Ex Parte Lebouitz et alDownload PDFPatent Trial and Appeal BoardApr 18, 201713512634 (P.T.A.B. Apr. 18, 2017) Copy Citation United States Patent and Trademark Office UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O.Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 13/512,634 05/30/2012 Kyle S. Lebouitz 33495-0006 9741 26587 7590 04/19/2017 MCNEES WALLACE & NURICK LLC 100 PINE STREET P.O. BOX 1166 HARRISBURG, PA 17108-1166 EXAMINER REMAVEGE, CHRISTOPHER ART UNIT PAPER NUMBER 1713 MAIL DATE DELIVERY MODE 04/19/2017 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte KYLE S. LEBOUITZ, ANDREW DAVID JOHNSON, EUGENE KARWACKI JR., SUHAS NARAYAN KETKAR, JOHN NEUMANN, and DAVID L. SPRINGER Appeal 2015-007270 Application 13/512,634 Technology Center 1700 Before TERRY J. OWENS, JAMES C. HOUSEL, and JEFFREY R. SNAY, Administrative Patent Judges. HOUSEL, Administrative Patent Judge. DECISION ON APPEAL Pursuant to 35 U.S.C. § 134(a), Appellants1 appeal from the Examiner’s decision finally rejecting claims 1—4, 9-12, 17, 18, 20, and 21. We have jurisdiction over the appeal under 35 U.S.C. § 6(b). We AFFIRM.2 1 According to Appellants, the real party in interest is SPTS TECHNOLOGIES LIMITED. Br. 1. 2 Our decision refers to the Specification (Spec.) filed May 30, 2012, the Examiner’s Final Office Action mailed May 19, 2014, Appellants’ Appeal Brief (Br.) filed November 13, 2014, and the Examiner’s Answer (Ans.) mailed June 4, 2015. Appeal 2015-007270 Application 13/512,634 STATEMENT OF THE CASE The invention relates to a process for vapor etching semiconductor materials and substrates with improved selectivity, which is the ratio of etching the material to be etched versus those materials that are intended to remain, i.e., not be etched. Spec. Tflf 8—9. Appellants disclose adding oxygen provides a selectivity benefit in the etching process. Id. 112. Further, Appellants contemplate mixtures of gases which include oxygen or are used in place of oxygen to obtain this selectivity benefit, including nitrous oxide, ozone, oxygen atoms, nitrogen dioxide, and carbon dioxide. Id. Appellants disclose a number of ways in which such gases including oxygen may be incorporated into the vapor etching process to provide improved selectivity including pulse cycling with a mixture of an etchant and the gas, etching with the etchant followed by flushing with the gas, and continuous etching with a mixture of the etchant and the gas. Id. 111. Claim 1, reproduced below from the Claims Appendix to the Appeal Brief, is illustrative of the subject matter on appeal. 1. A vapor etching method comprising: (a) placing a material to be etched and an etch resistant material into an etching chamber; (b) following step (a), adjusting a pressure in the etching chamber to a desired pressure; and (c) following step (b), exposing the materials in the etching chamber to an etching gas and to an amount of a gas that comprises oxygen that is selected to obtain a desired selectively ratio of a change in the material to be etched caused by said exposure over a change in the etch resistant material caused by said exposure, wherein step (c) includes sequentially exposing the materials to (1) the etching gas absent the gas that comprises oxygen and (2) to the gas that comprises oxygen absent the etching gas. 2 Appeal 2015-007270 Application 13/512,634 REJECTIONS The Examiner maintains, and Appellants request our review of, the following grounds of rejection under 35 U.S.C. § 103(a): 1. Claims 1—4, 9, 11, 12, 17, 18, 20, and 21 as unpatentable over Yan3 in view of Floyd;4 and 2. Claims 1 and 10 as unpatentable over Yan in view of Huibers.5 ANALYSIS After review of the opposing positions articulated by Appellants and the Examiner, the applied prior art, and Appellants’ claims and Specification disclosures, we determine that the Appellants’ arguments are insufficient to identity reversible error in the Examiner’s obviousness rejections over the combinations of Yan with either Floyd or Huibers. In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011). Accordingly, we affirm the stated obviousness rejections for substantially the fact findings and the reasons set forth by the Examiner in the Examiner’s Answer and the Final Office Action. We offer the following for emphasis. Rejection 1 Appellants do not argue the claims separately, instead focusing on the limitations of independent claims 1 and 17. Br. 4—9. Further, Appellants’ arguments do not distinguish between these independent claims. Thus, we select claim 1 as representative for resolving the issues on appeal. The 3 Yan et al., US 2008/0032439 Al, published February 7, 2008 (hereinafter “Yan”). 4 Floyd et al., US 2009/0071932 Al, published March 19, 2009 (hereinafter “Floyd”). 5 Huibers et al., US 7,362,494 B2, issued April 22, 2008 (hereinafter “Huibers”). 3 Appeal 2015-007270 Application 13/512,634 remaining claims stand or fall with claim 1. 