Ex Parte WhiteDownload PDFBoard of Patent Appeals and InterferencesJan 24, 201210990185 (B.P.A.I. Jan. 24, 2012) Copy Citation UNITED STATES PATENT AND TRADEMARKOFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 10/990,185 11/16/2004 John M. White APPM/9451/DISPLAY/AKT/RKK 4941 44257 7590 01/25/2012 PATTERSON & SHERIDAN, LLP - - APPM/TX 3040 POST OAK BOULEVARD, SUITE 1500 HOUSTON, TX 77056 EXAMINER GAMBETTA, KELLY M ART UNIT PAPER NUMBER 1715 MAIL DATE DELIVERY MODE 01/25/2012 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE BOARD OF PATENT APPEALS AND INTERFERENCES ____________ Ex parte JOHN M. WHITE ____________ Appeal 2010-003827 Application 10/990,185 Technology Center 1700 ____________ Before CHUNG K. PAK, TERRY J. OWENS, and PETER F. KRATZ, Administrative Patent Judges. PAK, Administrative Patent Judge. DECISION ON APPEAL Appellant appeals under 35 U.S.C. § 134(a) from the Examiner’s refusal to allow claims 9, 11, 12, 14, 15, 17, 19 through 21, 39, 41 through 43, 45, 46, and 52 through 60, all of the pending claims in the above- identified application.1 We have jurisdiction under 35 U.S.C. § 6. 1 See Appeal Brief (“App. Br.”) filed June 24, 2009, 5-6; Response to Notification of Non-Compliant Appeal Brief filed August 12, 2009, 3-4; and Examiner’s Answer (“Ans.”) filed October 20, 2009, 2. Appeal 2010-003827 Application 10/990,185 2 STATEMENT OF THE CASE The subject matter on appeal is directed to a method of forming a gate dielectric layer for use in thin film transistors (Spec. 4-5, paras. 0007-0013). Details of the appealed subject matter are recited in representative claim 9 reproduced from the Claims Appendix to the Appeal Brief, as shown below: 9. A method of forming a gate dielectric layer on a substrate, comprising: forming a semiconductor layer comprising silicon on a transparent substrate; preheating the transparent substrate to a first temperature; transferring the transparent substrate into a chemical vapor deposition plasma processing chamber; moving the transparent substrate to a first plasma processing region of the plasma processing chamber; flowing an oxidizing gas mixture into the plasma processing chamber and generating an inductively coupled high density plasma in the first plasma processing region at a substrate surface temperature of no more than about 550°C to form an oxidized layer on the semiconductor layer; moving the substrate to a second plasma processing region of the plasma processing chamber; forming a dielectric layer on the oxidized layer to form a gate dielectric layer, wherein at least a portion of the dielectric layer is formed while the transparent substrate is positioned at the second plasma processing region of the plasma processing chamber; and Appeal 2010-003827 Application 10/990,185 3 annealing the transparent substrate at a second temperature after forming the dielectric layer. As evidence of unpatentability of the claimed subject matter, the Examiner relies on the following prior art references at pages 2 and 3 of the Answer: Ikeda US 5,508,540 Apr. 16, 1996 Sandhu US 5,599,396 Feb. 4, 1997 Kawakami US 6,399,520 B1 June 4, 2002 Derwent Abstract on DE 29815132 published on Jan. 28, 1999, Hoffman et al. (2007) (hereinafter referred to as “Hoffman”).2 Appellant seeks review of the Examiner’s rejection of claims 9, 11, 12, 14, 15, 17, 19 through 21, 39, 41 through 43, 45, 46, and 52 through 60 under 35 U.S.C. § 103(a) as unpatentable over the combined disclosures of Kawakami, Ikeda, Sandhu, and Hoffman. RELEVANT FACTUAL FINDINGS, PRINCIPLES OF LAW, ISSUE, ANALYSIS AND CONCLUSION Appellant does not dispute the Examiner’s finding that Kawakami discloses a method of forming a gate insulator (corresponding to the claimed gate dielectric layer) on a substrate, comprising forming a semiconductor layer comprising silicon on a substrate, inclusive of a known transparent substrate, as evidenced by Hoffman, preheating the transparent substrate to a first temperature, transferring or moving the substrate into a first plasma processing chamber (32), flowing an oxidizing gas mixture into the first plasma processing chamber at a temperature less than 550oC and generating 2 Appellant does not argue that the content of the Derwent Abstract is not available as “prior art”. (See generally App. Br. and Reply Br.) Appeal 2010-003827 Application 10/990,185 4 a high density plasma containing oxygen with a microwave power supply to oxidize and form a silicon oxynitride insulating layer3 (a first dielectric layer), transferring or moving the resulting substrate to a second plasma processing chamber (33), and forming a silicon nitride insulating layer (a second dielectric layer corresponding to the claimed dielectric layer) on the silicon oxynitride layer via chemical vapor deposition (CVD). (Compare Ans. 4-5 with App. Br. 15-22 and Reply Br. 2-3.) Nor does Appellant dispute the Examiner’s