Ex Parte Buller et alDownload PDFPatent Trial and Appeal BoardOct 29, 201411378847 (P.T.A.B. Oct. 29, 2014) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte BENYAMIN BULLER, CHRIS M. GRONET, RATSON MORAD, and MARKUS E. BECK __________ Appeal 2012-010068 Application 11/378,847 Technology Center 1700 ____________ Before CATHERINE Q. TIMM, LINDA M. GAUDETTE, and MICHAEL P. COLAIANNI, Administrative Patent Judges. COLAIANNI, Administrative Patent Judge. DECISION ON APPEAL Appellants appeal under 35 U.S.C. § 134 the final rejection of claims 1–3, 6, 9–13, 15, 16, 34–45, 52, 88–92, 96, 97, 100–110, and 120. We have jurisdiction over the appeal pursuant to 35 U.S.C. § 6(b). We AFFIRM-IN-PART. Appellants’ invention is directed to cylindrical-shaped solar cells in a transparent tubular casing (Spec. 6:32–33). Claim 1 is illustrative: 1. A solar cell unit comprising: (A) a solar cell comprising: a substrate that is either (i) tubular or (ii) a solid rod; Appeal 2012-010068 Application 11/378,847 2 a back-electrode circumferentially disposed on the substrate; a semiconductor junction circumferentially disposed on said back-electrode, wherein said semiconductor junction comprises a first layer circumferentially disposed on a second layer, wherein said first layer comprises a first composition that comprises a first semiconductor and said second layer comprises a second composition that comprises a second semiconductor, wherein said first semiconductor is different than said second semiconductor and wherein the first composition in the first layer forms a semiconductor junction with said second composition in said second layer, wherein the first semiconductor or the second semiconductor is an absorber; and a transparent conductive layer circumferentially disposed on said semiconductor junction; and (B) a transparent tubular casing circumferentially disposed onto said solar cell, wherein a photovoltaic current generated by the solar cell unit is from absorption of light by the absorber. The Examiner maintains, and Appellants appeal, the following rejections:1 1. Claim 120 is rejected under 35 U.S.C. § 112, first paragraph, as failing to comply with the written description requirement. 2. Claims 1, 2, 6, 9–12, 15, 16, 43–45, 88, 89, 96, 97 and 100 are rejected under 35 U.S.C. § 103(a), as being unpatentable over Chittibabu et al. (US 2005/0040374 A1, published Feb. 24, 2005) in view of Gebeyehu et al. (Hybrid solar cells based on dye-sensitized nanoporous TiO2 electrodes and conjugated polymers as hole transport materials, 125 Synthetic Metals 279–287 (2002)) as evidenced by Antony et al. (Realization of red light-emitting diodes with a confinement layer, 12 Optical Materials 291–294 (1999)), Park 1 The Examiner withdrew a rejection of claim 120 under 35 U.S.C. § 112, second paragraph (Ans. 4). Appeal 2012-010068 Application 11/378,847 3 et al. (Structural and optical properties of rutile and anatase TiO2 thin films: Effects of Co doping, 484 Thin Solid Films 34–38 (2005)), Gueymard et al. (Proposed Reference Irradiance Spectra For Solar Energy Systems Testing, 73 Solar Energy 443–467 (2002)), and Mylar and Refraction websites. 3. Claims 3, 101, 105, 106, and 110 are rejected under 35 U.S.C. § 103(a), as being unpatentable over Chittibabu in view of Gebeyehu, Nakata (WO 2004/001858 A1, published Dec. 31, 2003, relying upon US 2006/0086384 A1, published Apr. 27, 2006 as a translation) or Sugita et al. (JP 2000-294821A, published Oct. 20, 2000). 4. Claim 13 is rejected under 35 U.S.C. § 103(a) as being unpatentable over Chittibabu in view of Gebeyehu and Fujimori et al. (US 6,683,244 B2, patented Jan. 27, 2004). 5. Claim 34 is rejected under 35 U.S.C. § 103(a) as being unpatentable over Chittibabu in view of Gebeyehu and Mlavsky (US 4,078,944, patented Mar. 14, 1978). 6. Claim 35 is rejected under 35 U.S.C. § 103(a) as being unpatentable over Chittibabu in view of Gebeyehu, Mlavsky, and Baumeister et al. (US 4,783,373, patented Nov. 8, 1988). 7. Claims 36–40 and 42 are rejected under 35 U.S.C. § 103(a) as being unpatentable over Chittibabu in view of Gebeyehu and Weinstein et al. (US 3,990,914, patented Nov. 9, 1976). 8. Claim 41 is rejected under 35 U.S.C. § 103(a) as being unpatentable over Chittibabu in view of Gebeyehu, Weinstein, and Nath et al. (US 5,474,620, patented Dec. 12, 1995). Appeal 2012-010068 Application 11/378,847 4 9. Claims 52 and 90 are rejected under 35 U.S.C. § 103(a) as being unpatentable over Chittibabu in view of Gebeyehu, Mlavsky, and Yamashita et al. (US 7,094,452 B2, patented Aug. 22, 2006). 