ASM IP HOLDING B.V.Download PDFPatent Trials and Appeals BoardFeb 2, 20212020004918 (P.T.A.B. Feb. 2, 2021) Copy Citation UNITED STATES PATENT AND TRADEMARK OFFICE UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www.uspto.gov APPLICATION NO. FILING DATE FIRST NAMED INVENTOR ATTORNEY DOCKET NO. CONFIRMATION NO. 15/581,726 04/28/2017 Elina Färm ASMMC.130AUS 4248 68852 7590 02/02/2021 Knobbe, Martens, Olson & Bear LLP ASM IP HOLDING B.V. 2040 Main Street 14th Floor Irvine, CA 92614 EXAMINER CHOUDHRY, MOHAMMAD M ART UNIT PAPER NUMBER 2816 NOTIFICATION DATE DELIVERY MODE 02/02/2021 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address(es): asm.pair@anaqua.com efiling@knobbe.com jayna.cartee@knobbe.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE ____________ BEFORE THE PATENT TRIAL AND APPEAL BOARD ____________ Ex parte ELINA FÄRM, HIDEMI SUEMORI, RAIJA MATERO, ANTTI NISKANEN, SUVI P. HAUKKA, and EVA TOIS ____________ Appeal 2020-004918 Application 15/581,726 Technology Center 2800 ____________ Before MAHSHID D. SAADAT, JEAN R. HOMERE, and BRADLEY W. BAUMEISTER, Administrative Patent Judges. SAADAT, Administrative Patent Judge. DECISION ON APPEAL1 Appellant2 appeals under 35 U.S.C. § 134(a) from the Examiner’s non-final rejection of claims 1–23, which constitute all the claims pending in this application. Appeal Br. 15 (Claims App.) We have jurisdiction under 35 U.S.C. § 6(b). We REVERSE. 1 An oral hearing was held for this appeal on January 11, 2021. A transcript of the oral hearing will be entered into the record in due course. 2 We use the word “Appellant” to refer to “applicant” as defined in 37 C.F.R. § 1.42. Appellant identifies the real party in interest as ASM IP Holding B.V. Appeal Br. 3. Appeal 2020-004918 Application 15/581,726 2 STATEMENT OF THE CASE Introduction According to the Specification, the claimed subject matter relates to a selective deposition process in the field of semiconductor device manufacturing and, “more particularly, to selective deposition of a material on a first surface of a substrate relative to a second organic surface.” Spec. ¶¶ 2–3. Claim 1 illustrates the invention and reads as follows: 1. A vapor deposition process for selectively depositing a material on a first surface of a substrate relative to a second organic surface, the method comprising: contacting the substrate with a first vapor phase hydrophobic reactant; and contacting the substrate with a second vapor phase reactant, wherein the material is deposited selectively on the first surface relative to the second organic surface. See Appeal Br. 15 (Claims App.). References and Rejections The Examiner relies on the following prior art: Name Reference Date Besser US 2002/0027261 Al Mar. 7, 2002 Bice US 2003/0176559 Al Sept. 18, 2003 George US 2005/0012975 Al Jan. 20, 2005 Frey US 2006/0121271 Al June 8, 2006 Cissell US 2013/0122722 Al May 16, 2013 Haukka US 2013/0196502 Al Aug. 1, 2013 Monroe US 2015/0083415 Al Mar. 26, 2015 Wang US 2017/0107413 Al Apr. 20, 2017 Claims 1, 2, 6, 7, 8, 10, 12, 13, 15, 20, and 21 stand rejected under 35 U.S.C. § 103(a) as being unpatentable over Besser and George. Final Act. 2–5. Appeal 2020-004918 Application 15/581,726 3 Claim 3 stands rejected under 35 U.S.C. § 103(a) as being unpatentable over Besser, George, and Wang. Final Act. 5–6. Claims 4 and 5 stand rejected under 35 U.S.C. § 103(a) as being unpatentable over Besser, George, and Monroe. Final Act. 6. Claims 9, 11, and 22 stand rejected under 35 U.S.C. § 103(a) as being unpatentable over Besser, George, and Frey. Final Act. 6–7. Claims 14 and 23 stand rejected under 35 U.S.C. § 103(a) as being unpatentable over Besser, George, and Haukka. Final Act. 7–8. Claim 16 stands rejected under 35 U.S.C. § 103(a) as being unpatentable over Besser, George, and Cissell. Final Act. 8. Claims 17–19 stand rejected under 35 U.S.C. § 103(a) as being unpatentable over Besser, George, and Bice. Final Act. 8–9. ANALYSIS We have reviewed the rejections in light of Appellant’s arguments that the Examiner erred. For the reasons explained below, we concur with Appellant’s arguments concerning unpatentability under § 103. We add the following to address and emphasize specific findings and arguments. In rejecting claim 1, the Examiner relies on Besser as disclosing the recited “vapor deposition process for selectively depositing a material on a first surface of a substrate relative to a second organic surface.” Final Act. 2–3 (citing Besser Fig. 2, ¶¶ 11, 56, 57). The Examiner specifically states: Besser discloses a vapor deposition process for selectively depositing a material on a first surface (Fig. 2; surface 6) of a substrate (Para 0057; Fig. 2; at least one thin layer 7 comprising at least one passivant element (e.g., Ni) for the metal 5 (e.g., unalloyed Cu) of the in-laid metal feature(s) of the metallization pattern is selectively deposited on the exposed, upper surface 6 Appeal 2020-004918 Application 15/581,726 4 thereof) relative to a second organic surface (Para 0056; Fig. 2; surface 4 of a layer 3 wherein layer 3 can be organic polymeric material), the method comprising: wherein the material is deposited selectively on the first surface (Para 0057; surface 6) relative to the second organic surface (Para 0011 and 0056- 0057; Fig. 2; metal 5 is selectively deposited on the exposed, upper surface 6 relative to surface 4. According to BRI “relative” can be interpreted as metal 5 is deposited on surface 6 but not on surface 4 (organic surface)). Id. The Examiner further relies on George as disclosing “contacting the substrate with a first vapor phase hydrophobic reactant; and contacting the substrate with a second vapor phase reactant.” Final Act. 3 (citing George ¶¶ 112, 114, 160). The Examiner concludes that it would have been obvious to one of ordinary skill in the art to use George’s disclosure in Besser’s process to provide “a surface that is less favorable to adsorption of water.” Id. Appellant contends the Examiner erred in concluding that the combination of Besser with George teaches or suggests the claimed invention because Besser is concerned with passivating the top surface of a copper metal feature and George relates to a hydrophobic coating of a micro-mechanical device. Appeal Br. 6–7. Appellant asserts that [t]he cited paragraphs of George do not teach a method of selectively depositing any material by contacting a substrate with a hydrophobic reactant and a second reactant, much less a passivation layer that could not only function in the context of Besser but serve the particular functions that Besser requires. Appeal Br. 7. Appellant also argues that there is no reason to combine the references because Besser is not concerned with water exposure[,] which is addressed in George by depositing a hydrophobic layer on a micro-mechanical device Appeal 2020-004918 Application 15/581,726 5 that allows using the device in a humid environment. Appeal Br. 9. According to Appellant, “[t]here is no indication of how the deposition process of George could be carried out successfully in the context of Besser, and no teaching of how selective deposition would be achieved.” Appeal Br. 10. The Examiner responds by explaining that, in view of the broadest reasonable interpretation of the claim term “relative,” Besser discloses selective deposition of a passivant element on surface 6 of the metal layer, but not on surface 4 of the dielectric layer, which may be an organic material. Ans. 4 (citing Besser Fig. 2, ¶¶ 56, 57). With respect to George’s teachings, the Examiner further points to Figure 18 and paragraph 18 and explains “George discloses contacting the substrate with a first vapor phase hydrophobic reactant (¶; 0112 and 0114); and contacting substrate with a second vapor phase reactant (¶0160).” Ans. 5. Next, the Examiner clarifies the reason for combining the references as “one of an ordinary [skill understood] that techniques and material applied to prevent moisture issues during lithographic process can be used to apply on devices to encapsulate and vice versa.” Ans. 6; see also Ans. 7. We agree with Appellant’s contention that the references’ teachings concern different aspects of device manufacturing. The cited portions of Besser disclose a process for depositing a passivating metallic layer over copper interconnect areas which, although requires selective deposition, does not involve using a vapor hydrophobic reactant for the selective deposition on a first surface relative to an organic surface, as claimed. The only reference made in Besser to “an organic” material is in the context of different types of materials suitable for inter-dielectric layer 3, as shown in Figure 2. See Besser ¶ 56. Appeal 2020-004918 Application 15/581,726 6 George, on the other hand, discloses using a hydrophobic material as the passivating layer over a micro-mechanical device that is used in a humid environment, but not as a tool for selective deposition of any material. See George Fig. 16, ¶¶ 110–114. We therefore agree with Appellant’s argument that the Examiner has not sufficiently explained how combining the passivating layer of George with the process disclosed by Besser for deposition a metal layer over copper interconnects would teach or suggest the recited claim features. In fact, the Examiner has not identified any teachings in Besser or George to support the assertion that providing “a surface that is less favorable to adsorption of water” would justify the combination or even result in the recited process for selectively depositing a material. See Ans. 5–7. That is, even if Besser is modified with George to use a hydrophobic passivating layer over the device, the Examiner has not explained how the modification would relate to deposition a material selectively over a first surface relative to a second organic surface. See also Reply Br. 6–9. Conclusion For the above reasons, we agree with Appellant that the Examiner’s proposed combination does not teach or suggest the recited features of claim 1. The Examiner has not identified any teachings in the other applied prior art references to cure the above-identified deficiency. Therefore, Appellant’s arguments have persuaded us of error in the Examiner’s position with respect to the rejections of independent claim 1, other independent claim which recites similar limitations (see claim 15), as well as the remaining claims dependent therefrom. See Appeal Br. 15–16 (Claims App.). Appeal 2020-004918 Application 15/581,726 7 DECISION SUMMARY In summary: Claims Rejected 35 U.S.C. § Basis Affirmed Reversed 1, 2, 6, 7, 8, 10, 12, 13, 15, 20, 21 103 Besser, George 1, 2, 6, 7, 8, 10, 12, 13, 15, 20, 21 3 103 Besser, George, Wang 3 4, 5 103 Besser, George, Monroe 4, 5 9, 11, 22 103 Besser, George, Frey 9, 11, 22 14, 23 103 Besser, George, Haukka 14, 23 16 103 Besser, George, Cissell 16 17–19 103 Besser, George, Bice 17–19 Overall Outcome 1–23 REVERSED Copy with citationCopy as parenthetical citation