Ex Parte Smyrniotis et alDownload PDFPatent Trial and Appeal BoardAug 13, 201812501590 (P.T.A.B. Aug. 13, 2018) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 12/501,590 07/13/2009 37138 7590 08/15/2018 THADDIUS J. CARVIS Law Offices of Thaddius Carvis 16341 Limestone CT LEESBURG, VA 20176 FIRST NAMED INVENTOR Christopher R. Smyrniotis UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. FTP6008A US 4651 EXAMINER PO, MING CHEUNG ART UNIT PAPER NUMBER 1771 NOTIFICATION DATE DELIVERY MODE 08/15/2018 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): admin@tjcarvis.com tjcarvis@email.com nsguth@comcast.net PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte CHRISTOPHER R. SMYRNIOTIS, KENT W. SCHULZ, and EMELITO P. RIVERA Appeal2017-009643 Application 12/501,590 Technology Center 1700 Before LINDA M. GAUDETTE, RAEL YNN P. GUEST, and MERRELL C. CASHION, JR., Administrative Patent Judges. CASHION, Administrative Patent Judge. DECISION ON APPEAL STATEMENT OF THE CASE This is an appeal under 35 U.S.C. § 134 from the final rejection of claims 1 and 3-9. App. Br. 1. We have jurisdiction under 35 U.S.C. § 6. We affirm. The invention relates to a process that increases the output of a combustor fired with coal having high iron and/or calcium content by reducing the tendency of slag to form on heat exchange surfaces, changing the nature of the slag to make it easier to remove, and actually removing slag. Spec. ,r 1. Claim 1 illustrates the invention: 1. A process for reducing slag cohesiveness and/or adhesiveness in a combustor, thereby decreasing the rate of fouling, comprising: Appeal2017-009643 Application 12/501,590 combusting a slag-forming coal, having an iron content of greater than about 15% based on the weight of the ash and expressed as Fe203 and/or a calcium content of greater than 5% based on the weight of the ash and expressed as CaO, with an overall excess of oxygen; moving the resulting combustion gases though heat exchange equipment under conditions which cause cooling of slag formed by burning the fuel; and prior to contact with said heat exchange equipment in the combustor, introducing into hot combustion gases in the combustor an aqueous liquid aluminum trihydroxide reagent in amounts, substoichiometric in terms of affecting the fusion point of the slag, and with droplet sizes and concentrations effective to form nano-sized particles of under 200 nanometers in the hot combustion gases and to decrease the rate of fouling by slag and to increase the friability of resulting slag. Appellants 1 request review of the Examiner's rejection of claims 1 and 3-9 under 35 U.S.C. §I03(a) as unpatentable over Smymiotis (US 2005/0150441 Al, published July 14, 2005), Pastore (US 2009/0178599 Al, published July 16, 2009), and Johnson (US 7,332,002 B2, issued February 19, 2008). App. Br. 3; Final Act. 3. Appellants identify each of independent claims 1, 6, 9, along with their respective dependent claims, where applicable, as separate claim groupings. App. Br. 4. However, Appellants rely on the same arguments to address all three claim groupings. Id. at 8. Accordingly, we select claim 1 as representative of all the claims presented for review on appeal. Claims 3- 9 stand or fall with claim 1. 1 Fuel Tech, Inc. is identified as the real party in interest. App. Br. 1. 2 Appeal2017-009643 Application 12/501,590 OPINION After review of the respective positions provided by Appellants and the Examiner, we AFFIRM the rejection of claims 1 and 3-9 for the reasons presented by the Examiner. We add the following for emphasis. The subject matter of independent claim 1 is directed to a process for reducing slag cohesiveness and/or adhesiveness in a combustor resulting from the combustion of a high iron and/or calcium content slag-forming coal by introducing an aqueous liquid aluminum trihydroxide reagent into hot combustion gases generated in the combustor prior to the gases contacting the heat exchange equipment in the combustor, thereby decreasing the rate of fouling by slag and increasing the friability of resulting slag. The Examiner finds Smymiotis teaches controlling slag from combustion of coal containing iron or calcium using a slag controlling chemical comprising magnesium hydroxide that is introduced at various points in the form of a spray into the combustion gas. Final Act. 3--4; Smymiotis ,r,r 2, 17, 23-26, 30. The Examiner finds Smymiotis does not teach (1) the content of the coal containing iron in the form ofFe20 3 and/or calcium oxide or (2) the use of a chemical comprising aluminum trihydroxide as a slag controlling chemical. Final Act. 4--5. With respect to difference (1 ), the Examiner finds Johnson teaches the claimed high iron/calcium slag-forming coal was known in coal-fired furnaces and determined that it would have been obvious to one of ordinary skill in the art to use the coal as the combustion source in the process disclosed by Smymiotis. Final Act. 4; Johnson col. 2, 11. 