Ex Parte CombsDownload PDFBoard of Patent Appeals and InterferencesJul 23, 200911031733 (B.P.A.I. Jul. 23, 2009) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE BOARD OF PATENT APPEALS AND INTERFERENCES ____________ Ex parte GEORGE COMBS ____________ Appeal 2009-000079 Application 11/031,733 Technology Center 1700 ____________ Decided:1 July 23, 2009 ____________ Before CHUNG K. PAK, CATHERINE Q. TIMM, and ROMULO H. DELMENDO, Administrative Patent Judges. PAK, Administrative Patent Judge. DECISION ON APPEAL STATEMENT OF THE CASE 1 The two-month time period for filing an appeal or commencing a civil action, as recited in 37 C.F.R. § 1.304, begins to run from the Decided Date shown on this page of the decision. The time period does not run from the Mail Date (paper delivery) or Notification Date (electronic delivery). Appeal 2009-000079 Application 11/031,733 This is a decision on an appeal under 35 U.S.C. § 134 from the Examiner's final rejection of claims 32 through 41, all of the pending claims in the above-identified application. We have jurisdiction pursuant to 35 U.S.C. § 6. We AFFIRM. The subject matter on appeal is related to the claimed subject matter drawn to a double metal cyanide (“DMC”) catalyst considered in the earlier opinion entered July 22, 2008 by the previous merits panel on Appeal No. 2008-2788 (Application 10/703,928). The currently appealed subject matter is directed to using such double metal cyanide (“DMC”) catalyst in an admittedly known process for producing a polyol. See the preamble of Jepson claim 32 on appeal. Details of the appealed subject matter are recited in currently appealed claim 32 reproduced below: 32. In a process for the production of a polyol by polyaddition of alkylene oxides onto starter compounds containing active hydrogen atoms, the improvement comprising conducting the polyaddition in the presence of the double metal cyanide (DMC) catalyst comprising a non- hexanitrometallate containing double metal cyanide compound, one or more unsaturated tertiary alcohols and about 0 to about 80 wt.%, based on the amount of catalyst, of a functionalized polymer having a number average molecular weight greater than about 200. As evidence of unpatentability of the appealed subject matter, the Examiner proffered the following prior art: Clement US 6,429,342 Aug. 6, 2002 2 Appeal 2009-000079 Application 11/031,733 The Examiner rejected claims 32 through 41 under 35 U.S.C. § 102(b) as anticipated by the disclosure of Clement.2 Appellant traverses the Examiner’s rejection, arguing that the Examiner erred in finding that Clement teaches employing the claimed double metal cyanide (DMC) catalyst comprising a non-hexanitrometallate containing double metal cyanide compound (DMC compound) and one or more unsaturated tertiary alcohols in a conventional polymerization process for producing a polyol (App. Br. 4-9 and Reply Br. 3). ISSUE and CONCLUSION Has Appellant identified reversible error in the Examiner’s factual finding that Clement teaches employing a premixture of a DMC compound and MBE corresponding to the claimed catalyst in its polymerization process for preparing a polyol within the meaning of 35 U.S.C. § 102(b)? On this record, we answer this question in the negative. FINDINGS OF FACT 1. According to Appellant, (Spec. 5, ll. 4-10): Examples of [the claimed] double metal cyanide compounds that can be used in the invention include, for example, zinc hexacyanocobaltate (III), zinc hexacyanoferrate (III), nickel hexacyanoferrate (II), cobalt hexacyanocobaltate (III), and the like. Further examples of suitable double metal cyanide complexes are listed in U.S. Pat. No. 5,158,922, the teachings of which are incorporated herein by reference. Zinc hexacyanocobaltate (III) is preferred. 2 To the extent that Appellant has presented substantive arguments for separate patentability of any individual claims on appeal, we will address them separately consistent with 37 C.F.R. § 41.37(c)(1)(vii) (2005). 3 Appeal 2009-000079 Application 11/031,733 2. Appellant also states (Spec. 5-6) that: The tertiary unsaturated alcohols useful in the present invention may be designated by the formula (I) wherein R1 represents a group containing from two to twenty carbon atoms having at least one site of unsaturation, where an unsaturated carbon atom is attached to the hydroxyl-bearing carbon of (I). Atoms other than carbon and hydrogen may be present. R1 may be an aromatic group. R2 represents a group containing from two to twenty carbon atoms having at least one site of unsaturation, where an unsaturated carbon is attached to the hydroxyl-bearing carbon of (I) or one to twenty carbon atoms free of any sites of unsaturation attached to the hydroxyl-bearing carbon (I). Atoms other than carbon and hydrogen may be present. R2 may be an aromatic group. R3 represents a group containing from two to twenty carbon atoms having at least one site of unsaturation, where an unsaturated carbon is attached to the hydroxyl-bearing carbon of (I) or one to twenty carbon atoms free of any sites of unsaturation attached to the hydroxyl-bearing carbon (I). Atoms other than carbon and hydrogen may be present. The structure of one such unsaturated tertiary alcohol, 2- methyl-3-butene-2-ol (MBE) . . . . 