Ex Parte Yu et alDownload PDFPatent Trials and Appeals BoardJun 13, 201914907359 - (D) (P.T.A.B. Jun. 13, 2019) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE FIRST NAMED INVENTOR 14/907,359 01/25/2016 Wanglin Yu 109 7590 06/17/2019 The Dow Chemical Company P.O. BOX 1967 2040 Dow Center Midland, MI 48641 UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 75351-US-PCT 8139 EXAMINER SUE-AKO, ANDREW B. ART UNIT PAPER NUMBER 3674 NOTIFICATION DATE DELIVERY MODE 06/17/2019 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): FFUIMPC@dow.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte WANGLIN YU and HARPREET SINGH1 Appeal2018-007670 Application 14/907,359 Technology Center 3600 Before DANIEL S. SONG, BENJAMIN D. M. WOOD, and SEAN P. O'HANLON, Administrative Patent Judges. SONG, Administrative Patent Judge. DECISION ON APPEAL STATEMENT OF THE CASE The Appellant appeals under 35 U.S.C. § 134(a) from the Examiner's Final Office Action ("Final Act.") rejecting claims 6-11 in the present application. We have jurisdiction under 35 U.S.C. §§ 6(b) and 134(a). We AFFIRM. The claimed invention is directed to a method for reducing accretion of bitumen on drilling components. Title. Representative independent claim 6 reads as follows: 1 The Appellant is the Applicant, Dow Global Technologies LLC, which is identified as the real party in interest. Appeal Brief ("App. Br.") 3. Appeal2018-007670 Application 14/907,359 6. A method for drilling a wellbore through a formation comprising the steps of: a) operating a drilling assembly to drill a wellbore; and b) circulating an aqueous-based drilling fluid through the wellbore as it is drilled, the aqueous-based drilling fluid comprising an anti-accretion additive comprising: i) from 5 to 30 parts by weight of a propoxylated alcohol of the formula: RO-(PO)x-H wherein R is a linear or branched alkyl having from 8 to 16 carbons and x is from 1 to 10 and ii) from 95 to 70 parts by weight of a propoxylated and ethoxylated alcohol of the formula: R10-(PO)y-(E'.O)z-H, wherein R 1 is a linear or branched alkyl having from 8 to 16 carbons, y is from 2 to 10, and z is from 3 to 20, wherein parts by weight is based on the combined weight of the propoxylated alcohol i and a propoxylated and ethoxylated alcohol ii and E:O and PO denote ethylene oxide and propylene oxide units, respectively. App. Br. 13 (Claims App'x). 2 Appeal2018-007670 Application 14/907,359 ANALYSIS Only those arguments actually made by the Appellant have been considered in this decision. Arguments that the Appellant could have made but chose not to make have not been considered and are deemed to be waived. See 37 C.F.R. § 41.37(c)(l)(iv); In re Jung, 637 F.3d 1356, 1365-66 (Fed. Cir. 2011); Ex parte Frye, 94 USPQ2d 1072, 1075-76 (BPAI 2010 (precedential)). The Examiner rejects claims 6-11 under 35 U.S.C. § 103 as obvious over Stoian et al. (US 2011/0281777 Al, pub. Nov. 17, 2011 ("Stoian")) in view of Hoffarth (US 5,705,476, iss. Jan. 6, 1998). Final Act. 3. The Examiner finds that Stoian discloses a method for drilling a wellbore substantially as claimed, including a propoxylated and ethoxylated alcohol as recited in limitation "ii)" of claim 6. Final Act. 3 ( citing Stoian ,i 41, Table 1 ). The Examiner states that Stoian "does not provide further detail" which would allow determination of whether ethoxylated and propoxylated alcohols that limit accretion via water wetting have the claimed degrees of propoxylation (y) and ethoxylation (z). Final Act. 3. The Examiner concludes that it would have been obvious to a person of ordinary skill in the art to derive, by routine experimentation, the optimal or workable ranges for the propoxylated and ethoxylated alcohol, wherein "y" is from 2 to 10, and "z" is from 3 to 20. Final Act. 4. In that regard, the Examiner further finds that Hoffarth discloses non-ionic ethoxylated propoxylated alcohol surfactants with water wetting, detergent characteristics ... includ[ ing] those with these [ claimed] degrees of propoxylation and ethoxylation, [Hoffarth] describing ethoxylated propoxylated alcohol wetting agents with y = 1-10 and z = 1-10 ( abstract, "(le)") such as "J) 3 Appeal2018-007670 Application 14/907,359 2-ethylhexanol+8 P0+6 EO" (i.e., y = 8; z = 6) (Col. 4, line 52). Final Act. 4 ( emphasis omitted). As to limitation "i)" of claim 6, the Examiner finds that Stoian discloses "non-ionic surfactants that may be useful in a drilling fluid" to "limit tar sand accretion to metal surfaces" via its "water wetting, detergent characteristics," but that Stoian again does not specify if surfactants "include known/commercially available propoxylated alcohols." Final Act. 4. However, the Examiner further finds that Hoffarth discloses "a 'low-foaming' 'wetting' agent" having propoxylated alcohol and propoxylated and ethoxylated alcohol, and further discloses the proportions thereof, and x, y, and z values within the ranges recited in the claims, which provide "water-dispersible wetting agents distinguished by their low-foaming characteristics." Final Act. 4-5. Indeed, Hoffarth discloses a low-foaming wetting agent consisting of 30 to 90% by weight, substance of the formula "(le)," and 70 to 10% by