Ex Parte Qin et alDownload PDFBoard of Patent Appeals and InterferencesMar 31, 201011153190 (B.P.A.I. Mar. 31, 2010) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE ____________________ BEFORE THE BOARD OF PATENT APPEALS AND INTERFERENCES ____________________ Ex parte JIAN QIN, SANDRA M. ROGERS, MICHAEL J. NIEMEYER, KENNETH R. JR. SCHUELER, STEVEN M. HURLEY, LAWRENCE H. SAWYER, WHEI-NEEN HSU, MARK C. JOY, SCOTT J. SMITH, MARKUS FRANK, and NANCY B. LANGE ____________________ Appeal 2009-009911 Application 11/153,190 Technology Center 1700 ____________________ Decided: March 31, 2010 ____________________ Before MICHAEL P. COLAIANNI, JEFFREY T. SMITH, and JEFFREY B. ROBERTSON, Administrative Patent Judges. COLAIANNI, Administrative Patent Judge. DECISION ON APPEAL This is a decision on an appeal under 35 U.S.C. § 134 from the Examiner's final rejection of claims 1 through 23, 25 through 28, 30 Appeal 2009-009911 Application 11/153,190 2 through 32, and 34 through 62 which are all of the claims pending in the above-identified application. We have jurisdiction pursuant to 35 U.S.C. § 6. We AFFIRM. STATEMENT OF THE CASE The subject matter on appeal is directed to an absorbent structure. Claim 1 is illustrative: 1. An absorbent structure comprising at least in part a superabsorbent material comprising a crosslinked superabsorbent polymer or combination of polymers comprising from about 55 to about 99.9 weight percent of polymerizable unsaturated acid group containing monomers, the superabsorbent material having a retention capacity (CRC) as determined by a Centrifuge Retention Capacity Test of at lest about 25 g/g and a free swell gel bed permeability (GBP) as determined by a Free Swell Gel Bed Permeability Test of at least 575 x 10-9 cm2. As evidence of unpatentability of the claimed subject matter, the Examiner relies upon the following references: Kellenberger '335 5,149,335 Sep. 22, 1992 Smith 5,462,972 Oct. 31, 1995 Kellenberger '461 EP 0 339 461 A1 Nov. 2, 1989 Johnson WO 95/11932 May 4, 1995 The Examiner maintains the following rejections1, 2: 1 As is apparent from pages 5 through 8 of the Final Rejection (mailed on Mar. 19, 2008) and pages 2, 3, and 6 of the Answer, the Examiner has withdrawn both of the § 102(b)/§103(a) rejections of claims 15-17 and 38-40 over Johnson and over Smith. In addition, the Examiner entered new grounds of rejection of claims 15-17 and 38-40 under § 103(a) over Johnson and Kellenberger '461 and over Smith and Kellenberger '461. Appeal 2009-009911 Application 11/153,190 3 1) Claims 1-14, 18-23, 25-28, 30-32, 34-37, and 41-62 under 35 U.S.C. § 102(b) or, in the alternative, under 35 U.S.C. § 103(a) over Johnson; 2) Claims 1-23, 25-28, 30-32, and 34-61 under 35 U.S.C. § 102(b) or, in the alternative, under 35 U.S.C. § 103(a) over Kellenberger '335; 3) Claims 1-14, 18-23, 25-28, 30-32, 34-37, and 41-61 under 35 U.S.C. § 102(b) or, in the alternative, under 35 U.S.C. § 103(a) over Smith; 4) Claims 15-17 and 38-40 under 35 U.S.C. § 103(a) over Johnson and Kellenberger '461; and 5) Claims 15-17 and 38-40 under 35 U.S.C. § 103(a) over Smith and Kellenberger '461. REJECTION (1): The rejection under § 102 or § 103 over Johnson The § 102 rejection ISSUE Did the Examiner err in finding that Johnson teaches “a superabsorbent material comprising a crosslinked superabsorbent polymer or combination of polymers comprising about 55 to about 99.9 weight percent of polymerizable unsaturated acid group containing monomers” as required by claims 1, 23, 60, 61, and 62? We decide this issue in the affirmative. PRINCIPLE OF LAW As stated in Net MoneyIN, Inc. v. VeriSign, Inc.: 2 We vacate Rejections (2), (3), and (5) because these rejections are cumulative to Rejections (1) and (4). Appeal 2009-009911 Application 11/153,190 4 [U]nless a reference discloses within the four corners of the document not only all of the limitations claimed but also all of the limitations arranged or combined in the same way as recited in the claim, it cannot be said to prove prior invention of the thing claimed and, thus, cannot anticipate under 35 U.S.C. § 102. . . . differences between the prior art reference and a claimed invention, however slight, invoke the question of obviousness, not anticipation. . . . see also In re Arkley, 59 C.C.P.A. 804, 455 F.2d 586, 587 (1972) (“[R]ejections under 35 U.S.C. § 102 are proper only when the claimed subject matter is identically disclosed or described in the prior art.” (emphasis and internal quotation marks omitted)). 