Ex Parte DavisDownload PDFPatent Trial and Appeal BoardMay 18, 201612617250 (P.T.A.B. May. 18, 2016) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 12/617,250 11112/2009 32425 7590 05/20/2016 NORTON ROSE FULBRIGHT US LLP 98 SAN JACINTO BOULEVARD SUITE 1100 AUSTIN, TX 78701-4255 FIRST NAMED INVENTOR Thomas A. Davis UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. UTSE:l34US/10911612 4221 EXAMINER FRIDAY, STEVEN A ART UNIT PAPER NUMBER 1756 NOTIFICATION DATE DELIVERY MODE 05/20/2016 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address( es): aoipdocket@nortonrosefulbright.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte THOMAS A. DA VIS 1 Appeal2014-009203 Application 12/617,250 Technology Center 1700 Before CHUNG K. PAK, JEFFREY T. SMITH, and WESLEY B. DERRICK, Administrative Patent Judges. DERRICK, Administrative Patent Judge. DECISION ON APPEAL This is a decision on an appeal under 35 U.S.C. § 134(a) from the Examiner's maintained final rejection of claims 1, 2, and 4--18. We have jurisdiction pursuant to 35 U.S.C. § 6(b ). We AFFIRM. CLAIMED SUBJECT MATTER Solid ion-removal materials such as ion exchange resin are commonly used for removal of dissolved ions from water. Spec. i-f 3. Salt solutions are 1 According to Appellant, the Real Party in Interest is The Board of Regents of the University of Texas System. Br. 2. Appeal2014-009203 Application 12/617,250 often used to regenerate ion exchange resins that have become saturated with valuable or objectionable ions. Spec. i-f 4. After being used to regenerate the ion exchange resins, the spent regenerant salt solution also contains the valuable or objectionable ions. Spec. ,-r 4. Appellant's claimed invention relates to a method for recovering ions from a spent regenerant solution using electrodialysis. Spec., Abstract. Claim I-the sole independent claim-is illustrative: 1. A process for recovery and reuse of ions from a spent regenerant, comprising the steps of: a) providing a solution of spent regenerant from regeneration of a first solid ion removal material with a monovalent salt, wherein the spent regenerant comprises a mixture of monovalent ions and multivalent ions; and b) treating the spent regenerant with an electrodialysis system having a selective membrane, wherein the selective membrane has higher permeability for the monovalent ions than for the multivalent ions; thereby separating the spent regenerant into at least a first stream and a second stream, the first stream enriched in the monovalent ions and the second stream enriched in the multivalent ions; wherein the electrodialysis system has a plurality of repeating cells, each cell comprising a single type of selective membrane and further comprising a non-selective membrane. Appeal Brief filed February 10, 2014 ("Br."), 17. 2 Appeal2014-009203 Application 12/617,250 REJECTIONS The Examiner maintains the following grounds of rejection under 35 U.S.C. § 103(a): Claims 1, 2, 4-7, and 9-14 stand rejected over Rawson et al. (US 7,132,052 B2, issued November 7, 2006) ("Rawson") and Davis (US 7,083,730 B2, issued August 1, 2006).2 Claims 6, 8, 15, and 16 stand rejected over Rawson, Davis, Tonelli et al. (US 6,258,278 B 1, issued July 10, 2001) ("Tonelli"), and Bourke et al. (US 2006/0011550 Al, published January 19, 2006) ("Bourke"). Claims 17 and 18 stand rejected over Rawson, Davis, Tonelli, Bourke, and Davis (US 2006/0060532 Al, published March 23, 2006) ("Davis II"). DISCUSSION Having reviewed the Examiner's decision in light of the arguments advanced by ii ..ppellant in the ii ..ppeal Brief, \Ve are of the opinion that Appellant has not identified reversible error in the Examiner's conclusion that claims 1, 2, and 4-18 are rendered obvious by the applied prior art. We add the following for emphasis. 3 2 While claim 3 is listed in the ground of rejection in both the body of the Final Office Action entered June 12, 2013 ("Final Act.") and the Examiner's Answer entered June 19, 2014 ("Ans."), the claim had been canceled earlier (See Amendment filed May 5, 2013). 3 We refer to the Final Office Action (entered June 12, 2013), the Appeal Brief (filed February 10, 2014), and the Answer (entered June 19, 2014). 