4 Appeal 2009-000079 Application 11/031,733 3. Appellant does not dispute the Examiner’s finding that Clement teaches a process for preparing a polyol by polyaddition of alkylene oxides onto starter compounds containing active hydrogen atoms. (Compare Ans. 3 with App. Br. 4-9). 4. Appellant does not dispute the Examiner’s finding that Clement teaches that such conventional polymerization process is carried out in the presence of a DMC compound defined as a catalyst and 2-methyl-3-butyn-2- ol (MBE) defined as an initiator compound. (Compare Ans. 3 with App. Br. 4-9). 5. Clement teaches (col. 3, l. 18 to col. 4, l. 9, together with col. 2, 58- 60) (emphasis added) that: The starting mixture of catalyst, initiator compound and alkylene oxide is conveniently made by combining the catalyst and initiator compound in a pressure reactor (or by forming the catalyst in the initiator), and then pressurizing the reactor with an initial quantity of the alkylene oxide used to activate the catalyst. The induction period [(the beginning of the polymerization in which little or no polymerization occurs)] follows, as indicated by a nearly constant or slowly decreasing pressure in the reactor. The onset of rapid polymerization that follows the induction period is evidenced by a drop in pressure as the initial quantity of alkylene oxide is consumed. . . . . The polymerization reaction may be performed continuously or batchwise. In such continuous processes, the activated initiator/catalyst mixture is continuously fed into a continuous reactor . . . . 6. Clement teaches that its preferred initiator compounds have secondary or tertiary hydroxyl groups with MBE as its exemplified initiator 5 Appeal 2009-000079 Application 11/031,733 compound and can react with ethylene oxide (col. 4, ll. 56-61, col. 5, ll. 15- 51, and col. 12. ll. 10-50). 7. Consistent with the above disclosures, Clement exemplifies premixing a zinc hexacyanocobaltate compound and 2-methyl-3-butene-2-ol (MBE) homogeneously and activating the zinc hexacyanocobaltate compound/ 2- methyl-3-butene-2-ol (MBE) mixture prior to the polymerization of alkylene oxides (col. 11, l. 45 to col. 12, l. 50, Examples 5, 7 and 8). 8. Clement teaches that 2-methyl-3-butyn-2-ol (MBE) in Examples 5, 7, and 8, which functions as an initiator, also functions as a complexing agent (col. 5, ll. 40-51 and col. 6, ll. 55-67). PRINCIPLES OF LAW The initial inquiry into the propriety of the Examiner's § 102(b) rejection requires interpretation of the claims on appeal to determine their scope. See, e.g., Gechter v. Davidson, 116 F.3d 1454, 1457 (Fed. Cir. 1997); In re Paulsen, 30 F.3d 1475, 1479 (Fed. Cir. 1994). During prosecution of a patent application, "[t]he PTO applies to the verbiage of the proposed claims the broadest reasonable meaning of the words in their ordinary usage as they would be understood by one of ordinary skill in the art." In re Morris, 127 F.3d 1048, 1054 (Fed. Cir. 1997). When a claim employs the transitional term "comprising," it is interpreted as not precluding the presence of additional ingredients and/or steps which are not recited. In re Baxter, 656 F.2d 679, 686-87 (CCPA 1981) ("As long as one of the [claimed] monomers in the reaction is propylene, any other monomer 6 Appeal 2009-000079 Application 11/031,733 may be present, because the term 'comprises' permits the inclusion of other [unclaimed] steps, elements, or materials."). Under 35 U.S.C. § 102(b), "[a] claim is anticipated only if each and every element as set forth in the claim is found, either expressly or inherently described, in a single prior art reference." Verdegaal Bros. v. Union Oil Co. of Cal., 814 F.2d 628, 631-32 (Fed. Cir. 1987). Moreover, as stated in In re Best, 562 F.2d 1252, 1255 (CCPA 1977): [w]here . . . the claimed and prior art products are identical or substantially identical, or are produced by identical or substantially identical processes, the PTO can require an applicant to prove that the prior art products do not necessarily or inherently possess the characteristics of his claimed product. Whether the rejection is based on 'inherency' under 35 U.S.C. § 102, on 'prima facie obviousness' under 35 U.S.C. § 