Ex Parte Koo et alDownload PDFPatent Trial and Appeal BoardSep 28, 201613201961 (P.T.A.B. Sep. 28, 2016) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE FIRST NAMED INVENTOR 13/201,961 08/17/2011 NamilKoo 4372 7590 09/30/2016 ARENT FOX LLP 1717 K Street, NW WASHINGTON, DC 20006-5344 UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. 108910-00268 4694 EXAMINER OCHYLSKI, RY AN M ART UNIT PAPER NUMBER 1743 NOTIFICATION DATE DELIVERY MODE 09/30/2016 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address( es): patentdocket@arentfox.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PA TENT TRIAL AND APPEAL BOARD Ex parte NAMIL KOO, 1 Ulrich Plachetka, and Christian Moonnann Appeal2015-003851 Application 13/201,961 Technology Center 1700 Before BRADLEY R. GARRIS, MARK NAGUMO, and JEFFREY R. SNAY, Administrative Patent Judges. NAGUMO, Administrative Patent Judge. DECISION ON APPEAL Namil Koo, Ulrich Plachetka, and Christian Moormann ("Koo") timely appeal under 35 U.S.C. § 134(a) from the Final Rejection2 of claims 1-14, which are all of the pending claims. We have jurisdiction. 35 U.S.C. § 6. We affirm. 1 The real party in interest is identified as Solvay Solexis S.P.A. (Appeal Brief, filed 29 September 2014 ("Br."), 2.) 2 Office action mailed 28 January 2014 ("Final Rejection"; cited as "FR"), as modified by the Advisory Action (8 August 2014) entering formal amendments to claim 1 filed 28 July 2014. Appeal2015-003851 Application 13/201,961 A. Introduction3 OPINION The subject matter on appeal relates to processes of imprint nanolithography using shaped soft elastomeric moulds as imprinting forms. Prior art methods using perfluoropolyether-based moulds are said to have "certain sagging and deformation problems in moulds having recesses or protrusions of sizes below 100 nm (e.g. 50 nm)" (Spec. 2 [0008].) These problems are said to be ameliorated by providing perfluoropolyoxyalkylene chains ("RI') having a molecular weight in the range of 1000 to 3500. (Id. at 3 [0012].) Moreover, as an imprint medium for the soft moulds, a UV-curable (pre )polymer compositions (P) comprising Si02 or Zr02 nanoparticles is preferred. (Id. at 12 [0059] and [0061].) The claimed processes comprise forming the soft mould (steps (a)-( c) ), followed by imprinting and curing the prepolymer composition (P), and processing the cured object to obtain the desired article, recited in steps (d) and (e). Claim 1 is representative and reads: A method for replicating a pattern, said method comprising: (a) providing a patterned template, wherein said patterned template comprises a patterned template surface having a plurality of recessed or protruded areas formed therein, and wherein the plurality of recessed or protruded areas have sizes less than 50 nm; 3 Application 13/201,961, Nanolithography process, filed 17 August 2011, as the national stage under 35 U.S.C. § 371 of PCT/EP2010/051880, filed 16 February 2010, claiming the benefit of an application filed in the EPO on 19 February 2009. We refer to the '"961 Specification," which we cite as "Spec." 2 Appeal2015-003851 Application 13/201,961 (b) contacting a volume of a curable pertluoropolyether composition (composition (C)) with said patterned template surface, said composition comprising: - at least one functional perfluoropolyether compound (compound (E) ), said compound (E) comprising a (per)fluoropolyoxyalkylene chain (chain (Rf)), wherein the molecular weight of said chain Rf is more than 1000 and less than 3500; and at least two unsaturated moieties; and - at least one photoinitiator; ( c) submitting to UV radiations said composition (C) to yield a mold comprising a patterned mold surface, and separating said mold from said patterned template; ( d) contacting said patterned mold surface with a (pre )polymer composition (composition (P)); (e) processing said composition (P) to yield an article having a patterned surface, and separating said article from said mold, wherein said composition (P) comprises an inorganic filler having an average particle size of less than 1 µm, wherein said composition (P) comprises Si02 and/or Zr02 particles having average sizes comprised between 1 and 15 nm. (Claims App., Br. 17; some indentation, paragraphing, and emphasis added.) 