Ex Parte HowardDownload PDFPatent Trial and Appeal BoardFeb 15, 201712207757 (P.T.A.B. Feb. 15, 2017) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 12/207,757 09/10/2008 HENRY EDWARD HOWARD 08-3019 1302 27182 7590 02/15/2017 PRAXAIR, INC. LAW DEPARTMENT 10 RIVERVIEW DRIVE DANBURY, CT 06810-5113 EXAMINER RUSSELL, DEVON L ART UNIT PAPER NUMBER 3744 MAIL DATE DELIVERY MODE 02/15/2017 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________________ Ex parte HENRY EDWARD HOWARD ____________________ Appeal 2014-003490 Application 12/207,757 Technology Center 3700 ____________________ Before MICHELLE R. OSINSKI, JILL D. HILL, and PAUL J. KORNICZKY, Administrative Patent Judges. OSINSKI, Administrative Patent Judge. DECISION ON APPEAL STATEMENT OF THE CASE Henry Edward Howard (Appellant)1 appeals under 35 U.S.C. § 134 from the Examiner’s decision rejecting claims 1–8, which are all of the pending claims. We have jurisdiction under 35 U.S.C. § 6(b). We AFFIRM-IN-PART. 1 Appellant identifies the real party in interest as Praxair Technology, Inc. Br. 2. Appeal 2014-003490 Application 12/207,757 2 THE CLAIMED SUBJECT MATTER Claim 1, the sole independent claim, is reproduced below and is representative of the claimed subject matter on appeal. 1. A method of supplying refrigeration to air separation plants located within an air separation plant facility, such method comprising: producing a refrigerant at a cryogenic temperature within a refrigeration system; and introducing streams of the refrigerant, while at the cryogenic temperature into the air separation plants such that all or a part of the refrigeration requirements of the air separation plants are supplied by the streams of the refrigerant. EVIDENCE The Examiner relied on the following evidence in rejecting the claims on appeal: REJECTIONS I. Claims 1–4 and 6–8 stand rejected under 35 U.S.C. § 103(a) as unpatentable over Dee and Tranier. Final Act. 2 (incorporating by reference the Non-Final Office Action mailed Aug. 31, 2012 (hereinafter referred to as “Non-Final Act.”)); Non-Final Act. (Aug. 31, 2012) 2–4. II. Claim 5 stands rejected under 35 U.S.C. § 103(a) as unpatentable over Dee, Tranier, and Voit. Final Act. 2 (incorporating by reference Non- Final Act.); Non-Final Act. 4–5. Voit Tranier Dee US 5,802,874 US 7,143,606 B2 US 2008/0000266 A1 Sept. 8, 1998 Dec. 5, 2006 Jan. 3, 2008 Appeal 2014-003490 Application 12/207,757 3 OPINION Rejection I Claims 1, 2, 4, and 6 The Examiner relies on Dee for disclosing a method of supplying refrigeration to an air separation plant, the method comprising “producing a refrigerant at cryogenic temperature (liquid nitrogen 186) within a refrigeration system (2); and introducing a stream of the refrigerant . . . into the air separation plant.” Non-Final Act. 2 (citing Dee, Fig. 1b); Ans. 2–3 (citing Dee, Fig. 1b). The Examiner acknowledges that Dee fails to disclose “multiple air separation plants located in an air separation plant facility.” Non-Final Act. 3; Ans. 3. The Examiner finds that “Tranier discloses the use of multiple air separation units in a single system which share common nitrogen sub-system piping.” Non-Final Act. 3; Ans. 3 (citing Tranier, Fig. 5). The Examiner concludes that “[i]t would have been obvious to one of ordinary skill in the art at the time of the invention to provide multiple air separation units, as taught by Tranier, in order to increase production capacity.” Non-Final Act. 3; Ans. 3. As to why Tranier would lead one of ordinary skill in the art to use streams from the same, single refrigeration system 2 to supply the multiple air separation units, the Examiner takes the position that Tranier teaches “to centrally consolidate functionalities that are common to all separation trains.” Ans. 6. More specifically, the Examiner states that: Trainer proposes that as a matter of optimization in plant design it is desirable to combine heat exchange functions into a central location when possible rather than splitting up an external stream. This optimization through centralization provides the Appeal 2014-003490 Application 12/207,757 4 motivation to simply increase the size of the existing liquid nitrogen generator and route the liquid nitrogen to each of the air separation units, rather than also doubling the number of liquid nitrogen production units. Ans. 6–7. Appellant argues that Dee contemplates “us[ing] the existing plant to supply more nitrogen to the [LNG] liquefier” in order “to allow the liquefier to produce more liquid nitrogen,” not “using the increased