Ex Parte Piner et alDownload PDFPatent Trial and Appeal BoardMay 21, 201812023480 (P.T.A.B. May. 21, 2018) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE FIRST NAMED INVENTOR 12/023,480 01/31/2008 Edwin L. Piner 57579 7590 05/23/2018 MURPHY, BILAK & HOMILLER/INFINEON TECHNOLOGIES 1255 Crescent Green Suite 200 CARY, NC 27518 UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 1012-1419/2004P80148 US02 7457 EXAMINER TRAN,TONY ART UNIT PAPER NUMBER 2894 NOTIFICATION DATE DELIVERY MODE 05/23/2018 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): official@mbhiplaw.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte EDWIN L. PINER, JOHN C. ROBERTS, and PRADEEP RAJAGOP AL Appeal2017-005909 Application 12/023 ,480 Technology Center 2800 Before ADRIENE LEPIANE HANLON, CATHERINE Q. TIMM, and JAMES C. HOUSEL, Administrative Patent Judges. HOUSEL, Administrative Patent Judge. DECISION ON APPEAL 1 Appellants2 appeal under 35 U.S.C. § 134 from the Examiner's decision finally rejecting claims 1 and 4--20 under 35 U.S.C. § 103(a) as unpatentable over Frayssinet3 and Sakai, 4 in view ofTemkin. 5 We have jurisdiction over the appeal under 35 U.S.C. § 6(b ). We REVERSE.. 1 Our decision refers to the Specification (Spec.) filed January 31, 2008, the Examiner's Final Office Action (Final Act.) dated May 4, 2016, Appellants' Brief (Br.) filed October 28, 2016, and the Examiner's Answer (Ans.) dated January 9, 2017. 2 Appellants identify the real party in interest in this appeal as International Rectifier Corporation. App. Br. 2. 3 US 2004/0137732 Al, published July 15, 2004. 4 US 6,475,882 Bl, issued November 5, 2002 5 US 6,391,748 Bl, issued May 21, 2002. Appeal2017-005909 Application 12/023,480 STATEMENT OF THE CASE The invention relates to a method of forming a semiconductor structure including a nitride material region and an amorphous strain- absorbing layer. Spec. 2:5-11. In particular, Appellants disclose the strain- absorbing layer covers substantially the entire top surface of the semiconductor substrate, and a nitride-based material layer is formed directly on the strain-absorbing layer, with a misfit dislocation density in the nitride-based material layer that is less than about 1010 defects/cm2. Id. at 2: 17-27. The overlying nitride-based material layer is disclosed to be formed in a vertical growth process, i.e., in a vertical direction with respect to the strain-absorbing layer. Id. at 18:5-9. Claim 1, reproduced below from the Claims Appendix to the Appeal Brief, is illustrative of the subject matter on appeal: 1. A method of forming a semiconductor structure comprising: forming an amorphous strain-absorbing layer on an entire top surface of a non-nitride material of a semiconductor substrate by nitridating the entire top surface, wherein said amorphous strain-absorbing layer does not include gallium; forming a nitride-based material layer using a vertical growth process, wherein the amorphous strain-absorbing layer separates the semiconductor substrate and the nitride- based material layer at all points with the amorphous strain- absorbing layer being directly on the non-nitride material of the semiconductor substrate and the nitride-based material layer being directly on the strain-absorbing layer, wherein said semiconductor substrate is a non-nitride material-based substrate, wherein the misfit dislocation density in the nitride-based material layer is less than about 1010 defects/ cm2. 2 Appeal2017-005909 Application 12/023,480 ANALYSIS The Examiner has the initial burden of establishing a prima facie case of obviousness. See In re Piasecki, 745 F.2d 1468, 1472 (Fed. Cir. 1984); In re Rinehart, 531 F.2d 1048, 1051 (CCPA 1976). Meeting that burden requires establishing that the applied prior art would have provided one of ordinary skill in the art with an apparent reason to modify the prior art to arrive at the claimed invention. See KSR Int 'l Co. v. Teleflex Inc., 550 U.S. 398, 418 (2007). The Examiner finds that Frayssinet teaches a method of forming a semiconductor structure comprising forming an amorphous strain-absorbing SiN layer directly on a semiconductor non-nitride sapphire substrate, and forming a nitride-based GaN material layer directly on the strain-absorbing layer using a vertical growth process, wherein the misfit dislocation density in the nitride-based material layer is in the mid 107 defects/cm2 range, i.e., less than about 1010 defects/cm2 . Final Act. 2-3. The