Ex Parte Wuister et alDownload PDFPatent Trial and Appeal BoardJul 15, 201611889213 (P.T.A.B. Jul. 15, 2016) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 111889,213 08/09/2007 909 7590 07119/2016 Pillsbury Winthrop Shaw Pittman, LLP (NV) PO Box 10500 McLean, VA 22102 FIRST NAMED INVENTOR Sander Frederik Wuister UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 081468-0362916 9991 EXAMINER COLEMAN, RY AN L ART UNIT PAPER NUMBER 1714 NOTIFICATION DATE DELIVERY MODE 07/19/2016 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address( es): docket_ip@pillsburylaw.com heather.marthers@pillsburylaw.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte SANDER FREDERIK WUISTER, V ADIM YEVGENYEVICH BANINE, and MAARTEN MARINUS JOHANNES VAN HERPEN Appeal2015-002227 Application 11/889,213 Technology Center 1700 Before: ROMULO H. DELMENDO, N. WHITNEY WILSON and AVEL YN M. ROSS, Administrative Patent Judges. ROSS, Administrative Patent Judge. DECISION ON APPEAL 1 Appellants2 appeal under 35 U.S.C. § 134(a) from a rejection of claims 1--4, 6, 7, 9--25, 29, and 30. We have jurisdiction under 35 U.S.C. § 6(b ). We AFFIRM. 1 In our decision below, we refer to the Final Office Action appealed from, mailed May, 9, 2014 (Final Act.), the Appeal Brief filed October 3, 2014 (Appeal Br.), the Examiner's Answer mailed November 3, 2014 (Ans.), and the Reply Brief filed December 31, 2014 (Reply Br.). 2 Appellants identify the real party in interest as ASML Netherlands, B.V. Appeal Br. 2. Appeal2015-002227 Application 11/889,213 STATEMENT OF CASE The claims are directed to cleaning methods, and in particular, methods for cleaning imprint lithography templates. Spec. i-f l. Claim 1, reproduced below, is illustrative of the claimed subject matter: 1. A method of cleaning an imprint template at least partially formed from glass, fused silica or quartz, the method comprising: exposing the imprint template to a reductive fluid that causes reduction of material on the imprint template; and exhausting gaseous reaction products formed during the reduction of the material from a vicinity of the imprint template. Claims Appendix at Appeal Br. 11. REJECTIONS The Examiner made the following rejections: A. Claims 1--4, 6, 7, 9-13, 20-25, 29, and 30 stand rejected under 35 U.S.C. § 103(a) as being unpatentable over Dibiase3 in view of Muranaka, 4 and in view of Sandhu. 5 Final Act. 3. B. Claims 15-17 stands rejected under 35 U.S.C. § 103(a) as being unpatentable over Dibiase in view of Muranaka, in view of Sandhu, and in further view of Yabuta. Id. at 7. C. Claim 14 stands rejected under 35 U.S.C. § 103(a) as being unpatentable over Dibiase in view of Muranaka, in view of Sandhu and in further view ofVadim. Id. at 9. 3 Dibiase, US 7 ,846,266 B 1, issued December 7, 2010 (hereinafter "Dibiase"). 4 Muranaka et al., US 6,410,454 B 1, issued June 25, 2002 (hereinafter "Muranaka"). 5 Sandhu et al., US 2003/0102008 Al, published June 5, 2003 (hereinafter "Sandhu"). 2 Appeal2015-002227 Application 11/889,213 D. Claims 18 and 19 stand rejected under 35 U.S.C. § 103(a) as being unpatentable over Dibiase in view of Muranaka in view of Sandhu (as applied to claim 1) and further in view of Freriks. Id. at 10. Appellants seek our review of Rejections A-D. But, Appellants argue only independent claim 1 and do not present any arguments for claims 2--4, 6, 7, 9-13, 20-25, 29, and 30 separate from what is argued for claim 1. Appeal Br. 7-9. Therefore, we focus our discussion on Rejection A, and in particular, claim 1 to resolve the issues on appeal. OPINION The Examiner rejects claim 1 (among others) under 3 5 U.S. C. § 1 0 3 (a) as being unpatentable over Dibiase in view of Muranaka, and in view of Sandu. Final Act. 3. The Examiner finds that the combination of Dibiase, Muranaka and Sandu teach all aspects of the claimed invention. Id. at 3-5. The Examiner further finds that one skilled in the art would have been motivated to modify the method of Dibiase by using the hydrogen radical cleaning method of Muranaka to remove the organic residue from the imprint lithography template. The motivation for performing the modification was provided by Muranaka, who