liquefaction capability of the liquefier to supply appreciably more refrigeration to the existing plant.” Br. 7. Appellant adds that “there is no suggestion in Dee that the liquefier 2 . . . would ever be used to supply refrigerant to two or more separate air production units 1 to increase production.” Id. at 9. Appellant’s argument is not persuasive because it fails to address the rejection as articulated by the Examiner which is not based on Dee alone, but on the combination of Dee and Tranier. As to Tranier, Appellant argues that rather than teaching supplying refrigeration from a single source (such as an LNG liquefier) to multiple air separation plants, Tranier teaches “a method of supplying refrigeration from [multiple] air separation plants to a [single] natural gas liquefier.” Br. 9 (emphasis added); see also id. at 10, 11 (restating the argument). In particular, Appellant argues that although “Tranier has common piping that connects all of the air separation plants to the natural gas liquefier, it does not have common piping that connects a liquefier or some similar device that would generate refrigerant streams to air separation plants to supply all or part of the refrigeration requirements to such air separation plants.” Id. at 10. Although we agree with Appellant on this point, we are not persuaded of error in the Examiner’s rejection because of it. The rejection as Appeal 2014-003490 Application 12/207,757 5 articulated by the Examiner in the Answer is not based on simply inserting Tranier’s system into that of Dee, but rather on optimizing Dee’s system (after it has been modified to include multiple air separation units as taught by Tranier) based on the broader centralization principles of Tranier so as to centralize the heat exchange function in Dee’s existing liquid nitrogen generator, rather than including multiple liquid nitrogen production units. Ans. 6–7. Appellant does not persuasively address why the Examiner’s reasoning based on the broader centralization principle of Tranier lacks rational underpinnings. Appellant further argues that because “no additional refrigeration is required by the plants shown in Tranier, there would be no suggestion to centrally supply the same from a refrigeration system.” Br. 12. Appellant asserts that the multiple air separation units of Tranier “each ha[ve] its own refrigeration system (turboexpander 13) that is necessary for the plants to operate and supply streams of refrigerant to liquefy the natural gas.” Id. at 11–12. Again, we do not disagree with Appellant on this point, but are not persuaded of error in the Examiner’s rejection because of it. The Examiner’s rejection is based on modifying and optimizing Dee based on the teachings of Tranier (Ans. 6–7), not on modifying Tranier. Appellant does not persuasively explain why the Examiner’s reasoning to modify Dee so as to include multiple air separation units and so as to centralize heat exchange via Dee’s existing liquid nitrogen generator, rather than increasing the number of liquid nitrogen production units, lacks rational underpinnings. Appellant additionally argues that Dee “specifically calls for the liquefier to be designed to accept additional compression equipment to allow the plant output to be increased,” rather than “indicati[ng] that two or more Appeal 2014-003490 Application 12/207,757 6 plants could be connected to the liquefier shown in Dee.” Br. 12. Again, we are not persuaded that the Examiner’s articulated reasoning lacks rational underpinnings. Merely because Dee suggests increasing plant output another way (via supplemental processing unit 3) does not demonstrate that the Examiner’s articulated reasoning to provide multiple air separation units to increase production capacity or plant output (Ans. 3) lacks rational underpinnings. For the foregoing reasons, we are not persuaded that the Examiner erred in concluding that Dee and Tranier renders obvious the subject matter of claim 1, and we sustain the rejection of independent claim 1 as unpatentable under 35 U.S.C. § 103(a) over these references. We also sustain the rejection of claims 2, 4, and 6, which depend therefrom, and for which Appellant relies on the same arguments and reasoning we found unpersuasive in connection with the independent claim. Br. 12. Claim 3 Claim 3 depends from claim 1 and recites that “the refrigeration system is operated on an intermittent basis such that liquid production of the air separation plants is increased during operation of the refrigeration system.” Br. 19 (Claims