37 C.F.R. § 41.37 (c)(l)(iv) (2014). The Examiner finds Yan teaches a vapor etching method comprising each of the steps as recited in claim 1 except for sequential exposure of the materials to the etchant absent the gas that comprises oxygen followed by the gas that comprises oxygen absent the etchant. Final Act. 4—5. The Examiner also finds Yan teaches an etching selectivity of the etchant alone without a co-etchant may be up to at least 500:1. Id. Therefore, the Examiner concludes that the ordinary artisan would reasonably have expected that performing the etching process with the etchant absent a co etchant would have successfully achieved high selectivity. Id. Moreover, the Examiner finds Yan teaches that purging between etching cycles removes reactive etching byproducts and intermediates, thereby improving selectivity. Id. However, Yan does not specify the purge gas. Id. at 4. For this feature, the Examiner finds Floyd teaches etching processes that utilize an etchant purge between etching cycles, wherein the purge gas may be carbon dioxide. Id. at 5. The Examiner concludes that it would have been obvious to use carbon dioxide as the purge gas in Yan’s process in order to remove etching byproducts and intermediates from the etching chamber as taught by Floyd, thereby improving selectivity. Id. at 6. Appellants contend that the combination of Yan and Floyd fails to disclose or suggest step (c) of claim 1, in particular, either sequentially exposing the materials to the etching gas in the absence of the gas that comprises oxygen and to the gas that comprises oxygen in the absence of the etching gas (or steps (b) and (c) of claim 17, particularly, separately exposing the substrate to the etching gas and the gas comprising oxygen). 4 Appeal 2015-007270 Application 13/512,634 Br. 4. In this regard, Appellants argue that, because Yan teaches that the device to be etched is contemporaneously contacted with both the etchant and a co-etchant, Yan does not teach sequential exposure to the etchant followed by the co-etchant. Id. at 4—5. Appellants also argue that Yan fails to teach that the co-etchant is present in an amount effective to improve etching selectivity. Id. at 5. However, these arguments fail to address the Examiner’s finding regarding Yan’s teaching that the co-etchant, while useful for improving etching selectivity, is not required. See Ans. 5, citing Yan | 83 (“an etching selectivity between the target material and the structural material in the absence of a co-etchant is at least 20:1” and may be “at least 500:1”). In addition, these arguments misapprehend the Examiner’s rejection which is not based on Yan’s use of the co-etchant or modifying Yan’s process to separately etch with the etchant and co-etchant. Instead, the Examiner’s rejection is based on the use of Floyd’s purge gas, carbon dioxide, in Yan’s process for purging the etchant between etching cycles. In this regard, Appellants additionally argue that the claims do not relate to purging with carbon dioxide. Br. 7. Appellants urge that the gas that comprises oxygen is not used to purge the chamber after the etching gas has been introduced, but instead is there to improve the selectivity of the etching gas. Id. Appellants further argue that Floyd fails to teach or suggest that the purge gas has the effect of a co-etchant or is in an amount selected to obtain a desired selectivity ratio of change in the material to be etched. Id. at 8. Moreover, Appellants argue that because Floyd’s purge gas pushes process gases through the system, the purge gas and the process gases are both present simultaneously and are not delivered sequentially. Id. 5 Appeal 2015-007270 Application 13/512,634 “[A]s an initial matter, the PTO applies to the verbiage of the proposed claims the broadest reasonable meaning of the words in their ordinary usage as they would be understood by one of ordinary skill in the art, taking into account whatever enlightenment by way of definitions or otherwise that may be afforded by the written description contained in the applicant’s specification.” In re Morris, 127 F.3d 1048, 1054 (Fed. Cir. 1997). The Examiner’s rejection relies on Floyd’s carbon dioxide purge gas as the “gas that comprises oxygen” recited in claim 1. Final Act 5—6. Appellants do not dispute that carbon dioxide is a gas that comprises oxygen. Instead, Appellants dispute the Examiner’s finding that Floyd’s carbon dioxide purge gas is used in “an amount. . . that is selected to obtain a desired selectivity ratio of a change in the material to be etched caused by said exposure over a change in the etch resistant material caused by said exposure” because Floyd does not attribute any etch function to the carbon dioxide. However, claim 1, rather than requiring that the gas that comprises oxygen itself perform any etching per se, merely requires that the gas that comprises oxygen is selected to obtain a desired etching selectivity ratio. We note Appellants disclose that the selectivity benefit of adding oxygen is shown for the scenario of etching using pulses of xenon fluoride in etching cycles with oxygen flushing between each cycle. Spec. 111. Appellants further disclose that mixtures of gases which include oxygen as well as other oxidizing gases, including carbon dioxide, are contemplated. Id. 112. In addition, Appellants disclose that a “flush of gas between etch cycles can also be incorporated ... by