10. Claims 91 and 92 are rejected under 35 U.S.C. § 103(a) as being unpatentable over Chittibabu in view of Gebeyehu, and Trupke et al. (Improving solar cell efficiencies by down-conversion of high-energy photons, 92 J. Appl. Phys. 1668–1674 (2002)). 11. Claims 102–104 and 107–109 are rejected under 35 U.S.C. § 103(a) as being unpatentable over Chittibabu in view of Gebeyehu, Nakata, Beauchamp et al. (US 5,449,413, patented Sept. 12, 1995), and Thelen (US 3,247,392, patented Apr. 19, 1966). 12. Claims 1–3, 6, 9–13, 15, 16, 43–45, 88, 89, 96, 97, and 100 are rejected under 35 U.S.C. § 103(a) as being unpatentable over Neudecker et al. (US 2003/0064292 A1, published Apr. 3, 2003) in view of Sugita as evidenced by Burgelman et al. (Modelling polycrystalline semiconductor solar cells, 361–362 Thin Solid Films 527–532 (2000)). REJECTIONS (1): WRITTEN DESCRIPTION ISSUE Did the Examiner reversibly err in finding that the subject matter of claim 120 lacks written descriptive support because the Specification discloses on page 57 that when polycrystalline silicon is used in the layers, a depleted layer 512 is formed between the n-doped and p-doped layers, which does not comport with what constitutes “circumferentially disposed” as that Appeal 2012-010068 Application 11/378,847 5 phrase is defined on pages 23–24 of the Specification? We decide this issue in the affirmative. FINDINGS OF FACT AND ANALYSES The Examiner’s findings are located on pages 6 and 26 of the Answer. The Examiner finds that there is no disclosure of a solar cell comprising a first layer comprising p-doped polycrystalline silicon circumferentially disposed on a second layer comprising n-doped polycrystalline silicon (Ans. 6). The Examiner finds that the only embodiment disclosed using polycrystalline silicon includes a depleted polycrystalline layer between the p-doped and n-doped polycrystalline layers (id.). The Examiner finds that the depleted layer would preclude the first layer from being circumferentially disposed on the second layer based upon the definition of “circumferentially disposed” on pages 23–24 of the Specification (id.). Appellants argue that the depletion layer disclosed on page 57 of the Specification is not a separate layer (Br. 7). Rather, Appellants contend that the depletion layer is a natural effect arising from the circumferential disposition of the p-doped semiconductor onto the n-doped semiconductor. Id. Appellants argue that the depletion layer forms due to the junction between a p-type semiconductor and an n-type semiconductor. Id. The test for sufficiency of the written description is whether the disclosure of the application relied upon reasonably conveys to those skilled in the art that the applicant had possession of the claimed subject matter as of the filing date. In re Owens, 710 F.3d 1362, 1366 (Fed. Cir. 2013). Appeal 2012-010068 Application 11/378,847 6 In the present case, on page 57 of the Specification, Appellants cite Bube,2 Photovoltaic Materials, 1998 Imperial College Press, London pages 57–66 as describing the p-n polycrystalline silicon junctions. Bube at page 60 discloses that a depletion region forms between a p-doped and n-doped polycrystalline silicon junction. Moreover, Bube discloses on page 18 that the p-doped and n-doped layers in a p-n junction are doped so that the doping is the same so that the resulting depletion region has equal widths. In light of these disclosures, we find that one of ordinary skill in the art would have understood that the depletion layer is formed from the p- doped region and n-doped region of the p-n junction as evinced by Bube. Accordingly, we do not find that claim 120 lacks written descriptive support. We reverse the Examiner’s § 112, first paragraph, rejection of claim 120. REJECTIONS (2), (4), (7), (8), AND (9) Appellants’ arguments focus solely on claim 1 (Br. 8–12, 16, 19). The rejections of the dependent claims under rejections (2), (4), and (7) to (9) will stand or fall with our analysis regarding the rejection of claim 1 over Chittibabu and Gebeyehu. ISSUE Did the Examiner reversibly err in finding that one of ordinary skill in the art would have modified Chittibabu’s solar cell to include Gebeyehu’s poly(3-octylthiphene) or a low-bandgap thiophene-isothianaphthene-based copolymer as the charge carrier material 415 in Chittibabu’s solar cell 2 The Bube reference including pages 1-277 was made of record in the Information Disclosure Statement (IDS) filed May 4, 2006. Appeal 