App.). The Examiner finds that Dee’s system meets this claim limitation because the “claim is broad enough to mean that the air separation system is switched on at the same time that the liquid production system is turned on or, alternatively, that the systems merely function concurrently.” Ans. 3 (citing Dee, ¶ 33). Appellant argues that “Dee does not . . . contemplate that liquefier 2 could be used on an intermittent basis or in other words[,] an[] ‘on’ and ‘off’ basis because liquefier 2 is the sole source of refrigeration that is supplied to Appeal 2014-003490 Application 12/207,757 7 air separation unit 1 . . . . If liquefier 2 w[]ere turned off, . . . the air separation unit 1 would rapidly heat up, liquid within the columns would dump[,] and it would take hours to restart the plant.” Br. 13. In contrast, Appellant explains that the Specification contemplates the air separation plant can supply its own refrigeration using compressors 26, 29 and expander 32, with this refrigeration being “sufficient to maintain the plant in thermal balance.” Id. As to the Examiner’s interpretation of the claim, Appellant asserts that it is in error because “[w]hile any product production would be non-existent in Dee if the liquefier 2 w[]ere turned off, this is not the case in the present invention and such a reading of claim 3 would be at odds with the plain meaning of the terminology used in the claim, the written description and knowledge in the art.” Id. During examination, claim terms are given their broadest reasonable interpretation consistent with the Specification. In re Acad. of Sci. Tech. Ctr., 367 F.3d 1359, 1369 (Fed. Cir. 2004). Appellant has not persuasively explained why the Examiner’s broad interpretation of “intermittent” operation of the refrigeration system is unreasonable. The Examiner’s interpretation, although broad, explains that the refrigeration system (Dee’s liquefier) and air separation plant can be turned on and off concurrently, thereby providing for intermittent operation of both the refrigeration system and the air separation plant. The Examiner’s interpretation also explains how liquid production of the air separation plant will be increased during the concurrent operation with the refrigeration system, relative to liquid production during the concurrent shutdown of the refrigeration system and air separation plant. Because the Examiner is contemplating concurrent shutdown of the refrigeration system (liquefier 2) and air separation unit 1 Appeal 2014-003490 Application 12/207,757 8 (Ans. 3), Appellant’s argument about air separation unit 1 rapidly heating up when operating without liquefier 2 does not adequately address the rejection as articulated by the Examiner (Br. 13). To the extent Appellant is arguing that “intermittent” operation of the refrigeration system contemplates that there be at least some refrigeration for the air separation plant even during “off” periods of the intermittent operation of the refrigeration system to provide at least some product production (Br. 13), the language of claim 3 is broader and we decline to import specific characteristics associated with “intermittent” operation of the refrigeration system in the Specification as a limitation of claim 3. See Superguide Corp. v. DirecTV Enterps., Inc., 358 F.3d 870, 875 (Fed. Cir. 2004) (“Though understanding the claim language may be aided by the explanations contained in the written description, it is important not to import into a claim limitations that are not a part of the claim. For example, a particular embodiment appearing in the written description may not be read into a claim where the claim language is broader than the embodiment.”). For the foregoing reasons, we are not persuaded that the Examiner erred in concluding that Dee and Tranier renders obvious the subject matter of claim 3, and we sustain the rejection of claim 3 as unpatentable under 35 U.S.C. § 103(a) over these references. Claim 7 Claim 7 depends indirectly from independent claim 1 and recites that: an oxygen-rich liquid stream is pumped to produce a pumped liquid oxygen stream; Appeal 2014-003490 Application 12/207,757 9 at least part of the pumped liquid oxygen stream is vaporized or pseudo vaporized within the main heat exchanger through indirect heat exchange with a compressed air stream; and the compressed air stream after the indirect heat exchange is introduced into a liquid expander and introduced into at least one of the higher pressure column and the lower pressure column, thereby to impart part of the