Examiner acknowledges that Frayssinet fails to teach nitridating the entire top surface of the substrate such that the amorphous strain-absorbing layer covers the entire top surface of the substrate and separates the substrate from the nitride-based material layer at all points. Id. at 3. The Examiner further finds that Sakai teaches nitridating an entire top surface of a non-nitride semiconductor sapphire substrate 10 to form an amorphous strain-absorbing layer ( GaN semiconductor layer 40 and SiN buffer body 42) directly on the substrate, and forming a nitride-based GaN material layer 44 using a vertical growth process directly on the amorphous strain-absorbing layer such that the amorphous strain-absorbing layer separates the nitride-based material layer from the substrate. Final Act. 3-5. 3 Appeal2017-005909 Application 12/023,480 The Examiner acknowledges Sakai fails to teach a reduction in the misfit dislocation density in the nitride-based material layer of less than about 1010 defects/ cm2. Id. at 5. The Examiner concludes that it would have been obvious to include forming the nitride-based material layer directly on Frayssinet's amorphous strain-absorbing layer for the purpose of reducing the dislocation density of this nitride-based material layer as taught by Sakai, with a reasonable expectation of success. Final Act. 4. In combining Frayssinet and Sakai, the Examiner determines that the resulting amorphous strain-absorbing layer would separate the nitride-based material layer and the substrate at all points. Id. Alternatively, the Examiner concludes that it would have been obvious to include Frayssinet's teaching regarding reduction of the misfit dislocation density down to the mid 107 defects/cm2 range into Sakai's process. Id. at 5. Recognizing that neither Frayssinet nor Sakai teach an amorphous strain-absorbing layer that does not include gallium, the Examiner finds that Temkin teaches an amorphous AlN strain-absorbing layer 28,30 not including gallium. Final Act. 6. The Examiner concludes that it would have been obvious to include Temkin's teaching regarding the use of an amorphous AlN strain-absorbing layer for the purpose of reducing defect density. Id. Appellants argue, inter alia, that Temkin purposely teaches away from forming an amorphous SiN layer on which GaN can be grown. Br. 9. In particular, Appellants contend that Temkin intentionally avoids the formation of an amorphous SiN layer. Id., citing Temkin, Abstract; 4:3-17; 5:3-8; 5:49---6:9; 6:11-12. Appellants further contend that Temkin's nitride- 4 Appeal2017-005909 Application 12/023,480 based material layer growth process is primarily vertical and requires a continuous non-amorphous SiN layer, whereas the nitride-based material layer growth process of both Frayssinet and Sakai relies on both lateral and vertical growth over a patterned or discontinuous amorphous SiN layer. Id., citing Temkin, 7:1-38. Appellants' argument is persuasive of reversible error in the Examiner's obviousness rejection of claim 1. Although the Examiner finds that Temkin specifically teaches a "process [that] minimizes the formation of amorphous silicon nitride, SiN.sub.x, compounds on the surface of the substrate and that "[a] surface free of amorphous silicon nitride is necessary for formation of high quality AlN," the Examiner nonetheless maintains that the process of claim 1 would have been obvious based on a combination of Temkin's teaching of a buffer of high quality nitride layers 28,30 between the substrate and a GaN layer at all points. Ans. 6. In other words, even though Temkin teaches away from the use of an amorphous strain-absorbing layer underlying the AlN layer, the Examiner ignores this teaching to conclude that it would have been obvious to do so. It has been held that "[ w ]hat the prior art teaches and whether it teaches toward or away from the claimed invention ... is a determination of fact." Para-Ordnance Mfg., Inc. v. SGS Importers Int'!, Inc., 73 F.3d 1085, 1088 (Fed. Cir. 1995). When the prior art teaches away from a combination, that combination is more likely to be nonobvious, KSR Int'!. Co. v. Teleflex Inc., 550 U.S. 398, 417 (2007), but to teach away, a reference must discourage one of ordinary skill in the art from following the path set out in the reference, or lead that person in a direction divergent from the path that was taken by the applicant. In re Gurley, 27 F.3d 551, 553 (Fed. Cir. 1994). 