Id. at 21–22. Regarding Ando’s agent, Appellant argues that “[t]he Examiner admitted that the coupling agents of Ando do not allow for greater freedom of movement.” Id. at 22. We agree with the Examiner that this misinterprets the rejection, which simply states that Ando does not disclose whether the material allows for greater freedom of movement. See Answer 23.12 12 Although the rejection does not specifically rely on Ando’s interfacial modifiers to achieve the recited property, we note that Ando teaches using “a titanium-based coupling agent” or, alternatively, “a silane-based coupling agent or aluminum-based coupling agent.” Ando A ¶ 50. Similarly, Appellant’s Specification teaches “silane compounds, titanate compounds, [and] aluminate compounds,” Spec. 32:2–3, while including “[t]itanate coupling agents” in four of its working examples, id. at 40:15–16, Table 1. Appeal 2017-009996 Application 12/278,638 8 Second, Appellant argues that “greater freedom of movement” is incompatible with Ando’s teaching that the coupling agent “enhance[s] the interfacial adhesion between thermoplastic resin composition molecules and the heavy metal grain surface,” Appeal Br. 22 (quoting Ando C ¶ 13), and Ohkawa’s teaching that coupling agents “increase the affinity between the polymer phase and the metal particle filler,” id. (citing Ohkawa 10:42–49). Appellant argues that because Ohkawa discloses a particular silane coupling agent identified in the Specification as SIA0591.0,13 this shows that Ohkawa’s reference to “affinity” refers to reactive coupling between the particle and the polymer. Id. According to Appellant’s declaratory evidence, this particular agent “reacts with a metal powder and forms a bond,” unlike other surface additives that allow for greater freedom of movement of the particles. Id. at 16–17 (citing Williams 2010 Decl.14 ¶¶ 7–13; Williams 2014 Decl.15). We disagree that the use of the terms “adhesion” or “affinity” in these references implies that the interfacial modifier is a reactive coupling agent, or that it is incapable of allowing for greater freedom of movement. ese statements are similar to those found in Appellant’s Specification, which states that its interfacial modifiers “improve the association of the particulate with the polymer.” Spec. 4:14–15; see also id. at 10:12–14 (“We believe an interfacial modifier . . . provides an exterior coating on the particulate promoting the close association of polymer and particulate.”). Based on the 13 See Spec. 47:30–31 (“SIA0591.0 is N-(2-aminoethyl)-3-am[i]nopropyl- trimethoxy-silane.”). 14 Declaration of Rodney Williams, Sept. 2, 2010 (“Williams 2010 Decl.”). 15 Declaration of Rodney Williams, Dec. 16, 2014 (“Williams 2014 Decl.”). Appeal 2017-009996 Application 12/278,638 9 Specification, some degree of close “association” (i.e., adhesion or affinity) between the particles and the polymer is consistent with freedom of movement. Moreover, Ohkawa teaches SIA0591.0 as only one example, among many others, of suitable water repellent agents. For example, Ohkawa teaches a preference for titanate compounds which, according to Appellant’s Specification, are among the broad class of suitable interfacial modifiers, the choice of which is “dictated by metal particulate, polymer, and application.” Spec. 32:2–4. us, a preponderance of evidence on this record supports the Examiner’s determination that the statements about “adhesion” or “affinity” in Ando and Ohkawa “suggest[] that there is improved compatibility which would provide the advantageous properties taught by Ohkawa,” evincing increased freedom of movement of the particles. Answer 23. ird, Appellant argues that the Examiner erred because, while Ohkawa teaches “good moldability in shaping by injection molding, extrusion molding and compression molding,” this moldability is only prior to melt processing, compounding, shaping, or creation of a composite article as required by claims 56, 68, 73, and 80, respectively. Appeal Br. 22–23 (quoting Ohkawa, Abstract). We disagree. As the Examiner correctly explains, Ohkawa teaches an example in which “the exemplified composition is extruded (first melting) and formed into solid pellets and subsequently