Ex Parte Feng et alDownload PDFPatent Trial and Appeal BoardMar 27, 201813666321 (P.T.A.B. Mar. 27, 2018) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 13/666,321 1110112012 22928 7590 03/29/2018 CORNING INCORPORATED SP-TI-3-1 CORNING, NY 14831 FIRST NAMED INVENTOR Jiangwei Feng UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. SPll-302 5520 EXAMINER SZEWCZYK, CYNTHIA ART UNIT PAPER NUMBER 1741 NOTIFICATION DATE DELIVERY MODE 03/29/2018 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address( es): usdocket@corning.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte JIANGWEI FENG, JANET MITCHELL, and LJERKA UKRAINCZYK Appeal2017-007783 Application 13/666,321 1 Technology Center 1700 Before ROMULO H. DELMENDO, KAREN M. HASTINGS, and JAMES C. HOUSEL, Administrative Patent Judges. PERCURIAM. DECISION ON APPEAL Appellant seeks our review under 35 U.S.C. § 134(a) of the Examiner's decision rejecting claims 1--4, 7-10, and 12-17. We have jurisdiction over the appeal under 35 U.S.C. § 6(b). We AFFIRM. 1 Appellant is the Applicant, Coming Incorporated, which, according to the Appeal Brief, is the real party in interest (Appeal Br. 4). Appeal2017-007783 Application 13/666,321 Independent claim 1 is illustrative of the subject matter on appeal (emphasis added): 1. A method for reconditioning a surface-coated glass- forming mold comprising: providing the glass-forming mold, wherein the glass- forming mold comprises a titanium-aluminum-nitride- containing glass release layer having a surface oxidation layer, wherein the surface oxidation layer (i) comprises oxygen, aluminum, silicon and alkali metal and (ii) is a nitrogen- depleted layer; and contacting the swface oxidation layer with an aqueous mineral acid solution comprising fluoride and phosphate ions to recondition the glass release layer, wherein after the contact with the aqueous mineral acid solution, the glass release layer has a surface layer comprising alkali metal, silicon, aluminum and oxygen that is substantially free of nitrogen depletion. The Examiner maintains the following rejections: 2 (a) claims 1--4, 7-10, 12, 16, and 17 under 35 U.S.C. § 103(a) as being unpatentable over Everson et al. (US 3,015,589, issued Jan. 2, 1962) ("Everson") in view of Mazzanti (US 2004/0021239 Al, published Feb. 5, 2004) and Bando et al. (JP 2001-335340 A, published Dec. 4, 2001) ("Bando"); and (b) claims 13-15 under 35 U.S.C. § 103(a) as being unpatentable over Everson in view of Mazzanti and Bando and further in view of Muramoto et al. (US 6,436,859 Bl, issued Aug. 20, 2002) ("Muramoto"). 2 We refer to the Specification, filed Nov. 1, 2012 ("Spec."); Final Office Action, notice emailed July 6, 2015 ("Final Act."), Appeal Brief, filed Feb. 5, 2016 ("Appeal Br."); and the Examiner's Answer, notice emailed Sept. 21, 2016 ("Ans."). 2 Appeal2017-007783 Application 13/666,321 ANALYSIS The § 103 (a) rejection over Everson, Mazzanti, and Banda Claims 1--4, 7-10, 12, 16, and 17 are rejected under 35 U.S.C. § 103(a) as being unpatentable over Everson in view of Mazzanti and Bando. Appellant sets forth arguments for claim 1 as a first group and arguments for claims 7, 8, and 17 as a second group (Appeal Br. 7-13). We address claims separately from representative claim 1 only to the extent that they have been argued separately pursuant to 37 C.F.R. § 41.37(c)(l)(iv). Claims 1--4, 9, 10, 12, and 16 Appellant's principal argument3 regarding claim 1 is that one of ordinary skill in the art would have lacked a reason or a reasonable expectation of success for using an acid solution of fluoride and phosphate ions to recondition a mold comprising a titanium-aluminum-nitride- containing glass release layer, as recited in claim 1 (Appeal Br. 9). Specifically, Appellant contends Everson discloses the use of individual acids to descale and de-invest metal molds, not a mixture of acids, while Mazzanti discloses an acid mixture to regenerate the pores of a resin mold, which might produce surface oxidation layers having different chemistries than surface oxidation layers formed on the surface of Everson's metal surfaces (id. at 8, 10). Appellant further argues that none of Everson, Mazzanti, and Bando disclose or suggest reconditioning a titanium- aluminum-nitride-containing glass release layer, which would have a 3 Appellant discusses their invention at page 7 of the Appeal Brief, including an asserted need for the invention. This appears to be an overview of the invention and Appellant's view of its place in industry. Appellant does not make any specific assertion of long felt need as a secondary consideration as a rebuttal to the Examiner's obviousness rejection. 