Ex Parte MARQUES MOTA et alDownload PDFPatent Trial and Appeal BoardFeb 27, 201914219058 (P.T.A.B. Feb. 27, 2019) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE FIRST NAMED INVENTOR 14/219,058 03/19/2014 Filipe Manuel MARQUES MOTA 23599 7590 03/01/2019 MILLEN, WHITE, ZELANO & BRANIGAN, P.C. 2200 CLARENDON BL VD. SUITE 1400 ARLINGTON, VA 22201 UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. PET-2934 7515 EXAMINER LOUIE, PHILIP Y ART UNIT PAPER NUMBER 1772 NOTIFICATION DATE DELIVERY MODE 03/01/2019 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): docketing@mwzb.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte FILIPE MANUEL MARQUES MOTA, CHRISTOPHE BOUCHY, PASCAL DUCHENE, and JOHAN MARTENS Appeal 2018-003 848 Application 14/219,058 Technology Center 1700 Before MICHAEL P. COLAIANNI, GEORGE C. BEST, and N. WHITNEY WILSON, Administrative Patent Judges. COLAIANNI, Administrative Patent Judge. DECISION ON APPEAL Appellants 1 appeal under 35 U.S.C. § 134 the final rejection of claims 1-3 and 5-17. We have jurisdiction over the appeal pursuant to 35 U.S.C. § 6(b ). We AFFIRM. 1 Appellants identify IFP Energies N ouvelles as the real party in interest (Appeal Br. 1 ). Appeal2018-003848 Application 14/219,058 Appellants' invention is directed to a method of making fuel from a paraffinic feed obtained from a renewable resource, such as vegetable oils or animal fats (Spec. 1:1-10). Claims 1, 16, and 17 are illustrative (emphasis added): 1. A hydroisomerization process of a paraffinic feed comprising hydrocarbons containing in the range of 9 to 25 carbon atoms, wherein said paraffinic feed has been produced from renewable resources, and excludes paraffinic feeds obtained by a process comprising a step for upgrading by a Fischer-Tropsch method, said process comprising hydroisomerizing the paraffinic feed in the presence of a catalyst, wherein the catalyst comprises at least one hydrodehydrogenating metal selected from the group consisting of metals from group VIB and from group VIII of the periodic classification of the elements, alone or as a mixture, and a support comprising at least one Nu-10 zeolite and at least one silica-alumina, the quantity by weight of the Nu-10 zeolite being less than the quantity by weight of the silica-alumina, said process operating at a temperature in the range of 150°C to 500°C, at a pressure in the range of0.1 MPa to 15 MPa, at an hourly space velocity in the range of 0.1 to 10 h-1 and in the presence of a total quantity of hydrogen mixed with the feed such that the hydrogen/feed ratio is in the range of 70 to 2000 Nm3 /m3 of feed, wherein the silica-alumina in the support for said catalyst contains a quantity of more than 5% by weight and less than or equal to 95% by weight of silica, and wherein said catalyst contains a binder and contains a total quantity ofNu-10 zeolite and silica-alumina in the range of 1.5% to 94.5% by weight with respect to the total mass of said catalyst, or wherein said catalyst does not contain a binder and contains a total quantity of Nu-10 zeolite and silica-alumina of at least 5 0% by weight with respect to the total mass of said catalyst. 2 Appeal2018-003848 Application 14/219,058 16. The process as claimed in claim 1, which has an iso-C16 multi-branched product yield of 3 9%. 1 7. The process as claimed in claim 1, which has a cracking yield of 11%. Appeal Br. 15, 17 (Claims App.). Appellants appeal the following rejection: 2 I. Claims 1-3 and 5-17 are rejected under 35 U.S.C. § 103 as unpatentable over McCall et al. (US 2009/0162264 Al; published June 25, 2009, "McCall") in view ofMarcilly et al. (US 6,198,015 B 1; issued Mar. 6, 2001, "Marcilly"), Benazzi et al. (US 7,250,106 B2; issued July 31, 2007, "Benazzi"), and further view of Krishna et al. (US 2011/0315598 Al; published Dec. 29, 2011, "Krishna") (Final Act. 10-22). With the exception of claims 16 and 17, Appellants do not argue any of the dependent claims separately (Appeal Br. 3-13; Reply Br. 1-10). We select independent claim 1 as representative. Any claim not argued separately will stand or fall with our analysis of the rejection of claim 1. FINDINGS OF FACT & ANALYSIS The Examiner's findings and conclusions regarding McCall, Marcilly, Benazzi, and Krishna are located on pages 10-22 of the Final Action dated March 3, 2017 and pages 16-25 of the Answer dated December 28, 2017. 