Ex Parte Thorman et alDownload PDFPatent Trial and Appeal BoardSep 29, 201412419766 (P.T.A.B. Sep. 29, 2014) Copy Citation UNITED STATES PATENT AND TRADEMARKOFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 12/419,766 04/07/2009 Joseph L. Thorman COS-1166 1224 25264 7590 09/29/2014 FINA TECHNOLOGY INC PO BOX 674412 HOUSTON, TX 77267-4412 EXAMINER ENG, ELIZABETH ART UNIT PAPER NUMBER 1762 MAIL DATE DELIVERY MODE 09/29/2014 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte JOSEPH L. THORMAN and STEVEN BORGFELD ____________ Appeal 2013-000623 Application 12/419,766 Technology Center 1700 ____________ Before CHUNG K. PAK, JAMES C. HOUSEL, and CHRISTOPHER M. KAISER, Administrative Patent Judges. PAK, Administrative Patent Judge. DECISION ON APPEAL Appellants1 appeal under 35 U.S.C. § 134(a) from the Examiner’s decision2 finally rejecting claims 1 through 12 and 14 through 19, which are all of the claims pending in the above-identified application. We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM. The subject matter on appeal is directed to “polymerization processes and polymers formed therefrom.” (Spec. 2, ¶ [0005].) The polymerization processes generally involve contacting an olefin monomer with a single-site transition metal 1 The Real Party in Interest is said to be Fina Technology, Inc. (See Appeal Brief filed June 19, 2012(“App. Br.”) at 6.) 2 Final Office Action mailed November 29, 2011. Appeal 2013-000623 Application 12/419,766 2 catalyst in the presence of a multi-functional block copolymer non-ionic surfactant within a reaction vessel under polymerization conditions. (Spec. 2, ¶ [0005].) The single-site transition metal catalyst can be selected from non-limiting examples of a myriad of metallocene catalysts listed at pages 4 through 16 of the Specification (Spec. 2 and 4–16, ¶¶ [0006] and [0015]–[0050].) The multi-functional block copolymer non-ionic surfactant can be selected from a myriad of multi-functional block copolymers listed at pages 19 through 21 of the Specification. (Spec. 19–21, ¶¶ [0060]–[0070].) These polymerization processes are said to minimize fouling “while maintaining catalyst activity or at least minimizing the reduction of catalyst activity.” (Spec. 4, ¶ [0014].) Details of the appealed subject matter are recited in representative claim 13 reproduced below from the Claims Appendix to the Appeal Brief: 1. A polymerization process comprising: introducing an olefin monomer into a reaction vessel; introducing a catalyst system comprising a single-site transition metal catalyst into the reaction vessel; introducing a non-ionic surfactant into the reaction vessel, wherein the non-ionic surfactant comprises a multi-functional block copolymer and wherein the non-ionic surfactant is introduced in an amount of from about 0.01 ppm to about 5 ppm with respect to the weight of the monomer; contacting the olefin monomer with the catalyst system in the 3 Appellants’ traversal of the rejections under 35 U.S.C. § 103(a) is based on limitations common to independent claim 1. (See generally App. Br. 14–22.) Appellants do not argue the claims on appeal separately. (Id.) Therefore, for purposes of this appeal, we select independent claim 1 as representative and confine our discussion to such claim. The remaining claims on appeal stand or fall with claim 1. 37 C.F.R. § 41.37(c)(1)(vii). Appeal 2013-000623 Application 12/419,766 3 presence of the non-ionic surfactant within the reaction vessel under polymerization conditions to form a polyolefin; and withdrawing the polyolefin from the reaction vessel. (App. Br. 23, Claims App’x (emphasis added).) Appellants seek review of following grounds of rejection maintained by the Examiner in the Examiner’s Answer mailed July 25, 2012 (“Ans.”): 1. Claims 1–3, 5, 6, 8, 9, 11, 12, and 17 under 35 U.S.C. §103(a) as unpatentable over Takahashi (JP 2000-313716 A, published November 14, 2000); and 2. Claims 1–4, 6–12, and 14–19 under 35 U.S.C. §103(a) as unpatentable over Sugimura (JP 2000-327707 A, published November 28, 2000). (App. Br. 13.) Upon consideration of the evidence on this record and each of Appellants’ contentions, we find that the preponderance of evidence supports the Examiner’s determination that one of ordinary skill in the art, armed with the knowledge reflected in Takahashi or Sugimura, would have been led to the subject matter recited in the claims on appeal within the meaning of 35 U.S.C. § 103(a). On this record, we find Appellants’ arguments unpersuasive of reversible error in the Examiner’s conclusion of obviousness for the reasons expressed in the Answer. We add the following primarily for emphasis and completeness. As is apparent from the record, Appellants do not dispute the Examiner’s finding that Takahashi or Sugimura discloses a polymerization process comprising introducing olefin monomer, a catalyst system comprising a single-site transition metal catalyst, a non-ionic