DONOVAN, Megan et al.Download PDFPatent Trials and Appeals BoardDec 6, 201913589235 - (D) (P.T.A.B. Dec. 6, 2019) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 13/589,235 08/20/2012 Megan DONOVAN 71471 1015 21898 7590 12/06/2019 ROHM AND HAAS COMPANY c/o The Dow Chemical Company P.O. Box 1967 2040 Dow Center Midland, MI 48641 EXAMINER ROBINSON, ELIZABETH A ART UNIT PAPER NUMBER 1787 NOTIFICATION DATE DELIVERY MODE 12/06/2019 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): FFUIMPC@dow.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte MEGAN DONOVAN, ADAM J. FASULA, QIANQIAN LI, SARADA NAMHATA, EDWIN H. NUNGESSER, and WEI ZHANG Appeal 2019-001819 Application 13/589,235 Technology Center 1700 ____________ Before ROMULO H. DELMENDO, JEFFREY B. ROBERTSON, and JAMES C. HOUSEL, Administrative Patent Judges. DELMENDO, Administrative Patent Judge. DECISION ON APPEAL The Appellant1 appeals under 35 U.S.C. § 134(a) from the Primary Examiner’s final decision to reject claims 1 and 13–16.2 We have jurisdiction under 35 U.S.C. § 6(b). We affirm. 1 We use the word “Appellant” to refer to “applicant” as defined in 37 C.F.R. § 1.42. The Appellant identifies the real parties in interest as “Rohm and Haas Company and The Dow Chemical Company” (Appeal Brief filed September 26, 2018 (“Appeal Br.”) at 2). 2 See Appeal Br. 4–10; Reply Brief filed December 28, 2018 (“Reply Br.”) at 2–6; Final Office Action entered April 26, 2018 (“Final Act.”) at 2–9; Examiner’s Answer entered October 31, 2018 (“Ans.”) at 3–8. Appeal 2019-001819 Application 13/589,235 2 I. BACKGROUND The subject matter on appeal relates to a coated substrate comprising a basecoat having a “Pigment Volume Concentration” (PVC) higher than critical PVC (CPVC)3 and a matte clearcoat (Specification filed August 20, 2018 (“Spec.”) at 2, ll. 10–21). Claims 1, 15, and 16 are reproduced from the Claims Appendix to the Appeal Brief, as follows: 1. A coated substrate comprising: (a) a substrate having at least one surface: and, disposed on said surface, (b) a first coating comprising: inorganic pigment, extender, or combination thereof, and having a Pigment Volume Concentration (“PVC”) higher than the critical PVC, and a first polymeric binder comprising an emulsion polymer or polyurethane dispersion, having a calculated Tg of from -60 °C to 150 °C and an average particle diameter of from 50 nm to 490 nm, wherein said first coating does not comprise core/shell polymeric particles having a core comprising, when dry, at least one void having a diameter of from 100 to 1200 nm; and an outer shell, substantially encapsulating 3 The Specification states that “[w]hen a coating is above critical PVC[,] air voids develop in the dry coating[,]” and “[a]t this point, the opacity of the coating is increased due to the relative differences in the refractive index between the coating components (typically 1.4-3.0) and air (1.0)” (Spec. 9, ll. 30–32). The Specification further states (id. at 10, ll. 2–9): To determine if a coating is above or below critical PVC for the purposes of the present invention the difference in reflectance of the paint in the dry state and after re-wetting with a solvent that penetrates into the air voids of the dry paint, fills the void with a higher refractive index solvent and reduces the reflectivity of the coating is measured. The solvent used herein is ISOPAR™ L (ExxonMobil Corp.). When a coating is above critical PVC the reflectance of the coating will decrease by at least 0.3% from the initial reflectance value of the paint. Appeal 2019-001819 Application 13/589,235 3 said core and having a calculated Tg of from -60 °C to 50 °C; and, disposed on said first coating, (c) a clear matte second coating comprising from 1% to 99% by weight, based on the weight of said second coating, of a core/shell particulate polymer comprising, as copolymerized units, from 0.5% to 10% by weight, based on the weight of the particulate polymer, of a multiethylenically unsaturated monomer, and from 1% to 99% by weight, based on the weight of said second coating, of a film-forming emulsion polymer or polyurethane dispersion; wherein the core/shell particulate polymer has a Tg of -60 to 75 °C and a particle diameter of from 0.5 microns to 30 microns; and wherein predominantly the particulate polymer remains a particulate polymer in the dry second coating. 15. The coated substrate of claim 1, wherein the core/shell particulate polymer has a core polymer composition comprising, as copolymerized units, at least 99.9 wt.