Ex Parte Bedell et alDownload PDFPatent Trial and Appeal BoardAug 31, 201612713560 (P.T.A.B. Aug. 31, 2016) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE FIRST NAMED INVENTOR 121713,560 02/26/2010 Stephen W. Bedell 133964 7590 09/02/2016 HOFFMAN WARNICK LLC 540 Broadway 4th Floor ALBANY, NY 12207 UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. CONFIRMATION NO. FIS920100005US1 4962 EXAMINER GRAYBILL, DAVIDE ART UNIT PAPER NUMBER 2894 NOTIFICATION DATE DELIVERY MODE 09/02/2016 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address( es): PTOCommunications@hoffmanwarnick.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte STEPHEN W. BEDELL, KEITH E. FOGEL, PAUL A. LAURO, DEVENDRA SADAN A, and DA VOOD SHAHRJERDI Appeal2014-003427 Application 12/713 ,5 60 Technology Center 2800 Before ADRIENE LEPIANE HANLON, CATHERINE Q. TIMM, and JAMES C. HOUSEL, Administrative Patent Judges. HOUSEL, Administrative Patent Judge. DECISION ON APPEAL 1 Pursuant to 35 U.S.C. § 134(a), Appellants2 appeal from the Examiner's decision finally rejecting claims 1, 3, 5, 6, 8-12, and 21-23 1 Our decision refers to Appellants' Specification filed February 26, 2010, the Examiner's Final Office Action delivered April 10, 2013, Appellants' Appeal Brief (Appeal Br.) filed August 28, 2013, the Examiner's Answer (Ans.) delivered November 15, 2013, and Appellants' Reply Brief (Reply Br.) filed January 15, 2014. 2 According to Appellants, the real party in interest is International Business Machines Corporation. Appeal Br. 1. Appeal2014-003427 Application 12/713,560 under 35 U.S.C. § 103(a) as unpatentable over Mathew3 and Sato,4 alone or further combined with Henley,5 Wesley,6 Ravkin,7 and Zhang.8'9 We have jurisdiction over the appeal under 35 U.S.C. § 6(b ). We AFFIRM. STATEMENT OF THE CASE The invention relates to semiconductor substrate fabrication using stress-induced substrate spalling. Spec. i-f 2. Claim 1, reproduced below from the Claims Appendix of the Appeal Brief, is illustrative of the subject matter on appeal. The limitations at issue are italicized. 1. A method for spalling a substrate layer from an ingot of a semiconductor substrate, the method comprising: forming a seed layer directly on a surface of the ingot of the semiconductor substrate; forming an adhesion layer, the adhesion layer comprising nickel; directly on the seed layer; annealing the adhesion layer after forming the adhesion layer; after annealing the adhesion layer, forming a metal layer, the metal layer comprising nickel and having a tensile stress, directly on the adhesion layer; 3 US 2009/0280635 Al, published November 12, 2009. 4 US 5,668,060, issued September 16, 1997. 5 US 2007/0037323 Al, published February 15, 2007. 6 US 2,274,112, issued February 24, 1942. 7 US 2006/0260932 Al, published November 23, 2006. 8 US 2008/0210563 Al, published September 4, 2008. 9 Although the Examiner states that every ground of rejection set forth in the Final Office Action of April 10, 2013 is maintained (Ans. 2), we note that the Examiner withdrew "[a]ll rejections and objections except the rejections over the prior art" in the Advisory Action of June 27, 2013. Accordingly, only these § 103 rejections are before us on appeal. 2 Appeal2014-003427 Application 12/713,560 forming a fracture in the ingot by the tensile stress in the metal layer such that the substrate layer is located in the ingot above the fracture, and a remaining portion of the ingot is located below the fracture; and removing the substrate layer from the remaining portion of the ingot at the fracture. The Examiner maintains the following rejections under 35 U.S.C. § 103(a): A. Claims 1, 3, 5, 6, 8, 9, 11, and 12 as unpatentable over Mathew and Sato; B. Claim 10 as unpatentable over Mathew and Sato, and further in view of Henley; C. Claim 21 as unpatentable over Mathew and Sato, and further in view of Wesley alone, or alternatively combined with Ravkin; and D. Claims 22 and 23 as unpatentable over Mathew and Sato, and further in view of Zhang. With regard to Rejection A, Appellants argue sole independent claim 1 and dependent claim 12 separately, but do not otherwise argue the remaining dependent claims. As such, claims 3, 5, 6, 8, 9, and 11 stand or fall with claim 1. 