545 F.3d 1359, 1371 (Fed. Cir. 2008). In addition, as stated in Atofina v. Great Lakes Chem. Corp., although there is a slight overlap [i.e., the prior art's range of 0.001 to 1.0 percent slightly overlaps the claimed range of 0.1 percent to 5.0 percent], no reasonable fact finder could determine that this overlap describes the entire claimed range with sufficient specificity to anticipate this limitation of the claim. The ranges are different, not the same. . . . the disclosure of a 0.001 to 1.0 percent range is not a disclosure of the end points of that range. Thus, there is no anticipation. 441 F.3d 991, 1000 (Fed. Cir. 2006). FINDINGS OF FACT 1. The Specification discloses that "[t]he crosslinked superabsorbent polymer is obtained by the initial polymerization of from about 55 to about 99.9 wt. percent of polymerizable unsaturated acid group containing monomers. Suitable monomers include those containing carboxyl groups, such as acrylic acid." (Spec. ¶ [0037]). Appeal 2009-009911 Application 11/153,190 5 2. Appellants do not specifically dispute the Examiner's finding that JOHNSON et al. discloses a particulate polymeric materials which is a partially neutralized polymer of an ethylenically unsaturated carboxylic monomer cross linked by a tryethylenic [sic] or higher ethylenic cross linking agent. (Abstract; page 2, lines 24-28) . . . . The polymerization is generally conducted on aqueous monomer solution having a monomer content in the range 25 to 60%. (Page 7, lines 11-13). (Compare Ans. 3-4 with App. Br. 5-8 and 15-19, and Reply Br. 1-8). In one of the sections relied upon by the Examiner, Johnson teaches that the "polymeric material has been obtained by copolymerisation [sic] of monoethylenically unsaturated carboxylic monomer and a polyethylenically unsaturated cross linking agent . . ." (Johnson, p. 2, ll. 24-26). In that regard, Johnson teaches that "[t]he monoethylenically unsaturated carboxylic monomer is generally acrylic acid . . . It can be copolymerized with other water soluble monomers but generally the polymer is a homopolymer of acrylic acid." (Johnson, p. 6, ll. 29-33). ANALYSIS AND CONCLUSION Appellants argue that "it cannot be assumed that simply because two superabsorbent polymers have similar starting materials . . . they will inherently (i.e., necessarily) have the same properties [e.g., the claimed amount of monomer]." (App. Br. 7). We agree. The Examiner has not specifically identified an embodiment in Johnson that teaches, inter alia, a crosslinked superabsorbent polymer or combination of polymers that comprises from about 55 to about 99.9 weight percent of polymerizable unsaturated acid group containing monomers as required by claims 1, 23, 60, 61, and 62. (See generally, Ans. 3-5). Appeal 2009-009911 Application 11/153,190 6 In this regard, while Johnson teaches that polymerization is conducted in a solution having a monomer, which may be a monoethylenically unsaturated carboxylic monomer such as acrylic acid (polymerizable unsaturated acid group containing monomers), in the amount of 25 to 60%, Johnson does not disclose within the four corners of the document all of the claimed limitations arranged in the same way as recited in the claims (i.e., the limitation "about 55 to about 99.9 weight percent of polymerizable unsaturated acid group containing monomers" as recited in the claims 1, 23, 60, 61, and 62). This difference in polymerizable unsaturated acid group containing monomers, "however slight, invoke[s] the question of obviousness, not anticipation." Net MoneyIN, 545 F.3d at 1371. In addition, although Johnson discloses a range having an end point of 60%, our reviewing court has held that "the disclosure of a . . . range is not a disclosure of the end points of that range." Atofina , 441 F.3d at 1000. (emphasis added). Accordingly, because the Examiner directs us to no specific embodiment in Johnson that teaches an amount of monomer falling within the range required by claims 