determination that it would have been obvious to anneal the silicon nitride insulation layer (dielectric layer) deposited substrate from the method taught by Kawakami at a second temperature, with a reasonable expectation of successfully reducing the number of dangling bonds in the layer. (Compare Ans. 5 with App. Br. 15-22 and Reply Br. 2-3.) Rather, Appellant contends that Kawakami does not teach or suggest employing a single chemical vapor deposition processing chamber having first and second plasma processing regions to form its oxidized and dielectric layers. (See App. Br. 15-22 and Reply Br. 2-3.) Appellant also contends that one of ordinary skill in the art would not have been led to employ the inductively coupled high density plasma taught by Sandhu to produce the silicon oxynitride or silicon oxide dielectric layer in the method suggested by Kawakami and Ikeda. (See Id.) 3 Appellant does not argue that the silicon oxynitride insulating layer taught by Kawakami is not an oxidized layer. (See App. Br. 15-22.) Moreover, Appellants acknowledge at page 16 of the Appeal Brief that Kawakami teaches silicon oxide or silicon oxynitride layer can be deposited as a gate insulating (dielectric) layer and that Ikeda teaches a silicon oxide layer as a known gate insulating (dielectric) layer. Appeal 2010-003827 Application 10/990,185 5 Thus, the dispositive question raised by the Examiner and Appellants is: Has the Examiner reversibly erred in determining that one of ordinary skill in the art, armed with the knowledge of Kawakami, Ikeda, Hoffman, and Sandhu would have been led to employ the inductively coupled high density plasma taught by Sandhu in the first plasma processing region of a chemical vapor deposition processing chamber to form its gate silicon oxynitride or silicon oxide insulating (first dielectric) layer corresponding to the claimed oxidized layer and then form its gate silicon nitride insulating (second dielectric) layer corresponding to the claimed dielectric layer in the second plasma processing region of the chemical vapor deposition processing chamber within the meaning of 35 U.S.C. § 103(a)? On this record, we answer this question in the negative. As correctly found by the Examiner at pages 4 and 5 of the Answer, Kawakami impliedly or expressly discloses using either a cluster having first and second plasma processing chambers or a single chamber having first and second plasma processing regions, to form its gate silicon oxynitride insulating (first dielectric) layer corresponding to the claimed oxidized layer and gate silicon nitride insulating (second dielectric) layer corresponding to the claimed dielectric layer. (Compare Ans. 3-4 with App. Br. 19) In particular, Kawakami teaches using a plasma processing unit (32) for generating a microwave “high density plasma” for depositing a gate insulating silicon oxynitride layer (an oxidized dielectric layer) and a chemical vapor deposition (CVD) processing unit (33) for depositing a second gate insulating silicon nitride layer (claimed dielectric layer). (See col. 6, ll. 3-19.) Kawakami also teaches that “both of these units for plasma processing 32 and CVD processing 33 can be replaced by a single chamber Appeal 2010-003827 Application 10/990,185 6 unit for plasma enhanced CVD processing.” (See id.at ll. 24-26) Implicit in this teaching of Kawakami is that the single chamber having two different plasma generating regions can be used to replace two plasma chambers for doing the same since a different dielectric layer is produced from a different location and two plasma generating chambers connote two different regions or locations.4 KSR Int’l Co. v. Teleflex Inc., 550 U.S. 398, 418 (2007) (“[A]nalysis [of whether the subject matter of a claim would have been obvious under § 103] need not seek out precise teachings directed to the specific subject matter of the challenged claim, for a court can take account of the inferences and creative steps that a person of ordinary skill in the art would employ.”); In re Preda, 401 F. 2d 825, 826 (CCPA 1968) (In determining what a reference discloses, “it is proper to take into account not only specific teachings of the reference but also the inferences which one skilled in the art would reasonably be expected to draw therefrom.”) Although Kawakami does not mention using an inductively coupled high density plasma to form its first (silicon oxynitride) dielectric layer, Sandhu teaches, at column 1, lines 10-18 and 32-48 and column 2, lines 5- 25, that its high density chemical vapor deposition plasma can be used to deposit a layer, including a dielectric film, onto a workpiece (substrate) or fill high aspect ratio spaces and can be formed by an inductive coil placed on 4 Note also that for a single chamber to replace two different chambers to produce two different plasmas as required by Kawakami, the single chamber must