37 C.F.R. § 41.37(c)(iv)(2013). In addition, Appellants do not raise substantively different arguments with regard to Rejections B, C, and D, instead arguing that Henley, Wesley, Ravkin, and Zhang do not remedy deficiencies asserted in the Examiner's proposed combination of Mathew and Sato in their arguments against claim 1. Accordingly, no new issues are presented for claims 10 and 21-23. We sustain the above rejections based on the findings of fact, conclusions of law, and rebuttals to arguments expressed by the Examiner in 3 Appeal2014-003427 Application 12/713,560 the Final Office Action and the Answer. The following comments are added for emphasis. Claim 1 The Examiner finds Mathew discloses a method for spalling a substrate layer from an ingot of a semiconductor substrate comprising forming a seed layer directly on a surface of the ingot, forming an adhesion layer comprising nickel directly on the seed layer, forming a metal layer comprising nickel directly on the adhesion layer, forming a fracture in the ingot such that a substrate layer in the ingot is located above the fracture with the remaining portion of the ingot located below the fracture, and removing the substrate layer from the remaining portion of the ingot. Final Act. 14--15. The Examiner further finds Mathew's process includes annealing the adhesion layer and the fracture formation step inherently is caused by tensile stress in the metal layer. Id. at 14. In support of this inherency finding, the Examiner notes that the formation of Mathew's metal layer is via an electroplating process substantially identical to Appellants', which Appellants teach causes the stressed metal layer to form on the adhesion layer. Id. at 20-21. With regard to the particular layer materials, the Examiner finds Mathew discloses these materials, in any combination. Id. at 16-17. 10 10 We note, although finding that Mathew discloses forming the layers directly on each other, the Examiner determines that it would have been an obvious matter of design choice to have formed the layers directly on each other because Appellants fail to teach that such an arrangement is for any particular unobvious purpose, produces an unexpected result, or is otherwise critical. Id. at 17. The Examiner also determines that direct formation of the 4 Appeal2014-003427 Application 12/713,560 The Examiner acknowledges that Mathew does not disclose forming the metal layer after annealing the adhesion layer. Final Act. 22-23. However, the Examiner finds Sato discloses forming a metal layer after annealing an adhesion layer. Id. at 22. The Examiner concludes it would have been obvious to anneal Mathew's adhesion layer prior to forming the metal layer to enhance the adhesion of the metal layer to the adhesion layer as taught by Sato. Id. Appellants contend that the Examiner's proposed combination of Mathew and Sato fails to teach or suggest each and every element of the claimed invention. Appeal Br. 3. In particular, Appellants argue that Mathew's annealing step is not performed until after both the metal containing film 206, 1006 and the conductive film 308, 1008, and not after the metal containing film is formed but before the conductive film is formed. Id. at 4. Appellants further argue that Sato's anneal or heat treatment is for enhancing bonding between silicon wafers, and is not applicable to annealing of a nickel adhesion layer before formation of a nickel metal layer on the nickel adhesion layer. 11 Id. at 4--5. layers on each other would have been obvious to try, as there are only two readily identified, predictable alternatives, layers formed directly on each other and layers not formed directly on each other. Id. at 18. Even further, the Examiner finds, based on Mathew's teachings, that one of ordinary skill in the art would at once envisage the alternative of directly forming the layers on each other. Id. For reasons explained infra, we need not address these determinations. 