1, 23, 60, 61, and 62, we agree with Appellants that there is no anticipation. Thus, it follows that Appellants have identified reversible error in the Examiner's finding that Johnson teaches the "about 55 to about 99.9 weight percent of polymerizable unsaturated acid group containing monomers" feature required by claims 1, 23, 60, 61, and 62. Accordingly, for the reasons stated by Appellants in the Briefs and above, we reverse the Examiner's decision rejecting claims 1-14, 18-23, Appeal 2009-009911 Application 11/153,190 7 25-28, 30-32, 34-37, and 41-62 under 35 U.S.C. § 102(b) as anticipated by Johnson. The § 103 rejection Appellants argue the claims in five groups: (1) claims 1-22 and 46-52; (2) claims 23, 25-28, 30-32, 34-45, and 53-59; (3) claim 60; (4) claim 61; and (5) claim 62. (App. Br. 5-19 and Reply Br. 1-7). With respect to claim group (1), we address Appellants' arguments regarding the rejection with respect to claim 1 only, as argued by Appellants. With respect to the claims in claim groups (2) through (4), Appellants do not advance any specific argument regarding the rejection of the claims. Id. Instead, in each of these claim groups, Appellants refer to arguments made in connection with the rejection of claim 1 in claim group (1). Id. Accordingly, we address Appellants' arguments regarding the rejection of claims 23, 25-28, 30-32, 34-45, and 53-61 with respect to claim 1 only. See 37 C.F.R. § 41.37(c)(1)(vii). With respect to claim group (5), we address Appellants' arguments regarding the rejection with respect to claim 62 only, as argued by Appellants. Claim 1 ISSUE Have Appellants identified reversible error in the Examiner's determination that Johnson would have rendered obvious an absorbent structure having a free swell gel bed permeability value within the range required by claim 1? We decide this issue in the negative. Appeal 2009-009911 Application 11/153,190 8 ADDITIONAL FINDINGS OF FACT (FF) 3. The Examiner finds and Appellants do not specifically dispute that [Johnson teaches that] . . . [a]mong the cross linking agents taught by the reference is triallyamine. (Page 5, line 20) The amount of cross linker may be selected within the conventional range of 0.05 to 3%. (Page 6, lines 26-28) The degree of polymerization or in the final polymer is usually at least 50% and generally at least 70%. (Page 6, lines 33-37) The reference further teaches subjecting the particles to a surface cross-linking treatment. The surface cross linking may be brought about by contact of the surfaces with an inorganic cross linking agent such as aluminum sulphate, sodium aluminate or other polyvalent metal compound. (Page 7, lines 25-36 - Page 8, lines 1-2) The reference further teaches supplementing the surface cross linking effect by treating the surface with finely divided silica. (Page 8, lines 12- 14). (Compare Ans. 4 with App. Br. 8-19 and Reply Br. 1-8). 4. Johnson teaches that "it is necessary to optimise [sic] the processes of making the particulate superabsorbent material in order to obtain the desired properties," such as maintaining a commercial centrifuge retention capacity. (Johnson, p. 3, ll. 4-17). Johnson also teaches that "there are several variables involved in the production of superabsorbent particles (including initiation conditions, monomer concentration, choice and amount of cross linking agent and surface cross linking) there are several variables that can be adjusted in order to obtain the required properties." (Johnson, p. 3, ll. 9-14). ADDITIONAL PRINCIPLES OF LAW The recitation of a property or characteristic not disclosed by the prior art does not necessarily confer patentability to a composition or a method of using that composition. See In re Skoner, 517 F.2d 947, 950 (CCPA 1975). Appeal 2009-009911 Application 11/153,190 9 “[D]iscovery of an optimum value of a result effective variable in a known process is ordinarily within the skill of the art.” In re Boesch, 617 F.2d 272, 276 (CCPA 1980). As stated in Ex parte Obiaya: The test of obviousness under 35 U.S.C. § 103 is not the express suggestion of the claimed invention in any or all of the references, but what the references taken collectively would suggest to those of ordinary skill in the art presumed to be familiar with them. . . . The fact that appellant has recognized another advantage which would flow naturally from following the suggestion of the prior art cannot be the basis for patentability when the differences would otherwise be obvious. 