surfactant comprising a multi-functional block copolymer into a reaction vessel, contacting the olefin monomer with the catalyst system in the presence of the non-ionic surfactant in the reaction vessel, and Appeal 2013-000623 Application 12/419,766 4 withdrawing the polyolefin from the reaction vessel. (Compare Ans. 2 and 6 with App. Br. 14–22.) Nor do Appellants dispute the Examiner’s finding that Takahashi and Sugimura disclose employing 0.1 ppm to 400 ppm and 1.05 ppm to 1047 ppm of the non-ionic surfactant, respectively, in their polymerization processes. (Compare Ans. 4 and 8–7 with App. Br. 14–22.) Thus, notwithstanding Appellants’ arguments to the contrary,4 a preponderance of evidence supports the Examiner’s finding that Takahashi or Sugimura expressly teaches using the non- ionic surfactant in an amount inclusive of 0. 1ppm to 5.0 ppm or 1.05 ppm to 5.0 ppm, respectively, which are within the amounts of the non-ionic surfactant used in the claimed polymerization process. As stated by our reviewing court in In re Peterson, 315 F.3d 1325, 1329–330 (Fed. Cir. 2003): In cases involving overlapping ranges, we and our predecessor court have consistently held that even a slight overlap in range establishes a prima facie case of obviousness… See also Ormco Corp. v. Align Technology Inc., 463 F. 3d 1299, 1311 (Fed. Cir. 2006); In re Geisler, 116 F.3d 1465, 1469 (Fed. Cir. 1997). This presumption of obviousness is rebuttable either by a showing that the prior art taught away from the invention or by a showing of new and unexpected results relative to the closest prior art. Iron Grip Barbell Co. v. USA Sports, Inc., 392 F.3d 1317, 1322 (Fed. Cir. 2004); accord Lazare Kaplan Int’l, Inc. v. Photoscribe Techs., Inc., 628 F.3d 1359, 1380–381 (Fed. Cir. 2010); see also In re Woodruff, 919 F.2d 1575, 1578 (Fed. Cir. 1990) (“The law is replete with cases in which the difference between the claimed invention and the prior art is some range or other variable within the claims. These cases have consistently held that in such 4 It is well-settled that prior art disclosures are not limited to the examples. In re Inland Steel Co., 265 F.2d 1354, 1361 (Fed. Cir. 2001) Appeal 2013-000623 Application 12/419,766 5 a situation, the applicant must show that the particular range is critical, generally by showing that the claimed range achieves unexpected results relative to the prior art range.”) Relying on the above principles of law, Appellants contend that Takahashi teaches away from less than 0.1 ppm. (App. Br. 15.) In support of this contention, Appellants refer to relevant part of paragraph [0016] of Takahashi, which states that: If the supply rate of a polyalkylene oxide block exceeds a mentioned range [i.e., 0.1-400 ppm], it is economically disadvantageous, or polymerization activity may fall, and if it becomes less than a mentioned range [0.1-400 ppm], the fluid improvement effect of a polymerization granular material may not be revealed. However, the claims on appeal are not limited to employing the polyalkylene oxide block non-ionic surfactant in an amount of less than 0.1 ppm. In re Self, 671 F.2d 1344, 1348 (CCPA 1982) (“[A]ppellant's arguments fail from the outset because. . . they are not based on limitations appearing in the claims.”) The claims, as written, include using the polyalkylene oxide block non-ionic surfactant in any amount within about 0.01 ppm to about 5 ppm, inclusive of 0. 1ppm to 5.0 ppm or 1.05 ppm to 5.0 ppm taught or suggested by Takhashi or Sugimura to be useful for a polymerization process involving olefin monomer and single-site transition metal catalysts under the polymerization conditions recited in claim 1 as discussed supra. Appellants also argue that the amount of the non-ionic surfactant recited in the claims on appeal imparts results not expected or recognized by Takahashi or Appeal 2013-000623 Application 12/419,766 6 Sugimura.5 (App. Br. 16-22.) In support of this argument, Appellants refer to paragraphs 0072 and 0073 of the Specification which state that: Unexpectedly, it has been observed that utilizing the surfactants described herein with olefin polymerization processes, and particularly with polymerization processes utilizing a metallocene catalyst, result in improved anti-fouling properties without substantially compromising catalyst system activity…. Unexpectedly, the embodiments of the invention result in polymerization processes wherein the activity is able to be maintained within at least about 100% (compared to an identical process absent the surfactant), or at least about 90%, or at least about 70%, or at least about 60% or at least about 50%, for example. (App. Br. 16–17 and 20). Appellants also refer to Tables 1 and 2 at pages 24 and 25 of the Specification to show that the claimed subject matter imparts unexpected results. (App. Br. 18, 19, and 22.) It is incumbent upon Appellants to show that the claimed subject