inject[ion] molded (second molding) to form test plates.” Answer 18 (citing Ohkawa 13:9–17). Also, as the Examiner persuasively explains, Ando teaches that after its resin composition is extruded, it can be re-melted and formed into a balance weight by injection and compression molding. Answer 24. us, a preponderance of the evidence on this record Appeal 2017-009996 Application 12/278,638 10 indicates that Ando’s modified composition, in light of Ohkawa’s teachings, remains moldable after its initial extrusion. Fourth, Appellant disagrees with the Examiner’s finding that Ohkawa strongly suggests freedom of movement (i.e., lubrication) when using an interfacial modifier at an operative concentration. Appeal Br. 23. According to Appellant, Ohkawa simply teaches that “using an amount of water repellant agent in excess of that needed to reactively couple the particle to polymer results in a failed material.” Id. at 20 (citing Ohkawa 8:10–14 (“When the amount of the water repellent agent is too small, no sufficient coupling effect can be exhibited between the surface of the filler and the matrix phase so that the resultant molding composition would be poor in the moldability.”)). We do not find this argument persuasive. To the extent that using too much coupling agent results in a failed material, Ohkawa teaches that it is because there is “excessively strong . . . lubrication between the filler surface and the matrix phase.” Ohkawa 8:16–17. As the Examiner persuasively explains, if the coupling reagent were reactive, the presence of too much of it “would just result in further crosslinking,” which is not the problem that Ohkawa describes. Answer 24. Moreover, we disagree that Ohkawa’s reference to “coupling,” and a “sufficient coupling effect” imply that there is reactive bonding between the particles and the polymer matrix. e passage in question states that “sufficient coupling effect” is needed to prevent the resultant molding composition from having “poor . . . moldability.” See Ohkawa 8:10–14. Elsewhere, Ohkawa teaches that the water repellent agent leads to “greatly improved affinity between the surface of the filler particles and the matrix Appeal 2017-009996 Application 12/278,638 11 polymer. Accordingly, the inventive molding composition has good moldability.” Ohkawa 10:49–52. us, Ohkawa teaches that the coupling effect, or this affinity between the particles and the polymer caused by the water repellent agent, improves moldability rather than destroys it.16 Fifth, Appellant argues that, even assuming that Ohkawa’s water repellent agent would result in greater freedom of movement, “the Examiner has failed to clearly articulate a reason for a person of ordinary skill in the art to include [such an agent] in the methods taught by Ando.” Appeal Br. 23. According to Appellant, Ando teaches a coupling agent for promoting interfacial adhesion, whereas an interfacial modifier of the claimed invention would be absent of any strong bonds between the particles and the polymer phase. See id. at 23–26 (citing Ando C ¶ 49; Williams 2014 Decl. ¶¶ 8–9, Figs. 3, 5). us, Appellant argues that the Examiner hasn’t articulated a reason to combine Ando with Ohkawa, and that Ando teaches away from using a coupling agent that allows for greater freedom of movement. We disagree. As we discuss above, Ando’s reference to interfacial “adhesion” would not have suggested to a person of ordinary skill in the art that there must be reactive bonding between the particles and the resin. Rather the evidence suggests that this refers to the same coupling effect (Ohkawa 8:10–14), affinity (Ohkawa 10:49–52), or “improved 16 Appellant’s Specification also refers to a “coupling” phenomenon. According to the Specification, “[t]he metal particulate can be coupled to the polymer phase . . . . In general the mechanism[s] used to couple metal particulate to polymer include solvation, chelation, coordination bonding (ligand formation), etc.” Spec. 34:14–18 (emphasis added). e Specification also describes working interfacial modifiers as “coupling agents.” Spec. 40. Appeal 2017-009996 Application 12/278,638 12 compatibility” (Answer 23) that improves moldability, and does not