%, based on the weight of the core polymer, of a combination of butyl acrylate, methyl methacrylate, alpha-methylstyrene, and allyl methacrylate, and a shell polymer composition consisting of, as copolymerized units, methyl methacrylate and ethyl acrylate. 16. The coated substrate of claim 1, wherein the core/shell particulate polymer has a core comonomer composition comprising, as copolymerized units, about 77% by weight butyl acrylate, about 0.4% by weight alpha- methylstyrene, about 3% by weight allyl methacrylate, and about 0.1 % by weight of methyl methacrylate, and a shell comonomer composition consisting of, as copolymerized units, about 18.5% by weight methyl methacrylate and about 1 % by weight ethyl acrylate, wherein all weight percents are based on the weight of the core/shell particulate polymer. (Appeal Br. 11–12 (emphases added)). Appeal 2019-001819 Application 13/589,235 4 II. REJECTIONS ON APPEAL The claims on appeal stand rejected as follows: A. Claims 15 and 16 under pre-AIA 35 U.S.C. § 112 ¶ 1, as failing to comply with the written description requirement; and B. Claims 1 and 13–16 under pre-AIA 35 U.S.C. § 103(a) as unpatentable over Chiou et al.4 (“Chiou”) in view of Wicks, Jr. et al.5 (“Wicks”). (Ans. 3–8; Final Act. 2–9). III. DISCUSSION Rejection A 1. The Examiner’s Position With respect to claims 15 and 16,6 the Examiner finds that “there is no general disclosure of which monomers are in the core and which are in the shell” (Final Act. 2). The Examiner acknowledges, however, that “there is an Example [Sample A described in the original disclosure] with the claimed monomers in the core and shell” but that “this does not support that when specifically used in the core and shell they would be combined at other monomer percentages than those of the example” (id.). Furthermore, with respect to claim 16, the Examiner finds that “given the wording ‘about’ for all weight percentages, this would encompass a range around each weight percentage that is not supported by Sample A” (id.). 4 US 2007/0218291 A1, published September 20, 2007. 5 Zeno W. Wicks, Jr., et al., Organic Coatings: Science and Technology 407–16 (2nd ed. 1998). 6 Claims 15 and 16, which depend from claim 1, were amended during examination on December 21, 2017. Appeal 2019-001819 Application 13/589,235 5 2. The Appellant’s Contentions With respect to claim 15, the Appellant contends that the claim complies with the written description requirement because the original disclosure contains a description of Sample A in which the particulate polymer has a core polymer composition of butyl acrylate (BA), α-methyl styrene (AMS), and allyl methacrylate (ALMA) and a shell copolymer composition of methyl methacrylate (MMA) and ethyl acrylate (EA) (Appeal Br. 4). The Appellant also refers to the original disclosure at page 6, lines 3–24, and the glass transition temperature (Tg) range of -60 to 75°C (id. at 4–5). The Appellant argues that, collectively, these descriptions support the subject matter recited in claim 15 (id.). As for claim 16, the Appellant contends that the claim complies with the written description requirement “because the person of ordinary skill in the art would have a reasonable expectation that comonomer weight fractions slightly below and slightly above the specific weight fractions of Sample A are enabled by the disclosure” (id. at 5 (emphasis added)). According to the Appellant, “[t]he person of ordinary skill in the art would have a reasonable expectation that comonomer weight fractions slightly below and slightly above the specific weight fractions of Sample A would provide core/shell particulate polymers that still meet the claimed Tg (-60 to 75 °C) and particle diameter (0.5 microns to 30 microns) limitations” and “also exhibit substantial stain resistance improvement relative to the first coating” (id.). Significantly, the Appellant argues that the Examiner “neglects ordinary experimental error” and that “[t]he modification of each comonomer weight fraction by ‘about’ allows for this expected experimental error in the core/shell particulate polymer synthesis” (id.). Appeal 2019-001819 Application 13/589,235 6 3. Opinion The Appellant’s arguments fail to identify reversible error in the Examiner’s rejection. In re Jung, 637 F.3d 1356, 1365 (Fed. Cir. 2011). The written description requirement does not require in haec verba support. In re Alton, 76 F.3d 1168, 1175 (Fed. Cir. 1996). Nevertheless, “the test for sufficiency is whether the disclosure of the application relied upon reasonably conveys to those skilled in the art that the inventor had possession of the claimed subject matter as of the filing date.” Ariad Pharms., Inc. v. Eli Lilly & Co., 598 F.3d 1336, 1351 (Fed. Cir. 2010). Claim 15, reproduced above, recites that “the core/shell particulate polymer has a core polymer composition comprising, as copolymerized units, at least 99.9 wt.