Ex Parte Finch et alDownload PDFBoard of Patent Appeals and InterferencesFeb 4, 201111480739 (B.P.A.I. Feb. 4, 2011) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 11/480,739 07/03/2006 William C. Finch A01759 2133 21898 7590 02/04/2011 ROHM AND HAAS COMPANY PATENT DEPARTMENT 100 INDEPENDENCE MALL WEST PHILADELPHIA, PA 19106-2399 EXAMINER TISCHLER, FRANCES ART UNIT PAPER NUMBER 1765 MAIL DATE DELIVERY MODE 02/04/2011 PAPER Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE __________ BEFORE THE BOARD OF PATENT APPEALS AND INTERFERENCES __________ Ex parte WILLIAM C. FINCH and XUN TANG __________ Appeal 2010-009754 Application 11/480,739 Technology Center 1700 __________ Before ERIC GRIMES, LORA M. GREEN, and JEFFREY N. FREDMAN, Administrative Patent Judges. FREDMAN, Administrative Patent Judge. DECISION ON APPEAL1 This is an appeal under 35 U.S.C. § 134 involving claims to a curable aqueous binder composition. The Examiner rejected the claims as obvious. We have jurisdiction under 35 U.S.C. § 6(b). We affirm-in-part. 1 The two-month time period for filing an appeal or commencing a civil action, as recited in 37 C.F.R. § 1.304, or for filing a request for rehearing, as recited in 37 C.F.R. § 41.52, begins to run from the “MAIL DATE” (paper delivery mode) or the “NOTIFICATION DATE” (electronic delivery mode) shown on the PTOL-90A cover letter attached to this decision. Appeal 2010-009754 Application 11/480,739 2 Statement of the Case The Specification teaches that the “invention relates to low cost curable aqueous binder compositions having low binder cure energy requirements, to methods of use thereof as binders for fibrous substrates and composites, and to the products produced by those methods” (Spec. 1 ¶ 0002). The Claims Claims 1-8 and 11-13 are on appeal. Claims 1 and 6 have been separately argued. The remaining claims have not been argued separately and therefore they stand or fall together with claim 1. 37 C.F.R. § 41.37(c)(1)(vii). Claims 1 and 6 are representative and read as follows: 1. A curable composition comprising: (i) one or more polymeric polyacid comprising at least two carboxylic acid groups, anhydride groups, or salts thereof; (ii) optionally, one or more polyol comprising at least two hydroxyl groups; and (iii) one or more reactive β-hydroxyamide group containing polyol of the following formula (I),which is the reaction product of a lactone or other cyclic ester and an alkanolamine: in which formula, R and R" independently represent H, or any monovalent C1 to C18 linear or branched alkyl radical, which radical may comprise one or two aryl or cycloalkyl group, one or more hydroxyl, amine, thiol, amide, carboxyl or alkenyl group, or Appeal 2010-009754 Application 11/480,739 3 combinations thereof; R’ represents either a covalent bond or a divalent C1 to C5 alkylene radical where the alkylene radical may bear alkyl group substituents; y is the integer 1 or 2; x is 0 or 1, such that (x + y) =2; wherein the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof to the number of equivalents of said hydroxyl groups is from 1/0.01 to 1/3. 6. A composition as claimed in claim 1, further comprising one or more reactive waterproofing agent. The issue2 The Examiner rejected claims 1-8 and 11-13 under 35 U.S.C. § 103(a) as obvious over Arkens3 and Stanssens4 (Ans. 3-7). The Examiner finds that Arkens teaches a curable composition suitable for use as a binder comprising (i) polymeric polyacid with at least two carboxylic acid groups, anhydride groups or salts thereof, such as polyacrylic acid, with a molecular weight of less than about 1,000 or with a molecular weight of from 300 - 10,000,000; (ii) polyol with at least two hydroxyl groups, including ethylene glycol, glycerol or alkanolamine; (iii) reactive beta-hydroxyamide group containing polyol. (Ans. 3). The Examiner finds that the “difference between the prior art and the present invention is that the present invention claims a beta- 2 The propriety of the Examiner’s restriction requirement and subsequent rejoinder is not an appealable issue but, rather is petitionable to the technology center director. See Manual of Patent Examining Procedure § 1002.02(c)(2) (8th ed., rev. 8, July 2010). 3 Arkens et al., US 5,661,213, issued Aug. 26, 1997. 