Jun Yang et al.Download PDFPatent Trials and Appeals BoardMar 10, 202014044279 - (D) (P.T.A.B. Mar. 10, 2020) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/044,279 10/02/2013 Jun Yang 83384870 8724 28395 7590 03/10/2020 BROOKS KUSHMAN P.C./FGTL 1000 TOWN CENTER 22ND FLOOR SOUTHFIELD, MI 48075-1238 EXAMINER MARTIN, ANGELA J ART UNIT PAPER NUMBER 1727 NOTIFICATION DATE DELIVERY MODE 03/10/2020 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): docketing@brookskushman.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte JUN YANG, PATRICK PIETRASZ, CHUNCHUAN XU, and SHINICHI HIRANO ____________ Appeal 2018-007413 Application 14/044,279 Technology Center 1700 ____________ Before KAREN M. HASTINGS, GRACE KARAFFA OBERMANN, and MICHAEL G. MCMANUS, Administrative Patent Judges. OBERMANN, Administrative Patent Judge. DECISION ON APPEAL Pursuant to 35 U.S.C. § 134(a), Appellant1 appeals from the Examiner’s decision to reject claims 1–15 and 21–25. Appeal Br. 2–6. We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM. 1 We use the word “Appellant” to refer to “applicant” as defined in 37 C.F.R. § 1.42. Appellant identifies the real party in interest as Ford Global Technologies, LLC. Appeal Br. 1. Appeal 2018-007413 Application 14/044,279 2 STATEMENT OF THE CASE Appellant’s invention is directed to an oxygen reduction reaction (ORR) catalyst. Spec. ¶¶ 2–3; Appeal Br. Claims App. 1–3. Fuel cell vehicles use ORR catalysts. Spec. ¶ 2. Appellant’s ORR catalyst comprises a graphitized carbon substrate, an amorphous metal oxide layer overlying the substrate, and a catalyst overlying the metal oxide layer. Id. ¶ 3. The amorphous metal oxide layer has a worm-like structure. Id. Claims 1, 10, and 21 are independent. Claim 1 is illustrative of the subject matter and states: 1. An oxygen reduction reaction catalyst comprising: a graphitized carbon substrate; an amorphous metal oxide layer overlying the substrate and having a worm-like structure; a plurality of junctions between the graphitized carbon substrate and the amorphous metal oxide layer; and a catalyst overlying the metal oxide layer and the plurality of junctions. Appeal Br. Claims App. 1. Appeal 2018-007413 Application 14/044,279 3 OPINION The Examiner rejects claims 1–15 and 21–25 under 35 U.S.C. § 103 as obvious over Zhang2 in view of Sun3 and Izumiya.4 Final Act. 2–5. For the most part, Appellant argues these claims as a group. Appeal Br. 2–6. We select claim 1 as representative of the group. See 37 C.F.R. § 41.37(c)(1)(iv). Appellant makes one additional argument regarding claim 21 (Appeal Br. 5–6), which we address separately. The first material dispute concerns whether Zhang discloses a metal oxide layer characterized by a worm-like structure.5 See Final Act. 4; Appeal Br. 2. The Examiner relies on Zhang’s Figure 3 as disclosing the worm-like structure. Final Act. 4; Ans. 6. Appellant disagrees that Zhang 2 Zhang, L., Wang, L., Holt, C. M. B., Navessin, T., Malek, K., Eikerling, M.H., & Mitlin, D. (2010). Oxygen reduction reaction activity and electrochemical stability of thin-film bilayer systems of platinum on niobium oxide. The Journal of Physical Chemistry, 114(39), 16463–16474. 3 Sun et al., US 2009/0208780 A1, published Aug. 20, 2009. 4 Izumiya et al., JP 2006-228546, published Aug. 31, 2006. The Examiner entered an English language machine translation of Izumiya into the record on May 11, 2018. Our citations are to the English language version. 5 Appellant’s written description does not clearly define the term worm-like structure. On that point, Appellant merely distinguishes Figure 2A (which illustrates a worm-like structure of the metal oxide layer) from Figure 2B (which illustrates a catalyst layer that is not worm-like). See Spec. ¶¶ 7–8, 24, 26, 31. Figure 2A may provide an illustration of one embodiment of a worm-like structure, but the written description does not define the metes and bounds of the term, except to describe a worm-like structure as being “discontinuous.” See id. ¶ 26. Significantly, Appellant’s written description does not explain the degree of discontinuity necessary to provide a worm- like structure. See id. The term worm-like structure, moreover, does not appear to have a well-known meaning in the art. Appeal 2018-007413 Application 14/044,279 4 discloses a worm-like structure. Appeal Br. 2. Appellant labels this as argument (1). Reply Br. 1–2. Appellant argues that, in Zhang, “the description of Fig. 3 is limited to showing ‘5 nm thick platinum films on . . . three oxide supports,’” but “Fig. 3 does not disclose or depict any structure for a metal