weight, substance of formula "(II)," these formulas corresponding to the recited formulas R10-(PO)y-(EO)z-H, and RO-(PO)x-H of the claims, respectively. Compare Hoffarth Abstract, with appealed claim 6. The Examiner concludes that it would have been obvious to a person of ordinary skill in the art to have used such known non-ionic surfactants having the claimed mixture of propoxylated alcohol, and propoxylated and ethoxylated alcohol "with 'water wetting' and 'low foaming' characteristics (as in Stoian and Hoffarth)" during drilling of well bores in order to "'limit tar sand accretion to metal surfaces' (as in Stoian)," and to realize "'advantages and simplifications when preparing the wetting agents' by 4 Appeal2018-007670 Application 14/907,359 including 'water-dispersible wetting agents distinguished by their low-foaming' with pure propoxylates (as in Hoffarth)." Final Act. 5. The Examiner further explains that the modification is obvious as no more than the use of familiar elements (known low-foaming wetting agents) according to known techniques (known drilling with non-ionic surfactants) in a manner that achieves predictable results (known reduction of tar/bitumen accretion). Final Act. 6. We agree with the Examiner's conclusion and address the Appellant's arguments below. The Appellant argues that "Hoffarth discloses low-foaming wetting agents ... for aqueous liquids used in textile processes, in particular to improve dying processes, formulating crop protection agents, and the like," but fails to teach or suggest use as an anti-accretion additive and/or "in a drilling fluid for the use in a wellbore of an oil well." App. Br. 7; see also id. at 9 (quoting Hoffarth, col. 4, 11. 10-24). This argument is unpersuasive because although Hoffarth provides example uses for the disclosed agent (such as in dying and crop protection), Hoffarth is clearly not limited thereto, and broadly discloses a low-foaming wetting agent without limiting it to specific uses. See, e.g., Hoffarth, Title; col. 1, 11. 10-16, 32-41, 45-46; col. 1, 1. 45-col. 2, 1. 19; claim 1. The Appellant also argues that Stoian discloses nonionic surfactants with capped alcohol ethoxylate, and does not disclose (i) the structure of the uncapped-propoxylated and ethoxylated alcohol, specifically a (PO) block, (EO) block copolymer with the (PO) block reacted on to the alcohol, (ii) that it should be mixed with a propoxylated alcohol, (iii) the structure of the 5 Appeal2018-007670 Application 14/907,359 propoxylated alcohol, or (iv) the weight ratio of these two alcohols in the composition. App. Br. 8. This argument is unpersuasive for various reasons. First, Stoian actually discloses that "[ s Jome useful nonionic surfactants include capped or branched alcohol ethoxylate, such as for example ethoxylated alcohols, ethoxylated propoxylated alcohols, etc." Stoian ,i 11; see also id. ,i 16. Thus, as the Examiner points out (Ans. 5), Stoian also discloses "branched" alcohol ethoxylate which is encompassed by the claimed non-ionic surfactants, for example, claim 6 reciting "linear or branched alkyl." This portion of Stoian' s disclosure is overlooked by the Appellant. Second, as the Examiner also points out, the specific surfactants "are provided by Hoffarth, not Stoian. Therefore, this difference between 'capped' surfactants and the claimed surfactants appears moot, and the 'capped' evidence does not indicate nonobviousness." Ans. 5. Third, as noted above, Hoffarth discloses an agent having a chemical composition satisfying the limitations of claim 6. The Appellant argues that it is not possible to apply Hoffarth with "Stoian' s broadly disclosed capped or branched alcohol ethoxylate and capped-ethoxylated propoxylated alcohols to arrive at Applicant's anti accretion composition." App. Br. 10. However, this assertion is not substantiated by any reasoning, and the evidence of record indicates the contrary, considering Hoffarth discloses an agent with both propoxylated alcohol, and ethoxylated and propoxylated alcohol together. As the Examiner notes, the Appellant has not established any "technical incompatibility." Ans. 5. 6 Appeal2018-007670 Application 14/907,359 The Appellant argues that there is no teaching in Stoian to alter its composition (App. Br. 10), and as to Hoffarth, argues that There is no hint of suggestion or teaching that either ( 1) his low-foaming wetting agent would act as anti-accretion agents and/or (2) that his low-foaming wetting agent would have any usefulness in the drilling of a well bore. Applicant respectfully assets that there is NO reason one skilled in the art would think to combine Hoffarth's low-foaming wetting agent with Stoian' s drilling method to arrive at Applicant's present invention. App. Br. 9. However, although the Appellant appears to imply that an explicit teaching or suggestion in the art for the suggested combination or modification is required, such explicit teaching is not required. KSR Int 'l v. Teleflex, Inc., 550 U.S. 398, 418-19 (2007) ("the analysis need not seek out precise teachings directed to the specific subject matter of the challenged claim" and "obviousness analysis cannot be confined ... by overemphasis on the importance of