Jesse Frantz et al.Download PDFPatent Trials and Appeals BoardOct 29, 202014701857 - (D) (P.T.A.B. Oct. 29, 2020) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/701,857 05/01/2015 Jesse A. Frantz 102977-US2 1046 26384 7590 10/29/2020 NAVAL RESEARCH LABORATORY ASSOCIATE COUNSEL (PATENTS) CODE 1008.2 4555 OVERLOOK AVENUE, S.W. WASHINGTON, DC 20375-5320 EXAMINER TRAN, UYEN M ART UNIT PAPER NUMBER 1726 NOTIFICATION DATE DELIVERY MODE 10/29/2020 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): patent.docketing@nrl.navy.mil PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte JESSE A. FRANTZ, JASON D. MYERS, ROBEL Y. BEKELE, and JASBINDER S. SANGHERA Appeal 2019-006894 Application 14/701,857 Technology Center 1700 ____________ Before ROMULO H. DELMENDO, MICHAEL P. COLAIANNI, and JEFFREY B. ROBERTSON, Administrative Patent Judges. DELMENDO, Administrative Patent Judge. DECISION ON APPEAL The Appellant1 appeals under 35 U.S.C. § 134(a) from the Primary Examiner’s final decision to reject claims 11–24.2 We have jurisdiction under 35 U.S.C. § 6(b). We affirm. 1 We use the word “Appellant” to refer to “applicant” as defined in 37 C.F.R. § 1.42—i.e., the named Inventors (Application Data Sheet filed May 1, 2015 at 5). The Appellant identifies “The Government of the United States, as represented by the Secretary of the Navy[,]” as the real party in interest (Appeal Brief filed March 15, 2019 (“Appeal Br.”) at 2). 2 See Appeal Br. 3–6; Final Office Action entered July 12, 2018 (“Final Act.”) at 3–20; Examiner’s Answer entered May 21, 2019 (“Ans.”) at 4–24. Appeal 2019-006894 Application 14/701,857 2 I. BACKGROUND The subject matter on appeal relates to a method of making a photovoltaic device in which a microstructured ZnO coating is provided as an antireflective layer and scatters a large fraction of the incoming radiation at a large angle, resulting in absorption that is closer to a p-n junction (Specification filed May 1, 2015 (“Spec.”) ¶¶ 8–9; Drawings filed May 1, 2015, Fig. 1). Representative claim 11 is reproduced from the Claims Appendix to the Appeal Brief, as follows: 11. A method of making a photovoltaic device, comprising: coating a substrate with a p-type layer; depositing an n-type layer on the p-type layer, forming a p-n junction; depositing a layer of ZnO on the n-type layer; depositing a layer of aluminum-doped ZnO (AZO) on the ZnO; depositing a continuous top layer of ZnO on the AZO; and etching the top ZnO layer to form a textured, continuous ZnO top layer comprising subwavelength surface structures, wherein the textured, continuous ZnO top layer forms antireflective surface structures on the AZO layer and scatters incoming light, increasing absorption of scattered light close to the p-n junction. (Appeal Br. 8 (emphasis added)). Claim 21, the only other independent claim on appeal, recites the same disputed limitations highlighted above in reproduced claim 11 (id. at 8–9). II. REJECTIONS ON APPEAL The claims on appeal stand rejected under 35 U.S.C. § 103 as follows: A. Claims 11–14 and 19–24 as unpatentable over Cho et al.3 3 US 2013/0048074 A1, published February 28, 2013. Appeal 2019-006894 Application 14/701,857 3 (“Cho”), Den Boer et al.4 (“Den Boer”), and Yeo et al.5 (“Yeo”); B. Claims 15 and 16 as unpatentable over Cho, Den Boer, Yeo, and Dhere et al.6 (“Dhere”); C. Claim 17 as unpatentable over Cho, Den Boer, Yeo, and Sano;7 D. Claims 18 and 22 as unpatentable over Cho, Den Boer, Yeo, and Adachi et al.8 (“Adachi”); E. Claims 11–14 and 19–24 as unpatentable over Cho, Ohyama et al.9 (“Ohyama”), Den Boer, and Yeo; F. Claims 15 and 16 as unpatentable over Cho, Ohyama, Den Boer, Yeo, and Dhere; G. Claim 17 as unpatentable over Cho, Ohyama, Den Boer, Yeo, and Sano; and H. Claims 18 and 22 as unpatentable over Cho, Ohyama, Den Boer, Yeo, and Adachi. (Ans. 4–24; Final Act. 3–20). 4 US 2008/0178932 A1, published July 31, 2008. 5 US 2013/0078750 A1, published March 28, 2013. 