11 The Examiner notes Appellants' argument includes reliance on and citation to a reference not relied on in the rejections before us on appeal. Ans. 3--4 (Appeal Br. 5:2-15 apparently refers to Sato, US 5,854,123, issued December 29, 1998). Appellants do not dispute this fact, nor otherwise 5 Appeal2014-003427 Application 12/713,560 We do not find Appellants' arguments persuasive of reversible error in the Examiner's rejection of claim 1. The rejection does not rely on Mathew for teaching of the annealing step before the formation of the metal layer, but instead relies on Sato for this feature. Sato teaches annealing promotes the growth of nickel grains in a base layer containing nickel to enhance the adhesion of a subsequent layer containing nickel to the base layer. Sato 4:66-5: 11. Thus, contrary to Appellants' argument, Sato's teaching is applicable to annealing of a nickel adhesion layer before formation of a nickel metal layer on the nickel adhesion layer. With regard to the Examiner's finding that Mathew's metal layer would inherently have a tensile stress that forms a fracture in the ingot, Appellants urge that the separation of the substrate layer from the ingot of Mathew occurs because of the diffusion of the separation-enhancing species along with stress within the ingot induced by annealing the substrate after formation of the metal layer. Appeal Br. 5. Because the separation of Mathew's substrate layer may be formed by any of these mechanisms "in the absence of any tensile stress in in [sic] a metal layer," Appellants assert Mathew does not inherently teach tensile stress in the metal layer that is configured to cause a fracture in the ingot. Id. Appellants also contend that the tensile stress in the metal layer is not an inherent result of electroplating as taught in Mathew. Reply Br. 4. According to Appellants, "there are many different methods of electroplating, and [] not all methods of electroplating are substantially identical." Id. Appellants assert the explain the relevance of their citation to this second Sato patent. We, therefore, need not further address this aspect of Appellants' argument. 6 Appeal2014-003427 Application 12/713,560 Specification describes an example of an electroplating process that may be used to form a metal layer having a tensile stress, features of which were included in dependent claim 21. 12 Id. Appellants argue that Mathew's electroplating process is not substantially identical to the described and claimed electroplating process for forming a metal layer having a tensile stress. Id. We also do not find these arguments persuasive of reversible error. "[I]t is elementary that the mere recitation of a newly discovered function or property, inherently possessed by things in the prior art, does not cause a claim drawn to those things to distinguish over the prior art. Additionally, where the Patent Office has reason to believe that a functional limitation asserted to be critical for establishing novelty in the claimed subject matter may, in fact, be an inherent characteristic of the prior art, it possesses the authority to require the applicant to prove that the subject matter shown to be in the prior art does not possess the characteristic relied on." In re Best, 562 F.2d 1252, 1254--1255 (CCPA 1977) (quoting In re Swinehart, 439 F.2d 210, 212-13 (CCPA 1971)). Here, the Examiner finds the fracture formation step inherently is caused by tensile stress in the metal layer, noting that the formation of Mathew's metal layer is via an electroplating process substantially identical 12 It has not escaped our attention that although Appellants mention dependent claim 21 in their argument against claim 1, Appellants do not argue claim 21 separately. See Appeal Br. 6; Reply Br. 5. Instead, Appellants argue that neither Wesley nor Ravkin remedy the deficiencies in the combination of Mathew and Sato applied to claim 1. As such, Appellants fail to identify reversible error in the Examiner's findings that Wesley alone, or combined with Ravkin, suggests the electroplating process as recited in claim 21 to one of ordinary skill in the art. 7 Appeal2014-003427 Application 12/713,560 to Appellants', which Appellants teach causes the stressed metal layer to form on the adhesion layer. Final Act. 14; 20-21. Appellants disclose "[ e ]lectroplating causes stressed metal layer 501 to form on adhesion layer 301 .... The tensile stress contained in metal layer 501 may be greater than about 100 megapascals (MPa) in some embodiments." Spec. i-f 20. Appellants further disclose that "[t]he stressed metal