teaches that his hydrogen radical cleaning method can advantageously remove undesired organic from a surface .... Id. at 4. Moreover, the Examiner finds that the skilled artisan would be motivated to include Sandhu in the combination of Dibiase and Muranaka because adding a pump to remove gaseous products would "prevent the gaseous reaction products from becoming undesirably deposited on the template after they are formed." Id. at 5. The Examiner reasons that this is consistent with Sandhu's teachings "that when a surface is being cleaned by 3 Appeal2015-002227 Application 11/889,213 reacting surface contaminants with activated reactive species that have been formed by the dissociation of a precursor gas, a pump can advantageously be used to remove the resulting gaseous products from the vicinity of the treated surface." Id. Appellants do not dispute that the Examiner's recited combination meets the limitations of claim 1; rather, Appellants argue that the Examiner's reasons for combining the references are not sufficient to sustain the obviousness rejection. Appeal Br. 6. First, Appellants assert that no reason exists to combine Dibiase to include the surface cleaning method of Muranaka because Dibiase "already discloses (and claims) methods for removing contaminants from the template" and the combination "would change the principle of operation of Dibiase." The Examiner finds that "Dibiase teaches that a template contaminated can be cleaned by using energized gaseous species to remove organic residue." Ans. 11. Therefore, finds the Examiner, "it would have been obvious ... to modify the method of Dibiase by using the hydrogen radical cleaning method of Muranaka to remove organic residue from the imprint lithography plate because Muranaka teaches that his hydrogen radical cleaning method can advantageously remove undesired organic [sic] from a surface." Id. The Examiner also finds that neither Muranaka nor Sandhu changes the principle of operation of Dibiase. Ans. 12-13. The Examiner explains that Dibiase teaches using 0 2 or 0 3 plasma to remove organic residue while Muranaka teaches using activated hydrogen gas to remove organic residue. Id. at 12. Therefore, using the activated gas of Muranaka in the method of Dibiase to remove surface organics from the surface of an imprint lithography template does not change the principle of 4 Appeal2015-002227 Application 11/889,213 operation. Id. at 12-13. Moreover, applying the pump of Sandhu to remove the gas reaction products from the surface of the template does not change the principle of operation of Dibiase. Id. 13-14. We agree with the Examiner and adopt the Examiner's findings and reasomng as our own. We add the following for emphasis. We understand Appellants argue that Dibiase discloses the method of rinsing the template with oxygenated or hydrogenated DI water and exposure to a reactive plasma to remove organic contaminant and also coating film of a water soluble polymer [is formed] on the template and then peeling off the coating film and removing organic residue from the film using oxygenated plasma" and that it is this operation which does not take place in the combination of Dibiase and Muranaka. Appeal Br. 6. We find that the cleaning method employing the "peeling step" of Dibiase is an alternative embodiment (see col. 3, 11. 1-3 (description of Fig. IB)) and the specification teaches embodiments that do not include the "peeling step" yet still utilize a reactive gaseous species to clean the surface of the template. See Fig. IA and col. 3, 11. 22-20 (describing a cleaning method of Fig. 1 A without a "peeling step")), and compare col. 6, 11. 60-col. 7, 11. 4 (claim 1) to col. 7, 11. 15-21 (claim 7). Thus, because both Dibiase and Muranaka teach removal of organic debris from a surface using activated gaseous species, we are not persuaded by Appellants' principle of operation argument. We also agree with the Examiner, for the reasons stated in the Answer, that Sandhu does not change the principle of operation for Dibiase. 6 Ans. 6. Sandhu is germane for teaching a pump to exhaust 6 Appellants do not specify which reference, Muranaka or Sandhu, changes the principle of operation of Dibiase. Appeal Br. 6. 