published articles and the explicit content of issued patents."). Indeed, what is required is "some articulated reasoning with some rational underpinning to support the legal conclusion of obviousness." Id. at 418 ( quotation marks and citation omitted). The Examiner has provided such reasoning as set forth above, i.e., to "'limit tar sand accretion to metal surfaces' (as in Stoian)," and to realize "'advantages and simplifications when preparing the wetting agents' by including 'water- dispersible wetting agents distinguished by their low-foaming' with pure propoxylates (as in Hoffarth)" (Final Act. 5), and further, that the modification is obvious as no more than the use of familiar elements (known low-foaming wetting agents) according to known techniques (known drilling with non-ionic surfactants) 7 Appeal2018-007670 Application 14/907,359 in a manner that achieves predictable results (known reduction of tar/bitumen accretion). Final Act. 6; see also KSR, 550 U.S. at 415-16. ("The combination of familiar elements according to known methods is likely to be obvious when it does no more than yield predictable results.")). As the Examiner notes, the Appellant does not address the rationales provided by the Examiner as set forth in the Final Office Action to support the obviousness rejection. Ans. 4-5 (quoting Final Act. 5, 6). The Appellant further argues that there is no disclosure in the art that "making such a change [to Stoian] would solve the problem of providing an improved anti-accretion additive with good biodegradability and low aquatic toxicity" (App. Br. 10), and that these benefits are demonstrated by the examples set forth in the Specification (App. Br. 8-9). However, we agree with the Examiner that "Stoian in view of Hoffarth provides all claimed elements," and that the "Appellant's data merely demonstrates that a mixture of two nonionic surfactants prevents more oil from sticking than just one nonionic surfactant. This effect is well-known in the art, as with other types of detergents/soaps." Ans. 6 ( emphasis omitted). As to the asserted biodegradability and low toxicity, we also agree with the Examiner that because "Hoffarth provides the same composition as claimed, the surfactants, if subjected to testing, would act in the same manner as claimed." Ans. 6. In that regard, we also agree with the Examiner that "the fact that Appellant has recognized another advantage which would flow naturally from following the suggestion of the Prior Art cannot be the basis for patentability when the differences would otherwise be obvious." Ans. 6. 8 Appeal2018-007670 Application 14/907,359 The Appellant further argues that there is no reason to combine Hoffarth with Stoian in the manner suggested because Hoffarth does not suggest which of the three disclosed alcohols, Ia, lb, or le, "is a better low-foaming wetting agent," and "would be the preferred anti-accretion agent for an aqueous based drilling fluid." App. Br. 9-10. This argument is also unpersuasive for various reasons. First, the fact that Hoffarth does not disclose which of the alcohols are better does not detract from the fact that the propoxylated and ethoxylated alcohol claimed is explicitly disclosed in Hoffarth. Second, as noted by the Examiner, "there is no claimed degree of 'anti-accretion."' Ans. 6. As such, it is not material that one of the three alcohols of Hoffarth may be superior to the others. Finally, the Appellant argues that in contrast to claim 6, which requires that the propoxylated alcohol is present in an amount of "5 to 30 parts by weight" and that the propoxylated and ethoxylated alcohol is present in an amount of "from 95 to 70 parts by weight"[,] Hoffarth requires that the propoxylated alcohol is present in an amount of "67 to 33 parts by weight" and that the propoxylated and ethoxylated alcohol is present in an amount of "from 3 0 to 60 parts by weight". App. Br. 10. However, it is not apparent where these weighed values are disclosed in Hoffarth. To the extent that the Appellant may be referring to claim 1 of Hoffarth, which claims 30 to 67% propoxylated and ethoxylated alcohol, and 67 to 33% propoxylated alcohol, the Appellant overlooks the broader scope of Hoffarth's disclosure. Hoffarth clearly discloses 30 to 90% propoxylated and ethoxylated alcohol, and 70 to 10% propoxylated alcohol. Hoffarth Abstr.; col. 1, 1. 45-col. 2, 1. 19. Thus, as the Examiner explains, 9 Appeal2018-007670 Application 14/907,359 Hoffarth discloses the weight proportions in the recited range of the claims. Ans. 4. Therefore, in view of the above considerations, we are not persuaded of Examiner error in rejecting claim 6. The Examiner relies on similar reasoning in rejecting independent claims 7 and 8. Final Act. 6-7. These claims fall for the same reasons discussed above relative to claim 6. The Appellant does not submit any separate arguments directed to multi-dependent claims 9-11. Accordingly, these dependent claims fall with independent claims 6-8. CONCLUSIONS The Examiner's rejection of claims 6-11 is AFFIRMED. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § l .136(a). See 37 C.F.R. § l.136(a)(l )(iv). AFFIRMED 10 Copy with citationCopy as parenthetical citation