matter imparts unexpected results relative to the closest prior art, namely Takahashi or Sugimura . In re Klosak, 455 F.2d 1077, 1080 (CCPA 1972) (“the burden of showing unexpected results rests on he who asserts them”); In re Baxter Travenol Labs., 952 F.2d 388, 392 (Fed. Cir. 1991) (“[W]hen unexpected results are used as evidence of nonobviousness, the results must be shown to be unexpected compared with the closest prior art.”) The mere assertion of unexpected results is not sufficient. In re Geisler, 116 F.3d 1465, 1471 (Fed. Cir. 1997) (attorney argument cannot take the place of evidence); In re De Blauwe, 736 F.2d 699, 705 (Fed. Cir. 5 See, e.g., In re Peterson, 315 F.3d at 1330–331(“In general, an applicant may overcome a prima facie case of obviousness by establishing ‘that the [claimed] range is critical, generally by showing the claimed range achieves unexpected results relative to the prior art range.’”) Appeal 2013-000623 Application 12/419,766 7 1984) (mere arguments in the Brief or conclusory statements in the Specification regarding unexpected results cannot take the place of objective evidence). Here, Tables 1 and 2 at pages 24 and 25 of the Specification relied upon by Appellants show that the fouling potential decreases as the concentration of a surfactant designated as “A,” “B,” “C,” or “D” increases from 1 ppm to 5 ppm in the presence of catalyst A.6 However, the showing in Tables 1 and 2 does not demonstrate that the polymerization process employing about 0.01 ppm to about 5 ppm of such surfactants recited in claim 1 is unexpectedly superior to the polymerization process employing more than 5 ppm of the surfactant taught by Takahashi or Sugimura, the closest prior art. (App. Br. 18–22.) Based on the trends shown in Tables 1 and 2, the polymerization process employing higher than 5 ppm (e.g., 50 ppm) of the surfactant exemplified by Takahashi or Sugimura is reasonably expected to be much more superior than the claimed polymerization 6While the showing in Tables 1 and 2 is limited to using one catalyst with four different non-ionic surfactants, the claims on appeal are not so limited. As is apparent from the written description in the Specification discussed supra, the claimed catalyst and non-ionic surfactant can be selected from a huge number of catalysts and surfactants. Nevertheless, Appellants do not address why such a limited showing is reasonably commensurate in scope with the degree of protection sought by the claims on appeal. In re Lindner, 457 F.2d 506, 508 (CCPA 1972) (“The claims, however, are much broader in scope, covering mixtures of numerous compounds, and we have to agree with the Patent Office that there is no ‘adequate basis for reasonably concluding that the great number and variety of compositions included by the claims would behave in the same manner as the [single] tested composition.’”); In re Greenfield, 571 F.2d 1185, 1189 (CCPA 1978) (“Establishing that one (or a small number of) species gives unexpected results is inadequate proof, for ‘it is the view of this court that objective evidence of non- obviousness must be commensurate in scope with the claims which the evidence is offered to support.’” ) In the event of further prosecution of the claimed subject matter, both the Examiner and Appellants are advised to determine whether the showing in Tables 1 and 2 is reasonably commensurate in scope with the claims if such showing is again relied upon by Appellants to show unexpected results. Appeal 2013-000623 Application 12/419,766 8 process in terms of the fouling potential decrease, while maintaining catalyst activity or at least minimizing the reduction of catalyst activity as discussed at paragraph [0073] of the Specification. (See also Takahashi, ¶¶ [0016], [0029], and [0030] which state that “polymerization activity may fall” if “polyalkylenoxide block exceeds” 400 ppm and explains the addition of a small quantity of the polyalkylene oxide block surfactant because “[i]t becomes possible to judge the influence of the polymerization states on the catalytic activity fall by addition of polyalkylene oxide block, . . . It becomes possible for there to be almost no influence of the fall of catalytic activity . . .”.) On this record, Appellants have not carried the burden of showing that the claimed invention imparts unexpected results relative to the closest prior art as explained by the Examiner. Accordingly, based on the totality of record, including due consideration of Appellants’ arguments and evidence, we determine that the preponderance of evidence weighs most heavily in favor of obviousness of the subject matter recited in the claims on appeal within the meaning of 35 U.S.C. § 103(a). It follows that the decision of the Examiner rejecting the claims on appeal under 35 U.S.C. § 103(a) is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1). AFFIRMED cam Copy with citationCopy as parenthetical citation