Ex Parte Mellott et alDownload PDFBoard of Patent Appeals and InterferencesAug 18, 201111514320 (B.P.A.I. Aug. 18, 2011) Copy Citation UNITED STATES PATENT AND TRADEMARKOFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 11/514,320 09/01/2006 Nathan P. Mellott 3691-1072 3458 23117 7590 08/18/2011 NIXON & VANDERHYE, PC 901 NORTH GLEBE ROAD, 11TH FLOOR ARLINGTON, VA 22203 EXAMINER VETERE, ROBERT A ART UNIT PAPER NUMBER 1712 MAIL DATE DELIVERY MODE 08/18/2011 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE BOARD OF PATENT APPEALS AND INTERFERENCES ____________ Ex parte NATHAN P. MELLOTT, THOMAS J. TAYLOR, and SCOTT V. THOMSEN ____________ Appeal 2010-006397 Application 11/514,320 Technology Center 1700 ____________ Before BRADLEY R. GARRIS, PETER F. KRATZ, and MICHAEL P. COLAIANNI, Administrative Patent Judges. GARRIS, Administrative Patent Judge. DECISION ON APPEAL Appellants appeal under 35 U.S.C. § 134 from the Examiner's decision rejecting claims 1-21. We have jurisdiction under 35 U.S.C. § 6. We AFFIRM-IN-PART and make a NEW GROUND OF REJECTION. Appellants claim a method of making a solar cell comprising providing a photovoltaic layer, a glass substrate, and an anti-reflection coating on the glass substrate, wherein flame pyrolysis is used to form the anti-reflection coating such that the flame pyrolysis causes nanostructures comprising peaks and valleys on an exterior surface of the anti-reflection Appeal 2010-006397 Application 11/514,320 2 coating, the peaks having an average elevation of from about 5-60 nm, and there being an average gap distance from about 10-80 nm between adjacent peaks or adjacent valleys (claim 1). In a narrower embodiment of this method, the glass substrate comprises a particular composition and possesses certain visible transmission and color value characteristics (claim 20). Appellants also claim a solar cell having the structural features recited in method claims 1 and 20 (claim 21). Representative claims 1, 20 and 21 read as follows: 1. A method of making a solar cell, the method comprising: providing a photovoltaic layer and at least a glass substrate on a light incident side of the photovoltaic layer; providing an anti-reflection coating on the glass substrate, the anti- reflection coating including at least one layer and being located on a light- incident side of the glass substrate; and wherein flame pyrolysis is used to form at least part of the anti- reflection coating which is provided on the light-incident side of the glass substrate of the solar cell such that the flame pyrolysis used to form the anti-reflection coating causes nanostructures comprising peaks and valleys on an exterior surface of the anti-reflection coating, the peaks having an average elevation of from about 5-60nm relative to adjacent valleys, and there being an average gap distance of from about 10-80nm between adjacent peaks or adjacent valleys. 20. The method of claim 1, wherein the glass substrate comprises: Ingredient wt. % SiO2 67 – 75 % Na2O 10 – 20 % CaO 5 – 15 % Total iron (expressed as Fe2O3) 0.001 to 0.06 % Cerium oxide 0 to 0.30 % Appeal 2010-006397 Application 11/514,320 3 wherein the glass substrate by itself has a visible transmission of at least 90%, a transmissive a* color value of -1.0 to +1.0 and a transmissive b* color value of from 0 to +1.5. 21. A solar cell, comprising: a photovoltaic layer and at least a glass substrate on a light incident side of the photovoltaic layer; an anti-reflection coating formed at least partially by flame pyrolysis provided on the glass substrate, the anti-reflection coating including at least one layer and being located on a light-incident side of the glass substrate; and wherein the glass substrate comprises: Ingredient wt. % SiO2 67 – 75 % Na2O 10 -20 % CaO 5 – 15 % Total iron (expressed as Fe2O3) 0.001 to 0.06 % Cerium oxide 0 to 0.30 % wherein the glass substrate by itself has a visible transmission of at least 90%, a transmissive a* color value of 01.0 to +1.0 and a transmissive b* color value of from 0 to +1.5, and wherein the flame pyrolysis used to form the anti-reflection coating causes nanostructures comprising peaks and valleys on an exterior surface of the anti-reflection