Ex Parte Vardeny et alDownload PDFPatent Trial and Appeal BoardMar 27, 201311404646 (P.T.A.B. Mar. 27, 2013) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte ZEEV VALENTINE VARDENY, CHUANZHEN LIU, and VLADIMIR KAMAEV ____________ Appeal 2010-010356 Application 11/404,646 Technology Center 2800 ____________ Before MARC S. HOFF, CAROLYN D. THOMAS, and JOHN A. EVANS, Administrative Patent Judges. EVANS, Administrative Patent Judge. DECISION ON APPEAL This is an appeal under 35 U.S.C. § 134(a) involving claims to perforated-electrode organic light-emitting diodes. The Examiner has rejected the claims as obvious. We have jurisdiction under 35 U.S.C. § 6(b). We affirm-in-part. Rather than reiterate the arguments of Appellants and the Examiner, we refer to the Appeal Brief (filed Feb. 12, 2010), the Answer (mailed Apr. 29, 2010), and the Reply Brief (filed June 29, 2010). We have considered in Appeal 2010-010356 Application 11/404,646 2 this decision only those arguments Appellants actually raised in the Briefs. Any other arguments which Appellants could have made but chose not to make in the Briefs are deemed to be waived. See 37 C.F.R. § 41.37(c)(1)(iv). STATEMENT OF THE CASE The claims relate to perforated-electrode organic light-emitting diodes. Claims 1-15 are on appeal. Claims 1 and 14 are independent. An understanding of the invention can be derived from a reading of exemplary claim 1, reproduced below: 1. An organic light-emitting diode (OLED) structure, comprising: an organic semiconductor polymer layer sandwich between two electrodes; and wherein at least one of the electrodes is perforated. The Examiner has entered the following rejections: 1. Claims 1, 3-10, and 12-15 are rejected under 35 U.S.C. § 103(a) as obvious over Yoneda1 and Kim.2 (Ans. 4-8). 2. Claim 2 is rejected under 35 U.S.C. § 103(a) as obvious over Yoneda, Kim, and Parthasarathy.3 (Ans. 8). 3. Claim 11 is rejected under 35 U.S.C. § 103(a) as obvious over Yoneda, Kim, and Moroz.4 (Ans. 8-9). 1 Yoneda (US 2001/0026123 A1, Oct. 4, 2001). 2 Kim (US 2004/0033388 A1, Feb. 19, 2004). 3 Parthasarathy (US 6,639,357 B1, Oct. 28, 2003). 4 Alexander Moroz, Metallo-Dielectric Diamond and Zinc-Blende Photonic Crystals, 66 PHYSICAL REV. B 115109 (2002). Appeal 2010-010356 Application 11/404,646 3 Claim Groupings Based on Appellants’ arguments in the Appeal Brief, we will decide the appeal on the basis of claims as set forth below. See 37 C.F.R. § 41.37(c)(1)(vii). CLAIMS 1, 3-10, AND 12-15 CONTENTIONS AND ISSUE The Examiner has rejected claims 1, 3-10, and 12-15 under 35 U.S.C. § 103(a) as obvious over Yoneda and Kim. (Ans. 4-8). Appellants contend that Yoneda does not teach or suggest an OLED. Appellants contend that the thin film transistor (TFT) of Yoneda includes semiconductor diode junctions, but that Yoneda’s electroluminescent (light-emitting) structure contains no diodes. (App. Br. 3). Appellants further contend that Yoneda does not teach or suggest an organic semiconductor polymer layer. Rather, the light-emitting layer is composed of Bebq2(10-benzo[h]quinolinol- beryllium complex) containing a Quinacridone delivative. The first hole transfer layer comprises TPD: triphenylamine dimer (4,4',4"-tris (3- methylphenylphenylamino) triphenylamine). The second hole transfer layer comprises MTDATA(4,4'-bis (3-methylphenylphenylamino) biphenyl), and the electron transfer layer is also comprised of Bebq2. (App. Br. 4). Appellants contend that the compounds of Yoneda’s electroluminescent layer are not organic polymers. Appellants further contend that the conjugated polymers of Kim, suggested by the Examiner, are not accompanied by a reasonable expectation of success because: [l]ight-emitting layers must be adjacent other layers having specific compositions to facilitate light emission. EL layers need layers to inject electrons and holes which recombine to Appeal 2010-010356 Application 11/404,646 4 emit exitons[.] Appellant’s structure uses a polymer layer between two metal electrodes, but absent transfer layers of the type disclosed by Yoneda. Just because