Ex Parte Wang et alDownload PDFPatent Trial and Appeal BoardAug 22, 201612577922 (P.T.A.B. Aug. 22, 2016) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE FIRST NAMED INVENTOR 12/577,922 10/13/2009 Shulin Wang 44257 7590 08/24/2016 PATTERSON & SHERIDAN, LLP- - Applied Materials 24 Greenway Plaza, Suite 1600 HOUSTON, TX 77046 UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 007785/USCl/FEP/LPCVD/PJT 5288 EXAMINER MILLER, MICHAEL G ART UNIT PAPER NUMBER 1712 NOTIFICATION DATE DELIVERY MODE 08/24/2016 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address( es): Pair_Eofficeaction@pattersonsheridan.com psdocketing@pattersonsheridan.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte SHULIN WANG, ERROL ANTONIO SANCHEZ, and AIHUA CHEN 1 Appeal2015-001263 Application 12/577 ,922 Technology Center 1700 Before BRADLEY R. GARRIS, MICHAEL P. COLAIANNI, and JEFFREY R. SNAY, Administrative Patent Judges. GARRIS, Administrative Patent Judge. DECISION ON APPEAL Appellants appeal under 35 U.S.C. § 134(a) from the Examiner's decision rejecting claims 1-10, 14, 15, 17, and 21-30. We have jurisdiction under 35 U.S.C. § 6. We AFFIRM. 1 Applied Materials, Inc. is identified as the real party in interest. App. Br. 3. Appeal2015-001263 Application 12/577,922 Appellants claim a method of processing a substrate comprising forming at least two treated silicon nitride layers on the substrate by depositing a silicon nitride layer and exposing the layer to hydrogen radicals thereby forming a treated silicon nitride layer, wherein successively formed treated silicon nitride layers are formed onto a surface of previously formed treated silicon nitride layers such that each successively formed treated silicon nitride layer is adjacent to each previously formed treated silicon nitride layer (independent claim 1; see also remaining independent claims 23 and 30). A copy of representative claim 1, taken from the Claims Appendix of the Appeal Brief, appears below. 1. A method of processing a substrate, comprising: heating a substrate to a temperature of 550° Corless; forming at least two treated silicon nitride layers on the substrate, wherein forming each treated silicon nitride layer compnses: thermally decomposing a gas mixture comprising a silicon and nitrogen containing source gas and ammonia to deposit a silicon nitride layer to a thickness of 1 ooA or less; and exposing the silicon nitride layer to hydrogen radicals formed by plasma decomposition of a hydrogen containing source gas to treat the silicon nitride layer, wherein successively formed treated silicon nitride layers are formed onto a surface of previously formed treated silicon nitride layers such that each successively formed treated silicon nitride layer is adjacent to each previously formed treated silicon nitride layer. Under 35 U.S.C. § 103(a), the Examiner rejects as unpatentable: Claims 1-7, 14, 17, 21-25, 29, and 30 over Graff (US 2003/0104753 Al; June 5, 2003), Brown (US 5,264,724; Nov. 23, 1993), Fujimura (US 2 Appeal2015-001263 Application 12/577,922 6,255,197 Bl; July 3, 2001), and Wang (US 2004/0096582 Al; May 20, 2004); Claims 8-10 and 26-28 over Graff, Brown, Fujimura, Wang, and Hochberg (US 4,992,306; Feb. 12, 1991); and Claim 15 over Graff, Brown, Fujimura, Wang, and Dory (US 4,877 ,651; Oct. 31, 1989). Appellants do not present separate arguments specifically directed to the dependent claims under rejection (App. Br. 7-11). Therefore, the dependent claims will stand or fall with their parent independent claims of which claim 1 is representative. We sustain the above rejections for the reasons given in the Final Action, the Answer, and below. The Examiner finds that Graff teaches a method of processing a substrate comprising forming at least two silicon nitride layers on the substrate but that Graff is silent as to specific processing details such as exposing a deposited silicon nitride layer to hydrogen radicals thereby obtaining a treated silicon nitride layer as required by claim 1 (Final Action 3--4). In this latter regard, the Examiner finds that Brown teaches specific processing details for depositing a silicon nitride layer on a substrate and exposing the silicon nitride layer to hydrogen radicals to treat the silicon layer as claimed (id. at 4). Based on these findings, the Examiner concludes that it would have been obvious to provide the method of Graff with the specific processing 3 Appeal2015-001263 Application 12/577,922 details taught by Brown (Final Action at 4--5). Concerning the claim 1 requirement that each successively formed treated silicon nitride layer is formed adjacent (i.e. onto) a previously formed treated silicon nitride layer, the Examiner further concludes that "it would have been an obvious matter of design choice to place multiple barrier layer films [i.e., silicon nitride layers] adjacent to one another" (id. at 5). Finally, the Examiner concludes that it would been obvious to provide the modified method of Graff with the hydrogen radical generation system of Fujimura (id.) and with the silicon nitride precursor taught by Wang (id. at 6) thereby resulting in a method having the corresponding features recited in claim 1. Appellants argue: [N]o reference or combination of references cited by the Examiner teaches or suggests the recitation of claim 1 of "forming at least two treated silicon nitride layers on the substrate, wherein forming each treated silicon nitride layer comprises deposit[inzl a silicon nitride layer" and "exposing the silicon nitride layer to hydrogen radicals ... to treat the silicon nitride layer, wherein successively formed treated silicon nitride layers are formed onto a swface of previously formed treated silicon nitride layers such that each successively formed treated silicon nitride layer is adjacent to each previously formed treated silicon nitride layer." (App. Br. 7; see also id. at 8-10.) Appellants' argument is not persuasive for the reasons detailed by the Examiner (Ans. 2--4). As correctly explained by the Examiner, when Graff and Brown are combined in the manner proposed in the rejection, "a 4 Appeal2015-001263 Application 12/577,922 plurality of treated layers [as well as other argued features of claim 1] would have been achieved" (id. at 3). In their Reply Brief, Appellants additionally argue that there is no motivation to combine Graff and Brown because Brown teaches away from applying hydrogen implantations to silicon nitride layers that are 100 Angstroms or less (Reply Br. 5-7) and that "the burden of showing forming treated silicon nitride layers successively is merely an obvious matter of design choice is not satisfied" (id. at 7 (bolding and capitalization removed); see also id. at 8-9). These additional arguments could have been but were not presented in the Appeal Brief. For this reason and because good cause has not been shown by Appellants, we will not consider these new arguments for purposes of the present appeal. 37 C.F.R. § 41.41(b )(2) (2013). For the reasons stated above and given by the Examiner, Appellants fail to show error in the § 103 rejections before us. The decision of the Examiner is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(l )(iv). AFFIRMED 5 Copy with citationCopy as parenthetical citation