Ex Parte Muha et alDownload PDFPatent Trial and Appeal BoardAug 31, 201611218618 (P.T.A.B. Aug. 31, 2016) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE FIRST NAMED INVENTOR 111218,618 0910612005 Joseph F. Muha 66376 7590 09/02/2016 ALLEGHENY TECHNOLOGIES INCORPORATED 1000 SIX PPG PLACE PITTSBURGH, PA 15222-5479 UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. APM-2170 1056 EXAMINER ZHU, WEIPING ART UNIT PAPER NUMBER 1733 NOTIFICATION DATE DELIVERY MODE 09/02/2016 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address( es): maria.dunn@atimetals.com A TIDocketing@atimetals.com uspatentmail@klgates.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte JOSEPH F. MUHA, ANDRZEJ L. WOJCIESZYNSKI, and BRIAN J. MCTIERNAN1 Appeal2015-000786 Application 11/218,618 Technology Center 1700 Before CHUNG K. PAK, JEFFREY T. SMITH, and RAEL YNN P. GUEST, Administrative Patent Judges. GUEST, Administrative Patent Judge. DECISION ON APPEAL STATEMENT OF THE CASE Appellants appeal2 under 35 U.S.C. § 134(a) from the rejection of claims 11-14, 17-19, 23, 24, 26-28, and 31-38 under 35 U.S.C. § 103(a) as unpatentable over Dorsch3 and of claims 20-22, 29, and 30 under 35 U.S.C. 1 Appellants identify the real party in interest as ATI Powder Metals LLC, a wholly-owned subsidiary of Allegheny Technologies Incorporated. Appeal Br. 1. 2 In our opinion below, we refer to the Specification filed September 6, 2005 ("Spec."), Final Office Action mailed May 16, 20154 ("Final Act."), the Appeal Brief filed August 29, 2014 ("Appeal Br."), the Examiner's Answer mailed October 15, 2014 ("Ans."), and the Reply Brief filed October 22, 2014 ("Reply Br."). 3 US Patent 5,447,800, issued September 5, 1995, to Carl J. Dorsch, et al. Appeal2015-000786 Application 11/218,618 § 103(a) as unpatentable over Dorsch in view of Wang. 4 We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM. The claims are directed to a method from producing a maraging steel article with a specific composition using a powder metallurgy processing method. Spec. i-f 1. According to the Specification, the process leads to improved resistance to high temperature or cyclic heating and cooling of maraging steel articles. Id. i-f 2. The articles made from the process exhibit favorable thermal fatigue resistance and strength, but also reduced thermal fatigue cracking. Id. The inventors believe that an increased cobalt content and a decreased nickel content may be at least partially responsible for the improvement in thermal fatigue resistance. Appeal Br. 6. Claim 11, with limitations of particular importance highlighted, is illustrative of the subject matter encompassed by the claims: 11. A method for producing a maraging steel article, said method comprising: preparing a prealloyed powder of steel comprising: 0.00 to 0.03 wt% S, 6.0-10.0 wt% Mo, 1.0-4.0 wt% Ni, and greater than 11.00 to 14.0 wt% Co, compacting said prealloyed powder to produce a fully dense article, annealing the fully dense article at a temperature in the range of 1740°F to 1925°F, and 4 US Patent Application Publication 2005/0187056 Al, published August 25, 2005, to Yucong Wang, et al. 2 Appeal2015-000786 Application 11/218,618 hardening the annealed article, wherein the hardening comprises heating the article at a temperature in the range of 1050°F to 1360°F. Appeal Br. 25 (Claims App'x). The other independent claim 24 has substantially identical processing steps but the prepared prealloyed powder of steel comprises the following components: 6.0- 10.0 wt% Mo, 1.0 - 4.0 wt% Ni, greater than 11.00 to 14.0 wt% Co, 2.5 - 6.0% Cr; up to 0.08% C; up to 1.0% Mn; up to 1.0% Si; 0.00 to 0.03% S; and the balance comprising incidental elements and impurities. Id. at 27. ANALYSIS The Examiner rejects all the claims on appeal as obvious over Dorsch either alone or further in view of Wang. There is no dispute that, as found by the Examiner, Dorsch discloses process a steel article having the compacting, annealing, and hardening steps of the claimed invention. Final Act. 2-3. The Examiner finds that Dorsch teaches temperature and concentration ranges that overlap the claimed ranges, rendering the claimed ranges obvious, with the exception of the sulfur content and the cobalt content. The Examiner acknowledges that Dorsch teaches a preferred sulfur content of 0.05 to 0.30 % by weight, which does not overlap the ranges recited in the claims of 0 to 0.03 % by weight (claims 11 and 24) and 0.01to0.03 % by weight (claim 14). Id. at 3. The 3 Appeal2015-000786 Application 11/218,618 Examiner also acknowledges that Dorsch teaches a preferred range of cobalt of "up to 11.0" % by weight, which does not overlap the range ranges recited in the claims of "greater than 11.00 to 14.0 wt.