Ex Parte YUM et alDownload PDFPatent Trial and Appeal BoardDec 23, 201613271522 (P.T.A.B. Dec. 23, 2016) Copy Citation United States Patent and Trademark Office UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O.Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 3487.003 7758 EXAMINER TALBOT, BRIAN K ART UNIT PAPER NUMBER 1715 MAIL DATE DELIVERY MODE 13/271,522 10/12/2011 Jung Hwan YUM 23405 7590 12/27/2016 HESLIN ROTHENBERG FARLEY & MESITI PC 5 COLUMBIA CIRCLE ALBANY, NY 12203 12/27/2016 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte JUNG HWAN YUM, GENNADI BERSUKER, and K. SANJAY BANERJEE Appeal 2014-008343 Application 13/271,522 Technology Center 1700 Before BEVERLY A. FRANKLIN, KAREN M. HASTINGS, and JAMES C. HOUSEL, Administrative Patent Judges. HOUSEL, Administrative Patent Judge. DECISION ON APPEAL1 Pursuant to 35 U.S.C. § 134(a), Appellants2 appeal from the Examiner’s decision finally rejecting, under 35 U.S.C. § 103(a), claims 1—8 and 10—12 as unpatentable over the combination of Maes,3 Parsons,4 and 1 Our decision refers to the Specification (Spec.) filed October 12, 2011, Appellants’ Appeal Brief (Appeal Br.) filed March 20, 2014, and the Examiner’s Answer (Ans.) mailed May 29, 2014. 2 According to Appellants, the real party in interest is Sematech, Inc. Appeal Br. 1. 3 US 6,818,517 Bl, issued November 16, 2004. 4 WO 84/03995, published October 11, 1984 (“Parsons”). Appeal 2014-008343 Application 13/271,522 Jones,5 and claim 9 as unpatentable over this combination adding Ritala.6 We have jurisdiction over the appeal under 35 U.S.C. § 6(b). We AFFIRM. STATEMENT OF THE CASE The invention relates to a process for preparing a beryllium oxide (BeO) layer on a semiconductor substrate. Spec. 11. Appellants disclose that BeO has some desirable properties including excellent thermal stability and conductivity, large energy band-gap, and a dielectric constant very close to atomic layer deposited (ALD) aluminum oxide. Id. at | 5. In addition, Appellants note that beryllium’s lack of d orbitals may reduce the formation of defects in the crystalline oxide. Id. Beryllium oxide also has a very short bond length with strong covalent bonding allowing formation of a dense structure with small interstitial spaces. Id. As such, Appellants disclose that BeO can provide an excellent interface passivation layer (IPL), if it can be applied in a discrete, well-ordered film. Id. Claim 1, reproduced below from the Claims Appendix to Appellants’ Brief, is illustrative of the subject matter on appeal: 1. A process for forming a beryllium oxide film on a substrate comprising the sequential steps of: (a) providing a substrate in a reaction chamber; (b) exposing said substrate to a dialkylberyllium or dihaloberyllium compound; (c) exposing said substrate to a source of oxygen, steps (b) and ( c) comprising a single cycle, whereby said dialkylberyllium compound and said source of oxygen react to form a beryllium oxide film on said substrate. 5 US 2011/0184156 Al, published July 28, 2011. 6 US 6,632,279 Bl, issued October 14, 2003 (“Ritala”). 2 Appeal 2014-008343 Application 13/271,522 ANALYSIS Claims 1—8 and 10—12 Appellants state that claims 1—8 and 10—12 stand or fall together. Br. 4. Accordingly, we select claim 1 to address the issues raised by Appellants’ arguments. 37 C.F.R. § 41.37(c)(iv) (2013). The dispositive issue before us on appeal is whether the Examiner’s rejections rely improperly on hindsight reconstruction by arbitrarily picking and choosing from three references guided by Appellants’ disclosure. We answer this question in the negative. Therefore, we sustain the above rejection based on the findings of fact, conclusions of law, and rebuttals to arguments expressed by the Examiner in the Final Office Action and the Answer. The following comments are added for emphasis. The Examiner finds Maes teaches a method of depositing plural layers in situ whereby one layer is formed by ALD and another layer is formed by chemical vapor deposition. Ans. 2. The Examiner finds Maes further teaches the ALD layer is a metal oxide which may be BeO, formed by sequential or alternating of precursor gases of metal and oxygen with intermediate purging of the precursors. Id. Also, the Examiner finds Maes’ process can be repeated to form multilayer films. Id. However, the Examiner acknowledges Maes fails to teach that the beryllium metal precursor gas is a dialkyberyllium compound such as