103, jointly or alternatively, the burden of proof is the same, and its fairness is evidenced by the PTO's inability to manufacture products or to obtain and compare prior art products. [Footnote and citations omitted)]. The argued limitations must appear in the claims on appeal. In re Self, 671 F.2d 1344, 1348 (CCPA 1982) (Appellant's arguments must be based on limitations appearing in the claims.). A showing of unexpectedly superior results is not relevant to a situation where a single prior art fully describes the claimed features under 35 U.S.C. § 102(b). In re Malagari, 499 F.2d 1297, 1302 (CCPA 1974). ANALYSES 7 Appeal 2009-000079 Application 11/031,733 The claimed subject matter is directed to employing a double metal cyanide (DMC) catalyst comprising a non-hexanitrometallate containing a double metal cyanide compound inclusive of a zinc hexacyanocobaltate compound and one or more unsaturated tertiary alcohols inclusive of MBE in a conventional polymerization process for preparing a polyol. (See claim 32.) The claimed functionalized polymer need not be present in the double metal cyanide (DMC) catalyst. (See claim 32 reciting 0 wt% of the functionalized polymer.). Moreover, additional ingredients and/or steps, which are not specifically recited in claim 32, can be present due to Appellant’s use of the transitional term “comprising” in claim 32. Appellant does not dispute the Examiner’s finding that Clement teaches the claimed conventional polymerization process for preparing a polyol which is carried out in the presence of a DMC compound defined as a catalyst and 2-methyl-3-butyn-2-ol (MBE) defined as an initiator compound. Clement also teaches forming an activated mixture of a DMC compound and an initiator, such as MBE, prior to using it in a polymerization process for preparing a polyol. Clement also exemplifies premixing of a zinc hexacyanocobaltate compound (DMC compound) with MBE prior to polymerization. Consequently, we concur with the Examiner that Clement teaches employing a premixture of a DMC compound and MBE corresponding to the claimed catalyst in the claimed conventional polymerization process for preparing a polyol within the meaning of 35 U.S.C. § 102(b). Appellant contends that “the catalyst of Clement et al. is not the catalyst of the instantly claimed polyol production process” (App. Br. 6, 8 Appeal 2009-000079 Application 11/031,733 together with Reply Br. 3). In support of this contention, Appellant refers to pages 70 and 198 of McGraw-Hill Dictionary of Chemistry (Sybil P. Parker et al. eds. 1997) containing the definitions of the terms “initiator” and “catalyst” to distinguish the claimed catalyst from Clement’s premixture of a DMC compound and an initiator (id). However, the fact remains that the claimed catalyst, like Clement’s premixture, includes a mixture of a zinc hexacyanocobaltate compound (DMC compound) and MBE. Appellant has not shown that the claimed mixture is patentably different from Clement’s premixture. Appellant also contends that “the order of addition in making a double metal cyanide catalyst is important because the catalyst maker is forming a crystalline structure” (App. Br. 8). However, claim 32 does not recite any specific order by which its catalyst is made or any structure by which the claimed mixture can be patentably distinguished over Clement’s premixture. Claim 32 only requires that the claimed catalyst, like Clement’s premixture, contain a mixture of a DMC compound, such as a zinc hexacyanocobaltate compound, and one or more unsaturated tertiary alcohols, such as MBE. Further, Appellant contends that Clement teaches 2-methl-3-buyn-2-ol (MBE) as one of a laundry list of possible complexing agents (App. Br. 9). However, as indicated supra, Clement exemplifies forming a premixture of a zinc hexacyanocobaltate compound and MBE prior to forming a polyol. Appellant appears to contend that the Examiner’s 35 U.S.C. § 102(b) rejection can be rebutted by a showing of unexpected results (App. Br. 9). However, a showing of unexpectedly superior results is not relevant to a 9 Appeal 2009-000079 Application 11/031,733 situation where a single prior art fully describes the claimed features under 35 U.S.C. § 102(b). It follows that Appellant has not shown that the Examiner erred in finding that Clement teaches employing a premixture of a DMC compound and MBE corresponding to the claimed catalyst in its polymerization process for preparing a polyol within the meaning of 35 U.S.C. § 102(b). ORDER The decision of the Examiner is affirmed. TIME PERIOD No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED ssl BAYER MATERIAL SCIENCE LLC 100 BAYER ROAD PITTSBURGH, PA 15205 10 Copy with citationCopy as parenthetical citation