%" (claims 11 and 24) and of 11.1 7 to 14. 0 % by weight (claims 3 5 and 3 6). Id. Nonetheless, the Examiner concludes that sulfur and cobalt concentrations within the ranges recited in the claims would have been obvious in light of these teachings because "[t]he lowest sulfur content and the highest Co content disclosed by Dorsch et al. (' 800) are close enough to the claimed highest sulfur content and lowest Co content respectively that one ordinary skilled in the art would have expected the same results." Id. Appellants contend that the Examiner's conclusion that the concentrations "are close enough" is conclusory and unsupported statements that lack evidentiary support of obviousness as to the particularly recited ranges in the claims. Appeal Br. 9. Appellants' arguments raise three issues: A. Have Appellants identified a reversible error in the Examiner's finding that the prior art would have suggested forming compositions comprising a maraging steel in light of the specific working embodiment recited in Table I; B. Have Appellants identified a reversible error in the Examiner's finding of a reason for the skilled artisan to have found the ranges obvious in view of the prior art; and C. Have Appellants established that Dorsch teaches away from the ranges recited in the claims? Appellants present arguments substantially identical for each of independent claims 11 and 24 and do not argue any dependent claims 4 Appeal2015-000786 Application 11/218,618 separately. Appeal Br. 10, 21; Reply Br. 3-7. For these arguments, we select claim 11 as representative to decide the issues on appeal. Issue A: Maraging steel For the reasons that follow, we determine that Appellants have not identified a reversible error in the Examiner's finding that Dorsch teaches a method of preparing a maraging steel article having identical elemental components. Appellants' arguments are directed only to the working example provided in Table I of Dorsch. Appeal Br. 10-11. Yet, Dorsch includes additional disclosure that is specific to using the powdered steel process of Dorsch with "maraging and precipitation hardening steels." See Dorsch, col. 4, 11. 38-53. Dorsch states that: Maraging steels and precipitation-hardening steels which are suitable for use as die casting die components and other hot work tooling components consist of, in weight percent, up to 0.20 carbon, up to 1.0 manganese, up to 0.04 phosphorus, up to 0.50 silicon, up to 19.0 nickel, up to 18.0 chromium, up to 8.0 molybdenum, up to 6.0 tungsten, up to 11.0 cobalt, up to 4.0 copper, up to 2.0 niobium, up to 2.0 titanium, up to 2.0 aluminum, balance iron and incidental impurities. Id. at col. 4, 11. 45-53. It is of no moment that Dorsch has a particular preference for the steel compositions of Table I (id. at col. 2, 1. 53 (stating that Table I is preferred)), where Dorsch clearly includes the use of either "AISI hot work tool steel" or "maraging or precipitation-hardening steel" as alternatives. Id. at col. 3, 11. 5-13. A reference may be relied upon for all that it would have reasonably suggested to one having ordinary skill in the art, including non-preferred 5 Appeal2015-000786 Application 11/218,618 embodiments. Pfizer, Inc. v. Apotex, Inc., 480 F.3d 1348, 1370 (Fed. Cir. 2007) ("[T]he teaching of a prior art patent is not limited to its preferred embodiment."); Merck & Co v. Biocraft Labs., Inc., 874 F.2d 804, 807 (Fed. Cir. 1989) ("[A ]ll disclosures of the prior art, including unpreferred embodiments, must be considered.") (quoting In re Lamberti, 545 F .2d 7 4 7, 7 50 ( CCP A 197 6) ). Disclosed examples and preferred embodiments do not constitute a teaching away from a broader disclosure or non-preferred embodiments. In re Susi, 440 F .2d 442, 446 n.3 (CCP A 1971 ). Appellants have not identified a reversible error in the Examiner's finding that Dorsch teaches using a powdered maraging steel alloy. Issue B: Modification of the preferred ranges of Dorsch The disclosure of Dorsch quoted above teaches concentration ranges for carbon, manganese, silicon, nickel, chromium, and molybdenum that are either encompassed by or overlap the ranges recited in claims 11, 14, and 24. Dorsch, col. 4, 11. 