227 USPQ 58, 60 (BPAI 1985). "[A]ppellants have the burden of explaining the data in any declaration they proffer as evidence of non-obviousness." Ex parte Ishizaka, 24 USPQ2d 1621, 1624 (BPAI 1992). ANALYSIS AND CONCLUSION Appellants argue that there is no "teaching or suggestion in Johnson, et al. as to how one skilled in the art would modify the Johnson, et al. disclosure to arrive at . . . [the claimed] superabsorbent material." (App. Br. 10). We disagree. As correctly found by the Examiner at page 4 of the Answer, Johnson teaches that "it is necessary to optimize the processes of making the particulate superabsorbent material in order to obtain the desired properties," such as maintaining a commercial centrifuge retention capacity (CRC). (See also FF 4). In this regard, given factual finding 4 above, Johnson teaches that several variables such as initiation conditions, monomer concentration, Appeal 2009-009911 Application 11/153,190 10 choice and amount of cross linking agent and surface cross linking are result effective variables that affect the centrifuge retention capacity (CRC) of a superabsorbent material. Thus, we agree with the Examiner that optimizing such result- effective variables to suit the particular end use (i.e., superabsorbent material having a commercial CRC value) would have been well within the ambit of one of ordinary skill in the art. See Boesch, 617 F.2d at 276. In addition, once the result-effective variables have been optimized to suit the particular end use, we further determine that a GBP value within the claimed range of at least 575 x 10-9 cm2 would follow naturally from the suggestion of Johnson since Johnson's absorbent structure has substantially the same ingredients and in substantially the same amounts as Appellants'. See Obiaya, 227 USPQ at 60. (See FF 3). Accordingly, Appellants' arguments are unpersuasive of reversible error. Appellants also argue that there is simply no reason or motivation to modify the teachings of Johnson, et al. to arrive at applicants claimed absorbent structure. As noted above, there is no disclosure in Johnson, et al. of free swell gel bed permeability generally, or that absorbent structures having applicants' claimed free swell gel bed permeability are desirable. (App. Br. 11-12). In addition, Appellants argue that in this present case there must be an enabling disclosure of superabsorbent material having a CRC as determined by a Centrifuge Retention Capacity Test of at least about 25 g/g and a GBP as determined by a Free Swell Gel Bed Permeability Test of at least 575 x 10-9 cm2. However, as noted above, Johnson, et al. do not mention GBP, much less describe how Appeal 2009-009911 Application 11/153,190 11 one skilled in the art would produce superabsorbent materials having the claimed combination of CRC and GBP. (App. Br. 12). It is well settled that the recitation of a property not disclosed by the prior art product does not necessarily confer patentability to the claimed product. See Skoner, 517 F.2d at 950. In our case, while it is true that Johnson does not expressly teach any GBP value, such argument is unpersuasive because it fails to identify reversible error in the Examiner’s determination that an absorbent structure having a GBP value within the claimed range would have been obvious within the meaning of § 103. Appellants also argue that Johnson, et al. have in fact suggested that superabsorbent materials made from similar starting materials will not inherently have the same properties. For instance, Johnson, et al. note that ideally a superabsorbent material would have optimum properties for CRC, AUL, and rewet parameter tests, but that superabsorbents having one desirable characteristic (e.g., good AUL) may have undesirable characteristics for another parameter (e.g., rewet parameters). (App. Br. 12-13). While Johnson teaches at page 2, lines 12-15 that superabsorbent materials having one desirable characteristic, such as good AUL (absorption under