3 Appeal2017-007783 Application 13/666,321 different surface oxidation layer chemistry than the surface oxidation layers of Everson and Mazzanti (id. at 10-11). Appellant also argues the "obvious to try" rationale is inapplicable because the applied references do not provide any direction about what acids to use for reconditioning a mold having a titanium-aluminum-nitride-containing glass release layer and do not indicate that using both fluoride and phosphate ions is critical (id. at 11- 12). Appellant's arguments are unpersuasive. The Examiner finds Everson discloses a method of reconditioning metal molds for shaping glass articles (Final Act. 2). As stated above, Appellant states that Everson treats metal molds (Appeal Br. 8) and does not argue this finding. The Examiner further finds Everson's process includes contacting the mold surface with an aqueous mineral acid solution comprising fluoride ions, chloride ions, or phosphate ions but does not disclose using a mixture of phosphate ions and fluoride ions in the solution (Final Act. 2). Everson discloses a descaling process in which metal is immersed in a molten salt bath, quenched in water, immersed in a dilute inorganic acid, rinsed, and immersed in another acid solution (Everson 3:57-72). Everson discloses the dilute inorganic acid can be "hydrochloric acid, sulfuric acid, phosphoric acid, nitric acid, or hydrofluoric acid, with or without corrosion inhibitor" (id. 3:62---65). Thus, Everson's disclosure supports the Examiner's findings regarding its use of acid for descaling. In response to Appellant's arguments, the Examiner reiterates that Everson discloses the use of hydrofluoric ions and phosphoric ions at column 3, lines 61-64 and the Examiner concludes it would have been obvious to combine hydrofluoric acid and phosphoric acid, which Everson 4 Appeal2017-007783 Application 13/666,321 uses for the same purpose, to make a third mixture that is used for the very same purpose (Ans. 3). Such a rationale has been previously expressed: "[i]t is prima facie obvious to combine two compositions each of which is taught by the prior art to be useful for the same purpose, in order to form a third composition which is to be used for the very same purpose." In re Kerkhoven, 626 F.2d 846, 850 (CCPA 1980) (citations omitted). Therefore, the Examiner has set forth findings supported by Everson's disclosure and a rationale supporting a conclusion that it would have been obvious to combine the acids disclosed by Everson for descaling a metal surface to form a mixture of the acids for the same purpose, thus meeting the "contacting" step of claim l. Appellant has not filed a Reply Brief or otherwise responded to the Examiner's findings and rationale in the Examiner's Answer. The Examiner also finds that Mazzanti discloses the use of acid mixtures for descaling molds (Ans. 2-3). Mazzanti appears to be merely cumulative in view of the Examiner's findings and conclusion regarding Everson. The Examiner finds Everson does not disclose a mold having a titanium-aluminum-nitride-containing glass release layer (Final Act. 3). The Examiner finds Bando discloses such a mold and concludes it would have been obvious to modify the process of Everson to include a mold having a titanium-aluminum-nitride-containing glass release layer because Bando teaches that such a release layer has excellent high temperature durability and mold release performance (id.). Bando teaches a titanium-aluminum- nitride (TiAlN) film for a mold and that the film "has excellent high temperature durability and mold-releasing performance" (Bando abstract). Thus, the disclosure of Bando supports the Examiner's findings and 5 Appeal2017-007783 Application 13/666,321 rationale to support a conclusion of obviousness. To the extent Everson does not explicitly disclose its process is used to treat titanium-aluminum-nitride-containing glass release layers, Everson discloses its process is "applicable to a wide variety of both ferrous and non- ferrous metals and alloys, including such metals as titanium" (Everson 3 :44-- 52). Thus, Everson's process can be used for a wide range of metals and alloys. Based upon such a disclosure, one of ordinary skill in the art would have had a reasonable expectation of success that Everson's process would be useful for reconditioning a titanium-aluminum-nitride-containing glass release layer, such as the film disclosed by Bando. In comparison, Appellant argues that a surface oxidation layer for the metal surface of Everson has a different chemistry than a surface oxidation layer for a titanium-aluminum- nitride-containing glass release layer and a person of ordinary skill in the art would have had no reason or reasonable expectation of success for using Everson's process to recondition a titanium-aluminum-nitride-containing glass release layer (Appeal Br. 9-11). However, Appellant does not cite any evidence or persuasive technical reasoning that the process of Everson would not be effective for reconditioning the titanium-aluminum-nitride film of Bando. Therefore, a