45-53. It is undisputed that the amounts of sulfur and cobalt taught in the maraging steel description of Dorsch does not overlap the ranges for these elements recited in the claims. Appellants argue that Dorsch only teaches maraging steels generally, and includes no description of any particular maraging steel species, and particularly a species falling within the more narrow ranges recited in the claims. Appeal Br. 10-11; Reply Br. 3--4. It has been often said that when a claimed range overlaps, is close to, or within a broader range disclosed in the prior art, the claimed range is prima facie obvious. Iron Grip Barbell Co. v. USA Sports, Inc., 392 F.3d 1317, 1321-22 (Fed. Cir. 2004). When 6 Appeal2015-000786 Application 11/218,618 "the difference between the claimed invention and the prior art is the range or value of a particular variable," then a patent should not issue if "the difference in range or value is minor." Haynes Int'! v. Jessop Steel Co., 8 F.3d 1573, 1577 n.3 (Fed. Cir. 1993); see also Titanium Metals Corp. of Am. v. Banner, 778 F.2d 775, 783 (Fed. Cir. 1985). Iron Grip, 392 F.3d at 1322. This principle applies even in the case of alloys for which several different elements have encompassed or overlapping ranges. See In re Harris, 409 F.3d 1339 (Fed. Cir. 2005). The case of Titanium Metals, 778 F.2d at 783 (emphasis added), explains why claimed ranges that are close to, or encompassed by, the prior art make compelling evidence of obviousness in stating that "[t]he proportions are so close that prima facie one skilled in the art would have expected them to have the same properties." See also KSR Int'! v. Teleflex Inc., 550 U.S. 398, 417 (2007) ("If a person of ordinary skill can implement a predictable variation, § 103 likely bars its patentability."); see also In re Gyurik, 596 F.2d 1012, 1018 (CCPA 1979) (holding that when the similarity in chemical structures and functions between the prior art and claimed compounds is sufficiently close, a prima facie case of obviousness is established.). It is this reasonable expectation of substantially identical properties or functions based on similarities or closeness of the ranges involved, which distinguished these types of range cases from the chemical genus and species cases argued by Appellants, in which certain changes in chemical structure (e.g. the presence or absence of functional groups) can lead to substantially different properties. 5 See Appeal Br. 13-15 (relying 5 Additionally, Appellants' reliance on Atofina v. Great Lakes Chem. Corp, 441 F.3d 991, 999 (Fed. Cir. 2006) is not persuasive. Atofina is directed specifically to a rejection based on anticipation under 35 U.S.C. § 102(b). 7 Appeal2015-000786 Application 11/218,618 heavily onln re Baird, 16 F.3d 380, 383 (Fed. Cir. 1994) and similar cases that hold a generic chemical formula, by itself and without further reasoning or evidence, does not render obvious a species of the disclosed formula); Reply Br. 3--4, 6-7. When predictable results can be expected within or near ranges described in the prior art, the selection of any particular amount would have been obvious. The alloy recited in claim 11 is analogous to the alloy in In re Peterson, 315 F.3d 1325, 1329-30 (Fed. Cir. 2003) and similar cases. In Peterson, the court stated: Selecting a narrow range from within a somewhat broader range disclosed in a prior art reference is no less obvious than identifying a range that simply overlaps a disclosed range. In fact, when, as here, the claimed ranges are completely encompassed by the prior art, the conclusion is even more compelling than in cases of mere overlap. The normal desire of scientists or artisans to improve upon what is already generally known provides the motivation to determine where in a disclosed set of