necessarily require reactive bonding between the particles and the polymer. Whether Ando teaches pre-treating the metal particles Appellant argues that “the Examiner failed to identify any teaching in Ando, Economy, or Ohkawa of pre-treating a metal particulate to form a coating of interfacial modifier, as claimed.” Appeal Br. 26. Appellant disputes the Examiner’s interpretation of Ando as describing a process in which one first mixes the metal particles with the coupling agent, and then combines this mixture with the polymer. Id. 26–28. According to Appellant, Ando is internally inconsistent and ambiguous as to the order of mixing. Id. at 27–28 (citing Ando B, 1 (translator noting an ambiguity)). e passage reads as follows: [0053] In a separate stage from that of the resin pellets described above, heavy metal comprising a mixture of, for example, tungsten large particle diameter heavy metal 4 and small particle diameter heavy metal 5 mixed together in suitably-selected proportions, and a titanium-based coupling agent for enhancing the interfacial adhesion between the heavy metal surface and the molecules of the polymer resin, are mixed together. Specifically, the titanium-based coupling agent is dissolved by mixing with n-propyl alcohol for about 1 hour at a temperature of 50°, and then added to resin pellets. Next, this mixture obtained by adding the coupling [agent]17 to the heavy metal is dried in a dryer. [0054] e mixture of coupling agent and heavy metal, plus the resin pellets formed by adding elastomer, biodegradable 17 Ando A adds the word “agent” here. See Ando A ¶ 53; see also Ando B, 1 (stating that the omission of “agent” here was “clearly a misprint”). Appeal 2017-009996 Application 12/278,638 13 additive, and plasticizer to the polymer resin are then mixed together using a powder mixer. . . .18 Ando B ¶¶ 53–54 (emphasis added). Appellant argues that we should read the passage as teaching “that the heavy metal and coupling agent are admixed with the resin pellets,” not that one should coat the metal with the coupling agent. Appeal Br. 28. e Examiner recognizes that paragraph 53 is ambiguous, but determines that paragraph 54 clears up the ambiguity by stating “that it is the mixture of coupling agent and heavy metal that is then mixed with the resin pellets.” Answer 27. We agree with the Examiner. According to the translator of Ando B, the second (emphasized) sentence of paragraph 53 can be interpreted either of two ways: either (1) “the coupling agent was added to the heavy metal rather than to resin pellets,” or, alternatively, (2) “the coupling agent was added to resin pellets and then these added to the heavy metal.” Ando B, 1. e context supports the translator’s first interpretation, because in three of the surrounding sentences (sentences 1 and 3 of paragraph 53; sentence 1 of paragraph 54), Ando refers to mixing the metal particles with the coupling agent. Based on the record before us, we determine that this passage in Ando, despite its ambiguity, is sufficient to 18 Ando A translates this sentence as “Next, this mixture of coupling agent and heavy metal is blended in a powder mixer with the resin pellets, in which an elastomer, biodegradable additive, and plasticizer have been added to the polymer resin and molded.” Ando A ¶ 54. Similarly, Ando C reads, “Next, the mixture comprising a coupling agent and a heavy metal is mixed together, in a powder mixer, with the resin pellets formed by adding an elastomer, a biodegradable additive and a plasticizing agent to a polymeric resin.” Ando C ¶ 54. Appeal 2017-009996 Application 12/278,638 14 teach particle pre-treatment to a person of ordinary skill in the art at the time of invention.19 Whether Ando teaches the recited circularity of claim 68 We reproduce Figure 2 of Ando below: Ando’s Figure 2 “is a semi-sectional view of a small-arms bullet” comprising a core material 3, “large/small particle diameter heavy metal 4, 5,” and a coupling agent inside jacket 2. Ando B ¶ 28. 