2012-010068 Application 11/378,847 7 because Chittibabu discloses using p-type conducting polymers for this layer and Gebeyehu discloses that using solid-hole transfer materials simplify construction and improve cell stability relative to liquid-electrolyte cells (Ans. 11)? We decide this issue in the negative. FINDINGS OF FACT & ANALYSIS The Examiner finds that Chittibabu teaches that subject matter of claim 1, except for, inter alia, the first layer (415 in Chittibabu’s Figure 4) of the photovoltaic layer comprising a first semiconductor element (Ans. 8–10). The Examiner finds that Gebeyehu teaches materials known to be useful for charge transport from titanium dioxide electrodes to the counter electrode in dye-sensitized cells, namely p-type polymeric semiconductors, such as poly(3-octylthiphene) (P3OT) or a low bandgap thiophene-isothianaphthene- based copolymer (Ans. 10). The Examiner finds that this function is the same function required of layer 415 in the cell of Chittibabu’s Figure 4c. Id. The Examiner concludes that it would have been obvious to modify Chittibabu’s solar cell to include Gebeyehu’s poly(3-octylthiphene) or a low-bandgap thiophene-isothianaphthene-based copolymer as the charge carrier material 415 in Chittibabu’s solar cell because Chittibabu discloses using p-type conducting polymers for this layer and Gebeyehu discloses that using solid-hole transfer materials simplify construction and improve cell stability relative to liquid-electrolyte cells (Ans. 11). Appellants argue that one of ordinary skill would not have been motivated to combine Gebeyehu’s P3OT or a thiophene-isothianaphthene- based copolymer with Chittibabu’s solar cell because Gebeyehu teaches away from the combination (Br. 9). Appellants contend that Gebeyehu Appeal 2012-010068 Application 11/378,847 8 would not have motivated one of ordinary skill in the art to use P3OT in a solar cell because using P3OT decreases the efficiency of the cell which would greatly outweigh the benefit of improved cell stability. Id. Appellants contend that Gebeyehu’s disclosure that the efficiencies achieved with a solar cell using P3OT are more than one order of magnitude smaller than the efficiencies observed for devices with a liquid electrolyte as transport medium (Br. 10–11). Appellants contend that Gebeyehu discloses problems with using a polymeric hole conductor include imperfect topological filling of the polymeric hole conductor into the pores between the nanoparticles in such solar cells and adhesion of the polymer on the titanium dioxide or the Ru dye in the solar cells (Br. 11). The Examiner’s rejection is based upon substituting Gebeyehu’s P3OT or a low-bandgap thiophene-isothianaphthene-based copolymer for the charge material 415 in Chittibabu’s solar cell. As noted by the Examiner, Chittibabu discloses using p-doped polymeric materials as the charge carrying material 415 (Ans. 10). Gebeyehu discloses that using liquid elecrolytes makes the manufacturing process more difficult because the cells must be electrically connected yet chemically separated (Gebeyehu 280 top of first column). Gebeyehu discloses that it would be desirable to substitute a solid hole conducting material for the liquid electrolyte to eliminate problems with sealing and degradation. Id. Gebeyehu states that “we demonstrate that conjugated semiconducting polymers can be successfully adopted to [the] concept of nanocrystalline TiO2 solar cells, replacing the electrolyte as well as the dye” (Gebeyehu 280 second column). Gebeyehu discloses that the lower efficiency and imperfect topological Appeal 2012-010068 Application 11/378,847 9 filling of the polymeric hole conductor into the pores between nanoparticles are challenges that remain to be solved (Gebeyehu 287). Like the Examiner (Ans. 27), we find that one of ordinary skill in the art would not have viewed Gebeyehu’s teachings as teaching away. “A reference may be said to teach away when a person of ordinary skill, upon reading the reference, would be discouraged from following the path set out in the reference, or would be led in a direction divergent from the path that was taken by the applicant.” In re Gurley, 27 F.3d 551, 553 (Fed. Cir. 1994). In the present case, the nature of Gebeyehu’s teaching is that polymeric p-doped material may be used to make solar cells in a less complicated manner than when liquid electrolyte is used, but with a trade-off that less efficient solar cells may result. As noted by the Examiner, one of ordinary skill in the art would have