percentage ranges is the optimum combination of percentages. Peterson, 315 F.3d at 1329-30; KSR, 550 U.S. at 421 (An improvement in the art is obvious if "it is likely the product not of innovation but of ordinary skill and common sense."); In re Aller, 220 F.2d 454, 456 (CCPA 1955) ("[W]here the general conditions of a claim are disclosed in the prior art, it is not inventive to discover the optimum or workable ranges by routine experimentation."). Therefore, we agree with the Examiner that in these types of range cases, there is no need for the prior art to expressly describe the resulting effect of altering each element because, absent evidence of unexpectedly superior results, the skilled artisan would expect these ranges to represent ranges for workable, if not optimized, results for the intended 8 Appeal2015-000786 Application 11/218,618 purpose. Here, Dorsch teaches workable elemental ranges for maraging steel used for hot work tooling components. Appellants argue that not all of the elements of the alloy recited in claim 11 fall within or overlap the ranges described in Dorsch. Appeal. Br. 8; Reply Br. 5-6. Dorsch teaches a cobalt range of "up to 11.0" % by weight. Under the principles discussed above, and without evidence to the contrary, the skilled artisan would have expected substantially identical results from an alloy having a cobalt concentration of 11.0 % by weight, as taught by Dorsch, and an alloy having a cobalt concentration "greater than 11.0" % by weight, which encompasses a very small amount greater than 11.0 % by weight. Without evidence to the contrary, we agree with the Examiner that the skilled artisan would have expected substantially similar results from an alloy having a cobalt concentration of 11.0 % by weight, as taught by Dorsch, and an alloy having a cobalt concentration of 11.17 % by weight, which is within the range recited in claim 14. Thus, we agree with the Examiner that the cobalt concentration taught by Dorsch is indeed close enough to an amount encompassed by the range recited in the claims that the skilled artisan would have expected the same results. Dorsch is further directed to an alloy having 0.05 to 0.30 % sulfur by weight. Dorsch, col. 3, 11. 8-13. Without evidence to the contrary, we agree with the Examiner that the skilled artisan would have expected substantially similar results from an alloy having a cobalt concentration of 0.05 % by weight, as taught by Dorsch, and an alloy having a cobalt concentration of 0.03 % by weight, which is within the range recited in claim 11. 9 Appeal2015-000786 Application 11/218,618 Moreover, the prior art clearly recognizes the concentration of sulfur to be a result effective variable. According to Dorsch: The sulfur additions in the steel make it machinable at the high hardness needed for die casting applications (35 to 50 HRC), but die components manufactured from the currently available prehardened die blocks exhibit short service life because the sulfur in the steel reduces thermal fatigue resistance and impact toughness, which in tum reduce die performance and die service life. Id. at col. 1, 11. 50-57. While sulfur was known to be useful for machinability, for "prehardened die blocks," the use of sulfur greater than 0.028% by weight reduced thermal fatigue resistance beyond acceptable levels due to "the effect of the inclusions produced by higher sulfur levels." Id. at col. 1, 1. 63---col. 2, 1. 2. In particular, Dorsch teaches that the industry standard maximum sulfur content for AISI H13 steel was 0.005 weight percent, because thermal fatigue failure could not be assured with higher sulfur contents. Dorsch; col. 2; 11. 2-13. Yet, Dorsch achieves high thermal fatigue resistance despite the use of sulfur in an amount greater than 0.028% by weight "with the use of [powdered] prealloyed particles" such that "the sulfur is uniformly distributed therein and thus the resulting sulfides in the fully dense consolidated mass of the prealloyed particles are small, and uniformly distributed, and most of them are generally spherical." Id. at col. 3, 11. 