6 US 2007/0257255 A1, published November 8, 2007. 7 US 6,211,454 B1, issued April 3, 2001. 8 US 2012/0097244 A1, published April 26, 2012. 9 WO 2013/179529 A1, published December 5, 2013. The Examiner relies on US 2015/0047701 A1, published February 19, 2015, as an English language equivalent (Ans. 13). Therefore, our citations to this reference are to the US document. Appeal 2019-006894 Application 14/701,857 4 III. DISCUSSION 1. Grouping of Claims The Appellant argues all rejections and claims together under one sub- heading, focusing only on the independent claims (Appeal Br. 3–6). Therefore, we confine our discussion to claim 11, which we select as representative. 37 C.F.R. § 41.37(c)(1)(iv). Pursuant to the rule, all other claims stand or fall with claim 11. 2. The Examiner’s Position With respect to Rejections A through D, the Examiner finds that Cho describes a method for manufacturing a thin film solar cell including some of the steps recited in claim 11 (Ans. 4–5; Final Act. 3–4). The Examiner acknowledges, however, that Cho does not disclose depositing a ZnO top layer and etching the ZnO top layer to form a textured, continuous ZnO top layer, as required by claim 11 (Ans. 5; Final Act. 4). Relying on Den Boer, which the Examiner finds as teaching a transparent electrode made of ZnO having a textured surface, the Examiner concludes that “[i]t would have been obvious to a person of ordinary skill in the art . . . to deposit[] the transparent conductive layer 3a of Den Boer . . . on top of the transparent electrode of Cho . . . for reducing reflection . . . [and] thus improve efficiency” (Ans. 5; Final Act. 4) (citing Den Boer Fig. 1 and ¶¶ 28, 33–34; emphasis removed). Additionally, the Examiner relies on Yeo for the etching step and concludes that “[i]t would have been obvious to a person of ordinary skill in the art . . . to texture the top ZnO layer of modified Cho . . . by [using the] etching method of Yeo . . . for simple process, short process time, low cost and easy process control [sic]” (Ans. 5; Final Act. 4) (citing Yeo ¶ 11; emphasis removed). Appeal 2019-006894 Application 14/701,857 5 With respect to Rejections E through H, the Examiner finds further that Ohyama teaches a “transparent conductive layer 38 being made of TCO [transparent conductive oxide] deposit[ed] on [a] TCO layer 36 wherein the transparent electrode comprises continuous subwavelength surface (texture[d] surface) structures . . . and the layer 38 being function as antireflection film [sic] ” (Ans. 14; Final Act. 13) (citing Ohyama Fig. 2 and ¶¶ 34, 39; emphasis removed). The Examiner concludes that “[i]t would have been obvious to a person of ordinary skill in the art . . . to deposit[] the transparent conductive layer 38 of Ohyama . . . on top of the transparent electrode of Cho . . . for reducing reflection . . . [and] thus improve efficiency” (Ans. 14; Final Act. 13) (emphasis removed). The Examiner states that although Cho and Ohyama do not disclose a transparent conductive layer made of ZnO, Den Boer teaches that ZnO is a transparent conductive layer (id.). 3. The Appellant’s Contentions The Appellant does not dispute the Examiner’s findings regarding Cho’s scope and content and the differences between it and claim 11’s subject matter (Appeal Br. 4). Rather, the Appellant contends that the prior art “references do not disclose the limitations [in claim 11] of depositing a continuous top layer of ZnO on the AZO and etching the top ZnO layer to form a textured, continuous ZnO top layer” (id.). Specifically, the Appellant argues that “[t]he electrode 3 of Den Boer is not a top layer, as it is provided below the glass substrate 1” (id.). As for Ohyama, the Appellant argues that “Ohyama does not disclose or suggest the use of ZnO as the top transparent layer 38, nor does it disclose or suggest that the top transparent layer 38 be etched” (id.). As for Yeo, the Appellant argues that although the reference Appeal 2019-006894 Application 14/701,857 6 teaches etching to provide a subwavelength nanostructure for antireflection, it teaches using a ZnO layer as a mask and not a continuous, textured ZnO top layer (id. at 5). 