5 Appeal2015-002227 Application 11/889,213 gaseous reaction products away from the template so that the reaction products are not deposited on the template. Id. And, modifying the teachings of Dibiase to include a pump does not change the principle of operation for Dibiase. Second, Appellants contend that no motivation is provided to include Sandhu in the combination of Dibiase and Muranaka because "Sandhu does not characterize the pump as providing an advantage." Appeal Br. 6. The Examiner, however, finds that Sandhu teaches that when a surface is being cleaned by reacting surface contaminants with activated reactive species that have been formed by the dissociation of a precursor gas, a pump (item 34 in Figure 2) can be used to remove the resulting gaseous products (that is, the products formed from the reactions between the targeted contaminants and the activated species) from the vicinity of the treated surface (Par. 0021-0024 and 0040-0045). Ans. 14. Therefore, the Examiner concludes that one skilled in the art would have found it obvious to modify Dibiase and Muranaka to include a pump to withdraw gaseous reaction byproducts from the surface of the template. Id. at 14--15. We agree with the Examiner. One of ordinary skill can use his or her ordinary skill, creativity, and common sense to make the necessary adjustments and further modifications to result in a properly functioning device. See KSR Int'! Co. v. Teleflex Inc., 550 U.S. 398, 418 (2007) ("a court can take account of the inferences and creative steps that a person of ordinary skill in the art would employ"). "[I]f a technique has been used to improve one device, and a person of ordinary skill in the art would recognize that it would improve similar devices in the same way, using the technique is 6 Appeal2015-002227 Application 11/889,213 obvious unless its actual application is beyond his or her skill." See id. at 417. Here, as the Examiner correctly finds (Ans. 14), Sandhu teaches that the products resulting from the reaction of the active gaseous species and the surface of the wafer can be exhausted to control the surface treatment and atmosphere. Sandhu i-fi-126, 32, and 44. Thus, like the Examiner, we conclude that a person skilled in the art would have reason to modify the method of Dibiase and Muranaka-using no more than ordinary skill, creativity, and common sense-to provide a pump to withdraw the gaseous reaction products from the surface of the template to prevent deposition on the surface. Id. at 14--15. That Sandhu does not expressly characterize the withdrawal of gaseous reaction products as "advantageous" does not mean that it is not in fact an advantage, as Appellants suggest. The skilled artisan would have reason to utilize the pump of Sandhu in the Dibiase/Muranaka method for the same purpose as used in Sandhu and would have reason to expect the same result. KSR, 550 U.S. at 417. We conclude that the skilled artisan would have found the Appellants' invention obvious in light of the combined teachings of Dibiase, Muranaka and Sandhu. In reply, Appellants present three additional arguments not considered by the Examiner and none of which we find persuasive of reversible error. 7 7 The Reply Brief contains a new arguments which could have been but were not presented in the Appeal Brief. Under regulations governing appeals to the Board, a new argument not timely presented in the Appeal Brief will not be considered when filed in a Reply Brief, absent a showing of good cause explaining why the argument could not have been presented in the Appeal Brief. Cf Ex parte Borden, 93 USPQ2d 1473, 1477 (BPAI 2010) (informative) ("Properly interpreted, the Rules do not require the Board to 7 Appeal2015-002227 Application 11/889,213 Appellants begin by contending the Examiner engaged in improper hindsight reconstruction. Reply Br. 3--4. Appellants urge Dibiase teaches "dry cleaning the template with a reactive plasma containing 0 2 or 0 3, forming a coating film" and then peeling the film off of the template to remove the residue. Reply Br. 3. And, according to Appellants, "Muranaka does not disclose, teach, or