Ex Parte SimpsonDownload PDFPatent Trial and Appeal BoardJan 27, 201713631212 (P.T.A.B. Jan. 27, 2017) Copy Citation United States Patent and Trademark Office UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O.Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 13/631,212 09/28/2012 John T. SIMPSON 59079-00336 [6321-410] 7061 46592 7590 01/31/2017 Foy RntWhilH T T P / TTTR EXAMINER 997 Lennox Drive NERANGIS, VICKEY M Building 3 Lawrenceville, NJ 08648 ART UNIT PAPER NUMBER 1768 NOTIFICATION DATE DELIVERY MODE 01/31/2017 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): ipdocket @ foxrothschild. com s vieau @ foxrothschild. com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte JOHN T. SIMPSON Appeal 2016-000172 Application 13/631,212 Technology Center 1700 Before ADRIENE LEPIANE HANLON, CATHERINE Q. TIMM, and JAMES C. HOUSEL, Administrative Patent Judges. PER CURIAM. DECISION ON APPEAL Appellant1 filed an appeal under 35U.S.C. § 134 from the Examiner’ decision rejecting claims 1—13.2 We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM-IN-PART.3 1 Appellant identifies the real party in interest as UT-Battelle, LLC. Br. 3. 2 Claims 14—33 have been withdrawn from consideration and are not before us on appeal. 3 Our decision refers to Appellant’s amended Specification (Spec.) filed September 28, 2012, the Final Office Action (Final Act.) received October 16, 2014, Appellant’s Appeal Brief (Br.) filed May 26, 2015, and the Examiner’s Answer (Ans.) mailed July 31, 2015. Appeal 2016-000172 Application 13/631,212 STATEMENT OF THE CASE The subject matter on appeal relates to superhydrophobic coatings (see, e.g., claim 1). Appellant discloses that superhydrophobic coatings are typically superhydrophobic only at their outer surfaces. Spec. 2:13—14. Once the outer surface containing superhydrophobic particles is abraded away, the coating is no longer superhydrophobic because any particles within the coating beneath the outer surface generally have their nanopores and nanotextured surfaces filled with the coating material. Id. at 2:14—18. In view of this, Appellant discloses a superhydrophobic coating including superhydrophobic particles embedded within a resin so that the resin does not completely fill the pores of the superhydrophobic particles. Id. at 2:25— 30. Thus, if an outer surface of the coating is abraded away, particles that were previously completely embedded within the coating can be exposed to impart superhydrophobicity to the coating. Id. at 6:2—18. Independent claim 1, reproduced below from the Claims Appendix to the Appeal Brief, is illustrative of the subject matter on appeal. The limitations at issue are italicized. 1. A superhydrophobic coating, comprising: a resin; and a plurality of superhydrophobic particles, wherein each superhydrophobic particle has a three dimensional, nanostructured surface topology, defining a plurality of pores, wherein at least a portion of the superhydrophobic particles are embedded within the resin so as to be surrounded by the resin, and wherein the resin does not fill the pores of the embedded superhydrophobic particles such that the three dimensional surface topology of the superhydrophobic particles is preserved. 2 Appeal 2016-000172 Application 13/631,212 Br. 10. The claims on appeal stand rejected, or provisionally rejected, as follows: (1) claims 1—3, 5, 6, and 8—13 under 35 U.S.C. § 102(b) as anticipated by Nun;4 (2) claim 7 under 35 U.S.C. § 102(b) as anticipated or, in the alternative, under 35 U.S.C. § 103(a) as unpatentable over Nun; (3) claim 4 under 35 U.S.C. § 103(a) as unpatentable over Nun and further in view of Simpson;5 and (4) claim 1 provisionally rejected under the ground of nonstatutory double patenting as unpatentable over claim 2 of copending Application No. 13/793,394. ANALYSIS Rejection under 35 U.S.C. §102 Claims 1—3, 5, 6, and 8—13 are rejected under 35 U.S.C. § 102(b) as anticipated by Nun. Appellant argues claims 1—3 and 9-13 as one group, claims 5 and 6 as a second group, and claim 8 as a third group. We select claims 1,5, and 8 as representative of these groups. The remaining claims stand or fall with the claim from which they depend. Claim 1 The Examiner finds Nun discloses self-cleaning hydrophobic surfaces that exhibit a “lotus effect” that can be self-regenerated. Ans. 2. The 4 Nun et al., US 2003/0013795 Al, published Jan. 16, 2003 (“Nun”). 5 Simpson et al., US 2010/0286582 Al, published Nov. 11, 2010 (“Simpson”). 