19 Although the Examiner did not include this as part of the rejection, Ohkawa also teaches pre-treating the particles. See Ohkawa 7:62–8:3 (“ e procedure for the surface treatment of the [metal filler] with the water repellent agent is not particularly limitative according to any known method conventionally undertaken for the surface treatment of a powdery material. A preferable method . . . is to use a Henschel mixer in which the water repellent agent is sprayed on to the filler under agitation and thoroughly mixed together.”). Because Ando teaches pre-treatment, we need not rely on this teaching in Ohkawa for the purpose of this decision. Appeal 2017-009996 Application 12/278,638 15 Appellant argues that the Examiner cannot rely on this figure for the circularity limitations, because “Ando does not suggest that the drawings are to scale.” Appeal Br. 28 (citing Hockerson-Halberstadt, Inc. v. Avia Group Int’l, 222 F.3d 951, 956 (Fed. Cir. 2000)). Also, Appellant argues that Ando suggests that the particles have surface irregularity. Id. (citing Ando C ¶ 47). In response, the Examiner agrees that “[t]he drawings are not to scale but the particles are shown to be round and therefore [this] suggests the claimed circularity and aspect ratio, which do not necessarily provide for spherical particles. Also, Ando does not teach that the particles are flakelike or fibrous.” Answer 28. A rejection cannot rely on a drawing to “define the precise proportions of the elements” or to “show particular sizes if the specification is completely silent on the issue.” Hockerson-Halberstadt, 222 F.3d at 956. However, this does not “mean that things patent drawings show clearly are to be disregarded.” In re Mraz, 455 F.2d 1069, 1072 (CCPA 1972). Here, Figure 2 clearly shows spherical particles. Moreover, the Specification refers to their “diameter.” See Ando A ¶ 28. We disagree with Appellant that paragraph 47 of Ando discloses surface irregularity in the particles. Rather, it discloses that if the “large diameter” particles 4 appear at the surface of core 3, “the core surface” (not the individual particles) becomes irregular. Ando A ¶ 47. us, a preponderance of the evidence supports the Examiner’s determination that a person of ordinary skill in the art would have understood Ando to teach that the particles may be substantially spherical within the limitations of claim 68. Appeal 2017-009996 Application 12/278,638 16 Whether Economy is a non-analogous reference Appellant argues that Economy is a non-analogous reference. See Appeal Br. 20, 29–30. According to Appellant, Economy is not within the same field of endeavor as the claimed invention, and not reasonably pertinent to the problem faced by the inventor, because it “is directed to orienting liquid crystal material,” and it “is not directed to the extrusion of a composite.” Id. at 29. is argument is not persuasive of reversible error in the Examiner’s rejection. To the extent that the reference is in a different field, a reference may still be analogous if it is “reasonably pertinent to the particular problem with which the inventor is involved.” In re Bigio, 381 F.3d 1320, 1325 (Fed. Cir. 2004) (citation omitted). e Examiner cites Economy as evidence of “known shear rates in extrusion processes.” Answer 28. Moreover, as the Examiner persuasively explains, these common shear rates “are not dependent on whether the material being extruded is filled or unfilled but rather on the viscosity of the material being extruded.” Id. at 29. Appellant does not offer evidence or arguments to rebut this in the Reply Brief. In addition, claims 56 and 73 recite a very broad range for the shear rate, “from about 1 sec.−1 to about 500 sec.−1” Appeal Br. Claims App’x 1, 4. ere is substantial overlap between this range and the broad typical range that Economy discloses (100–10,000 sec.