2 In the Final Office Action, dated March 3, 201 7, claims 16 and 17 were rejected as: (i) failing to comply with the written description requirement and (ii) indefinite. The Examiner has withdrawn these rejections (Ans. 14-- 15). 3 Appeal2018-003848 Application 14/219,058 The Examiner finds that McCall discloses or suggests each step and element of the claimed hydroisomerization process, with the exception that McCall is silent with respect to, inter alia, a support comprising at least one Nu-10 zeolite and at least one silica-alumina (Final Act. 10-11). The Examiner further finds that McCall does not disclose or suggest that the quantity by weight of the Nu- IO zeolite is less than the quantity by weight of the silica-alumina within this support (id. at 11 ). The Examiner, however, finds that Marcilly discloses at least one molecular sieve, such as Nu- I 0, and a matrix, such as silica-alumina (id. at 12 (citing Marcilly 3:34--37; 5:57---60)). The Examiner further finds that Marcilly discloses that the molecular sieve and matrix form a mixture[,] which is considered a support .... Marcilly further discloses that the content of molecular sieve (e.g.[,] Nu- I 0) in the mixture (i.e.[,] molecular sieve + matrix) is generally in the range of 0.5% to 99.9% and preferably in the range of 20% to 70%, by weight .... This indicates that the quantity by weight of Nu-10 zeolite may be less than the quantity by weight of silica-alumina when the molecular sieve content is less than 5 0%, and Marcilly is therefore considered to reasonably disclose a range of Nu-10 content that overlaps the claimed limitation of the quantity by weight of Nu-10 zeolite being less than the quantity by weight of silica-alumina. (Final Act. 12 (citing Marcilly 5:52-58; 6:48-59) (emphasis added). Appellants argue that the Examiner has not established a prima facie case of obviousness (Appeal Br. 9). In particular, Appellants argue that Marcilly's catalytic activity stems from the molecular sieve having Nu-I 0, but that silica-alumina is merely a matrix for shaping (id. ( citing Marcilly 3:7-9; 3:34--44; 5:59---60)). Thus, Appellants assert that Marcilly does not teach or suggest that "[s]ilica-alumina is provided as a molecular sieve 4 Appeal2018-003848 Application 14/219,058 component in an amount of greater than 50% or is even present as the active phase as in the catalysts at all" (Appeal Br. 9) ( emphasis added). Appellants' arguments are not persuasive because claim 1 does not exclude the support from the catalyst. Rather, the claimed catalyst comprises at least one hydrodehydrogenating metal and a support. Appellants' Specification describes "a fixed bed catalyst ... comprising a hydrodehydrogenating function and an amorphous support" (Spec. 8: 8-9 (emphasis added); see also id. at 8:13-15). Having determined that claim 1 encompasses a catalyst comprising a silica-alumina support, we note that Marcilly explicitly discloses that "the term 'support' means the molecular sieve [having Nu-1 Oj+matrix mixture" and that such a matrix may include "amorphous silica-aluminas" (Marcilly 5:57-58; see also id. at 3:34--37) (emphasis added). We, therefore, agree with the Examiner that Marcilly teaches or suggests the claimed catalyst comprising a support, which further comprises at least one Nu-10 zeolite and at least one silica-alumina (see Ans. 22-23). On these facts, Appellants have not identified reversible error in the Examiner's finding that Marcilly reasonably discloses a range ofNu-10 content that overlaps the claimed limitation of the quantity by weight ofNu- 10 zeolite being less than the quantity by weight of silica-alumina (see id.). On the other hand, Appellants argue that the Examiner's Answer "continues to rely upon mere generic overlap" in Marcilly (Reply Br. 7). We, however, agree with the Examiner that Marcilly's disclosure of compositions containing components in amounts that overlap the range of Nu- IO recited in claim 1 are sufficient to have rendered the claimed subject matter obvious. See In re Peterson, 315 F.3d 1325, 1329 (Fed. Cir. 2003) 5 Appeal2018-003848 Application 14/219,058 (holding that a prima facie case of obviousness typically exists when the ranges of a claimed composition overlap the ranges disclosed in the prior art). When the Examiner establishes a prima facie case of obviousness, "[t]he burden then shifts to the applicant, who then can present arguments and/or data to show that what appears to be obvious, is not in fact