%, based on the weight of the core polymer, of a combination of butyl acrylate [BA], methyl methacrylate [MMA], alpha- methylstyrene [AMS], and allyl methacrylate [ALMA]” (emphases added). The Specification, as originally filed, contains a description of Sample A in which the seed (core) polymer consists of 5113.0 g of BA, 26.8 g of AMS, and 214.2 g of ALMA (Spec. 13, l. 29–15, l. 18). Sample A’s core polymer, however, does not include MMA—i.e., methyl methacrylate. Although the Specification mentions the possibility of including MMA among numerous other monomers in the particulate polymer (Spec. 6, ll. 3–24), it does not specify whether the MMA should be included in the core polymer, the shell polymer, or both—let alone in a core polymer comprising “at least 99.9 wt.%, based on the weight of the core polymer, of a combination of butyl acrylate [BA], methyl methacrylate [MMA], alpha-methylstyrene, and allyl methacrylate “ as recited in claim 15. The broad Tg and particle diameter ranges recited in claim 1 are of no help to the Appellant because unguided Appeal 2019-001819 Application 13/589,235 7 picking and choosing would be required to arrive at the specified monomer composition for the core polymer. Thus, although the subject matter recited in claim 15 may have been obvious over the original disclosure as a whole, obviousness is not the proper test for written description. Lockwood v. Am. Airlines, Inc., 107 F.3d 1565, 1572 (Fed. Cir. 1997) (“One shows that one is ‘in possession’ of the invention by describing the invention, with all its claimed limitations, not that which makes it obvious.”). Claim 16, reproduced above, recites “a core comonomer composition comprising, as copolymerized units, about 77% by weight butyl acrylate, about 0.4% by weight alpha-methylstyrene, about 3% by weight allyl methacrylate, and about 0.1 % by weight of methyl methacrylate” (emphases added). For the same or similar reasons, we find that the original disclosure does not provide adequate written description support for claim 16, which specifies a core copolymer that contains BA, AMS, ALMA, and MMA in the amounts as recited in claim 16. Neither the description for Sample A nor the generic disclosure in the Specification (Spec. 6, ll. 3–24) mentions the copolymerization of MMA as part of the core polymer in the relative amounts as recited in claim 16. And, again, even with the broad Tg and particle diameter ranges recited in claim 1, indiscriminate picking and choosing would be required to arrive at the specified monomer compositions in the amounts as recited in claim 16. Moreover, contrary to the Appellant’s unsupported allegation, the Specification does not include any indication that the term “about” is intended to be limited to deviations approximating experimental errors, particularly with respect to the amounts for the specific monomers disclosed for the core polymer and the shell polymer in Sample A. See, e.g., Pall Appeal 2019-001819 Application 13/589,235 8 Corp. v. Micron Separations, Inc., 66 F.3d 1211, 1217 (Fed. Cir. 1995) (explaining that the use of the word “about” avoids a strict numerical boundary to the specified parameter, but that the degree of latitude or tolerance must be ascertained by consulting, e.g., the descriptions in the relevant specification). For these reasons, we sustain the Examiner’s rejection on this ground. Rejection B 1. Grouping of Claims Although the Appellant provides additional arguments for claim 14, those arguments rely on the same arguments offered for the other claims (Appeal Br. 6–10). Therefore, we decide this appeal on the basis of claim 1, which we designate as representative pursuant to 37 C.F.R. § 41.37(c)(1)(iv). Claims 13–16 stand or fall with claim 1. 2. The Examiner’s Position The Examiner finds that Chiou describes a coated substrate that can include all the limitations recited in claim 1 except for the requirement that the PVC in the first coating is higher than the CPVC (Final Act. 3–4). To resolve this difference, the Examiner relies on Wicks, which was found to teach that “underlayers having a PVC greater than the critical PVC (CPVC) provide better adhesion to the topcoat and better hiding of the underlying substrate” (id. at 4). Based on these findings, the Examiner concludes that “[i]t would have been obvious to one of ordinary skill in the art . . . to have the underlayer between the substrate and topcoat of Chiou have a PVC greater than the CPVC using inorganic pigments, in order to provide better Appeal 2019-001819 Application 13/589,235 9 adhesion for the topcoat and/or better hiding of the substrate as taught by Wicks” (id. at 4–5). 