Ex Parte Rahimo et alDownload PDFPatent Trial and Appeal BoardJan 16, 201814477229 (P.T.A.B. Jan. 16, 2018) Copy Citation United States Patent and Trademark Office UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O.Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 14/477,229 09/04/2014 MunafRAHIMO ABBCH-00140 7985 129925 ARR Tno 7590 01/18/2018 EXAMINER Taft, Stettinius & Hollister LLP One Indiana Square GHEYAS, SYED I Suite 3500 ART UNIT PAPER NUMBER Indianapolis, UN 4b2U4-2U23 2812 NOTIFICATION DATE DELIVERY MODE 01/18/2018 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): taft-ip-docket @ taftlaw. com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte MUNAF RAHIMO, CHIARA CORVASCE, JAN VOBECKY, and YOICHI OTANI Appeal 2017-002492 Application 14/477,229 Technology Center 2800 Before CATHERINE Q. TIMM, WESLEY B. DERRICK, and DEBRA L. DENNETT, Administrative Patent Judges. TIMM, Administrative Patent Judge. DECISION ON APPEAL1 STATEMENT OF CASE Pursuant to 35 U.S.C. § 134(a), Appellant2 appeals from the Examiner’s decision to reject claims 1—3, 6—8, 10-13, and 16—18 under 1 In explaining our Decision, we cite to the Specification dated September 4, 2014 (Spec.), Final Office Action dated September 8, 2015 (Final), Appeal Brief dated March 8, 2016 (Appeal Br.), Examiner’s Answer dated September 29, 2016 (Ans.), and Reply Brief dated November 23, 2016 (Reply Br.). 2 Appellant is the Applicant, ABB Technology AG, which, according to the Appeal Brief, is the real party in interest. Appeal Br. 2. Appeal 2017-002492 Application 14/477,229 35 U.S.C. § 103(a) as obvious over Suzuki3 in view of Miyazaki,4 Miyairi,5 and Hawryluk6 and the rejection of claims 4, 5, 9, 14, 15, 19, and 20 as obvious over those references in view of further prior art. We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM. In arguing against the Examiner’s rejections, Appellant focuses on the rejection of claim 1 (Appeal Br. 6—12). Thus, the question on appeal is whether Appellant has identified a reversible error in the Examiner’s rejection of claim 1. Claim 1 is directed to a method for manufacturing a power semiconductor device including steps of depositing a titanium deposition layer on the second main side of a doped wafer and laser annealing the titanium deposition layer at a temperature higher than 1200 °C. The result is an intermetal compound layer, such as titanium silicide, at an interface between the titanium deposition layer and the wafer. Annealing also causes diffusion of the dopant into the wafer. Claim 1 reads: 1. A method for manufacturing a power semiconductor device, comprising: providing a wafer of a first conductivity type, which wafer has a first main side and a second main side opposite to the first main side, part of the wafer having an unamended doping concentration forming a drift layer; applying on the second main side at least one of a dopant of the first conductivity type for forming a layer of the first 3 Suzuki et al., US 2008/0102576 Al, published May 1, 2008. 4 Miyazaki et al., US 5,623,157, issued Apr. 22, 1997. 5 Miyairi, US 2008/0299743 Al, published Dec. 4, 2008. 6 Hawryluk et al., US 6,303,476 Bl, issued Oct. 16, 2001. 2 Appeal 2017-002492 Application 14/477,229 conductivity type and a dopant of a second conductivity type, which is different from the first conductivity type, for forming a layer of the second conductivity type; depositing a Titanium deposition layer on the second main side after the applying of the dopant; laser annealing the Titanium deposition layer at a temperature higher than 1200 °C so that simultaneously (i) an intermetal compound layer is formed at an interface between the Titanium deposition layer and the wafer (ii) and the at least one dopant is diffused into the wafer, and so that the Titanium deposition layer will act as a light absorber to achieve an increased temperature in the wafer below the Titanium deposition layer; and creating a first metal electrode layer on the second side. Appeal Br., Claims Appendix 1. OPINION The Examiner finds Suzuki teaches a method of manufacturing a power semiconductor including providing a wafer, applying dopants, depositing a titanium deposition layer, and creating a first metal electrode as required by claim 1. Final 3. The Examiner further finds Suzuki teaches a laser annealing step, but acknowledges that Suzuki does not disclose the temperature or the intent to form an intermetal compound layer while simultaneously diffusing dopant into the wafer, and also does not disclose the titanium layer as acting as a light absorber. Final 3^4. Thus, the Examiner turns to Miyazaki’s teaching of laser annealing a titanium deposition layer overlying a doped silicon layer