1-39, col. 3, 11. 1-8, 43--45. With respect to difference (2), the Examiner finds Pastore teaches the use of aluminum hydroxide in liquid form as a slag-reducing agent combined with 3 Appeal2017-009643 Application 12/501,590 magnesium hydroxide in the combustion of coal. Final Act. 5; Pastore ,r,r 15, 22. The Examiner further relies on the combined teachings of Smymiotis and Pastore for the amount and size of particles for the aluminum hydroxide. Final Act. 5-6; Smymiotis ,r 6; Pastore ,r 21. The Examiner determines that it would have been obvious to one of ordinary skill in the art to add Pastore' s aqueous aluminum hydroxide to Smymiotis' s slag controlling agent because Pastore teaches its use with magnesium hydroxide as effective to reduce slag. Final Act. 5; Pastore ,r,r 17-18. Appellants argue that Johnson is not pertinent to the invention because it is directed to a technology that is different from the technology of the other references. App. Br. 5. According to Appellants, Johnson is directed to furnaces that require a liquid layer of slag at the location in a boiler that combustion is most intense and does not address the problem with particulate ash that leaves the combustor with the combustion gases and will foul heat transfer surfaces unless something is done. Id. We are unpersuaded. Appellants acknowledge in their Specification that there is an economic reason to use high iron/ calcium content coals in many plants. Spec. ,r 3. An applicant cannot defeat an obviousness rejection by asserting that the cited references fail to teach or suggest elements which the applicant has acknowledged are taught by the prior art. Constant v. Advanced Micro-Devices, Inc., 848 F. 2d 1560, 1570 (Fed. Cir. 1988) ("A statement in a patent that something is in the prior art is binding on the applicant and patentee for determinations of anticipation and obviousness."); In re Nomiya, 509 F.2d 566, 571 n.5 (CCPA 1975) (explaining that a statement by an applicant that certain matter is prior art is an admission that 4 Appeal2017-009643 Application 12/501,590 the matter is prior art for all purposes). Thus, there is no support for the argument that the type of coal itself is the patentable feature of the invention. Moreover, Appellants have not adequately explained why one skilled in the art would not have been capable of using Johnson's coal in a combustor if economically feasible and then treating the generated gases according to the combined teachings of Smymiotis and Pastore to reduce the impact of slag on the combustor components. KSR Int 'l Co. v. Teleflex Inc., 550 U.S. 398,421 (2007) ("A person of ordinary skill is also a person of ordinary creativity, not an automaton."); see also In re Sovish, 769 F.2d 738, 743 (Fed. Cir. 1985) (presuming skill on the part of one of ordinary skill in the art). Appellants argue neither Smymiotis, Pastore, nor their combined teachings disclose the use of aluminum trihydroxide alone as a slag reducing agent. App. Br. 5---6. We find this argument also unavailing. As noted by the Examiner, the language of claim 1 is drafted using the open transitional language of "comprising" and does not exclude the presence of additional slag reducing agents. Ans. 9. Further, Appellants direct us to no language in the claim that limits the slag reducing agent to only aluminum trihydroxide. Relying on the Declaration under 37 C.F.R. § 1.132 (Declaration)2 by co-inventor and Declarant Kent W. Schulz, Appellants contend that the use of magnesium hydroxide together with aluminum trihydroxide3, as taught by 2 The Declaration was submitted on December 23, 2014 and entered by the Examiner in the Final Action of April 27, 2015. 3 We understand that the aluminum hydroxide (1261) discussed in the Declaration and the Appeal Brief falls within the scope of the claimed aluminum trihydroxide. 