introducing an oxygen or oxygen mixture.” Id. 1 62. Finally, we note that Appellants describe an example wherein the use of 6 Appeal 2015-007270 Application 13/512,634 an oxygen flush gas between pure xenon difluoride etching cycles improved the Selectivity Ratio. Id. H 94—96. Based on these disclosures, we determine that the scope of claim 1 includes carbon dioxide as the claimed gas that comprises oxygen, used as a purge or flush that improves the selectivity ratio, contrary to Appellants’ argument otherwise. As such, the Examiner’s finding that Floyd’s carbon dioxide purge inherently improves the selectivity of the xenon difluoride etching process is likewise supported by the record. As to the recited “in an amount” in the claim recitation at issue, we note that Appellants fail to identify any criticality in the amount of the purge gas used in the disclosed process. In this regard, Appellants do not direct our attention to any disclosure, nor do we find any, of any specific amount of the gas that comprises oxygen that is used in the purging or flushing of the etching chamber between etching cycles with pure xenon difluoride. Appellants further argue that because claim 1 recites “an amount of a gas that comprises oxygen that is selected to obtain a desired selectivity ratio,” the Examiner erred in finding that the claims do not require that the gas that comprises oxygen improves selectivity of etching gases generated in situ. We note Appellants disclose that the concept of adding oxygen (or other gas that comprises oxygen) is believed to improve the selectivity of xenon difluoride or other vapor phased etching gases generated in situ. Spec. 113. Thus, while Appellants are correct that the claims include the possibility for improved selectivity of etching gases generated in situ, the claims do not definitively require such. Nonetheless, to the extent that Appellants’ claims cover this possibility, such would necessarily occur in the Examiner’s proposed modification of Yan’s process, which uses xenon 7 Appeal 2015-007270 Application 13/512,634 difluoride as the etching gas and provides a purge gas between etching cycles, with the use of Floyd’s carbon dioxide purge gas. It follows, therefore, that Appellants have not identified reversible error in the Examiner’s conclusion of obviousness over Yan in view of Floyd. Accordingly, we sustain this rejection. Rejection 2 Appellants do not argue the claims separately, instead focusing on the limitations of independent claim 1. Br. 9—12. As such, we limit our discussion below to claim 1. Claim 10 stands or falls with claim 1. The Examiner finds Yan teaches a vapor etching method comprising each of the steps as recited in claim 1 except for sequential exposure of the materials to the etchant absent the gas that comprises oxygen followed by the gas that comprises oxygen absent the etchant. Final Act. 9—10. The Examiner also finds Yan teaches an etching selectivity of the etchant alone without a co-etchant may be up to at least 500:1. Id. at 10. Therefore, the Examiner concludes that the ordinary artisan would reasonably have expected that performing the etching process with the etchant absent the co etchant would have successfully achieved high selectivity. Id. The Examiner finds Huibers discloses a method for forming micromirror devices by vapor phase etching that includes exposing a material to an etchant to remove a portion of sacrificial material to expose at least a portion of deformable hinges for the micromirrors, followed by exposure to an oxygen-containing gas other than air followed by removal of the remaining sacrificial material. Id. at 11. The Examiner concludes that it would have been obvious to modify Yan’s method of forming movable 8 Appeal 2015-007270 Application 13/512,634 micromirrors to include a step of oxidizing the deformable hinges by exposing to oxygen gas after etching in order to prevent micromirror device failure as taught by Huibers. Id. Appellants argue that the Examiner’s combination of Yan and Huibers fails to disclose step (c) of claim 1. Br. 9. In particular, Appellants argue that the present invention does not relate to oxidizing hinges, nor to addressing any problem associated with plastic deformation of these hinges. Id. at 10. As such, Appellants urge that the purpose of the claimed invention is completely different from that of Huibers. Id. at 10—11. Appellants further contend that neither Yan nor Huibers teach sequential exposure to two gases to achieve a desired selectivity. Id. Indeed, Appellants argue that Huibers is in a different technical field to that of the invention and the ordinary artisan would not look to Huibers to use oxygen for an entirely different reason to arrive at the invention of claim 1. Id. Appellants’ arguments are not persuasive of reversible error. Our reviewing court has stated that “[t]wo separate tests define the scope of analogous prior art: (1) whether the art is from the same field of endeavor, regardless of the problem addressed and, (2) if the reference is not within the field of the inventor’s endeavor, whether the reference still is reasonably pertinent to the particular problem with which the