Ex Parte Janssen et alDownload PDFPatent Trial and Appeal BoardJan 31, 201712933518 (P.T.A.B. Jan. 31, 2017) Copy Citation United States Patent and Trademark Office UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O.Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 12/933,518 12/13/2010 Robert Hendrik Catharina Janssen BHD-4662-1666 9543 23117 7590 02/02/2017 NIXON & VANDERHYE, PC 901 NORTH GLEBE ROAD, 11TH FLOOR ARLINGTON, VA 22203 EXAMINER PAPE, ZACHARY ART UNIT PAPER NUMBER 2835 NOTIFICATION DATE DELIVERY MODE 02/02/2017 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): PTOMAIL@nixonvan.com pair_nixon @ firsttofile. com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte ROBERT HENDRIK CATHARINA JANSSEN and FRANCISCUS VAN VEHMENDAHL Appeal 2016-000624 Application 12/933,518 Technology Center 2800 Before LINDA M. GAUDETTE, MARK NAGUMO, and, JENNIFER R. GUPTA, Administrative Patent Judges. GAUDETTE, Administrative Patent Judge. DECISION ON APPEAL Appeal 2016-000624 Application 12/933,518 Appellants1 appeal under 35 U.S.C. § 134(a) from the Examiner’s decision2 finally rejecting claims 1—14. We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM. “The invention relates to a heatsink for an electrical or electronic device.” Specification filed Sept. 20, 2010 (“Spec.”), 1:3—4. At the time of the invention, it was known in the art to use thermally conductive plastic materials as heatsinks. Id. at 1:12—15. According to the Specification, “[ajlthough thermally conductive plastic materials generally combine the properties of thermal conductivity and electrical insulation, they normally suffer in at least one of them.” Id. at 1:29—31. The Specification further discloses that fillers added to improve one property may have a detrimental effect on other properties of the heatsink, including mechanical properties. See id. at 1:35—2:11. The Specification discloses, for example, that a heatsink should have flame retarding properties, however, addition of a flame retardant increases filler load thereby reducing the mechanical properties of the heatsink. Id. at 2:5—10. According to the Specification, the inventors have discovered that “heatsinks with a plastic body made of a thermally conductive plastic material comprising at least 20 wt.% expanded graphite showed a substantial improvement in flame retardancy as demonstrated by a higher glow wire flammability index (GWFI). . . without the addition of flame retardant.” Id. at 2:18—23. The Specification discloses that although suitable thermally conductive components include aluminum, boron nitride, graphite, etc. {id. at 7:15—17), “[t]he advantage of expanded graphite as the thermally conductive component in the plastic 1 Appellants identity the real party in interest as DSM IP Assets, B.V. Appeal Brief filed May 26, 2015 (“App. Br.”), 2. 2 Final Office Action mailed Feb. 24, 2015. 2 Appeal 2016-000624 Application 12/933,518 composition from which the heatsink is made is that it imparts a high thermal conductivity already at a relatively low weight percentage, meanwhile significantly improving the GWFI properties” (id. at 9:1—4). According to the Specification, the composition used for making the heatsink “may be any composition having sufficient thermal conductivity and . . . suitable for making plastic parts” (id. at 6:4—5), but is preferably a thermoplastic polymer such as a polyamide (id. at 6:21 and 26—27. The Specification further discloses that the thermoplastic polymer can be an amorphous, a semi-crystalline, or a liquid crystal polymer. Id. at 6:21—23. The Specification discloses that the inventive heatsink can be either electrically conductive or electrically non-conductive “[depending on the amount of expanded graphite and eventually depending on the type and amount of other thermally conductive components.” Id. at 3:22—25. The Specification discloses a specific example in which a composition comprising 70% wt.% polyamide-46 (“PA 46”) and 30 wt.% expanded graphite achieved a passing GWFI at 960°C when tested according to IEC-60695-2 (id. at 12:19-25), and was used to mold a heat sink having very good electrical insulation properties (id. at 13:5—6). Claim 1 is representative of the invention, and is reproduced below: 1. A heatsink for an electrical or electronic device comprising a plastic body made of a thermally conductive plastic material comprising an expanded graphite in a sufficient amount of at least 25 wt.