refrigeration requirements of the at least first of the air separation plants. Br. 20 (Claims App.). The Examiner finds that Dee teaches liquid oxygen line 158 and compressed air stream 230 cooled through indirect heat exchange in main heat exchanger 110. Ans. 4. The Examiner also finds that Dee teaches compressed air stream 230 is introduced into liquid expander 236, 240 and two columns 114, 116. Id. The Examiner acknowledges that Dee fails to disclose that liquid oxygen line 158 is pumped and vaporized in main heat exchanger 110. Id. The Examiner finds that Tranier teaches liquid oxygen stream 21 is pumped 23 through main heat exchanger 7 and concludes that it would have been obvious to one of ordinary skill in the art to provide Dee’s system “with the use of pumped liquid oxygen for increased cooling power in the main heat exchanger, as taught by Tranier.” Id. Appellant argues that “even if [Dee and Tranier] were combined, they would not meet the terms of Applicants[’] invention as called for in claim 7 in that Tranier does not have a liquid expander that would impart refrigeration requirements to a plant.” Br. 14. Appellant also argues that “[t]here is no excess refrigeration generated in Dee that is either available for export or that would be required to balance warm end losses if the air stream were sufficiently compressed to heat a pumped liquid oxygen stream” because “liquefier 2 is [only] used to liquefy nitrogen produced by the plant and also to add refrigeration to the plant.” Id. at 15. These Appeal 2014-003490 Application 12/207,757 10 arguments are unpersuasive in that they each address the references individually, rather than the combination of Dee and Tranier. Appellant also argues that the Examiner’s stated reasoning lacks rational underpinnings in that “no[] increased cooling power is imparted by virtue of the pumped liquid oxygen” to the main heat exchanger because “the energy balance is a ‘wash.’” Br. 15. Appellant asserts that “[t]he energy of the compressed air is transferred to the warming pressurized oxygen and warm end heat exchange refrigeration losses are compensated for with the turbine 13.” Id. The Examiner responds that “it is clear that the use of the cooling power of the otherwise removed liquid oxygen stream (158) within the heat exchanger (110) would clearly increase the cooling capacity of the heat exchanger by using an already available source of cooling. Ans. 8. The Examiner further responds that “even a ‘wash’ is an improvement over the system of Dee which does not use the cooling power of the liquid oxygen available and therefore has an energy ‘loss’ with regard to the liquid oxygen stream.” Id. at 8–9. We agree with the Examiner’s response, and we are not persuaded that the Examiner’s articulated reasoning lacks rational underpinnings. For the foregoing reasons, we are not persuaded that the Examiner erred in concluding that Dee and Tranier renders obvious the subject matter of claim 7, and we sustain the rejection of claim 7 as unpatentable under 35 U.S.C. § 103(a) over these references. Claim 8 Claim 8 depends indirectly from independent claim 1 and recites that: the compressed air stream is a first compressed air stream; Appeal 2014-003490 Application 12/207,757 11 a second compressed air stream is partly cooled within the main heat exchanger and expanded to produce an exhaust stream; the exhaust stream is introduced into the higher pressure column to impart a further part of the refrigeration requirement of the at least first of the air separation plants; and the at least one of the nitrogen-rich liquid streams is introduced into the at least first of the air separation plants to increase liquid production within at least first of the air separation plants. Br. 21 (Claims App.). The Examiner finds that Dee teaches first air compressed stream 230 and second compressed air stream 208. Ans. 4. The Examiner acknowledges that Dee fails to teach that second compressed air stream 208 is only partly cooled, expanded, and introduced into the high pressure column. Id. The Examiner finds that Tranier teaches first compressed air stream 11 is cooled before being expanded and introduced into a column and second compressed air stream 9 is partially cooled in the heat exchanger, expanded 13, and introduced into high pressure column 15. Id. Appellant asserts that “the use of a turboexpander to impart refrigeration in Dee would not be obvious in the first instance in that refrigeration is imparted through LNG which would be available at a terminal in abundance