3 Appeal2015-003851 Application 13/201,961 The Examiner maintains the following grounds of rejection4 : A. Claims 1-6 and 8-13 stand rejected under 35 U.S.C. § 103(a) in view of the combined teachings of Petrucci-Samija5 and Wang. 6 Al. Claims 7 and 14 stand rejected under 35 U.S.C. § 103(a) in view of the combined teachings of Petrucci-Samija, Wang, and Watts. 7 B. Discussion Findings of fact throughout this Opinion are supported by a preponderance of the evidence of record. Koo urges (Br. 12-14) that the general disclosure in Wang of prepolymer compositions containing silica nanoparticles suitable for use in imprint nanolithography conducted with rigid nickel-based embossing tools is insufficient to establish that it would have been prima facie obviousness to use such prepolymer compositions as the imprinted media for the soft imprint nanolithographic printing forms described by Petrucci-Samija. Such teachings by Wang, in Koo's view, actually teach away from use with the soft imprint moulds taught by Petrucci-Samija. 4 Examiner's Answer mailed 12 December 2014 ("Ans."). 5 Maria Petrucci-Samija et al., Printing form precursor and process for preparing a stamp from the precursor, U.S. Patent Application Publication 2008/0000373 Al (2008). 6 Zhikai Wang, Curable halogenated compositions, U.S. Patent Application Publication 2003/0050358 Al (2003). 7 Michael P.C. Watts et al., Low viscosity high resolution patterning material, U.S. Patent Application Publication 2003/0235787 Al (2003). 4 Appeal2015-003851 Application 13/201,961 These arguments are not persuasive of harmful error in the appealed rejections. We find that Koo does not challenge the Examiner's findings that Petrucci-Samija teaches or suggests process steps corresponding to steps (a) through ( c ), or the Examiner's findings that Wang teaches a prepolymer composition corresponding to the composition (P) recited in steps ( d) and ( e ). We find further that Petrucci-Samija describes the soft imprinting device as being suitable for imprint lithography. (Petrucci-Samija 7 [0064].) Koo does not, however, direct our attention to any credible evidence of record that the artisan would have regarded the utility of the imprinting composition taught by Wang for rigid imprinting devices would have indicated that those compositions would not be suitable for the soft imprinting devices taught by Petrucci-Samija. The '961 Specification does not indicate that any particular problems arise regarding the prepolymer composition for soft-imprint nano-lithography. Indeed, the Specification teaches that "[t]he selection of the (pre)polymer composition is not particularly limited and will be selected taking into account the particular processing technique to be used." (Spec. 9 [0041].) A prima facie case of obviousness does not require certainty; a reasonable expectation of success suffices. Koo has not come forward with credible evidence and argument that the Examiner erred in concluding that the artisan, armed with the teachings of Petrucci-Samija regarding general utility of the soft imprinting device (Petrucci-Samija 7 [0064]) and the teachings of Wang regarding the imprinting composition (adhesion to the substrate before curing, release from the substrate after curing (Wang 6 [0046]), low surface energy, low volume shrinkage upon cure for 5 Appeal2015-003851 Application 13/201,961 precise surface-relief transfer (id. at [0047])) would have had a reasonable expectation of imprinting Wang's prepolymer compositions with the soft nano-lithography moulds described by Petrucci-Samija. Koo does not raise substantively distinct arguments for any dependent claims, including separately rejected claims 7 and 14. C. Order It is ORDERED that the rejection of claims 1-14 is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § l.136(a). AFFIRMED 6 Copy with citationCopy as parenthetical citation