a layer “emits light” does not mean that it will do so in the absence of a supporting environment. (App. Br. 4 (citation omitted)). Appellants contend that the materials of a light-emitting layer are not chosen for their mechanical properties, as suggested by the Examiner, but are chosen for their electro-chemical properties. Appellants further contend that Yoneda, Kim, and the application all use a glass substrate which imparts mechanical rigidity. Therefore, the mechanical stiffness of the polymer, suggested by the Examiner as a reason to combine Kim with Yoneda, is irrelevant. (App. Br. 5-6). Regarding claims 1, 4-9, and 12-15, the Examiner answers that the Academic Press Dictionary of Science and Technology (1996) defines “diode” as “a two-element active electronic device containing an anode and a cathode, characterized by the ability to pass an electronic current more easily from cathode to anode than from anode to cathode.” (Ans. 9). The Examiner further finds that Yoneda, paragraph [0009], clearly states that “holes injected from the anode electrode 28 and the electrons injected from the cathode electrode 23 are recombined inside the luminous layer 25.” In other words, electric current (or electrons) are passed from the cathode to the anode, which creates a “diode.” Therefore, the light emitting structure of Yoneda (the cathode, electroluminescent layer, and the anode) comprises a diode. Further, because the light emitting layer of Yoneda is organic, the light emitting structure is considered an OLED (Ans. 9-10). The Examiner finds that Kim teaches an organic semiconductor polymer layer. Contrary to Appellants’ contention, the Examiner finds that Appeal 2010-010356 Application 11/404,646 5 Kim discloses that the use of electron- and/or hole-transporting layers is optional. (Ans. 11). With respect to claims 14 and 15, the Examiner finds that Appellants’ argument that the light emitted by the Yoneda structure goes through the anode and not the cathode is moot because that limitation is not claimed. (Ans. 10) Appellants’ Reply contends that Yoneda’s structure requires doping in order to be a diode. (Reply 1). The issues presented with respect to these rejections are: (1) whether the electroluminescent structure of Yoneda comprises a diode; and (2) whether the electroluminescent organic polymer of Kim is properly combinable with the electroluminescent structure of Yoneda. ANALYSIS Claims 1, 4-9, and 12-15 The Specification discloses that “[i]n the simplest form of organic light emitting diodes (OLEDs) the active organic semiconductor is sandwiched between two metallic electrodes.” (Spec. 1:14-15). Appellants’ Figure 3A appears consistent with Figures 1 and 2 of Yoneda, with the Examiner’s finding that Yoneda discloses an OLED, and with the definition of one of ordinary skill in the art as evidenced by the definition of “diode” set forth in the Academic Press Dictionary of Science and Technology, cited by the Examiner. We, therefore adopt as our own, the Examiner’s finding that Yoneda teaches an OLED (Ans. 4). We also adopt the Examiner’s finding that Kim teaches a light- emitting, organic semiconductor polymer layer. Appellants do not contest this finding. Contrary to Appellants’ contention, the Examiner finds that Appeal 2010-010356 Application 11/404,646 6 Kim discloses that the use of electron- and/or hole-transporting layers is optional. (Ans. 11). We, therefore, find no error in the Examiner’s suggestion that Kim’s light-emitting, organic semiconductor polymer layer may be combined with Yoneda’s OLED. With respect to claims 14 and 15, we adopt the Examiner’s finding that Appellants’ argument that the light emitted by the Yoneda structure goes through the anode and not the cathode is moot because that limitation is not claimed. (Ans. 10). Appellants’ contention that the structure of Yoneda must be doped in order to be considered as a diode is not persuasive because Appellants have not provided any evidence for this contention and because the definition of “diode” set forth by the Academic Press Dictionary