that, when the invention is looked at as a whole." In re Dillon, 919 F.2d 688, 696 (Fed. Cir. 1990) ( en bane). Thus, "the burden of showing unexpected results rests on [the party] who asserts them." In re Klosak, 455 F.2d 1077, 1080 (CCPA 1972). For the reasons below, Appellants have not met their burden of showing unexpected results. Appellants argue that the isomerization performance obtained using Catalyst C3 provides unexpected results and, thus, rebuts any established prima facie case of obviousness (Appeal Br. 3-5; see Spec. 29; Table 1). There is no dispute that claims 16 and 1 7 are directed to the product yield and cracking yield, respectively, obtained by a single Catalyst C3 having a 6% Nu- IO amount based on the weight of Nu- IO and silica-alumina (Adv. Act. 2; see Spec. 29; Table 1 ). The Examiner finds, however, that these results are not probative evidence of unexpected results because: (i) they are not commensurate in scope with the claims, (ii) there is no comparison of the claimed process to the closest prior art, and (iii) there is an insufficient number of tests within and outside of the claimed range to show its criticality (Adv. Act. 2). Appellants respond by asserting that the Examiner made three reversible errors in finding that the proffered evidence was not a proper showing of unexpected results (Appeal Br. 5-9). 6 Appeal2018-003848 Application 14/219,058 First, Appellants contend that because claims 16 and 17 require the presence of the purported unexpected properties, the Examiner erred in requiring that Appellants "provide evidence of exactly which N[ u ]-10 values within the range defined in claim 1 result in either an iso-C[ 16] multi- branched product yield of 39% or a cracking yield of 11 %" (id. at 6). Appellants' argument is not persuasive. As the Examiner determined, claim 1 encompasses catalysts comprising Nu- IO amounts from greater than 0% to less than 50% based on the weight ofNu-10 and silica-alumina (see Ans. 16; 22-23). Based on this reasoned claim construction, we agree with the Examiner that claims 1, 16, and 17 are not limited to a catalyst having a 6% Nu- IO amount based on the weight ofNu-10 and silica-alumina. Thus, Appellants have not shown that the results recited in claims 16 and 17 are achievable using all catalysts having Nu-10 amounts throughout the range recited in claim 1 (Adv. Act. 2). As the Examiner finds, it is not clear whether a catalyst having 49% Nu- I 0 would have a similar product yield and cracking yield as Catalyst C3, having 6% Nu- IO (id.). Therefore, the performance results obtained by Catalyst C3 are not commensurate in scope with the claims. Second, Appellants argue that the Examiner erred in concluding that because the prior art combination discloses a similar process of hydroisomerization of a feed comprising hydrocarbons containing in the range of 9 to 25 carbon atoms, under overlapping conditions, in the presence of a similar catalyst as claimed, it follows that with the same feed, similar conditions 7 Appeal2018-003848 Application 14/219,058 and similar catalyst, the two processes would function the same and obtain similar results, absent evidence to the contrary. (Adv. Act. 2; see Appeal Br. 6). Appellants further argue that the Examiner's analysis leading to the conclusion that "the resulting process wou[l]d necessarily (inherently) result in a product having the same properties as the claims" was "specifically overturned" in Honeywell International, Inc. v. Mexichem Amanco Holding S.A., 865 F.3d 1348 (Fed. Cir. 2017) (Appeal Br. 6, 7). Appellants' arguments are not persuasive. As set forth above, a prima facie case of obviousness typically exists when the ranges of a claimed composition overlap the ranges disclosed in the prior art. See Peterson, 315 F.3d at 1329. Our review of Honeywell, 865 F .3d 1348 finds that overlapping ranges of a claimed composition were not at issue in that case, nor did the Honeywell Court specifically overturn the holding in Peterson. We, therefore, agree with the Examiner that Honeywell's facts "are not the same as the instant case and therefore the analysis of the decision is not precedential to the facts of the instant case" (Ans. 20; see generally id. at 20-21 ). Third, Appellants argue that the Examiner erred in finding that Appellants have not tested the closest prior art embodiment (Appeal Br. 8; citing MPEP § 716.02(e)(III) and In re Geiger, 815 F.2d 