4 Stanssens et al., US 6,706,853 B1, issued Mar. 16, 2004. Appeal 2010-009754 Application 11/480,739 4 hydroxyamide (formula (I) in the claim) which is made from the reaction product of a lactone or other cyclic ester and an alkanolamine” (Ans. 4). The Examiner finds that Stanssens teaches “a curable composition suitable for use as a binder comprising the reaction of an oxygen-containing cyclic compound, such as a lactone, with an alkanolamine, to form a beta- hydroxyamide” (Ans. 5). The Examiner finds it obvious to “have used Stanssens’ beta- hydroxyamide of figure 5 which is made from a lactone or other cyclic ester and an alkanolamine in lieu of Arkens’ beta-hydroxyamide . . . since both disclose to use a beta-hydroxyamide for the same purpose of reacting it with a polymeric polyacid” (Ans. 6). Appellants contend that “Arkens fails to disclose any β-hydroxyalkyl amide that reads on the instantly recited compounds. In the cited portion of Arkens relating to Arkens’ formula (I), the parameter A in Arkens does not include a hydroxyalkyl group” (App. Br. 5). Appellants contend that “Stannsens [sic Stanssens] fails to disclose any polymer or polymeric polyacid in combination with the Stannsens binder” (App. Br. 5). Appellants also contend that “the suggested combination of Arkens with Stannsens would require a substantial reconstruction and redesign of the combination to avoid the viscosity buildup issues disclosed in Stannsens” (App. Br. 6). Appellants contend that “in the instant specification, ample data confirms the unexpectedly superior curing rate of the instantly recited curable aqueous composition in comparison to a mix of TEA and polyacrylic acid (pAA) which represents the closest art of Arkens” (App. Br. 7). Appeal 2010-009754 Application 11/480,739 5 Appellants contend that “the evidence on the record shows an unexpected improvement over Arkens using two different reactive β-hydroxyamide group containing polyols and four different polyacids over a wide range of polyacid to polyol ratios” (App. Br. 8). Appellants contend that “nothing in Arkens reads on any reactive waterproofing agent. The rejection utterly fails to point to any reason for rejecting instant claim 6” (App. Br. 9). The issues with respect to this rejection are: (i) Does the evidence of record support the Examiner’s conclusion that the combination of Arkens and Stanssens renders claims 1 and 6 obvious? (ii) and, if so, have Appellants presented evidence of unexpected results that outweighs the evidence supporting a conclusion of obviousness? Findings of Fact 1. Arkens teaches “a formaldehyde-free curable aqueous composition and the use thereof as a binder for heat-resistant nonwovens” (Arkens, col. 2. l. 66 to col. 3, l. 1) 2. Arkens teaches that “composition contains (a) a polyacid containing at least two carboxylic acid groups, anhydride groups, or salts thereof; (b) a polyol containing at least two hydroxyl groups” (Arkens, col. 3, ll. 1-4). 3. Arkens teaches that the composition also contains “(c) a phosphorous-containing accelerator, wherein the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof Appeal 2010-009754 Application 11/480,739 6 to the number of equivalents of said hydroxyl groups is from about 1/0.01 to about 1/3” (Arkens, col. 3, ll. 4-8). 4. Arkens teaches that the composition “preferably includes a highly reactive polyol such as, for example, a β-hydroxyalkylamide of the formula wherein A is a bond, hydrogen or a monovalent or polyvalent organic radical” (Arkens, col. 7, ll. 31-38). 5. Table 3.1 of Arkens is reproduced below: “The test results for Samples 1-5 and Comparatives A-B . . . are presented in Table 3.1” (Arkens, col. 10, ll. 34-37). 6. Stanssens teaches “a compound or salts thereof suitable for use as a binder for mineral fibres, i.e. man made vitreous fibres (MMVF), for example glass slag or stone wool” (Stanssens, col. 1, ll. 5-7). Appeal 2010-009754 Application 11/480,739 7 7. Figures 4 and 5 of Stanssens are reproduced below: “FIGS. 4 and 5 show respectively the reaction between dimethyl adipate and caprolactone with diethanolamine in order to provide compounds” (Stanssens, col. 5, ll. 12-14). 8. The Examiner finds that Stanssens teaches that a “hydroxyamide is reacted with a polyacid acid with at least two carboxyl groups, such as acrylate monomers, with a molecular weight of less than 1000” (Ans. 5). 