−1). Economy 2:49–51. erefore, a preponderance of the evidence on this record supports the Examiner’s finding that Economy is reasonably pertinent to the problem faced by the inventor, and thus Economy is analogous art. Appeal 2017-009996 Application 12/278,638 17 For the above reasons, we sustain the Examiner’s rejection of claims 56, 57, 59, 61, 63–65, 68–73, 78, 80–83, and 88 over Ando, Economy, and Ohkawa (Rejection 1). B. Rejection 2 (Ando, Suezaki, Economy, and Ohkawa) e Examiner’s second ground of rejection is substantially the same as the first, except that the Examiner relies on Suezaki, rather than solely on Ando, for teaching pre-treatment of the metal particles. Action 6–7. According to the Examiner, it would have been obvious to pre-treat the particles in Ando because Suezaki teaches “that a coupling agent can be attached to particulate in a plurality of known ways (including mixing the coupling agent first with the particulate).” Id. at 7. In addition to the arguments with respect to the first rejection, Appellant argues that “the Examiner did not articulate why the person [of ordinary skill in the art] would have been motivated to ‘mix the coupling agent first with metal particulate’ from among the ‘plurality of known ways’ identified by the Examiner to attach the coupling agent.” Appeal Br. 31. We do not find this argument persuasive of reversible error. As the Examiner explains, Suezaki describes three alternatives for attaching the coupling agent to the surface of the particles, and one of those options is pre- treating the particles before adding the polymer. See Answer 29–30. at Suezaki discloses other alternatives does not nullify its disclosure of pre- treatment. Cf. Merck & Co. v. Biocraft Labs., Inc., 874 F.2d 804, 807 (Fed. Cir. 1989) (“ at the [prior art reference] discloses a multitude of effective combinations does not render any particular formulation less obvious.”); In re Fulton, 391 F.3d 1195, 1201 (Fed. Cir. 2004) (“ e prior art’s mere Appeal 2017-009996 Application 12/278,638 18 disclosure of more than one alternative does not constitute a teaching away from any of these alternatives.”) For the above reasons, we sustain the Examiner’s rejection of claims 56, 57, 59, 61, 63–65, 68–73, 78, 80–83, and 88 over Ando, Suezaki, Economy, and Ohkawa (Rejection 2). C. Rejection 3 (Sakaki, Economy, and Ohkawa) e Examiner finds that Sakaki teaches mixing and compounding a composite material to form a wheel weight with the composition recited in the independent claims, including the use of “titanate-, aluminum-, and silane-based coupling agents to increase the affinity of the tungsten powder to the resin.” Answer 10 (citing Sakaki 5:31–37). e remainder of the rejection is substantially the same as the first ground of rejection, discussed above in part A. Regarding the shear rate range recited in claims 56 and 73, the Examiner cites Economy as evidence “that conventional process[ing] techniques such as extrusion” operate at a shear rate within the recited range, and that temperature is a result-effective variable. Action 10 (citing Economy 2:49–63); see also Answer 28–29, 33. According to the Examiner, Sakaki “fails to disclose . . . that the interfacial modifier allows for greater freedom of movement between particles.” Action 10. However, the Examiner relies on Ohkawa for this teaching, based on the same rationale as outlined in part A. See id. at 11–12. Because Ohkawa teaches that coupling agents “are added to metallic filler in a polymer matrix in order to improve moldability,” the Examiner determines that “it would have been obvious to one of ordinary skill in the art to utilize a coupling agent . . . that improved moldability, i.e., improved freedom of movement between particle[s].” Id. at 12. Appeal 2017-009996 Application 12/278,638 19 In response, Appellant argues that the Examiner did not articulate a motivation to combine Sakaki and Ohkawa to achieve the recited “greater freedom of movement” of the particles.20 Appeal Br. 33–34. Appellant argues the claims as a group. See id. erefore, under 37 C.F.R. § 41.37(c)(1)(iv), we limit our discussion to independent claim 56. Claims 57, 59, 63, 66, 73, 78, and 79 fall with claim 56. In making this argument, Appellant reiterates the previous argument, discussed in part A.1 above, with respect to Ohkawa. Appeal Br. 33. According to Appellant, Ohkawa’s water repellent agents “would not form interfacial modifier coatings that allow for greater freedom of movement . . . after processing and/or in the resultant article.” Id. For the reasons given above in part A.1, we do not find this argument persuasive. Second, Appellant argues that, even assuming that Ohkawa’s water repellent agent would result in greater freedom of