5 Appeal2017-009643 Application 12/501,590 Pastore, leads to unexpectedly improved results in the control of slag while these materials, when used separately, were not effective. App. Br. 6; Deel. ,r,r 4---6 and Exhibit A. When evidence of secondary considerations is submitted, we begin anew and evaluate the rebuttal evidence along with the evidence upon which the conclusion of obviousness was based. In re Rinehart, 531 F.2d 1048, 1052 (CCPA 1976). The burden of establishing unexpected results rests on Appellants. Appellants may meet this burden by establishing that the difference between the claimed invention and the closest prior art was an unexpected difference. See In re Klosak, 455 F.2d 1077, 1080 (CCPA 1972). The unexpected results must be established by factual evidence, and attorney statements are insufficient to establish unexpected results. See In re Geisler, 116 F.3d 1465, 1470-71 (Fed. Cir. 1997). Further, a showing of unexpected results supported by factual evidence must be reasonably commensurate in scope with the degree of protection sought by the claims on appeal. In re Grasselli, 713 F.2d 731, 743 (Fed. Cir. 1983); In re Clemens, 622 F.2d 1029, 1035 (CCPA 1980). After weighing Appellants' evidence in support of patentability, including the Declaration, we agree with the Examiner's determination that a preponderance of the evidence weighs in favor of obviousness. Ans. 10. We first note that Appellants' arguments appear to be inconsistent with Appellants' showing of unexpected results because Appellants first argue that the claims are limited to the use of aluminum trihydroxide alone (App. Br. 5---6) and then argue that the combined use of aluminum trihydroxide and magnesium hydroxide is superior to aluminum trihydroxide by itself (id. at 6). Further, it is not clear that the showing distinguishes the 6 Appeal2017-009643 Application 12/501,590 claimed invention from the closest prior art, because Pastore expressly teaches using more than one slag-reducing ingredient. Moreover, the showing is not commensurate in scope with the claim because Declarant does not identify the composition of the high iron/calcium content coal used to perform the tests other than describing it as coal having an iron content higher than the Illinois Basin coals. Deel. ,r 3. In addition, Declarant has only tested a single aluminum trihydroxide reagent ( aluminum hydroxide (1261)) and has not adequately explained why this single reagent is representative of the broad scope of aluminum trihydroxide compositions claimed. Appellants also provide no details with respect to amounts and droplet sizes of the slag reducing reagent used. Thus, on this record, Appellants have not adequately explained why the evidence shows the improvement would have been unexpected by one of ordinary skill in the art and that the testing is reasonably commensurate in scope with the claims. Appellants additionally argue that one skilled in the art would not have been able to ascertain from the prior art references if their treatments would work to control slag in coals that are high in calcium or iron because the type of coal greatly affects the recovery of ash and effects of slag and there is no single set of data or charts available to predict ash and slag properties just because a chemical analysis has been done. App. Br. 6-8. Appellants also argue that none of the cited references disclose introducing a slag reducing agent in nano-sized particles of under 200 nanometers. Id. at 10. Appellants contend that they believe the particle size disrupts the normal crystalline or glass that forms the slag. Id. 7 Appeal2017-009643 Application 12/501,590 We are unpersuaded by these arguments because they are not supported by objective evidence showing the unpredictability of the art or the criticality of the slag-reducing agent's particle size. Appellants, at most, have provided mere attorney arguments and such arguments of counsel cannot take the place of evidence. See In re De Blauwe, 736 F.2d 699, 705 (Fed. Cir. 1984); In re Payne, 606 F.2d 303, 315 (CCPA 1979). Thus, Appellants have not adequately shown error in the Examiner's determination of obviousness. Accordingly, we affirm the Examiner's prior art rejection of claims 1 and 3-9 under 35 U.S.C. § 103(a) for the reasons presented by the Examiner and given above. ORDER The Examiner's prior art rejection of claims 1 and 3-9 under 35 U.S.C. § 103(a) is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED 8 Copy with citationCopy as parenthetical citation