3 Appeal 2016-000172 Application 13/631,212 surfaces comprise particles having fissured structures and having hydrophobic properties. Id. Because Nun discloses the fissured structures as advantageous for forming hydroscopic structures, the Examiner finds the fissured structures would be preserved, even upon adding the particles to the resin, as depicted in Figure 2 of Nun. Id. Appellant contends Nun does not disclose superhydrophobic particles, as recited in claim 1, because Nun merely discloses its particles as hydrophobic. Br. 4. To support this argument, Appellant cites a definition of superhydrophobic provided in U.S. Patent No. 8,216,674, issued July 10, 2012, incorporated by reference in its entirety at page 8 of the Specification. Br. 5. This patent states at column 1, lines 30—35: A super-hydrophobic surface is generally defined and defined herein as that which has a contact angle greater than 150° with a drop of water at normal ambient temperatures (about 25° C). The lotus leaf surface, for example, is known to be naturally super-hydrophobic due to the texture of its waxy surface. This argument is not persuasive of a reversible error. As stated by the Examiner, Nun describes its surface as providing a “lotus effect” in paragraph 27 of Nun. Ans. 2 and 5. This meets the definition of “superhydrophobic” provided by U.S. Patent No. 8,216,674, which includes the lotus leaf as a naturally occurring example of a superhydrophobic surface. Appellant further contends Nun does not disclose a superhydrophobic coating comprising a resin and superhydrophobic particles, “wherein at least a portion of the superhydrophobic particles are embedded within the resin so as to be surrounded by the resin” and “wherein the resin does not fill the pores of the embedded superhydrophobic particles such that the three 4 Appeal 2016-000172 Application 13/631,212 dimensional surface topology of the superhydrophobic particles is preserved” because the resin of Nun would fill the pores of its particles. Br. 5—6. Specifically, Appellant argues Figure 2a of Nun appears to show a carrier completely filling the pores of particles and Nun does not describe any way to prevent the pores from being filled with the carrier. Id. at 6. These arguments are also unpersuasive of a reversible error. The Examiner finds Nun discloses its surface includes particles so that when the surface is ablated by erosion, particles within the carrier are newly exposed on the surface, which provide the self-cleaning effect of the surface. Ans. 5. In other words, the Examiner finds that if particles that were formerly completely surrounded by the carrier (i.e., resin) of Nun are exposed via ablation of the self-cleaning surface and the exposed particles retain their hydrophobicity, the particles must have pores that were not filled by the carrier. Nun discloses that when particles of its self-cleaning hydrophobic surface are ablated, new particles are exposed to regenerate the self-cleaning effect. Nun abstract and 120. This is demonstrated in Figure 2a of Nun, which depicts the surface prior to ablation, Figure 2b of Nun, which depicts the surface after ablation. Therefore, the disclosure of Nun supports the Examiner’s findings that Nun discloses a self-cleaning hydrophobic surface that regenerates its self-cleaning hydrophobic properties when particles are ablated away to expose particles within the surface. Appellant has not responded to the Examiner’s findings and thus has not directed us to a reversible error in the Examiner’s findings.6 6 We further note Appellant defines “embedded” as including “not only particles that are completely surrounded or enveloped by the resin but also 5 Appeal 2016-000172 Application 13/631,212 Appellant additionally argues Nun discloses that self-regeneration of its surface is due to the binder being ablated more rapidly than the particles, which demonstrates self-regeneration is not due to preventing the carrier from filling pores of the particles. Br. 6. This argument is also unpersuasive because it demonstrates Nun regarded its particles as necessary for regeneration of its self-cleaning hydrophobic properties. Otherwise, if the binder (i.e., carrier) were not ablated more rapidly than the particles, the particles would be covered by the binder and the self-cleaning hydrophobic properties of the surface would be lost. See Nun 120. For the reasons described above and those set forth in the Examiner’s Answer, we sustain the Examiner’s § 102(b) rejection of claim 1 over Nun. Claims 2, 3, and 