3 Appeal2014-009203 Application 12/617,250 Rejection of Claims l, 2, 4--7, and 9-14 as obvious over Rawson and Davis Appellant argues claims 1, 2, 4--7, and 9-14 as a group on the basis of claim 1, to which we limit our discussion. Br. 9-15. Claim 1 is directed to a process for recovery of ions from a spent regenerant for their reuse that includes treating the spent regenerant with an electrodialysis system having a plurality of repeating cells, with each cell comprising a single type of selective membrane and a non-selective membrane. The Specification defines a "selective membrane" as "any membrane that has a restriction of permeation of macromolecules or ions across the membrane on the basis of molecular size, number of charges, or physical configuration, but excludes the selectivity that permeates all anions and no cations or the selectivity that permeates all cations and no anions." Spec. i-f 11. The Specification defines a "non-selective membrane" as a membrane that has essentially no selectivity of permeation on the basis of molecular size; number of charges; or physical configuration, and may include the selectivity that permeates all anions and no cations or the selectivity that permeates all cations and no anions, such as ordinary cation-exchange membranes or anion-exchange membranes. Spec. i-f 11. In other words, a selective membrane provides some restriction to permeation through the membrane on the basis of molecular size, number of charges, or physical configuration, but a membrane is not a selective membrane simply because it provides some restriction to permeation on the basis that species are positively charged (cations) or negatively charged (anions). The Examiner finds that Rawson discloses regeneration of a resin material that had been used to remove divalent cations (Ca2+ and Mg2+) from 4 Appeal2014-009203 Application 12/617,250 water, by washing the resin with a solution of concentrated NaCl, referred to as brine. Final Act. 2; Rawson col. 2, 11. 28-51. The Examiner finds that Rawson discloses that after this regeneration process, the solution that was used to wash the resin-the spent brine (spent regenerant}--contains monovalent ions (Na+ and Ci-) and divalent cations (Ca2+ and Mg2+) recovered from the resin. Final Act. 2; Rawson col. 2, 11. 44--51. The Examiner finds that Rawson discloses separating the monovalent ions from the divalent ions in the spent brine using a nanofiltration membrane, and further discloses that other devices can be used to perform this separation, including an electrodialysis device, which the Examiner finds to be "a well- known equivalent for performing the separation function." Final Act. 3; Rawson col. 2, 1. 57---col. 3, 1. 4. The Examiner acknowledges that Rawson does not disclose an electrodialysis system that includes a selective membrane having a higher permeability for monovalent ions than multivalent ions, and to remedy this deficiency in Rawson, the Examiner relies on Davis' disclosure of an electrodialysis system that includes repeating units or cells of ion exchange membranes. Final Act. 3; Davis col. 13, 11. 7-21; col. 14, 11. 62---63. Davis discloses that a preferred repeating cell arrangement includes an anion- exchange membrane, a cation-exchange membrane, a univalent anion- selective membrane, and a univalent cation-selective membrane. Davis col. 11, 11. 53-56; col. 13, 11. 7-16. Davis further discloses that electrodialysis systems having repeating units of an anion-exchange membrane and a univalent cation-selective membrane, or repeating units of a cation-exchange membrane and a univalent anion-selective membrane, were known in the art. 5 Appeal2014-009203 Application 12/617,250 Davis col. 14, 1. 63---col. 15, 1. 4, describing U.S. patents 3,933,610 and 5,376,250. The Examiner concludes in essence that it would have been obvious to one of ordinary skill in the art at the time of the invention to modify the process disclosed in Rawson to use an electrodialysis system as disclosed in Davis to separate monovalent ions from divalent ions in spent brine, and further determines that it would have been within the ambit of one of ordinary skill in the art to choose and arrange particular membranes in repeating cells of the electrodialysis system so as to separate monovalent ions from divalent ions in the spent brine (regenerant). Final Act. 4. Appellant argues that every embodiment of the electrodialysis system disclosed in Davis includes a repeating electrodialysis unit-which Appellant indicates is comparable to a cell as recited in claim I-that comprises two types of selective