coating, the peaks having an average elevation of from about 5-60nm relative to adjacent valleys, and there being an average gap distance of from about 10-80nm between adjacent peaks or adjacent valleys. Appeal 2010-006397 Application 11/514,320 4 The prior art listed below is relied upon by the Examiner as evidence of obviousness: Pecoraro 4,792,536 Dec. 20, 1988 Anderson 5,891,556 Apr. 6, 1999 Hunt 6,013,318 Jan. 11, 2000 Nelson 6,165,598 Dec. 26, 2000 Sopko 6,436,541 B1 Aug. 20, 2002 Appellants' Admitted Prior Art (AAPA) described in paragraphs [0003]- [0005] of the Specification. Under 35 U.S.C. § 103(a), the Examiner rejects as unpatentable: (1) claims 1, 2, and 5-19 over Nelson in view of AAPA, Hunt, and Sopko; (2) claims 3 and 4 over Nelson, AAPA, Hunt, Sopko, and Anderson; (3) claim 20 over Nelson, AAPA, Hunt, Sopko, and Pecoraro; and (4) claim 21 over Nelson, AAPA, Pecoraro, and Sopko. Rejection (1); the § 103 Rejection of Claims 1, 2, and 5-19 Because dependent claims 2 and 5-19 have not been separately argued (see App. Br. 12-17), they will stand or fall with independent claim 1. The Examiner concedes that the combination of Nelson and AAPA "does not explicitly disclose utilizing flame pyrolysis" (Ans. para. bridging 3-4) but concludes that "it would have been obvious . . . to utilize Hunt's flame pyrolysis technique to form Nelson/AAPA's color suppressed anti- reflective glass" (id.). Moreover, it is the Examiner's determination that the method resulting from this prior art combination corresponds to Appeal 2010-006397 Application 11/514,320 5 Appellants' method and accordingly that the resulting method would inherently form the nanostructures defined by claim 1 (id. at 4, para. bridging 8-9). Appellants do not contest in the appeal record the Examiner's combination of Nelson, AAPA, and Hunt or the Examiner's determination that the method resulting from this combination corresponds to Appellants' method (see App. Br.14-17). Instead, Appellants argue that "no objective evidence or cogent technical reasoning whatsoever has been presented to support the conclusion of inherency" (App. Br. 16). We cannot agree. The Examiner's inherency position is convincingly supported by the undisputed determination that the method resulting from the prior art combination corresponds to Appellants' method. That is, since the flame pyrolysis technique of the Nelson/AAPA/Hunt combination indisputably corresponds to the flame pyrolysis technique disclosed and claimed by Appellants, these two indistinguishable techniques must necessarily and inherently perform the same nanostructure-forming function. The fact that Appellants have recognized another advantage (i.e., formation of the claim 1 nanostructures) which would flow naturally from following the suggestion of the prior art cannot be the basis for patentability when the differences would otherwise be obvious. See Ex parte Obiaya, 227 USPQ 58 (BPAI 1985). The Examiner's inherency determination is additionally supported by Appellants' Specification in two respects. First, we find nothing and Appellants point to nothing in their Specification concerning manipulation Appeal 2010-006397 Application 11/514,320 6 of flame pyrolysis parameters in order to achieve the nanostructures required by claim 1 (see, e.g., Spec. para. [0021]). This circumstance reflects that these nanostructures are the result of practicing flame pyrolysis generally rather than the manipulation of specific flame pyrolysis parameters. Second, the Specification discloses examples of flame pyrolysis techniques suitable for practicing Appellants' invention by reference to certain U.S. patents including 5,652,021 (Spec. para. [0020]), of which Hunt is a continuation (Hunt title page, item [63]). It follows that at least one of the flame pyrolysis techniques disclosed in the Specification as suitable for achieving the nanostructures of claim 1 is identical to the flame pyrolysis technique taught by Hunt. As an apparent alternative to the above inherency theory, the Examiner seems to conclude that it would have been obvious, in view of Sopko, to create the claim 1 nanostructures "in order to achieve the predictable result of forming an anti-reflective