have either one plasma processing region for producing two different plasmas or two plasma processing regions for producing two different plasmas. In other words, one of ordinary skill in the art would have readily envisaged the single chamber having two plasma processing regions from the teachings of Kawakami due to the limited options for producing two different plasmas in a single chamber. Appeal 2010-003827 Application 10/990,185 7 the outside of a chemical vapor deposition chamber via inductively ionizing the deposition gases (plasmas). Sandhu, like Kawakami, teaches using a high density plasma to deposit a dielectric layer. Id. Given the above teachings, we concur with the Examiner that one of ordinary skill in the art, armed with the knowledge of Kawakami, Ikeda, Hoffman, and Sandhu would have been led to employ an inductive coil or microwave generating means on the first plasma processing region of the chemical vapor deposition chamber to generate a high density plasma (inductively coupled high density plasma) to deposit a silicon oxynitride insulating (first dielectric) layer prior to depositing the silicon nitride insulating (second dielectric) layer via generating a regular high density chemical vapor deposition plasma from the second plasma processing region of the same chemical vapor deposition chamber. In other words, the use of one known high density plasma generating means for depositing a dielectric layer, in lieu of another high density plasma generating means for doing the same, would have been obvious to one of ordinary skill in the art. KSR, 550 U.S. at 417 (quoting Sakraida v. Ag Pro, Inc., 425 U.S. 273, 282 (1976)(“[W]hen a patent ‘simply arranges old elements with each performing the same function it had been known to perform’ and yields no more than one would expect from such an arrangement, the combination is obvious.”); In re Mayne, 104 F.3d 1339, 1340 (Fed. Cir. 1997) (noting that the substitution of one known element for a known equivalent is prima facie obvious). Appellant appears to contend that Kawakami’s statement regarding the use of a single chamber is not sufficiently enabling. (See App. Br. 19.) However, Appellant has not demonstrated that the disclosure of Kawakami, Appeal 2010-003827 Application 10/990,185 8 coupled with information known in the art, would not enable one of ordinary skill in the art to make and use of a single chamber having two plasma processing regions. In particular, Appellant has not shown that one of ordinary skill in the art would not have been able to make or use a single chamber comprising one region having an inductive coil for producing an inductively coupled high density plasma and another region without an inductive coil for producing a regular high density plasma in a chemical vapor deposition chamber, without undue experimentation, based on the information provided by Kawakami, together with the information known in the art, including that taught by Sandhu.. Compare In re Spence, 261 F.2d 244, 246 (CCPA 1958). Appellant has not even discussed why factors, such as (1) the quantity of experimentation necessary, (2) the amount of direction or guidance presented, (3) the presence or absence of working examples, (4) the nature of the invention, (5) the state of the prior art, (6) the relative skill of those in the art, (7) the predictability or unpredictability of the art, and (8) the breadth of the claims, would supports his or her position that Kawakami’s disclosure relating to the use of a single chamber to replace two chambers for producing two different plasmas is not enabling. See In re Vaeck, 947 F.2d 488 (Fed. Cir. 1991). Thus, on this record, we determine that the Examiner has not reversibly erred in determining that one of ordinary skill in the art, armed with the knowledge of Kawakami, Ikeda, Hoffman, and Sandhu, would have been led to employ the inductively coupled high density plasma taught by Sandhu in the first plasma processing region of a chemical vapor deposition processing chamber to form Kawakami’s gate silicon oxynitride or silicon oxide insulating (first dielectric) layer corresponding to the claimed oxidized Appeal 2010-003827 Application 10/990,185 9 layer and then form Kawakami’s gate silicon nitride insulating (second dielectric) layer corresponding to the claimed dielectric layer in the second plasma processing region of the chemical vapor deposition processing chamber within the meaning of 35 U.S.C. § 103(a). It follows that based on the fact findings and reasons set forth in the Answer, we affirm the Examiner’s § 103(a) rejection. ORDER In view of the foregoing, it is ORDERED that the decision of the Examiner rejecting the claims on appeal under 35 U.S.C. § 103(a) is AFFIRMED; and FURTHER ORDERED that no time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1)(iv). AFFIRMED bar Copy with citationCopy as parenthetical citation