%, relative to the total weight of the thermally conductive plastic material, to cause the plastic body to achieve a passing glow wire flammability index (GWFI) at 960°C when tested according to IEC-60695-2. App. Br. 21 (Claims App’x). The claims stand rejected under pre-AIA 35 U.S.C. § 103(a) as follows (Final Act. 4—9; see Examiner’s Answer mailed Aug. 12, 2015 (“Ans.”), 2 3 Appeal 2016-000624 Application 12/933,518 (maintaining the Section 103 rejections as set forth in the Final Office Action, but withdrawing the .rejections of claims 1—14 as indefinite under 35 U.S.C. § 112)): 1. Claims 1, 2, 6, and 7 over Tobita et al. (US 2004/0048054 Al, published Mar. 11, 2004 (“Tobita”)) in view of Krassowski et al. (US 2002/0109125 Al, published Aug. 15, 2002 (“Krassowski”)) and Joachimi et al. (US 2003/0162900 Al, published Aug. 28, 2003 (“Joachimi”)); 2. claims 3, 4, 8—12, and 14 over Tobita in view of Krassowski, Joachimi, and Tobita et al. (US 2002/0090501 Al, published Jul. 11, 2002 (“Tobita ’501”)); 3. claim 5 over Tobita in view of Krassowski, Joachimi, Tobita ’501, and Morse (US 2008/0257585 Al, published Oct. 23, 2008); and 4. claim 13 over Tobita in view of Krassowski, Joachimi, Tobita ’501, and Reis et al. (US 2007/0103875 Al, published May 10, 2007 (“Reis”)). Appellants’ arguments in support of patentability are based on limitations common to independent claims 1 and 8. See generally, App. Br. 9—20. Appellants’ traversals of above-listed grounds of rejection 2—\ are limited to contentions that the additional references relied on by the Examiner in support of these rejections fail to cure the deficiencies in the combination of Tobita, Krassowski, and Joachimi. See id. at 17—20; Ans. 7—8. Accordingly, claims 2—7 and 9-14 stand or fall with claims 1 and 8. The Examiner relies on the following disclosures in Tobita, Krassowski, and Joachimi in support of the obviousness rejections (see Final Act. 4—6): Tobita describes several prior art compositions used for mounting electronic parts comprising thermotropic liquid crystalline polymers. Tobita 1 5. In particular, Tobita describes Japanese National Phase Laid-open Publication No. 2001-523892 as disclosing a composition comprising 80 to 20% by weight thermotropic liquid 4 Appeal 2016-000624 Application 12/933,518 crystalline polymer and 20 to 80% by weight of a thermally conductive filler, such as carbon fibers. Id. Tobita provides a list of other known thermally conductive fillers that includes graphite. Id. 14. Krassowski discloses “a process for providing increased electrical and/or thermal conductivity to a material” by incorporating particles of expanded graphite into the material. Krassowski 11. Joachimi discloses the use of polyamide compositions, including PA 46, to form thermoplastic materials having good mechanical properties. Joachimi H 16—17. Based on the foregoing disclosures in Tobita, Krassowski, and Joachimi, the Examiner finds one of ordinary skill in the art would have used 20 to 80% by weight expanded graphite as the thermally conductive filler in the known prior art composition described in Tobita, based on Krassowski’s teaching that expanded graphite provides increased thermal conductivity. Final Act. 4. The Examiner further finds one of ordinary skill in the art would have replaced the 80 to 20% by weight thermotropic liquid crystalline polymer in the composition with PA 46, based on Joachimi’s teaching that PA 46 provides a thermoplastic material with good mechanical/manufacturing qualities. Id. at 5. The Examiner finds the combination would have resulted “in a heat sink which has a thermoplastic body which is 70 wt. % PA-46 and 30 wt. % expanded graphite and thus, as per Table 1 of the present invention written description (Page 12), will pass the claimed glow wire flammability index test.” Id. Appellants argue the disclosure in Tobita relied on by the Examiner is a discussion of background art, and that Tobita actually discourages the use of thermally conductive fillers in amounts that exceed 5 wt. %. App. Br. 10—11 (citing Tobita 6 and 36). In paragraph 6, Tobita discloses that a drawback of the prior art thermally conductive polymer compositions containing large amounts of thermally conductive filler is that the “filler inhibits the thermotropic liquid 5 Appeal 2016-000624 Application 12/933,518 crystalline polymer from exhibiting excellent features, such as electrical insulation properties and low density.” Tobita 1 6. In paragraph 36, Tobita discloses that although thermal conductivity is improved when thermally conductive filler is incorporated into the thermotropic liquid crystalline polymer, density of a molded article made therefrom is increased, causing deterioration of electrical insulation properties. Id. 136. Appellants likewise argue Krassowski teaches away from including more than 20% expanded graphite, citing Krassowski’s statement that expanded graphite powder “should be incorporated at a level of about 1% by weight to about 20% by weight to avoid negatively affecting the mechanical properties of the finished substrate or material” (Krassowski 137). App. Br. 12 and 15. Appellants acknowledge that Joachimi describes the addition of fillers and reinforcing substances to a polyamide in amounts as high as 50%, but contend the ordinary artisan would not have had a reasonable expectation that expanded graphite could be added successfully to a polyamide in such high amounts. App. Br. 16. Appellants cite the Handbook of Reinforcements for Plastics3 as evidence that the amount of a particular filler that can be added to a thermoplastic polymer is a function of its shape and other physical limitations. Id. at 16—17. Appellants cite articles by Sengupta4 and George5 as evidence that one of ordinary skill in the art 3Handbook of Reinforcements for Plastics (pp. 16, 31, 44) by Van Nostrand Reinhold Company Inc., Library of Congress Catalog Card Number 86-28255, ISBN 0-442-26475-5 (Edition 1987). 