9—13 depend from claim 1. Therefore, we sustain the § 102 rejection of claims 2, 3, and 9—13 for the same reasons. particles that are only partially enveloped, enclosed, or surrounded in the surrounded resin.” Spec. 5:30 to 6:2. As a result, “particles are embedded within the resin so as to be surrounded by the resin,” as recited in claim 1, can include particles completely surrounded by the resin and particles partially surrounded by the resin. The Specification further describes an embodiment of a superhydrophobic coating including some particles that are completely embedded and some particles that are partially embedded. Id. at 6:2-4. This latter embodiment correlates to the surface shown in Figure 2a of Nun, which includes both particles completely surrounded by the carrier of Nun and particles at the surface of the carrier that are partially surrounded by the carrier. The particles partially surrounded by the carrier meet the definition set forth by Appellant for “embedded.” To the extent there are any pores in these particles at the surface of the carrier that have not come into contact with the carrier, the pores clearly would not be filled by the carrier, as recited in claim 1. 6 Appeal 2016-000172 Application 13/631,212 Claims 5 and 6 Claim 5, which depends from claim 1, further recites “wherein each of the plurality of superhydrophobic particles comprises a porous core, and wherein each porous core is hydrophilic.” Appellant asserts not only that Nun does not disclose these limitations, but that the Examiner has failed to provide any finding in this regard. Br. 6. “[T]he examiner bears the initial burden, on review of the prior art or on any other ground, of presenting a prima facie case of unpatentability.” In re Oetiker, 977 F.2d 1443, 1445 (Fed. Cir. 1992). In our review of the Examiner’s rejection, we are unable to locate any finding that Nun discloses superhydrophobic particles comprising a porous core “wherein each porous core is hydrophilic,” as recited in claim 5. Therefore, the preponderance of the evidence supports the Appellant’s argument and, thus, Appellant has identified a reversible error in the Examiner’s rejection. Claim 6 depends from claim 5 and therefore includes the recitations of claim 5. For these reasons, we do not sustain the Examiner’s rejection of claims 5 and 6 under 35 U.S.C. § 102(b) over Nun. Claim 8 Claim 8 depends from claim 1 and further recites “wherein the pore volume of the superhydrophobic particle is less than 50% filled by the resin.” Appellant argues “Nun provides absolutely no teaching or suggestion that this structure is even desirable.” Br. 6. However, the Examiner finds the self-cleaning hydrophobic surface of Nun includes resin and particles having fissured structures to provide hydrophobicity. Ans. 2. Therefore, the fissured structures would be preserved in the resin and the particles would 7 Appeal 2016-000172 Application 13/631,212 “inherently have less than 50% of pore volume filled with resin in order to preserve hydrophobic structure without resin within the porous and fissured structure.” Id. Appellant’s argument does not address this finding or otherwise demonstrate how the Examiner reversibly erred in this finding. For these reasons and those expressed in the Examiner’s Answer, we sustain the Examiner’s rejection of claim 8 under 35 U.S.C. § 102(b) over Nun. Rejection under 35 U.S.C. § 102/103 Claim 7 is rejected under 35 U.S.C. § 102(b) as anticipated or, in the alternative, under 35 U.S.C. § 103(a) as being unpatentable over Nun. Appellant does not argue claim 7 separately from claim 1. Br. 6. Therefore, we sustain the Examiner’s rejection of claim 7 under 35 U.S.C. § 102 as anticipated or, in the alternative, under 35 U.S.C. § 103. Rejection under 35 U.S.C. §103 The Examiner rejects claim 4 under 35 U.S.C. § 103(a) as being unpatentable over Nun in view of Simpson. Claim 4 further recites “wherein the superhydrophobic particle comprises a diatomaceous earth particle.” In the rejection of claim 4, the Examiner finds Nun discloses the use of inorganic particles, such as silica and silicates, but does not disclose the use of diatomaceous earth. Ans. 4. The Examiner finds Simpson discloses a superhydrophobic coating and that diatomaceous earth is a silicon-based material useful in superhydrophobic compositions. Id. The Examiner concludes it would have been obvious to modify Nun in view of Simpson to use diatomaceous earth for its superhydrophobic properties. Id. 8 Appeal 2016-000172 