inventor is involved.” In re Bigio, 381 F.3d 1320, 1325 (Fed. Cir. 2004). While these two criteria are helpful in many instances, we must not lose sight of the key question at hand: what is “prior art” as that term is used in 35 U.S.C. § 103(a)? References that are “too remote to be treated as ‘prior art’” are excluded from the obviousness analysis. In re Sovish, 769 F.2d 738, 741, 226 (Fed. Cir. 1985). The non-analogous art test provides helpful insight on 9 Appeal 2015-007270 Application 13/512,634 the underlying question of what is “prior art” within the meaning of the statute; we should not, however, be blind to the reality of the circumstances of the case before us. In re Wood, 599 F.2d 1032, 1036 (CCPA 1979). Nor should we adhere to rigid and mandatory formulas that overly limit the inquiry. KSRInt’l Co. v. Teleflex Inc., 550 U.S. 398, 419 (2007). Focusing on the first of the two tests above, the test for analogous art “requires the PTO to determine the appropriate field of endeavor by reference to explanations of the invention's subject matter in the patent application, including the embodiments, function, and structure of the claimed invention.” Bigio, 381 F.3d at 1325. We thus consider all explanations of the inventors’ subject matter while keeping in mind that prior art is analogous when it “is from the same field of endeavor, regardless of the problem addressed.” Bigio, 381 F.3d at 1320 (emphasis added). Thus, “field of endeavor” should not be defined narrowly based only upon the specific problem addressed. Moreover, when considering field of endeavor, we remain cognizant of the adage that “the name of the game is the claim.” In re Hiniker Co., 150 F.3d 1362, 1369 (Fed. Cir. 1998) (quoting Giles Sutherland Rich, Extent of Protection and Interpretation of Claims—American Perspectives, 21 Inf 1 Rev. Indus. Prop. & Copyright L. 497, 499 (1990)). The Supreme Court has articulated this same sentiment when emphasizing that the patentee’s motivation and purpose do not control an obviousness determination: In determining whether the subject matter of a patent claim is obvious, neither the particular motivation nor the avowed purpose of the patentee controls. What matters is the objective reach of the claim. If the claim extends to what is obvious, it is invalid under § 103. 10 Appeal 2015-007270 Application 13/512,634 KSR, 550 U.S. at 419. Claim 1 broadly recites a vapor etching method. Although Appellants argue that Huibers is in a different technical field to that of the invention, Appellants do not challenge the Examiner’s findings that both Yan and Huibers teach vapor etching methods. Nor do Appellants challenge the Examiner’s findings that Yan and Huibers are both directed to a method of forming micromirrors using vapor etching methods. Further, although the purpose of Huibers’ use of an oxygen exposure step separate from the etchant exposure step is different from that of Appellants, we note that the motivation for obviousness need not be the same as that of Appellants. KSR, 550 U.S. at 419. Here, the Examiner articulates a rational basis for modifying Yan’s method of forming micromirrors to include a separate step of exposure to oxygen after etchant exposure, i.e., to prevent micromirror device failure due to plastic deformation of the hinges. Final Act. 11. Moreover, the Examiner finds that Huibers’ oxidation process demonstrably changes the selectivity of the etching process to an oxidizing process and inherently alters the etching selectivity of the hinges by the formed oxide. Ans. 7. Appellants have not challenged these findings; no Reply Brief has been filed. Appellants additionally argue that because Huibers is silent as to the pressure of the oxygen used to effect oxidation, Huibers fails to disclose or suggest “adjusting a pressure in the etching chamber to a desired pressure.” Br. 11. This argument is not persuasive because claim 1 merely requires that the pressure is adjusted after step (a) and before step (c). Appellants do not dispute the Examiner’s finding that Yan’s method includes a step of adjusting the pressure in the etching chamber after placing a material to be 11 Appeal 2015-007270 Application 13/512,634 etched in the chamber and before exposing the material to the etchant. Final Act. 9. Further, the Examiner’s modification of Yan’s method in view of Huibers provides a separate exposure to oxygen after the etchant exposure. Id. at 11. As such, Yan’s pressure adjustment step is unmodified in the Examiner’s proposed combination. Appellants’ argument presumes otherwise and is therefore without merit. It follows, therefore, that Appellants have not identified reversible error in the Examiner’s conclusion of obviousness over Yan in view of Huibers. Accordingly, we sustain this rejection. DECISION Upon consideration of the record, and for the reasons given above and in the Final Office Action and the Answer, the decision of the Examiner rejecting claims 1—4, 9-12, 17, 18, 20, and 21 under 35 U.S.C. § 103(a) as unpatentable over Yan in view of Floyd or Huibers is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1). AFFIRMED 12 Copy with citationCopy as parenthetical citation