coating with nanostructures comprising peaks and valleys with the reasonable expectation of success" (Ans. 4, penultimate sentence). Contrary to the Examiner's apparent belief, such an obviousness conclusion is not supported by Sopko. As correctly argued by Appellants, "[a]lthough Sopko appears to teach 'surface roughness' for certain layers, there is no teaching or suggestion that such roughness is a result of nanostructures comprising peaks and valleys on an exterior surface of the anti-reflection coating, with the peaks having an average elevation of from about 5-60 nm relative to adjacent valleys, and there being an average gap Appeal 2010-006397 Application 11/514,320 7 distance of from about 10-80 nm between adjacent peaks or adjacent valleys [as required by claim 1]" (App. Br. para. bridging 14-15). Finally, Appellants argue that the Examiner's previously discussed inherency position is contradicted by Sopko which, according to Appellants, "suggests that its as-deposited layers need to be etched or otherwise modified to obtain the roughness that it desires -- which certainly is not the same as obtaining the specifically claimed nanostructures as a necessary result of the flame pyrolysis process itself" (Reply Br. para. bridging 4-5). As support for this argument, Appellants refer to the disclosure at column 8, lines 15-33 of Sopko (id.). This argument is unpersuasive. Sopko's disclosure at column 8, lines 15-33, teaches etching or otherwise modifying second layer 29 which is seemingly irrelevant to the first TCO layer 27 with a roughened as- deposited surface according to the disclosure cited by the Examiner (Sopko col. 8, ll. 34-50; Ans. 4). For this reason, the Sopko disclosure identified by Appellants is not contrary to the Examiner's inherency position. In light of the foregoing, we sustain the § 103 rejection of claims 1, 2, and 5-19 to the extent that the rejection is based on the above discussed inherency theory of the Examiner. Rejection (2); the § 103 Rejection of Claims 3 and 4 No additional arguments have been advanced by Appellants against this rejection (App. Br. 17). Therefore, we sustain the rejection of dependent claims 3 and 4 for the reasons discussed above. Appeal 2010-006397 Application 11/514,320 8 Rejection (3); the § 103 Rejection of Claim 20 The Examiner concludes that, in view of Pecoraro, it would have been obvious to provide the Nelson/AAPA/Hunt combination with a glass substrate having the composition required by claim 20. Further, the Examiner determines that, in view of their compositional identity, the resulting glass substrate would be expected to necessarily and inherently possess the claimed visible transmission and color values of the claim 20 glass substrate (Ans. 6, para. bridging 9-10). Appellants do not contest the Examiner's obviousness conclusion (see App. Br. 17-18). As for the Examiner's inherency determination, Appellants state that "myriad other factors may influence these values" (id. at 18) and argue that "[t]he Final Office Action does not reconcile these different possibilities, much less explain why the specifically claimed values are to be 'expected'" (id.). Contrary to Appellants' argument, the Examiner has reasonably explained why the glass substrate of the prior art combination would be expected to necessarily and inherently possess the visible transmission and color values required by claim 20. As indicated above, this explanation is based on the Examiner's undisputed determination that the glass substrates resulting from the prior art combination and defined by claim 20 are compositionally identical. Products of identical compositions cannot have mutually exclusive properties. In re Spada, 911 F.2d 705, 708 (Fed. Cir. 1990). As for Appellants' statement that "myriad other factors may influence these [claim 20] values" (App. Br. 18), no such "myriad other factors" have been identified by Appellants. Appeal 2010-006397 Application 11/514,320 9 Under these circumstances, the appeal record convincingly supports the Examiner's inherency determination under review. We sustain, therefore, the § 103 rejection of claim 20. Rejection (4); the § 103 Rejection of Claim 21 According to the