load), "frequently give poor rewet test results," Appellants have not explained how these rewet test results correspond to the claimed range of GBP values. Indeed, Johnson does not teach that superabsorbents having a good CRC value also have a poor GBP value (i.e., one outside the claimed range). Accordingly, Appellants' arguments are without persuasive merit. Appeal 2009-009911 Application 11/153,190 12 In an attempt to show that a GBP value within the claimed range would not flow naturally from the modification of Johnson, Appellants argue that "as noted above . . . the Johnson, et al. reference fails to . . . suggest [a] superabsorbent material having a free swell gel bed permeability as set forth in claim 1." (App. Br. 9 and 10). In that regard, Appellants argue that [i]n the declaration, Mr. Qin discusses . . . absorbent products that have an absorbent layer comprising in part a water soluble resin that may comprise crosslinked polymers containing acrylic acid salt and/or acrylic acid as the main monomer content of the polymer. Two superabsorbent materials disclosed as suitable superabsorbents . . . i.e., Favor 880 and Dow 2035 were tested for GBP, centrifuge retention capacity (CRC), and absorbency under load. Through testing, it was determined that neither of these absorbent polymers have the CRC and GBP values recited in claim 1. (App. Br. 7-8). However Appellants' arguments and evidence are directed to two superabsorbent materials (i.e., Favor 889 and Dow 2035) not relied upon by the Examiner to arrive at the claimed invention. (See FF 3). In addition, Appellants have not explained how the evidence provided in the Qin Declaration with respect to Favor 880 and Dow 2035 is relevant to Johnson's superabsorbent material relied upon by the Examiner. See Ishizaka, 24 USPQ2d at 1624. Accordingly, Appellants' arguments and evidence are insufficient to establish that a GBP value within the claimed range would not flow naturally from the modification of Johnson. Thus, it follows that Appellants have not identified reversible error in the Examiner's determination that Johnson would have rendered obvious an Appeal 2009-009911 Application 11/153,190 13 absorbent structure having a free swell gel bed permeability value within the range required by claim 1. Claim 62 Appellants argue that "Claim 62 is submitted to be patentable over Johnson, et al. because Johnson, et al. do not disclose or suggest each and every element of claim 62." (App. Br. 18). In particular, Appellants argue that "there is no disclosure or suggestion of superabsorbent polymers comprising both a polyvalent metal salt and a surface crosslinking agent." (App. Br. 18-19, FN 15). We disagree. Johnson teaches that "surface cross linking using a dilute aqueous solution of . . . [a] covalent cross linking agent [surface crosslinking agent], preferably in combination with. . . [an] aluminum salt [polyvalent metal salt]." (Johnson, p. 10). Stated differently, Johnson also teaches that "surface cross linking may be brought about by contact . . . with . . . aluminum sulfate [which is an aluminum salt] . . . Preferably, however, some or all of the cross linking is by reaction with a material that reacts covalently with the polymer." (Johnson, pp. 7 and 8). Accordingly, Appellants' argument is without persuasive merit. REJECTION (4): The § 103 rejection over Johnson and Kellenberger '461 With respect to Rejection (4), Appellants do not specifically argue any feature unique to claims 15-17 and 38-40, each of which ultimately depends from independent claim 1 or independent claim 23, but instead rely on the arguments they presented in rejection (1), which apply to both claim 1 and Appeal 2009-009911 Application 11/153,190 14 claim 23. (Reply Br. 1-4). We, therefore, sustain the rejection of claims 15- 17 and 38-40 for the reasons given above. ORDER For the above reasons, Rejection (1)'s § 103 rejection and Rejection (4) are sustained; Rejection (1)'s § 102 rejection is reversed; and cumulative Rejections (2), (3), and (5) are vacated. Accordingly, the Examiner's decision is affirmed. TIME PERIOD No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1)(2009). AFFIRMED cam CHRISTOPHER M. 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