of Science and Technology does not require doping. Claim 3 Appellants contend that claim 3 recites that the perforated electrode is at least semi-transparent and the term “semi-transparent” refers to the material itself and not to a material shaped in a comblike, meshlike, or gridlike pattern. (App. Br. 5). The Examiner considers the limitation of claim 3 to require the electrode to be semi-transparent, not the material of the electrode (Ans. 12). The claim does not state, “the material of the perforated electrode is at least semi-transparent,” but simply states, “the perforated electrode is at least semi-transparent.” Therefore, the Examiner considers paragraph [0019] of Yoneda, which states, “the [perforated] electrode in, for example, a comblike, meshlike or gridlike form can externally emit a sufficient amount of light,” to teach the limitation of claim 3. Appeal 2010-010356 Application 11/404,646 7 We find that the Specification distinguishes the intensity of light transmitted through the material of the electrode, from the intensity of light transmitted through the perforated material: The PL spectra of MEH-PPV spin-casted on the two A1 films are shown transmission and reflection geometries in Figure 2. The PL spectra (that are not normalized) show typical phonon replicas (0-n), and indicate that a good match exists with the transmission maxima of the perforated A1 film (Figure 1A) [25], and that of the Au top electrode (Figure 1B). The PL intensity measured in transmission is relatively strong for the perforated A1 electrode due to the match with the anomalous T(λ). On the contrary, the PL intensity measured through the control A1 film (not shown) is much smaller (by about two orders of magnitude). (Spec. 7:15-22 (brackets in original)). In view of this disclosure, we do not sustain the rejection of claim 3. Claim 10 Appellants contend that claim 10 adds the limitation that the perforated electrode act as a “patterned, periodic two-dimensional (2D) subwavelength hole array.” Appellants further contend that the Examiner’s finding that Yoneda teaches that “the perforated electrode acts as a patterned, periodic two-dimensional (2D) hole array” is not relevant because the Examiner has read out the limitation “subwavelength hole array” from the claims. (App. Br. 5-6). The Examiner finds that Yoneda teaches the perforated electrode acts as a patterned, periodic two-dimensional (2D) hole array.” (Ans. 7). The Examiner has examined claim 10 on the merits, but we agree with Appellants that the Examiner has read out of the claims the term “subwavelength,” assuming it to be a relative term of degree “with no corresponding comparative term within the claim.” The Examiner states that Appeal 2010-010356 Application 11/404,646 8 the claim has been treated “assuming subwavelength refers to different colors within a pixel” (Ans. 3). The Specification explicitly defines the term “subwavelength hole array” such that its meaning would be clear to a person of skill in the art: On a smooth metal-dielectric interface, light cannot efficiently couple to the SP excitations, which are the elementary excitations of the metal surface, because conservation of energy, E and momentum, k are not obeyed [6]. On an (E, k) plot the SP dispersion curve lies below that of the electro-magnetic waves in vacuum [6]. But in a metal film that is perforated with a 2D periodic array of holes, the periodicity allows grating coupling of the SP to light [7]; this coupling results in surface plasmon polariton (SPP) excitations. The lattice periodicity promotes zone folding of the SP dispersion relation, which results in the formation of SP band structure that makes it possible for light to directly couple to SP excitations. Indeed it was recently found [7-18] that the optical transmission through subwavelength hole arrays fabricated on optically thick metallic films is enhanced at resonance wavelengths (or maxima), where light couples to the film’s SPP excitations. If these maxima overlap with the photoluminescence (PL) band of the active organic layer