taken into consideration the lower efficiency with the easier construction in determining the suitability of using the polymer charge material in lieu of a liquid electrolyte for a particular solar cell application. Appellants do not respond to this finding of the Examiner (No Reply Brief filed). On this record, we affirm the Examiner’s § 103 rejections (2), (4), (7), (8), and (9). REJECTION (3): § 103 Claim 3 Claim 3 is representative of the arguments advanced by Appellants (Br. 12–15). Appeal 2012-010068 Application 11/378,847 10 ISSUE Did the Examiner reversibly err in finding that one of ordinary skill in the art would have used Sugita’s3 outer glass protective layer as Chittibabu’s outer protective layer 424 in order to provide a strong layer to protect the solar cell from water? We decide this issue in the negative. FINDINGS OF FACT & ANALYSIS The Examiner finds that the combined teachings of Chittibabu and Gebeyehu teach the subject matter of claim 3, except for the use of glass as a transparent tubular outer casing (Ans. 13). The Examiner finds that Sugita discloses a cylindrical fiber solar cell, which is coated with a protective layer 7 of glass that is circumferentially disposed on the outer transparent conductive layer 6, and which provides isolation from the atmosphere (id.). The Examiner concludes that it would have been obvious to modify Chittibabu’s solar cell by using a glass tubular casing for layer 424 as taught by Sugita because glass possesses strength and water impermeability required for such protective layers (id.). Appellants argue that Sugita’s solar cell is completely inapposite to Appellants’ claimed invention and Chittibabu’s solar cell (Br. 15). Appellants contend that Sugita’s invention is directed to a different kind of solar cell wherein a separate substrate and back electrode are not required 3 For reasons evident infra, we focus solely on the alterative rejection based upon the combined teachings of Chittibabu, Gebeyehu. and Sugita. Because we find that the Examiner’s rejection including Sugita is affirmable, we find it unnecessary to reach the Examiner’s rejection based upon Chittibabu in view of Gebeyehu and Nakata. Appeal 2012-010068 Application 11/378,847 11 and thus the presence or absence of a transparent tubular casing comprising glass would have had no import to one skilled in the art. Id. Appellants have not explained why the differences in solar cell structure would have led one of ordinary skill to the conclusion that the presence or absence of a transparent tubular casing would have had no import. Rather, both Sugita and Chittibabu teach using protective outer layers 7 and 424, respectively, on flexible solar cells. We find that Sugita would have suggested using glass as a protective layer in a solar cell. Indeed, Sugita discloses that the fiber solar cells may be flexed without damage to the solar cell and these fibers may be woven using a loom (Sugita ¶ [0017]). Chittibabu discloses that the photovoltaic fibers may be woven into a flexible fabric (Chittibabu ¶ [0079]). Based on these teachings, we agree with the Examiner that the combined teachings of Chittibabu and Sugita would have suggested using glass material as the outer protective layer on a flexible solar cell. We affirm the Examiner’s § 103 rejection over Chittibabu in view of Gebeyehu and Sugita. REJECTION (5): Claim 34 ISSUE Did the Examiner reversibly err in finding that the combined teachings of Chittibabu, Gebeyehu, and Mlavsky would have suggested an antireflective coating circumferentially disposed on the transparent tubular casing as recited in claim 34? We decide this issue in the negative. Appeal 2012-010068 Application 11/378,847 12 FINDINGS OF FACT & ANALYSIS Claim 34 recites: “[t]he solar cell unit of claim 1, the solar cell unit further comprising an antireflective coating circumferentially disposed on said transparent tubular casing.” The Examiner finds that Chittibabu and Gebeyehu fail to teach an antireflective coating on protective layer 424 (Ans. 15). The Examiner finds that Mlavsky teaches providing an antireflective coating on the outer surface of a protective tube containing solar cells to increase light transmission to the solar cells (id.). The Examiner concludes that it would have been obvious to modify Chittibabu’s solar cell by providing an antireflective coating on the protective layer as taught by Mlavsky because it would have increased the amount of light incident on the photoactive junction, thereby increasing the power output