Application 13/631,212 Appellant argues the Examiner has relied upon impermissible hindsight to reject claim 4 because Nun provides no guidance about which particles to use. Br. 6—7. This argument is unpersuasive because Nun discloses its particles may be made from silicates, silicas, minerals, and other materials. Nun 147. Simpson discloses diatomaceous earth as a siliceous sedimentary rock resulting from the accumulation of the amorphous silica cell walls of dead diatoms (i.e., microscopic, single-cell aquatic plants, such as algae). Simpson 144. Simpson further discloses diatomaceous earth as having superhydrophobic properties. Id. As a result, the combined disclosures of Nun and Simpson support the Examiner’s findings and conclusion of obviousness. In particular, Nun discloses which materials are suitable for its particles and demonstrates it is within the skill of a person of ordinary skill in the art to select from these materials when practicing the invention disclosed by Nun. Because diatomaceous earth is formed from silica, diatomaceous earth is one of the types of materials disclosed by Nun and furthermore enjoys the benefit of being superhydrophobic, as disclosed by Simpson. Appellant further argues claim 4 is nonobvious due to unexpected results. Br. 7. Specifically, Appellant asserts Example 3 of the Specification demonstrates a coating having superhydrophobic properties (i.e., a contact angle greater than 150°) after abrasion due to 400 Taber cycles, which would not have been expected by one of ordinary skill in the art. Id. at 7—8. Appellant contends Nun provides no results to compare with Example 3 and Simpson is directed to bandages and would not have considered abrasive forces. Id. at 8. 9 Appeal 2016-000172 Application 13/631,212 The Examiner finds Example 3 does not include comparative data to demonstrate whether any results are unexpected. Ans. 6. We agree. “[W]hen unexpected results are used as evidence of nonobviousness, the results must be shown to be unexpected compared with the closest prior art.” In re Baxter Travenol Labs., 952 F.2d 388, 392 (Fed. Cir. 1991). Furthermore, Appellant has not provided results commensurate in scope with their claims, which are broader in scope than the specific materials used for Example 3. Establishing unexpected results includes the burden of providing evidence that is commensurate in scope with the claims. See In re Grasselli, 713 F.2d 731, 743 (Fed. Cir. 1983); In re Clemens, 622 F.2d 1029, 1035 (CCPA 1980). In addition, Appellant has provided mere attorney argument of unexpected results without submitting any evidence of unexpected results. See In re Heyna, 360 F.2d 222, 228 (CCPA 1966) (“It was incumbent upon appellants to submit clear and convincing evidence to support their allegation of unexpected property”). Based on the foregoing, after considering all the evidence anew, we determine a preponderance of the evidence supports the Examiner’s obviousness determination. Therefore, for these reasons and the reasons described in the Examiner’s Answer, we sustain the Examiner’s § 103 rejection of claim 4 over the combination of Nun and Simpson. Double patenting rejection Claim 1 is provisionally rejected under the ground of nonstatutory obviousness-type double patenting as being unpatentable over claim 2 of copending Application No. 13/793,394. No arguments regarding the propriety of the double patenting rejection have been proffered by Appellant. 10 Appeal 2016-000172 Application 13/631,212 We therefore summarily affirm the Examiner’s provisional non-statutory obviousness-type double patenting rejection of claim 1. DECISION On the record before us: A. the Examiner’s rejection of claims 1—3 and 8—13 under 35 U.S.C. § 102(b) as being anticipated by Nun is affirmed', B. the Examiner’s rejection of claims 5 and 6 under 35 U.S.C. § 102(b) as being anticipated by Nun is reversed', C. the Examiner’s rejection of claim 7 under 35 U.S.C. § 102(b) as anticipated or, in the alternative, under 35 U.S.C. § 103(a) as being unpatentable over Nun is affirmed', D. the Examiner’s rejection claim 4 under 35 U.S.C. § 103(a) as being unpatentable over Nun and further in view of Simpson is affirmed', and E. the Examiner’s provisional rejection of claim 1 under the ground of nonstatutory double patenting as being unpatentable over claim 2 of copending Application No. 13/793,394 is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1). AFFIRMED-IN-PART 11 Copy with citationCopy as parenthetical citation