for such purposes.” Br. 16. Appellant also asserts that “not only is there no need for an expander to produce refrigeration, there is also no need for any liquid nitrogen introduction to the high pressure column.” Id. The Examiner responds that Appellant “fails to address the inherent benefits of the combination in increased efficiency” by “economizing the otherwise withdrawn liquid oxygen stream.” Ans. 9. Although the Examiner’s response reiterates the reasoning for pumping Appeal 2014-003490 Application 12/207,757 12 liquid oxygen line 158 for vaporization in main heat exchanger 110, we are not persuaded that the Examiner has articulated adequate reasoning having a rational underpinning to explain specifically why one of ordinary skill in the art would have been led to partly cool and expand second compressed air stream 208 before introduction into the high pressure column. For the foregoing reasons, we are persuaded that the Examiner erred in concluding that Dee and Tranier render obvious the subject matter of claim 8, and we do not sustain the rejection of claim 8 as unpatentable under 35 U.S.C. § 103(a) over these references. Rejection II Claim 5 depends indirectly from independent claim 1 and recites that “the nitrogen-rich vapor stream is liquefied in the refrigeration system by compressing and cooling a portion of the nitrogen-rich vapor contained within the nitrogen-rich vapor stream and refrigeration for the cooling is generated at least in part by expanding another portion of the nitrogen-rich vapor within a turbo expander.” Br. 20 (Claims App.). The Examiner finds that Voit teaches that it is old and well-known in the art to liquefy a gaseous nitrogen stream originating from the top of a low pressure column (504, 1) which has been fully warmed in a main heat exchanger (502) in an air separation unit (500) by: compressing (4, 6, 8, 10) and cooling (12a) a portion of the gaseous nitrogen (19) and providing refrigeration in part by expanding (102) another portion (101, 103) of the nitrogen vapor in a turbo expander. Final Act. 2 (incorporating by reference Non-Final Act.); Non-Final Act. 5. The Examiner concludes that it would have been obvious to one of ordinary skill in the art to provide Dee’s method, as modified by Tranier, with a nitrogen liquefaction process as taught by Voit “in order to allow the Appeal 2014-003490 Application 12/207,757 13 construction of air separation facilities independently of LNG facilities.” Non-Final Act. 5; Ans. 5. Appellant acknowledges that “nitrogen liquefiers exist that use compression and expansion cycles as shown in Voit,” but assert that it would not be obvious to modify Dee to do so. Br. 17–18. Appellant explains that “if the liquefier of Voit were used to replace the LNG liquefier 2 of Dee[,] there would be . . . no reason to add a unit 3 thereto when a greater nitrogen production were desired” as taught by Dee. Id. at 18. The Examiner responds that Appellant’s argument does not persuasively explain “why simply changing the mechanism that provides liquefaction power from LNG (as taught by Dee) to a well-known compression-expansion cycle (as taught by Voit) would decrease the demand for liquid nitrogen in the system.” Ans. 9–10. The Examiner “maintains that the usefulness of top of the column nitrogen gas as a feed to the modified liquefying structure to generate a larger amount of liquid nitrogen would remain unaltered.” Id. at 10. We agree with the Examiner’s response. Absent a persuasive explanation of why changing the liquefaction power mechanism from LNG to a compression-expansion cycle would decrease the demand for liquid nitrogen in the system, we are not persuaded that the Examiner’s articulated reasoning lacks rational underpinnings. For the foregoing reasons, we are not persuaded that the Examiner erred in concluding that Dee, Tranier, and Voit renders obvious the subject matter of claim 5, and we sustain the rejection of claim 5 as unpatentable under 35 U.S.C. § 103(a) over these references. Appeal 2014-003490 Application 12/207,757 14 DECISION The Examiner’s decision to reject claims 1–4, 6, and 7 under 35 U.S.C. § 103(a) as unpatentable over Dee and Tranier is affirmed. The Examiner’s decision to reject claim 8 under 35 U.S.C. § 103(a) as unpatentable over Dee and Tranier is reversed. The Examiner’s decision to reject claim 5 under 35 U.S.C. § 103(a) as unpatentable over Dee, Tranier, and Voit is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1)(iv). AFFIRMED-IN-PART Copy with citationCopy as parenthetical citation