movement, “the Examiner has failed to clearly articulate a reason for a person of ordinary skill in the art to include [such agents] in the methods taught by Sakaki.” Appeal Br. 34. According to Appellant, “Sakaki teaches using a coupling treatment ‘to enhance the affinity’ of a tungsten powder ‘with the resin,’” unlike the claimed invention. Id. (citing Sakaki 5:31–33). We disagree that Sakaki’s resulting “affinity” between the powder and the resin is incompatible with greater freedom of movement of the particles in the resin. Sakaki’s use of the term affinity is consistent with Ando’s and Ohkawa’s use of similar terminology as discussed above in part A.1. It is 20 Appellant also reiterates its argument, which we addressed above in part A.4, that Economy is not analogous art. Appeal Br. 34–35. Because it is substantially the same argument, we need not repeat our analysis here. Appeal 2017-009996 Application 12/278,638 20 also consistent with the teachings in Appellant’s Specification that “an interfacial modifier . . . provides an exterior coating on the particulate promoting the close association of polymer and particulate,” Spec. 10:12–14 (emphasis added), that it may “improve the association of the particulate with the polymer,” id. at 4:14–15 (emphasis added), and that it may “overcome the forces that prevent the matrix from forming a substantially continuous phase of the composite,” id. at 10:9–11. us, the preponderance of the evidence supports the Examiner’s finding that a person of ordinary skill in the art would have understood Sakaki’s use of affinity to describe “compatibiliz[ing] the particle filler to the polymer in order to disperse the particles in the polymer.” Answer 32. Next, Appellant argues that Sakaki “does not specifically identify any reactive coupling agent other than . . . SIA0591.0.” Appeal Br. 34 (citing Sakaki 8:31–34). As in its arguments responding to the first rejection, Appellant argues that SIA0591.0 is a reactive coupling agent that “has the opposite effect of an interfacial modifier coating that allows for a greater freedom of movement . . . after processing and/or in the resultant article.” Id. us, Appellant argues that Sakaki’s disclosure of SIA0591.0 teaches away from “replacing Sakaki’s ‘coupling agent’ with Ohkawa’s ‘water repellent agent.’” Id. is is not persuasive of reversible error. Sakaki teaches that suitable coupling agents may include, for example, “titanate-, aluminum- and silane- based coupling agents.” Sakaki 5:33–35. Similarly, as we discuss in part A.1, Ohkawa teaches numerous options for the water repellent agent, including titanate-based coupling agents. us, both Ohkawa and Sakaki teach interfacial modifiers other than SIA0591.0, including some within the class Appeal 2017-009996 Application 12/278,638 21 of titanate-based interfacial modifiers found in the working examples of the Specification. See Spec. 40:15–16, Table 1. In addition, the evidence on this record does not support a determination that Sakaki or Ohkawa teaches away from the claimed invention by disclosing SIA0591.0 as a potential reactive coupling agent. We recognize that Sakaki’s Example 1 uses SIA0591.0 as the coupling agent, and that the 2010 Williams Declaration presents evidence that an attempt to reproduce Example 1 failed to achieve a moldable material. See Appeal Br. 16–17; Williams 2010 Decl. ¶¶ 6–13. is appears to contradict Sakaki’s disclosure, in Example 1, that one may blend SIA0591.0 in a mixture of particles and polymer, pelletize them, and then use the pellets in subsequent injection molding to form a balance weight. See Sakaki 8:47–63. However, even if Sakaki’s Example 1 is mistaken or inoperative (which we need not decide here), “a non-enabling reference may qualify as prior art for the purpose of determining obviousness under § 103.” Symbol Techs. Inc. v. Opticon Inc., 935 F.2d 1569, 1578 (Fed. Cir. 1991). A preponderance of the evidence suggests that an ordinarily skilled artisan would have been motivated, and able, to select a suitable interfacial modifier other than SIA0591.0 to achieve a moldable material according to the teachings of Sakaki and Ohkawa. See, e.g., Sakaki 8:5–13 (describing the production