diethylberyllium. Id. Nonetheless, the Examiner finds Parsons teaches a metal organic chemical vapor deposition (MOCVD) beryllium precursor may be diethylberyllium. Id. In addition, the Examiner finds Jones teaches precursors for forming metal oxide films by MOCVD and ALD, wherein the precursors may include alkyl groups. Id. The Examiner concludes that it 3 Appeal 2014-008343 Application 13/271,522 would have been obvious to use diethylberyllium as the metal precursor gas in Maes’ process for forming a BeO film “with the expectation of achieving similar success since it is shown that alkyl precursors for MOCVD and ALD are interchangeable for forming metal oxide films.” Id. Appellants contend that the Examiner’s obviousness conclusion is based on hindsight reconstruction involving picking and choosing the elements of claim 1 from the three applied prior art references. Br. 4. In particular, Appellants argue that the rejection requires selecting a single non preferred metal from Maes’ disclosure of 24 metals to use in only the first half of a two-step process. Id. at 5. As to the selection of a non-preferred metal in Maes as the starting point for obviousness, Appellants cite to Takeda Chemical Industries, Ltd. V. Alphapharm Pty., Ltd., 492 F.3d 1350 (Fed. Cir. 2007) and Otsuka Pharm. Co. v. Sandoz, Inc., 678 F.3d 1280 (Fed. Cir. 2012), without further comment or elaboration. Id. at 7. Appellants further argue that the Examiner then arbitrarily selects bits of the disclosures of Parsons and Jones. Id. at 5. Parsons, Appellants assert, uses a mixture of trimethylgallium, arsine, and diethylberyllium to produce Be-doped GaAs, and does not disclose the deposition of a BeO film or an oxidative process. Id. at 6. Jones, Appellants assert, discloses metal alkoxide precursors for making oxides of rare earth metals, and fails to disclose beryllium. Therefore, according to Appellants, other than Appellants’ disclosure, there is no motivation to consider Parsons or Jones. Id. Moreover, Appellants argue that an ordinary artisan, looking for a process to make BeO, would never have found either Parsons or Jones. Id. Appellants’ arguments not only raise the issue of improper hindsight reconstruction, but also allude to Parsons and Jones being non-analogous 4 Appeal 2014-008343 Application 13/271,522 prior art. As Appellants recognize (Br. 5), “[a]ny judgment on obviousness is in a sense necessarily a reconstruction based upon hindsight reasoning, but so long as it takes into account only knowledge which was within the level of ordinary skill at the time the claimed invention was made and does not include knowledge gleaned only from applicant’s disclosure, such a reconstruction is proper.” In re McLaughlin, 443 F.2d 1392, 1395, 170 USPQ 209, 212 (CCPA 1971). Thus, in order to determine whether the Examiner’s hindsight reconstruction is proper, we look to determine whether it takes account only knowledge within the ordinary skill in the art, as evidenced by the applied prior art. Yet, as we noted above, Appellants’ arguments imply that Parsons and Jones are non-analogous prior art, in that one would not have found and considered either reference in forming a BeO film. Our reviewing court has stated that “[t]wo separate tests define the scope of analogous prior art: (1) whether the art is from the same field of endeavor, regardless of the problem addressed and, (2) if the reference is not within the field of the inventor's endeavor, whether the reference still is reasonably pertinent to the particular problem with which the inventor is involved.” In re Bigio, 381 F.3d 1320, 1325 (Fed. Cir. 2004) (citations and internal quotes omitted). While these two criteria are helpful in many instances, we must not lose sight of the key question at hand: what is “prior art” as that term is used in 35 U.S.C. § 103(a)? References that are “too remote to be treated as ‘prior art’” are excluded from the obviousness analysis. In re Sovish, 769 F.2d 738, 741, 226 (Fed. Cir. 1985). The non-analogous art test provides helpful insight on the underlying question of what is “prior art” within the meaning of the statute; we should not, however, be blind to the reality of the circumstances 5 Appeal 2014-008343 Application 13/271,522 of the case before us. In re Wood, 599 F.2d 1032, 1036 (CCPA (1979). Nor should we adhere to rigid and mandatory formulas that overly limit the inquiry. KSRInt’l Co. v. Teleflex Inc., 550 U.S. 398, 419 (2007). Here, the