King Abdullah University of Science and TechnologyDownload PDFPatent Trials and Appeals BoardNov 27, 20202020000482 (P.T.A.B. Nov. 27, 2020) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 15/424,558 02/03/2017 Klaus-Viktor Peinemann 0338-362-2/2015-148-02 9721 144099 7590 11/27/2020 Patent Portfolio Builders, PLLC P.O. Box 7999 Fredericksburg, VA 22404-7999 EXAMINER WEISS, PAMELA HL ART UNIT PAPER NUMBER 1796 NOTIFICATION DATE DELIVERY MODE 11/27/2020 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): Mailroom@ppblaw.com eofficeaction@appcoll.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte KLAUS-VIKTOR PEINEMANN, JAMALIAH HANI BURABIE, LUIS FRANCISCO VILLALOBOS VAZQUEZ DE LA PARRA Appeal 2020-000482 Application 15/424,558 Technology Center 1700 Before JEFFREY B. ROBERTSON, CHRISTOPHER C. KENNEDY, and SHELDON M. MCGEE, Administrative Patent Judges. MCGEE, Administrative Patent Judge. DECISION ON APPEAL STATEMENT OF THE CASE Pursuant to 35 U.S.C. § 134(a), Appellant1 appeals from the Examiner’s decision to reject claims 1–46. We have jurisdiction. 35 U.S.C. § 6(b). We reverse. 1 We use the word Appellant to refer to “applicant” as defined in 37 C.F.R. § 1.42(a). Appellant identifies the real party in interest as King Abdullah University of Science and Technology. Appeal Br. 2. Appeal 2020-000482 Application 15/424,558 2 CLAIMED SUBJECT MATTER The claims are directed to methods of making a multi-layer asymmetrical membrane and membranes produced by such methods. The claimed methods recite a multi-step process of a) preparing a polymeric solution via a condensation reaction of monomers using a first solvent, b) casting the polymeric solution to form a polymeric film, c) contacting the polymeric film with a second solvent comprising a cross-linker to form a first layer on the top side of the polymeric film, and d) contacting the layered polymeric film with a non-solvent to form a porous second layer on the bottom of the polymeric film. See, e.g., Appeal Br. 26 (claim 18), 29–30 (claim 35). Claim 18, reproduced below with the key limitation italicized, is illustrative of the claimed subject matter: 18. A method of making a multi-layer asymmetric membrane comprising the steps of: (a) preparing a polymeric solution comprising one or more polymers, said preparing step includes a condensation reaction of monomers in a first solvent; (b) casting the polymeric solution to form a polymeric film; (c) contacting the polymeric film with a second solvent comprising a crosslinker under conditions to form a first layer on a top side of the polymeric film, wherein the crosslinker includes one or more functional groups that are incorporated into the first layer, the first layer is a dense, solvent-resistant first layer including crosslinked polymeric chains, said contacting step includes immersing the polymeric film for an immersion time of more than 0.1 seconds in the second solvent comprising the crosslinker and said solvent-resistant first layer floats on a remaining part of the polymeric film; and Appeal 2020-000482 Application 15/424,558 3 (d) contacting the polymeric film, having the dense, solvent-resistant first layer, with a non-solvent solution under conditions that form, by precipitation of the remaining part of the polymeric film, a porous second layer on the bottom of the polymeric film, the second layer including uncrosslinked polymeric chains and not the one or more functional groups. Appeal Br. 26 (Claims Appendix). STATEMENT OF THE CASE The Examiner rejects claims 1–46 under 35 U.S.C. § 103 as unpatentable over Boyanova (Polybenzimidazole Membranes for Organic Solvent Nanofiltration – Formation Parameters and Applications, Imperial College London Department of Chemical Engineering (2015)). Final Act. 3–19. Regarding method claims 18–46, Appellant argues, inter alia, that Boyanova does not disclose that its polymeric solution is prepared by a condensation reaction of monomers as required by these claims. Appeal Br. 14–15; Reply Br. 8. Regarding product claims 1–17, Appellant asserts that the claimed method of making the claimed membrane imparts structural differences over that disclosed in Boyanova. Appeal Br. 20. Specifically, Appellant argues that the claimed method results in structural features such as “the first layer is dense, solvent resistant and includes polymeric chains . . . [and] one or more functional groups,” and “the second layer includes uncrosslinked polymeric chains . . . [but] does not include the one or more functional groups of the first layer.” Id. OPINION The dispositive issue in this appeal is whether the Examiner has established by a preponderance of the evidence that Boyanova teaches or Appeal 2020-000482 Application 15/424,558 4 suggests “preparing a polymeric solution comprising one or more polymers, said preparing step includes a condensation reaction of monomers in a first solvent” as recited in each independent claim 1, 18, and 35. Upon consideration of the evidence provided in this appeal record, we determine that the Examiner has not supported this finding with a preponderance of the evidence and reverse the rejection. In re Oetiker, 977 F.2d 1443, 1449 (Fed. Cir. 1992) (“In rejecting an application, factual determinations by the PTO must be based on a preponderance of the evidence.”). To support the finding that the claimed condensation reaction of monomers is disclosed by Boyanova, the Examiner states that “the reference teaches the steps with the compositional components