of a balance weight by “integrally molding a metal clip and a weight made of a resin composition having high specific gravity,” or by “covering a previously produced metal clip with a resin composition having high specific gravity to form a weight portion. On molding, there can be used conventionally known various methods such as injection molding and compression molding.”) Appeal 2017-009996 Application 12/278,638 22 Because Appellant has not identified reversible error, we sustain the Examiner’s rejection of claims 56, 57, 59, 63, 66, 73, 78, 79 over Sakaki, Economy, and Ohkawa (Rejection 3). D. Rejection 4 (Sakaki, Economy, Ohkawa, and Ando) e Examiner’s fourth ground of rejection is substantially the same as the third ground, except that as with the first rejection, the Examiner cites Ando for the circularity and aspect ratio limitations of claim 68. Action 13– 14. According to the Examiner, “it would have been obvious from the teachings of Ando to utilize spherical particles in the composite of Sakaki given that they are both drawn to the same field of endeavor.” Id. at 13. Appellant refers to the arguments made with respect to the rejections of claims 56, 57, 59, 63, 66, 73, 78, and 79 over Sakahi in view of Economy and Ohkawa, specifically that the cited documents do not teach or suggest the use of an interfacial modifier coating that allows for a greater freedom of movement of the pre-treated metal particulate within the polymer phase, and that a person of ordinary skill in the art would not have looked to the teachings of Economy. See Appeal Br. 33–35. For the reasons we discussed above in part A.3, these arguments are not persuasive of reversible error. us, we sustain the Examiner’s rejection of claims 68–72 and 89 over Sakaki, Economy, Ohkawa, and Ando (Rejection 4). E. Rejection 5 (Sakaki, Economy, Ohkawa, and Bray) e Examiner’s fifth ground of rejection is also substantially the same as the third ground, except that the Examiner cites Bray for the limitation in claim 80 that the metal particulate is “iron-comprising.” Appeal Br. Claims Appeal 2017-009996 Application 12/278,638 23 App’x 4. According to the Examiner, “Sakaki fails to disclose . . . that the metal particulate comprises iron,” Action 15, but discloses that the particles can be tungsten, id. at 14. However, “Bray teaches that base metals such as tungsten can be alloyed with other metals such as iron” in “a high density composite material suitable for use in wheel weights.” Id. at 16. us, the Examiner determines that “it would have been obvious to one of ordinary skill in the art to alloy the tungsten of Sakaki with the alloying metal such as iron taught by Bray as a way to adjust density.” Id. at 17. Appellant reiterates substantially the same arguments as for the third rejection, and also argues that Bray cannot remedy the alleged defect of that rejection in failing to teach “a composite that allows for greater freedom of movement of the pre-treated metal particulate within the polymer phase after processing and/or in the resultant article.” Appeal Br. 36. Appellant also notes that Bray does not teach any particle coating. See id. is argument is not persuasive of reversible error, for the reasons given above in part C. In addition, “ e test for obviousness is not . . . that the claimed invention must be expressly suggested in any one or all of the references.” In re Keller, 642 F.2d 413, 425 (CCPA 1981). us, Bray itself need not suggest the presence of an interfacial modifier. For the above reasons, we sustain the Examiner’s rejection of claims 80–83, 88, and 90 over Sakaki, Economy, Ohkawa, and Bray (Rejection 5). CONCLUSION For the above reasons, and based on the Examiner’s findings and conclusions as a whole which we find persuasive, the preponderance of the evidence supports the Examiner’s conclusion of obviousness, and Appellant Appeal 2017-009996 Application 12/278,638 24 has not shown reversible error. erefore, we affirm the Examiner’s decision on all grounds. DECISION e Examiner’s decision is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended. See 37 C.F.R. §§ 1.136(a)(1)(iv), 41.50(f) (2018). AFFIRMED Copy with citationCopy as parenthetical citation