from the cell (Ans. 15). Appellants argue that Mlavsky’s rigid envelope 16 with the antireflective coating is not circumferentially disposed on the solar cell (Br. 16). Appellants contend that Mlavsky’s teachings would not have suggested that an antireflective coating could have been added to the flexible fibers of Chittibabu (Br. 17). Appellants argue that Mlavsky’s application of an antireflective coating to a rigid glass envelope 16 would not have suggested overlaying an antireflective coating on the fibers of Chittibabu. Id. Appellants contend that there is no indication that Mlavsky’s antireflective coating may be used with Chittibabu’s dye sensitized solar cells. Id. Contrary to Appellants’ arguments, the Examiner finds that Mlavsky teaches that it is beneficial to apply an antireflective coating to increase light transmission to the solar cells. Appellants’ arguments do not specifically refute that finding. Rather, Appellants’ arguments merely allege that Appeal 2012-010068 Application 11/378,847 13 Mlavsky’s antireflective coating would not have been compatible with Chittibabu’s solar cell. Appellants have not proffered any evidence to substantiate the mere attorney argument. Moreover, the Examiner is not suggesting that Mlavsky’s antireflective coating would have been added to Chittibabu’s solar cell. Instead the Examiner finds that one of ordinary skill in the art would have found it desirable to add an antireflective coating to the outer cover of a solar cell to increase light transmission. In other words, the Examiner appears to be using Mlavsky to demonstrate what would have been known in the art and within the skill of the ordinary artisan to implement. On this record, we affirm the Examiner’s § 103 rejection of claim 34. REJECTION (6): Claim 35 Claim 35 recites: “[t]he solar cell unit of claim 34, wherein the antireflective coating comprises MgF2, silicon nitrate, titanium nitrate, silicon monoxide, or silicon oxide nitrite.” The Examiner finds that the combined teachings of Chittibabu, Gebeyehu, and Mlavsky teach the subject matter of claim 35, but the Examiner finds that Mlavsky fails to teach the composition of the antireflective coating (Ans. 16). The Examiner finds that Baumeister teaches using a magnesium fluoride antireflective coating on a solar cell (id.). The Examiner concludes that it would have been obvious to modify the solar cell suggested by Chittibabu as modified by Gebeyehu and Mlavsky by using the magnesium fluoride antireflective coating as taught by Baumeister because Baumeister teaches the effectiveness in reducing the reflection of solar radiation by using an antireflective coating (id.). Appeal 2012-010068 Application 11/378,847 14 Appellants argue that the applied prior art, either alone or in combination, fails to provide a reasonable expectation of success that any of the materials recited in claim 35 may be used on Chittibabu’s fibers as an antireflective coating (Br. 18). Appellants contend that Chittibabu’s fibers are flexible and there is no teaching or expectation that any of the claimed antireflective coatings of Baumeister may be used on Chittibabu’s flexible fibers while still permitting Chittibabu’s fibers to achieve their intended purpose: solar cells that may be woven into a fabric (id.). Appellants further contend that there is no teaching in any of the references that an antireflective coating is compatible with, Chittibabu’s dye sensitized solar cells (id.). The Examiner finds that Appellants’ argument that there is no reasonable expectation of success for forming an antireflection coating on a flexible substrate is lacking evidence (Ans. 30). Appellants assert that there would be no reasonable expectation of success, but Appellants fail to cite to any portion of the applied prior art or other evidence to establish that there would have been no reasonable expectation of success for forming an antireflective coating on a flexible substrate. In our view, the Examiner has provided evidence via the applied prior art that there is a reasonable expectation that antireflective coatings on solar cells, which includes flexible solar cells, would have been formed successfully. Appellants’ mere attorney argument does not specifically address this evidence. In response to Appellants’ argument that there is no teaching that an antireflective coating is suitable for the dye-sensitized solar cells of Chittibabu, the Examiner finds that the antireflective coating would have permitted more light to enter the solar cell, which would