to show that it was known in the art to laser anneal after depositing the titanium layer to diffuse the dopant and to simultaneously achieve low 3 Appeal 2017-002492 Application 14/477,229 contact resistance by forming titanium silicide at the interface between the titanium and silicon. Final 4. As to the temperature, the Examiner determines that Miyazaki teaches the general conditions of the annealing process such that discovering the optimum or workable ranges of annealing temperature would have involved only routine skill in the art and provides an evidentiary basis and reasoning indicating that temperatures above 1200 °C would have been within the optimal or workable ranges. Final 5—6. The Examiner further finds that the titanium layer inherently acts as a light absorber to achieve an increased temperature in the wafer below the titanium deposition layer and provides Miyairi to support this finding. Final 6. The Examiner also relies upon Hawryluk to support the finding that the use of temperatures above 1200 °C was known in the art for laser annealing titanium deposition layers to diffuse dopant into wafers and it was known that the titanium layer acts as a light absorber. Final 6—7. Appellant contends that the Examiner’s proposed combination of prior art fails to disclose or suggest the combination of features (B)-(D) as recited in claim 1. Appeal Br. 9. Appellant further contends that “the Examiner has, in several cases, disregarded the express teachings of the applied references in an attempt to piece together incongruous teachings of the applied references to arrive at the features of the claimed invention.” Appeal Br. 10. Appellant specifically finds fault with the Examiner’s determination that Miyazaki teaches the general conditions of laser annealing and tries to differentiate Miyairi and Hawryluk from the method of the claims based on a teaching in those references that the heating method is indirect. Appeal Br. 10-11. 4 Appeal 2017-002492 Application 14/477,229 We determine a preponderance of the evidence supports the Examiner’s well-presented and detailed findings of fact, analysis, and conclusions of law. We agree with the Examiner that Appellant has misinterpreted the prior art and we incorporate by reference the Examiner’s thorough response to Appellant’s arguments. Ans. 3—15. We add the following for emphasis. The Examiner finds that Suzuki teaches manufacturing a power semiconductor device including steps of providing a wafer and doping it, depositing a titanium layer, and creating a first metal electrode as required by claim 1. Final 3. These findings are supported by Suzuki. Suzuki teaches a power semiconductor device with a silicon substrate 20, doped regions 9 and 10, and a back electrode 14 with a titanium layer 11 in contact with the doped regions 9 and 10. Suzuki H 25, 28—31. The Examiner further finds that Suzuki teaches laser annealing to diffuse the dopant into the wafer. Final 3. Suzuki supports this finding as well. Suzuki teaches activating dopant regions 9 and 10 by laser annealing. Suzuki 147. Laser annealing is used to control diffusion depth and peak concentration in region 9 so that excellent ohmic contact between back electrode 14 and semiconductor substrate 20 is achieved and an increase in the ON voltage can be further prevented. Suzuki 135. The Examiner acknowledges that Suzuki does not teach laser annealing the titanium layer at a temperature higher than 1200 °C to form an intermetal compound layer at the interface with the wafer and diffuse the dopant. Final 3^4. Suzuki teaches laser annealing the doped wafer before depositing the titanium layer in order to use high temperatures, i.e., temperatures higher than the melting point of the back electrode, to activate 5 Appeal 2017-002492 Application 14/477,229 the dopants. Suzuki | 55. Performing the laser anneal before depositing the titanium layer reduces warping between the silicon wafer and back electrode due to the difference in thermal coefficient of expansion between these materials. Suzuki || 11, 13. However, Suzuki also indicates that heat treatment after forming back electrodes was known in the art for achieving excellent ohmic contact albeit with back electrodes of a different composition such as Al/Mo/Ni/Au back electrodes. Suzuki 110. Although Suzuki laser anneals before depositing the titanium layer, Suzuki discloses that the timing of the laser anneal has little effect on ON voltage properties VcE(sat) and V/ when using a Ti/Ni/Au back electrode. Suzuki || 63, 65. As a whole, Suzuki provides evidence that performing laser annealing after depositing the titanium layer would have been known in the art although those of ordinary skill would have expected some product loss due to warpage. The Examiner finds Miyazaki teaches laser annealing a titanium deposition layer to form an intermetal compound layer and to diffuse dopant into the wafer. Final 4. Miyazaki supports the Examiner’s finding. Like Suzuki, Miyazaki seeks to form a good ohmic contact. Miyazaki, col. 3, 11. 