Examiner, "[r]egarding the structural features [i.e., nanostructures] of the film [sic, anti-reflection coating] claimed by applicant, it is axiomatic that one who performs the steps of a process must necessarily produce all of its advantages and the mere recitation of a newly discovered property that is inherently possessed by the steps in the prior art does not cause a claim drawn to those steps to distinguish over the prior art" (Ans. para. bridging 7-8). The deficiency of this statement is that the Examiner has not identified any disclosure in the applied prior art which corresponds to the process recitation in claim 21 concerning use of flame pyrolysis to form the claimed nanostructures. In the record before us, only Hunt has been identified by the Examiner as containing such disclosure, and this reference has not been applied in the rejection under consideration. For these reasons, the record provides no support for a determination that the prior art combination of this rejection would necessarily and inherently result in an anti-reflection coating with the nanostructures required by claim 21. In addition, the Examiner concludes that "it would have been obvious . . . to create an anti-reflective coating having nanostructures comprising peaks and valleys (e.g. surface roughness) as taught by Sopko Appeal 2010-006397 Application 11/514,320 10 in Nelson/AAPA/Pecoraro in order to achieve the predictable result of forming an anti-reflective coating with nanostructures comprising peaks and valleys with the reasonable expectation of success" (Ans. sentence bridging 7-8). As indicated previously and correctly argued by Appellants (App. Br. para. bridging 14-15, 19), Sopko contains no teaching or suggestion of the nanostructures required by claim 21. As a consequence, the prior art identified by the Examiner fails to establish a prima facie case of obviousness for the claim 21 subject matter. For the above stated reasons, we cannot sustain the § 103 rejection of claim 21. The New Ground of Rejection Pursuant to our authority under 37 C.F.R. § 41.50(b), we make a new ground of rejection against claim 21 under 35 U.S.C. § 103(a) as unpatentable over Nelson in view of AAPA, Hunt, and Pecoraro. For the reasons detailed above, the appeal record supports a conclusion that it would have been prima facie obvious for one with ordinary skill in this art to combine the here applied prior art in the manner proposed by the Examiner in rejecting claims 1 and 20, thereby resulting in a solar cell of the type defined by claim 21. Moreover, as previously explained, Appellants have provided the record with no argument contesting the Examiner's proposed combination of this prior art. Finally, the record reasonably supports the earlier discussed determinations (1) that the resulting anti-reflection coating formed by Hunt's flame pyrolysis Appeal 2010-006397 Application 11/514,320 11 would necessarily and inherently possess the nanostructures required by claim 21 and (2) that the resulting glass substrate comprising Pecoraro's composition would necessarily and inherently possess the visible transmission and color values required by claim 21. This decision contains a new ground of rejection pursuant to 37 C.F.R. § 41.50(b). 37 C.F.R. § 41.50(b) provides “[a] new ground of rejection pursuant to this paragraph shall not be considered final for judicial review.†37 C.F.R. § 41.50(b) also provides that the Appellants, WITHIN TWO MONTHS FROM THE DATE OF THIS DECISION, must exercise one of the following two options with respect to the new ground of rejection to avoid termination of the appeal as to the rejected claims: (1) Reopen prosecution. Submit an appropriate amendment of the claims so rejected or new evidence relating to the claims so rejected, or both, and have the matter reconsidered by the examiner, in which event the proceeding will be remanded to the examiner. . . . (a) Request rehearing. Request that the proceeding be reheard under § 41.52 by the Board upon the same record. . . . Conclusion The decision of the Examiner is affirmed-in-part. A new ground of rejection is made against claim 21. AFFIRMED-IN-PART 37 C.F.R. § 41.50(b) cam Copy with citationCopy as parenthetical citation