4 Sengupta et al., A review on the mechanical and electrical properties of graphite and modified graphite reinforced polymer composites, 36 Progress In Polymer Science 638-670 (2011). 5 George et al., Ethylene vinyl acetate/expanded graphite nanocomposites by solution intercalation: preparation, characterization and properties 43 J. Mater. Sci. 702-708 (2008). 6 Appeal 2016-000624 Application 12/933,518 would have understood expanded graphite physically differs from other carbon materials such that it could not be added as a filler to thermoplastic polymers in amounts as high as 25%. App. Br. 13—14. Specifically, Appellants contend Sengupta and George evidence that one of ordinary skill in the art would have understood: expanded graphite is effective in amounts as low as 1.8 wt. %, and no significant increase of desired properties would be expected when expanded graphite is added in amounts above 3.5 wt. % (App. Br. 13 (citing Sengupta); see also Reply Brief filed October 13, 2015 (“Reply Br.”), 4 ); and a “high amount” of expanded graphite is 8 wt.%, and amounts this high have the drawback of lowering tensile strength (App. Br. 13 (citing George); see also Reply Br. 4). We have considered Appellants’ arguments, but do not find them persuasive of reversible error in the Examiner’s conclusion of obviousness for the reasons stated in the Answer. See Ans. 2—7. Tobita discloses that, in the specific case of thermotropic liquid crystalline polymers, the addition of filler increases density and may cause deterioration of electrical insulation properties. Tobita 136. As argued by the Examiner, there is no indication in Tobita that larger amounts of conductive filler would be undesirable when a polyamide is used as the thermoplastic polymer and/or higher electrical conductivity is a desired feature of a heat sink formed from the polymer. Ans. 3. Moreover, Tobita clearly discloses that fillers in amounts of 20—80% have been used successfully in thermotropic liquid crystalline compositions. Tobita 1 5; see Ans. 4. Krassowski teaches that a significant increase in electrical and/or thermal conductivity is provided to “molded plastic articles,” in general (Krassowski 134; see also id. 126 (“a material or article, such as a motor vehicle component part, a grease or oil, an adhesive or a rubber composition”)), by the addition of expanded graphite, and that the potential for causing undesirable effects 7 Appeal 2016-000624 Application 12/933,518 by such addition, such as loss of mechanical properties, can be avoided by limiting the amount of expanded graphite to “about 20% by weight” of the composition (id. 36—37). However, Krassowski also teaches that “higher amounts of [expanded] graphite are feasible,” and that the amount of expanded graphite to be added to a polymer composition “will depend on factors selected by the artisan.” Id. 136. Thus, the Examiner had a reasonable basis for finding that when higher electrical and/or thermal conductivity is desired, the ordinary artisan would have added expanded graphite to the thermoplastic polymer in amounts of 25 wt.% or greater, and had a reasonable expectation of success in so doing based on the teachings of Tobita and Krassowski. Moreover, based on Krassowski’s teaching that addition of expanded graphite in amounts that exceed 20% might have a negative impact on mechanical properties (see Krassowski 136), the Examiner had a reasonable basis for finding that the ordinary artisian would have utilized a polyamide such as PA 46 as the thermoplastic polymer in light of Joachimi’s teaching that polyamides “are characterized by high thermal stability, very good mechanical properties, high toughness values, good resistance to chemicals, and easy processability,” and that “[t]he properties of polyamides can be significantly broadened by reinforcement with glass fibers, glass spheres, mineral fillers and mixtures thereof’ (Joachimi 12). We have considered the teachings of Sengupta, George, and the Handbook of Reinforcements for Plastics, but agree with the Examiner’s determination that the totality of the evidence on this appeal record still favors a conclusion of obviousness as to the appealed claims. See Ans. 5 (“At the very best, the Sengupta et al. and George et al. references may teach that 25 wt. % of expanded graphite in their composition [(e.g. poly(methyl methacrylate) and polystyrene (see Sengupta 644, Table 2), and ethylene vinyl acetate (George, Abstract))] is a large amount.”). 8 Appeal 2016-000624 Application 12/933,518 In sum, for the reasons stated in the Final Office Action, the Answer, and above, we sustain the Examiner’s rejections of claims 1—14 under 35 U.S.C. § 103(a). No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. §1.136(a)(l)(iv). AFFIRMED 9 Copy with citationCopy as parenthetical citation