membranes, and contends that Davis does not teach or suggest elimination of one type of selective membrane from the electrodialysis unit (cell), as required by claim 1. Br. 11-13. The entirety of Davis' disclosures, however, must be evaluated for what they would have fairly suggested to one of ordinary skill in the art at the time of the invention. Merck & Co. v. Biocraft Labs., Inc., 874 F.2d 804, 807 (Fed. Cir. 1989) (quoting In re Lamberti, 545 F.2d 747, 750 (CCPA 197 6)("[T]he fact that a specific [embodiment] is taught to be preferred is not controlling, since all disclosures of the prior art, including unpreferred embodiments, must be considered."); In re Fracalossi, 681 F .2d 792, 794 n.1 (CCPA 1982) (A prior art reference's disclosure is not limited to its examples.); In re Boe, 355 F.2d 961, 965 (CCPA 1966) (All of the 6 Appeal2014-009203 Application 12/617,250 disclosures in a prior art reference "must be evaluated for what they fairly teach one of ordinary skill in the art."). As discussed above, Davis discloses that a preferred electrodialysis unit includes both a univalent anion-selective membrane and a univalent cation-selective membrane, as well as an anion-exchange membrane and a cation-exchange membrane. Davis col. 11, 11. 53-56; col. 13, 11. 7-16. In view of Davis' disclosure that this arrangement is preferred, and not required, one of ordinary skill in the art reasonably would have inferred that an electrodialysis unit could contain either type of univalent selective membrane, as recited in claim 1, and need not necessarily contain both types. KSR Int'! Co. v. Teleflex Inc., 550 U.S. 398, 418 (2007) (an obviousness analysis "need not seek out precise teachings directed to the specific subject matter of the challenged claim, for [an examiner] can take account of the inferences and creative steps that a person of ordinary skill in the art would employ.''); In re Preda, 401F.2d825, 826 (CCPA 1968) ("[I]t is proper to take into account not only specific teachings of the reference but also the inferences which one skilled in the art would reasonably be expected to draw therefrom.") Moreover, as also discussed above, Davis discloses that electrodialysis systems were known in the art that included repeating units of either an anion-exchange membrane and a univalent cation-selective membrane, or a cation-exchange membrane and a univalent anion-selective membrane, corresponding to a plurality of repeating cells comprising a single type of selective membrane-the univalent anion- or cation-selective membranes-and a non-selective membrane-the anion- or cation-exchange membranes-as recited in claim 1. Davis col. 14, 1. 63---col. 15, 1. 4. 7 Appeal2014-009203 Application 12/617,250 Accordingly, we agree with the Examiner that the combined disclosures of Rawson and Davis reasonably would have led one of ordinary skill in the art at the time of the invention, through no more than ordinary skill and creativity, to modify the process disclosed in Rawson for separating monovalent ions from divalent ions in spent brine by using an electrodialysis system as disclosed in Davis having a plurality of repeating cells, with each cell comprising a single type of selective membrane and a non-selective membrane, as recited in claim 1. Appellant's argument is therefore unpersuasive of reversible error. Appellant argues that Davis specifically, repeatedly, and exclusively discloses the use of pairs of selective membranes together, which "would tend to steer one of ordinary skill in the art away from using only one type of selective membrane." Br. 15. However, as discussed above, Davis discloses that a preferred repeating cell arrangement includes both a univalent anion- selective membrane and a univalent cation-selective membrane, and Davis thus does not disclose that this arrangement is a necessary feature of the invention. Davis col. 11, 11. 53-56; col. 13, 11. 7-16. Moreover, Davis does not criticize, discredit, or otherwise discourage utilizing only a single type of selective membrane in a repeating cell, and actually discloses that such an arrangement is conventional. Davis col. 14, 1. 63---col. 15, 1. 4. Therefore, we find that Davis does not teach away from a single type of selective membrane as recited in claim 1. In re Fulton, 391 F.3d 1195, 1201 (Fed. Cir. 2004); In re Gurley, 27 F.3d 551, 552-53 (Fed. Cir. 1994). Appellant further argues that electrodialysis is not a well-known equivalent of nanofiltration as the Examiner contends because the two separation techniques operate using different principles. Br. 9-10. 