3. The Appellant’s Contentions The Appellant does not dispute the Examiner’s findings regarding Chiou’s scope and content (Appeal Br. 7–9). Rather, the Appellant contends that the claimed subject matter would not have been obvious to a person having ordinary skill in the art because “in addition to providing one advantage to having CPVC > PVC, Wicks also teaches several disadvantages to having CPVC > PVC” (id. at 7). Citing Wicks’s Fig. 21.2 (Wicks 408), the Appellant argues that “[a]s can be seen from graphs (b) and (c), both tensile strength and fracture value drop precipitously at PVC higher than CPVC” (id. at 8). The Appellant also argues that Wicks teaches additional disadvantages for PVC > CPVC because the reference teaches that “if one applies a single coat of a coating with PVC above CPVC to steel and exposes the panel to humidity, rapid rusting can occur, since the pores permit water and oxygen to get to the surface of the steel with little interference” (id. at 8 (quoting Wicks 408–409)). According to the Appellant, “giving substantially more weight to the one advantage accruing to CPVC > PVC than the many disadvantages likewise accruing to CPVC > PVC, appears to be an example of impermissible hindsight” (id.). 4. Opinion We are in complete agreement with the Examiner that the claimed subject matter would have been obvious to a person having ordinary skill in the art. In describing the relationship between a film’s properties and PVC, Wicks lists both the advantages and disadvantages of having a coating with Appeal 2019-001819 Application 13/589,235 10 PVC > CPVC (Wicks 408–409). Specifically, Wicks teaches an advantage, as follows: It is sometimes desirable to design a primer with PVC greater than CPVC. Adhesion of a top coat to such a primer is enhanced by mechanical interlocking resulting from penetration of vehicle from the top coat into pores of the primer. Many of the pores in the primer are filled with binder from the top coat, which decreases the PVC of the top coat resulting in loss of gloss of the top coat. Such a primer is said to have poor enamel hold out. The primer PVC should be only enough higher than CPVC to provide adhesion to minimize loss of gloss of the top coat. (Id. at 409). Wicks teaches that a further advantage of PVC > CPVC is that an “increase in hiding above CPVC results from air voids left in the film when PVC is above CPVC” and that such an “increase in hiding above CPVC can be useful” and “particularly desirable in ceiling paints” (id. at 409–410). Thus, although Wicks does teach some disadvantages (e.g., a decrease in tensile strength and adhesion above CPVC as shown in Fig. 21.1(b) and (c) (id. at 408), we agree with the Examiner (Ans. 5) that the person having ordinary skill in the art would have considered both the advantages and disadvantages disclosed in Wicks and that the mere existence of some disadvantages in certain situations does not negate a motivation or reason to combine Wicks with Chiou. Medichem S.A. v. Rolabo, S.L., 437 F.3d 1157, 1165 (Fed. Cir. 2006) (“[A] given course of action often has simultaneous advantages and disadvantages, and this does not necessarily obviate motivation to combine.”). Additionally, claim 1 reads on situations in which PVC is only slightly higher than CPVC or even higher levels to the extent that the tensile strength or adhesion levels would not result in an unusable coating. As Appeal 2019-001819 Application 13/589,235 11 shown in Wicks’s Fig. 21.1 (a) and (b), the decreases in tensile strength and adhesion at PVC levels only slightly above CPVC are not significant and, even in the case of much higher PVC levels, some level of tensile strength or adhesion is maintained. Thus, Wicks does not indicate that PVC > CPVC would result in an unusable coated substrate in all instances, and, in any event, a person having ordinary skill in the art would have balanced the advantages against the disadvantages. For these reasons, and those well-stated by the Examiner, we uphold the Examiner’s rejection. IV. CONCLUSION In summary: Claims Rejected 35 U.S.C. § Reference(s)/ Basis Affirmed Reversed 15, 16 112 ¶ 1 Lack of Written Description 15, 16 1, 13–16 103(a) Chiou, Wicks 1, 13–16 Overall Outcome 1, 13–16 No time period for taking any subsequent action in connection with this appeal may be extended under 37 C.F.R. § 1.136(a). AFFIRMED Copy with citationCopy as parenthetical citation