oxide layer.” Appeal Br. 2 (quoting Zhang 16,467, Fig. 3). In response, the Examiner states that “in Fig. 3(b) and 3(c) of Zhang, there is a discontinuous formation which appears to be worm-like.” Ans. 6. The Examiner, however, does not adequately explain how Figures 3(b) and 3(c) show the metal oxide layer to have a worm-like structure. As Appellant indicates, Zhang describes Figure 3 as showing “platinum films on the three oxide supports.” Accordingly, any structure shown in Figure 3(b) and (c) would appear to be the structure of the platinum overlayer – a structure not relevant to the claim term at hand. See Zhang 16,466 (explaining that in Figure 3, the “bare oxide surfaces are relatively uniform . . . , with the observed surface morphology being due to the Pt overlayer”). That does not end the inquiry, however, because the Examiner presents an alternative finding that the combination of Zhang, Sun, and Izumiya would have resulted in the metal oxide having a worm-like structure. Final Act. 4. Specifically, the Examiner finds: Alternatively, applicant states that nanoparticles of graphitized carbon in the substrate promote the growth of a worm-like structure in the overlying metal oxide layer (see instant specification, para. 25). Since Zhang, as modified by Sun and lzumiya above, teaches that the substrate is composed of graphitized carbon nanoparticles, the amorphous metal oxide deposited on that substrate will form a worm-like structure. Id. Appeal 2018-007413 Application 14/044,279 5 Appellant presents three arguments—labeled (2) through (4)—in response to that alternative finding. Reply Br. 1–3. In argument (2), Appellant asserts that the Examiner’s rejection relies on Appellant’s disclosure as a source of motivation for combining the three prior art references and, therefore, represents an exercise of impermissible hindsight. Appeal Br. 3; Reply Br. 1–3. We disagree with Appellant that the Examiner has used Appellant’s disclosure as a source of the motivation to combine (Reply Br. 3). The Examiner articulates rational reasons, grounded in specific teachings of Sun and Izumiya, for combining those references with Zhang. See Final Act. 3 (citing Sun ¶¶ 34, 42, 69; Izumiya Abs.) (relying on Sun’s teachings that nano-sized graphitized carbon particles are suitable for use in fuel cells and have high surface areas, high durability, and corrosion resistance, and Izumiya’s teaching as to improved catalyst capability at lower costs, in providing reasons to combine Sun and Izumiya with Zhang). The Examiner may use Appellant’s disclosure to show that a claim limitation is the natural result of a combination of elements taught in the prior art. See Hospira, Inc. v. Fresenius Kabi USA, LLC, 946 F.3d 1322, 1329–30 (Fed. Cir. 2020) (explaining that “the work of the inventor or the patentee can be used as the evidence of inherency,” which, in the context of obviousness, may demonstrate that a claimed feature is “the natural result of the combination of elements explicitly disclosed by the prior art” (quoting Par Pharm., Inc. v. TWi Pharm., Inc., 773 F.3d 1186, 1196 (Fed. Cir. 2014))). Here, the Examiner finds that the combination of Zhang and Izumiya teaches the amorphous metal oxide, and the combination of Zhang and Sun teaches the graphitized carbon substrate composed of nanoparticles. Final Act. 3. Appellant does not show that the Examiner reversibly erred by Appeal 2018-007413 Application 14/044,279 6 relying on a statement in the Specification indicating that the specified worm-like structure is the natural result of the combination of prior art elements (namely, depositing an amorphous metal oxide onto a substrate composed of graphitized nanoparticles). On that point, the Examiner states cogent reasons (independent of Appellant’s disclosures) why the prior art would have suggested the combination (and, thereby, the inherent result). In argument (3), Appellant contends that the Examiner fails to demonstrate that a worm-like structure is a latent property of the prior art combination. Appeal Br. 3; Reply Br. 1. Similarly, in argument (4), Appellant states that the Examiner fails to provide a basis in fact or technical reasoning to show that the worm-like structure is inherent or necessarily present in Zhang. Appeal Br. 3–4; Reply Br. 1. As the Examiner observes, however, Appellant’s Specification indicates that a worm-like structure is the natural result when an amorphous metal oxide is deposited on a substrate of graphitized nanoparticles. Spec. ¶ 25 (the substrate “can promote the growth of . . . a worm-like structure in the overlying metal