9. The Examiner finds that the β-hydroxyamide of Figure 4 is a β- hydroxyalkylamide of the formula shown in Arkens and finds that the hydroxyamides of Figure 4 and 5 of Stanssens “are functionally equivalent” (Ans. 5). Appeal 2010-009754 Application 11/480,739 8 10. Table 2 of the Specification on page 28 is reproduced below: Table 2 shows that “all formulations comprising reactive β-hydroxyamide group containing polyols show higher wet tensile strength than the control and the tensile strength develops faster” (Spec. 26 ¶ 0099) Principles of Law “The combination of familiar elements according to known methods is likely to be obvious when it does no more than yield predictable results.” KSR Int’l Co. v. Teleflex Inc., 550 U.S. 398, 416 (2007). “If a person of ordinary skill can implement a predictable variation, § 103 likely bars its patentability.” Id. at 417. Moreover, an “[e]xpress suggestion to substitute one equivalent for another need not be present to render such substitution obvious.” In re Fout, 675 F.2d 297, 301 (CCPA 1982). As noted by the Court in KSR, “[a] person of ordinary skill is also a person of ordinary creativity, not an automaton.” 550 U.S. at 421. Appeal 2010-009754 Application 11/480,739 9 The fact that an invention provides results which would not have been expected by those skilled in the art is strong evidence in rebuttal of an assertion that the invention would have been obvious. However, the burden of showing unexpected results rests on he who asserts them. Thus it is not enough to show that results are obtained which differ from those obtained in the prior art: that difference must be shown to be an unexpected difference. In re Klosak, 455 F.2d 1077, 1080 (CCPA 1972). Analysis Claim 1 Arkens teaches a curable composition which comprises “(a) a polyacid containing at least two carboxylic acid groups, anhydride groups, or salts thereof; (b) a polyol containing at least two hydroxyl groups” (Arkens, col. 3, ll. 1-4; FF 1-2). Arkens further teaches that the curable composition ““preferably includes a highly reactive polyol such as, for example, a β-hydroxyalkylamide of the formula wherein A is a bond, hydrogen or a monovalent or polyvalent organic radical” (Arkens, col. 7, ll. 31-38; FF 4). Arkens also teaches that the composition contains an accelerator where “the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof to the number of equivalents of said hydroxyl groups is from about 1/0.01 to about 1/3” (Arkens, col. 3, ll. 4-8; FF 3). Appeal 2010-009754 Application 11/480,739 10 Arkens does not teach a β-hydroxyalkylamide of formula I of the instant claim 1 (see Ans. 5). Stanssens teaches a curable binder where polyols with two hydroxyl groups reacted to form β-hydroxyalkylamides (FF 6-9). In particular, Stanssens teaches one reaction in figure 4 which results in a β-hydroxyalkylamide which falls within Arkens’ formula and teaches a second reaction in figure 5 which results in a β-hydroxyalkylamide which falls within formula I of the instant claim 1. The Examiner reasonably finds that the hydroxyamides of Figure 4 and 5 of Stanssens “are functionally equivalent” since they are used for similar reactions to result in similar compositions for the same purpose (Ans. 5; FF 9). Applying the KSR standard of obviousness to the findings of fact, we conclude that the person of ordinary creativity would have predictably substituted the β-hydroxyalkylamide of figure 5 of Stanssens for the β- hydroxyalkylamide of Arkens, since these are shown by Stanssens to be predictably equivalent. “[W]hen the question is whether a patent claiming the combination of elements of prior art is obvious”, KSR directs that “a court must ask whether the improvement is more than the predictable use of prior art elements according to their established functions.” KSR, 550 U.S. at 417. Here, the β-hydroxyalkylamides are predictably used as suggested by Stanssens. Appellants contend that “Stannsens fails to disclose any polymer or polymeric polyacid in combination with the Stannsens binder” (App. Br. 5). Appellants also contend that “the suggested combination of Arkens with Stannsens would require a substantial reconstruction and redesign of the Appeal 2010-009754 Application 11/480,739 11 combination to avoid the viscosity buildup issues disclosed in Stannsens” (App. Br. 6). We are not persuaded. Stanssens expressly teaches the equivalence of the β-hydroxyalkylamides and Arkens teaches the application of β- hydroxyalkylamide to the synthesis of the curable compositions as described above (FF 1-9). While we are aware that hindsight bias often plagues determinations of obviousness, Graham v. John Deere Co., 383 U.S. 1, 36 (1966), we are also mindful that the Supreme Court has clearly stated that the “combination of familiar elements according to known methods is likely to be obvious when it does no more than