have increased the Appeal 2012-010068 Application 11/378,847 15 efficiency regardless of the type of solar cell (Ans. 31). We agree. The Examiner proposes placing the antireflective coating on the outside of the casing 424 of Chittibabu (Ans. 30). Accordingly, the antireflective coating would not come into contact with any of the other components of Chittibabu’s solar cell. Moreover, the Examiner’s finding that the antireflective coating would have resulted in more light entering the solar cell and increasing efficiency is not contested by Appellants (no Reply Brief). On this record, the preponderance of the evidence favors the Examiner’s conclusion that claim 35 would have been obvious over the combined teachings of Chittibabu, Gebeyehu, Mlavsky, and Baumeister. REJECTION (10): Claims 91 and 92 Claim 91 recites: “[t]he solar cell unit of claim 1, wherein the transparent conductive layer is coated with a fluorescent material.” Claim 92 recites: “[t]he solar cell unit of claim 1, wherein a luminal or an exterior surface of said transparent tubular casing is coated with a fluorescent material.” The Examiner finds that Chittibabu in view of Gebeyehu teaches the subject matter of claims 91 and 92, except for providing a fluorescent material over the transparent conducting layer or on the outer tubular casing (Ans. 21). The Examiner finds that Trupke teaches efficiency gains are achieved by adding a phosphorescent material as a luminescent converter for down-conversion of high-energy photons impacting a photovoltaic device and providing this fluorescent layer on the front of the cell (id.). The Examiner concludes that it would have been obvious to modify the device of Appeal 2012-010068 Application 11/378,847 16 Chittibabu by providing a down-conversion layer on the front surface of the solar cell as taught by Trupke because Trupke teaches that overall cell efficiency is increased, due to overall better utilization of high-energy photons resulting from application of such a layer (id.). Appellants argue that Trupke’s solar cell operates by a different mechanism than Chittibabu’s solar cell such that there would have been no expectation that Trupke’s luminescence converter would improve the efficiency of the device formed by the combination of Chittibabu and Gebeyehu (Br. 20). Appellants contend that the device proposed by the combination of Chittibabu and Gebeyehu does not generate photovoltaic current from the absorption of light by a semiconductor in a semiconductor junction, such that there is no teaching in any of the references that the dye utilized in the combination of Chittibabu and Gebeyehu would benefit from the down-converted photons of Trupke (Br. 20). Appellants’ arguments attack the references individually instead of addressing what the combined teachings would have suggested to one of ordinary skill in the art. In re Keller, 642 F.2d 413, 425 (CCPA 1981). While Chittibabu uses a dye-sensitized solar cell (DSSC), the Examiner proposes substituting Gebeyehu’s P3OT polymer for the charge carrier material in Chittibabu. Gebeyehu discloses a hybrid solar cell that uses both solid state and dye-sensitized components (Gebeyehu abstract). Accordingly, Appellants’ arguments regarding the different types of solar cells are not persuasive because the combination uses a solid state p-n junction too. Appellants have not established that Chittibabu’s solar cell as modified by Gebeyehu that includes a solid state component would not have Appeal 2012-010068 Application 11/378,847 17 benefited from the use of Trupke’s fluorescent material for the reasons found by the Examiner. On this record, we affirm the Examiner’s § 103 rejection of claims 91 and 92 over Chittibabu, Gebeyehu, and Trupke. REJECTION (11): Claims 102 and 104 Appellants argue claims 102–104, and 107–109 as a group (Br. 22– 23). We select claims 102 and 104 as representative. The Examiner finds that Chittibabu as modified by Gebeyehu, Nakata teaches the subject matter of claims 102 and 104, but the applied prior art fails to teach applying an ultraviolet (UV) protective coating to the transparent tubular casing (claim 102) or where the transparent tubular casing is made of glass with additives and wherein the transparent tubular casing provides complete protection from UV wavelengths (claim 104) (Ans. 21). The Examiner finds that Beauchamp or Thelen teaches solar cell covers that reflect nearly all UV light to reduce the amount of light that is converted to heat in the solar cell (Ans. 22). The Examiner