5 Appeal2017-005909 Application 12/023,480 Here, as Appellants argue and the Examiner acknowledges, Temkin specifically discourages the use of an amorphous strain-absorbing layer when using the non-gallium nitride-based AlN material layer. Because Frayssinet and Sakia both teach the use of an amorphous strain-absorbing layer between the nitride-based GaN material layer and the substrate, Temkin clearly teaches away from the substitution of AlN in Frayssinet and Sakia absent the use of a non-amorphous layer separating the AlN layer from the substrate. Appellants further argue that Sakai fails to teach an amorphous strain- absorbing layer not including gallium that covers and is directly on the entire top surface of the substrate and separating the nitride-based layer from the substrate at all points. Br. 7. Appellants contend that Sakai includes GaN layer 40 directly on substrate 10 and SiN layer 42 is not directly on substrate IO. Id. In addition, Appellants contend that Sakai's SiN layer 12 as shown in Figure 1 contains intentional pores or gaps and, therefore, does not cover the entire top surface of the underlying substrate nor separate the overlying nitride-based GaN material layer from the substrate at all points. Id. at 8. This argument is also persuasive of reversible error. As the Examiner finds, Sakai's Figure 1 is substantially similar to Frayssinet's Figure 3. Ans. 4. However, although the Examiner relies on the fact that Sakai teaches Figure 12 as a different embodiment which appears to show continuous SiN layer 42, this layer is not formed directly on non-nitride based semiconductor substrate 10 as required by claim 1. Moreover, we note Sakai discloses that SiN buffer body layer 42 of Figure 12 is formed in the same process as SiN buffer body layer 12 of Figure 1, a process which produces a layer with pores or gaps. Sakai, 4:15-21. As such, Sakai's SiN 6 Appeal2017-005909 Application 12/023,480 buffer body 42 is neither directly formed on the substrate nor separates the substrate from nitride-based material layer 44 at all points. Therefore, Sakai fails to teach an amorphous strain-absorbing layer not including gallium that covers and is directly on the entire top surface of the substrate and separating the nitride-based layer from the substrate at all points. Finally, Appellants assert that Frayssinet specifically teaches use of a discontinuous SiN layer in order to enable epitaxial lateral overgrowth (ELO) of the GaN layer thereby reducing defect density as compared to a GaN layer vertically grown on the substrate. Br. 6. Appellants, therefore, argue that modifying Frayssinet's SiN layer to be continuous would have been expected to increase defect density of the GaN layer. Id. As such, Appellants contend the Examiner's proposed modification of Frayssinet would change Frayssinet's principle of operation by increasing, rather than decreasing, defect density. Id. This argument is also persuasive of reversible error. As Appellants urge, Frayssinet's principle of operation is the inclusion of a discontinuous amorphous SiN layer over the substrate so as to enable the growth of the GaN layer by ELO without the requirement of making a mask. Frayssinet ,r 11. Frayssinet's amorphous SiN layer has islands that function as a micro- mask during subsequent GaN ELO growth, which Frayssinet attributes to a significant reduction in defect density. Id. ,r 12. Therefore, modifying Frayssinet's SiN layer to cover the entire top surface of the substrate would effectively prevent Frayssinet from operating as disclosed. Accordingly, the Examiner has not carried the burden of establishing, by a preponderance of the evidence, the factual basis for the conclusion that the claimed invention would have been obvious. Under these circumstances, 7 Appeal2017-005909 Application 12/023,480 we cannot conclude that the Examiner has met the minimum threshold of establishing obviousness under 35 U.S.C. § 103(a) of claim 1 and dependent claims 4--20. See In re Oetiker, 977 F.2d 1443, 1445 (Fed. Cir. 1992); KSR Int'! Co. v. Teleflex, Inc., 550 U.S. 398,418 (2007) (quoting In re Kahn, 441 F.3d 977, 988 (Fed. Cir. 2006)). DECISION Upon consideration of the record, and for the reasons given above and in the Appeal Brief, the decision of the Examiner rejecting claims 1 and 4-- 20 under 35 U.S.C. § 103(a) as being unpatentable over Frayssinet and Sakai, in view of Temkin, is reversed. REVERSED 8 Copy with citationCopy as parenthetical citation