15—45. Titanium silicide was known to form a good ohmic contact. Id. Miyazaki teaches forming a titanium film 212 over doped regions 208, 209, 210, 211 of silicon that reside on a glass substrate 201. Miyazaki, col. 8, 11. 38—53; col. 9,11. 39-55; Figs. 7(C), 7(E), 7(F). Miyazaki irradiates the structure with a KrF excimer laser of wavelength 248 nm and a pulse width of 20 nsec to activate the implanted impurity (dopant) and to cause the titanium film to react with the silicon to form regions 213 and 214 of titanium silicide intermetal compound. Miyazaki, col. 9,11. 56—65; 6 Appeal 2017-002492 Application 14/477,229 Fig. 7(G). Miyazaki does not disclose the temperature to which the titanium layer is heated during the laser annealing. Id. Miyazaki merely provides guidance regarding the temperature to which the glass substrate should be heated. Id. According to Miyazaki, “[w]hen the laser light was illuminated, if the substrate was heated to 200° to 500° C., then the peeling of the titanium film could be suppressed.” Id. Miyazaki discloses an alternate embodiment of irradiating with visible or near infrared light using a lamp to heat the surface to about 800-1000°C. Miyazaki, col. 10,11. 16—29. Lamp annealing at 800 °C requires a longer heating time of several minutes whereas the higher temperature of 1000 °C can be conducted for a shorter time period of tens of seconds. Id. Thus, the evidence supports the Examiner’s finding that one of ordinary skill in the art would have conducted the annealing to create a temperature gradient of high temperature at the surface and lower temperature in the substrate to prevent peeling of the titanium layer. Ans. 11—12. Given that Miyazaki is silent with respect to the laser annealing surface temperature and laser heating is more localized than lamp annealing and Miyazaki teaches performing the annealing for the same purpose of Appellant, i.e., to activate the dopant and form an intermetal compound of titanium silicide, we agree with the Examiner that Miyazaki teaches the general conditions of the process such that performing routine optimization would have resulted in laser annealing temperatures higher than 1200 °C. Ans. 11—13. The evidence is sufficient to shift the burden to Appellant to show that they obtain some unexpected result from heating to above 1200 °C. See In re Alter, 220 F.2d 454, 456 (CCPA 1955) (explaining that where the general conditions of a claimed process are disclosed in the prior 7 Appeal 2017-002492 Application 14/477,229 art, patentability does not lie in discovering the optimum or workable ranges for process parameters such as temperature or concentration by routine experimentation, instead the burden shifts to the applicant to show that the particular ranges recited in the claim are critical for producing an unexpected result). Appellant contends that because Miyazaki does not disclose a range of temperature overlapping Appellant’s higher than 1200 °C range, it cannot be said that claim 1 is only directed to an optimal working range. Reply Br. 4. Appellant oversimplifies the state of the law. The prior art need not disclose an overlapping range; it need only disclose the general conditions the ordinary artisan would use to experiment to discover the optimum conditions. See In re Aller, 220 F.2d at 456 (upholding a conclusion of obviousness where the prior art the general conditions of the process, but exemplified the use of lower temperatures and higher sulphuric acid concentrations); In re Kulling, 897 F.2d 1147, 1149 (Fed. Cir. 1990) (upholding a finding that the amount of eluent to be used in a washing sequence was a matter of routine optimization where the reference failed to provide any numerical quantities). The evidence also supports the Examiner’s finding that the titanium layer inherently acts as a light absorber to achieve the increased temperature in the wafer region below the titanium layer. Laser irradiation heats the region under the titanium layer to cause the diffusion of the dopant in the silicon layer and form the titanium silicide. Miyazaki, col. 9,11. 56—61. CONCLUSION We sustain the Examiner’s rejections. 8 Appeal 2017-002492 Application 14/477,229 DECISION The Examiner’s decision is affirmed. TIME PERIOD FOR RESPONSE No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1,.136(a)(1). AFFIRMED 9 Copy with citationCopy as parenthetical citation