8 Appeal2014-009203 Application 12/617,250 However, Appellant does not provide any explanation or evidence establishing that both techniques could not be used to separate monovalent ions from divalent ions in a spent brine regenerant, regardless of their principles of operation, and this argument is therefore lacking in persuasive merit. Br. 9-15. Appellant further argues that Rawson's process includes steps that would be extraneous if electrodialysis were incorporated into the process. Br. 10. However, Appellant does not demonstrate that modification of Rawson's process as proposed by the Examiner to incorporate electrodialysis as disclosed in Davis would not result in a process that could separate monovalent ions from divalent ions in a spent brine regenerant, even if the supposedly extraneous steps were included in the modified process. Br. 9-15. Appellant's argument is therefore unpersuasive of reversible error. Appellant also argues that Rawson does not provide an enabling disclosure of an electrodialysis system. Br. 9. However, this argument is not persuasive because "a non-enabling reference may qualify as prior art for the purpose of determining obviousness under§ 103." Symbol Techs., Inc. v. Opticon, Inc., 935 F.2d 1569, 1578 (Fed. Cir. 1991). Moreover, Appellant's argument is unsupported by any evidence establishing that one of ordinary skill in the art would not have arrived at the subject matter recited in claim 1 without undue experimentation based on the disclosures of Rawson and Davis coupled with information known in the art. Br. 9-15; In re Antor Media Corp., 689 F.3d 1282, 1288 (Fed. Cir. 2012) (A prior art printed publication, like a prior art patent, "is presumptively enabling barring any showing to the contrary by a patent applicant or patentee."); In 9 Appeal2014-009203 Application 12/617,250 re Morsa, 713 F.3d 104, 110 (Fed. Cir. 2013) ("[A]n applicant must generally do more than state an unsupported belief that a reference is not enabling."); In re Wands, 858 F.2d 731, 737 (Fed. Cir. 1988) (explaining that undue experimentation is determined based on both the nature of the invention and the state of the art.) Appellant also argues that even if Rawson did teach electrodialysis, "the Office does not explain why one of ordinary skill in the art would have recognized the source of the problem, i.e., recycling spent regenerant from salt-regeneration of solid ion removal material such as ion exchange resins." Br. 15. However, as the Examiner points out (Ans. 5), Rawson explicitly recognizes the problem of recycling spent regenerant after regeneration of a resin material used for removal of divalent cations, and discloses that electrodialysis can be used as part of the solution to this problem (Rawson col. 1, 11. 28-51; col. 1, 1. 57---col. 2, 1. 4). Accordingly, we agree with the Examiner that "the present case is not one where a patentable invention lies in the discovery of the problem because, here, it clearly had been recognized by the prior art at the time the instant invention was made." Ans. 5. Appellant's argument therefore lacks persuasive merit. Under these circumstances, it cannot be said that Appellant has identified reversible error in the Examiner's determination that the preponderance of the evidence weighs in favor of obviousness of the subject matter of claims 1-7 and 9-14 within the meaning of 35 U.S.C. § 103(a). In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011). Therefore, we sustain the rejection of these claims under§ 103(a). 10 Appeal2014-009203 Application 12/617,250 Rejections of Claims 6, 8, 15, 16, 17, and 18 In addressing the separate rejections of claims 6, 8, 15, and 16 and of claims 17 and 18, Appellant relies on the arguments presented for claim 1. Br. 16. Because we are not persuaded of reversible error in the Examiner's obviousness rejection of claim 1, we are likewise not persuaded of reversible error in the Examiner's decision rejecting claims 6, 8, 15, 16, 17, and 18, and we therefore sustain these rejections. DECISION The Examiner's rejections of claims 1, 2, and 4--18 under 35 U.S.C. § 103(a) are AFFIRMED. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED 11 Copy with citationCopy as parenthetical citation