of an OLEO, then it might be possible to extract more EL light out of the device [5, 19-21] without compromising the current injection capability of the patterned electrode. (Spec. 2:3-17 (brackets in original)). The Specification further defines the term as it applies to the claimed invention: “The periodic hole array with square symmetry consisted of a 80 nm thick aluminum film on a glass substrate with subwavelength hole size of about 150 nm and lattice constant periodicity, a0 of about 300 nm (Figure 1A inset).” (Spec. 4:24-27). Moreover, “[i]n the standard aperture theory of Bethe [26], the transmission through a sub-wavelength aperture follows (d/λ)4 dependence due to diffraction, where d is the hole diameter.” (Spec. 6:14-16 (referring to H. A. Appeal 2010-010356 Application 11/404,646 9 Bethe, Theory of Diffraction by Small Holes, 66 PHYSICAL REV. 163 (1944)) (second brackets in original)). We find that a person of ordinary skill in the art would cognize a term from standard aperture theory. Because the art cited by the Examiner does not teach or suggest the claimed “subwavelength hole array,” we do not sustain the rejection of claim 10. CLAIM 2 CONTENTIONS AND ANALYSIS The Examiner has rejected claim 2 under 35 U.S.C. § 103(a) as obvious over Yoneda, Kim, and Parthasarathy. (Ans. 8). The Examiner finds that Yoneda and Kim teach that one electrode, the anode, may be perforated to permit the passage of light and that Parthasarathy teaches that both electrodes, the top and bottom, may be transparent to emit light from opposite sides. Thus it would have been obvious to perforate both the Yoneda electrodes to permit the passage of light from both sides of the device. (Ans. 8). Appellants contend that Yoneda seeks to avoid emission through the back, transistor, side and that fabrication would be difficult. (App. Br. 5). The Examiner answers that Parthasarathy provides the motivation for dual emission and that Yoneda provides the means, i.e., perforation. (Ans. 12). Appellants’ arguments are not persuasive that the Examiner has erred. Appeal 2010-010356 Application 11/404,646 10 CLAIM 11 CONTENTIONS AND ANALYSIS The Examiner has rejected claim 11 under 35 U.S.C. § 103(a) as obvious over Yoneda, Kim, and Moroz. (Ans. 8-9). Appellants contend that the Examiner’s motivation to combine Moroz, because the substituted materials would “provide a clearer displayed picture,” is incomprehensible. (App. Br. 6). In reply to Appellants’ Brief, the Examiner now finds that the diamond and zinc blende photonic crystals of Moroz have applications as “filters.” (Ans. 9). Appellants contend that this altered finding of motivation to combine is still not relevant to the claims. (Reply 3). The Examiner finds that Moroz teaches that diamond and zinc-blende photonic crystals “are useful as color filters.” (Ans. 14 (citing Moroz, p. 1, par. 1)). We do not agree with the Examiner’s reading of Moroz. The cited passage of Moroz reads: There is a common belief that, in the near future, photonic crystals systems will allow us to perform many functions with light that ordinary crystals do with electrons. In addition to numerous potential technological applications (filters, … photonic crystals also promise to become a laboratory for testing fundamental processes. (Moroz, p. 1, par. 1) (emphasis added). Moroz is not describing the state of an existing technology. Rather, the reference is clearly speculating as to a potential future state that may subsequently permit experimentation. The Moroz reference would not convey to a person of skill in the art a reasonable expectation of success that Moroz’ diamond and zinc-blende photonic crystals could be substituted in place of the claimed perforated electrodes. Therefore, we do not sustain the rejection of claim 11. Appeal 2010-010356 Application 11/404,646 11 SUMMARY We affirm the rejection of claims 1, 2, 4-9, and 12-15. We reverse the rejection of claims 3, 10, and 11. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1)(iv). AFFIRMED-IN-PART babc Copy with citationCopy as parenthetical citation