yield predictable results,” KSR, 550 U.S. at 401. Appellants have provided no evidence that substituting the β- hydroxyalkylamide of Stanssens into the reaction of Arkens would result in viscosity buildup. Appellants contend that Arkens is the closest prior art (App. Br. 6) and that “in the instant specification, ample data confirms the unexpectedly superior curing rate of the instantly recited curable aqueous composition in comparison to a mix of TEA and polyacrylic acid (pAA) which represents the closest art of Arkens” (App. Br. 7). Appellants contend that “the evidence on the record shows an unexpected improvement over Arkens using two different reactive β-hydroxyamide group containing polyols and four different polyacids over a wide range of polyacid to polyol ratios” (App. Br. 8). While we agree with Appellants that Arkens is reasonably identified as the closest prior art, we are not persuaded by the cited evidence that the claimed invention is unexpectedly superior to Arkens. Appellants point out Appeal 2010-009754 Application 11/480,739 12 that polyols within the scope of the claim “always provide at least 32% higher wet tensile strength than the closest art of Arkens” (App. Br. 7). However, simply because the wet tensile strength of a claimed composition different than Arkens shows some improvement does not mean that the result is unexpected. Appellants have the burden of showing that the claimed invention imparts not just any improvement, but an unexpected improvement. In re Klosak, 455 F.2d 1077, 1080 (CCPA 1972). Appellants do not provide declaration evidence, a statistical analysis or other discussion to distinguish which results are truly “unexpected” and which simply differ slightly from the “expected” values due to random chance or other variables. We are not persuaded that this data demonstrates unexpected results. Additionally, even if there may be one or two β-hydroxyalkylamide compounds for which the data shows results which are superior, the data presented is not commensurate in scope with the claim, which specifically claims any compound of formula I, and is not limited to any particular β- hydroxyalkylamides. See In re Harris, 409 F.3d 1339, 1344 (Fed. Cir. 2005) (Unexpected results must also be “commensurate in scope with the degree of protection sought by the claimed subject matter.”) Claim 6 The Examiner finds that “[o]ne of ordinary skill in the art would know to choose a waterproofing agent among the various conventional treatment components, depending on the use of the composition” (Ans. 13). Appeal 2010-009754 Application 11/480,739 13 Appellants contend that “nothing in Arkens reads on any reactive waterproofing agent. The rejection utterly fails to point to any reason for rejecting instant claim 6” (App. Br. 9). We find that Appellants have the better position. The Examiner has not provided any evidence that a single additive compound in either Arkens or Stanssens is a waterproofing agent. The Examiner states that hydrophobizing agents are “believed to be waterproofing agents” (Ans. 13). However, no evidence is presented to support this belief. Further, the hydroxyamide cannot serve as the composition and the additive. See Becton, Dickinson and Co. v. Tyco Healthcare Group, LP, 616 F.3d 1249, 1254 (Fed. Cir. 2010) (Where a claim lists elements separately, “the clear implication of the claim language” is that those elements are “distinct component[s]” of the patented invention). Conclusion of Law The evidence of record supports the Examiner’s conclusion that the combination of Arkens and Stanssens renders claim 1 obvious. The evidence of record does not support the Examiner’s conclusion that the combination of Arkens and Stanssens renders claim 6 obvious. Appellants have not presented evidence of unexpected results that outweighs the evidence supporting a conclusion of obviousness. SUMMARY In summary, we affirm the rejection of claim 1 under 35 U.S.C. § 103(a) as obvious over Arkens and Stanssens. Pursuant to 37 C.F.R. § 41.37(c)(1)(vii)(2006), we also affirm the rejection of claims 2-5, 7, 8, and 11-13 as these claims were not argued separately. Appeal 2010-009754 Application 11/480,739 14 We reverse the rejection of claim 6 under 35 U.S.C. § 103(a) as obvious over Arkens and Stanssens. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(1)(iv)(2006). AFFIRMED-IN-PART alw ROHM AND HAAS COMPANY PATENT DEPARTMENT 100 INDEPENDENCE MALL WEST PHILADELPHIA, PA 19106-2399 Copy with citationCopy as parenthetical citation