686, 689 (Fed. Cir. 1987) ). As evidence of such testing, Appellants point to the product and cracking yields obtained using Catalyst C4 (Appeal Br. 4, 8; see Declaration of Jean-Pierre Burzynski under 37 C.F.R. § 1.132, Table 1 '; see also Marcilly 7 :44--45 Example 1 ). The Examiner finds, however, that in testing Catalyst C4, Appellants elected to show a comparison of a catalyst containing 60% Nu- I 0, which 8 Appeal2018-003848 Application 14/219,058 falls outside the claimed range (Adv. Act. 2). As set forth above, Marcilly suggests preferable amounts of20-70% Nu-10, which overlaps the claim 1 's limitation of Nu- IO amounts from greater than 0% to less than 50% based on the weight ofNu-10 and silica-alumina (Final Act. 12 (citing Marcilly 5:52- 56)). Thus, the Examiner finds that Appellants did not show a comparison ranging from 20% to less than 50% Nu-10, which falls within Marcilly's suggested amounts and within the claimed process (Adv. Act. 2). The Examiner, therefore, finds that "App[ ell]ant has not compared the closest prior art" (id.). In response, Appellants argue that "[ t ]he correct standard for determining the closest prior art in an unexpected results analysis" is actual testing of the closest prior art embodiment (Reply Br. 8). According to Appellants, "the closest prior art embodiment is one that actually exists in the prior art as opposed to a hypothetical embodiment imagined or constructed in a rejection in view of the teachings of the prior art" (id.) ( emphasis added). Appellants assert that testing of Marcilly' s embodiment Catalyst C4, having 60% Nu- I 0, adequately demonstrates a comparison with the closest prior art. We find these arguments unpersuasive of reversible error because Appellants' argument is premised on an incorrect statement of law. Our review of both MPEP § 716.02(e)(III) and In re Geiger, 815 F.2d at 689 finds that there is no requirement for testing the closest prior art embodiment. Therefore, Appellants have not proffered any evidence to show that the claimed subject matter imparts unexpected results relative to the range disclosed in the closest prior art. See Peterson, 315 F.3d at 1330 ("In general, an applicant may overcome a prima facie case of obviousness 9 Appeal2018-003848 Application 14/219,058 by establishing 'that the [ claimed] range is critical, generally by showing the claimed range achieves unexpected results relative to the prior art range'" (emphasis added) (quoting In re Woodruff, 919 F.2d 1575, 1577-78 (Fed. Cir. 1990))). 3 Furthermore, it is not clear whether a catalyst having 49% Nu- I 0 would have a similar product yield and cracking yield as Catalyst C3, having 6% Nu- I 0, and Catalyst C4, having 60% Nu- IO (see Adv. Act. 2). We, thus, agree with the Examiner that there is an insufficient number of tests within and outside of the claimed Nu- IO range to show its criticality. Therefore, Appellants' arguments fail to identify reversible error in the Examiner's analysis of the proffered showing of unexpected results. On this record, we find that the preponderance of the evidence favors the Examiner's obviousness conclusion with regard to claims 1, 16, and 17. Accordingly, we affirm the Examiner's§ 103 rejection of claims 1-3 and 5-17. 37 C.F.R. § 4I.37(c)(l)(iv). 3 We note the Examiner finds that because "Marcilly discloses Nu-10 amounts less than 50%, ... a closer prior art embodiment than 60% would be a value less than 50%" (Ans. 21) ( emphasis added). Appellants persuasively argue that that "there is no embodiment in Marcilly which discloses this less than 50% embodiment which the Examiner's Answer incorrectly identifies as the 'closest prior art embodiment."' (Reply Br. 6). We, however, view the Examiner's inclusion of the term "embodiment" as harmless error (see Ans. 21 ). As set forth above, Appellants have not identified any persuasive authority for the proposition that only prior art embodiments must be tested to demonstrate unexpected results from the claimed hydroisomerization process. See In re Fritch, 972 F.2d 1260, 1264 (Fed. Cir. 1992) ("It is well settled that a prior art reference is relevant for all that it teaches to those of ordinary skill in the art," including disclosed ranges). 10 Appeal2018-003848 Application 14/219,058 DECISION The Examiner's decision is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(l )(iv). ORDER AFFIRMED 11 Copy with citationCopy as parenthetical citation