14-- 18, 27-32. According to Dorsch, "the segregation of sulfur that is inherent within cast ingots of AISI H13 and other conventional wrought steels is eliminated to in tum avoid the presence of conventional, relatively thick, elongated, sulfide stringers in die blocks forged from these ingots." Id. at col. 3, 11. 23-26. Thus, Dorsch achieves good machinability with an increase 10 Appeal2015-000786 Application 11/218,618 in sulfur, without suffering the usual thermal fatigue resistance typically experienced with a higher sulfur content using conventional processes. The Specification states that sulfur is added to improve machinability, which is consistent with the teaching of Dorsch. Spec. i-f 26. Using the process of Dorsch with the conventional amount of sulfur, namely less than 0.028 % by weight, which would fall within the range recited in the claims of0--0.03 or 0.01---0.03 % by weight, is not patentably inventive. The skilled artisan merely accepts that the article will have good, yet somewhat less, machinability than that described for Dorsch's alloy, which has a higher amount of sulfur. In re Gurley, 27 F.3d 551, 552-53 (Fed. Cir. 1994) ("A known or obvious composition does not become patentable simply because it has been described as somewhat inferior to some other product for the same use."); see also In re Larson, 340 F.2d 965, 969 (CCPA 1965) ("If this additional [superior] feature is not desired, it would seem a matter of obvious choice to eliminate it and the function it serves."). Appellants point to the declaration of Mr. Wojcieszynski as evidence that alloying technology is unpredictable. Appeal Br. 11-12. This evidence was are determined to be unpersuasive in the Board Decision of December 23, 2011. Appellants have presented no additional evidence for our consideration. Accordingly, on this record, Appellants have not identified a reversible error in the Examiner's determination that using sulfur and cobalt in the process of Dorsch within the ranges recited in the claims would have been obvious to one of ordinary skill in the art. 11 Appeal2015-000786 Application 11/218,618 Issue C: Teaching away Appellants contend that Dorsch teaches away from a sulfur content as low as recited in the claims because Dorsch teaches that a "sulfur content of about 0.10 weight percent or more is necessary to make the steel machinable." Appeal Br. 19 (citing Dorsch, col. 5, 11. 56-61); Reply Br. 5- 6. However, we do not find this argument persuasive. A teaching that a process would be inferior or less desirable is not a teaching away unless the use would render the process "inoperable." See In re ICON Health and Fitness Inc., 496 F.3d 1374, 1381 (Fed. Cir. 2007); Gurley, 27 F.3d at 553 ("[I]n general, a reference will teach away if it suggests that the line of development flowing from the reference's disclosure is unlikely to be productive of the result sought by the applicant."). Here, as discussed above in detail, the prior indicates that acceptable machinability at sulfur concentrations as low as the industry standard of 0.005 % by weight, while not ideal, is nonetheless achievable. Even using the powder metallurgy process taught by Dorsch, however, thermal fatigue resistance is still reduced with an increase in sulfur. Dorsch, col. 9, 11. 8-34, Fig. 9; see also Fig. 8 (showing a machinability trend as a function of sulfur content but only to about 0.075 weight percent). Thus, the skilled artisan seeking maximum thermal fatigue resistance, at the expense of some machinability, would reduce the sulfur content. Moreover, the skilled artisan would have been capable of adjusting the sulfur content, using a power metallurgy process as taught by Dorsch, to achieve both good machinability and good thermal fatigue resistance, because the effects of sulfur were well known in the art at the time of the invention. 12 Appeal2015-000786 Application 11/218,618 Thus, Dorsch does not teach away from using a lower sulfur content than that disclosed in the preferred amount described in Dorsch, but would have optimized the sulfur content for either improved machinability or improved thermal fatigue resistance depending upon the more desired property. DECISION The decision of the Examiner is affirmed. TIME PERIOD FOR RESPONSE No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(l )(iv). AFFIRMED 13 Copy with citationCopy as parenthetical citation