4. Opinion For the reasons below, we agree with the Appellant that the Examiner Rejections A through D are not well-founded. We conclude, however, that the Appellant’s arguments are insufficient to identify reversible error in Rejections E through H. In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011). Den Boer teaches a photovoltaic device in which a front electrode 3 has a textured surface and may contain a single or multilayers of a transparent conductive oxide such as tin oxide or zinc oxide (Den Boer Fig. 1 and ¶ 28). But, as the Appellant points out (Appeal Br. 4), Den Boer’s front electrode 3 is not a “top layer,”10 as recited in claim 11, because it is provided below a glass substrate 1 (Den Boer Fig. 1; ¶ 28 (requiring both a glass substrate 1 and front electrode 3 to effect improved efficiency in terms of light absorption)). Cf. In re Suitco Surface, Inc., 603 F.3d 1255, 1260 (Fed. Cir. 2010). Therefore, we do not sustain Rejections A through D. Rejections E through H stand on a different footing. Ohyama teaches a solar cell including a transparent layer 38, which may be conductive or insulative, that is antireflective and protective of the light-receiving surface of the solar cell (Ohyama Fig. 2 and ¶¶ 9, 39). As shown in Ohyama’s 10 The Examiner states that claim 11 “requires [a] top layer, not the topmost layer” (Ans. 22). But the difference between “top” and “topmost” is not readily apparent on this record. See https://www.merriam- webster.com/dictionary/top; https://www.merriam- webster.com/dictionary/topmost. Appeal 2019-006894 Application 14/701,857 7 Figure 2, the transparent (antireflective) film 38 is textured. Although Ohyama does not specifically identify ZnO as a material for the transparent layer 38, it does not place any limitations as to the materials that can make up this layer (id. ¶ 39). Indeed, it actually teaches that a layer made of ZnO and a dopant, which is not excluded by claim 11, is in fact a transparent conductive layer (id. ¶ 38). Given Ohyama’s teachings, taken together with Den Boer’s additional disclosure that ZnO is a transparent conductive layer (Den Boer ¶ 28), we discern no reversible error in the Examiner’s determination that a person having ordinary skill in the art would have been prompted to provide a textured ZnO transparent conductive layer on top of Cho’s transparent electrode with a reasonable expectation of providing an antireflective, protective film that improves efficiency. As for the etching step to provide the textured surface, we find no reversible error in the Examiner’s finding that Yeo, although directed to materials other than ZnO, demonstrates that etching is a simple technique that may be used to provide a textured surface (Ans. 23 (citing Yeo ¶ 11)). KSR Int’l Co. v. Teleflex Inc., 550 U.S. 398, 417 (2007) (“[I]f a technique has been used to improve one device, and a person of ordinary skill in the art would recognize that it would improve similar devices in the same way, using the technique is obvious unless its actual application is beyond his or her skill.”). For these reasons, and those well-stated by the Examiner, we uphold Rejections E through H. Appeal 2019-006894 Application 14/701,857 8 IV. CONCLUSION In summary: Claims Rejected 35 U.S.C. § Reference(s)/Basis Affirmed Reversed 11–14, 19–24 103 Cho, Den Boer, Yeo 11–14, 19–24 15, 16 103 Cho Den Boer, Yeo, Dhere 15, 16 17 103 Cho, Den Boer, Yeo, Sano 17 18, 22 103 Cho, Den Boer, Yeo, Adachi 18, 22 11–14, 19–24 103 Cho, Ohyama, Den Boer, Yeo 11–14, 19– 24 15, 16 103 Cho, Ohyama, Den Boer, Yeo, Dhere 15, 16 17 103 Cho, Ohyama, Den Boer, Yeo, Sano 17 18, 22 103 Cho, Ohyama, Den Boer, Yeo, Adachi 18, 22 Overall Outcome 11–24 No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED Copy with citationCopy as parenthetical citation