oxide layer . . . due to the nanoparticle arrangements to be coated”). Appellant does not address the statement upon which the Examiner relies (Spec. ¶ 25). Accordingly, we find no basis on this record for concluding the Examiner reversibly erred in construing the statement as sufficient to demonstrate that a worm-like structure is the natural result of the combination of prior art elements taught in Zhang, Sun, and Izumiya. See Par Pharm., Inc. v. TWi Pharm., Inc., 773 F.3d 1186, 1195–96 (Fed. Cir. 2014) (it may be appropriate “to rely on inherency to establish the existence of a claim limitation in the prior art in an obviousness analysis” where the limitation at issue is “the natural result of the combination of Appeal 2018-007413 Application 14/044,279 7 elements explicitly disclosed by the prior art.”); see also Ex parte Obiaya, 227 USPQ 58, 60 (BPAI 1985) (“The fact that appellant has recognized another advantage which would flow naturally from following the suggestion of the prior art cannot be the basis for patentability when the difference would otherwise have been obvious.”). Appellant presents three additional arguments—labeled (5) through (7)—in contesting the Examiner’s rejection. Reply Br. 1–2. In argument (5), Appellant asserts that combining the disclosure of Zhang with that of Izumiya does not result in a graphitized carbon substrate. Appeal Br. 4; Reply Br. 1. The Examiner, however, relies on Sun—not Zhang and Izumiya—for teaching the graphitized carbon substrate. See Final Act. 3. Appellant’s argument (5) is not persuasive because it does not account for the entirety of the combined teachings of Zhang, Sun, and Izumiya. See In re Keller, 642 F.2d 413, 208 USPQ 871 (CCPA 1981) (stressing that nonobviousness cannot be established by attacking the disclosures of individual references but must take account of what the combined disclosures of the applied prior art references fairly would have suggested to the ordinarily skilled artisan). Appellant also argues that “by using Izumiya with Zhang, you would need to replace one form of an oxide layer with another.” Appeal Br. 4. Appellant, however, does not specifically rebut the Examiner’s reason for making the replacement. See Final Act. 3 (“improve catalyst capability at lower costs”); Appeal Br. 4. In argument (6), Appellant contends that Zhang does not disclose or suggest the formation of a catalyst on the junctions between NbOx and graphitic carbon. Appeal Br. 4–5; Reply Br. 1–3. However, Appellant does Appeal 2018-007413 Application 14/044,279 8 not dispute the Examiner’s interpretation of the term junction to be “a state of being joined; union; a place or point where two or more things meet or converge” (Final Act. 4; Ans. 5, 7). Applying that interpretation, the Examiner reasonably found that a plurality of junctions would occur between the carbon substrate and niobium oxide layer in Zhang because the niobium oxide layer is deposited onto the carbon. See Zhang 16,464 (“niobium oxide films were deposited onto the [glassy carbon] supports”). Accordingly, because the platinum catalyst overlays the niobium oxide layer (see id. at 16,466), and because the junctions are directly beneath the niobium oxide layer, the catalyst overlays the junctions. In argument (7), Appellant alleges that Izumiya does not disclose “an amorphous metal oxide layer of 100% niobium oxide” as recited in claim 21. Appeal Br. 5–6; Reply Br. 2–4. Appellant argues that Izumiya teaches a mixture of an amorphous metal oxide and a metal catalyst, and a mixture is not a pure metal oxide. Appeal Br. 5 (citing Izumiya Abs.); Reply Br. 4. The Examiner’s rejection, however, does not propose substituting Izumiya’s mixture of a metal oxide and metal catalyst for Zhang’s metal oxide. Rather, the Examiner proposes modifying Zhang’s metal oxide to make it amorphous. See Final Act. 3 (finding that it would have been obvious “to employ an amorphous metal oxide in the ORR catalyst of Zhang”). In any event, the Examiner additionally relies on claim 2 of Izumiya, which states that the metal oxide and the metal unify in layers. Ans. 7 (citing Izumiya Claim 2). Appellant does not adequately explain why a layer of metal oxide would not be entirely metal oxide. See Reply Br. 3–4. Appeal 2018-007413 Application 14/044,279 9 CONCLUSION We affirm the Examiner’s decision to reject claims 1–15 and 21–25. Claims Rejected 35 U.S.C. § References/Basis Affirmed Reversed 1–15 and 21–25 103 Zhang, Sun, Izumiya 1–15 and 21–25 No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1). AFFIRMED Copy with citationCopy as parenthetical citation