concludes that it would have been obvious to modify the device of Chittibabu by providing a highly UV- reflective coating to reflect portions of the UV spectrum that provide little or no photo response over the protective layer as taught by Beauchamp or Thelen because this would reduce deleterious heating of the solar cell and thereby increase solar cell efficiency (id.). Referring to page 663 of reference C13 to Luque cited on the Information Disclosure Statement filed May 3, 2006, Appellants argue that the dye-sensitized solar cells cannot absorb visible light due to their relatively wide band gaps (Br. 23). Appellants contend that any Appeal 2012-010068 Application 11/378,847 18 modification of Chittibabu or Gebeyehu to include a UV-reflective coating would severely limit absorption efficiency of the Chittibabu and/or Gebeyehu absorbers (id.). Based upon these arguments, Appellants contend that modifying Chittibabu’s solar cell to include Beauchamp’s or Thelen’s UV-reflective coating would have severely limited the absorption efficiency of the Chittibabu and/or Gebeyehu absorbers (id.). While Appellants’ cite to page 663 of the Luque reference to support their position that the proposed modification would severely limit the absorption efficiency, our review of Luque reveals that there is no page 663 in the document (only pages 1-662 are included). Accordingly, Appellants’ have not directed us to any evidence to substantiate their argument that stable oxide semiconductors used in dye-sensitized solar cells cannot absorb visible light due to their relatively wide band gaps. The Examiner reasonably finds that providing a UV-reflective coating would provide the beneficial result of avoiding deleterious heating of the solar cell. Appellants do not dispute this reason for the modification of Chittibabu. On this record, we affirm the Examiner’s § 103 rejection of claims 102–104 and 107–109 over Chittibabu in view of Gebeyehu, Nakata, Beauchamp or Thelen. REJECTION (12): Claim 1: Neudecker in view of Sugita The Examiner finds that Neudecker teaches all the limitations of claim 1, except for a transparent tubular casing circumferentially disposed on the solar cell (Ans. 22–23). The Examiner finds that Sugita teaches a cylindrical solar cell having a glass protective layer 7 disposed on the solar cell to Appeal 2012-010068 Application 11/378,847 19 protect the solar cell from the atmosphere (Ans. 23). The Examiner concludes that it would have been obvious to modify Neudecker’s solar cell by providing a protective glass coating as taught by Sugita to protect the sensitive photovoltaic layers from the atmosphere (Ans. 23). Appellants argue that Neudecker’s solar cells do not need a protective layer and adding such a layer would have added unnecessary expense to the manufacture of Neudecker’s solar cells (Br. 24). Appellants further contend that other researchers have used a transparent conductive layer as the protective layer rather than adding a tubular casing (Br. 24). The Examiner finds that Sugita teaches placing a tubular glass protective layer over a doped tin oxide layer to provide protection (Ans. 33). The Examiner finds that Neudecker, like Sugita, teaches using a doped tin oxide as the transparent conductive oxide over the solar cell. Id. The Examiner reasons that one of ordinary skill in the art would have adapted the protective layers for the similar solar cells to suit the particular environment where the solar cell will be used. Id. Appellants do not respond or otherwise show error in these reasonable findings of the Examiner. Appellants’ citation to a list of patents where no tubular protective layer was used is not dispositive. In any event, Appellants concede that the art is replete with solar cells having transparent conductors and further external protective layers (Br. 24). This admission further supports the Examiner’s finding that one of ordinary skill in the art would have determined the appropriate protection, including adding tubular protective layer circumferentially disposed on the solar cell, required for the solar cell in a particular environment. Appeal 2012-010068 Application 11/378,847 20 On this record, we affirm the Examiner’s § 103 rejection of claims 1– 3, 6, 9–13, 15, 16, 43–45, 88, 89, 96, 97, and 100 over Neudecker in view of Sugita. DECISION The Examiner’s decision is affirmed-in-part. TIME PERIOD FOR RESPONSE No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). ORDER AFFIRMED-IN-PART cdc Copy with citationCopy as parenthetical citation