layer may be formed by electroplating or electroless plating." Id. at i-f 16. Finally, Appellants disclose that "[ c ]ontrolled spalling may be made to become spontaneous spalling upon heating of the stressed metal 501." Id. at i-f 22. Mathew similarly teaches that the metal layer 308 may be formed by electroplating or electro less plating. Mathew i-f 30. Thus, the Examiner's finding that Mathew's metal layer 308 is inherently tensile stressed is supported by a preponderance of the evidence in the record. Appellants disclose the conditions of one electroplating process for forming a metal layer having tensile stress (Spec. ,-r 19; claim 21 ). However, Appellants neither indicate that these conditions are critical to forming a tensile stressed metal layer or that generally known electroplating processes will not successfully form stressed metal layers. Also, although Appellants assert that not all electroplating processes are substantially identical, Appellants fail to assert that all electroplating processes will not form tensile stressed metal layers. Moreover, even assuming arguendo that Appellants are asserting that not all electroplating processes will form tensile stressed metal layers, Appellants fail to direct our attention to any evidentiary support for such an assertion. As such, Appellants have not shown reversible error in the Examiner's finding that Mathew's metal layer 308 is inherently tensile stressed. 8 Appeal2014-003427 Application 12/713,560 In addition, although Mathew teaches that spalling or fracture may be enhanced or facilitated using separation-enhancing species, and optionally, a wedge, wire or saw, Appellants have not identified reversible error in the Examiner's finding that Mathew's fracture is inherently formed by the tensile stress in the metal layer. In each case, stress must be applied within the ingot to cause fracture and formation of the substrate layer. As the Examiner finds, Mathew's metal layer 308 is inherently tensile stressed. Mathew teaches that, during heating or cooling of the ingot, stress develops near the separation-enhancing species and either causes fracture or makes fracture easier. Mathew i-f 24. Appellants similarly disclose the use of heating to cause spontaneous fracture. Spec. i-f 22. While Mathew's separation-enhancing species, and optional wedge, wire or saw, may facilitate fracture formation, the inherent tensile stress in Mathew's metal layer 308 would also necessarily contribute to fracture formation in the same manner as occurs in Appellants; invention. Thus, a preponderance of the evidence supports the Examiner's finding that Mathew's fracture is inherently formed by the tensile stress in the metal layer 308. Accordingly, we will sustain the Examiner's obviousness rejection of claim 1. Claim 12 Claim 12 depends from claim 1, and further requires that the tensile stress in the metal layer is greater than about 100 megapascals. The Examiner finds, as indicated above, that Mathew's metal layer 308 is inherently tensile stressed. Final Act. 20. The Examiner further finds that this tensile stress "is inherently greater than 100 megapascals" id. at 19. 9 Appeal2014-003427 Application 12/713,560 Appellants focus primarily on the Examiner's inherency finding that Mathew's metal layer 308 is tensile stressed, rather than the specific further inherency finding that this tensile stress is greater than 100 megapascals. Appeal Br. 6; Reply Br. 4. Indeed, Appellants' argument that Mathew cannot teach or suggest a tensile stress greater than 100 megapascals relies on Appellants' prior argument than Mathew's metal layer 308 does not inherently have tensile stress, which we did not find persuasive for the reasons supra. Accordingly, we will sustain the Examiner's obviousness rejection of claim 12. DECISION Upon consideration of the record, and for the reasons given above, in the Final Office Action, and the Examiner's Answer, the decision of the Examiner rejecting claims 1, 3, 5, 6, 8-12, and 21-'23 under 35 U.S.C. § 103(a) as unpatentable over Mathew and Song, alone or further combined with Henley, Wesley, Ravkin, and Zhang is affirmed. No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a)(l). AFFIRMED 10 Copy with citationCopy as parenthetical citation