and conditions of the instant claims regardless of whether the same syntax is used (for example, a polymeric solution of the claimed one or more polymers in a solvent is expressly taught[;] as such the condensation reaction of monomers is taught, etc.).” Final Act. 20. See also Ans. 29 (“The reference teaches step (a) preparing a polymeric solution comprising one or more polymers in a first solvent. Since the reference adds the claimed species of polymers2 to the claimed solvent a condensation reaction is expected to occur.”). The Appellant argues: Appellant[s] understand[s] . . . the Examiner to mean that whenever somebody mixes two monomers, inherently a condensation reaction would take place. This is not so because the Examiner did not prove inherency of this reaction. Note that the initial burden is on the Examiner to provide support for a rejection based on inherency, and not on the Applicant to prove 2 This statement is confusing because the method claims require a condensation reaction of monomers in a solvent to prepare the polymeric solution. Appeal Br. 26 (claim 18), 29–30 (claim 35). Appeal 2020-000482 Application 15/424,558 5 that this will not happen, as suggested by the Examiner in the same paragraph. Reply Br. 8. We agree with the Appellant that the Examiner has not adequately established inherency. The mere existence of a polymeric solution, without more, does not reveal how that polymeric solution was prepared. Here, Boyanova’s disclosure is informative as it evinces that at least three different methods are known to be used in preparing polybenzimidazole, i.e., “PBI.”3 Boyanova 12–13 (discussing three different PBI synthesis methods developed by “Vogel and Marvel,” “Choe,” and “Iwakura”). Significantly, the claimed “condensation reaction of monomers” is not mentioned among these methods, nor is such a reaction disclosed in the preparation of the specific PBI relied on in the experimental portion of Boyanova. Id. at 12– 13, 31–33. While we agree with the Examiner’s statement (Final Act. 20) that “the same syntax” of the claims need not be used in the prior art to establish obviousness, factual findings must be supported by at least a preponderance of the evidence. Oetiker, 977 F.2d at 1449; Ethicon v. Quigg, 849 F.2d 1422, 1427 (Fed. Cir. 1988). Here, the Examiner’s finding that Boyanova’s polymeric solution is prepared by a process that “includes a condensation reaction of monomers in a first solvent” is not so supported. For this reason, we do not sustain the Examiner’s rejection of method claims 18–46. With respect to product-by-process claims 1–17, we recognize the principles set forth in In re Thorpe, 777 F.2d 695 (Fed. Cir. 1985) governing 3 The Examiner relies on PBI to establish the polymeric solution of step (a) that is then cast to form the polymeric film of step (b). Final Act. 4–6, 8–10, 15. Appeal 2020-000482 Application 15/424,558 6 the treatment of such claims. There, our reviewing court held that “[i]f the product in the product-by-process claim is the same as or obvious from a product of the prior art, the claim is unpatentable even though the prior product was made by a different process.” Id., 777 F.2d at 698 (emphasis added). Here, however, the Examiner has not established that the claimed membrane is the same as, or would have been obvious over, the membrane disclosed by Boyanova. Rather, the Examiner relies on the rationale of In re Best, 562 F.2d 1252 (CCPA 1977) by stating “[w]here the claimed and prior art products are identical or substantially identical in structure or composition, or are produced by identical or substantially identical processes, a prima facie case of either anticipation or obviousness has been established.” Final Act. 17, 20. Such rationale is insufficient on the current record, however, because the Examiner has failed to establish that the claimed and prior art membranes “are identical or substantially identical in structure or composition, or are produced by identical or substantially identical processes.” Best, 562 F.2d at 1255. It is manifestly unclear on this record whether Boyanova’s process of preparing its polymeric solution of PBI “includes a condensation reaction of monomers.” We again emphasize Boyanova’s disclosure that PBI has at least three ways of being synthesized, and the Examiner has not established that such methods include a condensation reaction of monomers. Boyanova 12–13. Because the Examiner does not establish that Boyanova’s product or process is identical or substantially identical to that claimed, we determine that the Examiner prematurely shifts the burden to Appellant to establish that the claimed membrane is different than that disclosed by Boyanova. Final Act. 17–18, 20–21 (citing Best, 562 F.2d at 1255). Because of the lack of evidence surrounding precisely how Boyanova’s “polymeric solution” of Appeal 2020-000482 Application 15/424,558 7 PBI is prepared, it follows that the Examiner’s finding that certain structural aspects of the claimed membrane (e.g., functional groups in the first layer, but not the second layer) would “necessarily form” is not supported. See Final Act. 20 (finding that Boyanova “teaches the claimed compositional components of polymers, solvents, non [-] solvents and the claimed steps performed” (emphasis added)). CONCLUSION The Examiner’s rejection is reversed. DECISION SUMMARY Claims Rejected 35 U.S.C. § Basis Affirmed Reversed 1–46 103 Boyanova 1–46 REVERSED Copy with citationCopy as parenthetical citation