Examiner’s findings are not in dispute. See Br. 4 (“Appellants do not here argue whether the [EJxaminer has found the elements of claim 1 in the three cited references.”). Maes teaches the metal oxide is preferably selected from a group including BeO, although Maes further discloses a subgroup of “particularly preferred oxides” which does not include BeO. Maes 2:26—31; also 3:51—58. Nonetheless, Maes does not teach BeO is a non-preferred embodiment; BeO is a preferred embodiment, but is not a particularly preferred embodiment. Further Maes teaches the oxide film may be formed by ALD using a metal precursor or source compound.7 Maes 4:10-40. As to Parsons, although Parsons does not form a BeO film, but instead uses a beryllium precursor as a source of Be dopant, Parsons is nonetheless reasonably pertinent to the particular problem with which Appellant is involved and for which the ordinary artisan seeking to implement Maes’ ALD process in forming a BeO film would be concerned, i.e., selecting a precursor compound for delivering beryllium to the reactor. Furthermore, although Jones does not form a BeO film, but instead forms films of rare earth metal oxides, Jones is also reasonably pertinent to this same problem. Jones teaches an ALD process for forming a metal oxide 7 Maes teaches a metal halide, HfCE, as an example metal precursor or source compound. Maes 4:62. Since Be has two valence electrons (as opposed to Hf’s four valence electrons), beryllium chloride, would be BeCE, or dihaloberyllium. Thus, the ordinary artisan would have found use of beryllium chloride to have been an obvious precursor compound when forming BeO films within the teaching of Maes. 6 Appeal 2014-008343 Application 13/271,522 film and includes alkyl containing metal precursor compounds for delivering the metal to the reactor. We, therefore, find that the ordinary artisan faced with the problem of selecting a beryllium precursor compound for use in Maes’ ALD process would have looked to both Parsons and Jones for guidance in that selection. As to Appellants’ hindsight reconstruction argument, we note the Examiner articulates reasoning with rational underpinning in support of the obviousness conclusion. In re Kahn, 441 F.3d 977, 988 (Fed. Cir. 2006) (“[R]ejections on obviousness grounds cannot be sustained by mere conclusory statements; instead, there must be some articulated reasoning with some rational underpinning to support the legal conclusion of obviousness.”), quoted with approval in KSR, 550 U.S. at 418. Appellants neither dispute the Examiner’s findings nor the Examiner’s articulated reasoning for combining the teachings of the applied prior art references. In addition, Appellants fail to identity in what way the Examiner has failed to fully appreciate what each of these references fairly suggest to one of ordinary skill in the art. In re Wesslau, 353 F.2d 238 (CCPA 1965). As indicated above, Appellants’ argument merely implies unpersuasively that Parsons and Jones are non-analogous prior art, e.g., “one would not look to a reduction process for guidance in devising process parameters for an oxidation.” Br. 5. Accordingly, we do not find Appellants’ improper hindsight reconstruction argument persuasive of reversible error in the Examiner’s rejection of claim 1. 7 Appeal 2014-008343 Application 13/271,522 Claim 9 Claim 9 depends from claim 1 via claim 8, and further requires that the substrate is either InGaAs or GaAs. The Examiner adds Ritala to the prior combination of Maes, Parsons, and Jones to reject claim 9. Appellants traverse this rejection only by arguing that Ritala fails to cure the deficiencies previously argued with regard to the combination of Maes, Parsons, and Jones. However, as discussed above, Appellants’ arguments with regard to the Maes, Parsons, and Jones combination fails to persuade us of reversible error. As such, this combination has no such deficiencies nor does the Examiner rely on Ritala to cure such deficiencies. Accordingly, we will also sustain the Examiner’s obviousness rejection of claim 9. DECISION Upon consideration of the record, and for the reasons given above and in the Answer, the decision of the Examiner rejecting claims 1—12 under 35 U.S.C. § 103(a) as unpatentable over the combination of Maes, Parsons, and Jones, alone or further combined with Ritala, is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1). AFFIRMED 8 Copy with citationCopy as parenthetical citation