preponderance of the evidence in the record supports the Examiner's conclusion that it would have been obvious to modify Everson in view of Bando to use a mixture of acid ions to recondition a titanium-aluminum-nitride-containing glass release layer, as recited in claim 1. Moreover, with regard to Appellant's arguments that none of the applied references disclose reconditioning a titanium-aluminum-nitride- containing glass release layer with an aqueous mineral acid solution 6 Appeal2017-007783 Application 13/666,321 comprising fluoride and phosphate ions, as recited in claim 1, the test for obviousness is not that the claimed invention be expressly suggested in any one or all of the references but what the combined teachings of the references would have suggested to one of ordinary skill in the art. In re Keller, 642 F.2d 413, 425 (CCPA 1981). Here, Everson demonstrates it was known to use acidic solutions containing phosphate or fluoride ions to recondition metal surfaces, Bando discloses the benefits of using a titanium- aluminum-nitride film for a mold, and the Examiner has set forth rationales for combining the acids disclosed by Everson and for modifying Everson's process to use Bando' s film. In addition, Appellant argues that the acid of Everson would not contact a surface oxidation layer, as recited in claim 1, because the molten salt bath of Everson would have already removed any surface oxidation layer (Appeal Br. 8-10). In support of this, Appellant asserts Everson's examples XIII, XIV, and XV demonstrate it is optional to apply acid after using the molten salt bath (id. at 9-10). Appellant's arguments are unpersuasive. The Examiner correctly finds Everson teaches that salt baths alone have not been adequate to clean mold surfaces and, based upon this, one of ordinary skill in the art would have understood that the acid used by Everson treats oxidation remaining after the salt treatment (Ans. 2, citing Everson 1 :54--58). Indeed, Everson discloses the particular procedure used to treat a surface depends upon the type of metal treated and the material adhering to it (Everson 4:3-7). Everson further teaches "it is frequently desirable, after the fused salt treatment, to contact the surface of the metal being treated with an inorganic acid at an elevated temperature" (id. 4: 18-21 ). Moreover, although 7 Appeal2017-007783 Application 13/666,321 examples XIII, XIV, and XV do not include an acid treatment, examples XVI and XVII do (id. 3:70-75, 4:1-25). Therefore, Everson's disclosure demonstrates treatments including the application of acid after a salt bath are effective, and even advantageous, for treating the surfaces of molds. For these reasons and those set forth in the Examiner's Answer, the Appellant's arguments do not identify a reversible error in the Examiner's rejection of claim 1. Appellant states claims 2--4, 9, 10, 12, and 16 stand or fall with claim 1 (Appeal Br. 8). Claims 7, 8, and 17 Claim 7 depends from claim 1 and further recites "wherein the aqueous mineral acid solution comprises an acid mixture of HF, HCl, and H3P04." Claims 8 and 17 depend from claim 7. For the rejection of claim 7, Appellant cites the arguments for claim 1 and asserts "[ t ]here is even less of a reason to modify the single acid of Everson to include three components" (Appeal Br. 13). However, Everson discloses that hydrochloric acid, phosphoric acid, or hydrofluoric acid can be used for its acid immersion step (Everson 3: 62---64 ). As discussed above, the Examiner concludes it would have been obvious to combine these acids, which are used for the same purpose of reconditioning metal surfaces, to form a mixture used for the same purpose (Ans. 3). Therefore, the Examiner has set forth findings supported by Everson's disclosure and a rationale supporting a conclusion that it would have been obvious to combine the claimed acids. As a result, Appellant's arguments do not identify a reversible error in the Examiner's rejection. 8 Appeal2017-007783 Application 13/666,321 For the reasons discussed above and those set forth in the Examiner's Answer, we sustain the Examiner's§ 103(a) rejection of claims 1--4, 7-10, 12, 16, and 17 over Everson, Mazzanti, and Bando. The § 103 (a) rejection over Everson, Mazzanti, Banda, and Muramoto Claims 13-15 are rejected under 35 U.S.C. § 103(a) as being unpatentable over Everson in view of Mazzanti and Bando and further in view of Muramoto. Appellant states claims 13-15 stand or fall with claim 1 (Appeal Br. 8). Therefore, for the reasons discussed above and those set forth in the Examiner's Answer, we sustain the Examiner's§ 103(a) rejection of claims 13-15 over Everson, Mazzanti, Bando, and Muramoto. DECISION The Examiner's rejection of claims 1--4, 7-10, and 12-17 is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED 9 Copy with citationCopy as parenthetical citation