remotely suggest that its method of removing contaminants on the surface of a semiconductor wafer in a film-forming ... process is suitable to clean imprint templates." Reply Br. 4. Appellants further argue that while Muranaka does teach use of hydrogen radicals, "Muranaka is clearly referring to the use of etching to clean the surface of a semiconductor wafer in the prior art." Id. Therefore, say Appellants, no motivation (in the absence of hindsight) exists for the combination. We disagree. Dibiase clearly teaches that optical surfaces, such as imprint templates, semiconductor swfaces and photomasks need to be cleaned to remove organic residue. Dibiase, col. 2, 11. 16-27. Muranaka teaches the removal of organic residue from wafer surfaces. Muranaka, col. 4, 11. 50-col. 5, 11. 13 and col. 10, 11. 4--6 and 15-19. Both Dibiase and Muranaka utilize gaseous radicals for the removal of the unwanted organics from surfaces. Dibiase col. 2, 11. 45-59 and Muranaka, col. 4, 11. 50-col. 5, 11. 13. The Examiner finds that "[ t ]he motivation for performing the modification was provided by Muranaka who teaches that his hydrogen radical cleaning method can advantageously remove undesired organic from take up a belated argument that has not been addressed by the Examiner, absent a showing of good cause."), as well as 3 7 C.F .R. § 41.3 7 and § 41.41. Because the record contains no such showing, these new arguments are ineffective in this appeal. However, we briefly discuss why, if timely-filed and considered, these arguments would not be persuasive of reversible error. 8 Appeal2015-002227 Application 11/889,213 a surface." Final Act. 4. Thus, we observe no evidence of improper hindsight in this analysis. Appellants next argue that if it is so obvious to use a reductive fluid and exhaust the gaseous reaction products then why did Dibiase not disclose such an embodiment earlier. Reply Br. 5. We again disagree. Appellants seem to argue for an elevated obviousness standard, i.e., one that rises to the level of anticipation. No such heightened requirement exists and Appellants argument is unconvincing. Finally, Appellants argue that because Muranaka and Sandhu do not teach an "environmentally friendly" method to remove contaminants these references are not suitable for the intended purpose of Dibiase. Reply Br. 6. We are not persuaded as Appellants have not established the proposed change would result in such a change that renders Dibiase unsuitable for its intended purpose such that it would make the claimed invention nonobvious. "Counsel's argument cannot take the place of evidence lacking in the record." Estee Lauder Inc. v. L 'Orea!, S.A., 129 F.3d 588, 595 (Fed. Cir. 1997). Moreover, Dibiase criticizes conventional methods of contaminant removal, i.e., "wet chemical cleaning" methods, because such methods often "involve[] hazardous and corrosive chemicals that must be disposed somehow." Dibiase, col. 2, 11. 6-15. It is the disposal of these chemicals that "presents [the] environmental hazard" Dibiase seeks to overcome. Id. Similarly, Muranaka criticizes wet cleaning methods, albeit for different reasons. Muranaka, col. 1, 11. 34--49. The solutions of both Dibiase and Muranaka avoid wet cleaning methods in favor of using reactive gaseous species to remove organic contaminants. Dibiase, col. 6, 11. 33--42 and Muranaka, col. 1, 11. 61---65. Appellants do not explain how Muranaka 9 Appeal2015-002227 Application 11/889,213 would have any negative effect on the "environmental friendliness" of Dibiase. Nor have Appellants explained how the addition of Sandhu- teaching use of pump to remove reaction products-would render the Dibiase unsuitable for its intended purpose. Accordingly, we are unconvinced the proposed combination renders Dibiase unsuitable for its intended purpose. CONCLUSION The Examiner did not reversibly err in rejecting claims 1--4, 6, 7, 9-- 25, 29, and 30 as unpatentable under 35 U.S.C. § 103(a) DECISION For the above reasons, the Examiner's rejection of claims 1--4, 6, 7, 9-- 25, 29, and 30 is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(l )(iv) (2009). AFFIRMED 10 Copy with citationCopy as parenthetical citation